巢湖蓝藻水华时空分布(2000-2015年)

巢湖是我国五大淡水湖之一,近年来水体富营养化严重,蓝藻水华频繁暴发.通过收集2000-2015年晴好天气下2478景MODIS Terra和Aqua影像,利用浮游藻类指数,提取巢湖蓝藻水华时空分布数据.结果显示,巢湖蓝藻水华覆盖面积、暴发频率以及持续时间都在增加,每年最初暴发时间提前.从分布上来看,西巢湖依然严重,中巢湖、东巢湖水华暴发面积较以往大大增加;过去16年内巢湖蓝藻水华暴发频率持续增长,其中2007年最为严重,2008-2010年暴发频率出现缓和,此后又出现增长趋势.这些研究结果有助于掌握蓝藻水华的情况,为巢湖科学治理提供了数据支持.     

Eutrophication Dynamics of Tolo Harbour, Hong Kong

The time and spatial variation of water quality in Tolo Harbour, a eutrophic landlocked semi-enclosed bay frequented by algal blooms, is studied using a dynamic eutrophication model. Hourly changes of tide levels and currents are computed by a link-node model assuming M₂ tidal forcing. Phytoplankton growth is assumed to be limited by solar radiation, nitrogen and temperature. The model incorporates light acclimation by algae, self-shading, photosynthetic production, nutrient uptake, and a dynamic determination of the carbon to chlorophyll ratio. In particular, sediment-water-pollutant interactions are modelled via an anaerobic benthic layer segment. Using recorded pollution loads and environmental forcing as input, the model predictions of daily-averaged water quality are compared with the extensive water quality monitoring data of the Environmental Protection Department (EPD). The predicted spatial distribution and trends of algal biomass, inorganic nitrogen, dissolved oxygen (DO), as well as sediment oxygen demand (SOD), are in general agreement with field observations.     

基于多源遥感数据的巢湖水华长时序时空变化(20092018年)分析与发生概率预测

湖泊富营养化导致的水华问题严重影响了淡水资源的利用和保护,快速、全面、准确的监测水华信息对于湖泊水环境的治理具有十分重要的意义.本文以巢湖为研究区域,利用多源光学遥感影像和时空融合技术,采用波段融合的方式将NDVI指数波段加入到遥感影像当中,并通过监督分类解译水华信息,以此揭示20092018年10年间巢湖水华的时空变...     

A comparison of the toluene distillation and vacuum/heat methods for extracting soil water for stable isotopic analysis

Hanford Loam, from Richland, Washington, was used as a test soil to determine the precision, accuracy and nature of two methods to extract soil water for stable isotopic analysis: azeotropic distillation using toluene, and simple heating under vacuum. The soil was oven dried, rehydrated with water of known stable isotopic compositions, and the introduced water was then extracted.

Compared with the introduced water, initial aliquots of evolved water taken during a toluene extraction were as much as 30 ‰ more depleted in D and 2.7 ‰ more depleted in ¹⁸O, whereas final aliquots were as much as 40 ‰ more enriched in D and 14.3 ‰ more enriched in ¹⁸O. Initial aliquots collected during the vacuum/heat extraction were as much as 64 ‰ more depleted in D and 8.4 ‰ more depleted in ¹⁸O than was the introduced water, whereas the final aliquots were as much as 139 ‰ more enriched in D, and 20.8 ‰ more enriched in ¹⁸O. Neither method appears quantitative; however, the difference in stable isotopic composition between the first and last aliquots of water extracted by the toluene method is less than that from the vacuum/heat method. This is attributed to the smaller fractionation factors involved with the higher average temperatures of distillation of the toluene. The average stable isotopic compositions of the extracted water varied from that of the introduced water by up to 1.4 ‰ in δD and 4.2 ‰ in δ¹⁸O with the toluene method, and by 11.0 ‰ in δD and 1.8 ‰ in δ¹⁸O for the vacuum/heat method.

The lack of accuracy of the extraction methods is thought to be due to isotopic fractionation associated with water being weakly bound (not released below 110°C) in the soil. The isotopic effect of this heat-labile water is larger at low water contents (3.6 and 5.2% water by weight) as the water bound in the soil is a commensurately larger fraction of the total. With larger soilwater contents the small volume of water bound with an associated fractionation is not enough to affect the remaining unbound introduced soil water. Pretreatment of the soil to equilibrate the heat-labile water to the test water produced good results for the toluene distillation but not the vacuum/heat extraction method.

Vapors collected over the soils also show stable isotopic variations related to soilwater content. These vapors also appear to be in closer equilibrium with the free water, as extracted by the toluene method, than with the originally introduced water; thus, the soil vapors do not appear to be isotopically affected by the heat-labile water.

The toluene method appears to be better for extracting soil water for stable isotopic analysis because it allows more precise temperature control and excludes the extraction of heat-labile water which is isotopically fractionated. The bound nature of this heat-labile water limits association with the hydrologically active soil water; thus, the exclusion of this water from the soil water attained by toluene distillation may be advantageous. However, the azeotropic nature of toluene distillation affords no benefit and the extraction procedure must continue to completion.     

巢湖蓝藻水华监测预警与模拟分析平台设计与实践

近20年来,巢湖蓝藻水华频繁暴发,对流域内居民生活和社会生产产生了严重影响.由于缺乏蓝藻水华全方位监测、高精度模拟和智能化分析手段,传统方法难以实现"现状掌握、异常识别、原因追溯、未来模拟"的目标,无法满足巢湖蓝藻水华科学防控与应急处置的要求,蓝藻水华引起的突发事件随时可能发生.本文针对巢湖蓝藻水华的全面监测和应急决策...     

The effects of a spillage of diesel fuel on a rocky shore in the sub-Antarctic region (Macquarie Island)

On 3 December 1987, the supply ship Nella Dan ran aground at Macquarie Island (54°29′S, 158°58′E) releasing about 270 000 I of oil, mostly light marine diesel, into the sea. At the time of the incident, many marine invertebrates were washed up dead along 2 km of shoreline. Twelve months later, the shore community was investigated using 1. algal and invertebrate populations of the littoral and sublittoral rocky shore, and 2. the invertebrate communities living in the holdfasts of the giant kelp Durvillaea antarctica, which were collected for later examination. Investigations were undertaken at both affected and control locations. Analyses of differences in community structure involved nested ANOVA and multidimensional scaling techniques. On the rocky substrate, the effect of the spill was restricted to some biota of the lower littoral and sublittoral zones—particularly echinoderms and the patellid limpet Nacella macquariensis. There were differences in cover for some algal species between locations. Within the kelp holdfasts, communities were dominated by peracarid crustaceans at control locations and by polychaetes (particularly the opportunistic groups—capitellids, cirratulids and spionids) at oil-affected locations.

The communities have recently been re-surveyed (in the summer of 1994–1995) to assist in the interpretation of the results and to gauge the extent of recovery of the affected biota.     

Understanding how physical-biological coupling influences harmful algal blooms,low oxygen and fish kills in the Sea of Oman and the Western Arabian Sea

In the last decade, green Noctiluca scintillans with its symbiont and other dinoflagellates such as Cochlodinium polykrikoides, Prorocentrum micans and Scrippsiella trochoidea have become the dominant HABs, partially replacing the previously dominant diatoms and red Noctiluca scintillans, especially during the northeast monsoon. Fish kills in the Sea of Oman are linked to a slow seasonal decline in oxygen concentration from January to November, probably due to the decomposition of a series of algal blooms and the deep, low oxygen waters periodically impinging the Omani shelf. In the western Arabian Sea, cyclonic eddies upwell low oxygen, nutrient-rich water and the subsequent algal bloom decays and lowers the oxygen further and leads to fish kills. Warming of the surface waters by 1.2 °C over the last 5 decades has increased stratification and resulted in a shoaling of the oxycline. This has increased the probability and frequency of upwelling low oxygen water and subsequent fish kills.     

The environmental impact of marine fish culture: Towards a sustainable future

The environmental impact of marine fish-farming depends very much on species, culture method, stocking density, feed type, hydrography of the site and husbandry practices. In general, some 85% of phosphorus, 80–88% of carbon and 52–95% of nitrogen input into a marine fish culture system as feed may be lost into the environment through feed wastage, fish excretion, faeces production and respiration. Cleaning of fouled cages may also add an organic loading to the water, albeit periodically. Problems caused by high organic and nutrient loadings conflict with other uses of the coastal zone. The use of chemicals (therapeutants, vitamins and antifoulants) and the introduction of pathogens and new genetic strains have also raised environmental concerns.

Despite the high pollution loadings, results from various studies show that some 23% of C, 21% of N and 53% of P of feed input into the culture system is being accumulated in the bottom sediments and the significant impact is normally confined to within 1 km of the farm. The major impact is on the sea bottom, where high sediment oxygen demand, anoxic sediments, production of toxic gases and a decrease in benthic diversity may result. Decreases in dissolved oxygen and increases in nutrient levels in the water are also evident but are normally confined to the vicinity of the farm. Tributyltin (TBT) contamination and the development of antibiotic-resistant bacteria have been reported near fish farms. The stimulating effects of vitamins/fish wastes on growth of red tide species have been demonstrated in a number of laboratory studies. Nevertheless, there is no evidence to support the suggestion that the present use of therapeutants, vitamins and antibiotics and the introduction of pathogens and new genetic strains would pose a significant threat to the environment.

Marine fish culture can be a sustainable development, provided pollution loadings generated by fish farms are kept well below the carrying capacity of the water body. Effects can be significantly reduced by careful site selection, control of stock density, improved feed formulation and integrated culture (with macroalgae, filter-feeders and deposit-feeders). An example of the application of computer modelling in mariculture management is demonstrated. Environmental impact assessment and monitoring should also be carried out to ensure culture activities are environmentally sustainable.     

Environmental management of marine fish culture in Hong Kong

Marine fish farming is an important commercial practice in Hong Kong. Marine fish farms located in eutrophic coastal waters often face the threat of severe dissolved oxygen depletion associated with algal blooms and red tides. On the other hand, mariculture activities also contribute to pollution. The sustainable management of mariculture requires proper siting of the fish farms and stocking density control. Both of these are related to the carrying capacity of the water body concerned, which is mainly governed by its flushing characteristics. A simple method to determine the carrying capacity of a fish farm has been developed by using three-dimensional (3D) hydrodynamic modelling and its effective coupling with a diagenetic water quality model. A systematic methodology using numerical tracer experiments has been developed to compute the tidal flushing in a fish farm. The flushing time is determined from the results of a numerical tracer experiment using robust 3D hydrodynamic and mass transport models. A unit tracer concentration is initially prescribed inside the region of interest and zero elsewhere; the subsequent mass transport and the mass removal process are then tracked. The fish farms are usually situated in well-sheltered shallow embayments and may not connect directly to the open water. It is found that it is necessary to define both "local" and "system-wide" flushing times to represent the effectiveness of the mass exchange with the surrounding water body and the open sea respectively. A diagenetic water quality model simulating the sediment-water-pollutant interaction is employed to address the response of the water column and the benthic layer to pollution discharges. With the flushing rate reliably computed, the carrying capacity of the fish farm can be determined in terms of key water quality parameters: chlorophyll-a, dissolved oxygen, organic nitrogen and potential lowest dissolved oxygen level on a day of negligible photosynthetic production. The predictions are well-supported by field data.     

Preliminary stratigraphic and structural architecture of Bhutan: Implications for the along strike architecture of the Himalayan system

High-precision in-situ ion microprobe (SIMS) oxygen isotope analysis of zircons from two diorite intrusions associated with the late Caledonian Lochnagar pluton in Scotland has revealed large differences in the degree of heterogeneity in zircon δ¹⁸O between the diorites. Zircon crystals from the Cul nan Gad diorite (CnG) show a unimodal distribution of oxygen isotope values (δ¹⁸O = 6.0 ± 0.6‰ (2σ)) and no or only minor grain-scale variation. Those from the Allt Darrarie diorite (AD1) show a large range in δ¹⁸O and an apparent bimodal distribution with modes of 6.6 ± 0.4‰ and 7.3 ± 0.4‰. Variations of up to 1.2‰ occur between and within grains; both an increase and decrease in δ¹⁸O with zircon growth has been observed. The δ¹⁸O composition of growing zircon can only change if open-system processes affect the magma composition, i.e. if material of contrasting δ¹⁸O composition is added to the magma. The variability in AD1 is interpreted to represent a cryptic record of magma mixing. A ‘deep crustal hot zone’ is a likely site for generation of the dioritic magmas which developed by mixing of residual melts and crustal partial melts or by melting of mafic lower crustal rocks. The overall small number of zircons with mantle-like δ¹⁸O values (5.3 ± 0.6‰ (2σ)) in the Lochnagar diorites is largely the product of crustal differentiation rather than crustal growth.

The δ¹⁸O of quartz from the CnG and AD1 diorites shows only minor variation (CnG: 10.9 ± 0.5‰ (2σ), AD1: 11.7 ± 0.6‰ (2σ)) within single populations, with no evidence of mixing. Quartz–zircon isotopic disequilibrium is consistent with later crystallisation of quartz from late magmatic fluids, and in case of the AD1 diorite after the inferred magma mixing from a homogenised, higher δ¹⁸O melt.

High-precision SIMS oxygen isotope analysis of zircon provides a new approach to identifying and resolving previously undetected early-stage magma mixing and constraining the compositions and origins of the component magmas. A combination of zircon, quartz and whole-rock data has proven to be a powerful tool in reconstructing the petrogenetic evolution of diorite from early crystallisation to late alteration.     

基于遥感藻总量和气象因子的巢湖不同湖区藻华预测

湖泊能为人类提供不可或缺的资源,而全球普遍存在的湖泊富营养化导致的藻华频繁暴发正不断损害湖泊生态环境服务功能.为合理保护湖泊环境和防治藻华危害,需预测藻华暴发.以我国富营养巢湖为研究区,本文构建了一种基于遥感藻总量和气象因子的不同湖区藻华暴发概率预测方法.基于MODIS/Aqua数据,研究首先反演了2003—2019年日尺度的藻华分布和考虑垂向结构的水柱藻总量.然后,统计了西、中和东巢湖的藻华面积,判别了藻华/非藻华日,并匹配日平均藻总量和气象因子.最后,筛选出藻华形成的关键影响因子——藻总量、气温和水汽压,并构建了不同湖区日藻华暴发概率的Logistic预测模型.不同湖区月平均藻总量基本一致,但藻华暴发日占比呈“西高东低”特征.对西、中和东巢湖的藻华/非藻华检验样本,模型精度分别为90%、85%和89.5%,模型也适用于2020年夏秋季和冬春季藻华预测.湖泊藻华暴发是藻类大量增殖并在一定气象条件下的产物,故基于遥感藻总量和气象因子的藻华暴发概率预测科学合理,可推广应用于太湖等其他富营养湖泊.     

Water quality in the Dickinson Bayou watershed (Texas, Gulf of Mexico) and health issues

The Dickinson Bayou watershed (near Houston, Texas, Gulf of Mexico) provides habitat for numerous coastally influenced communities of wildlife, including scores of birds and fish. Encroaching development and impervious surfaces are altering the habitat and degrading water quality. Herein we have defined the current health of the bayou using water quality data collected between 2000 and 2006. Elevated bacteria (fecal coliform, Escherichia coli and Enterococcus) and depressed dissolved oxygen concentrations (often <3 mg l⁻¹) are the two major impairments to this ecosystem. While nutrient ratios indicate primary productivity may be nitrogen limited, concerns of eutrophication persist because the bayou has a low intrinsic flushing rate. Consistent with this is the magnitude of algal blooms (ca. 100 μg chl l⁻¹) which often occur in spring/summer. The findings of this study will assist with the understanding of the influence of urban development on small watersheds.     

Vertical exchange due to horizontal density gradients in lakes; the case of Lake Lucerne

Recent field investigations have shown that differential mixing causes a significant density driven exchange between the two eastern basins of Lake Lucerne, Gersauersee and Urnersee. The long term vertical mixing characteristics during the winter mixing period and the influence of the resulting exchange flow on water quality are examined through the analysis of ten years (1964 to 1974) of monthly limnological data. Vertical homogenization of the state variables (temperature, electric conductivity and density) occurred on average once every two years in Urnersee, but not once in Gersauersee where the ten year average winter mixed-layer depth extended to 120 m. In Urnersee intense mixing was evident over the whole water column for every year. In contrast intense mixing in the deeper layers of Gersauersee occurred approximately once every four years. A three layer model shows that theT/ ₂₀ signature of the Gersauersee intermediate water correlates best with the Urnersee deep water confirming the regular occurrence of a density driven exchange. For the lower layers the oxygen consumption rate in Urnersee was approximately twice that for Gersauersee. It appears the exchange flow can act either as a source or sink for the oxygen balance of Urnersee deep water. The larger rate in Urnersee hypolimnion might also be associated with the larger sediment input to this system. Density driven exchange resulting from differential mixing is probably an important contribution to the vertical water replenishment in many lakes.     

Prediction of algal blooms using genetic programming

In this study, an attempt was made to mathematically model and predict algal blooms in Tolo Harbor (Hong Kong) using genetic programming (GP). Chlorophyll plays a vital role in blooms and was used in this model as a measure of algal bloom biomass, and eight other variables were used as input for its prediction. It has been observed that GP evolves multiple models with almost the same values of errors-of-measure. Previous studies on GP modeling have primarily focused on comparing GP results with actual values. In contrast, in this study, the main aim was to propose a systematic procedure for identifying the most appropriate GP model from a list of feasible models (with similar error-of-measure) using a physical understanding of the process aided by data interpretation. Evaluation of the GP-evolved equations shows that they correctly identify the ecologically significant variables. Analysis of the final GP-evolved mathematical model indicates that, of the eight variables assumed to affect algal blooms, the most significant effects are due to chlorophyll, total inorganic nitrogen and dissolved oxygen for a 1-week prediction. For longer lead predictions (biweekly), secchi-disc depth and temperature appear to be significant variables, in addition to chlorophyll.     

Spatiotemporal variability of algae in monitoring aquatic environment in the Panjiakou Reservoir (Northern China)

The spatial and temporal variations of algae within a large drinking water reservoir with mesotrophy (Panjiakou Reservoir, Northern China) were investigated in relation to variations in environmental factors over a 6-month period (May to October) in 2013 and 2014. The analysis based on in-situ samples upstream to downstream (Puhekou, Jiajia’an, Yanziyu Panjiakou and Baqian) showed that three harmful algae species of Cyanophyta, Chlorophyta and Bacillariophyta prevail in the reservoir. The variations in algal concentrations presented a seasonal cycle with high values in the flood season and low values in the drought season and a spatial concentration in main water storage area of the reservoir. Compared with the environmental factors of pH value, permanganate index, ammonia nitrogen and total nitrogen, water temperature, dissolved oxygen content and total phosphorus were significant related to algae concentrations with correlation coefficients of 0.76, 0.62 and 0.85, respectively. The impact analysis of three factors on prevailing algae species indicated that Chlorophyta was the main contributor to the algal photosynthesis of the Panjiakou Reservoir. An extremely high value of algal concentrations with little variety in August 2013 revealed that pollution carried by tremendous runoff may induce algae blooms later.     

典型风力条件及水力调度下太湖藻华高频时空动态监测

湖泊藻华问题已成为全球水生态环境领域面临的长期挑战,风力条件变化和引调水工程的水力调度能改变湖体水动力结构,对藻类的生长和聚集过程产生影响,进行该过程的精细化监测和机制分析对于湖泊藻华预报预警和应急处置具有重要意义。本研究基于Hiamwari-8/AHI卫星遥感高频监测数据,对比分析了归一化差异植被指数(NDVI)、增强植被指数(EVI)和浮游藻类指数(FAI) 3种不同指数对太湖藻华的反演效果,开展了典型风力条件下和水力调度下太湖藻华生消过程的持续监测分析。结果表明,FAI对藻华区域和非藻华区域的区分更加明显,其阈值提取的藻华面积与基于MODIS图像解译的藻华面积的相对误差最低,为-2.27%。当营养盐充足且水温持续保持在蓝藻大量生长增殖的阈值以上时,风力条件是导致太湖藻类迁移聚集的关键因子,风向主要影响藻类的水平迁移,使其进行方向性迁移并逐渐形成大面积藻华区域。风速主要影响藻类的垂向迁移并存在临界阈值,当风速低于约2.5 m/s的临界风速时,藻华面积随风速增加而增加;当风速高于临界风速时,藻华面积随风速增加而降低。水力调度对距离较近的贡湖湾区域具有显著影响,主要通过水动力扰动来影响...     

Der Kohlendioxid-Gehalt und die Kalzitsättigung der Ilm, einschließlich einiger Vergleichsuntersuchungen im Thüringer Raum

The CO₂ content, air saturation and calcite equilibrium of the River Ilm and some of its tributaries were analysed. CO₂ content was measured by degasing the CO₂ from water. The CO₂ level is a very sensitive indicator for a low pollution in oxygen saturated waters. Clean running waters have a CO₂ content close to the air saturation of 0.1–0.3 mg C l⁻¹. Ground water and springs are rich in CO₂. Polluted waters are characterised by higher CO₂ contents, also organic pollution can result in high values of CO₂. Carbon dioxide concentration of streams and brooks is limited by re-aeration.

The headwater region (softwater) of the River Ilm is unsaturated, the hard water in the middle- and underflow is oversaturated. In summer and autumn high saturation could be found, but without autochthonous calcite precipitation like in hard water lakes.     

汉江中下游水华防控生态调度研究

汉江中下游1992-2021年冬春季节共计暴发了十余次大规模水华事件,水生态安全和饮用水安全频繁受到威胁.基于历次水华发生情况,分析总结了汉江中下游水华特征和暴发成因,根据水华与水文过程响应关系研究提出了抑制水华的关键指标及其调控阈值,构建了汉江中下游水利工程联合生态调度方案,明确了抑制水华的生态调度方式和调度持续时间...     

Isotope variations in a Sierra Nevada snowpack and their relation to meltwater

Isotopic variations in melting snow are poorly understood. We made weekly measurements at the Central Sierra Snow Laboratory, California, of snow temperature, density, water equivalent and liquid water volume to examine how physical changes within the snowpack govern meltwater δ¹⁸O. Snowpack samples were extracted at 0.1 m intervals from ground level to the top of the snowpack profile between December 1991 and April 1992. Approximately 800 mm of precipitation fell during the study period with δ¹⁸O values between −21.35 and −4.25‰. Corresponding snowpack δ¹⁸O ranged from −22.25 to −6.25‰. The coefficient of variation of δ¹⁸O in snowpack levels decreased from −0.37 to −0.07 from winter to spring, indicating isotopic snowpack homogenization. Meltwater δ¹⁸O ranged from −15.30 to −8.05‰, with variations of up to 2.95‰ observed within a single snowmelt episode, highlighting the need for frequent sampling. Early snowmelt originated in the lower snowpack with higher δ¹⁸O through ground heat flux and rainfall. After the snowpack became isothermal, infiltrating snowmelt displaced the higher δ¹⁸O liquid in the lower snowpack through a piston flow process. Fractionation analysis using a two-component mixing model on the isothermal snowpack indicated that δ¹⁸O in the initial and final half of major snowmelt was 1.30‰ lower and 1.45‰ higher, respectively, than the value from simple mixing. Mean snowpack δ¹⁸O on individual profiling days showed a steady increase from −15.15 to −12.05‰ due to removal of lower δ¹⁸O snowmelt and addition of higher δ¹⁸O rainfall. Results suggest that direct sampling of snowmelt and snow cores should be undertaken to quantify tracer input compositions adequately. The snowmelt sequence also suggests that regimes of early lower δ¹⁸O and later higher δ¹⁸O melt may be modeled and used in catchment tracing studies.