Crystalline silicates in comets: How did they form?

Two processes have been proposed to explain observations of crystalline silicate minerals in comets and in protostellar sources, both of which rely on the thermal annealing of amorphous grains. First, high temperatures generated by nebular shock processes can rapidly produce crystalline magnesium silicate grains and will simultaneously produce a population of crystalline iron silicates whose average grain size is ∼10-15% that of the magnesium silicate minerals. Second, exposure of amorphous silicate grains to hot nebular environments can produce crystalline magnesium silicates that might then be transported outward to regions of comet formation. At the higher temperatures required for annealing amorphous iron silicates to crystallinity the evaporative lifetime of the grains is much shorter than a single orbital period where such temperatures are found in the nebula. Thermal annealing is therefore unable to produce crystalline iron silicate grains for inclusion into comets unless such grains are very quickly transported away from the hot inner nebula. It follows that observation of pure crystalline magnesium silicate minerals in comets or protostars is a direct measure of the importance of simple thermal annealing of grains in the innermost regions of protostellar nebulae followed by dust and gas transport to the outer nebula. The presence of crystalline iron silicates would signal the action of transient processes such as shock heating that can produce crystalline iron, magnesium and mixed iron-magnesium silicate minerals. These different scenarios result in very different predictions for the organic content of protostellar systems.     

Comet Grains: Their IR Emission and Their Relation to ISm Grains

Comets and the chondritic porous interplanetary dust particles (CP IDPs) that they shed in their comae are reservoirs of primitive solar nebula materials. The high porosity and fragility of cometary grains and CP IDPs, and anomalously high deuterium contents of highly fragile, pyroxene-rich Cluster IDPs imply these aggregate particles contain significant abundances of grains from the interstellar medium (ISM). IR spectra of comets (3–40 μm) reveal the presence of a warm (near-IR) featureless emission modeled by amorphous carbon grains. Broad andnarrow resonances near 10 and 20 microns are modeled by warm chondritic (50% Feand 50% Mg) amorphous silicates and cooler Mg-rich crystalline silicate minerals, respectively. Cometary amorphous silicates resonances are well matched by IRspectra of CP IDPs dominated by GEMS (0.1 μm silicate spherules) that are thought to be the interstellar Fe-bearing amorphous silicates produced in AGB stars. Acid-etched ultramicrotomed CP IDP samples, however, show that both the carbon phase (amorphous and aliphatic) and the Mg-rich amorphous silicate phase in GEMS are not optically absorbing. Rather, it is Fe and FeS nanoparticles embedded in the GEMS that makes the CP IDPs dark. Therefore, CP IDPs suggest significant processing has occurred in the ISM. ISM processing probably includes in He⁺ ion bombardment in supernovae shocks. Laboratory experiments show He⁺ ion bombardment amorphizes crystalline silicates, increases porosity, and reduces Fe into nanoparticles. Cometary crystalline silicate resonances are well matched by IR spectra of laboratory submicron Mg-rich olivine crystals and pyroxene crystals. Discovery of a Mg-pure olivine crystal in a Cluster IDP with isotopically anomalous oxygen indicates that a small fraction of crystalline silicates may have survived their journey from AGB stars through the ISM to the early solar nebula. The ISM does not have enough crystalline silicates (<5%), however, to account for the deduced abundance of crystalline silicates in comet dust. An insufficient source of ISMMg-rich crystals leads to the inference that most Mg-rich crystals in comets are primitive grains processed in the early solar nebula prior to their incorporation into comets. Mg-rich crystals may condense in the hot (～1450 K), inner zones of the early solar nebula and then travel large radial distances out to the comet-forming zone. On the other hand, Mg-rich silicate crystals may be ISM amorphous silicates annealed at ～1000 K and radially distributed out to the comet-forming zone or annealed in nebular shocks at ～5-10 AU. Determining the relative abundance of amorphous and crystalline silicatesin comets probes the relative contributions of ISM grains and primitive grains to small, icy bodies in the solar system. The life cycle of dust from its stardust origins through the ISM to its incorporation into comets is discussed.     

Protosolar nebula and composition of comets

Comets seem to be composed of matter, which is supposed to have the same molecular composition as protosolar nebula. Although there are no unbiased evidence that cometary nuclei retain the molecular composition inherited from the protosolar cloud, the observed properties of comets indicate that there is at least a resemblance between cometary composition and the material properties of dense interstellar clouds. Therefore the origin of comets could be searched in the cold stages of the protosolar nebula and molecular abundances of grain mantles in this nebula may be similar to those in the cometary dust. It is suggested that comets may contain pristine, virtually unaltered protosolar material and their study might be very relevant way to more information about processes in early stages of the solar nebula. Our knowledge about composition of the cometary nucleus is still relatively scarce, but we can partly deduce it from data obtained either by ground-based spectroscopy or by in situ mass spectrometry from space experiments. Most important were the discovery of fluffy CHON particles composed partly or even completely from compounds containing light elements. No consensus concerning the presence of interstellar pristine matter in comet has been reached from various approaches to determine the relationship between comets and interstellar grains. Most of these studies are based on infrared spectroscopy. Another method is the comparison on the chemical models of the protosolar nebula with the volatile compounds of the cometary nuclei. Both gas-phase and grain-surface chemistry are considered and initial gas-phase atomic abundances are assumed to be protosolar. The cometary matter is certainly not identical with the typical material of dense interstellar cool dense clouds, but it is closer to it than any other type of matter in solar system so far accessible to us. The data from comets combined with models of chemical evolution of matter in environment similar as prevailed the early stage of presolar nebula may at least impose constrains on the condition for comet formation. Here presented study is a preliminary contribution to such studies.     

On the Light-Absorbing Surface Layer of Cometary Nuclei: I. Radiative Transfer

A small but increasing volume of observations of cometary nuclei has accumulated during the past two decades. This development is accelerating with upcoming space missions such as Stardust, Contour, and Rosetta. In response to the growing need for a theoretical understanding of optical properties of cometary nuclei, we have calculated synthetic reflectance spectra in the wavelength region 0.2-2.0 μm, photometric colors in the Johnson-Kron-Cousins UBVRI system, and visual geometric albedos for a large number of porous ice-dust mixtures with differing composition, regolith grain sizes, and grain morphologies, such as core-mantle grains, dense clusters of such grains, and large irregular particles with internal scatterers. The calculations are based on Mie theory, the discrete dipole approximation, Hapke theory, and a numerical solution to the equation of radiative transfer in particulate media. In addition, wavelength-integrated directional-hemispherical albedos and flux attenuation profiles in the regolith as functions of depth have been calculated in order to improve the energy budget and treatment of energy boundary conditions in thermal models of cometary nuclei.Our results are compared with spectra and colors of observed cometary nuclei. Our main conclusions are that only regolith consisting of relatively large core-mantle grains, or clusters of smaller core-mantle grains, is capable of reproducing the red colors seen in comets; that ice-dust mixtures actually can be darker than ice-free regolith in certain circumstances; and that solar radiation sometimes penetrates to a depth that is comparable to the region in which diurnal temperature variations occur.     

Short-period Jupiter family comets after Stardust

The NASA Stardust mission has provided for laboratory study an extensive data set of cometary dust of known provenance (from comet 81P/Wild 2) yielding detailed insights into the composition of the comet. Combined with the results of data from other missions to short-period Jupiter family comets (JFC), this has greatly deepened the understanding of such objects. If depressions on the surface of comet 81P/Wild 2 are all taken as evidence of impact cratering, their number suggests a long occupancy in the outer region of the Solar System. The dust from comet 81P/Wild 2 has been shown to be heavily deficient in pre-Solar grains and rich in materials formed at high temperatures in the inner Solar System. Although it is too early to know if this is typical of JFC, it does argue for rapid and thorough mixing of materials in the disk on timescales related to comet formation, and may also suggest outward migration of small icy bodies after their formation. Thus, instead of providing mainly new knowledge of the pre-Solar materials expected to be rich in comets, Stardust and comet 81P/Wild 2 have instead focussed attention on large-scale transport processes during the critical period when cometary parent bodies were forming in the early Solar System.     

The effects of disk building on the distributions of refractory materials in the solar nebula

Abstract– Refractory materials, such as calcium‐aluminum‐rich inclusions (CAIs) and crystalline silicates, are widely found in chondritic meteorites as well as comets, taken as evidence for large‐scale mixing in the solar nebula. Most models for mixing in the solar nebula begin with a well‐formed protoplanetary disk. Here, we relax this assumption by modeling the formation and evolution of the solar nebula during and after the period when it accreted material from its parent molecular cloud. We consider how disk building impacts the long‐term evolution of the disk and the implications for grain transport and mixing within it. Our model shows that materials that formed before infall was complete could be preserved in primitive bodies, especially those that accreted in the outer disk. This potentially explains the discovery of refractory objects with low initial ²⁶Al/²⁷Al ratios in comets. Our model also shows that the highest fraction of refractory materials in meteorites formed around the time that infall stopped. Thus, we suggest that the calcium‐aluminum‐rich inclusions in chondrites would be dominated by the population that formed during the transition from class I to class II stage of young stellar objects. This helps us to understand the meaning of t = 0 in solar system chronology. Moreover, our model offers a possible explanation for the existence of isotopic variations observed among refractory materials—that the anomalous materials formed before the collapse of the parent molecular cloud was complete.     

Structure and density of cometary nuclei

Abstract— Understanding the nature of the cometary nucleus remains one of the major problems in solar system science. Whipple's (1950) icy conglomerate model has been very successful at explaining a range of cometary phenomena, including the source of cometary activity and the nongravitational orbital motion of the nuclei. However, the internal structure of the nuclei is still largely unknown. We review herein the evidence for cometary nuclei as fluffy aggregates or primordial rubble piles, as first proposed by Donn et al. (1985) and Weissman (1986). These models assume that cometary nuclei are weakly bonded aggregations of smaller, icy‐conglomerate planetesimals, possibly held together only by self‐gravity. Evidence for this model comes from studies of the accretion and subsequent evolution of material in the solar nebula, from observations of disrupted comets, and in particular comet Shoemaker‐Levy 9, from measurements of the ensemble rotational properties of observed cometary nuclei, and from recent spacecraft missions to comets. Although the evidence for rubble pile nuclei is growing, the eventual answer to this question will likely not come until we can place a spacecraft in orbit around a cometary nucleus and study it in detail over many months to years. ESA's Rosetta mission, now en route to comet 67P/Churyumov‐Gerasimenko, will provide that opportunity.     

Experimental aqueous alteration of cometary dust

Abstract– Recent spacecraft missions to comets have reopened a long‐standing debate about the histories and origins of cometary materials. Comets contain mixtures of anhydrous minerals and ices seemingly unaffected by planetary processes, yet there are indications of a hydrated silicate component. We have performed aqueous alteration experiments on anhydrous interplanetary dust particles (IDPs) that likely derived from comets. Hydrated silicates rapidly formed from submicrometer amorphous silicates within the IDPs at room temperature in mildly alkaline solution. Hydrated silicates may thus form in the near‐surface regions of comets if liquid water is ever present. Our findings provide insight into origins of cometary IDPs containing both anhydrous and hydrated minerals and help reconcile the seemingly inconsistent observations of hydrated silicates from the Stardust and Deep Impact missions.     

Connection between micrometeorites and Wild 2 particles: From Antarctic snow to cometary ices

Abstract— We discuss the relationship between large cosmic dust that represents the main source of extraterrestrial matter presently accreted by the Earth and samples from comet 81P/Wild 2 returned by the Stardust mission in January 2006. Prior examinations of the Stardust samples have shown that Wild 2 cometary dust particles contain a large diversity of components, formed at various heliocentric distances. These analyses suggest large‐scale radial mixing mechanism(s) in the early solar nebula and the existence of a continuum between primitive asteroidal and cometary matter. The recent collection of CONCORDIA Antarctic micrometeorites recovered from ultra‐clean snow close to Dome C provides the most unbiased collection of large cosmic dust available for analyses in the laboratory. Many similarities can be found between Antarctic micrometeorites and Wild 2 samples, in terms of chemical, mineralogical, and isotopic compositions, and in the structure and composition of their carbonaceous matter. Cosmic dust in the form of CONCORDIA Antarctic micrometeorites and primitive IDPs are preferred samples to study the asteroid‐comet continuum.     

Overview of the rocky component of Wild 2 comet samples: Insight into the early solar system,relationship with meteoritic materials and the differences between comets and asteroids

Abstract– The solid 2–10 μm samples of comet Wild 2 provide a limited but direct view of the solar nebula solids that accreted to form Jupiter family comets. The samples collected by the Stardust mission are dominated by high‐temperature materials that are closely analogous to meteoritic components. These materials include chondrule and CAI‐like fragments. Five presolar grains have been discovered, but it is clear that isotopically anomalous presolar grains are only a minor fraction of the comet. Although uncertain, the presolar grain content is perhaps higher than found in chondrites and most interplanetary dust particles. It appears that the majority of the analyzed Wild 2 solids were produced in high‐temperature “rock forming” environments, and they were then transported past the orbit of Neptune, where they accreted along with ice and organic components to form comet Wild 2. We hypothesize that Wild 2 rocky components are a sample of a ubiquitously distributed flow of nebular solids that was accreted by all bodies including planets and meteorite parent bodies. A primary difference between asteroids and the rocky content of comets is that comets are dominated by this widely distributed component. Asteroids contain this component, but are dominated by locally made materials that give chondrite groups their distinctive properties. Because of the large radial mixing in this scenario, it seems likely that most comets contain a similar mix of rocky materials. If this hypothesis is correct, then properties such as oxygen isotopes and minor element abundances in olivine, should have a wider dispersion than in any chondrite group, and this may be a characteristic property of primitive outer solar system bodies made from widely transported components.     

Dust in cometary comae: Present understanding of the structure and composition of dust particles

In situ probing of a very few cometary comae has shown that dust particles present a low albedo and a low density, and that they consist of both rocky material and refractory organics. Remote observations of solar light scattered by cometary dust provide information on the properties of dust particles in the coma of a larger set of comets. The observations of the linear polarization in the coma indicate that the dust particles are irregular, with a size greater (on the average) than about 1 μm. Besides, they suggest, through numerical and experimental simulations, that both compact grains and fluffy aggregates (with a power law of the size distribution in the −2.6 to −3 range), and both rather transparent silicates and absorbing organics are present in the coma. Recent analysis of the cometary dust samples collected by the Stardust mission provide a unique ground truth and confirm, for comet 81P/Wild 2, the results from remote sensing observations. Future space missions to comets should, in the next decade, lead to a more precise characterization of the structure and composition of cometary dust particles.     

Formaldehyde polymers in comets

The possibility that crystalline formaldehyde polymers are present in cometary dust is discussed. In common with most other parent molecules proposed for comets, (H₂CO) _n is difficult to detect, even if it is present in relatively high concentrations. The optical properties of these polymers in the visual and infrared regions are similar to those of silicate grains, and crystalline formaldehyde polymers provide no emission at 6 cm wavelength. The lifetime of gaseous H₂CO in the solar radiation field is too short, and the expected transitions in the microwave region would be too weak to be detected. However, the available data concerning the physical properties of comets indicate that polymerized formaldehyde cannot be ruled out as a major constituent of cometary material.     

The composition of dust in Jupiter-family comets inferred from infrared spectroscopy

We review the composition of Jupiter-family comet (JFC) dust as inferred from infrared spectroscopy. We find that JFCs have silicate emission features with fluxes roughly 20-25% over the dust continuum (emission strength 1.20-1.25), similar to the weakest silicate features in Oort Cloud (OC) comets. We discuss the grain properties that alter the silicate emission feature (composition, size, and structure/shape), and emphasize that thermal emission from the comet nucleus can have significant influence on the derived silicate emission strength. Recent evidence suggests that grain porosity is the is different between JFCs and OC comets, but more observations and models of silicates in JFCs are needed to determine if a consistent set of grain parameters can explain their weak silicate emission features. Models of 8 m telescope and Spitzer Space Telescope observations have shown that JFCs have crystalline silicates with abundances similar to or less than those found in OC comets, although the crystalline silicate mineralogy of comets 9P/Tempel and C/1995 O1 (Hale-Bopp) differ from each other in Mg and Fe content. The heterogeneity of comet nuclei can also be assessed with mid-infrared spectroscopy, and we review the evidence for heterogeneous dust properties in the nucleus of comet 9P/Tempel. Models of dust formation, mixing in the solar nebula, and comet formation must be able to explain the observed range of Mg and Fe content and the heterogeneity of comet 9P/Tempel, although more work is needed in order to understand to what extent do comets 9P/Tempel and Hale-Bopp represent comets as a whole.     

Organics-glued dust aggregates in Halley's coma and some implications of the snow line inward motion for the formation of comets

In view of the solar nebula models, organics-glued dust aggregates (whose disintegration resulted in the two phenomena found in Halley's coma, the dust boundary and small-scale dust structures) originated due to coagulation of iceless dust particles somewhere within the snow line, and then were incorporated into Halley's nucleus as a consequence of the snow line inward motion. This implies that two types of comets exist: outer comets, formed entirely beyond the snow line, and inner comets, similar to Halley, which are bodies intermediate between outer comets and primitive asteroids. The presence of large iceless dust aggregates in nuclei of inner comets constrains the inward drift velocity of meter-sized dust bodies, which in turn implies that the radial transport of water in the solar nebula was predominantly outward. It is shown that in nuclei of inner comets: both the upper mass limit of iceless dust aggregates and the ice mantle thickness increase with decreasing formation heliocentric distance, while the cumulative mass distribution index decreases; the lower limit of the mass index is ∼0.8, and the upper limit of the ice mantle thickness is ∼10⁻³ cm (∼200 times the interstellar value); the lower limit of the latent heat of organics in organic mantles of submicron particles increases toward small heliocentric distances; the recondensation of organics combined with the growth of dust bodies leads to a fractionation of organics within iceless dust aggregates; last accreted sub-units of an aggregate are always glued by organics with the lowest value of the latent heat, which somewhat exceeds 60 kJ/mol. Based on in situ observations at Halley, the parameters characterizing iceless dust aggregates in that comet are calculated. Finally, feasible observational tests of the conclusions drawn are discussed.     

Formaldehyde Polymers in Comets

The possibility that crystalline formaldehyde polymers are present in cometary dust is discussed. In common with most other parent molecules proposed for comets, (H₂CO)_n is difficult to detect, even if it is present in relatively high concentrations. The optical properties of these polymers in the visual and infrared regions are similar to those of silicate grains, and crystalline formaldehyde polymers provide no emission at 6 cm wavelength. The lifetime of gaseous H₂CO in the solar radiation field is too short, and the expected transitions in the microwave region would be too weak to be detected. However, the available data concerning the physical properties of comets indicate that polymerized formaldehyde cannot be ruled out as a major constituent of cometary material. This revised version was published online in July 2006 with corrections to the Cover Date.     

The origin of crystalline residues in Stardust Al foils: Surviving cometary dust or crystallized impact melts?

Abstract– Samples returned by the Stardust mission from comet 81P/Wild 2 provide an unequaled opportunity to investigate cometary formation and evolution. Crystalline silicates have been identified in impact craters in Stardust Al foil, yet their origin is ambiguous. They may be original cometary components, or they may have grown from melt generated by impact. We have now studied experimental impacts of the calcium silicate mineral wollastonite, using scanning and transmission electron microscopy to document the relationship between impact feature shape and crystal lattice orientation in impact residue. Wollastonite can have a characteristic acicular habit, forming crater shapes that indicate crystal orientation upon impact. From extracted impact residue, we determined the lattice orientation of crystalline material for comparison with the whole particle orientation. We assume that crystallization from melt, without surviving seed nuclei, should result in randomly oriented crystallite growth, with no preferred direction for individual crystals. However, we find that the majority of crystalline material in the residue retains b‐axis orientation parallel to the long axis of the crater form. This, together with impact parameter calculations and lack of Al incorporation by the residue (suggesting melting did not occur), indicates that these crystals and, by analogy, the majority of Al‐free crystalline silicates in Stardust foil, are surviving remnants of the impactor. Furthermore, amorphous wollastonite residue probably did not form via melting and subsequent quenching, but instead by high‐pressure amorphization or degradation of unquenchable phases. Finally, one crystal studied appears to be a new high‐pressure/temperature polymorph of CaSiO₃, indicating that such polymorphs may be observed in Stardust residues in craters.     

The distributions and ages of refractory objects in the solar nebula

Refractory objects such as Calcium, Aluminum-rich Inclusions, Amoeboid Olivine Aggregates, and crystalline silicates, are found in primitive bodies throughout our Solar System. It is believed that these objects formed in the hot, inner solar nebula and were redistributed during the mass and angular momentum transport that took place during its early evolution. The ages of these objects thus offer possible clues about the timing and duration of this transport. Here we study how the dynamics of these refractory objects in the evolving solar nebula affected the age distribution of the grains that were available to be incorporated into planetesimals throughout the Solar System. It is found that while the high temperatures and conditions needed to form these refractory objects may have persisted for millions of years, it is those objects that formed in the first 10⁵ years that dominate (make up over 90%) those that survive throughout most of the nebula. This is due to two effects: (1) the largest numbers of refractory grains are formed at this time period, as the disk is rapidly drained of mass during subsequent evolution and (2) the initially rapid spreading of the disk due to angular momentum transport helps preserve this early generation of grains as opposed to later generations. This implies that most refractory objects found in meteorites and comets formed in the first 10⁵ years after the nebula formed. As these objects contained live ²⁶Al, this constrains the time when short-lived radionuclides were introduced to the Solar System to no later than 10⁵ years after the nebula formed. Further, this implies that the t=0 as defined by meteoritic materials represents at most, the instant when the solar nebula finished accreting significant amounts of materials from its parent molecular cloud.     

Dust Grains in the Comae and Tails of Sungrazing Comets: Modeling of Their Mineralogical and Morphological Properties

Observations of sungrazing comets, all of which belong to the Kreutz family, provide the opportunity of studying the properties of dust in the comae and tails of the comets. On the basis of available information on cometary and interplanetary dust as well as observations of dust in the tails of sungrazers, we model dust in sungrazing comets as fluffy silicate aggregates of submicrometer sizes. To better interpret observational data, we numerically calculate the solar radiation pressure, the equilibrium temperature, and the sublimation and crystallization rates of silicate grains near the Sun. Our results show that the dust tails contain aggregates of submicrometer crystal grains, but not amorphous grains, since amorphous silicates mostly crystallize after release from the comets. The peak in the lightcurves of the dust comae observed either at 11.2 or 12.3 solar radii (R_⊙) seems to result from sublimation of fluffy aggregates consisting of crystalline or amorphous olivines, respectively. We attribute an additional enhancement in the lightcurves inside 7 R_⊙ to increasing out-flow of crystalline and amorphous pyroxenes composed fluffy aggregates. According to our model, the observed lightcurves indicate a high abundance of olivine and a low abundance of pyroxene in the comets, which may bear implications about the dynamical and thermal history of the sungrazers and their progenitor.     

Interpretation of Wild 2 dust fine structure: Comparison of Stardust aluminum foil craters to the three‐dimensional shape of experimental impacts by artificial aggregate particles and meteorite powders

Abstract— New experimental results show that Stardust crater morphology is consistent with interpretation of many larger Wild 2 dust grains being aggregates, albeit most of low porosity and therefore relatively high density. The majority of large Stardust grains (i.e. those carrying most of the cometary dust mass) probably had density of 2.4 g cm^?3 (similar to soda‐lime glass used in earlier calibration experiments) or greater, and porosity of 25% or less, akin to consolidated carbonaceous chondrite meteorites, and much lower than the 80% suggested for fractal dust aggregates. Although better size calibration is required for interpretation of the very smallest impacting grains, we suggest that aggregates could have dense components dominated by μm‐scale and smaller sub‐grains. If porosity of the Wild 2 nucleus is high, with similar bulk density to other comets, much of the pore space may be at a scale of tens of micrometers, between coarser, denser grains. Successful demonstration of aggregate projectile impacts in the laboratory now opens the possibility of experiments to further constrain the conditions for creation of bulbous (Type C) tracks in aerogel, which we have observed in recent shots. We are also using mixed mineral aggregates to document differential survival of pristine composition and crystalline structure in diverse finegrained components of aggregate cometary dust analogues, impacted onto both foil and aerogel under Stardust encounter conditions.     

Searching for calcium‐aluminum‐rich inclusions in cometary particles with Rosetta/COSIMA

The calcium‐aluminum‐rich inclusions (CAIs) found in chondritic meteorites are probably the oldest solar system solids, dating back to 4567.30 ± 0.16 million years ago. They are thought to have formed in the protosolar nebula within a few astronomical units of the Sun, and at a temperature of around 1300 K. The Stardust mission found evidence of CAI‐like material in samples recovered from comet Wild 2. The appearance of CAIs in comets, which are thought to be formed at lower temperatures and larger distances from the Sun, is only explicable if some mechanism allows the efficient transfer of such objects from the inner solar nebula to the outer solar nebula. Such mechanisms have been proposed such as an X‐wind or turbulence. In this work, particles collected from within the coma of comet 67P/Churyumov–Gerasimenko are examined for compositional evidence of the presence of CAIs. COSIMA (the Cometary Secondary Ion Mass Analyzer) uses secondary ion mass spectrometry to analyze the composition of cometary dust captured on metal targets. While CAIs can have a radius of centimeters, they are more typically a few hundred microns in size, and can be smaller than 1 μm, so it is conceivable that particles visible on COSIMA targets (ranging in size from about 10 μm to hundreds of microns) could contain CAIs. Using a peak fitting technique, the composition of a set of 13 particles was studied, looking for material rich in both calcium and aluminum. One such particle was found.