Absorption bands and extinction in small interstellar particles

The production of discrete line and broad-band extinction by small interstellar oxide and silicate particles is discussed quantitatively. Restrictions on particle size and refractive index that are required to produce ‘pure’ absorption features are reviewed. The relationship between optical depth in interstellar extinction and absorption coefficients for bulk materials is used to reach some general conclusions concerning the diffuse interstellar features, VUV extinction and the composition of interstellar dust. It is noted that charge transfer bands of ions such as Fe³⁺ may be detectable in the VUV spectrum of dust. Several effects that lead to the enhancement of oscillator strength by 10³–10⁴ in small particles are discussed.     

Laboratory comparisons of organic materials to interstellar dust and the Murchison meteorite

Spectra of objects which lie along several lines of sight through the diffuse interstellar medium (DISM) reveal an absorption feature near 3.4 micrometers, which has been attributed to saturated aliphatic hydrocarbons on interstellar grains. The similarity of the absorption bands near 3.4 micrometers (2950 cm-1) along different lines of sight indicates that the carrier of this band lies in the diffuse dust. Several materials have been proposed as "fits" to the 3.4 micrometers feature over the years. A comparison of these identifications is presented. These comparisons illustrate the need for high resolution, high signal-to-noise observational data as a means of distinguishing between laboratory organics as matches to the interstellar material. Although any material containing hydrocarbons will produce features in the 3.4 micrometers region, the proposed "matches" to the DISM do differ in detail. These differences may help in the analyses of the chemical composition and physical processes which led to the production of the DISM organics, although ISO Observations through the 5-8 micrometers spectral region are essential for a definitive identification. A remarkable similarity between the spectrum of the diffuse dust and an organic extract from the Murchison meteorite suggests that some of the interstellar organic material may be preserved in primitive solar system bodies. The 3.4 micrometers absorption feature (in the rest frame) has recently been detected in external galaxies, indicating the widespread availability of organic material for incorporation into planetary systems.     

Kinetic Monte Carlo method for simulating astrochemical kinetics: Hydrogen chemistry in diffuse clouds

We perform numerical simulations of the molecular hydrogen production on the surface of interstellar dust grains and its dissociation by the ultraviolet background in conditions typical for the interstellar medium. The kinetic version of the Monte Carlo method is used for the modeling of the catalytic chemical reactions on the surface of the dust fraction and in the surrounding medium. Our simulations show the importance of the interstellar dust particles for hydrogen chemistry in diffuse molecular clouds.     

Interstellar Dust in the Solar System

We deduce the mass distribution and total mass density of interstellar dust streaming into the solar system and compare the results to the conditions of the very local interstellar medium (VLISM). The mass distribution derived from in situ measurements shows a gentler slope and includes larger grains, compared to a model distribution proposed for the wavelength dependence of the interstellar extinction. The mass density of grains in the solar system is consistent with that expected from measurements of the visible interstellar extinction and the abundance constraints of elements in the diffuse interstellar medium (ISM), instead of those in the VLISM. This may imply that interstellar dust grains are not associated with the VLISM and that the conditions of the grains are better represented by the ones expected in the diffuse ISM. If this is the case, then the flatter slope in the mass distribution and the detection of larger interstellar grains in the solar system may even indicate that coagulation growth of dust in the diffuse ISM is more effective than previously inferred. This revised version was published online in July 2006 with corrections to the Cover Date.     

ISO observations of 3–200 μm emission by three dust populations in an isolated local translucent cloud

We present isophot spectrophotometry of three positions within the isolated high-latitude cirrus cloud G 300.2−16.8, spanning from the near- to far-infrared (NIR to FIR). The positions exhibit contrasting emission spectrum contributions from the unidentified infrared bands (UIBs), very small grains (VSGs) and large classical grains, and both semi-empirical and numerical models are presented. At all three positions, the UIB spectrum shapes are found to be similar and the large grain emission may be fitted by an equilibrium temperature of  ∼17.5 K  . The energy requirements of both the observed emission spectrum and optical scattered light are shown to be satisfied by the incident local interstellar radiation field (ISRF). The FIR emissivity of dust in G 300.2−16.8 is found to be lower than in globules or dense clouds and is even lower than model predictions for dust in the diffuse interstellar medium (ISM). The results suggest physical differences in the ISM mixtures between positions within the cloud, possibly arising from grain coagulation processes.     

Molecules and dust in circumstellar shells

Circumstellar shells provide a unique environment for the study of dust formation and the relation of dust composition to specific atomic and molecular components. As a specific example, the formation of carbonaceous dust is discussed in relation to the presence of polycyclic aromatic hydrocarbon molecules and their survival in the interstellar medium. Some conclusions will be drawn concerning the composition of carbonaceous dust in circumstellar sources and that in the diffuse interstellar medium.     

X-Ray Scattering on the Interstellar Dust

The interaction of X-rays with interstellar dust leads to small angle scattering. X-ray sources behind sufficiently dense dust columns are therefore surrounded by haloes of faint and diffuse X-ray emission. Since these X-ray sources are also highly absorbed, X-ray observations offer the unique opportunity to measure both components of interstellar extinction simultaneously. This method provides an excellent means of determining interstellar gas to dust ratios, a differentiation between interstellar and circumstellar matter, and, last but not least, a clue to the physical nature of dust itself. In particular we have a plausible explanation why the supernova- explosion in Cassiopaea 300 years ago, of which we know today the remnant Cas A, has not been seen. Furthermore, we find that dust grains must be ‘fluffy’ or porous with voids up to 70%. This revised version was published online in July 2006 with corrections to the Cover Date.     

The identification of diffuse bands

Our present knowledge of the diffuse interstellar bands (two of which were first noted by Wilson in 1958) is briefly summarized. Other broad and very broad interstellar features (the 220nm extinction bump, the very broad structure in the extinction curve, the extended red emission in reflection and other nebulae, and the unidentified-sometimes called the “overidentified”-infrared bands) are also briefly described. The origins of all these features remain unknown, in spite of intensive study. Possible relations between these various features and families is briefly discussed. Recent observations are shown to support the hypothesis that the carriers of the diffuse bands are free-flying molecules, whereas the alternative hypothesis of dust grains now seems to be untenable. Candidate types of molecular carriers are mentioned, and the possible source of such molecules in the diffuse interstellar medium is briefly discussed.     

Dust metamorphosis in the galaxy

Summary Cosmic dust grains play an important role for the thermal, dynamical, and chemical structure of the interstellar medium. This is especially true for the star formation process and the late stages of stellar evolution. Dust grains determine the spectral appearance of protostars, very young stellar objects with disk-like structures as well as of evolved stars with circumstellar envelopes.In this review, we will demonstrate that solid particles in interstellar space are both agent and subject of galactic evolution. We will especially discuss the different dust populations in circumstellar envelopes, the diffuse interstellar medium, and the molecular clouds with strong emphasis on the evolutionary aspects and the metamorphosis of these populations.     

Diatoms on Earth, Comets, Europa and in Interstellar Space

There exists a close correspondence between the measured infrared properties of diatoms and the infrared spectrum of interstellar dust as observed in the Trapezium nebula and toward the galactic center source GC-IRS 7. Diatoms and bacteria also exhibit an absorbance peak near 2200 Å, which is found to agree with the observed ultraviolet absorbance properties of interstellar grains. We review the observational data and consider the known properties of diatoms and bacteria. It is suggested that these characteristics are consistent with the concept of acosmic microbiological system in which these or similar microorganisms might exist on comets, Europa and in interstellar space.     

Diatoms on earth,comets, europa and in interstellar space

There exists a close correspondence between the measured infrared properties of diatoms and the infrared spectrum of interstellar dust as observed in the Trapezium nebula and toward the galactic center source GC-IRS 7. Diatoms and bacteria also exhibit an absorbance peak near 2200 », which is found to agree with the observed ultraviolet absorbance properties of interstellar grains. We review the observational data and consider the known properties of diatoms and bacteria. It is suggested that these characteristics are consistent with the concept of a cosmic microbiological system in which these or similar microorganisms might exist on comets, Europa and in interstellar space.     

Carbon chain abundance in the diffuse interstellar medium.

Thanks to the mid-IR sensitivities of the ISO and IRTS orbiting spectrometers it is now possible to search the diffuse interstellar medium for heretofore inaccessible molecular emission. In view of the recent strong case for the presence of C(7-) (Kirkwood et al. 1998, Tulej et al. 1998),and the fact that carbon chains possess prominent infrared active modes in a very clean portion of the interstellar spectrum, we have analyzed the IRTS spectrum of the diffuse interstellar medium for the infrared signatures of these species. Theoretical and experimental infrared band frequencies and absolute intensities of many different carbon chain species are presented. These include cyanopolyynes, neutral and anionic linear carbon molecules, and neutral and ionized, even-numbered, hydrogenated carbon chains. We show that--as a family--these species have abundances in the diffuse ISM on the order of 10(-10) with respect to hydrogen, values consistent with their abundances in dense molecular clouds. Assuming an average length of 10 C atoms per C-chain implies that roughly a millionth of the cosmically available carbon is in the form of carbon chains and that carbon chains can account for a few percent of the visible to near-IR diffuse interstellar band (DIB) total equivalent width (not DIB number).     

Infrared spectra of small interstellar grains

It is shown that surface stresses in small particles will lead to a broadening and weakening of strong resonances in the infrared spectrum of interstellar dust.     

Remarks on a vibronic origin for the diffuse band spectrum

We have demonstrated that the diffuse band spectrum could not originate as a series of vibronic transitions from atomic impurities in interstellar MgO grains as has recently been proposed since laboratory spectra of such materials show no evidence for such complex structure. Furthermore, recent observational evidence indicates that the extinction feature at 160 nm in the standard interstellar extinction curve upon which the identification of interstellar MgO was founded is actually the result of a calibration error in the original observational data.     

What is the Behavior of the ISM in the SMC?

We describe quantitatively the neutral hydrogen (HI) and dust content of the interstellar medium (ISM) in the Small Magellanic Cloud (SMC),using the spatial power spectrum. The velocity modification of the HI density power spectrum is investigated and discussed.     

DuneXpress

The DuneXpress observatory will characterize interstellar and interplanetary dust in-situ, in order to provide crucial information not achievable with remote sensing astronomical methods. Galactic interstellar dust constitutes the solid phase of matter from which stars and planetary systems form. Interplanetary dust, from comets and asteroids, represents remnant material from bodies at different stages of early solar system evolution. Thus, studies of interstellar and interplanetary dust with DuneXpress in Earth orbit will provide a comparison between the composition of the interstellar medium and primitive planetary objects. Hence DuneXpress will provide insights into the physical conditions during planetary system formation. This comparison of interstellar and interplanetary dust addresses directly themes of highest priority in astrophysics and solar system science, which are described in ESA’s Cosmic Vision. The discoveries of interstellar dust in the outer and inner solar system during the last decade suggest an innovative approach to the characterization of cosmic dust. DuneXpress establishes the next logical step beyond NASA’s Stardust mission, with four major advancements in cosmic dust research: (1) analysis of the elemental and isotopic composition of individual interstellar grains passing through the solar system, (2) determination of the size distribution of interstellar dust at 1 AU from 10^− 14 to 10^− 9 g, (3) characterization of the interstellar dust flow through the planetary system, (4) establish the interrelation of interplanetary dust with comets and asteroids. Additionally, in supporting the dust science objectives, DuneXpress will characterize dust charging in the solar wind and in the Earth’s magnetotail. The science payload consists of two dust telescopes of a total of 0.1 m² sensitive area, three dust cameras totaling 0.4 m² sensitive area, and a nano-dust detector. The dust telescopes measure high-resolution mass spectra of both positive and negative ions released upon impact of dust particles. The dust cameras employ different detection methods and are optimized for (1) large area impact detection and trajectory analysis of submicron sized and larger dust grains, (2) the determination of physical properties, such as flux, mass, speed, and electrical charge. A nano-dust detector searches for nanometer-sized dust particles in interplanetary space. A plasma monitor supports the dust charge measurements, thereby, providing additional information on the dust particles. About 1,000 grains are expected to be recorded by this payload every year, with 20% of these grains providing elemental composition. During the mission submicron to micron-sized interstellar grains are expected to be recorded in statistically significant numbers. DuneXpress will open a new window to dusty universe that will provide unprecedented information on cosmic dust and on the objects from which it is derived.     

The 3.4-μm absorption feature towards three obscured active galactic nuclei

The results of 3–4-μm spectroscopy towards the nuclei of NGC 3094, 7172, and 7479 are reported. In ground-based 8–13-μm spectra, all the sources have strong absorption-like features at ∼10 μm, but they do not have detectable polycyclic aromatic hydrocarbon (PAH) emission features. The 3.4-μm carbonaceous dust absorption features are detected towards all nuclei. NGC 3094 shows a detectable 3.3-μm PAH emission feature, while NGC 7172 and 7479 do not. Nuclear emission whose spectrum shows dust absorption features but no PAH emission features, is thought to be dominated by highly obscured active galactic nuclei (AGNs) activity. For NGC 7172, 7479, and three other such nuclei in the literature, we investigate the optical depth ratios between the 3.4-μm carbonaceous dust and 9.7-μm silicate dust absorption     The     ratios towards three highly obscured AGNs with face-on host galaxies are systematically larger than the ratios in the Galactic diffuse interstellar medium or the ratios for two highly obscured AGNs with edge-on host galaxies. We suggest that the larger ratios can be explained if the obscuring dust is so close to the central AGNs that a temperature gradient occurs in it. If this idea is correct, our results may provide spectroscopic evidence for the presence of the putative 'dusty tori' in the close vicinity of AGNs.     

Optical emission at 5800 Å in the Red Rectangle and the 5797-Å diffuse interstellar band

An analysis of the intensity and spatial distribution of the discrete 5800-Å emission band in the spectrum of the Red Rectangle has been used to constrain the abundance and physical properties of the carrier of this emission. An origin in a large (>30 C atom) molecule is indicated. This molecule is formed in situ in the Red Rectangle, but is also a component of the diffuse interstellar medium. The UV photodissociation probability for this molecule is ≲10⁻⁵ per absorbed photon, and the luminescence efficiency is in the range 10⁻²–10⁻³. This molecule may be a product of the dissociation of carbonaceous dust.     

Correlation patterns between 11 diffuse interstellar bands and ultraviolet extinction

We relate the equivalent widths of 11 diffuse interstellar bands, measured in the spectra of 49 stars, to different colour excesses in the ultraviolet. We find that most of the observed bands correlate positively with the extinction in the neighbourhood of the 2175-Å  bump. Correlation with colour excesses in other parts of the extinction curve is more variable from one diffuse interstellar band to another; we find that some diffuse bands (5797, 5850 and 6376 Å) correlate positively with the overall slope of the extinction curve, while others (5780 and 6284 Å) exhibit negative correlation. We discuss the implications of these results on the links between the diffuse interstellar band carriers and the properties of the interstellar grains.     

2002 Kuiper prize lecture: Dust Astronomy

Dust particles, like photons, carry information from remote sites in space and time. From knowledge of the dust particles' birthplace and their bulk properties, we can learn about the remote environment out of which the particles were formed. This approach is called “Dust Astronomy” which is carried out by means of a dust telescope on a Dust Observatory in space. Targets for a dust telescope are the local interstellar medium and nearby star forming regions, as well as comets and asteroids. Dust from interstellar and interplanetary sources is distinguished by accurately sensing their trajectories. Trajectory sensors may use the electric charge signals that are induced when charged grains fly through the detector. Modern in-situ dust impact detectors are capable of providing mass, speed, physical and chemical information of dust grains in space. A Dust Observatory mission is feasible with state-of-the-art technology. It will (1) provide the distinction between interstellar dust and interplanetary dust of cometary and asteroidal origin, (2) determine the elemental composition of impacting dust particles, and (3) monitor the fluxes of various dust components as a function of direction and particle masses.