The volcanic history of Mars: High-resolution crater-based studies of the calderas of 20 volcanoes

Determining absolute surface ages for bodies in the Solar System is, at present, only possible for Earth and Moon with radiometric dating for both bodies and biologic proxies such as fossils for Earth. Relative ages through cratering statistics are recognized as one of the most reliable proxies for relative ages, calibrated by lunar geologic mapping and Apollo program sample returns. In this work, we have utilized the Mars Reconnaissance Orbiter’s ConTeXt Camera’s images which provide the highest resolution wide-scale coverage of Mars to systematically crater-age-date the calderas of 20 of Mars’ largest volcanoes in order to constrain the length of time over which these volcanoes - and major volcanic activity on the planet, by extension - were active. This constitutes the largest uniform and comprehensive research on these features to date, eliminating unknown uncertainties by multiple researchers analyzing different volcanoes with varied data and methods. We confirm previous results that Mars has had active volcanism throughout most of its history although it varied spatially and temporally, with the latest large-scale caldera activity ending approximately 150 ma in the Tharsis region. We find a transition from explosive to effusive eruption style occurring in the Hesperian, at approximately 3.5 Ga ago, though different regions of the planet transitioned at different times. Since we were statistically complete in our crater counts to sizes as small as ∼60 m in most cases, we also used our results to study the importance of secondary cratering and its effects on crater size-frequency distributions within the small regions of volcanic calderas. We found that there is no “golden rule” for the diameters secondaries become important in crater counts of martian surfaces, with one volcano showing a classic field of secondaries ∼2 crater diameters from the center of its primary but not affecting the size-frequency distribution, and another clearly showing an influence but from no obvious primary.     

Hydrovolcanic features on Mars: Preliminary observations from the first Mars year of HiRISE imaging

We provide an overview of features indicative of the interaction between water and lava and/or magma on Mars as seen by the High Resolution Imaging Science Experiment (HiRISE) camera during the Primary Science Phase of the Mars Reconnaissance Orbiter (MRO) mission. The ability to confidently resolve meter-scale features from orbit has been extremely useful in the study of the most pristine examples. In particular, HiRISE has allowed the documentation of previously undescribed features associated with phreatovolcanic cones (formed by the interaction of lava and groundwater) on rapidly emplaced flood lavas. These include “moats” and “wakes” that indicate that the lava crust was thin and mobile, respectively [Jaeger, W.L., Keszthelyi, L.P., McEwen, A.S., Dundas, C.M., Russel, P.S., 2007. Science 317, 1709-1711]. HiRISE has also discovered entablature-style jointing in lavas that is indicative of water-cooling [Milazzo, M.P., Keszthelyi, L.P., Jaeger, W.L., Rosiek, M., Mattson, S., Verba, C., Beyer, R.A., Geissler, P.E., McEwen, A.S., and the HiRISE Team, 2009. Geology 37, 171-174]. Other observations strongly support the idea of extensive volcanic mudflows (lahars). Evidence for other forms of hydrovolcanism, including glaciovolcanic interactions, is more equivocal. This is largely because most older and high-latitude terrains have been extensively modified, masking any earlier 1-10 m scale features. Much like terrestrial fieldwork, the prerequisite for making full use of HiRISE’s capabilities is finding good outcrops.     

Spectral evidence for zeolite in the dust on Mars

Spectral features observed in Mars Global Surveyor Thermal Emission Spectrometer data (∼1670-220 cm⁻¹) of martian surface dust provide clues to its mineralogy. An emissivity peak at ∼1630 cm⁻¹ is consistent with the presence of an H₂O-bearing mineral. This spectral feature can be mapped globally and shows a distribution related to the classical bright regions on Mars that are known to be dust covered. An important spectral feature at ∼830 cm⁻¹ present in a newly derived average spectrum of surface dust likely is a transparency feature arising from the fine particulate nature of the dust. Its shape and location are consistent with plagioclase feldspars and also zeolites, which essentially are the hydrous form of feldspar. The generally favored visible/near-infrared spectral analog for martian dust, JSC Mars-1 altered tephra, does not display the ∼830 cm⁻¹ feature. Zeolites commonly form from the interaction of low temperature aqueous fluids and volcanic glass in a variety of geologic settings. The combination of spectral features that are consistent with zeolites and the likelihood that Mars has (or had) geologic conditions necessary to produce them makes a strong case for recognizing zeolite minerals as likely components of the martian regolith.     

Emplacement of the youngest flood lava on Mars: A short, turbulent story

Recently acquired data from the High Resolution Imaging Science Experiment (HiRISE), Context (CTX) imager, and Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) onboard the Mars Reconnaissance Orbiter (MRO) spacecraft were used to investigate the emplacement of the youngest flood-lava flow on Mars. Careful mapping finds that the Athabasca Valles flood lava is the product of a single eruption, and it covers 250,000 km² of western Elysium Planitia with an estimated 5000-7500 km³ of mafic or ultramafic lava. Calculations utilizing topographic data enhanced with MRO observations to refine the dimensions of the channel system show that this flood lava was emplaced turbulently over a period of only a few to several weeks. This is the first well-documented example of a turbulently emplaced flood lava anywhere in the Solar System. However, MRO data suggest that this same process may have operated in a number of martian channel systems. The magnitude and dynamics of these lava floods are similar to the aqueous floods that are generally believed to have eroded the channels, raising the intriguing possibility that mechanical erosion by lava could have played a role in their incision.     

The morphologies of volcanic landforms at Central Elysium Planitia: Evidence for recent and fluid lavas on Mars

This paper focuses on physical parameters (flow rates and rheological properties) of lava flows observed in the Central Elysium Planitia (CEP) region of Mars. The flows are modeled as Newtonian fluids, using the Jeffrey's equation and the concept of Graetz number, or alternatively as Bingham fluids. In addition to these approaches, a theoretical model of the shape of shield volcanoes based on the solution for the porous flow of an unconfined aquifer is applied to 5 shields, providing independent quantifications of rheological variations between the shields. This analysis indicates that of the five volcanoes studied, two are partially buried by lava postdating their formation, a result which has been confirmed independently in one case by high resolution images. Our observations reveal that two types of lava flows may be found in the CEP region. The first group is composed of large lava flows with viscosities around ∼2.5×¹⁰⁵ Pa s or yield strengths ranging from 100 to 500 Pa. The second group includes small lava flows of the shield volcanoes and large leveed lava channels on the plains with viscosities below 10³ Pa s, or yield strengths less than 200 Pa. When compared with other volcanic regions on Mars investigated with similar approaches, these latter values are, at present, the lowest inferred for martian lava flows. Several hypotheses for the formation of these lavas are discussed in the context of CEP given that low viscosity can be the result of (1) high temperature, (2) low crystal content, (3) low Si abundance of the liquid phase, and/or (4) the presence of dissolved volatiles. Two scenarios are considered. In the first one, it is demonstrated that low viscosity lavas (of low silica content) can be produced in the context proposed by Schumacher and Breuer [Schumacher, S., Breuer, D., 2007. Geophys. Res. Lett. 34. L12202] for recent volcanism. However, geochemical maps derived from GRS measurements do not provide support for anomalously low silica concentrations in this region. In the second scenario, a water-rich magma is proposed, although arguments in favor of a water-rich mantle source below the CEP are not available at the present time.     

Identification of the Ca-sulfate bassanite in Mawrth Vallis, Mars

The region surrounding the Mawrth Vallis outflow channel on Mars hosts thick layered deposits containing diverse phyllosilicate minerals. Here we report detection of the Ca-sulfate bassanite on the outflow channel floor, requiring a more complex aqueous chemistry than previously inferred for this region. The sulfate-bearing materials underlie phyllosilicate-bearing strata, and provide an opportunity for testing proposed models of martian geochemical evolution with a future landed mission.     

The dispersal of pyroclasts from Apollinaris Patera, Mars: Implications for the origin of the Medusae Fossae Formation

The Medusae Fossae Formation (MFF) has long been thought to be of Amazonian age, but recent studies propose that a significant part of its emplacement occurred in the Hesperian and that many of the Amazonian ages represent modification (erosional and redepositional) ages. On the basis of the new formational age, we assess the hypothesis that explosive eruptions from Apollinaris Patera might have been the source of the Medusae Fossae Formation. In order to assess the likelihood of this hypothesis, we examine stratigraphic relationships between Apollinaris Patera and the MFF and analyze the relief of the MFF using topographic data. We predict the areal distribution of tephra erupted from Apollinaris Patera using a Mars Global Circulation Model (GCM) combined with a semi-analytical explosive eruption model for Mars, and compare this with the distribution of the MFF. We conclude that Apollinaris Patera could have been responsible for the emplacement of the Medusae Fossae Formation.     

A search for basaltic-to-intermediate glasses on Mars: Assessing martian crustal mineralogy

Multiple datasets have demonstrated that the crust of Mars is fundamentally basaltic. However, spectral libraries used to interrogate thermal infrared spectra of Martian dark regions through spectral deconvolution have heretofore lacked mafic glasses despite the importance of amorphous phases (or phases with amorphous-like spectral signatures) in Martian mineralogy. To establish the presence and importance of basaltic-to-intermediate glasses in Martian lithologies, we created five such glasses, obtained their thermal infrared spectra and included the spectra in a library used to deconvolve nine regional Thermal Emission Spectrometer spectra from Mars. We employed the nonnegative least squares (NNLS) deconvolution method, which yields deconvolved phase abundances and the uncertainties associated with those abundances. The basaltic-to-intermediate glasses do not appear in the deconvolution solutions, indicating they are not globally or regionally important phases. Because Martian igneous or impact processes are capable of basaltic-to-intermediate glass formation, the lack of such glasses in the deconvolved mineralogies suggests either the glasses did not form in detectable quantities or they (or their signatures) have been removed. The masking or replacement of basaltic-to-intermediate glasses through alteration is supported by the appearance in the deconvolution solutions of amorphous phases (e.g., silica-rich glasses, opal) or phases with amorphous-like spectral signatures (e.g., clays, zeolites) that commonly form through aqueous alteration of mafic glasses. The glasses may still be important to local-scale thermal infrared studies given the basaltic nature of Mars and the variety of local-scale lithologies detected by various missions. The regional mineralogies derived from the NNLS deconvolution analysis divide into five statistically separable groups, which provide insight into regional trends in mineralogy.     

Indications of brine related local seepage phenomena on the northern hemisphere of Mars

Springtime low albedo features, called Dark Dune Spots, on the seasonal frost covered dunes on Mars between 77°N and 84°N latitude have been analyzed. Two groups of these spots have been identified: “small” and “large” ones, where large spots have diameters above 4 m, and complex internal structure. From these “large” spots branching seepage-like features emanate and grow on the steep slopes. They show a characteristic sequence of changes: first only wind-blown features emanate from them, while later a bright circular and elevated ring forms, and dark seepage-features start from the spots. These streaks grow with a speed between 0.3 m/day and 7 m/day respectively, first only from the spots, later from all along the dune crest.During this “seepage period” the temperature is between 150 K and 180 K at a 3-9 km spatial resolution scale, indicating that CO₂ ice-free parts must be present at the observed dark spots. Around the receding northern seasonal CO₂ cap, an annulus of water ice lags behind, which is probably present in the spots too where the CO₂ frost has sublimated. Our model estimates show in the present work and in Kereszturi et al. (Kereszturi, A., Möhlmann, D., Berczi, Sz., Ganti, T., Kuti, A., Sik, A., Horvath, A. [2009b]. Icarus 201, 492-503) that the warming driven by solar insolation may produce not only interfacial water, but also bulk brines around the dune grains. The brine can support the movement of liquids and dune grains, enhances the sublimation of CO₂ frost, and produce the dark features, as well as liquid modifies the optical properties of the surface.Signs of movement of dune material after the total defrosting of the terrain is also visible but it is uncertain because of the limit of resolution. In our previous work (Kereszturi et al., 2009b) we showed that resembling seepage-like streaks at the southern hemisphere might have been formed by ephemeral interfacial water, as well as these northern features. Such wet environments may have astrobiological importance too.     

Discovery of jarosite within the Mawrth Vallis region of Mars: Implications for the geologic history of the region

Analysis of visible to near infrared reflectance data from the MRO CRISM hyperspectral imager has revealed the presence of an ovoid-shaped landform, approximately 3 by 5 km in size, within the layered terrains surrounding the Mawrth Vallis outflow channel. This feature has spectral absorption features consistent with the presence of the ferric sulfate mineral jarosite, specifically a K-bearing jarosite (KFe₃(SO₄)₂(OH)₆). Terrestrial jarosite is formed through the oxidation of iron sulfides in acidic environments or from basaltic precursor minerals with the addition of sulfur. Previously identified phyllosilicates in the Mawrth Vallis layered terrains include a basal sequence of layers containing Fe-Mg smectites and an upper set of layers of hydrated silica and aluminous phyllosilicates. In terms of its fine scale morphology revealed by MRO HiRISE imagery, the jarosite-bearing unit has fracture patterns very similar to that observed in Fe-Mg smectite-bearing layers, but unlike that observed in the Al-bearing phyllosilicate unit. The ovoid-shaped landform is situated in an east-west bowl-shaped depression superposed on a north sloping surface. Spectra of the ovoid-shaped jarosite-bearing landform also display an anomalously high 600 nm shoulder, which may be consistent with the presence of goethite and a 1.92 μm absorption which could indicate the presence of ferrihydrite. Goethite, jarosite, and ferrihydrite can be co-precipitated and/or form through transformation of schwertmannite, both processes generally occurring under low pH conditions (pH 2-4). To date, this location appears to be unique in the Mawrth Vallis region and could represent precipitation of jarosite in acidic, sulfur-rich ponded water during the waning stages of drying.     

Geomorphological evidence of water level changes in Nepenthes Mensae, Mars

In the western sector of Nepenthes Mensae, Mars, there are some geomorphological features that could be related to a standing water sheet in the area, such as fluvial terraces, deltas and shorelines. A detailed analysis of these features reveals two variations in water level, probably related to tectonic processes, as suggested by the existence of a fissural volcano at this site.     

Evidence for Hesperian impact-induced hydrothermalism on Mars

Several hydrated silicate deposits on Mars are observed within craters and are interpreted as excavated Noachian material. Toro crater (71.8°E, 17.0°N), located on the northern edge of the Syrtis Major Volcanic Plains, shows spectral and morphologic evidence of impact-induced hydrothermal activity. Spectroscopic observations were used to identify extensive hydrated silicate deposits, including prehnite, chlorites, smectites, and opaline material, a suite of phases that frequently results from hydrothermal alteration in terrestrial craters and also expected on Mars from geochemical modeling of hydrothermal environments. When combined with altimetry and high-resolution imaging data, these deposits appear associated predominantly with the central uplift and with portions of the northern part of the crater floor. Detailed geologic mapping of these deposits reveals geomorphic features that are consistent with hydrothermal activity that followed the impact event, including vent-like and conical mound structures, and a complex network of tectonic structures caused by fluid interactions such as fractures and joints. The crater age has been calculated from the cumulative crater size-frequency distributions and is found to be Early Hesperian. The evidence presented here provides support for impact-induced hydrothermal activity in Toro crater, that extends phyllosilicate formation processes beyond the Noachian era.     

Spectral reflectance properties of minerals exposed to simulated Mars surface conditions

A number of mineral species were exposed to martian surface conditions of atmospheric pressure and composition, temperature, and UV light regime, and their evolution was monitored using reflectance spectroscopy. The stabilities for different groups varied widely. Phyllosilicate spectra all showed measurable losses of interlayer H₂O, with some structural groups showing more rapid H₂O loss than others. Loss of OH from the phyllosilicates is not always accompanied by a change in metal-OH overtone absorption bands. OH-bearing sulfates, such as jarosite and alunite, show no measurable change in spectral properties, suggesting that they should be spectrally detectable on Mars on the basis of diagnostic absorption bands in the 0.4-2.5 μm region. Fe³⁺- and H₂O-bearing sulfates all showed changes in the appearance and/or reduction in depths of hydroxo-bridged Fe³⁺ absorption bands, particularly at 0.43 μm. The spectral changes were often accompanied by visible color changes, suggesting that subsurface sulfates exposed to the martian surface environment may undergo measurable changes in reflectance spectra and color over short periods of time (days to weeks). Organic-bearing geological materials showed no measurable change in CH related absorption bands, while carbonates and hydroxides also showed no systematic changes in spectral properties. The addition of ultraviolet irradiation did not seem to affect mineral stability or rate of spectral change, with one exception (hexahydrite). In some cases, spectral changes could be related to the formation of specific new phases. The data also suggest that hydrated minerals detected on Mars to date retain their diagnostic spectral properties that allow their unique identification.     

Sulfates and iron oxides in Ophir Chasma, Mars, based on OMEGA and CRISM observations

We investigate the sulfate and iron oxide deposits in Ophir Chasma, Mars, based on short-wave infrared data from the Compact Reconnaissance Imaging Spectrometer for Mars - CRISM and from the Observatoire pour la Minéralogie, l’Eau, les Glaces et l’Activité - OMEGA. Sulfates are detected mainly in two locations. In the valley between Ophir Mensa and the southern wall of Ophir Chasma, kieserite is found both within the slope of Ophir Mensa, and superposed on the basaltic wall of the chasm. Here, kieserite is unconformably overlain by polyhydrated sulfate deposits and iron oxides. Locally, jarosite and unidentified phases with absorptions at 2.21 μm or 2.23 μm are detected, which could be mixtures of jarosite and amorphous silica or other poorly crystalline phases.The second large sulfate-rich outcrop is found on the floor of the central valley. Although the same minerals are found here, polyhydrated sulfates, kieserite, iron oxides, and locally a possibly jarosite-bearing phase, this deposit is very distinct. It is not layered, almost horizontal, and located at a much lower elevation of below −4250 m. Kieserite superposes polyhydrated sulfate-rich deposits, and iron oxides form lags.The facies of sulfate formation remains unclear, and could be different for the two locations. A formation in a lake, playa or under a glacier is consistent with the mineralogy of the central valley and its flat, low-lying topography. This is not conceivable for the kieserite deposits observed south of Ophir Mensa. These deposits are observed over several thousands of meters of elevation, which would require a standing body of water several thousands of meters deep. This would have lead to much more pervasive sulfate deposits than observed. These deposits are therefore more consistent with evaporation of groundwater infiltrating into previously sulfate-free light-toned deposits. The overlying polyhydrated sulfates and other mineral phases are observed in outcrops on ridges along the slopes of the southern chasm wall, which are too exposed to be reached by groundwater. Here, a water supply from the atmosphere by rain, snow, fog or frost is more conceivable.     

Episodic flood inundations of the northern plains of Mars

Throughout the recorded history of Mars, liquid water has distinctly shaped its landscape, including the prominent circum-Chryse and the northwestern slope valleys outflow channel systems, and the extremely flat northern plains topography at the distal reaches of these outflow channel systems. Paleotopographic reconstructions of the Tharsis magmatic complex reveal the existence of an Europe-sized Noachian drainage basin and subsequent aquifer system in eastern Tharsis. This basin is proposed to have sourced outburst floodwaters that sculpted the outflow channels, and ponded to form various hypothesized oceans, seas, and lakes episodically through time. These floodwaters decreased in volume with time due to inadequate groundwater recharge of the Tharsis aquifer system. Martian topography, as observed from the Mars Orbiter Laser Altimeter, corresponds well to these ancient flood inundations, including the approximated shorelines that have been proposed for the northern plains. Stratigraphy, geomorphology, and topography record at least one great Noachian-Early Hesperian northern plains ocean, a Late Hesperian sea inset within the margin of the high water marks of the previous ocean, and a number of widely distributed minor lakes that may represent a reduced Late Hesperian sea, or ponded waters in the deepest reaches of the northern plains related to minor Tharsis- and Elysium-induced Amazonian flooding.     

Possible impact melt and debris flows at Tooting Crater, Mars

Candidate examples of impact melt flows and debris flows have been identified at Tooting crater, an extremely young (<2 Myr), 29 km diameter impact crater in Amazonis Planitia, Mars. Using HiRISE and CTX images, and stereo-derived digital elevation models derived from these images, we have studied the rim and interior wall of Tooting crater to document the morphology and topography of several flow features in order to constrain the potential flow formation mechanisms. Four flow types have been identified; including possible impact melt sheets and three types of debris flows. The flow features are all located within 2 km of the rim crest on the southern rim or lie on the southern interior wall of the crater ∼1500 m below the rim crest. Extensive structural failure has modified the northern half of the crater inner wall and we interpret this to have resulted in the destruction of any impact melt emplaced, as well as volatile-rich wall rock. The impact melt flows are fractured on the meter to decameter scale, have ridged, leveed lobes and flow fronts, and cover an area >6 km × 5 km on the southern rim. The debris flows are found on both the inner wall and rim of the crater, are ∼1-2 km in length, and vary from a few tens of meters to >300 m in width. These flows exhibit varying morphologies, from a channelized, leveed flow with arcuate ridges in the channel, to a rubbly flow with a central channel but no obvious levees. The flows indicate that water existed within the target rocks at the time of crater formation, and that both melt and fluidized sediment was generated during this event.     

Effect of Mars analogue dust deposition on the automated detection of calcite in visible/near-infrared spectra

We have developed an artificial neural net detector for use on board Mars rovers that correctly identifies calcite under Mars analogue dust (JSC Mars-1 regolith simulant) layers up to ∼100 μm thickness and 80% aerial coverage. Both the detector output and the band depth of the ∼2300 nm CO⁼₃ absorption are linearly related to the surface area of exposed calcite. This detector provides a means for rapid and robust automated recognition of calcite on Mars in areas of active aeolian erosion.     

Concentric crater fill in the northern mid-latitudes of Mars: Formation processes and relationships to similar landforms of glacial origin

Hypotheses accounting for the formation of concentric crater fill (CCF) on Mars range from ice-free processes (e.g., aeolian fill), to ice-assisted talus creep, to debris-covered glaciers. Based on analysis of new CTX and HiRISE data, we find that concentric crater fill (CCF) is a significant component of Amazonian-aged glacial landsystems on Mars. We present mapping results documenting the nature and extent of CCF along the martian dichotomy boundary over −30 to 90°E latitude and 20-80°N longitude. On the basis of morphological analysis we classify CCF landforms into “classic” CCF and “low-definition” CCF. Classic CCF is most typical in the middle latitudes of the analysis area (∼30-50°N), while a range of degradation processes results in the presence of low-definition CCF landforms at higher and lower latitudes. We evaluate formation mechanisms for CCF on the basis of morphological and topographic analyses, and interpret the landforms to be relict debris-covered glaciers, rather than ice-mobilized talus or aeolian units. We examine filled crater depth-diameter ratios and conclude that in many locations, hundreds of meters of ice may still be present under desiccated surficial debris. This conclusion is consistent with the abundance of “ring-mold craters” on CCF surfaces that suggest the presence of near-surface ice. Analysis of breached craters and distal glacial deposits suggests that in some locations, CCF-related ice was once several hundred meters higher than its current level, and has sublimated significantly during the most recent Amazonian. Crater counts on ejecta blankets of filled and unfilled craters suggests that CCF formed most recently between ∼60 and 300 Ma, consistent with the formation ages of other martian debris-covered glacial landforms such as lineated valley fill (LVF) and lobate debris aprons (LDA). Morphological analysis of CCF in the vicinity of LVF and LDA suggests that CCF is a part of an integrated LVF/LDA/CCF glacial landsystem. Instances of morphological continuity between CCF, LVF, and LDA are abundant. The presence of formerly more abundant CCF ice, coupled with the integration of CCF into LVF and LDA, suggests the possibility that CCF represents one component of the significant Amazonian mid-latitude glaciation(s) on Mars.     

Alteration of five organic compounds by glow discharge plasma and UV light under simulated Mars conditions

The Viking missions to Mars failed to detect any organic material in regolith samples. Since then, several removal mechanisms of organic material have been proposed. Two of these proposed methods are removal due to exposure to plasmas created in dust devils and exposure to UV irradiation. The experiments presented here were performed to identify similarities between the two potential removal mechanisms and to identify any compounds produced from these mechanisms that would have been difficult for the Viking instruments to detect. Five organic compounds, phenanthrene, octadecane, octadecanoic acid, decanophenone and benzoic acid, were exposed to a glow discharge plasma created in simulated martian atmospheres as might be present in dust devils, and to UV irradiation similar to that found at the surface of Mars. Glow discharge exposure was carried out in a chamber with 6.9 mbar pressure of a Mars like gas composed mostly of carbon dioxide. The plasma was characterized using emission spectroscopy and found to contain cations and excited neutral species including carbon dioxide, carbon monoxide, and nitrogen. UV irradiation experiments were performed in a Mars chamber which simulates the temperature, pressure, atmospheric composition, and UV fluence rates of equatorial Mars. The non-volatile residues left after each exposure were characterized by mass loss, infrared spectroscopy and high resolution mass spectrometry. Oxidized, higher molecular weight versions of the parent compounds containing carbonyl, hydroxyl and alkenyl functional groups were identified. The presence of these oxidized compounds suggests that searches for organic material in soils on Mars use instrumentation suitable for detection of compounds which contain the above functional groups. Discussions of possible reaction mechanisms are given.     

Silica-rich deposits and hydrated minerals at Gusev Crater, Mars: Vis-NIR spectral characterization and regional mapping

The Mars Exploration Rover (MER) Spirit has discovered surprisingly high concentrations of amorphous silica in soil and nodular outcrops in the Inner Basin of the Columbia Hills. In Pancam multispectral observations, we find that an absorption feature at the longest Pancam wavelength (1009 nm) appears to be characteristic of these silica-rich materials; however, spectral analyses of amorphous silica suggest that the ∼1009 nm spectral feature is not a direct reflection of their silica-rich nature. Based on comparisons with spectral databases, we hypothesize that the presence of H₂O or OH, either free (as water ice), adsorbed or bound in a mineral structure, is responsible for the spectral feature observed by Pancam. The Gertrude Weise soil, which is nearly pure opaline silica, may have adsorbed water cold-trapped on mineral grains. The origin of the ∼1009 nm Pancam feature observed in the silica-rich nodular outcrops may result from the presence of additional hydrated minerals (specific sulfates, halides, chlorides, sodium silicates, carbonates or borates). Using the ∼1009 nm feature with other spectral parameters as a “hydration signature” we have mapped the occurrence of hydrated materials along the extent of Spirit’s traverse across the Columbia Hills from West Spur to Home Plate (sols 155-1696). We have also mapped this hydration signature across large panoramic images to understand the regional distribution of materials that are spectrally similar to the silica-rich soil and nodular outcrops. Our results suggest that hydrated materials are common in the Columbia Hills.