Variation in pyrite size, form, and microlithotype association in the springfield (no. 9) and herrin (no. 11) coals, Western Kentucky

Channel samples of the Springfield (No. 9) and Herrin (No. 11) (Pennsylvanian, Desmoinesian/Westphalian D) coals were acquired in three mines each in the Western Kentucky coal field. Pyrite was characterized petrographically in terms of its size, form, and microlithotype association. Within each coal seam significant variations in the amount of pyrite of certain forms occurred between the sites. Pyritic sulfur as determined chemically did not exhibit significant variation between the seams or between the sites. The variation in dendritic pyrite in vitrite plus clarite between seams and between sites was highly significant and the variation in framboidal pyrite in vitrite plus clarite between sites was also highly significant.     

Petrogenesis of monzonoritic dykes in the Egersund-Ogna anorthosite (Rogaland,S.W. Norway): trace elements and isotopic (Sr,Pb) constraints

Two major monzonoritic dykes occur in the Egersund-Ogna anorthositic massif (S.W. Norway): the Lomland dyke, which varies from norite to monzonite, and the Vettaland ferronoritic dyke. They are characterized by high Fe, Ti and P contents, low SiO₂, variable K₂O (0.5%–4.5%) and high Fe/Mg ratios. Small variations in REE distribution are observed inside the Lomland dyke [La/Yb=12; LREE ca. 150–180 (chondrite-normalized values), neutral to slightly positive Eu anomaly]. Part of the Vettaland dyke is severely depleted in Zr, Rb and REE and shows a positive Eu anomaly. All rocks are depleted in U and Th, and show very low Cr and Ni contents, as well as high Sr contents (400–600 ppm). Variation within the Lomland dyke is satisfactorily ex-plained through subtraction of an apatite-bearing noritic cumulate. The role of apatite is predominant in controlling the REE behaviour. Eutectic partial melting of a Fe-rich noritic cumulate (containing apatite) under low pH₂O conditions is suggested for the Vettaland dyke by REE modelling. Sr isotopic initial ratios are different in Lomland (ca. 0.708) and Vettaland (ca. 0.706) dykes. These values preclude direct derivation from the mantle as well as comagmatic relationship with anorthosite. Contamination of a mantle derived magma by deep crustal material or anatexis of the LIL depleted lower crust is compatible with the low U and Th contents, and with the Pb isotopic ratios. The Vettaland partial melting process is extended to all monzonoritic types, the necessary heat being provided by the high temperature anorthositic crystal mush. Chargé de Recherches du F.N.R.S (Belgium)     

Lower Carboniferous (Dinantian) stratigraphy and structure of the Walterstown-Kentstown area,Co. Meath,Ireland

Stratigraphic units are defined and described for the Lower Carboniferous succession in the Walterstown-Kentstown area of Co. Meath, Ireland. A complete (unexposed) Courceyan succession from the terrestrial red bed facies of the Baronstown Formation to the Moathill Formation of the Navan Group has been penetrated in several boreholes. Although the lower part of the sequence is comparable with the Courceyan succession at Navan and Slane, the middle part of the sequence differs markedly in the Walterstown-Kentstown area and two new members, the Proudstown and Walterstown Members, are defined in the upper part of the Meath Formation. Syndepositional faulting was initiated during the Courceyan, probably in latest Pseudopolygnathus multistriatus or early Polygnathus mehli latus time. Movement on the ENE trending St. Patrick's Well Fault influenced the deposition of the Walterstown Member and the overlying Moathill Formation and was probably associated with the development of the East Midlands depocentre to the south of the area. A second episode of tectonism in the latest Courceyan or early Chadian resulted in uplift and erosion and the development of ‘block and basin’ sedimentation. Subsequent transgression of the uplifted block led to the establishment of the Kentstown Platform, bounded to the north, west and south by rocks of basinal facies. The Milverton Group (Chadian-Asbian), confined to this platform, unconformably overlies Courceyan or Lower Palaeozoic strata and is subdivided into three formations: Crufty Formation (late Chadian), Holmpatrick Formation (late Chadian-Arundian) and Mullaghfin Formation (late Arundian-Asbian). The Walterstown Fault controlled the western margin of the Kentstown Platform at this time. Contemporaneous basinal sediments of the Fingal Group (Lucan and Naul Formations) accumulated to the west of the Walterstown Fault and are much thicker than age-equivalent platform facies. Platform sedimentation ceased in latest Asbian to early Brigantian time with tectonically induced collapse and drowning of the platform; platform carbonates of the Mullaghfin Formation are onlapped northwards by coarse proximal basinal facies of the Loughshinny Formation. A distinct gravity anomaly in the Kentstown area suggests the presence of a granitoid body within the basement. The Kentstown Platform is therefore considered to have formed on a buoyant, granite-cored, footwall high analogous to the Askrigg and Alston Blocks of northern England.     

Quantitative modeling of Sr,Ca, Rb,and K in the Bjerkrem-Sogndal layered lopolith (S.W. Norway)

A systematic approach with graphic techniques is used to establish a quantitative model of fractional crystallization process in igneous layered complexes. Modeling of the evolution of Sr-Ca in plagioclase and K-Rb in plagioclase and whole rock coming from the Bjerkrem-Sogndal layered lopolith (Rogaland-S.W. Norway) is taken as an example. The relationships in logarithmic coordinates can be decomposed in a succession of segments. This permits identifying the Rayleigh law as controlling the process. A step by step solution is used to determine the parameters of the model which lead to the adjustment of the calculated evolution to the observed trend. Evidence in favour of an open system crystallization of the cumulate rocks permits determining the equilibrium partition coefficients between the various minerals and the liquid. The mean cumulate corresponding to a phase of crystallization of the intrusion is determined by averaging the mineral composition of the rocks belonging to that phase. The concentrations of the major elements Ca and K are used instead of activities. The adopted plagioclase-magma partition coefficients are close to those measured in anorthositic rocks for the same range of plagioclase composition between megacrysts and liquid. For an anorthite content of respectively 50, 43 and 31, D _Sr ^plag is equal to 2.0, 2.3 and 3.9, D _K ^plag varies between 0.40 and 0.25, D _Rb ^plag is either constant (ca. 0.10) or increases from 0.12 to 0.25, D _Ca ^plag is supposed to remain at an approximately constant value of 1.48. The fraction of residual liquid in the intrusion is 0.47 at the end of the anorthositic-leuconoritic phase, and 0.21 at the end of the cpxnoritic phase.     

Site selectivity of the boring Rogerella isp. infesting Cardiaster granulosus (Goldfuss) (Echinoidea) in the type Maastrichtian (Upper Cretaceous,Belgium)

A burrowing spatangoid echinoid (heart urchin), Cardiaster granulosus (Goldfuss), from the type area of the Maastrichtian Stage (Upper Cretaceous) in Belgium, was infested only in the plates of the ambulacral petals by acrothoracian barnacle borings, Rogerella isp. This infestation was after the death and exhumation of the echinoid. The distribution of Rogerella may indicate the azimuth of current flow at the time of exhumation prior to final burial. Copyright © 2015 John Wiley & Sons, Ltd.     

On Liaoximordellidae Fam. Nov. (Coleoptera, Insecta) from the Jurassic of Western Liaoning, China

A new insect family Liaoximordellidae (fam. nov.) has been named for a well-preserved specimen which was collected from the Upper Jurassic outcropping west of Daxinfangzi Village, Lingyuan County, Liaoning Province. The specimen can not be put into Mordellidae or Praemordellidae because it possesses some original and intermediate characters in morphology. It serves the study of mordellid evolution. Besides, the fossil group associated with the insect is important for the stratigraphic division of the Mesozoic in western Liaoning.     

Trace elements (REE) and isotopes (O,C, Sr) to characterize the metasomatic fluid sources: evidence from the skarn deposit (Fe,W, Cu) of Traversella (Ivrea,Italy)

The skarn complex of Traversella was formed at the expense of various rock types (calcic hornfels, gneiss, dolomitic marble) occurring in the contact aureole of the dioritic intrusion of Traversella (30±5 Ma). Application of phase equilibria has fixed the temperature of the primary stage of skarn formation between 550° C to 625° C. Similar applications indicate a larger range of temperature (525° C to 300° C) for the secondary stage. The different types of skarn (primary stage) are enriched in REE relative to the corresponding precursor rock (T.R.=126 ppm (protolith) to 228 ppm (inner zone) for the skarn on gneisses; T.R.=14 ppm to 71 ppm for the skarn on calcic hornfelses; T.R.=12 ppm to 200 ppm for the skarn on dolomitic marbles), but all the inner zones of these different types of skarn show a similar REE distribution with a slight LREE fractionation and no Eu anomaly. It is inferred that the primary metasomatic fluid has a parallel REE pattern. The oxygen isotope composition of water in equilibrium with the early stage of skarn at T=600° C ranges from 8.3 per mil to 8.9 per mil. At the beginning of the first hydroxylation stage (secondary stage), the fluid σ ¹⁸O remains in the range observed in the primary stage but within it, there is a sharp decrease from 8.0 per mil to 5.0 per mil. During the sulphidation stage, the fluid σ ¹⁸O decreases more gradually from 5.0 per mil to 3.0 per mil. The I _Sr of the early skarn silicates ranges from the values observed in the dolomitic marbles (0.70874 to 0.70971) to the I _Sr of the intrusion (0.70947 to 0.71064). During the secondary stage, there is a progressive increase of the minerals I _Sr up to 0.71372. The REE pattern of the primary metasomatic fluid does not put any precise constraint on the primary fluid source. On the other hand, both stable and radiogenic isotopes suggest that the early high-temperature metasomatic fluid was isotopically equilibrated with the dioritic intrusion. This implies that this early fluid is either exsolved from the crystallizing intrusion or a metamorphic water previously equilibrated with the intrusion. During the secondary stage, the replacement of the early anhydrous phases by hydrated parageneses is accompanied by the mixing with meteoric fluid as indicated by stable (σ ¹⁸O) and radiogenic (⁸⁷Sr/⁸⁶Sr) isotopes.     

Chemical and isotopic (C, O, Sr, Nd) characteristics of the Xiluvo carbonatite (central-western Mozambique)

Summary The Xiluvo complex of central Mozambique is made up of coarse- to fine-grained calciocarbonatites (sövites and alvikites), heavily altered lamprophyres and syenitic rocks that intruded the Precambrian basement ca. 120Ma ago. The carbonatites have fractionated rare earth element patterns (chondrite-normalized La/Yb=30–80) and markedly negative Rb, K, P, Zr and Ti anomalies in mantle-normalized incompatible element diagrams. The ¹⁸O (+7 to +8), ¹³C (–5), and the age-corrected ⁸⁷Sr/⁸⁶Sr (0.7032–0.7033) and ¹⁴³Nd/¹⁴⁴Nd (0.51263–0.51262) indicate an origin in the mantle. A few carbonatitic samples have higher ¹⁸O (+13), indicating interaction with high-¹⁸O crust or late-stage fluids. The chemical and isotopic compositions of the Xiluvo carbonatites and nearby carbonatites of similar age in Malawi indicate very similar sources, characterized by time-integrated depletion of Rb with respect to Sr and of Sm with respect to Nd. These characteristics point to a source similar in many respects to those of other East African carbonatites and to those of some ocean island basalts, with the additional influx of components possibly located in the African lithospheric mantle.     

Palaeosols in the Reading Beds (Paleocene) of Alum Bay, Isle of Wight, U.K.

Fossil soils occur in the Reading Beds of Alum Bay. All soils have hydromorphic characteristics, caused by either groundwater or stagnating pluvial water; some have illuviation of clay. The combination of bioturbation (striated burrows) and iron segregation may indicate that the Reading Beds in Alum Bay are of fluviomarine origin. The soils were formed in a warm climate with a marked dry season. They indicate a landscape with minor variations in surface level. The Reading Beds have clay mineral assemblages that are partly inherited and partly changed by soil formation. Some soil horizons might be used for stratigraphic correlation.     

Changes in the abundance of the seagrassesZostera marina L. (eelgrass) andRuppia maritima L. (widgeongrass) in San Diego, California, following and El Niño Event

Changes in environmental conditions can be accompanied by shifts in the distribution and abundances of organisms. When physical factors become unsuitable for growth ofZostera marina (eelgrass), which is a dominant seagrass species in North America, other more ruderal seagrass species, includingRuppia maritima (widgeongrass), often increase in abundance or replace the dominant species. We report the proliferation of widgeongrass into eelgrass beds in Mission Bay and San Diego Bay in San Diego, California, during the 1997 to 1998 El Niño Southern Oscillation (ENSO). Widgeongrass persisted in these eelgrass beds at least one year after a return to non-ENSO conditions and an increase in eelgrass density. We suggest that a warming of the water in two bays in San Diego by 1.5–2.5°C could result, in a permanent shift in the local seagrass vegetation from eelgrass to widgeongrass. This shift, could, have substantial ecosystem-level ramifications.