福建永泰云山晚中生代双峰式火山岩的地球化学及岩石成因

永泰云山早白垩世石帽山群第Ｉ、Ⅱ旋回岩石组合由沉积岩、基性熔岩、酸性火山岩构成,缺乏中性成分的岩石单元,为典型的双峰式岩石组合。其玄武岩富碱（尤其富钾）、富铝、富铁,贫镁,富轻稀土元素和大离子亲石元素,贫高场强元素及亲铁元素,并具偏高的ＩＳｒ值和显著偏低的εＮｄ（Ｔ）值［ＩＳｒ＝０．７０６８２￣０．７０７７０,εＮｄ（Ｔ）＝－７．４２￣－３．２２。流纹质岩石总体具富碱、富硅、富铝,贫铝、贫镁特征,     

武当地块基性岩墙群及耀岭河群基性火山岩的Sr,Nd,Pb,O同位素研究

武当地块基性岩墙群与耀岭河群基性火山岩的Ｓｒ、Ｎｄ、Ｐｂ同位素特征反映它们具相同的混合地幔源区。前者的（＾８７Ｓｒ／＾８６Ｓｒ）ｉ＝０．６９０５￣０．７０６１,εＮｄ（ｔ）＝－１．９￣５．０,Δ＾２０８Ｐｂ／＾２０４Ｐｂ＝３５．４９￣１９０．２６,Δ＾２０７Ｐｂ／＾２０４Ｐｂ＝４￣８５,Ｔｈ／Ｔａ低,Ｌａ／Ｙｂ变化大;后者的（＾８７Ｓｒ／＾８６Ｓｒ）ｉ＝０．６４８７￣０．７０７５,εＮｄ（ｔ）＝０     

河北风化店中生代火山岩的地球化学特征及其成因探讨

河北风化店中生代火山岩主要为钙碱性到偏碱性的流纹英安岩－流纹岩－碱流岩及少量碱性粗面岩和石英粗面岩。岩石全碱含量高,平均９．２５％,大部分岩石的Ｋ２Ｏ／Ｎａ２Ｏ＞１,Ｆｅ２Ｏ３／ＦｅＯ比值大,ＴｉＯ２含量低,以富集大离子亲石元素（ＬＩＬＥ）和贫高场强元素（ＨＦＳＥ）及贫亲铁元素为特征。稀土元素配分型式表现为轻稀土富集并具Ｅｕ弱负异常。（８７Ｓｒ／８６Ｓｒ）初始比和（１４３Ｎｄ／１４４Ｎｄ）初始比分别为０．７０５４和０．５１１５,εＮｄ（ｔ）为－１８．２。所有这些特征均表明该区火山岩的物源来自地壳硅铝层的重熔并有消减带物质及幔源物质的加入。该火山岩形成于中生代时期中国东部活动大陆边缘挤压作用向引张作用转变前的挤压应力环境,是较成熟火山孤后拉张前的产物。     

山东中生代橄榄安粗岩系火山岩的地质、地球化学特征及岩石成因

山东中生代橄榄安粗岩系火山岩主要分布在沂沭断裂带及其两侧的断陷型陆相火山盆地中，为早白垩世火山活动的产物．Ｒｂ－Ｓｒ全岩等时年龄变化于１１１．４～１１９．６Ｍａ．岩石组合主要为粗面玄武岩－橄榄安粗岩－安粗岩－粗面岩．这套岩石在化学上具有富碱富钾、富铝贫钛、高氧化系数及富轻稀土和大离子亲石元素的特点，并具有较高的ＩＳｒ值和明显偏低εＮｄ值．根据对岩石地质、地球化学特征和产出构造环境的详细分析，表明这套岩石的成因应主要是富集型地幔的部分熔融     

广东恶鸡脑碱性正长岩的地球化学及其地球动力学意义

广东从化恶鸡脑碱性正长岩岩体是广东乃至华南地区唯一已各的中生代含副长石及碱性暗色矿物的碱性正长岩岩体。岩石含有霞石、白榴石及岩浆成因的方钠石。碱性正长岩体侵入到燕山期第三期的佛冈岩体之中,岩体侵位年龄为１２７．５Ｍａ（角闪石Ａｒ￣Ａｒ法）。岩体富大离子亲石元素,贫Ｓｒ和Ｂａ,具有明显的铕负异常,富Ｎｂ和Ｚｒ等高场强元素。εＥｄ（ｔ）为近于零的负值（－０．６６￣－１．６）,模式年龄ｔＤＭ较小（０．９     

铜陵地区高钾钙碱系列侵入岩

铜陵地区侵入岩在化学性质上不属于一般的钙碱系列岩石。它们可能是幔源碱性玄武岩浆同化古老麻粒岩相下地壳为主的酸性组分，同时发生结晶分离（ＡＦＣ的产物。铜陵地区侵入岩的特点是：以石英二长闪长岩为主，高钾富碱，富Ｓｒ，δＥｕ＝０．９±。εＮｄ和ＩＳｒ较低，Ｐｂ同位素比值中等，但均有较好的线性关系。在εＮｄ－ＩＳｒ图和＾２０７Ｐｂ／＾２０４Ｐｂ－＾２０６Ｐｂ／＾２０４Ｐｂ图上，样品投影点的特点是均作陡倾斜     

赣东北地区晚元古代钾玄岩岩石学特征及成因

Ｓｍ－Ｎｄ同位素测龄研究表明,赣东北广丰地区桃源组火山岩的Ｓｍ－Ｎｄ等时线年龄为（１１００±１６８）Ｍａ,形成时代应归属晚元古代,与扬子、华夏两板块在晋宁期对接造山作用的时间一致。岩石学、岩石地球化学的系统研究表明,该组火山岩富碱、Ｋ２Ｏ,Ａｌ２Ｏ３,ＬＲＥＥ及地幔不相容元素,属碱性系列中的钾玄岩系列;低εｔ（Ｎｄ）（－４．５±１．９）,Ｉｔ（Ｓｒ）为０．７０４８～０．７１３１,变化范围很大,具壳幔混合成因的Ｓｍ－Ｎｄ、Ｒｂ－Ｓｒ同位素组成。笔者研究认为,桃源组钾玄岩系列火山岩是晋宁期岛弧火山岩的重要组成部分。     

青藏高原乌依塔克花岗岩体地球化学及其大地构造意义

乌依塔克花岗岩体分布于乌依塔克蛇绿岩套中,与其中的基性熔岩呈侵入接触关系,形成时代比蛇绿岩套（超）镁质岩稍晚;岩石类型为斜长花岗岩,斜长石属钠长石;岩石高ＳｉＯ２,低Ａｌ２Ｏ３,富Ｎａ２Ｏ,贫Ｋ２Ｏ（〈１％）,里特曼指数σ为０．９６￣１．０８,是钙质的;稀土元素总量较低,并且属轻稀土元素亏损型;除Ｙ含量较高外,其他微量元素含量均较低;ＩＳｒ为０．７０２５８８,εＳｒ（ｔ）为－１６．１,εＮｄ（ｔ）     

西南极利文斯顿岛百耳斯半岛中生代火山岩地球化学特征

西南极利文斯顿岛百耳斯半岛中生代火山岩是晚侏罗纪至晚白垩纪三期火山活动的产物。岩石普遍贫钾,轻稀土元素略为富集,但轻重稀土分馏不强烈;Ｓｒ、Ｋ、Ｒｂ、Ｂａ、Ｔｈ等大离子亲石元素（ＬＩＬ）明显富集,Ｎｂ和Ｔａ明显亏损,过渡金属族元素Ｃｒ和Ｎｉ强烈亏损,表明它们属于火山弧环境中生成的钙碱性系列岩石。白垩纪中期和白垩纪晚期岩石的８７Ｓｒ／８６Ｓｒ比值主要在０．７０３９～０．７０５３之间变化,εＮｄ＞０,８７Ｓｒ／８６Ｓｒ相对１／Ｓｒ、Ｒｂ、Ｋ和ＳｉＯ２等的变化不大,表明其源区岩浆可能直接来自上地幔,很少受到壳源物质的混染。而晚侏罗纪火山岩的Ｓｒ同位素比值较高,说明早期岩浆可能受到少量地壳物质的混染。但在Ｔｈ／Ｔａ－Ｔｈ和Ｔｈ／Ｓｍ－Ｔｈ图解上所有岩石的投影点分布趋势相同,趋势线的斜率＞０。百耳斯半岛中生代火山岩是上地幔部分熔融生成的同源岩浆不同期的产物     

陕南铁船山岩体的地球化学特征、成因及其形成的构造环境

扬子克拉通北缘的铁船山岩体形成于新元古代，其岩石类型为霓石－钠铁门石花岗岩，岩石富碱质、Ｓｔ、Ｆｅ、ＲＥＥ和高场强元素，而贫Ａｌ、Ｃａ、Ｍｇ、Ｓｒ、Ｂａ、Ｃｏ、Ｎｉ等组分，δＥｕ＝０．２０，Ａ／ＫＮＣ＝０．８５，Ｋ２Ｏ＋Ｎａ２Ｏ／Ａｌ２Ｏ３＝１．０９，Ａ·Ｒ＝９．２８，岩石属典型的Ａ型花岗岩，Ｎｄ、Ｓｒ和Ｏ同位素示踪反映其成岩物质来自于壳幔混合源区。根据区域地质背景的综合分析，岩体形成于活动陆缘的张裂构造环境，属活动板块边缘拉张型花岗岩。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。