Chemical composition of late Pleistocene-Holocene pelagic sediments in Gakkel Ridge,Arctic Ocean

The paper presents data on the chemical composition of Late Pleistocene-Holocene sediments in the Gakkel Ridge according to data on sediment core PS 70/306-3, offers a hypothetical litho-stratigraphic model, and provides data on chemo-stratigraphic horizons distinguished based on the distribution of carbonates, organic carbon, metals (Fe, Mn, Cu, Zn, Co, Ni, V, Pb), As, and P in the core. Chemical transformations of sediments at the redox barrier are discussed, along with relations between the composition of the sediments and the facies sedimentation conditions.     

Composition and formation of laminated sediments in Diss Mere, Norfolk, England

The chemical and biological composition of laminated lake-sediments deposited between about 2,500 and 5,500 years B.P. in Diss Mere, Norfolk, England is described. The distribution of Ca, Fe, S, and Si in pale and dark laminae is established by energy-dispersive X-ray microanalysis. The pale laminae consist primarily of calcium carbonate and the dark layers contain mainly Fe, S, Si, and dark organic material. The diatom composition of 16 individual light and dark laminae shows no consistent differences between light and dark layers. There are, however, higher frequencies of chrysophycean cysts in seven of the eight dark layers, suggesting these layers were deposited in late summer or fall. Pollen analyses of the pale and dark layers show that pollen percentages of early-flowering trees and shrubs are highest in the dark laminae and that pollen values of late-flowering plants are highest in the pale layers. The biological data indicate that the pale layers were formed in the late spring and early summer, whereas the dark laminae were deposited in late summer, fall, winter, and the early spring. Seasonal supply of CaCO₃ was the major variable responsible for couplet formation.     

Identification of perylene in sediments: Occurrence and diagenetic evolution

Perylene and penta-aromatic hydrocarbons were determined in sediments as part of a study that was dedicated to the aquatic ecosystem of Elelenwo Creek (Southern Nigeria) in order to carry out a critical corroboration of occurrence and diagenetic evolution of perylene in the sediments of the creek. The results show that the annual mean levels of Benzo [g, h, i] Perylene ranged from 209.00–245.28 ?g/kg dry weight at the various stations sampled. Meanwhile, Station 3 recorded the highest mean level of 245.28 ?g/kg dry weight. The observed values for total penta-aromatic hydrocarbons were high (787.00–1154.36?g/kg dry weight) in all the stations sampled. In addition, the highest mean value of 1154.36?g/kg dry weight was again recorded at station 3 for the penta-aromatic hydrocarbons. One origin index or concentration ratio of Ip/Ip+BghiP was also used to evaluate the suitability of the penta-aromatic hydrocarbons as a tracer to distinguish between contaminations arising from different sources. The values for the sampling stations therefore ranged from 0.41 to 0.43. A critical appraisal of the PAH index, consequently, suggested that petroleum combustion is the major penta-aromatic hydrocarbon source in sediments of the creek. The PAH group profile shows that perylene was high in the sediments and would pose apparent effects in fauna. The high concentration of perylene in the sediments was also indicative of an in situ biogenic derivation. Furthermore, a concentration of perylene > 10 % of total penta-aromatic hydrocarbons established a credible diagenetic origin.     

Alkane and PAH biomarkers as tracers of terrigenous organic carbon in Arctic Ocean sediments

We present the first sedimentary biomarker study encompassing the entire Arctic Ocean. A large data set of organic markers for terrigenous, petroleum and combustion inputs [alkanes, hopanes and steranes, parent and alkyl polycyclic aromatic hydrocarbons (PAHs)] is examined for patterns in space and time using principal components analysis (PCA) and partial least squares (PLS). Biomarker patterns reveal the central Arctic Ocean basin sediments to be compositionally distinct from those of the Mackenzie River/Beaufort Sea and Barents Sea, but similar to those of the Laptev Sea. PAH distributions reflected in PAH ratios and PCA projections demonstrate that Arctic Ocean sediment is dominated by natural inputs to the extent that anthropogenic combustion PAHs are not significant. We find only modest changes between the glacial and post-glacial sediments for atmospherically transported hydrocarbon biomarkers, while particle associated biomarkers were captured strongly at basin edges during the glacial period, and much more evenly transported across basins during the post-glacial period. The orders of magnitude decreases in particle associated petrogenic alkanes and PAHs in central basins during glacial times, coupled with the uniformity of most petrogenic biomarker parameters for most basin and shelf locations, reflect a massive reduction in ice transport that makes the margins the most likely source of petrogenic material for the Pleistocene/Holocene central Arctic basins. The proximity of large coal deposits of various maturity levels along the Lena River, the overlap in PAH and biomarker composition of the Laptev Sea and surficial sediments from the central Arctic Ocean and the location of the Laptev Sea at the origin of the main Transpolar Drift all point to eroded coals from the Lena River/Laptev Sea as the likely source of petrogenic hydrocarbons to the central Arctic Ocean. The ubiquitous presence of allochthonous coal in Arctic Ocean surface sediments provides a major constraint on the use of petrogenic biomarkers to infer the presence of subsurface petroleum reserves.     

Composition and characteristics of the ferromanganese crusts from the western Arctic Ocean

Layered ferromanganese crusts collected by dredge from a water depth range of 2770 to 2200 m on Mendeleev Ridge, Arctic Ocean, were analyzed for mineralogical and chemical compositions and dated using the excess ²³⁰Th technique. Comparison with crusts from other oceans reveals that Fe-Mn deposits of Mendeleev Ridge have the highest Fe/Mn ratios, are depleted in Mn, Co, and Ni, and enriched in Si and Al as well as some minor elements, Li, Th, Sc, As and V. However, the upper layer of the crusts shows Mn, Co, and Ni contents comparable to crusts from the Atlantic and Indian Oceans. Growth rates vary from 3.03 to 3.97 mm/Myr measured on the uppermost 2 mm. Mn and Fe oxyhydroxides (vernadite, ferroxyhyte, birnessite, todorokite and goethite) and nonmetalliferous detrital minerals characterize the Arctic crusts. Temporal changes in crust composition reflect changes in the depositional environment. Crust formation was dominated by three main processes: precipitation of Fe-Mn oxyhydroxides from ambient ocean water, sorption of metals by those Fe and Mn phases, and fluctuating but large inputs of terrigenous debris.     

Palygorskite in sediments: Detrital,diagenetic or neoformed — A critical review

The origin of palygorskite in sediments is critically reviewed. In sediments, palygorskite may be detrital, diagenetic (formed by the transformation of a precursor mineral) or neoformed (formed by precipitation from solution).The most reliable information on palygorskite has been obtained from hydrothermal alteration products of igneous rocks, where palygorskite forms pseudomorphically, and from soils and paleosols, where palygorskite precipitates from solution. Palygorskite formation is also described from alkaline paleolake sediments. From these occurrences requirements for palygorskite formation could be specified: Alkaline pH, high Si and Mg and low Al activities.A detrital origin for palygorskite in marine sediments is proposed when it is associated with other clay minerals of accepted detrital origin, when a direct relation to continental deposits of the mineral exists and when conditions for its detrital accumulation appear favourable. In the Mediterranean, East Atlantic, North-Western Indian Ocean and Gulf of Aden large palygorskite occurrences are detrital. The formation of palygorskite in marine sediments occurred whenever the geochemical requirements were met, in following situations: (a) — near sites of hydrothermal activity; (b) — in peri-marine, shallow water environments, adjacent to landmasses undergoing intensive desilication by weathering: (c) — in response to fluctuations in ocean water temperature that affected solubility levels of limiting chemicals, such as Si. Various considerations of published field and laboratory data appear to favour a formation of palygorskite by neoformation rather than by diagenesis.

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Zusammenfassung Palygorskit kann in Sedimenten detritisch, diagenetisch (aus der Umwandlung vorhandener Minerale) oder neoform (aus Lösung gefällt) vorliegen.Die wichtigsten Informationen über Palygorskit stammen aus hydrothermalen Umwandlungsprodukten magmatischer Gesteine, wo Palygorskit Pseudomorphosen bildet. In Böden und Paläoböden wird Palygorskit direkt aus Lösungen gefällt. Er wird auch aus alkalischen See-Sedimenten beschrieben. Hier kann man folgende Bildungsbedingungen bestimmen: alkalisches Milieu, hohe Si und Mg und niedrige Al Aktivitäten.Der detritische Ursprung in marinen Sedimenten liegt nahe, wenn Palygorskit mit anderen detritischen Tonmineralen vergesellschaftet ist, und eine Beziehung zu terrestrischen Ablagerungen besteht sowie die marinen Sedimentationsbedingungen günstig sind. Im Mittelmeer, im Ost-Atlantik, im nordwestlichen Indischen Ozean und Golf von Aden treten große Palygorskite-Vorkommen detritisch auf.Palygorskit kommt in marinen Sedimenten unter bestimmten geochemischen Bedingungen vor: nahe von Hydrothermen; in Landnähe unter Flachwasser, wobei im Hinterland kräftige sialitische Verwitterung vorherrschen muß; als Folge schwankender Temperaturen des Meereswassers, die den Chemismus bestimmter Elemente wie den des Si beeinflussen. Aus allen bisher bekannten Daten läßt sich ableiten, daß die neomorphe Bildung von Palgorskit am häufigsten zu beobachten ist. Diagenetisch gebildete Palygorskite sind dagegen seltener.

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Résumé L'origine de la palygorskite dans les sédiments fait l'objet d'une revue critique. Dans les sédiments, la palygorskite peut Être détritique, diagénétique (formée par la transformation d'un minéral précurseur) ou de néoformation (formée par précipitation à partir d'une solution).L'information la plus crédible sur la palygorskite est fournieo par les produits d'altération hydothermale des roches ignées, où la palygorskite se forme par pseudomorphose, et par les sols et paléosols, où la palygorskite est précipitée à partir de solutions. La formation de la palygorskite est également décrite à partir de sédiments alcalins paléolacustres. Sur la base de ces occurrences, les conditions pour la formation de la palygorskite peuvent Être définies: pH alcalin, activité forte en Si et Mg, et basse en Al.Une origine détritique pour la palygorskite dans les sédiments marins peut Être proposée lorsqu' elle est associée avec d'autres minéraux argileux dont l'origine détritique est acceptée, quand une relation directe existe avec des dépÔts continentaux renfermant ce minéral, et quand des conditions pour son accumulation détritique apparaissent favorables. Dans la Méditerranée, dans l'Atlantique oriental, dans le nord-ouest de l'Océan Indien et dans le Golfe d'Aden, les grandes occurrences de palygorskite sont détritiques. La formation de palygorskite dans les sédiments marins se présente chaque fois que les conditions géochimiques sont rencontrées, dans les cadres suivants: a) sites proches d'une activité hydrothermale; b) dans des milieux d'eau peu profonde péri-marins, attenant à des masses continentales subissant une désilicatation intense par voie d'altération athmosphérique; c) en réponse à des fluctuations dans la température de l'eau océanique, affectant les niveaux de solubilité de certains éléments chimiques, comme le Si. Des considérations diverses concernant les données de terrain et de laboratoire semblent favoriser pour la palygorskite une formation par néoformation plutÔt que par diagénèse.

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Evinosponges in the Triassic Esino Limestone (Southern Alps): documentation of early lithification and late diagenetic overprint

A carbonate buildup of Middle Triassic age, the Esino Limestone, outcrops in the Southern Calcareous Alps of Lombardy (N Italy). Along its margin and within the open subtidal facies, the Esino Limestone contains calcite cement-filled cavities of cm to m size. These features, known as evinosponges, may form pervasive networks within the host rock. The filling consists of concentric, isopachous layers of fibrous low-Mg calcite crystals characterized by strong undulose extinction and bent cleavages. The cement crusts are non-luminescent under cathodoluminescence, but both cements and host rock are cross-cut by micro-fractures filled with bright-luminescent calcite, related to late void-filling sparite. Mixing of different carbonates is reflected in stable isotope data. On the hand specimen scale, the oxygen and carbon isotope compositions of cements and host rock show little variation. When compared on a regional scale, the values cover a broad range from δ¹⁸O(PDB)=?5‰ to ?12‰ and from δ¹³O =0‰ to +3‰. The linear covariant trends defined by the oxygen and carbon isotope data for different sampling regions reflect the admixture of late, isotopically depleted calcite with an isotopically enriched non-luminescent calcite of early diagenetic origin. The Esino Limestone fibrous cements, which were probably precipitated in the marine or marine-meteoric phreatic environment, were affected by late diagenetic processes that caused mineral deformation and isotopic depletion through recrystallization and the admixture of a later calcite. These later calcites precipitated from penetrative fluids possibly related to Late Triassic volcanic activity and/or to the Late Cretaceous/Early Palaeogene alpine orogeny.     

Provenance and sea-ice transportation of Mid-Pliocene and Quaternary sediments, Yermak Plateau, Arctic Ocean (ODP Site 911)

In this study, the clay and heavy mineral analysis of ODP Site 911 sediments is used to investigate the sources and transport mechanisms (sea ice and oceanic currents) of sediments in the Arctic Ocean during the Mid to Late Pliocene (3.10–2.78 Myr) and upper Quaternary (800 kyr to the present). The time period between 3.10 and 3.00 Myr is characterized by a decreasing smectite and increasing illite content, which is interpreted as reflecting cooling conditions. At the beginning of the Mid-Pliocene Global Warmth period at ∼3.00 Myr, the smectite content shows an abrupt increase. This change can also be seen as a drop in the amount of kaolinite and TOC. After 3.00 Myr the kaolinite and TOC values start to increase, probably indicating high rates of reworked glacially eroded matter. During the Pleistocene, smectite shows a lower and illite a higher fluctuation level compared with the Pliocene. This might be due to reigning glacial conditions during the Pleistocene, when the freshwater input was much lower than during the Pliocene. During the Pliocene, the fluctuating heavy minerals might reflect changes in freshwater input from the great Siberian rivers, which would have led to changes in the supply of terrigenous material delivered to the shelf by the rivers. The heavy mineral fluctuation also reflects changes in the amount of sea-ice formation, which correlates with climate variations and the freshwater input from the continent. Based on the composition of the clay and heavy mineral groups in this study, the most likely transportation path is the Siberian branch of the Transpolar Drift.     

Steroid and triterpenoid distributions in bransfield strait sediments: Hydrothermally-enhanced diagenetic transformations

Recent sediments from Bransfield Strait, Antarctica have been analyzed for triterpenoid and steroid hydrocarbons, sterols and steroid ketones to consider the effects of hydrothermal fluids on the sedimentary organic matter. The steroid distributions in unaltered and altered sediments are controlled more by inputs from source organisms than by the effects of hydrothermal activity, which is suggested to be limited to low temperature alteration. Nevertheless, chemical reactions occurred in altered sediments and include dehydration of sterols to sterenes, isomerization of triterpenes and sterenes, rearrangement of sterenes to diasterenes and reductive processes leading to generation of phytane from phytol via phytenes.     

Geochemistry of organic matter of bottom sediments in the rises of the central Arctic Ocean

Based on geomorphological, lithological, and facial characteristics of the East Arctic continental margin, we studied the main factors controlling the Late Cenozoic supply of organic matter (OM) to the bottom sediments of the Central Arctic rises of the Arctic Ocean. Complex analysis of dispersed OM in the samples taken during the expeditions of the R/V “Akademik Fedorov” in 2000 and 2005 showed a significant difference between the sediments of the Lomonosov Ridge and Mendeleev Rise. The bottom sediments of the latter are strongly transformed and lack terrigenous components, as evidenced results from the main geochemical characteristics (contents of C_org, C_carb, N_org, bitumens, and humic acids) and the composition and distribution of hydrocarbon molecular markers (alkanes, saturated and aromatic cyclanes). The obtained data evidence that ancient sedimentary rocks containing genetically uniform deeply transformed (up to mesocatagenesis) OM played a significant role in the formation of the Pleistocene–Holocene sediments of the axial part of the Mendeleev Rise.     

Composition and formation conditions of petroliferous Cenozoic sediments in the Anadyr Basin

This paper discusses specific features in the origin of the Cenozoic sediments filling the Anadyr Basin. Two petroliferous rock complexes have been recognized: (1) lower, orogenic, including sedimentary rocks of an Eocene-Early Miocene age and (2) upper, postorogenic, embracing Middle Miocene-Pliocene sediments. The total initial hydrocarbon resources in the land and aquatorial parts of the Anadyr petroliferous basin have been calculated.     

Genesis and diagenetic evolution of Habo formation,Kachchh, Gujarat

The Kachchh Basin is a pericratonic rift basin situated at the western margin of the Indian plate. The Habo Dome embodies an important exposure of Bathonian to Kimmergian sediments among the Kachchh Mainland exposures. Based on vertical facies transitions, facies associations were documented: mixed shallow marine (Facies association 1), shoreface and lagoon deposits (Facies association II) and subtidal innershelf below fair weather wave base (Facies association III). The documented facies associations reflect that Habo Dome sediments deposited in a variety of environments from shallow marine to fluvio-deltaic and were strongly influenced by fluctuation of relative sea level. The dominance of floating grains and point contacts in the sandstone indicate that detrital grains do not show much pressure effects as a result of either shallow burial or early cementation. The sandstones were cemented by iron oxide, carbonate and silica in order of abundance. Three types of cements, blocky, rim and fibrous cement occur in the studied limestone representing phreatic, fresh water phreatic and deep burial diagenetic stages. Neomorphism and micritization are common. Both primary and secondary porosity exists in these sediments. Different graphs of porosity versus depth suggest a depth of burial in the range of 615–769 m.     

The sequestration of terrestrial organic carbon in Arctic Ocean sediments: A comparison of methods and implications for regional carbon budgets

A variety of approaches have previously been developed to estimate the fraction of terrestrial or marine organic carbon present in aquatic sediments. The task of quantifying each component is especially important for the Arctic due to the regions’ sensitivity to global climate change and the potential for enhanced terrestrial organic carbon inputs with continued Arctic warming to alter carbon sequestration. Yet it is unclear how each approach compares in defining organic carbon sources in sediments as well as their impact on regional or pan-Arctic carbon budgets. Here, we investigated multiple methods: (1) two end-member mixing models utilizing bulk stable carbon isotopes; (2) the relationship between long-chain n-alkanes and organic carbon (ALKOC); (3) principal components analysis (PCA) combined with scaling of a large suite of lipid biomarkers; and (4) ratios of branched and isoprenoid glycerol dialkyl glycerol tetraether lipids (the BIT index) to calculate the fraction of terrestrial organic matter components preserved in Arctic marine sediments.Estimated terrestrial organic carbon content among approaches showed considerable variation for identical sediment samples. For a majority of the samples, the BIT index resulted in the lowest estimates for terrestrial organic carbon, corroborating recent suggestions that this proxy may represent a distinct fraction of terrestrial organic matter; i.e., peat or soil organic matter, as opposed to markers such as n-alkanes or long-chain fatty acids which measure higher plant wax inputs. Because of the patchy inputs of n-alkanes to this region from coastal erosion in the western Arctic, the ALKOC approach was not as effective as when applied to river-dominated margins found in the eastern Arctic. The difficulties in constraining a marine δ¹³C end-member limit the applicability of stable isotope mixing models in polar regions. Estimates of terrestrial organic carbon using the lipid-based PCA method and the bulk δ¹³C mixing model approach varied drastically at each site, suggesting that organic matter fractions such as amino acids or carbohydrates may affect bulk organic matter composition in a manner that is not captured in the lipid-based analysis. Overall, terrestrial organic matter inputs to the Chukchi and western Beaufort Seas using the average of the methods at each site ranged from 11% to 44%, indicating that land-derived organic matter plays a substantial role in carbon dynamics in the western Arctic Ocean.     

Continental ridges in the Arctic Ocean: Lorex constraints

Recent multidisciplinary geophysical measurements over the Lomonosov Ridge close to the North Pole support the widely held belief that it was formerly part of Eurasia. The known lithologies, ages, P-wave velocity structure and thickness of the crust along the outer Barents and Kara continental shelves are similar to permitted or measured values of these parameters newly acquired over the Lomonosov Ridge. Seismic, gravity and magnetic data in particular show that the ridge basement is most likely formed of early Mesozoic or older sedimentary or low-grade metasedimentary rocks over a crystalline core that is intermediate to basic in composition. Short-wavelength magnetic anomaly highs along the upper ridge flanks and crest may denote the presence of shallow igneous rocks. Because of the uncertain component of ice-rafted material, seafloor sediments recovered from the ridge by shallow sampling techniques cannot be clearly related to ridge basement lithology without further detailed analysis. The ridge is cut at the surface and at depth by normal faults that appear related to the development of the Makarov Basin. This and other data are consistent with the idea that the Makarov Basin was formed by continental stretching rather than simple seafloor spreading. Hence the flanking Alpha and Lomonosov ridges may originally have been part of the same continental block. It is suggested that in Late Cretaceous time this block was sheared from Eurasia along a trans-Arctic left-lateral offset that may have been associated with the opening of Baffin Bay. The continental block was later separated from Eurasia when the North Altantic rift extended into the Arctic region in the Early Tertiary. The data suggest that the Makarov Basin did not form before the onset of rifting in the Artic.     

Carbon and oxygen isotope ratios in diagenetic carbonates from marine sediments

The isotopic composition of some sixty samples of penecontemporaneous diagenetic carbonates from marine horizons shows that they are strikingly different from normal marine limestones. The variation of C¹³ ratio is 5·6 per cent, the lightest carbonate measuring -54%. A mechanism for the formation of such light carbon dioxide is postulated, involving the enzymic decarboxylation of organic compounds at low temperatures. A study of the oxygen isotopic composition of coexisting calcite and rhodochrosite indicates that, whereas the latter has retained its isotopic composition from the time of precipitation, the calcite has undergone equilibration during diagenesis. Isotopic measurements on such diagenetic carbonates would confuse palaeoenvironmental studies but may throw light on the processes of diagenesis.     

Silicification of sulphate evaporites and their carbonate replacements in Eocene marine sediments, Tunisia: two diagenetic trends

Samples of chert nodules, diagenetic carbonates and evaporites (gypsum/anhydrite) collected from the gypsiferous limestones of the Kef Eddour Member (Ypressian‐Priabonian) near Metlaoui and Sehib (Tunisia) show selective silicification with great variety in the silicified by‐products. Based on δ¹³C values, which support an organic origin for the carbon, carbonates replaced evaporites microbially through bacterial sulphate reduction. Observations and results suggest two scenarios for chert formation that are related to the rate and timing of diagenetic carbonate replacement of the evaporites (anhydrite/gypsum). In the absence of early diagenetic carbonate phases, silica with δ¹⁸O values from +25 to +28·6‰ [standard mean ocean water (SMOW)] replaced the outer parts of anhydrite nodules at pH < 9. In contrast, pore‐fluid pH values > 9 in the innermost parts of the anhydrite nodules prevented silica precipitation. The record of this chemical barrier is preserved in the microquartz rims and geode features that formed in the inner parts of the nodules after dissolution of the anhydrite nucleus. The microbial diagenetic replacement of evaporites (bacterial sulphate reduction) by carbonates (calcite, aragonite and dolomite) favoured silica replacement of carbonates rather than evaporites. Silica, with δ¹⁸O signature of +21 to +26‰ (SMOW), replaced carbonates on a volume‐for‐volume basis, yielding a more siliceous groundmass, and accounting for 90–95% of the nodules. The relatively higher δ¹⁸O values of quartz replacing anhydrite can be explained by a diagenetic fluid in equilibrium with mixed (meteoric/marine) to marine water. The lower δ¹⁸O values of the quartz that replaced the diagenetic carbonates are ascribed to flushing by meteoric water in a later diagenetic stage. The silica supply for chert formation could be derived from the reworked bio‐siliceous deposits (diatomites) to the west of the basin [vestiges of an opal‐CT precursor undetectable by X‐ray diffraction (XRD) were revealed by δ²⁹Si magic‐angle‐spinning nuclear magnetic resonance investigations], diagenesis of the extraformational and overlying clay‐rich beds (the host limestones are clay‐poor as shown by XRD measurements), and minor volcanogenic and hydrothermal contributions during early diagenetic stages.