Orthogonality of spherical harmonic coefficients

An essentially arbitrary function V(θ, λ) defined on the surface of a sphere can be expressed in terms of spherical harmonics $\text{V(θ, Λ) = a}\text{∑}\text{n=1}\text{∞}\text{∑}\text{m=0}\text{n}\text{p}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{(cos θ) (g}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{cos mΛ + h}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{sin mΛ)}$ where the P_n^m are the seminormalized associated Legendre polynomials used in geomagnetism, normalized so that $\text{〈[P}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{(cos θ) cos mΛ]〉}{}^2\text{=1/}\text{(2n+1)}$ The angular brackets denote an average over the sphere. The class of functions V(θ, λ) under consideration is that normally of interest in physics and engineering. If we consider an ensemble of all possible orientations of our coordinate system relative to the sphere, then the coefficients g_n^m and h_n^m will be functions of the particular coordinate system orientation, but $\text{〈:(g}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{)}{}^2\text{〉) = 〈(h}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{)}{}^2\text{=}\text{S}{}_{\mathrm{n}}\text{/}\text{(2n=1)}$ where $\text{S}{}_{\mathrm{n}}\text{=}\text{∑}\text{m=0}\text{n}\text{[(g}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{)}{}^2\text{+ (h}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{)}{}^2\text{]}$ for any orientation of the coordinate system (S_n is invariant under rotation of the coordinate system). The averages are over all orientations of the system relative to the sphere. It is also shown that 〈g^m_ng^l_p〉 = 〈h^m_nh^l_p〉 = 0 for l ≠ m or p ≠ n and 〈g^m_nh^l_p〉 = 0 fro all n, m, p, l.     

High-pressure recovery of olivine: implications for creep mechanisms and creep activation volume

High-temperature and high-pressure recovery experiments were made on experimentally deformed olivines at temperatures of 1613–1788 K and pressures of 0.1 MPa to 2.0 GPa. In the high-pressure experiments, a piston cylinder apparatus was used with BN and NaCl powder as the pressure medium, and the hydrostatic condition of the pressure was checked by test runs with low dislocation density samples. No dislocation multiplication was observed. The kinetics of the dislocation annihilation process were examined by different initial dislocation density runs and shown to be of second order, i.e.

$\text{d}\text{ρ}\text{d}\text{t}\text{= ?p}{}^2\text{K}{}_0\text{exp}\text{[?(}\text{E}{}^1\text{+PV}{}^1\text{RT}\text{]}$

where ρ is the dislocation density, k₀ is a constant, $\text{E}{}^1\text{and}\text{V}{}^1$ are the activation energy and volume respectively, and P, R and T are pressure, gas constant and temperature, respectively. Activation energy and volume were estimated from the temperature and pressure dependence of the dislocation annihilation rate as $\text{E}{}^1\text{=389±59}\text{kJ mol}{}^{\mathrm{?1}}$ and $\text{V}{}^1\text{=14±2}\text{cm}{}^3\text{mol}{}^{\mathrm{?1}}$, respectively.The diffusion constants relevant to the dislocation annihilation process were estimated from a theoretical relation k=αD where $\text{k=k}{}_0\text{exp}\text{[?(E}{}^1\text{+ PV}{}^1\text{)/RT], D}$ is the diffusion constant and α is a non-dimensional constant of ca. 300. The results agree well with the self-diffusion constant of oxygen in olivine. This suggests that the dislocation annihilation is rate-controlled by the (oxygen) diffusion-controlled dislocation climb.The mechanisms of creep in olivine and dry dunite are examined by using the experimental data of static recovery. It is suggested that the creep of dry dunite is rate-controlled by recovery at cell walls or at grain boundaries which is rate-controlled by oxygen diffusion. Creep activation volume is estimated to be 16±3 cm³ mol^?1.     

Physical constraints for the analysis of the geomagnetic secular variation

Slow changes in the magnetic field are believed to originate in the core of the Earth. Interpretation of these changes requires knowledge both of the vertical component of the field and of its rate of change at the core-mantle boundary (CMB). While various spherical harmonic models show some agreement for the field at the CMB, those for secular variation (SV) do not. SV models depend heavily on annual means at relatively few and poorly distributed magnetic observatories. In this paper, the SV at the CMB is modelled by fitting 15-year differences in the annual means of the X, Y and Z components (from 1959 to 1974). The model is made unique by imposing the constraint that $\text{?}{}_{\mathrm{CMB}}\text{B}\text{?}{}_{\mathrm{r}}{}^2\text{d}\text{S}$ be a minimum, using the method of Shure et al. (1982). If SV is attributed to motions of core fluid, then this model will yield, in some sense, the slowest core motions. The null space is determined by the distribution of observations, and therefore, to be consistent, only those observatories have been retained which recorded almost continuously throughout the interval 1959–1974.The method allows misfit between the model and the observations. The best value for the misfit can be derived from estimates of errors in the data, or alternatively, because larger misfit leads to smoother models (i.e., smaller $\text{?}\text{B}\text{?}{}_{\mathrm{r}}{}^2\text{d}\text{S}$), the best value can be estimated subjectively from the final appearance of the model. Both procedures have their counterparts in the conventional spherical harmonic expansion approach, when smoothing is achieved by lowering the truncation level. The new proposal made in this paper is to use objective criteria for determining the misfit, based on the assumption that diffusion is negligible, in which event all integrals $\text{∫}\text{B}\text{?}{}_{\mathrm{r}}{}^2\text{d}\text{S}$ will vanish when S_i is a region on the CMB bounded by a contour of zero vertical component of field. For the 1965 definitive model which is adopted here, and for most other contemporary models, there are six such areas, giving five independent integrals (the integrals over the six regions must sum to zero if ? · B = 0). Tabulating these integrals for various choices of the misfit gives minimum values near 2 nT y^?1. It is impossible to achieve this good a fit to the data using a reasonable model derived by truncating the spherical harmonic expansion. The value 2 nT y^?1 corresponds to errors of ～ 20 nT in individual annual means, which is rather larger than expected from the scatter in the data.     

Theoretical estimates of the westward drift

Virtually all dynamo models may be expected to give rise to a permanent differential rotation between mantle and core. Weak conductivity in the mantle permits small leakage currents which couple to the radial component of the magnetic field, producing a Lorentz torque. Mechanical equilibrium is achieved when a zero net torque is established at a critical rotation rate. An estimate of the drift is determined easily given the magnetic field structure predicted by any dynamo model. The result for the drift rate at the core-mantle interface along the equator is given by the product of three factors

$\text{U}{}_{\mathrm{\phi 1}}\text{=U}{}_{\mathrm{\phi }}\text{R}\text{λ}{}_{\mathrm{*}}\text{L}{}_{\mathrm{*}}$

The first of these is a geometrical factor which depends only on the structural character of the field. For a variety of model fields, this factor ranges from 16 to 35. The second factor is the ratio of r.m.s. toroidal to poloidal field. This ratio is an (implicitly) adjustable parameter of both α² and α-ω dynamos, and is a measure of the relative efficiency of the generation process for each component. The third (dimensional) term is the ratio of core magnetic diffusivity to core radius, 10^?4 cm s^?1.The result is essentially independent of the value of mantle diffusivity and its effective depth. The sign of the result may be positive or negative. For α² dynamos a westward drift is produced by choosing α > 0 in the Northern Hemisphere, which constitutes a dynamical assertion about the dynamo process. For an r.m.s. toroidal field of the order of 15 Gs, based on fairly general considerations, a drift rate comparable to observation is expected.     

Melting temperature distribution and fractionation in the lower mantle

The melting curve of perovskite MgSiO₃ and the liquidus and solidus curves of the lower mantle were estimated from thermodynamic data and the results of experiments on phase changes and melting in silicates.The initial slope of the melting curve of perovskite MgSiO₃ was obtained as $\text{d}\text{T}{}_{\mathrm{<mtext>m</mtext>}}\text{/}\text{d}\text{P?77}\text{K}\text{GPa}{}^{\mathrm{?1}}$ at 23 GPa. The melting curve of perovskite was expressed by the Kraut-Kennedy equation as $\text{T}{}_{\mathrm{<mtext>m</mtext>}}\text{(}\text{K}\text{)=917(}\text{1+29.6ΔV}\text{V}{}_0\text{)}$, where T_m?2900 K and P?23 GPa; and by the Simon equation, $\text{P(}\text{GPa}\text{)?23=21.2[}\text{(T}{}_{\mathrm{<mtext>m</mtext>}}\text{(}\text{K}\text{)}\text{2900)}{}^{1.75}\text{?1}\text{]}$.The liquidus curve of the lower mantle was estimated as $\text{T}{}_{\mathrm{<mtext>liq</mtext>}}\text{? 0.9 T}{}_{\mathrm{<mtext>m</mtext>}}$ (perovskite) and this gives the liquidus temperature T_liq=7000 ±500 K at the mantle-core boundary. The solidus curve of the lower mantle was also estimated by extrapolating the solidus curve of dry peridotite using the slope of the solidus curve of magnesiowüstite at high pressures. The solidus temperature is ～ 5000 K at the base of the lower mantle. If the temperature distribution of the mantle was 1.5 times higher than that given by the present geotherm in the early stage of the Earth's history, partial melting would have proceeded into the deep interior of the lower mantle.Estimation of the density of melts in the MgOFeOSiO₂ system for lower mantle conditions indicates that the initial melt formed by partial fusion of the lower mantle would be denser than the residual solid because of high concentration of iron into the melt. Thus, the melt generated in the lower mantle would tend to move downward toward the mantle-core boundary. This downward transportation of the melt in the lower mantle might have affected the chemistry of the lower mantle, such as in the D″ layer, and the distribution of the radioactive elements between mantle and core.     

Observational study of terrestrial eigenvibrations

A comprehensive analysis has been made of analog and digital recordings of eigenvibration ground motion obtained following four great earthquakes; August 1976 (Philippines), August 1977 (Indonesia), September 1979 (West Irian), and December 1979 (Colombia). The time series (ranging in length from ～28 to ～140 h) are assumed to be linear combinations of damped harmonics in the presence of noise. Tables are calculated from values of the four parameters: Θ, used in describing eigenvibrations, period of oscillation, amplitude, damping factor Q, and phase together with their statistical uncertainties (53 spheroidal modes, ${}_0\text{S}{}_4\text{to}{}_0\text{S}{}_{48}$, and 13 torsional modes, ${}_0\text{T}{}_8\text{to}{}_0\text{T}{}_{45}$). The estimation procedures are by the methods of complex demodulation and non-linear regression that specifically incorporate into the basic model the decaying aspect of the oscillations. These methods, extended to simultaneous estimations of groups of modes, help to eliminate measurement error and measurement bias from estimations of Θ. The result is that overtone modes very near in frequency to fundamental modes can, under certain conditions, be resolved through a non-linear regression technique, although parameter uncertainties are underestimated in general.Of the time series analyzed, 17 were from a northern California regional network of ultra-long period seismographs at Berkeley (three components), Jamestown (vertical component), and Whiskeytown (vertical component) following the four listed earthquakes. The other 7 time series were recorded digitally by the worldwide IDA network following the 1977 Indonesian earthquake. Weighted regional and worldwide averages were made for period and Q of each eigenvibration mode.From the theoretical viewpoint, comparisons of measured period, Q, amplitude, and phase for all modes analyzed led to five conclusions. First, there are no detectable systematic shifts in period, Q, or phase of eigenvibrations within a region whose dimensions are less than a wavelength. Second, though not conclusive, there may be slight systematic shifts in period (<0.65 s) and relative amplitudes within the California regional network due to different source positions and mechanisms. Differences in Q values are not statistically significant. Third, even though differences in period obtained worldwide were as great as 1.33 s (≈0.33%), differences between Q values (as great as 20%) for the same mode were not significant. The conclusion is that the damping characteristics of singlet eigenfunctions are not observed to be significantly different. Fourth, the assumption that a multiplet ${}_{\mathrm{n}}\text{S}{}_{\mathrm{l}}$ behaves as a single oscillation is valid from at least ${}_0\text{S}{}_7$ through ${}_0\text{S}{}_{30}$. Fifth, no systematic pattern emerged for the shift of eigenperiod as a function of order / or posit on the Earth.     

Spatial power spectra of the crustal geomagnetic field and core geomagnetic field

Lowes (1966, 1974) has introduced the function R_n defined by $\text{R}{}^{\mathrm{n}}\text{=(n + 1)}\text{∑}\text{m=0}\text{∞}\text{[(g}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{)}{}^2\text{+ (h}{}^{\mathrm{m}}{}_{\mathrm{n}}\text{)}{}^2\text{]}\text{where}\text{g}{}_{\mathrm{n}}{}^{\mathrm{m}}\text{and}\text{h}{}_{\mathrm{n}}{}^{\mathrm{m}}$ are the coefficients of a spherical harmonic expansion of the scalar potential of the geomagnetic field at the Earth's surface. The mean squared value of the magnetic field B = ??V on a sphere of radius r > α is given by $\text{〈}\text{B}\text{·〉 =}\text{∑}\text{n=1}\text{∞}\text{R}{}^{\mathrm{n}}\text{(}\text{a/}\text{r}\text{)}{}^{\mathrm{2n=4}}\text{where}\text{a}$ is the Earth's radius. We refer to R_n as the spherical harmonic spatial power spectrum of the geomagnetic field.In this paper it is shown that Rⁿ = R^M_n = R^C_n where the components R_n^M due to the main (or core) field and R_n^C due to the crustal field are given approximately by $\text{R}{}^{\mathrm{M}}{}_{\mathrm{n}}\text{= [}\text{(n =1)/}\text{(n + 2)}\text{](1.142 × 10}{}^9\text{)(0.288}{}^{\mathrm{n}}\text{Λ}{}^2\text{R}{}^{\mathrm{C}}{}_{\mathrm{n}}\text{= [}\text{(n =1){[1 — exp(-n/290)]/}\text{(n/290)} 0.52 Λ}{}^2\text{where}\text{Iγ = 1 nT}$. The two components are approximately equal for n = 15.Lowes has given equations for the core and crustal field spectra. His equation for the crustal field spectrum is significantly different from the one given here. The equation given in this paper is in better agreement with data obtained on the POGO spacecraft and with data for the crustal field given by Alldredge et al. (1963).The equations for the main and crustal geomagnetic field spectra are consistent with data for the core field given by Peddie and Fabiano (1976) and data for the crustal field given by Alldredge et al. The equations are based on a statistical model that makes use of the principle of equipartition of energy and predicts the shape of both the crustal and core spectra. The model also predicts the core radius accurately. The numerical values given by the equations are not strongly dependent on the model.Equations relating average great circle power spectra of the geomagnetic field components to R_n are derived. The three field components are in the radial direction, along the great circle track, and perpendicular to the first two. These equations can, in principle, be inverted to compute the R_n for celestial bodies from average great circle power spectra of the magnetic field components.     

Variation of the magnetic properties in a basaltic dyke with concentric cooling zones

The effects of the variation of magnetic grain size on the magnetic properties of rocks have been studied throughout a reversely magnetized basaltic dyke with concentric cooling zones.Except in a few tachylites in which the magnetic mineral is a Ti-rich titanomagnetite, in the bulk of the dyke the magnetization is carried by almost pure magnetite grains. Although the percentage p of these magnetic oxides varies slightly, the large changes in the various magnetic parameters observed across the dyke are essentially attributable to large variations in the grain size of the magnetic particles.From the outer scoria region, where the magnetic grains are a mixture of single-domain (SD) and superparamagnetic (SP) grains, to the tachylite zone with finely crystallized basaltic glass containing interacting elongated SD particles, one observes an increase of both the ratio of the saturation remanent magnetization and the saturation induced magnetization J_rs/J_is, the bulk coercive force H_c, the median destructive field MDF, the intensity of the remanent magnetization J_r, and the Koenigsberger ratio Q. In the tachylites these parameters reach unusually high values, for subaerial basalts:

$\text{〈}\text{J}{}_{\mathrm{rs}}\text{J}{}_{\mathrm{is}}\text{〉 = 0.3, 〈H}{}_{\mathrm{c}}\text{〉 = 460 O}{}_{\mathrm{e}}\text{, 〈MDF〉 = 620 O}{}_{\mathrm{e}}\text{r.m.s., 〈J}{}_{\mathrm{r}}\text{〉 = 2.7 · 10}{}^{\mathrm{?2}}\text{e.m.u. cm}{}^{\mathrm{?3}}\text{〈Q〉 = 24}$

These parameters decrease in the basalt toward the centre of the dyke where pseudo-single-domain (pseudo-SD) particles coexist together with multidomain (MD) grains. The susceptibility remains approximately constant from the inner basalt to the tachylite, but increases in the scoria up to values 10 times higher owing to the presence of SP particles. The magnetic viscosity increases also drastically toward the margin of the dyke due to an increase of the fraction of the SD particles just above the superparamagnetic threshold.     

Applications of liquid state physics to the Earth's core

By use of the modern theory of liquids and some guidance from the hard-sphere model of liquid structure, the following new results have been derived for application to the Earth's outer core. (1) dK/$\text{d}\text{P ? 5 ? 5. 6P}$/K, where K is the incompressibility and P the pressure. This is valid for a high-pressure liquid near its melting point, provided that the pressure is derived primarily from a strongly repulsive pair potential φ. This result is consistent with seismic data, except possibly in the lowermost region of the outer core, and demonstrates the approximate universality of dK/dP proposed by Birch (1939) and Bullen (1949). (2) dlnT_M/dlnρ = (γC_V ? 1)/($\text{C}{}_{\mathrm{<mtext>V</mtext>}}\text{?}\text{3}\text{2}\text{),}\text{where}\text{T}{}_{\mathrm{<mtext>M</mtext>}}$ is the melting point, ρ the density, γ the atomic thermodynamic Grüneisen parameter and C_V the atomic contribution to the specific heat in units of Boltzmann's constant per atom. This reduces to Lindemann's law for C_V = 3 and provides further support for the approximate validity of this law. (3) It follows that the “core paradox” of Higgins and Kennedy can only occur if $\text{γ <}\text{2}\text{3}$. However, it is shown that $\text{γ <}\text{2}\text{3}\text{? ∫}{}^{\mathrm{\infty }}{}_0\text{(?g/?T)}{}_{\mathrm{\rho }}\text{r(}\text{d}\text{/}\text{d}\text{r)(r}{}^2\text{φ)}\text{d}\text{r > 0}$, which cannot be achieved for any strongly repulsive pair potential φ and the corresponding pair distribution function g. It is concluded that $\text{γ >}\text{2}\text{3}$ and that the core paradox is almost certainly impossible for any conceivable core composition. Approximate calculations suggest that γ ～ 1.3–1.5 in the core. Further work on the thermodynamics of the liquid core must await development of a physically realistic pair potential, since existing pair potentials may be unsatisfactory.     

Interionic repulsive force and compressibility of ions

The compressibility of an individual ion is examined, in comparison with a known set of data for the alkali halides. A simple extrapolation of ionic radius to high pressure is not acceptable, because the pressure derivative of ionic radius changes for different salts. According to the classical concept of an elastic ion, the repulsive potential energy between the ions i and j is specified by the nature of each ion as:

$\text{(ρ}{}_{\mathrm{i}}\text{+ ρ}{}_{\mathrm{j}}\text{) exp[}\text{(ρ}{}_{\mathrm{i}}\text{+ ρ}{}_{\mathrm{j}}\text{? r)}\text{(ρ}{}_{\mathrm{i}}\text{+ ρ}{}_{\mathrm{j}}\text{)}\text{]}$

as a function of the interionic distance r. In this expression, q_i and ρ_i are the ionic radius and ionic compressibility, respectively, in a suitably modified meaning. Such a form of the repulsive potential fits well to the data of lattice constants and bulk moduli. The parameters q_i and ρ_i are evaluated for alkali and halogen ions, and an anion turns out to be much more compressible than a cation. The present treatment may be usefully applied to the minerals in the Earth's mantle, which contain only a few major ions.     

The electric field produced in the mantle by the dynamo in the core

A rigorous singular perturbation theory is developed to estimate the electric field E produced in the mantle M by the core dynamo when the electrical conductivity σ in M depends only on radius r, and when |r?_rln σ| ? 1 in most of M. It is assumed that σ has only one local minimum in M, either (a) at the Earth's surface ?V, or (b) at a radius b inside the mantle, or (c) at the core-mantle boundary ?K. In all three cases, the region where σ is no more than e times its minimum value constitutes a thin critical layer; in case (a), the radial electric field E_r ≈ 0 there, while in cases (b) and (c), E_r is very large there. Outside the critical layer, E_r ≈ 0 in all three cases. In no case is the tangential electric field E_S small, nearly toroidal, or nearly calculable from the magnetic vector potential A as ??_tA_S. The defects in Muth's (1979) argument which led him to contrary conclusions are identified. Benton (1979) cited Muth's work to argue that the core-fluid velocity u just below ?K can be estimated from measurements on ?V of the magnetic field B and its time derivative $\text{?}{}_{\mathrm{t}}\text{B}$. A simple model for westward drift is discussed which shows that Benton's conclusion is also wrong.In case (a), it is shown that knowledge of σ in M is unnecessary for estimating E_S on ?K with a relative error |r?_r 1nσ|^?1from measurements of E_S on ?V and knowledge of ?_tB in M (calculable from ?_tB on ?V if σ is small). Then, in case (a), u just below ?K can be estimated as $\text{?}\text{r}\text{×}\text{E}{}_{\mathrm{S}}\text{/B}{}_{\mathrm{r}}$. The method is impractical unless the contribution to E_S on ?V from ocean currents can be removed.The perturbation theory appropriate when σ in M is small is considered briefly; smallness of σ and of |r?_r ln σ|^?1 a independent questions. It is found that as σ → 0, B approaches the vacuum field in M but E does not; the explanation lies in the hydromagnetic approximation, which is certainly valid in M but fails as σ → 0. It is also found that the singular perturbation theory for |r?_r ln σ|^?1 is a useful tool in the perturbation calculations for σ when both σ and |r?_r ln σ|^?1 are small.     

Electrical conductivity of ultramafic rocks to 1820 kelvin

Electrical conductivity, σ, of six ultramafic rocks (garnet-bearing peridotites and an eclogite) has been investigated in the temperature range 670–1820 K under known environment. Between 670 and ～1320 K σ increases with 1/T monotonically, first slowly, by 1–1.5 orders of magnitude. Above 1320 K σ increases sharply; an increase of 3–4 orders of magnitude is observed between 1320 and 1670 K. In the same temperature range the σ values for all the six rocks fall within 1.5 orders of magnitude, the lowest conductivity being for a spinel lherzolite. The range of σ values is narrowed at higher temperatures. The differences in σ values above 1470 K may be explained on the basis of varying degrees of partial melting in the rocks. Over the entire range of temperature, the σ values for the ultramafic rocks are lower than those reported for basalts but higher (by 1–2 orders of magnitude) than those for single-crystal olivines.     

General relationships among sound speeds: II. Theory and discussion

The dependence of bulk sound speed V_φ upon mean atomic weight $\text{m}$ and density ρ can be expressed in a single equation:

$\text{V}{}_{\mathrm{\phi }}\text{=Bρ}{}^{\mathrm{\lambda }}\text{(}\text{m}{}_0\text{m}{}^{\mathrm{<mtext>[</mtext><mtext>1</mtext><mtext>2</mtext><mtext>+\lambda (1?c)]</mtext>}}\text{(}\text{km/sec}\text{)}$

Here B is an empirically determined “universal” parameter equal to 1.42, $\text{m}{}_0\text{= 20.2}$, a reference mean atomic weight for which well-determined elastic properties exist, and λ = 1.25 is a semi empirical parameter equal to $\text{γ ?}\text{1}\text{3}$ where γ is a Grüneisen parameter. The constant c = (? ln V_M/? ln $\text{m}\text{)}{}_{\mathrm{X}}$, where V_M is molar volume, is in general different for different crystal structure series and different cation substitutions. However, it is possible to use c_Fe = 0.14 for Fe²⁺Mg²⁺ and GeSi substitutions and c_Ca ? 1.3 for CaMg substitutional series. With these values it is pos to deduce from the above equation Birch's law, its modifications introduced by Simmons to account for Ca-bearing minerals, variations in the seismic equation of state observed by D.L. Anderson, and the apparent proportionality of bulk modulus K to V_M^?4.     

Elasticity of ilmenites

Ultrasonic data for the velocities of the ilmenites MgTiO₃ and CoTiO₃ have been determined as a function of pressure to 7.5 kbar at room temperature for polycrystalline specimens hot-pressed in a piston-cylinder apparatus at pressures up to 30 kbar. Titanate and germanate ilmenites define divergent isostructural trends on a Birch diagram of bulk sound velocity (υ_φ) vs. density (ρ). On a υ_φ vs. mean atomic weight ($\text{M}$) diagram, however, all of the ilmenite consistent with a single $\text{υ}{}_{\mathrm{\phi }}\text{M}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{=}\text{constant trend}$. Elasticity systematics for isostructural sequences are used to e the bulk modulus (2.09 Mbar) and bulk sound velocity (7.4 km/sec) of MgSiO₃-elmenite.     

Anelastic degradation of acoustic pulses in rock

Measurements on acoustic pulses propagating in massive rock lead to a simple empirical relationship between the pulse rise time, τ and the time of propagation of a pulse, t:

$\text{τ=τ}{}_0\text{+C}\text{∫}\text{)}\text{T}\text{Q}{}^{\mathrm{?1}}\text{d}\text{t}$

where τ₀ is the initial rise time (at t = 0), Q is the anelastic parameter which may be expressed in terms of the fractional loss of energy per cycle of a sinusoidal wave, Q = 2π(ΔE/E)^?1, and is assumed to be essentially independent of frequency, and C is a constant whose value we estimate experimentally to be 0.53 ± 0.04. Of the linear theories of seismic pulse attenuation, model 2 of Azimi et al. (1968) is favoured. Pulse shapes computed from equations of Futterman (1962) also give C = 0.5, but the pulse arrives earlier than in a non-attenuating medium with the same elasticity and density. Pulse shapes calculated using Strick's (1967, 1970, 1971) theory give values of C incompatible with our results. The observations suggest that a method of estimating the Q-structure of the earth from seismic pulse rise times may have a particular advantage over the spectral ratio method.     

A confirmation of the correlation between hydrocarbons and chlorophyll a in the upper euphotic zone

The average hydrocarbon content found in 14 water samples from the euphotic zone off Northwest Africa was 4.4 μg l.^?1 with no extreme values. The average chlorophyll $\text{a}$ content was 1.9 μg l.^?1. The data fit a model proposed in a previous paper (Zsolnay, 1977). The resulting equation was $\text{HC}\text{= ?2.7 + 4.82}\text{Ch}\text{?0.942}\text{Ch}{}^2$ and could explain 59% of the variance in the hydrocarbon distribution. This indicates a correlation that is significant at the 0.002 level.     

The cooling Earth: A reappraisal

By treating the lithosphere as a diffusive boundary layer to mantle convection, the convective speed or mantle creep rate, $\text{?}\text{?}$, can be related to the mantle-derived heat flux, $\text{Q}\text{?}$. If cell size is independent of $\text{Q}\text{?}{}^2$ then $\text{?}\text{?}\text{∝}\text{Q}\text{?}$. (If cell size varies with $\text{Q}\text{?}$, then a different power law prevails, but the essential conclusions are unaffected.) Then the factthat for constant thermodynamic efficiency of mantle convection, the mechanical power dissipation is proportionalto $\text{Q}\text{?}$, gives convective stress $\text{σ ∝}\text{Q}\text{?}{}^{\mathrm{?1}}$, i.e. the stress increases as the convection slows. This means an increasing viscosityor stiffness of the mantle which can be identified with a cooling rate in terms of a temperature-dependent creep law. If we suppose that the mantle was at or close to its melting point within 1 or 2 × 10⁸ years of accretionof the Earth, the whole scale of cooling is fixed. The present rate of cooling is estimated to be about 4.6 × 10^?8 deg y^?1 for the average mantle temperature, assumed to be 2500 K, but this very slow cooling rate represents a loss ofresidual mantle heat of 7 × 10¹² W, about 30% of the total mantle-derived heat flux. This conclusion requires theEarth to be deficient in radioactive heat, relative to carbonaceous chondrites. A consideration of mantle outgassing and atmospheric argon leads to the conclusion that the deficiency is due to depletion of potassium, and that the K/U ratio of the mantle is only about 2500, much less than either the crustal or carbonaceous chondritic values. Thetotal terrestrial potassium is estimated to be about 6 × 10²⁰ kg. Acceptance of the cooling of the Earth removes the necessity for potassium in the core.