Diffuse interstellar band formation in dense clouds

Measurements of the strengths of the diffuse interstellar bands at 4430, 5780 and 5797 Å show that the bands tend to be week with respect to extinction in dense interstellar clouds. Data on 10 stars in the ? Ophiuchi cloud complex show further that the diffuse band-producing efficiency of the grains decreases systematically with increasing grain size. It is concluded that the diffuse bands are not formed in the mantles which accrete on the grains in interstellar clouds, but that they could be produced in the cores of grains or in some molecular species.     

Primitive Grain Clumps and Organic Compounds in Carbonaceous Chondrites

Refractory interstellar grains acquire tarry polymeric coatings in dense protostellar molecular clouds. Collisions between polymer-coated grains lead to the formation of micron sized grain clumps that are subsequently expelled into the diffuse interstellar medium. Such grains could contain the building blocks of life such as amino acids in their interiors protected from dissociative ultraviolet radiation. This revised version was published online in July 2006 with corrections to the Cover Date.     

Zur zeitlichen Variation des Metallgehaltes in der Galaxis

The two oldest known open clusters, NGC 188 and M67, are observed to have a higher heavy-element abundance than the sun and the stars in the Hyades. This observation might be explained by assuming that these clusters were formed from unusually dusty and hence metal-rich interstellar clouds. Alternatively it may be supposed that the radiation pressure produced by stars in the spiral arms of the Galaxy ejected dust from high-latitude clouds. The calculations presented in this paper show that the loss of dust from such clouds might just be sufficient to produce a significant decrease in the mean heavy-element abundance of the interstellar gas. According to this picture, the first burst of star formation in the Galaxy led to a rapid increase in the interstellar heavy-element abundance. Subsequently, the metal abundance of the interstellar gas decreased due to the radiation pressure by young stars. The present rate of change of the heavy-element abundance in the Galaxy depends on the ratio of heavy-element production by stars to ejection of these elements by radiation pressure on dust grains. Since noble gases do not condense on grains, the neon abundance in the interstellar gas should be a monotonously increasing function of time. The observation that the neon abundance in the sun is much lower than that in young stars and nebulae lends some support to the suggestion that ejection of grains from the Galaxy effects the heavy-element abundance in the interstellar gas.     

Large interstellar molecules

We propose that photocycloaddition reactions in molecular complexes in normal interstellar clouds will create unusually large molecules. These may be sufficiently radiation stable to be circulated with the interstellar gas, and so provide convenient nucleation centres for growth of loosely bound grains in dark regions.     

Formaldehyde Polymers in Interstellar Space

Refractory grains of graphite and silicates ejected from cool giant stars acquire mantles of organic polymers typified by polyoxymethyline in interstellar clouds. Infrared emission from theTrapezium nebula is consistent with the occurrence of such polymers. This revised version was published online in July 2006 with corrections to the Cover Date.     

Possible mechanism for limiting grain sizes

It is suggested that grains are driven out of interstellar clouds by galactic radiation pressure and it is shown that the corresponding sizes which they can achieve within the cloud due to condensation is in reasonable agreement with observations.     

Dust metamorphosis in the galaxy

Summary Cosmic dust grains play an important role for the thermal, dynamical, and chemical structure of the interstellar medium. This is especially true for the star formation process and the late stages of stellar evolution. Dust grains determine the spectral appearance of protostars, very young stellar objects with disk-like structures as well as of evolved stars with circumstellar envelopes.In this review, we will demonstrate that solid particles in interstellar space are both agent and subject of galactic evolution. We will especially discuss the different dust populations in circumstellar envelopes, the diffuse interstellar medium, and the molecular clouds with strong emphasis on the evolutionary aspects and the metamorphosis of these populations.     

Kinetic Monte Carlo method for simulating astrochemical kinetics: Hydrogen chemistry in diffuse clouds

We perform numerical simulations of the molecular hydrogen production on the surface of interstellar dust grains and its dissociation by the ultraviolet background in conditions typical for the interstellar medium. The kinetic version of the Monte Carlo method is used for the modeling of the catalytic chemical reactions on the surface of the dust fraction and in the surrounding medium. Our simulations show the importance of the interstellar dust particles for hydrogen chemistry in diffuse molecular clouds.     

The charge distribution on interstellar grains—The effect of induced charge

A calculation of the equilibrium charge acquired by interstellar grains is given, which takes account of polarization charges that are induced in a grain by incident ions and electrons.Both metal and dielectric grains are considered and photoionization of the latter grains by UV radiation is taken into account where necessary. It is found that the inclusion of the polarization charges in the calculation is only important in gas clouds where the mean charge on a grain is low (<1e); that is, for HI regions and dense molecular clouds. In such clouds, the effect of the polarization charges is to increase the amount of negative charge acquired by a grain. A discussion is given concerning the validity of the classical electrostatic theory employed in the paper for small grains of radius 10^–6 cm, and some astrophysical consequences of the modification of the grain charge by polarization effects are considered.     

The role of induced charges in the accretion of charged dust grains

The electrostatic interaction of charged dust grains is analysed by considering the interaction of two charged conducting spheres, rather than the hitherto considered model of a sphere and a point charge. Considerable mofification of the induced charge effects results when the nonzero radius of the second sphere is taken into account.In particular, it is shown that image charge or polarization effects can only be of significance as far as collision rates are concerned when modulus of the charge ratio of two colliding grains is very different from the ratio of their radii. Such a charge ratio deviates from the original Spitzer calculation, where grains have identical charge, irrespective of the grain material, for a given radius. This deviation may occur in cool gas clouds such as Hi regions and dense molecular clouds where the discreteness of electron charge is important, or in interstellar clouds where considerable photo-ionization of a mixture of grain materials of widely varying photoelectric efficiencies takes place.It is further argued that, with regard to the induced charge effects, the accretion rate will not be significantly different for dielectric as compared to conducting grains, regardless of the type of gas cloud under consideration.     

Interstellar graphite grain temperature and infrared optical constants

The temperature of graphite grains in the interstellar medium has been computed with different assumptions on the extrapolation of its optical constants into infrared. It is found that values computed up to now are generally underestimated by 10–20% in normal interstellar conditions. For extreme conditions (very dark clouds) errors by a factor of two are possible and more attention has to be paid in dealing with problems related to molecule formation.     

Interpretation of carbon overabundances in the atmospheres of carbon stars

An attempt is made to estimate the rate of accretion of interstellar grains by red giants. It seems possible for a red giant traversing dust clouds to acquire, under realistic conditions, an amount of carbon sufficient to turn its spectrum into that of a carbon star. Coarse grains exceeding 10^–3 cm in diameter are most effective in this process.     

Ultraviolet observations of interstellar molecules and grains fromSpacelab

Observational results obtained to date on interstellar grains and molecules are briefly reviewed, and several promising areas for further research withSpacelab are suggested. Regarding grains, useful data can be expected on the shape of the ultraviolet extinction curve for new interstellar regions; the nature of UV extinction at short wavelengths, down to the Lyman limit; the presence or absence of structure in the UV extinction curve comparable to the visible-wavelength diffuse bands; the scattering properties of grains in new kinds of clouds and nebulae; and the polarization properties of grains in UV wavelengths. The principal advances which may be expected in observations of molecules will include the ability to probe more heavily-obscured regions, where molecular species are more abundant than in the diffuse clouds observed to date; coverage of wavelength regions (such as 1400–3200) not well-studied with previous instruments such asCopernicus; and the capability of observing in optical absorption species detected in the same line of sight in radio emission, which provides unique information on cloud geometry and physical conditions.     

Segregation of dust grains in dark clouds

Gravitational settling of dust grains in dark clouds has been considered. It has been shown that such a process gives rise to a modification of the grain size distribution. Starting with a simple model of uniform spherical cloud and normal interstellar grain size distribution for the dust we derive expressions for the modified grain size distribution function, average grain size and extinction as functions of distance from the cloud's center and the age of the cloud. The mean grain size increases towards the center of the cloud as does the extinction. Results of the numerical evaluation of these quantities have been discussed with their implications for the observations of anomalous reddening and polarization within dark clouds and Bok globules.     

Effects of charged dust grains

Dust grains expelled by radiation pressure of stars are charged to potentials in the range 30–40 V in Hi clouds. These grains may be responsible for the following phenomena which are otherwise hardly explicable. (1) A considerable fraction of electrons knocked-out by charged grains of high speeds have energies around 15 eV and produce singly ionized ions but not doubly ionized ones in accord with an ultraviolet observation of interstellar atoms and ions. (2) Transverse momentum transferred to grains by Coulomb scattering of ambient electrons and protons is greater than that by multiple scattering of cosmic ray protons, thus the former being more effective for the grain alignment than the latter. (3) At a shock front charge separation due to a large inertial mass of grains produces an electric field, thus accelerating charged particles and causing a drift of interstellar matter.     

The inventory of interstellar materials available for the formation of the solar system

Tremendous progress has been made in the field of interstellar dust in recent years through the use of telescopic observations, theoretical studies, laboratory studies of analogs, and the study of actual interstellar samples found in meteorites. It is increasingly clear that the interstellar medium (ISM) contains an enormous diversity of materials created by a wide range of chemical and physical processes. This understanding is a far cry from the picture of interstellar materials held as recently as two decades ago, a picture which incorporated only a few generic types of grains and few molecules. In this paper, I attempt to review some of our current knowledge of the more abundant materials thought to exist in the ISM. The review concentrates on matter in interstellar dense molecular clouds since it is the materials in these environments from which new stars and planetary systems are formed. However, some discussion is reserved for materials in circumstellar environments and in the diffuse ISM. The paper also focuses largely on solid materials as opposed to gases since solids contain a major fraction of the heavier elements in clouds and because solids are most likely to survive incorporation into new planetary systems in identifiable form. The paper concludes with a discussion of some of the implications resulting from the recent growth of our knowledge about interstellar materials and also considers a number of areas in which future work might be expected to yield important results.     

Model for surface reactions on interstellar grains — A numerical study

A model of the formation of molecules by surface reactions on interstellar grains is described and assessed numerically. The model predicts that for the molecules—other than H₂-likely to be important in the interstellar medium, the formation rates by surface reactions are insensitive to the nature of the surface. The formation rates have magnitudes which are significant when compared with other routes. The model also describes H₂ formation in high density clouds and shows it to be parameter dependent.     

Interstellar molecule formation in grain mantles: The laboratory analog experiments,results and implications

Laboratory and theoretical studies have been made of the effects of ultraviolet photolysis of interstellar grain mantles which consist of combinations of hydrogen, oxygen, carbon and nitrogen — dirty ice. It is shown that processes involving photolysis (photoprocessing) of interstellar grains are important during most of their lifetime even including the time they spend in dense clouds. A laboratory designed to simulate the interstellar conditions is described. This is the first time such a laboratory has been able to provide results which may be directly scaled to the astrophysical situations involving interstellar grains and their environment. The evolution of grain analogs is followed by observing the infrared absorption spectra of photolyzed samples of ices deposited at 10 K. The creation and storage of radicals and the production of molecules occur as a result of reactions within the solid. A large number of molecules and radicals observed in the interstellar gas appear in the irradiated ices. Energy released during warm-up is seen from visible luminescence and inferred from vapor pressure enhancement which occurs during warming of photolyzed samples relative to unphotolyzed samples. The evolution of a grain and its role as a source as well as a sink of molecules is pictured as a statistical process within dense clouds. The gradual accretion on and photolysis of an individual grain provides the stored chemical energy the release of which is sporadically triggered by relatively mild events (such as low velocity grain-grain collisions) to produce the impulsive heating needed to eject or evaporate a portion of the grain mantle. An extremely complex and rather refractory substance possessing the infrared signatures of amino groups and carboxylic acid groups and having a maximum mass of 514 amu has been produced at a rate corresponding to a mass conversion rate of interstellar grains of between 2% and 20% in 10⁷ yr. The shape and position of the astronomically observed 3.1 m band is duplicated in the laboratory and is shown to be a natural consequence of the processing of grain mantles.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.     

The formation of iron,stone, and mixed planetesimals in the early solar system

The interaction of dust grains with each other in a finite-temperature solar nebula are examined, taking into account the important fact that such grains would carry net steady-state charges like those of grains in interstellar clouds. This charge is given by the well-known Spitzer relation. It provides a screening mechanism that operates during accretion and results in bodies of differing compositions depending on the local temperature in the nebula. In a typical nebula, it is found that planetesimals of 0.1–10²-cm size form in a time of order 10⁶–10⁷ years. These planetesimals are of iron and stone and mixed composition in the inner solar system, but of mixed composition only in the outer solar system. The predictions of this type of charged-dust accretion can be compared to known data on meteorites and the composition of the planets.     

On the detection of interstellar homonuclear diatomic molecules

The pure rotational spectrum of homonuclear diatomic molecules in the interstellar medium is strongly forbidden, and no such spectrum has been detected. In regions of high excitation, vibrational emission may occur, as is widely detected in the case of H₂ in interstellar shocks and photon-dominated regions. However, it is of considerable interest to know the abundance of homonuclear diatomics in quiescent regions. We propose that vibrational emission from homonuclear diatomic molecules in cold clouds may be detectable, where the excitation is mainly through collisions with non-thermal electrons arising from the cosmic-ray ionization of H₂. As an example, we estimate the intensity of emission from N₂ in cold, dark interstellar clouds. We show that such emission is at the limit of detectability with current technology. Other excitation mechanisms may also contribute and enhance this emission.