STUDIES OF BRAZILIAN METEORITES XIV. MINERALOGY,PETROLOGY, AND CHEMISTRY OF THE CONQUISTA,MINAS GERAIS,CHONDRITE

The Conquista chondrite consists of major olivine, low-Ca pyroxene (both ortho- and twinned clino-), troilite and metallic nickel-iron; minor glassy to microcrystalline material and pigeonite; and accessory chromite, high-Ca clinopyroxene and hydrous ferric oxides that formed by terrestrial weathering of metallic nickel-iron. Results of microscopic, electron microprobe, and bulk chemical studies, particularly the compositions of olivine (Fa_17.2) and low-Ca pyroxene (Fs_15.4); the contents of metallic nickel-iron (18.5%) and total iron (25.83%); and the ratios of Fe°/Fe_total (0.64), Fe°/Ni° (9.59) and Fe_total/SiO₂ (0.69) indicate H-group classification. The pronounced, well-developed chondritic texture; the slight compositional variations in constituent phases; the high Ca contents of pyroxene and the presence of pigeonite, glassy to microcrystalline interstitial material rich in alkalis and SiO₂, and of twinned low-Ca clinopyroxene suggest that Conquista is of petrologic type 4.     

THE INMAN,McPHERSON COUNTY,KANSAS METEORITE

Inman (find, 1966) is a single, relatively unweathered stone of 7.25 kg that contains fresh metal and only few weathering products away from fractures. It has a pronounced chondritic texture, with 38 vol % of the meteorite being made up of chondrules of virtually all textural types. The recalculated bulk analysis, particularly the ratios of Fe_total/SiO₂ (0.46), Fe°/Fe_total (0.35), and Fe°/Ni° (6.67) and the contents of Fe_total (19.45%) and metallic nickel-iron (7.94%), indicate that Inman is an L-group chondrite. The pronounced chondritic texture; the compositional variabilities of olivine, pyroxene, chromite, and ilmenite; the presence of a fine-grained, nearly opaque matrix, glass and twinned monoclinic low-Ca pyroxene indicate that the chondrite belongs to petrologic type 3.     

AN H4–6 CHONDRITE: MOTTA DI CONTI

The mineralogical and chemical compositions of meteorites from the Motta di Conti, Vercelli, Italy, shower (February 29, 1868) have been determined. Microprobe analyses, of olivine (Fa_19,6) and orthopyroxene (Fs_17,8), as well as the bulk chemical composition, particularly the ratios of SiO₂/MgO (1.50), Fe°/Ni° (11.03), Fe_total/SiO₂ (0.81), Fe°/Fe_total (0.70) and the content of Fe_total (28.60%) classify the meteorite as an H-group chondrite. The percentage of total metallic nickel-iron (22.06%) is somewhat higher than the average in H-group chondrites. The texture of our stone shows evidence of metamorphism. The integration between matrix and chondrules is advanced and may suggest a high petrographic grade, but the identification of several microscopic features (e.g. small grains of monoclinic twinned pyroxene, FeNi-FeS intergrowths, globules and mosaic) leads to the conclusion that a variety of petrographic types (4–6) are present. Metamorphic equilibration in chondrites is discussed and a preliminary hypothesis for H4–6 chondrites is suggested.     

MINERALOGY,PETROGRAPHY AND CHEMISTRY OF THE CHONDRITE,KAMIOMI, SASHIMA-GUN,IBARAKI-KEN,JAPAN

The Kamiomi, Sashima-gun (Iwai-shi), Ibaraki-ken, Japan, chondrite (observed to fall in spring, during the period 1913–6), consists of olivine, orthopyroxene, nickel-iron and troilite with minor amount of plagioclase, clinopyroxene, apatite and chromite. The average molar composition of olivine (Fa₁₉) and orthopyroxene (Fs₁₇) indicates that Kamiomi is a typical olivine bronzite chondrite. From the well-recrystallized texture, the presence of poorly-definable chondrules, homogeneous composition of olivine and absence of glass, this chondrite could be classified in petrologic type 5. The bulk chemical composition, especially, total Fe (27.33%) and metallic Fe (17.00%) as well as Fe_total/SiO₂(0.72), Fe_metal/Fe_total (0–633) and SiO₂/MgO (1.59) support the above conclusion. Coexistence of heavily-shocked olivine grains in the matrix composed of olivines and pyroxenes which suffered from light to moderate shock effect suggest that impacting phenomena, small-scaled but locally strong, occurred on the Kamiomi parent body.     

THE CHEMISTRY AND MINERALOGY OF THE HOMEWOOD,MANITOBA, METEORITE

The Homewood meteorite is a slightly weathered find of 325 grams discovered in 1970 about 64 km southwest of Winnipeg, Manitoba. It consists of olivine (Fa_25.4; 43.8 normative wt. percent), orthopyroxene (Fs_23.3; 28.5 percent), kamacite and taenite (7.5 percent), troilite (5.6 percent), maskelynite (8.3 percent), chromite (1.0 percent), whitlockite (0.7 percent) and minor patchy Ca pyroxene. Bulk chemical analysis yielded Fe_total 21.60 wt. percent, Fe/SiO₂0.55, SiO₂/MgO 1.53 and Fe^O/Fe_total 0.29. Barred olivine, radiating pyroxene and porphyritic chondrules, all with ill-defined outlines, occur in the meteorite. Most chemical and mineralogical features characterize the Homewood meteorite as an L6 (hypersthene) chondrite. The presence of maskelynite, the undulatory extinction, extensive fracturing and pervasive mosaicism of olivine, and the poor definition of chondrule outlines suggest that the Homewood meteorite has been shocked in the range of 300–350 kbar.     

CHEMICAL COMPOSITION,PETROGRAPHY AND MINERALOGY OF THE SHIBAYAMA CHONDRITE FOUND IN SHIBAYAMA-MACHI,SANBU-GUN,CHIBA-KEN,JAPAN

In April 1969, the chondrite was accidentally found in the side wall of the vegetable storage excavated at Shibayama-machi, Sanbu-gun, Chiba-ken, Japan, by Mr. A. Ishii and his grandson, Mr. S. Ito. The chondrite named Shibayama has been weathered thoroughly for a long period of burial underground. The bulk chemical composition, especially total Fe (21.41%) and ratios of Fe_total/SiO₂(0.557), SiO₂/MgO (1.59) and molar composition of olivine (Fa₂₃) and pyroxene (Fs₂₂) as well as mineral composition, indicate that Shibayama is a typical olivine-hypersthene chondrite. If the oxidized Fe is assumed only from metallic Fe, the original metallic Fe (7.75%) and Fe_metal/Fe_total(0.361) also support the above conclusion. From the well-recrystallized texture, indistinct and obliterated chondrule-matrix boundary, homogeneous composition of olivine and pyroxene, absence of igneous glass, and interstitial and well-developed plagioclase, this chondrite could be classified in petrologic type 6. Mosaic texture, kink bands, undulatory extinction of silicate grains and maskelynitization of plagioclase indicate that Shibayama suffered from a heavy shock effect, as is seen in other L-6 group chondrites.     

The Hashima,Japan H4 chondrite: A newly reported meteorite

Abstract We report a new chondrite that fell in Hashima City in central Japan sometime during the period 1868–1912. The chondrite weighs 1110.64 g and exhibits distinct chondritic structure. Chondrules occupy 24 vol% of the stone and consist of olivine (average Fa_17,8), low-Ca pyroxene (average Fs_15,8 Wo_0.9), devitrified glass and lesser amounts of oligoclase (ca. Ab₈₀Or₄), kamacite, taenite, troilite and chromian spinel. Matrix occupying 76 vol% of the stone consists of olivine, low-Ca pyroxene, kamacite, taenite, troilite, cryptocrystalline minerals and lesser amounts of chromian spinel and chlorapatite. Matrix minerals have the same compositions as those in chondrules. Mineral chemistry, bulk chemistry and magnetic properties indicate that Hashima is an H-group chondrite. Well-defined chondrules, scarcely recrystallized oligoclase and relatively small variations of olivine and low-Ca pyroxene compositions indicate that Hashima is of petrologic type 4.     

The Loxton meteorite: A new olivine-bronzite chondrite from South Australia

Abstract— The Loxton meteorite is a single stone of 22 g found in South Australia in 1968. It has been classified as an L5 chondrite, shock facies ‘a,’ and contains olivine (Fa₂₄), orthopyroxene (Fs_21–22), clinopyroxene (Wo_44.7En_45.9Fs_9.4), nickel-iron, troilite, chromite and chlorapatite.     

Multi-zone fusion crust formation and classification of the 2004 Auckland meteorite (L6, S5, and W0)

On June 12, 2004, a meteorite passed through Earth's atmosphere and landed under the television in the living room of a house in Auckland, New Zealand. Textural characteristics, the chemistry of olivine (Fa_23–24) and orthopyroxene (Fs_20.7), and the bulk rock triple oxygen isotopes (δ¹⁷O + 3.1; δ¹⁸O + 4.2‰) from the interior of the completely unweathered (W0) 1.3 kg meteorite, hereafter referred to as Auckland, suggest it to be a strongly metamorphosed fragment from the interior of a low iron ordinary chondrite (L6) parent asteroid. The occurrence of maskelynite but shock fracturing of olivine and pyroxene indicates Auckland experienced extreme shock metamorphism (S5), likely during Ordovician fragmentation of the asteroid parent. The fusion crust consists of three zones: (1) an innermost zone containing narrow Fe-Ni-S-bearing veins that migrated along pre-existing shock fractures in olivine and pyroxene; (2) a middle zone in which the meteorite partially melted to form a silicate glass and immiscible blebs of metal and troilite, and is accompanied by unmelted silicate minerals; and (3) an approximately 0.1 mm wide vesicular-rich outermost layer that largely melted, volatilizing sulfides, before quenching to form glass and olivine. Oxygen isotope values of the bulk rock and/or maskelynite of melted rim and modified substrate are 2–3‰ greater than the meteorite interior and indicate that up to 19% of terrestrial atmospheric O₂ was incorporated into the fusion crust during the formation. The fusion crust migrated inwards as ablation occurred, enabling melting, migration, and re-precipitation ± loss of sulfide and metal components, with the prominent glassy rim therefore forming from an already chemically modified zone.     

THE METEORITIC SHOWER OF PARAMBU,CEARA STATE,BRAZIL: — MINERALOGY AND PETROLOGY

The fall of a meteorite shower in Parambú, Ceará State, Brazil, is described. Parambú is an L-group chondrite (Urey and Craig, 1953). The mineralogical composition is olivine Fa₂₈. ortho- and clinopyroxenes, plagioclase, maskelynite, whitlockite, nickel-iron, troilite, chromite, and ilmenite. The structure of Parambú is characteristically polymict and shows an advanced brecciation. Interesting features of metamorphism are notable, with good evidence of shock.     

THE KRAMER CREEK,COLORADO METEORITE: A NEW L4 CHONDRITE

The Kramer Creek, Colorado, chondrite was found in 1966 and identified as a meteorite in 1972. Bulk chemical analysis, particularly the total iron content (20.36%) and the ratio of Fe_total/SiO₂ (0.52), as well as the compositions of olivine (Fa_21.7) and orthopyroxene (Fs_18.3) place the meteorite into the L-group of chondrites. The well-defined chondritic texture of the meteorite, the presence of igneous glass in the chondrules and of low-Ca clinopyroxene, as well as the slight variations in FeO contents of olivine (2.4% MD) and orthopyroxene (5.6% MD) indicate that the chondrite belongs to the type 4 petrologic class.     

PETROGRAPHY AND CHEMISTRY OF THE FAUCETT METEORITE,BUCHANAN COUNTY,MISSOURI

Nine, possibly ten, stones from northwestern Missouri are known as the Faucett meteorite. These stones are finds, but may be fragments of a large fireball seen in the area in 1907. The meteorite is an olivine-bronzite chondrite (H4) containing approximately 31% chondrules and 69% matrix. Modal analysis gives: olivine 43%, orthopyroxene 28.3%, oligoclase 5.9%, glass 1.2%, metallic grains (both nickel-iron and troilite) 19.7%, other minerals and unidentified grains 2.0%. The chemical analysis is typical of modern analyses of H-group chondrites with a total iron value of 26.59 weight percent.     

Rumanová H5 chondrite,Slovaki

Abstract— An H5 chondrite was found near the village of Rumanová, Slovakia. dominant minerals of the meteorite are enstatite, olivine, kamacite, taenite and troilite. The minor minerals are oligoclase, augite, pigeonite, accessory chromite, whitlockite and chlorapatite. The composition of olivine (Fa_19.0) and low-Ca orthopyroxene (Fs_17.0), and the density and chemical composition of the meteorite correspond to those of an H chondrite. Normal zoning of Ni in metal grains and parallel planar fractures in olivine suggest weak shock metamorphism of stage S3. Due to moderate oxidation of metal, iron hydroxides were formed corresponding to weathering stage W2.     

THE BEAVER-HARRISON,BEAVER COUNTY,UTAH L6 CHONDRITE

The Beaver-Harrison, Utah chondrite (find July 24, 1979), a single, shock-veined stone of 925 grams, consists of major olivine (Fa_25.0), low-Ca pyroxene (En_77.3Fs_21.1Wo_1.6) and metallic nickel-iron; minor troilite and plagioclase (Ab_82.6An_11.1Or_6.3), accessory high-Ca pyroxene (En_47.0Fs_8.5Wo_44.5), chromite (Cm_8.7Sp_10.6Uv_9.4Pc_0.6Hc_0.7), chlorapatite and whitlockite; and hydrous ferric oxide of terrestrial weathering origin. Mineral compositions indicate L-group classification, and homogeneity of minerals, highly recrystallized texture and presence of clear plagioclase suggest that the meteorite belongs to petrologic type 6.     

Northwest Africa 428: Impact‐induced annealing of an L6 chondrite breccia

Abstract— Northwest Africa (NWA) 428 is an L chondrite that was successively thermally metamorphosed to petrologic type‐6, shocked to stage S4–S5, brecciated, and annealed to approximately petrologic type‐4. Its thermal and shock history resembles that of the previously studied LL6 chondrite, Miller Range (MIL) 99301, which formed on a different asteroid. The petrologic type‐6 classification of NWA 428 is based on its highly recrystallized texture, coarse metal (150 ± 150 μm), troilite (100 ± 170 μm), and plagioclase (20–60 μm) grains, and relatively homogeneous olivine (Fa_{24.4 ± 0.6}), low‐Ca pyroxene (Fs_{20.5 ± 0.4}), and plagioclase (Ab_{84.2 ± 0.4}) compositions. The petrographic criteria that indicate shock stage S4–S5 include the presence of chromite veinlets, chromite‐plagioclase assemblages, numerous occurrences of metallic Cu, irregular troilite grains within metallic Fe‐Ni, polycrystalline troilite, duplex plessite, metal and troilite veins, large troilite nodules, and low‐Ca clinopyroxene with polysynthetic twins. If the rock had been shocked before thermal metamorphism, low‐Ca clinopyroxene produced by the shock event would have transformed into orthopyroxene. Post‐shock brecciation is indicated by the presence of recrystallized clasts and highly shocked clasts that form sharp boundaries with the host. Post‐shock annealing is indicated by the sharp optical extinction of the olivine grains; during annealing, the damaged olivine crystal lattices healed. If temperatures exceeded those approximating petrologic type‐4 (?600–700°C) during annealing, the low‐Ca clinopyroxene would have transformed into orthopyroxene. The other shock indicators, likewise, survived the mild annealing. An impact event is the most plausible source of post‐metamorphic, post‐shock annealing because any ²⁶Al that may have been present when the asteroid accreted would have decayed away by the time NWA 428 was annealed. The similar inferred histories of NWA 428 (L6) and MIL 99301 (LL6) indicate that impact heating affected more than 1 ordinary chondrite parent body.     

Mineral and chemical composition of the Jezersko meteorite—A new chondrite from Slovenia

The Jezersko meteorite is a newly confirmed stony meteorite found in 1992 in the Karavanke mountains, Slovenia. The meteorite is moderately weathered (W2), indicating short terrestrial residence time. Chondrules in partially recrystallized matrix are clearly discernible but often fragmented and have mean diameter of 0.73 mm. The meteorite consists of homogeneous olivine (Fa_19.4) and low‐Ca pyroxenes (Fs_16.7Wo_1.2), of which 34% are monoclinic, and minor plagioclase (Ab₈₃An₁₁Or₆) and Ca‐pyroxene (Fs₆Wo_45.8). Troilite, kamacite, zoned taenite, tetrataenite, chromite, and metallic copper comprise about 16.5 vol% of the meteorite. Phosphates are represented by merrillite and minor chlorapatite. Undulatory extinction in some olivine grains and other shock indicators suggests weak shock metamorphism between stages S2 and S3. The bulk chemical composition generally corresponds to the mean H chondrite composition. Low siderophile element contents indicate the oxidized character of the Jezersko parent body. The temperatures recorded by two‐pyroxene, olivine‐chromite, and olivine‐orthopyroxene geothermometers are 854 °C, 737–787 °C, and 750 °C, respectively. Mg concentration profiles across orthopyroxenes and clinopyroxenes indicate relatively fast cooling at temperatures above 700 °C. A low cooling rate of 10 °C Myr^?1 was obtained from metallographic data. Considering physical, chemical, and mineralogical properties, meteorite Jezersko was classified as an H4 S2(3) ordinary chondrite.     

The Linum Chondrite

Abstract— Based on optical microscopy and electron microprobe analysis, Linum is classified as an L6b chondrite that contains olivine (Fa₂₄), orthopyroxene (Fs₂₀), clinopyroxene (Wo₄₅En₄₇Fs₈), plagioclase (An₁₀Ab₈₄Or₆), nickel-iron, troilite, chromite and accessory amounts of chlorapatite and whitlockite.     

THE CORREO AND SUWANEE SPRING METEORITES: TWO NEW ORDINARY CHONDRITE FINDS

Two new ordinary chondrites were found about 40 km west of Albuquerque, New Mexico. Correo is an H4 chondrite with distinct chondrules and major olivine (Fo_81.4), orthopyroxene (En_82.3) and plagioclase (An₁₂). Suwanee Spring is an L5 chondrite with few distinct chondrules and a highly recrystallized matrix. Major minerals are olivine (Fo_75.4), orthopyroxene (En_77.7) and plagioclase (An₉). The metallic Ni-Fe phases of both meteorites are typical of slowly-cooled ordinary chondrites.     

Reclassification and thermal history of Trenzano chondrite

Abstract— We present a new single‐crystal X‐ray diffraction (XRD) study performed on a suite of six orthopyroxene grains from the low‐shocked H6 Trenzano meteorite. The quenched intracrystalline Fe²⁺‐Mg ordering state in orthopyroxene preserves the memory of the cooling rate near closure temperature T_c, thus yielding useful constraints on the last thermal event undergone by the host rock. The orthopyroxene T_c of 522 ± 13 °C, calculated using a new calibration equation obtained by Stimpfl (2005b), is higher than in previously published H chondrite data. The orthopyroxene cooling rate at this T_c is about 100 °C/kyr. This fast rate is inconsistent with the much slower cooling rate expected for H6 in the onion shell structural and thermal model of chondrite parent bodies. A petrographic study carried out at the same time indicated that the Trenzano meteorite is an H5 chondrite and not an H6 chondrite, as it is officially classified. Furthermore, the two‐pyroxene equilibrium temperature of Trenzano (824 ± 24 °C), calculated with QUILF95, is similar to the two‐pyroxene temperature of 750–840 °C obtained for the Carcote (H5) chondrite (Kleinschrot and Okrusch 1999).