Sublimation’s impact on temporal change of albedo dichotomy on Iapetus

Iapetus, one of the saturnian moons, has an extreme albedo contrast between the leading and trailing hemispheres. The origin of this albedo dichotomy has led to several hypotheses, however it remains controversial. To clarify the origin of the dichotomy, the key approach is to investigate the detailed distribution of the dark material. Recent studies of impact craters and surface temperature from Cassini spacecraft data implied that sublimation of H₂O ice can occur on Iapetus’ surface. This ice sublimation can change the albedo distribution on the moon with time.In this study, we evaluate the effect of ice sublimation and simulate the temporal change of surface albedo. We assume the dark material and the bright ice on the surface to be uniformly mixed with a certain volume fraction, and the initial albedo distribution to incorporate the dark material deposits on the surface. That is, the albedo at the apex is lowest and concentrically increases in a sinusoidal pattern. This situation simulates that dark materials existed around the Iapetus’ orbit billions of years ago, and the synchronously rotating Iapetus swept the material and then deposited it on its surface. The evolution of the surface albedo during 4.0 Gyr is simulated by estimating the surface temperature from the insolation energy on Iapetus including the effect of Saturn’s eccentricity and Iapetus’ obliquity precession, and evaluating the sublimation rate of H₂O ice from the Iapetus’ surface.As a result, we found that the distribution of the surface albedo changed dramatically after 4.0 Gyr of evolution. The sublimation has three important effects on the resultant surface albedo. First, the albedo in the leading hemisphere has significantly decreased to approach the minimum value. Second, the albedo distribution has been elongated along the equator. Third, the edge of the low albedo region has become clear. Considering the effect of ice sublimation, the current albedo distribution can be reconstructed from the sinusoidal albedo distribution, suggesting the apex-antapex cratering asymmetry as a candidate for the origin of the albedo dichotomy. From the model analysis, we obtained an important aspect that the depth of the turn-over layer where the darkening process proceeded for 4 Gyr should be an order of 10 cm, which is consistent with evaluation from the Cassini radar observations.     

New Cassini RADAR results for Saturn’s icy satellites

Cassini radar tracks on Saturn’s icy satellites through the end of the Prime Mission in 2008 have increased the number of radar albedo estimates from 10 (Ostro et al., 2006) to 73. The measurements sample diverse subradar locations (and for Dione, Rhea, and Iapetus almost always use beamwidths less than half the target angular diameters), thereby constraining the satellites’ global radar albedo distributions. The echoes result predominantly from volume scattering, and their strength is thus strongly sensitive to ice purity and regolith maturity. The combination of the Cassini data set and Arecibo 13-cm observations of Enceladus, Tethys, Dione, Rhea (Black et al., 2007), and Iapetus (Black et al., 2004) discloses an unexpectedly complex pattern of 13-to-2-cm wavelength dependence. The 13-cm albedos are generally smaller than 2-cm albedos and lack the correlation seen between 2-cm and optical geometric albedos. Enceladus and Iapetus are the most interesting cases. We infer from hemispheric albedo variations that the E-ring has a prominent effect on the 13-cm radar “lightcurve”. The uppermost trailing-side regolith is too fresh for meteoroid bombardment to have developed larger-scale heterogeneities that would be necessary to elevate the 13-cm radar albedo, whereas all of Enceladus is clean and mature enough for the 2-cm albedo to be uniformly high. For, Iapetus, the 2-cm albedo is strongly correlated with optical albedo: low for the optically dark, leading-side material and high for the optically bright, trailing-side material. However, Iapetus’ 13-cm albedo values show no significant albedo dichotomy and are several times lower than 2-cm values, being indistinguishable from the weighted mean of 13-cm albedos for main-belt asteroids, 0.15 ± 0.10. The leading side’s optically dark contaminant must be present to depths of at least one to several decimeters, so 2-cm albedos can mimic the optical dichotomy; however, it does not have to extend any deeper than that. The fact that both hemispheres of Iapetus look Asteroid-like at 13 cm means that coherent backscattering itself is not nearly as effective as it is at 2 cm. Since Iapetus’ entire surface is mature regolith, the wavelength dependence must involve composition, not structure. Either the composition is a function of depth everywhere (with electrical loss much greater at depths greater than a decimeter or two), or the intrinsic electrical loss of some pervasive constituent is much higher at 13 cm than at 2 cm. Ammonia is a candidate for such a contaminant. If ammonia’s electrical properties do not depend on frequency, and if ammonia is globally much less abundant within the upper one or two decimeters than at greater depths, then coherent backscattering would effectively be shut down at 13 cm, explaining the Asteroid-like 13-cm albedo.     

Production and detection of carbon dioxide on Iapetus

Cassini VIMS detected carbon dioxide on the surface of Iapetus during its insertion orbit. We evaluated the CO₂ distribution on Iapetus and determined that it is concentrated almost exclusively on Iapetus’ dark material. VIMS spectra show a 4.27-μm feature with an absorption depth of 24%, which, if it were in the form of free ice, requires a layer 31 nm thick. Extrapolating for all dark material on Iapetus, the total observable CO₂ would be 2.3 × 10⁸ kg.Previous studies note that free CO₂ is unstable at 10 AU over geologic timescales. Carbon dioxide could, however, be stable if trapped or complexed, such as in inclusions or clathrates. While complexed CO₂ has a lower thermal volatility, loss due to photodissociation by UV radiation and gravitational escape would occur at a rate of 2.6 × 10⁷ kg year⁻¹. Thus, Iapetus’ entire inventory of surface CO₂ could be lost within a few decades.The high loss/destruction rate of CO₂ requires an active source. We conducted experiments that generated CO₂ by UV radiation of simulated icy regolith under Iapetus-like conditions. The simulated regolith was created by flash-freezing degassed water, crushing it into sub-millimeter sized particles, and then mixing it with isotopically labeled amorphous carbon (¹³C) dust. These samples were placed in a vacuum chamber and cooled to temperatures between 50 K and 160 K. The samples were irradiated with UV light, and the products were measured using a mass spectrometer, from which we measured ¹³CO₂ production at a rate of 2.0 × 10¹² mol s⁻¹. Extrapolating to Iapetus and adjusting for the solar UV intensity and Iapetus’ surface area, we calculated that CO₂ production for the entire surface would be 1.1 × 10⁷ kg year⁻¹, which is only a factor of two less than the loss rate. As such, UV photochemical generation of CO₂ is a plausible source of the detected CO₂.     

Iapetus surface variability revealed from statistical clustering of a VIMS mosaic: The distribution of CO2

We present a detailed study of an Iapetus mosaic of VIMS data with high spatial resolution (0.5 × 0.5° or ∼6.4 km/pixel). The spectra were taken in August 2007 and provide the highest VIMS spatial resolution data for this object during Cassini’s primary mission. We analyze this set of data using a statistical clustering approach to reduce the analysis of a large number of data (∼10⁴ spectra from 0.35 to 5.10 μm) to the study of seven representative groups accounting for 99.6% of the surface covered by the original sample. We analyze the spectral absorption bands in the spectra of the different clusters indicative of different composition over the observed surface. We find coherence between the distribution of the clusters and the geographical features on the surface. We give special attention to the study of the water ice and CO₂ bands. We find that CO₂ is widespread over the entire surface being studied, including the bright and dark areas on Iapetus’ surface, and is probably trapped at the molecular level with other materials. The strength of the CO₂ band in the areas where both, H₂O- and carbon-bearing materials exist, gives support to the hypothesis that this volatile is formed on the surface of Iapetus as a product of irradiation of these two components. Finally, we also compare the Iapetus CO₂ with that on other satellites confirming, that there are evident differences on the center, depth and width of the band on Iapetus and Phoebe, where CO₂ has been suggested to be endogenous.     

Saturn’s icy satellites investigated by Cassini-VIMS: II. Results at the end of nominal mission

We report the detailed analysis of the spectrophotometric properties of Saturn’s icy satellites as derived by full-disk observations obtained by visual and infrared mapping spectrometer (VIMS) experiment aboard Cassini. In this paper, we have extended the coverage until the end of the Cassini’s nominal mission (June 1st 2008), while a previous paper (Filacchione, G., and 28 colleagues [2007]. Icarus 186, 259-290, hereby referred to as Paper I) reported the preliminary results of this study.During the four years of nominal mission, VIMS has observed the entire population of Saturn’s icy satellites allowing us to make a comparative analysis of the VIS-NIR spectral properties of the major satellites (Mimas, Enceladus, Tethys, Dione, Rhea, Hyperion, Iapetus) and irregular moons (Atlas, Prometheus, Pandora, Janus, Epimetheus, Telesto, Calypso, Phoebe). The results we discuss here are derived from the entire dataset available at June 2008 which consists of 1417 full-disk observations acquired from a variety of distances and inclinations from the equatorial plane, with different phase angles and hemispheric coverage. The most important spectrophotometric indicators (as defined in Paper I: I/F continua at 0.55 μm, 1.822 μm and 3.547 μm, visible spectral slopes, water and carbon dioxide bands depths and positions) are calculated for each observation in order to investigate the disk-integrated composition of the satellites, the distribution of water ice respect to “contaminants” abundances and typical regolith grain properties. These quantities vary from the almost pure water ice surfaces of Enceladus and Calypso to the organic and carbon dioxide rich Hyperion, Iapetus and Phoebe. Janus visible colors are intermediate between these two classes having a slightly positive spectral slope. These results could help to decipher the origins and evolutionary history of the minor moons of the Saturn’s system. We introduce a polar representation of the spectrophotometric parameters as function of the solar phase angle (along radial distance) and of the effective longitude interval illuminated by the Sun and covered by VIMS during the observation (in azimuth) to better investigate the spatial distribution of the spectrophotometric quantities across the regular satellites hemispheres. Finally, we report the observed spectral positions of the 4.26 μm band of the carbon dioxide present in the surface material of three outermost moons Hyperion, Iapetus and Phoebe.     

Tectonics on Iapetus: Despinning, respinning, or something completely different?

Saturn’s moon Iapetus is unique in that it has apparently despun while retaining a substantial equatorial bulge. Stresses arising from such a non-hydrostatic shape should in principle cause surface deformation (tectonics). As part of a search for such a tectonic signature, lineaments (linear surface features) on Iapetus were mapped on both its bright and dark hemispheres. Lineament orientations were then compared to model stress patterns predicted for spin-down from a rotation period of 16.5 h (or less) to its present synchronous period, and for a range of lithospheric thicknesses. Many lineaments are straight segments of crater rimwalls, which may be faults or joints reactivated during complex crater collapse. Most striking are several large troughs on the bright, trailing hemisphere. These troughs appear to be extensional and are distinctive on that hemisphere, because the interior floors and walls of the troughs contain dark material. Globally, no specific evidence of strike slip or thrust offsets are seen, but this could be due to the age and degraded nature of any such features. We find that observed lineament orientations do not correlate with predicted patterns due to despinning on either hemisphere (the equatorial ridge was specifically excluded from this analysis, and is considered separately). Modest evidence for preferred orientations ±40° from north could be construed as consistent with respinning, which is not necessarily far-fetched. Assuming the rigidity of unfractured ice, predicted maximum lithospheric differential stresses from despinning range from ∼1 MPa to ∼160 MPa for the elastic spheroid and thin lithosphere limits, respectively (although it is only for thicker elastic lithospheres that we expect a nonhydrostatic state to be maintained over geologic time against lithospheric failure). The tectonic signature of despinning may have been obscured over time because the surface of Iapetus is very ancient, Iapetus’ thick lithosphere may have inhibited the full tectonic expression of despinning, or both. Several prominent lineaments strike E–W, and are thus parallel to the equatorial ridge (though not physically close to it), but a tectonic or volcanic origin for the ridge is highly problematic.     

Thermal inertia and bolometric Bond albedo values for Mimas, Enceladus, Tethys, Dione, Rhea and Iapetus as derived from Cassini/CIRS measurements

Spectra taken by Cassini’s Composite Infrared Spectrometer (CIRS) between 10 and 600 cm⁻¹ (17-1000 μm) of surface thermal emission of Mimas, Enceladus, Tethys, Dione, Rhea and Iapetus have been used to derive the thermal inertia and bolometric Bond albedo values. Only an upper limit for the bolometric Bond albedo of Iapetus’ dark leading side could be determined due to the insensitivity of the thermal model to albedo when albedos are very low. The thermal inertia in this region however is better constrained. The CIRS coverage of Enceladus is extensive enough that the latitudinal variation in these values from 60°S to 70°N has been determined in 10° wide bins. The bolometric Bond albedos determined here are consistent with literature values which show the surface of the saturnian icy moons to be covered in ice contaminated to varying degrees. The thermal inertia of the moons is shown to be in the range 9-, approximately 2-6 times lower than that of the Galilean satellites, implying a less well consolidated and more porous surface. The thermal inertias of Iapetus and Phoebe are somewhat higher, suggesting that the very low thermal inertias of satellites from Rhea inwards may be related to their probable coating of E-ring material. Latitudinal variations on the surface of Enceladus show that the bolometric Bond albedo and thermal inertia increase towards the active plume source at the south pole.     

The albedo dichotomy of Iapetus measured at UV wavelengths

The dramatic hemispheric dichotomy in albedo displayed by Saturn's moon Iapetus has intrigued astronomers for centuries. Here we report on far-ultraviolet observations of Iapetus' bright and dark terrains from Cassini. We compare the reflectance spectra of Iapetus's dark terrain, Hyperion and Phoebe and find that both Phoebe and Hyperion are richer in water ice than Iapetus' dark terrain. Spectra of the lowest latitudes of the dark terrain display the diagnostic water ice absorption feature; water ice amounts increase within the dark material away from the apex (at 90° W longitude, the center of the dark leading hemisphere), consistent with thermal segregation of water ice. The water ice in the darkest, warmest low latitude regions is not expected to be stable and may be a sign of ongoing or recent emplacement of the dark material from an exogenic source.     

Correlations between VIMS and RADAR data over the surface of Titan: Implications for Titan’s surface properties

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples.In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters.On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.     

The dark side of Iapetus

This paper presents new photometric and spectrophotometric observations of the dark (leading) hemisphere of Saturn's satellite Iapetus. Spectrophotometry from 0.3–1.0 um (May 1979) shows the dark hemisphere to be very red, similar to a few asteroids and the Moon, but with no spectral features attributable to olivine or pyroxene. Near-infrared spectrophometry in the regions 1.4–2.5 um (May 1981) and 3.0–3.8 um (February 1981) reveals water ice absorption bands, probably resulting from the polar caps intruding onto the dark hemisphere. The reflectance of Iapetus is unlike that of carbonaceous chondrites or C-type asteroids and most closely resembles the reflectance (and low albedo) of carbonaceous (organic) residue from the Murchison C2 carbonaceous chondrite. The Murchison material has the same red slope and a probable spectral feature near 0.6 um seen in Iapetus data. Three hypotheses for the formation of the dark hemisphere are discussed in light of the observational data. The favored hypothesis is that debris from Phoebe or other unknown outer satellites of Saturn impacts the dark hemisphere of Iapetus as Poynting-Robertson drag causes the debris to spiral toward Saturn. The high-velocity impacts preferentially remove ice from the satellite's surface, causing enrichment of included carbonaceous material intrinsic to Iapetus. The reflectance of Phoebe itself is significantly different from that of Iapetus, suggesting that relatively little Phoebe debris lies on the dark hemisphere. There remains the possibility that the impacting debris originates from another body of composition similar to the Murchison residue and that this material is exposed on the surface of Iapetus.     

Topographic modeling of Phoebe using Cassini images

High-resolution Cassini stereo images of Saturn's moon Phoebe have been used to derive a regional digital terrain model (DTM) and an orthoimage mosaic of the surface. For DTM-control a network of 130 points measured in 14 images (70-390 m/pixel resolution) was established which was simultaneously used to determine the orientation of the spin-axis. The J2000 spin-axis was found at Dec=78.0°±0.1° and RA=356.6°±0.3°, substantially different from the former Voyager solution. The control points yield a mean figure radius of 107.2 km with RMS residuals of 6.2 km demonstrating the irregular shape of this body. The DTM was computed from densely spaced conjugate image points determined by methods of digital image correlation. It has a horizontal resolution of 1-2 km and vertical accuracies in the range 50-100 m. It is limited in coverage, but higher in resolution than the previously derived global shape model of Phoebe [Porco et al., 2005. Cassini imaging science: initial results on Phoebe and Iapetus. Science 307, 1237-1242] and allows us to study the morphology of the surface in more detail. There is evidence for unconsolidated material from a steep and smooth slope at the rim of a 100 km impact feature. There are several conically shaped craters on Phoebe, which may hint at highly porous and low compaction material on the surface.     

High-Resolution 0.33-0.92 μm Spectra of Iapetus, Hyperion, Phoebe, Rhea, Dione, and D-Type Asteroids: How Are They Related?

New high-resolution spectra in the 0.33 to 0.92 μm range of Iapetus, Hyperion, Phoebe, Dione, Rhea, and three D-type asteroids were obtained on the Palomar 200-inch telescope and the double spectrograph. The spectra of Hyperion and the low-albedo hemisphere of Iapetus can both be closely matched by a simple model that is the linear admixture of the spectrum of a medium-sized, high-albedo icy saturnian satellite and D-type material. Our results support an exogenous origin to the dark material on Iapetus; furthermore, this material may share a common origin and a similar means of transport with material on the surface of Hyperion. The recently discovered retrograde satellites of Saturn (Gladman et al., Nature412, 163-166) may be the source of this material. The leading sides of Callisto and the Uranian satellites may be subjected to a similar alteration mechanism as that of Iapetus: accretion of low-albedo dust originating from outer retrograde satellites. Phoebe does not appear to be related to either Iapetus or Hyperion. Separate spectra of the two hemispheres of Phoebe show no identifiable global compositional differences.     

Eight-color photometry of Hyperion,Iapetus, and Phoebe

Eight-color spectrophotometry was obtained of Phoebe, Hyperion, and the dark side of Iapetus. Our observed V magnitudes and Voyager-derived diameters yield geometric albedos of 0.07 for Iapetus (with some bright-side contamination), 0.06 for Phoebe, and limits of 0.19 to 0.25 for Hyperion (using the satellite's maximum and minimum dimensions, respectively). Hyperion and Iapetus have quite reddish spectra similar to each other and the spectra of D-type asteroids. Hyperion, however, has a much higher albedo than the dark side of Iapetus or any D-type asteroid measured to date. The mean spectrum of Phoebe is much flatter, with a broad absorption feature near 1 μm. Therefore the surface materials of Phoebe and the dark side of Iapetus are optically quite different, a result that constraints the possible modes of interaction between Phoebe and the other two satellites.     

Transient surface liquid in Titan’s polar regions from Cassini

Cassini RADAR images of Titan’s south polar region acquired during southern summer contain lake features which disappear between observations. These features show a tenfold increases in backscatter cross-section between images acquired one year apart, which is inconsistent with common scattering models without invoking temporal variability. The morphologic boundaries are transient, further supporting changes in lake level. These observations are consistent with the exposure of diffusely scattering lakebeds that were previously hidden by an attenuating liquid medium. We use a two-layer model to explain backscatter variations and estimate a drop in liquid depth of approximately 1-m-per-year. On larger scales, we observe shoreline recession between ISS and RADAR images of Ontario Lacus, the largest lake in Titan’s south polar region. The recession, occurring between June 2005 and July 2009, is inversely proportional to slopes estimated from altimetric profiles and the exponential decay of near-shore backscatter, consistent with a uniform reduction of 4 ± 1.3 m in lake depth.Of the potential explanations for observed surface changes, we favor evaporation and infiltration. The disappearance of dark features and the recession of Ontario’s shoreline represents volatile transport in an active methane-based hydrologic cycle. Observed loss rates are compared and shown to be consistent with available global circulation models. To date, no unambiguous changes in lake level have been observed between repeat images in the north polar region, although further investigation is warranted. These observations constrain volatile flux rates in Titan’s hydrologic system and demonstrate that the surface plays an active role in its evolution. Constraining these seasonal changes represents the first step toward our understanding of longer climate cycles that may determine liquid distribution on Titan over orbital time periods.     

Impact cratering records of the mid-sized, icy saturnian satellites

Resolution of Voyager 1 and 2 images of the mid-sized, icy saturnian satellites was generally not much better than 1 km per line pair, except for a few, isolated higher resolution images. Therefore, analyses of impact crater distributions were generally limited to diameters (D) of tens of kilometers. Even with the limitation, however, these analyses demonstrated that studying impact crater distributions could expand understanding of the geology of the saturnian satellites and impact cratering in the outer Solar System. Thus to gain further insight into Saturn’s mid-sized satellites and impact cratering in the outer Solar System, we have compiled cratering records of these satellites using higher resolution CassiniISS images. Images from Cassini of the satellites range in resolution from tens m/pixel to hundreds m/pixel. These high-resolution images provide a look at the impact cratering records of these satellites never seen before, expanding the observable craters down to diameters of hundreds of meters. The diameters and locations of all observable craters are recorded for regions of Mimas, Tethys, Dione, Rhea, Iapetus, and Phoebe. These impact crater data are then analyzed and compared using cumulative, differential and relative (R) size-frequency distributions. Results indicate that the heavily cratered terrains on Rhea and Iapetus have similar distributions implying one common impactor population bombarded these two satellites. The distributions for Mimas and Dione, however, are different from Rhea and Iapetus, but are similar to one another, possibly implying another impactor population common to those two satellites. The difference between these two populations is a relative increase of craters with diameters between 10 and 30 km and a relative deficiency of craters with diameters between 30 and 80 km for Mimas and Dione compared with Rhea and Iapetus. This may support the result from Voyager images of two distinct impactor populations. One population was suggested to have a greater number of large impactors, most likely heliocentric comets (Saturn Population I in the Voyager literature), and the other a relative deficiency of large impactors and a greater number of small impactors, most likely planetocentric debris (Saturn Population II). Meanwhile, Tethys’ impact crater size-frequency distribution, which has some similarity to the distributions of Mimas, Dione, Rhea, and Iapetus, may be transitional between the two populations. Furthermore, when the impact crater distributions from these older cratered terrains are compared to younger ones like Dione’s smooth plains, the distributions have some similarities and differences. Therefore, it is uncertain whether the size-frequency distribution of the impactor population(s) changed over time. Finally, we find that Phoebe has a unique impact crater distribution. Phoebe appears to be lacking craters in a narrow diameter range around 1 km. The explanation for this confined “dip” at D = 1 km is not yet clear, but may have something to do with the interaction of Saturn’s irregular satellites or the capture of Phoebe.     

Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

Global contraction of planetary bodies due to despinning: Application to Mercury and Iapetus

We extend previous work on the global tectonic patterns generated by despinning with a self-consistent treatment of the isotropic despinning contraction that has been ignored. We provide simple analytic approximations that quantify the effect of the isotropic despinning contraction on the global shape and tectonic pattern. The isotropic despinning contraction of Mercury is ∼93 m (T/1 day)⁻², where T is the initial rotation period. If we take into account both the isotropic contraction and the degree-2 deformations associated with despinning, the preponderance of compressional tectonic features on Mercury’s surface requires an additional isotropic contraction ?1 km (T/1 day)⁻², presumably due to cooling of the interior and growth of the solid inner core. The isotropic despinning contraction of Iapetus is ∼9 m (T/16 h)⁻², and it is not sensitive to the presence of a core or the thickness of the elastic lithosphere. The tectonic pattern expected for despinning, including the isotropic contraction, does not explain Iapetus’ ridge. Furthermore, the ridge remains unexplained with the addition of any isotropic compressional stresses, including those generating by cooling.     

Compositional mapping of Saturn's satellite Dione with Cassini VIMS and implications of dark material in the Saturn system

Cassini VIMS has obtained spatially resolved imaging spectroscopy data on numerous satellites of Saturn. A very close fly-by of Dione provided key information for solving the riddle of the origin of the dark material in the Saturn system. The Dione VIMS data show a pattern of bombardment of fine, sub-0.5-μm diameter particles impacting the satellite from the trailing side direction. Multiple lines of evidence point to an external origin for the dark material on Dione, including the global spatial pattern of dark material, local patterns including crater and cliff walls shielding implantation on slopes facing away from the trailing side, exposing clean ice, and slopes facing the trailing direction which show higher abundances of dark material. Multiple spectral features of the dark material match those seen on Phoebe, Iapetus, Hyperion, Epimetheus and the F-ring, implying the material has a common composition throughout the Saturn system. However, the exact composition of the dark material remains a mystery, except that bound water and, tentatively, ammonia are detected, and there is evidence both for and against cyanide compounds. Exact identification of composition requires additional laboratory work. A blue scattering peak with a strong UV-visible absorption is observed in spectra of all satellites which contain dark material, and the cause is Rayleigh scattering, again pointing to a common origin. The Rayleigh scattering effect is confirmed with laboratory experiments using ice and 0.2-μm diameter carbon grains when the carbon abundance is less than about 2% by weight. Rayleigh scattering in solids is also confirmed in naturally occurring terrestrial rocks, and in previously published reflectance studies. The spatial pattern, Rayleigh scattering effect, and spectral properties argue that the dark material is only a thin coating on Dione's surface, and by extension is only a thin coating on Phoebe, Hyperion, and Iapetus, although the dark material abundance appears higher on Iapetus, and may be locally thick. As previously concluded for Phoebe, the dark material appears to be external to the Saturn system and may be cometary in origin. We also report a possible detection of material around Dione which may indicate Dione is active and contributes material to the E-ring, but this observation must be confirmed.     

Keck adaptive optics images of Jupiter’s north polar cap and Northern Red Oval

We present observations at near-infrared wavelengths (1-5 μm) of Jupiter’s north polar region and Northern Red Oval (NN-LRS-1). The observations were taken with the near-infrared camera NIRC2 coupled to the adaptive optics system on the 10-m W.M. Keck Telescope on UT 21 August 2010. At 5-μm Jupiter’s disk reveals considerable structure, including small bright rings which appear to surround all small vortices. It is striking, though, that no such ring is seen around the Northern Red Oval. In de Pater et al. [2010a. Icarus 210, 742-762], we showed that such rings also exist around all small vortices in Jupiter’s southern hemisphere, and are absent around the Great Red Spot and Red Oval BA. We show here that the vertical structure and extent of the Northern Red Oval is very similar to that of Jupiter’s Red Oval BA. These new observations of the Northern Red Oval, therefore, support the idea of a dichotomy between small and large anticyclones, in which ovals larger than about two Rossby deformation radii do not have 5-μm bright rings. In de Pater et al. [2010a. Icarus 210, 742-762], we explained this difference in terms of the secondary circulations within the vortices. We further compare the brightness distribution of our new 5-μm images with previously published radio observations of Jupiter, highlighting the depletion of NH₃ gas over areas that are bright at 5 μm.     

Hydrocarbons on Saturn's satellites Iapetus and Phoebe

Material of low geometric albedo (pV?0.1) is found on many objects in the outer Solar System, but its distribution in the saturnian satellite system is of special interest because of its juxtaposition with high-albedo ice. In the absence of clear, diagnostic spectral features, the composition of this low-albedo (or “dark”) material is generally inferred to be carbon-rich, but the form(s) of the carbon is unknown. Near-infrared spectra of the low-albedo hemisphere of Saturn's satellite Iapetus were obtained with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft at the fly-by of that satellite of 31 December 2004, yielding a maximum spatial resolution on the satellite's surface of ∼65 km. The spectral region 3-3.6 μm reveals a broad absorption band, centered at 3.29 μm, and concentrated in a region comprising about 15% of the low-albedo surface area. This is identified as the CH stretching mode vibration in polycyclic aromatic hydrocarbon (PAH) molecules. Two weaker bands attributed to CH₂ stretching modes in aliphatic hydrocarbons are found in association with the aromatic band. The bands most likely arise from aromatic and aliphatic units in complex macromolecular carbonaceous material with a kerogen- or coal-like structure, similar to that in carbonaceous meteorites. VIMS spectra of Phoebe, encountered by Cassini on 11 June 2004, also show the aromatic hydrocarbon band, although somewhat weaker than on Iapetus. The origin of the PAH molecular material on these two satellites is unknown, but PAHs are found in carbonaceous meteorites, cometary dust particles, circumstellar dust, and interstellar dust.