激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。     

Catastrophic floods as a possible cause of organic matter accumulation giving rise to coal, Paraná Basin, Brazil

Gondwana coals of the Rio Bonito Formation (Paraná Basin) in Southern Brazil have generally large ash yields, so they could be better called coaly siltstones than coal. In addition, hummocky cross stratification (HCS) was found in several coal beds of the Rio Bonito Formation throughout the basin. In this formation, the frequent and close relationship between facies involving rocks generated by subaqueous gravity flows (diamictites) and coal itself provides an excellent depositional model based on resedimentary processes acting during deposition, as well as a stratigraphic rearrangement of the present units.In the State of Rio Grande do Sul (southern part of Paraná Basin), coals are actually prodelta deposits related to delta-front diamictite and conglomeratic sandstone with sigmoidal bedding. Coal-forming organic sediments would come from trees plucked by the floods, as indicated by the wood logs floating in the diamictite, and reworking of previous peat accumulations. Every coal layer is covered generally by paleosoil siltstones, which represent colonization at the top of the catastrophic flood deposit, ending a sedimentary cycle.In case of Brazilian coal settings, several authors recognized deltas (fan deltas or braid deltas). Here is particularly considered the general environment as a salted interior sea (lago mare, Hsü et al. sense).The present study will refer to three important lithostratigraphic units in the Carboniferous–Early Triassic cycle: the Itararé Group, the Rio Bonito Formation, and the Palermo Formation.Although the preferential mode of occurrence of HCS in shallow marine environments indicates a genesis attributed to storm action, other causes, such as catastrophic flooding, have been advanced. Mutti et al. [Mem. Sci. Geol. 48 (1996) 233] described flood-dominated deltaic systems with thick conglomerate, sandstone, and pelitic deposits, derived from small- to medium-scale fluvial systems and mountain-bordered drainage basins adjacent to the sea. In such settings, seaward sediment flow can increase dramatically when weather conditions can supply water in such amounts to produce catastrophic floods. Thick and laterally extensive sandstone lobes with HCS are the fundamental depositional elements of fan deltas and other river-dominated delta systems.Diamictites and coal together could be a result from Jökullhlaups—an Icelandic term for glacial outburst flood—in case of catastrophic floods coming from a melting mountain glacier, similar to the Columbia River Valley Scablands (15,000 BP) and in modern Iceland examples.     

Ice flow direction during late Paleozoic glaciation in western Paraná Basin, Brazil

The recent discovery of ice-striated surfaces associated with the late Paleozoic Aquidauana Formation suggests that glaciers coming from southwest Africa reached westernmost parts of the Paraná Basin in central Brazil. Abrasion features were developed by glaciers moving from SSE towards NNW, mainly on an unconsolidated bed. These records expand to about 1,050,000 km², the coverage of the late Paleozoic glaciation in the region of the Paraná Basin in Western Gondwana.

Resumen

A recente descoberta de superfícies estriadas associadas à Formação Aquidauana, de idade permocarbonífera, sugere que as geleiras provenientes do sudoeste da África alcançaram as porções ocidentais da Bacia do Paraná, na região central do Brasil. As feições de abrasão foram geradas pelo deslocamento de geleiras de SSE para NNW, principalmente sobre substrato inconsolidado. Estes novos registros evidenciam que a glaciação neopaleozóica cobriu uma área de pelo menos de 1.050.000 km² na região ocupada pela Bacia do Paraná no Gondwana Ocidental.     

Coal petrology of coal seams from the Leão-Butiá Coalfield, Lower Permian of the Paraná Basin, Brazil — Implications for coal facies interpretations

In the Leão-Butiá Coalfield, Rio Grande do Sul the coal seams occur in the Rio Bonito Formation, Guatá Group, Tubarão Supergroup of the Paraná Basin, Brazil and are of Permian (Artinskian–Kungurian) age.This study is the first detailed investigation on the coal petrographic characterization of the coal-bearing sequence in relation to the depositional settings of the precursor mires, both in terms of whole seam characterization and in-seam variations. The study is based on the analyses of nine coal seams (I2, CI, L4, L3, L2, L1, S3, S2, S1), which were selected from core of borehole D-193, Leão-Butiá and represent the entire coal-bearing sequence.The interpretation of coal facies and depositional environment is based on lithotype, maceral and microlithotype analyses using different facies-critical petrographic indices, which were displayed in coal facies diagrams. The seams are characterized by the predominance of dull lithotypes (dull, banded dull). The dullness of the coal is attributed to relatively high mineral matter, inertinite and liptinite contents. The petrographic composition is dominated by vitrinite (28–70 vol.% mmf) and inertinite (> 30 vol.% mmf) groups. Liptinite contents range from 7 to 30 vol.% (mmf) and mineral matter from 4–30 vol.%. Microlithotypes associations are dominated by vitrite, duroclarite, carbominerite and inertite. It is suggested that the observed vertical variations in petrographic characteristics (lithotypes, microlithotypes, macerals, vitrinite reflectance) were controlled by groundwater level fluctuations in the ancient mires due to different accommodation/peat accumulation rates.Correlation of the borehole strata with the general sequence-stratigraphical setting suggests that the alluvial fan system and the coal-bearing mudstone succession are linked to a late transgressive systems tract of sequence 2. Based on average compositional values obtained from coal facies diagrams, a deposition in a limno-telmatic to limnic coal facies is suggested.