华北克拉通中部古元古代高Mg低Ti-P镁铁质岩墙的富晶集地幔源区——锆石Hf同位素的制约

华北克拉通中部是古元古代岩墙群最为发育的地区.以镁铁质成分为主的岩墙群可以分为变质的和不变质的两类.不变质岩墙群是在1780～1760 Ma之间大约20 Ma时间内形成的,是华北克拉通古元古代最晚期镁铁质岩浆活动的产物.不变质岩墙又可以细分成高Mg-Ti低P、低Mg高Ti-P和高Mg低Ti-P等3组.本文报道了采自丰镇附近高Mg低Ti-P岩墙样品的锆石U-Pb年龄和Hf同位素组成分析结果.新获得的SHRIMP锆石U-Pb年龄为1769±4 Ma,与其它不变质岩墙的锆石、斜锆石U-Pb年龄和^40Ar/^39Ar年龄的范围相同.高Mg低Ti-P岩墙的锆石εHf（t）值的变化范围在-6.4～＋0.4之间,平均值为-2.2,略高于时代相近的花岗质岩石.由于镁铁质岩浆在上升、侵位和结晶过程中几乎没有受到地壳物质混染,因而锆石εHf（t）值可以代表镁铁质岩浆的富集的岩石圈地幔源区的特征.文献资料显示,高Mg低Ti-P岩墙的岩石圈地幔源区的87Sr/86Sr初始比值为0.7040～0.7050,平均值为0.7046,εNd（t）值为-5.6～-2.8,平均值为-4.4.     

华北克拉通中部古元古代高Mg低Ti-P镁铁质岩墙的富集地幔源区——锆石Hf同位素的制约

华北克拉通中部是古元古代岩墙群最为发育的地区。以镁铁质成分为主的岩墙群可以分为变质的和不变质的两类。不变质岩墙群是在1780～1760Ma之间大约20Ma时间内形成的,是华北克拉通古元古代最晚期铗铁质岩浆活动的产物。不变质岩墙又可以细分成高Mg-Ti低P、低Mg高Ti-P和高Mg低Ti-P等3组。本文报道了采自丰镇附近高Mg低Ti-P岩墙样品的锆石U-Pb年龄和Hf同位素组成分析结果。新获得的SHRIMP锆石U-Pb年龄为1769±4Ma,与其它不变质岩墙的锆石、斜锆石U-Pb年龄和~(40)At/~(39)Ar年龄的范围相同。高Mg低Ti-P岩墙的锆石ε_(Hf)(t)值的变化范围在-6.4～ 0.4之间,平均值为-2.2,略高于时代相近的花岗质岩石。由于镁铁质岩浆在上升、侵位和结晶过程中几乎没有受到地壳物质混染,因而锆石ε_(Hf)(t)值可以代表镁铁质岩浆的富集的岩石圈地幔源区的特征。文献资料显示,高Mg低Ti-P岩墙的岩石圈地幔源区的~(87)Sr/~(86)Sr初始比值为0.7040～0.7050,平均值为0.7046,ε_(Nd)(t)值为-5.6～-2.8,平均值为-4.4。     

离子探针锆石U-Pb定年

锆石是大型离子探针U-Pb定年技术应用最早和最广的矿物,离子探针U-Pb定年可以有效获取粒径微小锆石或具有复杂环带结构的锆石中不同区域的年龄信息。文中以Cameca IMS 1280型离子探针为例,对离子探针锆石U-Pb定年原理、仪器分析流程、数据校正方法和数据误差分析等多方面进行综述,并总结了近年来离子探针锆石U-Pb定年技术新进展。     

沂水青龙峪超镁铁质岩石和基性麻粒岩的锆石SHRIMP U-Pb定年

本文主要对沂水青龙峪出露的超镁铁质岩石和基性麻粒岩进行了锆石SHRIMP U-Pb定年研究。超镁铁质岩石以捕掳体形式存在于沂水杂岩中,不发育鬣刺结构,氧化物组成具有超镁铁质科马提岩的高MgO、富CaO、低SiO2、TiO2、K2O和Na2O含量特征;矿物组合以单斜辉石+橄榄石±斜方辉石+铬铁矿为主;变质矿物以角闪石+蛇纹石化为特征;该岩石以稀土元素总含量(∑REE)低、LREE/HREE=3.35～4.40及Ce和Eu负异常为特征。微量元素组成以Ba、Nb、Zr负异常和Nd、Sm正异常为特征。根据锆石SHRIMP U-Pb定年法对该超镁铁质岩石中捕获的早期岩浆结晶锆石和新生的变质锆石进行的研究,年龄值分别为2657～2702Ma和2551～2585Ma,表明该超镁铁质岩石形成年龄为2585～2657Ma。基性麻粒岩的氧化物组成特征表明其属高Mg的洋岛拉斑玄武岩,麻粒岩相——高角闪岩相变质作用与新太古代的深熔和岩浆侵入作用有关,矿物组合以紫苏辉石+单斜辉石±角闪石+斜长石±石榴子石为特征;晚期蚀变作用与辉长岩墙、辉绿岩脉及石英闪长岩买的侵入有关,矿物组合以滑石化+绢云母化+绿泥石化为特征;稀土元素组成以轻重稀土元素无分异和无Eu异常为特征;微量元素组成以Nb、Zr、P、Ti负异常和Sr、K正异常为特征;锆石SHRIMP U-Pb定年结果表明麻粒岩相——角闪岩相变质作用年龄为2498.4±7.6Ma,导致麻粒岩相——角闪岩相变质的深熔和岩浆结晶年龄为2551±24Ma,晚期蚀变作用的年龄分别为2231～2235Ma和1850±19Ma。     

吉林红旗岭镍矿田茶尖岩体锆石SHRIMP U-Pb年代学及其意义

茶尖1号岩体是茶尖矿床主要成矿岩体,其岩相组合为辉石橄榄岩、橄榄辉石角闪岩、角闪辉岩、辉长岩和闪长伟晶岩.辉长岩的锆石SHRIMP U-Pb测年结果表明,茶尖镁铁-超镁铁岩的形成时代为239.6±2.6 Ma,属于印支期.结合红旗岭矿田已有年代学数据显示,红旗岭矿田成矿岩体形成时代具有由西南至东北依次变新的趋势.茶尖1号岩体的形成年龄明显早于红旗岭成矿岩体,矿床形成年龄差最大可达20 Ma,红旗岭矿区的镁铁-超镁铁岩浆的活动时间应开始于240 Ma之前且持续时间较长.茶尖矿床1号岩体中发现的捕获锆石核年龄为1.7 Ga和0.6 Ga,为镁铁-超镁铁岩浆混入地壳物质提供了直接证据.捕获锆石年龄与华北地台新元古代和中元古代构造－热事件相对应,表明其来源为华北地台基底.      

斜锆石U-Pb定年应用于内蒙古东北部镁铁-超镁铁岩带的讨论

斜锆石作为一种岩浆锆石产于镁铁-超镁铁岩中,是测定其形成年代的理想对象。目前斜锆石定年应用最广泛的三种方法包括ID-TIMS法、SHRIMP法和LA-ICP-MS法,各自有其适用的范围及局限性。内蒙古东北部乃至兴蒙造山带的镁铁-超镁铁岩的斜锆石定年研究相对欠缺,该地区好老鹿场-牤牛海镁铁-超镁铁岩带由于锆石成因的复杂性造成其年代学研究出现了较大分歧。通过与前人研究进行对比分析在杜尔基镁铁-超镁铁岩定年样品CL图像中识别出斜锆石,结合斜锆石U-Pb定年研究现状分析认为在内蒙古东北部镁铁-超镁铁岩带采用LA-ICP-MS法斜锆石U-Pb同位素定年工作可行,有望取得良好的效果,可以为古亚洲洋构造域演化提供准确可靠的年代学依据。     

西藏邦铺钼铜矿区花岗斑岩成岩年龄研究

邦铺钼铜矿床是发育于冈底斯成矿带的大型斑岩型钼铜矿床,矿区内岩浆岩发育,(二长)花岗斑岩为成矿母岩。利用斑岩中锆石离子探针U-Pb法和全岩Rb-Sr法测定邦铺含矿斑岩的年龄,以确定含矿斑岩的形成时代。花岗斑岩中锆石SHRIMP U-Pb法测定其年龄为14.2 Ma±0.2 Ma(MSWD=0.79);二长花岗斑岩中锆石SHRIMP U-Pb法测试值为13.9 Ma±0.3 Ma(MSWD=3.05);全岩Rb-Sr等时线年龄为13.88 Ma±0.38 Ma(MSWD=1.7)。因此14.2 Ma~3.9 Ma年龄值可以作为邦铺矿区含矿斑岩体的结晶年龄。     

3.8 Ma:青藏高原年轻碱性玄武岩锆石离子探针U-Pb年龄测定

离子探针(SHRIMP)是一种主要用于锆石U-Pb年龄测定的仪器,已获得了大量有意义的年龄数据,但十分年轻地质体锆石年龄测定方面的报道还不多见.报道了北京离子探针中心应用SHRIMP技术测定青藏高原晚第三纪3.8 Ma碱性玄武岩的年龄结果,同时讨论了获得十分年轻地质体高精度锆石U-Pb年龄的条件.     

湘南宜章地区辉绿岩、花岗斑岩、安山岩的形成时代和成因——锆石U-Pb年龄和Hf同位素组成

湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf(t)值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。     

大别山双河硬玉石英岩的超高压变质和退变质事件——SHRIMP测年的证据

应用北京SHRIMPⅡ,精确地测定了大别山双河硬玉石英岩中超高压变质锆石的中心、幔和壳的年龄。大部分锆石中心和幔的年龄集中于239～255Ma之间,加权平均值为243±1Ma(n=23)。壳和含矿物包体的晶域年龄集中在225～234Ma,加权平均值为228±2Ma(n=8)。这些锆石的中心、幔和壳都具有极低的Th/U(0.01～0.09)和REE总量,以及重REE平坦型的配分模式。因此,以锆石内部结构、矿物包体、Th/U值和REE地球化学特征为依据,本文提出了大别山超高压变质作用发生于243±1Ma,退变质作用发生于228±2Ma的新观点。     

南秦岭下地壳组成及岩石圈的拆离俯冲作用

根据新提供的Pb同位素组成及岩石地球化学研究成果，本文进一步证实了位于北秦岭北界的明港地区发育的早中生代安山玄武质火山角砾岩岩筒所携带的下地壳捕虏体属于南秦岭。所恢复的南秦岭下地壳剖面自下而上为：底侵成因的变辉长岩-基性麻粒岩(其中含有榴辉岩及辉石岩的透镜体)-酸性麻粒岩。秦岭造山带总体的岩石因模型为：南秦岭(扬子块体)向北拆离俯冲，北秦岭地壳向华北仰冲，华北岩石因呈楔状插入秦岭造山带，拆离面约在中、下地壳之间。南秦岭俯冲岩片延伸的范围在平面上有可能达到400km。     

青藏高原综合观测研究站的回顾与展望

中国科学院青藏高原综合观测研究站从１９８８年建站到１９９８年以来,在各个方面均取得了长足的发展,横向生产性项目的开展和完成不仅解决了部队和地方的实际问题,而且缓和了观测研究站在运行过程中所面临的经费严重不足的问题,同时也为我所冻土专业研究人员提供了在生产中实践的机会,在基础理论研究方面,承担了国家攀登计划项目,国家基金项目,中国科学院重点项目和中国科学院冰冻圈专项项目等的研究工作,在多年冻土变化,     

铀钍的地球化学及对地壳演化和生物进化的影响

本文论述了在含挥发份和贫挥发份条件下Ｕ、Ｔｈ的迁移行为及其对地球和行星演化的影响,并阐述了造成地球独特地质演化历史的原因。提出了Ｕ、Ｔｈ在地球中的迁移模式以及该模式对地壳形成、演化的控制作用和对生物发展演化的可能影响。     

Wavelets and the Generalization of the Variogram

The experimental variogram computed in the usual way by the method of moments and the Haar wavelet transform are similar in that they filter data and yield informative summaries that may be interpreted. The variogram filters out constant values; wavelets can filter variation at several spatial scales and thereby provide a richer repertoire for analysis and demand no assumptions other than that of finite variance. This paper compares the two functions, identifying that part of the Haar wavelet transform that gives it its advantages. It goes on to show that the generalized variogram of order k=1, 2, and 3 filters linear, quadratic, and cubic polynomials from the data, respectively, which correspond with more complex wavelets in Daubechies's family. The additional filter coefficients of the latter can reveal features of the data that are not evident in its usual form. Three examples in which data recorded at regular intervals on transects are analyzed illustrate the extended form of the variogram. The apparent periodicity of gilgais in Australia seems to be accentuated as filter coefficients are added, but otherwise the analysis provides no new insight. Analysis of hyerpsectral data with a strong linear trend showed that the wavelet-based variograms filtered it out. Adding filter coefficients in the analysis of the topsoil across the Jurassic scarplands of England changed the upper bound of the variogram; it then resembled the within-class variogram computed by the method of moments. To elucidate these results, we simulated several series of data to represent a random process with values fluctuating about a mean, data with long-range linear trend, data with local trend, and data with stepped transitions. The results suggest that the wavelet variogram can filter out the effects of long-range trend, but not local trend, and of transitions from one class to another, as across boundaries.     

共和盆地层状地貌系统与青藏高原隆升及黄河发育

利用卫星遥感影像,结合实地调查和测年结果,对共和盆地层状地貌系统进行了解译、分析。研究表明,共和盆地层状地貌系统由山麓剥蚀面、洪积扇面、盆地面以及黄河阶地面构成,其空间结构、物质组成对发生于早更新世早期的青藏运动C幕和中更新世末期的共和运动反映清晰。青藏运动C幕使青藏高原主夷平面在高原差异性隆升中彻底解体,垂直变形量高达1700m。共和运动使黄河在0.11Ma进入共和盆地,其后黄河平均以3.5mm/a的侵蚀速率下切盆地,同时在盆地边部的山前古冲洪积扇以大致相近的速率被抬升,最终导致高差在2000m左右的层状地貌系统的出现。     

从榴辉岩与围岩的关系论苏鲁榴辉岩的形成与折返

位于华北和扬子两板块碰撞带中的苏鲁榴辉岩形成的温压条件不但是超高压，而且是高温。榴辉岩的PTt轨迹表明其为陆-陆磁撞俯冲带的产物。榴辉岩的区域性围岩花岗质片麻岩为新元古代同碰撞期花岗岩，榴辉岩及其他直接围岩皆呈包体存在于其中，并见新元古代花岗岩呈脉状侵入榴辉岩包体中。区域性围岩新元古代花岗岩的锆石中发现有柯石英、绿辉石等包裹体，表明新元古代花岗岩的组成物质也经受过超高压变质作用，且榴辉岩与围岩新元古代花岗岩的锆石U-Pb体系同位素年龄基本相同。但新元古代花岗岩所记录的变质作用和变形作用期次（或阶段）却少于榴辉岩。椐上述可得如下推断：超高压榴辉岩与新元古代花岗岩岩浆是同时在碰撞带底部（俯冲板块前部）形成的；榴辉岩的第一折返阶段是由新元古代花岗岩岩浆携带上升的，其第二折返阶段是和新元古代花岗岩一起由逆冲及区域性隆起而上升，遭受剥蚀。     

南海的形成演化与新特提斯在南海的重新活化

南海位于印度板块、欧亚板块和太平洋板块之间,是世界上最大的边缘海,其构造位置处于太平洋构造域和特提斯构造域,地质构造复杂.关于南海形成演化的动力学机制存在有多种不同观点,其中最重要的一个观点是印度板块与欧亚板块的碰撞致使华南地块和印支地块地幔物质沿东南方向蠕动,从而导致南海的海底扩张.从特提斯的演化规律,以及新特提斯的闭合过程来看,南海并不是特提斯洋的残留海,而是新特提斯在闭合过程中配合印度板块与欧亚板块碰撞导致华南地块和印支地块地幔物质东南方向蠕动的动力学机制下,在南海重新活化的结果.     

Principles of spatial organization and evolution of the biosphere and the noosphere

In his last lifetime essay, “A Few Words about the Noosphere”, Academician V.I. Vernadsky (1944) wrote that all living organisms on the planet, including man, are integral to the biosphere of the Earth, its material and energy structure and cannot be physically independent of it even for a minute. However, the substrate that generates all living beings and is no less tightly bound to the biosphere has always been characterized by a significant geochemical heterogeneity, traced both in the vertical and in the lateral structure of all geospheres.

The present work is devoted to three most important aspects of modern geochemistry and biogeochemistry:

• — evolution of the ecological and geochemical state of the environment under conditions of a virgin (anthropogenically untouched) biosphere;
• — structural features of the geochemical organization of the modern noosphere;
• — specificity of the interaction of living matter with the environment under increasing anthropogenic load.

On the basis of theoretical concepts of biogeochemistry and geochemical ecology, formulated in the works of V.I. Vernadsky, A.P. Vinogradov, A.E. Fersman, B.B. Polynov, A.I. Perel’man, M.A. Glazovskaya, V.V. Kovalsky, E. Odum, B. Commoner, E.I. Kolchinskii and others, the author puts forward a hypothesis that there exist two qualitatively different stages in the evolution of the biosphere.The first stage is recognized as the period of natural evolution of the biosphere during which it evolves successively into a more complex and more biogeochemically specialized object. In the course of the geological time, this constantly results, on the one hand, in an increase in species diversity and the perfection of individual species, and, on the other hand, to directed improvement and a greater differentiation of the geochemical conditions of the environment. At this stage, the evolution of all systems of the biosphere that were controlled by the mechanisms of self-organization and self-regulation resulted in the establishment of a dynamic equilibrium, which was responsible for the cycling of all essential chemical elements and therefore providing ecologically optimal geochemical conditions in all ecological niches and for all species and biocenoses inhabiting the biosphere at any given moment.The beginning of the second stage is related to the appearance of reason and qualitative changes in the biosphere caused by the goal-directed activity of the human mind, as an entirely new geological force that appeared to be able not only to disrupt the functioning of natural mechanisms of self-regulation and selforganization, but also to transform the environment in the intersts of a single biological species, Homo sapiens. A direct consequence of this change was the uncontrolled transformation of the natural environment, during which the primary structure (geochemical background) created in the course of billions of years was eventually superimposed by a qualitatively new layer of anthropogenically-derived chemical elements and compounds, thus building an interference pattern of a new geochemical field with which practically all modern living organisms are now forced to interact.An outstanding feature of the new evolutionary stage of the natural environment, called by Vernadsky the noosphere, is that biogeochemical changes at this stage proceed at a rate which exceeds that required for the living matter to adapt to these changes. The result is the disruption of the existing parameters of the biological cycle, leading to the emergence of a significant number of endemic diseases of geochemical nature.The proposed approach was used to prove the anthropogenic genesis of existing geochemical endemic diseases and explain the mechanisms of their appearance. In addition, this approach allowed us to develop a new methodology for mapping zones of ecological and geochemical risk and noticeably simplify the procedure of monitoring distribution and prevention of all diseases of geochemical nature.