The crater lake and hydrothermal system of Mount Pinatubo,Philippines: evolution in the decade after eruption

The June 1991 eruption of Mount Pinatubo, Philippines breached a significant, pre-eruptive magmatic-hydrothermal system consisting of a hot (>300 °C) core at two-phase conditions and surrounding, cooler (<260 °C) liquid outflows to the N and S. The eruption created a large, closed crater that accumulated hydrothermal upwellings, near-surface aquifer and meteoric inflows. A shallow lake formed by early September 1991, and showed a long-term increase in level of ~1 m/month until an artificial drainage was created in September 2001. Comparison of the temporal trends in lake chemistry to pre- and post-eruptive springs distinguishes processes important in lake evolution. The lake was initially near-neutral pH and dominated by meteoric influx and Cl–SO₄ and Cl–HCO₃ hydrothermal waters, with peaks in SO₄ and Ca concentrations resulting from leaching of anhydrite and aerosol-laden tephra. Magmatic discharge, acidity (pH~2) and rock dissolution peaked in late 1992, during and immediately after eruption of a lava dome on the crater floor. Since cessation of dome growth, trends in lake pH (increase from 3 to 5.5), temperature (decline from 40 to 26 °C), and chemical and isotopic composition indicate that magmatic degassing and rock dissolution have declined significantly relative to the input of meteoric water and immature hydrothermal brine. Higher concentrations of Cl, Na, K, Li and B, and lower concentrations of Mg, Ca, Fe, SO₄ and F up to 1999 highlight the importance of a dilute hydrothermal contribution, as do stable-isotope and tritium compositions of the various fluids. However, samples taken since that time indicate further dilution and steeper trends of increasing pH and declining temperature. Present gas and brine compositions from crater fumaroles and hot springs indicate boiling of an immature Cl–SO₄ geothermal fluid of near-neutral pH at approximately 200 °C, rather than direct discharge from magma. It appears that remnants of the pre-eruptive hydrothermal system invaded the magma conduit shortly after the end of dome emplacement, blocking the direct degassing path. This, along with the large catchment area (~5 km²) and the high precipitation rate of the area, led to a rapid transition from a small and hot acid lake to a large lake with near-ambient temperature and pH. This behavior contrasts with that of peak-activity lakes that have more sustained volcanic gas influx (e.g., Kawah Ijen, Indonesia; Poas and Rincón de la Vieja, Costa Rica).Editorial responsibility: H. Shinohara     

Geochemistry of the magmatic–hydrothermal system of Kawah Ijen volcano, East Java, Indonesia

Samples from Kawah Ijen crater lake, spring and fumarole discharges were collected between 1990 and 1996 for chemical and isotopic analysis. An extremely low pH (<0.3) lake contains SO₄–Cl waters produced during absorption of magmatic volatiles into shallow ground water. The acidic waters dissolve the rock isochemically to produce “immature” solutions. The strong D and ¹⁸O enrichment of the lake is mainly due to enhanced evaporation at elevated temperature, but involvement of a magmatic component with heavy isotopic ratios also modifies the lake D and ¹⁸O content. The large Δ_SO4–S⁰ (23.8–26.4‰) measured in the lake suggest that dissolved SO₄ forms during disproportionation of magmatic SO₂ in the hydrothermal conduit at temperatures of 250280°C. The lake δ¹⁸O_SO4 and δ¹⁸O_H2O values may reflect equilibration during subsurface circulation of the water at temperatures near 150°C. Significant variations in the lake's bulk composition from 1990 to 1996 were not detected. However, we interpret a change in the distribution and concentration of polythionate species in 1996 as a result of increased SO₂-rich gas input to the lake system.Thermal springs at Kawah Ijen consist of acidic SO₄–Cl waters on the lakeshore and neutral pH HCO₃–SO₄–Cl–Na waters in Blawan village, 17 km from the crater. The cation contents of these discharges are diluted compared to the crater lake but still do not represent equilibrium with the rock. The SO₄/Cl ratios and water and sulfur isotopic compositions support the idea that these springs are mixtures of summit acidic SO₄–Cl water and ground water.The lakeshore fumarole discharges (T=170245°C) have both a magmatic and a hydrothermal component and are supersaturated with respect to elemental sulfur. The apparent equilibrium temperature of the gas is 260°C. The proportions of the oxidized, SO₂-dominated magmatic vapor and of the reduced, H₂S-dominated hydrothermal vapor in the fumaroles varied between 1979 and 1996. This may be the result of interaction of SO₂-bearing magmatic vapors with the summit acidic hydrothermal reservoir. This idea is supported by the lower H₂S/SO₂ ratio deduced for the gas producing the SO₄–Cl reservoir feeding the lake compared with that observed in the subaerial gas discharges. The condensing gas may have equilibrated in a liquid–vapor zone at about 350°C.Elemental sulfur occurs in the crater lake environment as banded sediments exposed on the lakeshore and as a subaqueous molten body on the crater floor. The sediments were precipitated in the past during inorganic oxidation of H₂S in the lake water. This process was not continuous, but was interrupted by periods of massive silica (poorly crystallized) precipitation, similar to the present-day lake conditions. We suggest that the factor controlling the type of deposition is related to whether H₂S- or silica-rich volcanic discharges enter the lake. This could depend on the efficiency with which the lake water circulates in the hydrothermal cell beneath the crater. Quenched liquid sulfur products show δ³⁴S values similar to those found in the banded deposits, suggesting that the subaqueous molten body simply consists of melted sediments previously accumulated at the lake bottom.     

Some results from recent chemical studies at Kilauea volcano,Hawaii

The chemical surveillance of Kilauea volcano, Hawaii, has continued. No relationship has thus far been identified between the helium content of an associated fumarole and the activity at the volcano. Fume samples from Halemaumau crater in Kilauea caldera and from a fissure eruption that occurred nearby on the floor of the caldera during August 1971 were examined for their halogen (Cl and F) and sulfur contents. The ratio of Cl/F in fume showed an abnormal increase in samples taken at Halemaumau a month before the eruption. This change in ratio may be a helpful indicator of the onset of eruption in volcanic areas.     

Integrated field, satellite and petrological observations of the November 2010 eruption of Erta Ale

Erta Ale volcano, Ethiopia, erupted in November 2010, emplacing new lava flows on the main crater floor, the first such eruption from the southern pit into the main crater since 1973, and the first eruption at this remote volcano in the modern satellite age. For many decades, Erta Ale has contained a persistently active lava lake which is ordinarily confined, several tens of metres below the level of the main crater, within the southern pit. We combine on-the-ground field observations with multispectral imaging from the SEVIRI satellite to reconstruct the entire eruptive episode beginning on 11 November and ending prior to 14 December 2010. A period of quiescence occurred between 14 and 19 November. The main eruptive activity developed between 19 and 22 November, finally subsiding to pre-eruptive levels between 8 and 15 December. The estimated total volume of lava erupted is ??0.006?km³. The mineralogy of the 2010 lava is plagioclase?+?clinopyroxene?+?olivine. Geochemically, the lava is slightly more mafic than previously erupted lava lining the caldera floor, but lies within the range of historical lavas from Erta Ale. SIMS analysis of olivine-hosted melt inclusions shows the Erta Ale lavas to be relatively volatile-poor, with H₂O contents ??1,300?ppm and CO₂ contents of ??200?ppm. Incompatible trace and volatile element systematics of melt inclusions show, however, that the November 2010 lavas were volatile-saturated, and that degassing and crystallisation occurred concomitantly. Volatile saturation pressures are in the range 7?C42?MPa, indicating shallow crystallisation. Calculated pre-eruption and melt inclusion entrapment temperatures from mineral/liquid thermometers are ??1,150?°C, consistent with previously published field measurements.     

Seismological studies of the soufriere of St. Vincent, 1953-79: Implications for volcanic surveillance in the lesser antilles

The Soufriere of St. Vincent has been monitored for more than 25 years as part of a regional programme in the Lesser Antilles. In that time the volcano has erupted twice but our studies have shown no discernible change in regional seismicity before either event. However, very small seismic events were observed in the crater during the 1971–1972 eruption and were detected before the start of the 1979 explosive eruption; we believe that they were generated by thermally induced hydraulic fracturing within the lava mass inside the crater lake. We conclude that seismographic monitoring of Lesser Antillean volcanoes can give ambiguous results but that at least one instrument must be placed within 1 km of the vent if the earliest signs of activity are to be detected.     

The geology of split butte — A maar of the south-central snake river plain,Idaho

Split Butte is a volcanic crater of Quaternary age consisting of a tephra ring which at one time retained a lava lake. The tephra is thinly bedded and is composed of partially palagonitized sideromelane clasts and subordinate lithic fragments. The beds typically dip radially away from the center of the crater, but locally dip toward the crater center. The tephra ring resulted from phreatomagmatic eruptions as a result of interaction of groundwater with rising basaltic magma, evidenced by glassy and granulated pyroclastic debris, the presence of abundant palagonite and other secondary minerals, numerous armored lapilli, and plastically deformed ash layers below ejecta blocks. Statistical analysis of the grain size distribution of the ash also indicates a phreatomagmatic origin of Split Butte tephra. In addition, the analysis reveals that the stratigraphically lowest tephra was deposited primarily by pyroclastic flow mechanisms while the upper tephra layers, comprising the bulk of the deposits, were deposited dominantly by airfall and pyroclastic surge. The lava lake and four en echelon basalt dikes were emplaced when phreatomagmatic activity at the vent ceased. Subsequent collapse caused a broad, shallow pit crater to form in the laval lake, and minor spattering occurred at one point along the pit crater scarp. Partial erosion of the tephra, deposition of aeolian sediments and encroachment of the Butte by later lava flows completed the development of Split Butte.     

A preparation zone for volcanic explosions beneath Naka-dake crater,Aso volcano,as inferred from magnetotelluric surveys

The 1st crater of Naka-dake, Aso volcano, is one of the most active craters in Japan, and known to have a characteristic cycle of activity that consists of the formation of a crater lake, drying-up of the lake water, and finally a Strombolian-type eruption. Recent observations indicate an increase in eruptive activity including a decrease in the level of the lake water, mud eruptions, and red hot glows on the crater wall. Temporal variations in the geomagnetic field observed around the craters of Naka-dake also indicate that thermal demagnetization of the subsurface rocks has been occurring in shallow subsurface areas around the 1st crater. Volcanic explosions act to release the energy transferred from magma or volcanic fluids. Measurement of the subsurface electrical resistivity is a promising method in investigating the shallow structure of the volcanic edifices, where energy from various sources accumulates, and in investigating the behaviors of magma and volcanic fluids. We carried out audio-frequency magnetotelluric surveys around the craters of Naka-dake in 2004 and 2005 to determine the detailed electrical structure down to a depth of around 1 km. The main objective of this study is to identify the specific subsurface structure that acts to store energy as a preparation zone for volcanic eruption. Two-dimensional inversions were applied to four profiles across the craters, revealing a strongly conductive zone at several hundred meters depth beneath the 1st crater and surrounding area. In contrast, we found no such remarkable conductor at shallow depths beneath the 4th crater, which has been inactive for 70 years, finding instead a relatively resistive body. The distribution of the rotational invariant of the magnetotelluric impedance tensor is consistent with the inversion results. This unusual shallow structure probably reflects the existence of a supply path of high-temperature volcanic gases to the crater bottom. We propose that the upper part of the conductor identified beneath the 1st crater is mainly composed of hydrothermally altered zone that acts both as a cap to upwelling fluids supplied from deep-level magma and as a floor to infiltrating fluid from the crater lake. The relatively resistive body found beneath the 4th crater represents consolidated magma. These results suggest that the shallow conductor beneath the active crater is closely related to a component of the mechanism that controls volcanic activity within Naka-dake.     

DUCKS: Low cost thermal monitoring units for near-vent deployment

During 1999 we designed and tested a thermal monitoring system to provide a cheap, robust, modular, real-time system capable of surviving the hostile conditions encountered proximal to active volcanic vents. In November 2000 the first system was deployed at Pu'u 'O'o (Kilauea, Hawai'i) to target persistently active vents. Aside from some minor problems, such as sensor damage due to tampering, this system remained operational until January 2004. The success of the prototype system led us to use the blueprint for a second installation at Stromboli (Aeolian Islands, Italy). This was deployed, dug into a bomb-proof bunker, during May 2002 and survived the April 2003 paroxysmal eruption despite being located just 250 m from the vent. In both cases, careful waterproofing of connectors and selection of suitable protection has prevented water damage and corrosion in the harsh atmosphere encountered at the crater rim.The Pu'u 'O'o system cost ∼US$10,000 and comprises four modules: sensors, transmission and power hub, repeater station and reception site. The sensor component consists of three thermal infrared thermometers housed in Pelican™ cases fitted with Germanium–Arsenide–Selenium windows. Two 1° field of view (FOV) sensors allow specific vents to be targeted and a 60° FOV sensor provides a crater floor overview. A hard wire connection links to a Pelican™-case-housed microprocessor, modem and power module. From here data are transmitted, via a repeater site, to a dedicated PC at the Hawaiian Volcano Observatory. Here data are displayed with a delay of ∼3 s between acquisition and display. The modular design allows for great flexibility. At Stromboli, 1° and 15° FOV sensor modules can be switched depending changes in activity style and crater geometry. In addition a direct line of site to the Stromboli reception center negates the repeater site requirement, reducing the cost to US$5500 for a single sensor system.We have also constructed self-contained units with internal data loggers for US$1500/unit. These have been tested at Kilauea, Stromboli, Etna, Masaya, Santiaguito, Fuego, Pacaya, Poas, Soufriere Hills, Villarrica and Erta Ale. These instruments have proved capable of detecting thermal signals associated with: (1) gas emission; (2) gas jetting events; (3) crater floor collapse; (4) lava effusion; (5) lava flow in tubes; (6) lava lake activity; (7) lava dome activity; and (8) crater lake skin temperature.     

Numerical model of crater lake eruptions

We present results from a numerical investigation of subaqueous eruptions involving superheated steam released through a lake mimicking the volcanic setting at Mt. Ruapehu. The simulations were conducted using an adaptive mesh, multi-material, hydrodynamics code with thermal conduction SAGE, (Simple Adaptive Grid Eulerian). Parameters investigated include eruption pressure, lake level and mass of superheated vapor. The simulations produced a spectrum of eruption styles from vapor cavities to radial jets that resulted in hazards that ranged from small-scale waves to high amplitude surges that reached and cascaded over the edge of the crater rim. There was an overall tendency for lake surface activity to increase (including wave amplitude) with increasing mass of superheated vapor and eruption pressure. Surface waves were induced by the formation and collapse of a gas cavity. The collapse of the cavity is considered to play a major role in the characteristic features observed during a subaqueous eruption. The additional mass of superheated vapor produced a larger cavity that displaced a larger area of the lake surface resulting in fast moving surges upon the collapse of the cavity. High lake levels (>90 m) appear to suppress the development of explosive jetting activity when eruption pressures are <10 MPa. At very large eruption pressures (>10 MPa), vertical jets and radial ejections of steam and water can occur in water depths >90 m. Less explosive eruption styles can produce hazardous events such as lahars by the outward movement of surface waves over the crater rim.     

Statistical analysis of intermittent volcanic tremor associated with the September 1989 summit explosive eruptions at Mount Etna, Sicily

The pattern of volcanic tremor accompanying the 1989 September eruption at the south-east summit crater of Mount Etna is studied. In specific, sixteen episodes of lava fountaining, which occurred in the first phase of the eruption, are analysed. Their periodic behaviour, also evidenced by autocorrelation, allows us to define the related tremor amplitude increases as intermittent volcanic tremor episodes. Focusing on the regular intermittent behaviour found for both lava fountains and intermittent volcanic tremors, we tried an a posteriori forecast using simple statistical methods based on linear regression and the Student’ t-test. We performed the retrospective statistical forecast, and found that several eruptions would have been successfully forecast. In order to focus on the source mechanism of tremor linked to lava fountains, we investigated the relationship between volcanic and seismic parameters. A mechanism based on a shallow magma batch ‘regularly’ refilled from depth is suggested.     

Basanite glaciovolcanism at Llangorse mountain,northern British Columbia,Canada

The Llangorse volcanic field is located in northwest British Columbia, Canada, and comprises erosional remnants of Miocene to Holocene volcanic edifices, lava flows or dykes. The focus of this study is a single overthickened, 100-m-thick-valley-filling lava flow that is Middle-Pleistocene in age and located immediately south of Llangorse Mountain. The lava flow is basanitic in composition and contains mantle-derived peridotite xenoliths. The lava directly overlies a sequence of poorly sorted, crudely bedded volcaniclastic debris-flow sediments. The debris flow deposits contain a diverse suite of clast types, including angular clasts of basanite lava, blocks of peridotite coated by basanite, and rounded boulders of granodiorite. Many of the basanite clasts have been palagonitized. The presence and abundance of clasts of vesicular to scoriaceous, palagonitized basanite and peridotite suggest that the debris flows are syngenetic to the overlying lava flow and sampled the same volcanic vent during the early stages of eruption. They may represent lahars or outburst floods related to melting of a snow pack or ice cap during the eruption. The debris flows were water-saturated when deposited. The rapid subsequent emplacement of a thick basanite flow over the sediments heated pore fluids to at least 80–100°C causing in-situ palagonitization of glassy basanite clasts within the sediments. The over-thickened nature of the Llangorse Mountain lavas suggests ponding of the lava against a down-stream barrier. The distribution of similar-aged glaciovolcanic features in the cordillera suggests the possibility that the barrier was a lower-elevation, valley-wide ice-sheet.     

The November 2002 eruption at Piton de la Fournaise volcano,La Réunion Island: ground deformation,seismicity, and pit crater collapse

An eruption on the eastern flank of Piton de la Fournaise volcano started on 16 November, 2002 after 10 months of quiescence. After a relatively constant level of activity during the first 13 days of the eruption, lava discharge, volcanic tremor and seismicity increased from 29 November to 3 December. Lava effusion suddenly ceased on 3 December while shallow earthquakes beneath the Dolomieu summit crater were still recorded at a rate of about one per minute. This unusual activity continued and increased in intensity over the next three weeks, ending with the formation of a pit crater within Dolomieu. Based on ground deformation, measured by rapid-static and continuous GPS and an extensometer, seismic data, and lava effusion patterns, the eruptive period is divided into five stages: 1) slow summit inflation and sporadic seismicity; 2) rapid summit inflation and a short seismic crisis; 3) rapid flank inflation, onset of summit deflation, sporadic seismicity, accompanied by stable effusion; 4) flank inflation, coupled with summit deflation, intense seismicity, and increased lava effusion; and finally 5) little deflation, intense shallow seismicity, and the end of lava effusion. We propose a model in which the pre-intrusive inflation of Stage 1 in the months preceding the eruption was caused by a magma body located near sea level. The magma reservoir was the source of an intrusion rising under the summit during Stage 2. In Stage 3, the magma ponded at a shallow level in the edifice while the lateral injection of a radial dike reached the surface on the eastern flank of the basaltic volcano, causing lava effusion. Pressure decrease in the magmatic plumbing system followed, resulting in upward migration of a collapse front, forming a subterranean column of debris by faulting and stoping. This caused intense shallow seismicity, increase in discharge of lava and volcanic tremor at the lateral vent in Stage 4 and, eventually the formation of a pit crater in Stage 5.     

The Hekla eruption 1980–1981

The sixteenth eruption of Hekla since 1104 began on August 17th, 1980, after the shortest repose period on record, only ten years. The eruption started with a plinian phase and simultaneously lava issued at high rate from a fissure that runs along the Hekla volcanic ridge. The production rate declined rapidly after the first day and the eruption stopped on August 20th. A total of 120 million m³ of lava and about 60 million m³ of airborne tephra were produced during this phase of the activity. In the following seven months steam emissions were observed on the volcano. Activity was renewed on April 9th 1981, and during the following week additional 30 million m³ of lava flowed from a summit crater and crater rows on the north slope. The lavas and tephra are of uniform intermediate chemical composition similar to that of earlier Hekla lavas. Although the repose time was short the eruptions fit well into the behaviour pattern of earlier eruptions. Distance changes in a geodimeter network established after the eruptions are interpreted as due to inflation of magma reservoirs at 7–8 kilometers depth.     

Estimating thermal inflow to El Chichón crater lake using the energy-budget,chemical and isotope balance approaches

El Chichón crater lake appeared immediately after the 1982 catastrophic eruption in a newly formed, 1-km wide, explosive crater. During the first 2 years after the eruption the lake transformed from hot and ultra-acidic caused by dissolution of magmatic gases, to a warm and less acidic lake due to a rapid “magmatic-to-hydrothermal transition” — input of hydrothermal fluids and oxidation of H₂S to sulfate. Chemical composition of the lake water and other thermal fluids discharging in the crater, stable isotope composition (δD and δ¹⁸O) of lake water, gas condensates and thermal waters collected in 1995–2006 were used for the mass-balance calculations (Cl, SO₄ and isotopic composition) of the thermal flux from the crater floor. The calculated fluxes of thermal fluid by different mass-balance approaches become of the same order of magnitude as those derived from the energy-budget model if values of 1.9 and 2 mmol/mol are taken for the catchment coefficient and the average H₂S concentration in the hydrothermal vapors, respectively. The total heat power from the crater is estimated to be between 35 and 60 MW and the CO₂ flux is not higher than 150 t/day or ~ 200 gm^− 2 day^− 1.     

Geophysics and geology of an explosion crater in the Ethiopian rift valley

Geophysical and geological studies of an Ethiopian maar, Haro Maja, demonstrate that its eruptive history is more complex than surface geology alone suggests. The crater is 750 m by 1000 m in diameter and varies in depth from 70 m to 110 m. A strong magnetic anomaly is caused by a central basaltic mound, but a broader crater-wide anomaly is best modelled by a 50 m thick frozen lava lake, 30 m below the crater floor. The central mound was not erupted directly onto the lava lake, but was extruded onto top of the sedimentary infill after a quiescent depositional interval. Electrical resistivity measurements further indicate that other basaltic intrusions failed to reach the surface during that eruptive period.     

Hydrochemical dynamics of the “lake–spring” system in the crater of El Chichón volcano (Chiapas,Mexico)

El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO₄ = 0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake, meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009 ± 1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ¹⁸O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.     

The 1963–65 eruption of Lopevi Volcano (New Hebrides)

The eruption commenced on July 7th 1963 with activity at the summit crater which had been dormant for at least 50 years. Production of lava spatte r characterised the opening stages of the eruption, and although hot lava blocks avalanched down the north-eastern slope no flows were produced. In August a crater opened at a height of approximately 1,000 metres at the head of a north-west trending fissure, the site of the 1960 eruption. Intermittent lava fountaining up to a height of 600 feet took place at the crater which was active throughout the remainder of the eruption, and viscous steep-sided tongues of «aa» lava flowed from it. A new east-west trending fissure 200 feet deep and 400 feet wide opened in September at a height of approximately 240 metres and extended up the slope to a point approximately 660 metres above sea level. From this fissure lavas of more fluid character though identical in mineral composition to tongues issuing from the flank crater flowed into the sea until mid November when activity at the fissure ceased. Whilst the fissure was active gas issued from a vent located immediately beyond it’s uper end. The slopes above the anchorage at Tematu were the site of subsidiary activity. Four small fissures opened at heights of up to 180 metres above sea level from mid-October to February 1964 producing short tongues of «aa» lava which flowed into the water. Emission of small ash clouds at sporadic intervals was noted at a crater situated in the highest fissure during a visit in December, 1963. There was a change from activity of «Strombolian type» with associated production of lava flows at the flank crater from November 1963 when the proportion of ash emitted increased. Ash emission became the predominant type of activity throughout the remainder of the eruption. Although the interval between successive outbursts lengthened progressively during 1964 the activity reached a climax on April 8th when the ash column attained a height of 30,000 feet, the maximum recorded during the course of the eruption. There was also an increase in July culminating in the production of a dense ash cloud 15 miles in diameter on the 26th. The activity entered a new phase in July 1964 when fissures producing lava tongues opened not only on the northern slopes but on the east side of the volcano as well. Activity continued on the opposite side to the north-west quadrant in which it had previously been localised when a fissure with a small crater at it’s head appeared in September on the south-east slopes a few hundred metres above sea level. The infrequency of outbursts during 1965 suggests that the present cycle of activity is waning, and that the volcano will soon become quiescent once more. Structures of interest in the lava flows include channels and tunnels. Hypersthene andesite was produced simultaneously with tholeiitic olivine bearing basalt during the opening stages of the eruption although the lavas produced later were all of the latter type. It is suggested that the hypersthene andesite was formed by magmatic differentiation of an olivine-bearing basalt parent magma, the lighter more acid fraction being tapped first at the beginning of the eruption. Such differentiation could account for similar basalt-andesite associations in older volcanic sequences within the central area.     

Monitoring of volcanic eruptions at Yugama crater lake by aqueous sulfur oxyanions

Variations of polythionates (sulfane disulfonates) and sulfate in the Yugama crater lake, Japan, have been monitored for more than 25 years. Just before the 1982 eruption at the crater lake, polythionate ions decreased to zero from the normal level of about 2000 ppm and sulfate ions increased from 2500 to 5000 ppm. During the 1982 eruption polythionate and sulfate ions varied inversely in concentration and the variations exactly coincided with the frequency of volcanic earthquakes and subsequent explosions. These observations are interpreted in terms of aqueous reactions of fumarolic SO₂-H₂S gases, resulting in precipitation of alunite. The behavior of polythionate and sulfate ions strongly suggests that they are useful indicator for prediction of impending volcanic hazards from active crater lakes.     

Structure and evolution of the Rockeskyllerkopf Volcanic Complex, West Eifel Volcanic Field, Germany

The Rockeskyllerkopf Volcanic Complex (RVC) comprises three overlapping monogenetic volcanic centers: Southeast Lammersdorf (SEL), Mäuseberg (M) and Rockeskyllerkopf (RKK). Each volcanic center comprises proximal wall deposits with a well defined crater wall unconformity and crater fill deposits that partially to completely cover the outer crater wall. The SEL Center is a phreatomagmatic tuff ring composed of lithic rich tephra deposited by pyroclastic falls and surges. The second center, Mäuseberg, with its crater to the northwest of the SEL Center is predominantly magmatic. Topographic and outcrop patterns suggest that this center may have formed a series of overlapping scoria cones along a N–S trending fissure. The youngest center, RKK, which lies on a poorly developed palaeosol within the earlier Mäuseberg deposits, comprises a well developed proximal crater wall sequence. This sequence of magmatic, likely Strombolian, fall and grain avalanche deposits passes upward into a crater fill sequence that comprises variably welded bombs. The final eruptions in the center were massive lava flows that were ponded within the RKK crater. Ar–Ar age dating of reequilibrated fragments of phlogopite megacrysts in the SEL lavas indicates volcanic activity began at 474?±?39 ka. Literature K–Ar dates for the youngest lava flows in the RKK Center give ages of 360?±?60 to 470 ka. Our interpretation of the age data and the presence of the poorly developed palaeosol between the Mäuseberg and RKK centers indicates that volcanism in the RVC began around 470 ka with the eruption of the SEL and Mäuseberg centers followed a few thousand years later by the eruption of the RKK Center.     

THE VOLCANIC ACTIVITIES AND HAZARD PREDICTION OF WUDALIANCHI VOLCANIC BELT

More than 40 late Cenozoic monogenetic volcanoes formed a volcanic belt striking NNW from Keluo, through Wudalianchi to Erkeshan in NE China. These volcanoes belong to a unified volcano system, namely Wudalianchi volcanic belt(WVB for short). Based on the volcanic evolution history and the nature of monogenetic volcanic system, we estimate that the volcanic system of WVB is still active and has the potential to erupt again. Hence, this paper studied the temporal-spatial distribution and volcanic eruption types to evaluate the possible eruption hazard types and areas of influence in the future. Volcanic field characteristics and K-Ar radiometric data suggest two episodes of volcanism in the WVB, the Pliocene to early Pleistocene volcanism(4.59~1.00MaBP)and the middle Pleistocene to Holocene volcanism(0.79Ma to now). The early episode volcanoes are distributed only in the north of WVB(mainly in Keluo volcanic field), featured by effusive eruption, and mainly formed monogenetic shield, whose base diameter is large and slope is gentle. However, the late episode eruptions occurred over the entire WVB. The explosive eruption in this stage formed numerous relatively intact scoria cones of explosive origin. Meanwhile the effusive eruption formed widely distributed lava flows. Both effusive eruption and explosive eruption are common in WVB. The effusive eruption formed monogenetic shields and lava flows. The resulting pahoehoe lava, aa lava and block lava appeared in WVB. There are three end-member types of explosive eruption driven by magmatic volatile. Violent Strombolian eruption has the highest degree of fragmentation and mass flux, characterized by eruption column. Strombolian eruption has the high degree of fragmentation, but low mass flux, featured by pulse eruption. Hawaiian eruption has low degree of fragmentation, but high in mass flux, generating large scoria cones. In addition, this paper for the first time found phreatomagmatic eruption in WVB, which formed tuff cone. Transitional eruptions are also common in WVB, which have certain characteristics among the end-member eruption types. Besides, certain volcanoes displayed multiple explosive eruption types during the whole eruption span. According to the volcanic temporal-spatial distribution and eruption characteristics in WVB, the potential volcanic hazards in future are constrained. It appears that the violent Strombolian and Strombolian eruption will not have significant impact on aviation safety in the vertical direction. In the radial direction, the ejected volcanic bomb can reach as far as 1km from the vents and the fallout tephra may disperse downwind over a distance ranging from 1~10km. The major hazard of Hawaiian eruption and effusive eruption comes from lava flow, and its migration distance may reach 3.0~13.5km for pahoehoe lava and 2.9~14.9km for aa lava. The base surge in phreatomagmatic eruption can reach a velocity of 200~400m/s, and the migration distance is around 10km. This is a big threat that people should pay more attention to and take precautions in advance. Besides, it is necessary to strengthen the real-time observation of the volcanoes in the WVB, especially those formed in the late episode as well as near the active fault.