吉林省红旗岭矿区铜镍硫化物矿床成矿规律、矿床成因、找矿标志

红旗岭镍矿区是我国岩浆岩型铜镍硫化矿床的主要矿化集中区之一,在本区内出露的镁铁-超镁铁质岩所划分的3个岩带中,有的岩体含铜镍矿,有的不含矿.通过近期在区内开展的全国危机矿山找矿中所形成的资料及从构造控岩控矿、岩性控矿、成矿与岩石类型的关系进行对比,对区内镁铁-超镁铁质岩体的综合找矿标志进行总结,为今后在区内寻找隐伏岩体及其含矿性的评价提供一定的理论依据.     

吉林磐石市三道岗镁铁——超镁铁质岩体成矿地质特征及找矿意义

三道岗镁铁-超镁铁质岩体位于吉林省红旗岭镍矿区外围,岩体中赋存有小型铜镍矿床,这一矿床的发现为红旗岭镍矿区外围及红旗岭镍矿区Ⅱ岩带岩体找矿提供了依据.     

云南金平县新安里铜镍矿成矿规律与外围找矿

新安里铜镍矿属产于超基性岩中的熔离铜镍硫化物矿床,矿体赋存于基性—超基性岩体中,岩体分异较好、岩相分带清楚,物、化探组合异常与岩体、矿体对应较好.通过对比,新安里铜镍矿成矿规律与已知的营盘Ⅰ、Ⅱ号杂岩体铜镍矿床相似,岩浆分异程度高,推测新安里岩体深部应为地质找矿的有利部位.     

吉林省茶尖矿区镁铁-超镁铁质岩体地质特征及找矿方向

红旗岭铜镍矿田由红旗岭岩体群、三道岗岩体群及茶尖岩体群构成,蕴藏着大、中、小型铜镍矿床.茶尖矿区是红旗岭铜镍矿田重要组成部分,已往勘查中发现20余个镁铁-超镁铁质岩体,并在1号、新6号、9号、18号岩体中发现小型铜镍矿床,2号、10号、14号等岩体中发现铜镍矿化.从岩体特征等方面进行分析与红旗岭区对比,确定了该区的找矿标志和找矿方向,力求在茶尖矿区发现中型以上的铜镍矿床.     

东天山白鑫滩铜镍矿锆石U-Pb年代学、地球化学特征及对Ni-Cu找矿的启示

白鑫滩铜镍矿床位于觉罗塔格构造岩浆带内,岩体走向受大草滩断裂控制,目前矿床规模达中型。含矿岩体侵入于中奥陶统恰干布拉克组,直接围岩为英安岩和火山角砾凝灰岩,主要岩石类型为辉长岩、橄榄辉石岩和辉石橄榄岩,岩石由中心向两侧基性程度逐渐降低,岩体产状平缓,主要赋矿岩相为辉石橄榄岩相,矿体多呈似层状或透镜状。含长辉石橄榄岩中锆石La-ICP-MS U-Pb定年结果为(277.9±2.6)Ma,表明岩体形成于早二叠纪。以24号勘探线为界,岩体西段矿石Cu/Ni比值普遍高于岩体东段矿石。样品中Mg O与Fe OT呈正相关关系,与Ca O、Si O2和Ti O2呈负相关关系,样品m/f值为2.43~3.9,为铁质系列超镁铁岩,有利于铜镍矿的形成;样品稀土元素配分型式为轻稀土略富集的右倾型,轻、重稀土元素之间分馏程度较弱,具有弱的负Eu异常;富集大离子亲石元素,而相对亏损高场强元素,有明显的Nb、Ta负异常。岩浆演化过程中主要发生了橄榄石和辉石的分离结晶/堆晶作用,并遭受了少量中—下地壳物质混染,岩浆源区遭受了明显的俯冲流体交代作用。白鑫滩矿床形成时代及构造背景与黄山东、黄山、香山等典型矿床一致,是图拉尔根—黄山东—土墩铜镍矿带的西延部分,该铜镍矿带向西仍有较大的铜镍找矿潜力,大草滩断裂可能也是该区重要的控岩控矿断裂。     

吉林红旗岭铜镍矿床的地质特征及成因

红旗岭铜镍矿床地处华北地台和吉黑地槽系接触带———辉发河断裂带内 ,属大型铜镍硫化物矿床。矿区出露地层为下元古界呼兰群变质岩系。呈北东向展布的辉发河断裂具有切割深度大、继承性活动频繁等特征 ,由该断裂构造活动派生的北西向构造构成区域性重要的控岩控矿构造 ,控制超镁铁、镁铁质岩体及铜镍硫化物矿体在空间上呈北西向产出。与铜镍矿成矿有关的岩体具有复合杂岩体特征 ,多属辉长岩—辉石岩—橄榄岩型镁铁—超镁铁质岩。铜镍矿体呈似板状、脉状、透镜状及囊状等赋存于镁铁—超镁铁质岩体内。岩矿石微量元素特征、稀土元素地球化学特征均反映其为地幔部分熔融作用的产物 ,且矿石与镁铁—超镁铁质岩具同源性 ,矿床属岩浆深部熔离分异成因     

吉林省红旗岭镍矿区3号岩体成矿地质特征及找矿方向

吉林省红旗岭镍矿区是我国岩浆岩型铜镍硫化矿床的主要矿化集中区之一,已往勘查年中发现30余个镁铁—超镁铁质岩体,并在1号岩体中发现中型铜镍矿床、7号岩体中发现大型铜镍矿床,2号、3号、9号、32号岩体中发现小型铜镍矿床。3号岩体是本区规模较大岩体之一,通过对岩体特征的分析和对比,确定了深部镍钴矿体的找矿标志和找矿方向,为红旗岭镍矿区评价其它岩体提供依据。     

红旗岭镁铁-超镁铁岩侵入体及铜镍硫化物矿床的成岩成矿机制

红旗岭铜镍矿床地处华北地台与吉黑地槽系接触带--辉发河断裂北侧.区内出露30多个镁铁-超镁铁质岩体,其中1、7号超镁铁岩体中赋存铜镍硫化物矿(床)体.含矿岩体分相明显,各类岩石均具堆积结构.铜镍矿体呈似板状、脉状、透镜状及囊状赋存于超镁铁岩体底部橄榄辉岩相中.岩石学和地球化学研究表明,7号岩体形成以流动分异为主,1号岩体为重力分异;原始岩浆属拉斑玄武质,块状矿石系压滤作用产物,后续岩浆的补给和混合补充了成矿物质,硫化物不混溶程度受挥发分制约,矿床属岩浆深部熔离分异成因,成矿时代为印支期.     

东昆仑夏日哈木铜镍矿床Ⅱ号岩体辉长岩形成年龄与找矿潜力

东昆仑夏日哈木铜镍矿床以赋存110万吨Ni金属成为全球镍床近二十年来最重要的发现之一,也是仅次于金川岩浆铜镍矿床的中国第二大铜镍矿床。矿区发育5个镁铁-超镁铁质岩体,目前仅Ⅰ号镁铁-超镁铁岩体内发现了具有经济价值的超大矿体,110万吨Ni金属均赋存Ⅰ号岩体内;其他4个岩体中仅Ⅱ号岩体发现了矿化,是多种构造体制叠加岩浆活动的结果。调查发现Ⅱ号岩体的主要岩性是辉长岩,LA ICP-MS锆石U-Pb测试获得Ⅱ号岩体辉长岩的成岩年龄为385.2 Ma,比Ⅰ号岩体成岩成矿时代稍年轻,属于早泥盆世岩浆活动的产物。岩浆铜镍矿体多赋存于辉石岩与橄榄岩中,辉长岩内一般无经济价值的矿体存在。在夏日哈木矿区,辉长岩基本是含矿辉石岩及橄榄岩的围岩,辉长岩中所见的铜镍矿化也是后期岩浆活动贯入的表现。结合区域年代学综合分析认为,夏日哈木超大型岩浆铜镍硫化物矿床的形成,是早泥盆世早期岩浆活动于柴达木盆地边缘东昆仑造山带夏日哈木地区具体的成矿表现。目前所发现的Ⅱ号岩体以辉长岩为主,不具备成镍矿良好条件,较难发现有经济价值的铜镍矿体。     

吉林省红旗岭茶尖矿区镁铁-超镁铁岩石地球化学特征及找矿意义

红旗岭镍矿田是我国岩浆岩型铜镍硫化矿床的主要矿化集中区之一,茶尖矿区是其重要组成部分之一.在茶尖矿区已往勘查中共发现20余个镁铁-超镁铁质岩体,并在1号、新6号、9号、18号岩体中发现小型铜镍矿床,2号、10号、14号等岩体中发现铜镍矿化.从岩体岩石学及蚀变矿化特征、岩体常量元素、微量元素、稀土元素特征方面进行分析,并与红旗岭镍矿区进行对比,认为其与红旗岭区镁铁-超镁铁岩具同源性,矿床属熔离-贯入型成因,后期热液叠加又是茶尖区独有的成矿特征,通过分析、对比,确定了该区找矿意义和前景区.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

Petrographic, mineralogy, and geochemistry of coals of Pabedana, Kerman Province, Central Iran

This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.