Principles of Probabilistic Regional Mineral Resource Estimation

Five principal sources of uncertainty in quantitative mineral resource estimation are listed and illustrated by means of a simple example (mosaic model) and a case history study for large copper deposits in the Abitibi area of the Canadian Shield. Abitibi copper potential originally was estimated on the basis of 1968 estimates of production and reserves totalling 3.12 Mt Cu. This prognostication now could be evaluated on the basis of 2008 copper production and reserves totalling 9.50 Mt Cu. An earlier hindsight study performed on the basis of 1977 data (totalling 5.23 Mt Cu) showed seven new discoveries occurring either in the immediate vicinities of known deposits or on broad regional copper anomalies predicted from the 1968 inputs. By 1977, the global geographic distribution pattern of large copper deposits in the Abitibi area had stabilized. During the next 30 years, new copper was essentially found close to existing deposits, much of it deeper down in the Earth's crust. In this paper, uncertainties associated with copper ore tonnage are analyzed by comparison of 2008 data with 1968 data using (a) log-log plots of size versus rank, and (b) lognormal QQ-plots. Straight lines fitted by least squares on these plots show that 1968 slopes provide good estimates of 2008 slopes but 1968 intercepts are much less than 2008 intercepts. In each linear log-weight versus log-rank plot, the slope is related to fractal dimension of a Pareto frequency distribution, and in a lognormal QQ-plot it is determined by logarithmic variance. The difference between 2008 and 1968 intercepts represents the increase in copper ore production and reserves from 1968 to 2008. The Pareto model fits actual copper and massive sulphides increase over the past 40 years better than the lognormal frequency distribution model for 10 km×10 km cells on favorable environments in the Abitibi area.      

利用测井信息评价盐湖相烃源岩

盐湖相烃源岩富含膏、盐质成分,使其测井响应特征发生极大改变,给测井评价烃源岩带来困难。基于实测数据,分析了盐湖相烃源岩中普遍发育的纯泥岩、含膏(盐)泥岩和膏(盐)质泥岩有机碳含量的测井响应模式,发现纯泥岩和含膏(盐)泥岩TOC与AC和LogRt呈正比,与DEN呈反比,膏(盐)质泥岩TOC与DEN呈正比,与LogRt呈反比,并基于此建立了盐湖相烃源岩测井评价方法,即首先利用ΔGR区分岩性,再针对不同岩性建立TOC评价模型,最后根据实测S₁+S₂和TOC建立相关关系,就可以求取烃源岩的TOC和S₁+S₂。利用该方法对东营凹陷沙四下亚段烃源岩性质和展布进行分析,发现预测TOC与实测TOC吻合程度高,具有一定推广价值。     

中国昆明地区岩溶洞穴洞口带苔藓植物研究

为了研究中国西南岩溶洞穴植物区系与生物多样性特征, 作者曾两次对云南昆明地区12个岩溶洞穴进行了野外考察和苔藓植物标本采集工作。其中含昆明市石灰岩洞穴1个, 石林县石灰岩洞穴5个和宜良县白云岩洞穴6个。根据采自12个岩溶洞穴洞口带的164件苔藓植物标本研究, 本文首次报道昆明地区洞穴苔藓植物10科18属25种。昆明地区洞穴中分布较多的苔藓植物科有丛藓科( Po ttiaceae) 5属8种,凤尾藓科( Fi ssidentaceae ) 1属4种,柳叶藓科( Amblystegiaceae ) 3 属3 种和青藓(Brachytheciaceae ) 2属3种。溶洞中较常见的4种苔藓植物种类是萤光苔类植物光苔Cyathodiumcavernarum Kunze ( 见于6个溶洞中) , 小凤尾藓Fissidens bryoides Hedw ( 见于4个溶洞中) , 橙色净口藓Gymnostonum calcareum Nees et Ho rsch (见于3 个溶洞中)和长叶扭口藓Tortella tortuosa( Hedw ) Limp ( 见于3个溶洞中)。野外观察表明,受洞穴弱光环境生态因子的限制, 昆明地区洞穴苔藓植物主要生长于洞穴洞口0～ 26m带范围内; 2种丛集型藓类植物, 橙色净口藓Gymnostonumcalcareum Nees et Horsch, 和钩喙净口藓G.recurvirost re Hedw 参与洞口带钟乳石或石笋钙华沉积。      

Analysis on the deployment of mining research supported by the grant program of Deep Resources Exploration and Mining

The Deep Resources Exploration and Mining(DREAM) grant program, within the framework of The National Key Research and Development Program grants, is a pillar to implement China's science and technology strategy in the area of deep resources exploitation. To tackle the insufficient of theories and technologies for the 1000-meter-deep mining, a section of mining, covering the research of basic theories, general technologies and application demonstration, was arranged in the layout of DREAM under the principle of "whole chain design, integrated implementation". In the aspect of basic research, DREAM mainly focused on the deep rock mechanics and mining theory, such as the in-situ mechanical behavior of deep rock, deep high stress induction and energy regulation theory. For the general and key technologies, DREAM supported the research on the mine construction and hoisting, excavation, rock breaking, mining methods and mining safety according to the characteristics of coal and metal mines. For the demonstration application, taking green, safe and efficient as the starting point, DREAM aimed at the green, safe and high efficiency mining, and the demonstration and leading role projects such as the low-waste and high-efficiency back fill mining. Since 2016, 10 RD projects have been funded, and 122 institutional participants with a total budget of RMB 235 million from the central government and RMB 480 million from enterprises as well as local governments have been involved. It is expected that the mining section of DREAM would contribute to establishing the theory and technology system in the area of deep mining and promoting the ability of deep resource exploitation in China.     

Geology and mineralization of the Tiegelongnan supergiant porphyry-epithermal Cu (Au,Ag) deposit (10 Mt) in western Tibet,China: A review

The Tiegelongnan Cu(Au,Ag)deposit in central Tibet contains more than 10 Mt of copper ranking 29 th in the world.It is characterized by typical porphyry-epithermal alteration and mineralization.In order to improve the understanding of porphyry-epithermal copper deposit in Tibet,new zircon U-Pb age and sulfur isotope data along with published data in the Tiegelongnan are presented to investigate the formation and preservation mechanism.Ore-related intrusive rocks in the Tiegelongnan including Early Cretaceous(about 120 Ma)granodiorite porphyry and diorite porphyry are closely related to the northward subduction of Bangongco-Nujiang ocean.Sulfur mainly comes from deep magma,and ore-forming fluid is affected by both magmatic and meteoric water.The metallogenic setting of Tiegelongnan is consistent with those of Andean porphyry copper deposits in South America.The cover of the Meiriqiecuo Formation volcanic rocks,Lhasa-Qiangtang collision and India-Eurasian collision have significance in the preservation and uplift of the deposit.The formation,preservation and discovery of Tiegelongnan play an important role in exploration of ancient porphyry-epithermal deposits in Tibet.     

Ecological environment response of benthic foraminifera to heavy metals and human engineering: A case study from Jiaozhou Bay,China

The estuary and coastal zone are the key areas for socio-economic development,and they are also the important channels for pollutants transported to the sea.The construction of the Jiaozhou Bay Bridge changed the hydrodynamic condition of the bay,which made the self-purification capacity of the bay weakened and the pollution in the estuary and adjacent coastal zone become more serious.In this study,55 surface sediment samples were collected from the three seriously polluted estuaries and the adjacent coastal zone of Jiaozhou Bay to comprehensively study how the benthic foraminifera response to heavy metal pollution and human engineering,and to assess the ecological risks of the bay.A total of 80 species,belonging to 42 genera,were identified in this study.The results showed that Cu,Pb,Cr,Hg,Zn,and As had low to median ecological risks in the study area which would definitely affect the ecological system.The construction of the Jiaozhou Bay Bridge has resulted in pollutants accumulated at the river mouth of Loushan River,which has adverse effects on the survival and growth of benthic foraminifera.The lowest population density and diversity as well as the highest FAI(Foraminiferal Abnormality Index)and FMI(Foraminiferal Monitoring Index)occurred at Loushan River Estuary which indicated that the ecological environment of the northeastern part of Jiaozhou Bay(Loushan River Estuary)had been seriously damaged.Licun River and Haipo River estuaries and the adjacent coastal zone were slightly polluted and had low ecological risk.As a consequence,it suggested that the supervision of industrial and domestic waste discharge and the protection of the ecological environment in northeast Jiaozhou Bay should be paid more attention.     

Molecular Organic Geochemical Characteristics and Coal Gas Potential Evaluation of Mesozoic Coal Seams in the Western Great Khingan Mountains

Coal-bearing strata are widespread in the western Great Khingan Mountains. Abundant coal resources have been found in the Jurassic Alatanheli Groups, the Cretaceous Bayanhua Groups, the Damoguaihe Formation and the Yimin Formation. The organic geochemical characteristics were analyzed in combination with hydrocarbon source rock evaluation and molecular organic geochemistry experiments, and the coal gas potential of coal seams was evaluated. The source rock evaluation results indicated that the Mesozoic coal samples have the characteristics of high organic matter abundance(TOC>30%), low maturity(Ro values of approximately 0.6%), and type Ⅲ composition. The hydrocarbon generation potentials of the Alatanheli Groups and Bayanhua Groups are high, while the generation potentials of the Damoguaihe Formation and the Yimin Formation are low. The results of geochemistry show that the depositional environment of the coal seam was a lacustrine, oxidizing environment with a low salinity, and the source of the organic matter was mainly higher plants. Affected by weak degradation, the coal seams mainly formed low-maturity gas of thermal catalytic origin. The Cretaceous coal seams contain a large amount of phytoplankton groups deposited in a low-stability environment affected by a transgression event, and the potential range varied widely. For the Jurassic coal seams, the depositional environment was more stable, and the coal seams feature a higher coal-forming gas potential.     

Carbon cycle variability in tropical Atlantic across two Early Eocene hyperthermals

Early Eocene hyperthermals are geologically short-lived global warming events and represent fundamental perturbations to the global carbon cycle and the Earth’s ecosystem due to massive additions of isotopically light carbon to the ocean-atmosphere system.They serve as ancient analogs for understanding how the oceanic carbonate system and surface-ocean ecosystem would respond to ongoing and future climate change.Here,we present a continuous carbonate record across the Eocene Thermal Maximum 2(ETM2 or H1,ca.54.1 Ma)and H2(ca.54 Ma)events from an expanded section at Ocean Drilling Program Site 1258 in tropical Atlantic.The abundant calcareous nannofossils and moderate carbonate content throughout the studied interval suggest this record was deposited above the calcite compensation depth(CCD),but below the lysocline and under the influence of terrestrial dilution.An Earth system model cGENIE is used to simulate the carbon cycle dynamics across the ETM2 and H2 to offer insights on the mechanism of the rapid warming and subsequent recovery in climate and ecosystem.The model suggests moderate changes in ocean pH(0.1–0.2 unit)for the two scenarios,biogenic methane from a rechargeable methane capacitor and organic matter oxidation from thawing of the permafrost.These pH changes are consistent with a recent independent pH estimate across the ETM2 using boron isotopes.The carbon emission flux during the ETM2 is at least an order of magnitude smaller than that during the Paleocene–Eocene Thermal Maximum(PETM)(0.015–0.05 Pg C yr^-1vs.0.3–1.7 Pg C yr^-1).The comparable pre-and post-event carbonate contents suggest the lysocline did not over deepen following the ETM2 at this tropical Atlantic site,indicating spatial heterogeneity in the carbonate system due to strong dilution influence from terrestrial weathering and riverine discharge at Site 1258.     

Controlling Effects of Tight Reservoir Micropore Structures on Seepage Ability: A Case Study of the Upper Paleozoic of the Eastern Ordos Basin,China

In this study, the types of micropores in a reservoir are analyzed using casting thin section(CTS) observation and scanning electron microscopy(SEM) experiments. The high-pressure mercury injection(HPMI) and constant-rate mercury injection(CRMI) experiments are performed to study the micropore structure of the reservoir. Nuclear magnetic resonance(NMR), gas-water relative seepage, and gas-water two-phase displacement studies are performed to examine the seepage ability and parameters of the reservoir, and further analyses are done to confirm the controlling effects of reservoir micropore structures on seepage ability. The experimental results show that Benxi, Taiyuan, Shanxi, and Shihezi formations in the study area are typical ultra-low porosity and ultra-low permeability reservoirs. Owing to compaction and later diagenetic transformation, they contain few primary pores. Secondary pores are the main pore types of reservoirs in the study area. Six main types of secondary pores are: intergranular dissolved pores, intragranular dissolved pores, lithic dissolved pores, intercrystalline dissolved pores, micropores, and microfracture. The results show that reservoirs with small pore-throat radius, medium displacement pressure, and large differences in pore-throat structures are present in the study area. The four types of micropore structures observed are: lower displacement pressure and fine pores with medium-fine throats, low displacement pressure and fine micropores with fine throats, medium displacement pressure and micropores with micro-fine throats, and high displacement pressure and micropores with micro throats. The micropore structure is complex, and the reservoir seepage ability is poor in the study areas. The movable fluid saturation, range of the gas-water two-phase seepage zone, and displacement types are the three parameters that well represent the reservoir seepage ability. According to the characteristic parameters of microscopic pore structure and seepage characteristics, the reservoirs in the study area are classified into four types(Ⅰ–Ⅳ), and types Ⅰ, Ⅱ, and Ⅲ are the main types observed. From type Ⅰ to type Ⅳ, the displacement pressure increases, and the movable fluid saturation and gas-water two-phase seepage zone decrease, and the displacement type changes from the reticulation-uniform displacement to dendritic and snake like.     

"江苏省生态环境地质调查与监测"项目在宁通过评审

2007年1月29日,“江苏省生态环境地质调查与监测”项目在南京通过评审,成果优秀。中国地质调查局常务副局长王宝才出席评审会并发表讲话,江苏省国土资源厅厅长陶培荣在评审会上致辞。出席此次评审会的专家分别来自中科院、中国地质环境监测院以及中国地质大学等科研机构和院校,参加此次评审会的还有中国地质调查局、江苏省政府、江苏省国土资源厅有关负责人及多家媒体单位。评审会由江苏省国土资源厅副厅长刘聪主持。“江苏省生态环境地质调查与监测”项目是江苏省人民政府和国土资源部中国地质调查局合作开展的、大调查实施以来全国最大的…     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.