2014年夏季长江口有色溶解有机物(CDOM)的分布、光学特性及其来源探究

通过测定有色溶解有机物(CDOM)的吸收光谱、荧光光谱、溶解有机碳(DOC)浓度,探究了2014年夏季长江口CDOM的来源及河口混合行为。结合吸收系数a(355)、光谱斜率S275-295、比紫外吸光度SUVA254与盐度的关系,结果表明南港水道受黄浦江输入影响显著,北港水道由长江径流控制呈保守性混合行为,二者CDOM的物质结构性质较为相似。DOC的浓度可通过a(275)与a(295)模拟估算:ln[DOC]=4.94–0.87ln[a(275)]+0.90ln[a(295)],a(275)8.0 m–1;ln[DOC]=4.77–6.79ln[a(275)]+8.05ln[a(295)],a(275)≥8.0 m–1。模拟结果表明,在长江口及邻近海域,CDOM对DOC具有示踪意义。利用三维荧光光谱-平行因子分析(EEMs-PARAFAC)技术,可得到夏季长江口FDOM含有3个类腐殖质组分(C2,C4和C5)和3个类蛋白质组分(C1,C3和C6)。类腐殖质组分具有相似的来源及地球化学行为,且与a(355)及盐度存在显著相关性;类蛋白质组分则与a(355)及盐度之间无显著相关性,揭示其与区域内微生物的活动有关。     

长江口枯季水沙特性分析——以2003年为例

基于2003年2月长江口大面积水沙同步观测资料的分析结果,长江口枯季水沙特性:a)垂线平均流速特性:时间上大潮＞小潮,落潮＞涨潮;纵向上由徐六泾向口门呈"先减小后增大再减少"的变化;断面上北支＞南支,南港＞北港,南槽最小.大潮徐六泾垂线平均流速为102cm/s,浑浊带水域北港最大,为128cm/s;口门水域南槽口外最大,为100cm/s.小潮徐六泾为78cm/s;浑浊带水域北槽最大,为83cm/s;口门水域北港口外最小,为36cm/s.b)垂线平均含沙量特性:时间上大潮＞小潮,涨潮＞落潮;纵向上由徐六泾向口门呈"先增大后减小"的变化;断面上北支＞南支,大潮北港＞南港,小潮南港＞北港,北槽较高,北港大潮较高,小潮最低.大潮徐六泾垂线平均含沙量为0.09kg/m3;浑浊带水域北港最高,为1.14kg/m3;口门水域南槽最高,为0.81kg/m3.小潮时徐六泾为0.06kg/m3,浑浊带水域北槽最高,为0.99kg/m3,口门水域北港最低,为0.09kg/m3.c)无论大小潮,水沙净通量均为北槽＞北港＞南槽.d)0.4H流速和含沙量能近似表示其对应的垂线平均值.南北槽大、小潮的水动力和含沙量分布均匀,变化较小,北港变化较大.e)流速和含沙量梯度表明,紊动强度大潮＞小潮,落潮＞涨潮,水体垂向混合的强度大潮＞小潮,涨、落潮的水体垂向混合的强度差别较小.     

上海市第二水源（长江口引水）取水点地址探讨

随着工农业生产的发展和人民生活水平的进一步提高,上海市生产和生活用水的需求量将大幅度的增长,原有的取供水设施将不能满足发展的需要。由于水质的污染,在上海境内内河已难选取新的取水点,除向黄浦江上游继续扩大引水外,急需开发新的水源。长江水量充沛,水质净化能力强,开发利用长江口的水资源,以供作上海市的工农业生产及人民生活的用水有其重要的意义。长江口水域浩大,总水面积达4000km~2,它包括北支、南支、南港、北港、南槽、北槽以及口外水域。根据实测资料分析及调查研究的结果,目前长江口的北支、南北港、南北槽三个水域,     

北极孔斯峡湾表层沉积物中溶解有机质的来源与转化历史

在北极地区孔斯峡湾采集28个表层沉积物样品,测定了其中水溶性有机质(也称溶解有机质,DOM)的分子量分布、紫外/可见吸收光谱和三维荧光光谱特征,并利用平行因子分析(PARAFAC)模型对DOM的荧光组分和来源进行了解析。结果表明:孔斯峡湾表层沉积物中有色溶解有机质(CDOM)及其中的荧光溶解有机质(FDOM)含量均从内湾向外湾方向呈逐渐累积的趋势,但CDOM中的FDOM所占比例逐渐减小,与DOM趋于老龄化密切相关。沉积作用减弱以及长期的光化学降解和微生物降解作用对此起主要贡献,并导致腐殖质和小分子组分在沉积物DOM中所占的比例呈逐渐递增的趋势。沉积物DOM包含陆源类腐殖质、自生源类腐殖质和类蛋白等三个荧光组分,但是其组成比例空间差异很大。吸收光谱斜率比(S_R)随自生源所占百分比增加而减小,随DOM腐殖质组分中陆源与自生源的比值增加而增加;腐殖化指数(HIX)随类腐殖质与类蛋白质比值和水深的增加而增加,生物源指数(BIX)随自生源比例增加而增加。峡湾沉积物DOM的组成和来源存在着高度的空间差异,在冰川湾区由水体颗粒有机质(POM)的近期转化和迁移而来,而在峡湾中央及口门附近以较老的腐殖质为优势,主要源于水体DOM长期迁移和转化。研究表明,FDOM/CDOM,S_R,HIX和BIX等构成的CDOM光谱指纹信息可以作为揭露沉积物溶解有机质来源及迁移转化历史的工具,对探索海洋与冰川相互作用影响下的峡湾环境演变有着重要意义。     

长江河口水沙分流和输移的探讨

据2002年9月长江口同步实测水文资料,运用标准水文法,对南、北支和南、北港的落潮分水分沙比和净泄分水分沙比进行了计算。结果表明,两者存在差异,后者更能反映分水分沙在长江河口演变中的作用,“涨潮汇沙比”更能揭示北支泥沙的倒灌。水沙平衡分析结果表明,观测期间北支仍趋于淤积,南支有冲刷迹象。经多站水沙综合分析,揭示了长江口水沙运动具有径流“主体南泄”、汊道“副淤主刷”和水沙“输移分异”等特征,并指出水沙“输移分异”是北港泥沙输运大于南港的原因之一。     

长江口滞流点洪、枯季移动的数值分析

为研究长江口滞流点位置的季节变化,利用Delft3D-Flow模块建立长江口二维潮流数学模型,通过实测水文资料对模型进行验证。在此基础上,模拟长江口各汊道洪、枯季滞流点移动情况,并从各汊道沿程断面的落潮量、涨潮量和落、涨潮量之比3个方面进行了水动力分析。结果显示:洪季,北支滞流点在八滧港东北方向约1.9 km处;在南支各汊道中,北港滞流点位于鸡骨礁东北方向约10.0 km处,北槽滞流点位于牛皮礁东南方向约3.8 km处,南槽滞流点位于大辑山东北方向约14.1 km处。枯季,除北槽外,其余各汊道均出现两个滞流点,且北支的两个滞流点相距最远,分别在灵甸港西南方向约3.2 km处和六滧港东北方向约3.1 km处;北港滞流点分别在鸡骨礁西北方向约25.8 km和20.2 km处,北槽滞流点在横沙以西约5.3 km处,南槽滞流点分别在中浚西北方向约6.5 km和东北方向约5.5 km处。北支洪、枯季滞流点的移动距离为4.6~53.3 km,北港、南槽洪、枯季滞流点的移动距离分别为22.0~27.7km和34.6~39.2 km,而北槽洪、枯季滞流点的移动距离最大,为57.1km。长江口各汊道滞流点的移动反映了河流径流和海洋潮流的综合作用。     

长江口盐度的时空变化特征及其指示意义

2003年2,7月在长江口进行了枯、洪季大规模综合水文测验,布控范围西自江阴东至口外-20m,测验站点覆盖4条入海汊道.测验资料统计分析表明:(1)径流大小、汊道分流比、潮汐强弱和地形条件是控制盐度时空变化的主要要素;(2)在盐度空间分布上从大至小的顺序是:北支,南槽,北槽,北港口;(3)北支枯季发生盐水倒灌南支,而洪季可有一半以上区段为淡水所控;在其他3个入海汊道中,北港口门段是长江口盐淡水混合相对最弱的区段,盐度潮周期变幅最大,但洪枯变幅最小;南槽的盐淡水混合较强,盐度潮周期变幅较小,但洪枯变幅很大;北槽介于两者之间.(4)盐度时空变化反映洪季北支、南港和南槽分流比都有所增加.     

径流量变化对长江口水动力特性的影响

为了研究径流量变化对长江口水动力特性的影响,利用MIKE21建立长江口水动力数学模型,分别模拟计算长江口不同径流量影响的潮流场,统计分析不同径流量时各汊道涨落潮量和净泄量以及分配比例;统计分析不同径流量对各汊道潮位变化的影响;统计分析不同径流量对北槽中下段水动力特性的影响。得到如下结论:1)径流量的变化对于涨潮分流的影响显著,随着径流量的增加,更多的潮流从北支、北港、南槽进入长江口内。当上游的径流动力增强,外海潮流受上游径流的阻挡,难以继续上溯。2)越是靠近上游,径流量的变化对平均潮位的影响程度越高,入海口处受径流的影响微弱;上游径流量越大,潮波向内陆传播越受阻,能量消耗越大,致使其动力减弱。3)径流量的变化对平均流速的影响与上述潮位变化类似,上游径流量越大,各汊道流速越大;越靠近海洋,径流影响越小。4)长江口北槽中下段转流时刻会出现平面对流现象。横向方向上普遍存在越堤水流,且南北导堤均为北向越堤流占优势。     

长江口南北支二维氯度数学模型

枯水大潮期间，长江口北支向南支倒灌盐水，使南支河段和黄浦江水质恶化。，多年来这一问题为各界所重视。本文采用二维数学模型模拟了南北支水流和氯度的变化。数学模型经验证以后，计算了封堵北支方案，分析了工程前后含氯度变化情况。封堵北支后，切断了北支向南支倒灌盐水的来源，南支河段含氯度大幅度下降，数模计算反映了北支倒灌盐水在南支河段中的重要作用     

长江口北支盐水倒灌的数值模型研究

20世纪80年代以来,国内对长江口盐水入侵进行了大量系统专门的研究,对长江口的盐水入侵规律有了一个比较基本的认识.但是,长江口特别是在南支及南北港的盐度变化规律极其复杂,主要有盐度的周日变化峰值与潮流变化关系不尽协调,落潮时盐度反而最大;盐度的纵向分布上游比下游高;盐度的半月变化峰值一般发生在小潮和寻常潮期间,而且各测点盐度峰值的发生时间不尽一致[1,2]等等.其中北支盐水向南支倒灌是引起长江口盐度变化异常复杂的主要原因[1-5].北支倒灌在长江口盐度变化中扮演了重要的角色,掌握北支倒灌是认识长江口盐水入侵规律特别是南支和南北港盐度变化规律的重要内容,同时也是长江口淡水咨源利用的一个重要方面.     

南大洋环流动力学研究动态

本文基于南大洋环流研究最新资料，从资料来源、动力模式以及有待解决的问题几个方面较详细地阐述南大洋环流动力学研究动态。     

长江口外赤潮多发区近几十年来的古生产力记录及环境意义

选取长江口外赤潮多发区沉积物柱状样,在高分辨率测年基础上,通过有机碳、有机碳同位素(δ13C)、生物硅、绿素等多项指标的分析获得了调查海区古生产力的变化信息。并结合近几十年来营养盐浓度及组成结构的变化探讨了海洋浮游藻类组成结构的变化在海洋古环境中的记录。柱状样年代可追溯到20世纪40年代初。δ13C值在柱中的分布为-26.15×10-3~-19.5×10-3,表明有机碳为陆源与海生的混合。生物标志物在柱状样中的分布可大致分为三个阶段,50年代以前含量均较低;50年代至80年代含量均增加,表明海洋浮游藻类活动强烈且以硅藻为主,与此阶段长江口营养盐浓度迅速增加相对应;80年代以后,生物硅的含量下降至整个柱中最低水平,绿素有所降低,但高于50年代前的水平,而有机碳含量增加,表明在该时段硅藻生物量降低,其他藻类生物量有所增加,这与长江口营养盐氮盐持续增加而硅酸盐逐年降低、氮与磷的含量比值、磷与硅的含量比值迅速增大有关。沉积记录还表明此阶段陆源有机碳的贡献增强。     

Trends in the variation of the sea level in the lagoons of the Southeastern Baltic

This paper analyses the global tendency of the sea level rise (SLR) and its long term influence on the sea level upstream drainage cascade based on the example of the level’s variation in the Vistula Lagoon of the Baltic Sea compared to the other lagoons and coastal regions of the southeastern part of the Baltic Sea. A steady positive trend in the water level variations was revealed; its magnitude varies significantly depending on the time period. In general, during the 100–150 year period, the rate of the SLR in the lagoons and coastal areas of the Baltic Sea (1.7–1.8 mm per year) is close to the SLR rate in the World Ocean. In the second half of the 20th century, the increased rate of the SLR in the lagoons and marine areas became stronger (up to 3.6 mm per year in the Vistula Lagoon and in 1959–2006 in the sea and exceeded the rate of global ocean SLR). It dramatically increased at the end of the last century both in the lagoons and in the sea (up to 10.0–15.0 mm per year). This is the response not only to the global climate warming but it is likely that it is also a response to the changes of the climate driving forces that influence the regimes of the local wind and precipitation in the catchment.     

Modeling the water circulation in the North Atlantic in the scope of the CORE-II experiment

A numerical experiment on the reproduction of the variability in the state of North Atlantic water in 1948–2007 with a spatial resolution of 0.25° has been performed using the global ocean model developed at Institute of Numerical Mathematics, Russian Academy of Sciences (INM RAS), and the Shirshov Institute of Oceanology (IO RAS) (the INM–IO model). The data on the state of the atmosphere, radiation fluxes, and bulk formulas of the CORE-II protocol are used as boundary conditions. Five successive 60-year calculation cycles have been performed in order to obtain the quasi-equilibrium state of a model ocean. For the last 20 years, the main elements of large-scale ocean circulation have been analyzed and compared with the WOA09 atlas data and the results of other models.     

近30年来莱州湾滨海湿地景观格局变化特征研究

基于莱州湾滨海湿地特征以及野外实地观测数据,利用landsat遥感影像手段,揭示1990—2018年莱州湾滨海湿地景观格局变化特征,并结合景观指数分析莱州湾滨海湿地异质性.结果表明,1990—2018年间,莱州湾滨海湿地呈现人工滨海湿地面积增加而天然滨海湿地面积减少的趋势.截至2018年莱州湾滨海湿地面积总计1954 ...     

Distribution of Pacific-origin water in the region of the Chukchi Plateau in the Arctic Ocean in the summer of 2003

1Introduction Besidestheprecipitationandriverdischarges,the watersinthePacificOceanandtheAtlanticOceanare thesourcesoftheArcticOceanwater.TheAtlantic waterenterstheArcticOceanviatheFramStraitand theBarentsSea.Foritsdenserfeatureduetohigh salinity,mostofitsinkstothenorthofSvaldbardand circulatesinallthedeepbasinsintheArcticOcean, formingthedeepandbottomwatersoftheArcticO- cean(Aagaardetal.,1985;Rudelsetal.,1999).The BeringStraitistheonlychannelforthePacificwater toflowintotheArcticOce…     

The Moho transition zone in the Oman ophiolite-relation with wehrlites in the crust and dunites in the mantle

Field data in the Oman ophiolite show that the Moho transition zone (MTZ), which is on average 300 m thick above mantle diapirs, reduces to 50 m away from diapirs, with a sharp transition at the outskirts of the diapirs. We show here that this reduction is dominantly due to compaction of a dunitic mush present above diapirs in the MTZ, with upward injection of a wehrlitic magma in the crust, and, to a lesser extent, due to tectonic stretching. In order to explain the fraction of wehrlites injected into the crust, which is in the range of 25%, it is necessary that mantle upwelling is active, with a mantle flow velocity away from diapirs several times faster than the spreading velocity. If this velocity exceeds 5 times the ridge spreading-rate, a significant part of the MTZ may be entrained down into the mantle, flowing away from the diapir as tabular dunites.     

近15 a来三门湾海域氮、磷营养盐分布与富营养化状况的变化分析

以1997年8月中旬和2011年10月中旬对三门湾附近海域开展的海域水质现状调查为依据,分析了近15 a间该海域水体环境氮、磷营养盐的分布现状及变化特征。结果表明:近15 a来,三门湾海域的无机氮和活性磷酸盐含量均成倍增长,水体营养程度由轻度富营养化逐步上升为重度富营养化;从营养结构来看,活性磷酸盐仍为限制性富营养化因子;大量的海水养殖是导致该海域营养盐大幅提高的直接原因。因此,为控制三门湾的富营养化现象进一步加剧,建议适度控制海水养殖规模,调整海水养殖结构,加强对三门湾沿岸排污控制,以获得养殖经济效益和生态环境效益的协调、可持续发展。     

Variability in the speciation of iron in the northern North Sea

Variations in the speciation of iron in the northern North Sea were investigated in an area covering at least two different water masses and an algal bloom, using a combination of techniques. Catalytic cathodic stripping voltammetry was used to measure the concentrations of reactive iron (Fe_R) and total iron (Fe_T) in unfiltered samples, while dissolved iron (Fe_D) was measured by GFAAS after extraction of filtered sea water. Fe_R was defined by the amount of iron that complexed with 20 μM 1-nitroso-2-napthol (NN) at pH 6.9. Fe_T was determined after UV-digestion at pH 2.4. Concentrations of natural organic iron complexing ligands and values for conditional stability constants, were determined in unfiltered samples by titration. Mean concentrations of 1.3 nM for Fe_R, 10.0 nM for Fe_T and 1.7 nM for Fe_D were obtained for the area sampled. Fe_R concentrations increased towards the south of the area investigated, as a result of the increased influence of continental run off. Fe_R concentrations were found to be enhanced below the nutricline (below 40 m) as a result of the remineralisation of organic material. Enhanced levels of Fe_T were observed in some surface samples and in samples collected below 30 m at stations in the south of the area studied, thought to be a result of high concentrations of biogenic particulate material and the resuspended sediments respectively. Fe_D concentrations varied between values similar to those of Fe_T in samples from the north of the area to values similar to those of Fe_R in the south. The bloom was thought to have influenced the distribution of both Fe_R and Fe_T, but less evidence was observed for any influence on Fe_R and Fe_D. The concentration of organic complexing ligands, which could possibly include a contribution from adsorption sites on particulate material, increased slightly in the bloom area and in North Sea waters. Iron was found to be fully (99.9%) complexed by the organic complexing ligands at a pH of 6.9 and largely complexed (82–96%) at pH 8. The ligands were almost saturated with iron suggesting that the ligand concentration could limit the concentration of iron occurring as dissolved species.