Isolation and water-level fluctuations of Lake Kachishayoot, Northern Québec, Canada

This study combines different methods, including grain size, macrofossil, and pollen analyses, to reconstruct paleogeographical and paleoclimatological conditions for periods before, during, and after the isolation of a small lake (Lake Kachishayoot) in northern Québec. After the retreat of the Laurentide Ice Sheet around 8000 ¹⁴C yr B.P., the area was submerged by the Tyrrell Sea. The transition from marine to lacustrine environment occurred about 5400 yr B.P. Two major periods of water-level fluctuations were inferred from organic and mineral sediments: a high water level that occurred after 3200 yr B.P. and a low water level that started before 2200 yr B.P. Our chronological data for the first period are consistent with those from nearby Lac des Pluviers and from other lakes in east central Canada and in the northeastern United States. During the low-water-level period, however, there is no evidence for minor fluctuations, whereas other lakes in northern Québec and east-central Canada underwent several brief lowerings. Long-term changes in atmospheric circulation caused by changing global boundary conditions likely explained long-term water-level fluctuations of Lake Kachishayoot.     

Characterization of the Soil Hydromorphic Conditions in a Paludified Dunefield during the Mid-Holocene Hemlock Decline near Québec City, Québec

The mid-Holocene eastern hemlock [Tsuga canadensisL. (Carr.)] decline has been recently attributed to the activity of insect defoliators. N. Bihiry and L. Filion,Quaternary Research45,312–320 (1996). In this study, soil hydromorphic conditions were investigated for the period 6800–3200 yr B.P. using micromorphological data from a peat section from a swale in a paludified dunefield in southern Québec. After a short period of plant colonization in shallow pools between 6800 and 6400 yr B.P., mesic conditions predominated in the interdune before the decline (6400–4900 yr B.P.), as evidenced by strong bioturbation and abundance of excrements from the soil fauna. During the decline, a shift from mesic to wet conditions occurred (4900–4100 yr B.P.), although xeric to mesic conditions persisted on dune ridges until at least 4200 yr B.P. Wetness culminated when beaver occupied the site (4100–3750 yr B.P.). Hemlock needles with chewing damage typical of hemlock looper (Lambdina fiscellaria) feeding were identified at levels dated 4900, 4600, and 4200 yr B.P., respectively, implying that the hemlock decline was associated with at least three defoliation events. The ca. 400-yr interval between these events likely represents the time required for this late-sucessional tree species to recover.     

Late Glacial De Geer moraines with glaciofluvial sediment in the Chapais area, Québec (Canada)

Glaciofluvial De Geer moraines have rarely been described in detail in the literature. This study presents a model for the genesis of moraines of this type in the Chapais area, Québec. The model is based mainly on facies and deformatin structures analysis, and geomorphological data. Well-stratified glaciofluvial material is commonly found in the core of the moraines, whereas till or glacial diamicton may be present as surficial cover on their proximal side or as injected lenses in the sorted sediments. The paleocurrents are systematically directd downglacier. The moraines were built up in subglacial crevasses in areas where meltwater was channelized. Water flowed under pressure from small upglacier cavities, carrying a load of coars-grained material When flowing water entered crevasses already occupied by water, flow sparation occurred, reducing the capacity of the flow to carry the particles, and avalanching glaciofluvial material on the leeside of the piled sediments. The occurrence, in these sediments, of glaciotectonic deformation structures such as overturned to recumbent folds and thrust faults is evidence that the glacier was still active to some degree during and after the sedimentation phase.     

Isotopic compositions of S, N and C in soils and vegetation of three forest types in Québec, Canada

The concentrations and the isotopic compositions of S, N and C were studied in soils and in the dominant plant species of three forested watersheds (Québec, Canada) located along a latitudinal and atmospheric deposition gradient. Large increases in S, N and C isotope ratios (up to 3.9‰, 10‰, 2.6‰, respectively) were observed with increasing soil depth at the three watersheds. These increases were accompanied by a strong decrease in elemental concentrations resulting in a strong negative relationship between these two variables. Both S and N concentrations throughout the soil profile and δ³⁴S and δ¹⁵N in the mineral soil appeared to increase with increasing S and N deposition rates and decreasing latitude. A strong positive linear relationship was found between δ³⁴S and δ¹⁵N (R² = 0.72) values and between organic S and N concentrations (R² = 0.96) in soils. The slope of the linear relationship between δ³⁴S and δ¹⁵N (δ³⁴S = f(δ¹⁵N)) indicated that isotopic fractionation was almost 4 times higher for S than for N during transformations that occurred in soil. However, this difference might reflect a higher degree of openness of the S cycle compared to the N cycle rather than an isotope effect per se. Overall, the results suggest that N and S inputs significantly impact the isotope ratios and the concentrations of N and S in the soils, and that S and N were closely associated and subject to similar processes with the same isotopic effects throughout the soil profile. Contrary to most studies, δ³⁴S-SO₄ in stream water of the most northerly site with the lowest S deposition rate was significantly higher than δ³⁴S-SO₄ in atmospheric depositions but similar to the δ³⁴S of the bulk mineral soil. It suggests that the mineral soil actually contributes a large portion of the stream S-SO₄ for this site.     

Water escape fissures resembling ice-wedge casts in Late Quaternay subaquesous outwash near St. Lazare Québec, Canada

Post-depositional structures in late Quaternary subaqueous outwash near St. Lazare, Québec resemble icewedge casts but are interpreted as water escape fissures. Cryogenic origin is discounted because, in contrast with ice-wedge casts, the fissures have a higher depth to width ratio, do not form an intersecting network, and do not exhibit adjacent upward turning of strata. In addition, their truncation by the sub-littoral unconformitydemonstrates formation before regression of the post-glacial Champlain Sea, under conditions in which ground ice development was highly unlikely. The fissures probably formed in response to elevated pore pressures caused by melting of remnant glacier ice or by liquefaction of deeper units. Excess pore water pressure initiated upward flow of dilute sediment-water mixtures that became concentrated in planar zones (fissures) along which they entrained and removed sediment. Slumping of the fissure walls followed, either during or after water escape. Minor faulting over cavities created by melting ice or water escape along fractures in underlying strata may have controlled the morphology of the fissures.     

Upper Ordovician facies in the Lac Saint-Jean outlier, Québec (eastern Canada): palaeoenvironmental significance for Late Ordovician oceanography

Upper Ordovician (Caradocian) carbonates of eastern North America were deposited along the Iapetus continental margin and record a transition from warm- to cool-water settings despite this margin having been within the southern hemisphere tropical belt. This event has been documented from Virginia (USA) to southern Québec (Canada) although, not previously from areas close to the palaeoequator. Field, petrographic and major element geochemistry data have been gathered from the poorly-known Upper Ordovician carbonate succession outcropping in the Lac Saint-Jean outlier in central Québec. The succession consists of a lower siliciclastic formation (Tremblay) overlain by three limestone formations (Simard, Shipshaw and Galets) and capped by shales (Pointe-Bleue Shale). From macro- and microfaunal evidence, carbonate sedimentation occurred during the late Caradoc and is younger than the early- to mid-Caradoc carbonate succession present farther south. Relative sea level fluctuations recorded in the sediments suggest an overall sea level rise briefly halted by a minor end-Caradocian sea level fall. The lower limestone formation (Simard) consists of muddy sediments with algal-coral-stromatoporoid boundstones; green algae are abundant. This unit reflects low energy sedimentation on a shallow warm-water carbonate ramp colonized by a diverse chlorozoan fauna. The upper limestone formation (Galets) is typified by coarse-grained bioclastic sediments punctuated by numerous phosphate-rich hardgrounds with evidence for high energy shallow marine conditions. Faunas were dominated by crinoids and bryozoans. This unit represents high energy sedimentation on a cool shallow water carbonate ramp colonized by a brynoderm faunal association. Between both units, a deeper marine (outer shelf) limestone formation (Shipshaw) was developed. In the Lac Saint-Jean area, a transition from warm- to cool-water carbonate ramps occurred in latest Caradoc times and is litho- and biofacies-wise, similar to what is documented for lower Caradocian limestones present farther south. Upwelling of nutrient-rich cool bottom oceanic waters was a probable cause for this transition.     

Reconstruction of the long-term fire history of an old-growth deciduous forest in Southern Québec, Canada, from charred wood in mineral soils

Charcoal particles are widespread in terrestrial and lake environments of the northern temperate and boreal biomes where they are used to reconstruct past fire events and regimes. In this study, we used botanically identified and radiocarbon-dated charcoal macrofossils in mineral soils as a paleoecological tool to reconstruct past fire activity at the stand scale. Charcoal macrofossils buried in podzolic soils by tree uprooting were analyzed to reconstruct the long-term fire history of an old-growth deciduous forest in southern Québec. Charcoal fragments were sampled from the uppermost mineral soil horizons and identified based on anatomical characters. Spruce (Picea spp.) fragments dominated the charcoal assemblage, along with relatively abundant wood fragments of sugar maple (Acer saccharum) and birch (Betula spp.), and rare fragments of pine (Pinus cf. strobus) and white cedar (Thuja canadensis). AMS radiocarbon dates from 16 charcoal fragments indicated that forest fires were widespread during the early Holocene, whereas no fires were recorded from the mid-Holocene to present. The paucity of charcoal data during this period, however, does not preclude that a fire event of lower severity may have occurred. At least eight forest fires occurred at the study site between 10,400 and 6300 cal yr B.P., with a dominance of burned conifer trees between 10,400 and 9000 cal yr B.P. and burned conifer and deciduous trees between 9000 and 6300 cal yr B.P. Based on the charcoal record, the climate at the study site was relatively dry during the early Holocene, and more humid from 6300 cal yr B.P. to present. However, it is also possible that the predominance of conifer trees in the charcoal record between 10,400 and 6300 cal yr B.P. created propitious conditions for fire spreading. The charcoal record supports inferences based on pollen influx data (Labelle, C., Richard, P.J.H. 1981. Végétation tardiglaciaire et postglaciaire au sud-est du Parc des Laurentides, Québec. Géographie Physique et Quaternaire 35, 345-359) of the early arrival of spruce and sugar maple in the study area shortly after deglaciation. We conclude that macroscopic charcoal analysis of mineral soils subjected to disturbance by tree uprooting may be a useful paleoecological tool to reconstruct long-term forest fire history at the stand scale.     

Hydrogeochemistry and groundwater origin of the Basses-Laurentides sedimentary rock aquifer system, St. Lawrence Lowlands, Québec, Canada

A comprehensive hydrogeochemical study was carried out in the Paleozoic Basses-Laurentides sedimentary rock aquifer system in Québec over a 1500 km² study area. Groundwater samples were collected at 153 sites, characterizing all geological and hydrogeological units to a maximum depth of 140 m. Groundwater was analyzed for major, minor and trace inorganic constituents, stable isotopes δ ²H, δ ¹⁸O, and δ ¹³C of dissolved inorganic carbon (DIC), and some samples were analyzed for ³H, and ¹⁴C of DIC. The regional distribution of groundwater types shows that the hydrogeological conditions exert a dominant control on the major ions chemistry of groundwater. Preferential recharge areas are characterized by tritiated Ca-Mg-HCO₃ groundwater, and confined conditions by submodern Na-HCO₃ and Na-Cl groundwater types. Two groundwater end-members are identified in the aquifer system, modern meteoric water and Pleistocene Champlain Sea water. The region displays significant variations of groundwater geochemistry and quality controlled by glaciation, Champlain Sea invasion, lithological rock diversity, and flow system scales. This situation leads to varied groundwater types and origins within a restricted area.     

Contrasting mineral isograd sequences in metabasites of the Cape Smith Belt, northern Québec, Canada: three new bathograds for mafic rocks

Regional-scale mapping of index-mineral isograds in mafic units of the early Proterozoic Cape Smith Thrust Belt (northern Québec) has revealed contrasting pressure-temperature regimes associated with two distinct structural domains. In the southern domain, crustal thickening was accomplished by early, piggy-back thrust faults. Isograds cross-cut the thrusts, indicating that thermal-peak mineral growth outlasted deformation associated with early imbrication. Mineral zones are: (1) actinolite (Act) + albite (Alb); (2) hornblende (Hbl) + Act + Alb; (3) Hbl + Act + oligoclase (Oli); (4) Hbl + Oli; and (5) garnet (Grt) or clinopyroxene + Hbl + Oli-andesine. The oligoclase isograd occurs at higher grade than the hornblende isograd, a sequence typical of medium-pressure terranes (5–7 kbar). An Hbl-Alb bathograd. calibrated from mixed-volatile equilibria in the NCMASH-CO₂ model system, suggests minimum pressures of about 5.4 kbar. Metamorphism in the northern domain was a consequence of re-imbrication, by means of out-of-sequence thrust faults active during and after peak metamorphic conditions. Mineral growth was coeval with thrusting, as documented by the syn-kinematic garnet porphyroblasts. Compared to the southern domain, a different sequence of isograds in mafic rocks shows that the albite-oligoclase transition takes place in the garnet zone. Based on thermobarometry in garnet-hornblende rocks, the oligoclase isograd occurs in a temperature range of 525–600°C, typical of high-pressure terranes (7–10 kbar). Calibrated bathograds for the Hbl-Ms-Alb and Grt-Alb bathozonal assemblages, respectively in the KNCMASH-CO₂ and NCMASH model systems, indicate minimum pressures in the northern domain of 6.7 and 8.5 kbar. Higher-pressure series for this domain are explained by out-of-sequence thrusts exposing deeper crustal levels. For similar structural levels, only minor amounts of syn-deformational uplift (1–2 kbar and 50–75°C) are recorded in metabasites of this domain, compared to results in adjacent metapelites of the area (essentially isothermal uplift of 3–5 kbar). RESUME La bande du Cap Smith (nord du Québec) est une ceinture de chevauchement d'ǎge protérozoique inférieur, dominée par des roches mafiques. La cartographie d'isogrades à minéraux indicateurs dans les unités mafiques de la ceinture a révelé deux régimes contrastes de pression–température, chacun associéà des épisodes distincts d'épaississement crustal. Dans le domaine sud, des failles de chevauchement en-série sont responsables pour l'empilement tectonique. Les isogrades recoupent les failles, indiquant que l'apogée thermale a suivi l'emplacement initial des nappes de charriage. Les zones minérales sont: (1) actinote (Act) + albite (Alb); 2) hornblende (Hbl) + Act + Alb; (3) Hbl + Act + oligoclase (Oli); 4) Hbl + Oli; et (5) grenat (Grt) où clinopyroxene + Hbl + Oli-andésine. L'isograde d'oligoclase apparaǐt à plus haute température que l'isograde d'hornblende, une séquence typique des terrains de pressions moyennes. Un bathograde Hbl–Alb, calibréà partir d'équilibre mixte de volatiles dans le système NCMASH–CO₂, suggère des pressions minimales d'environ 5.4 kbar. Le métamorphisme dans le domaine nord de la ceinture a été le résultat d'une réimbrication, causé par des chevauchements hors-série actifs pendant et après l'apogée thermale. La croissance minérale fǔt synchrone au chevauchement, documentée par des porphyroblastes de grenat syn-cinénatique. Comparé au domaine sud, une différente séquence d'isogrades dans les métabasaltes montre que la transition albite–oligoclase se situé dans la zone à grenat. Par la thermobarométrie dans les roches à grenat–hornblende l'isograde d'oligoclase se situe dans un écart de température de 525–600°C, typique des terrains de hautes pressions (7–10 kbar). Des bathogrades calibrés pour les assemblages bathozonales Hbl–Ms–Alb et Grt–Alb, rcspectivement dans les systèmes KNCMASH–CO₂ et NCMASH, indique des pression minimales pour le domaine nord de 6.7 et 8.5 kbar. Une zonégraphie à plus haute pression pour ce domaine est expliquée par des chevauchements hors-série exposant des niveaux plus inférieurs de la croǔte imbriqué. Pour des niveaux structuraux similaries, des soulèvements syn-métamorphiques mineurs sont enregistrés dans les métabasaltes (1–2 kbar et 50–75°C), comparés aux métapélites adjacentes avec un soulèvement (essentially isothermal uplift of 3–5 kbar.     

Age of landslides along the Grande Rivière de la Baleine estuary, eastern coast of Hudson Bay, Québec (Canada)

A 12km long terrace along the estuary of the Grande Rivière de la Baleine, northern Québec (5517'N, 7747'W), has been locally modified by seven large landslides during the last 3,200¹⁴ C years. The oldest undated landslide occurred between 3,200 B.P(formation of the upper terrace) and 2,200B.P., i.e. the radio carbon age of the second oldest landslide. The third one occurred around 900B.P. sometime before peat started to accumulate on the flowbowl floor. The more recent landslides were dendrochronologically dated. They were formed in less than 30 years, i.e. in 1818 (2 synchronous landslides), 1839 and 1846 A.D. These 19th-century landslides were dated through a comparative analysis of growth curves derived from buried trees found in the flowing sediments or from tilted and cut trees, with the regional master chronologies and the northern Québec light-ring chronology, using more specifically the 1816 and 1817 light-ring years. The 1818 landslides occurred during the growing season (July), whereas the 1839 and 1846 landslides were formed during spring. The occurrence of numerous landslides during this short period seems to be related to sustained cool and humid climatic conditions that may have enhanced the subsoil water content.     

A shear-diffusion model of till genesis based on the dispersal pattern of indicator rocks in the Grand-Volume Till of central Gaspésie, Québec, Canada

Dispersal patterns of indicator rocks in central Gaspésie reveal that glacial debris is entrained in a basal debris-rich zone of shearing where clast diffusion takes place. The Grand-Volume Till forms a thin till sheet over the high plateaus of Gaspésie Peninsula and resulted from a succession of two Wisconsinan ice flows of distinct orientations (SSE and NE). The lithological composition of this till determined by pebble counts and the three-dimensional dispersal patterns of indicator rocks in it suggest that debris transport occurred principally by simple shear deformation of glacial debris. In addition, the intermixing of clasts at the intersection of two lithologically distinct dispersal trains of SSE and NE orientations, respectively, suggests that extensive mixing takes place during shearing. Physical interactions among the clasts lead to both upward and downward movements which cause the clasts to diffuse across the zone of shearing. This process of shear-diffusion results in continuous incorporation and mixing of the newly encountered rock types during glacial transport.     

Fossil pollen, molluscs, and stable isotopes in the Dättnau valley, Switzerland

Pollen and mollusc deposits in a sedimentation series laid down in the Dattnau valley during the Late Glacial and early Post-glacial were studied. For the first time δ¹³C and δ¹⁸O in land-snail shells were measured. It was possible to reconstruct vegetational and climatic developments from the Bölling ( c . 12,500 B.P.) until well into the early Boreal ( c . 9,000 B.P.). The two sets of findings agree well. The Late Glacial is seen to comprise two intervals: the continuous, locally rather moist, warm Bölling/Alleröd period, and the subsequent dry . cold Younger Dryas. The profile ceases after the changeover from the Late Glacial to the Post-glacial. The transitions from the Alleröd to the Younger Dryas and hence to the Preboreal and Boreal are both clearly identifiable in the pollen diagram; the mollusc record, however, ceases to be interpretable shortly before the climatic change to the Post-glacial. The δ¹⁸O curve shows a clear distinction between the AllerÖd and the Younger Dryas. The Gerzensee fluctuation, immediately before this transition. is evident as a negative deviation.     

Glacial dispersal of boulders in the James Bay Lowlands of Quebéc, Canada

Paleozoic fossiliferous limestones from the Hudson Bay area were dispersed southeastward a total distance of 110 km in the Québec part of theJames Bay Lowlands during the surging Cochrane flow event of the Laurentide Ice Sheet. The dispersal by the surging ice appears comparable to non-surging ice dispersal events elsewhere in terms of the dispersal index and the half distance of transportation; however, the total distance of transportation of the limestone clasts and their relatively high abundance far away from their source suggest that part of the transport of the debris during the surge was englacial, with the load later deposited as a surface mantle, or that the flow of the surging ice was limited to rapid basal sliding, with little or no internal shear within the ice mass. The glacial transport characteristics of earlier non-surging flow events in the same area were determined using the Total Transport Distance (TTD) method of measurements. Based on an indirect measurement of the half distance of transportation, the Selbaie till is characterized by longer transport distance than the Matheson till, and the Nouveau-Québec till has the shortest transport distance of all the tills of the area.     

Evaluation of the potential for gas leakage along wellbores in the St. Lawrence Lowlands basin,Quebec, Canada

Wellbore attributes (i.e., deviation, casings and plugging characteristics) for 85 wells in the St. Lawrence Lowlands basin of southern Quebec were compiled from drilling reports and abandonment programs to provide an overview of the abandoned well characteristics and to establish a diagnosis on the long-term reliability of the completion and abandonment practices carried out by the companies since the beginning of oil and gas exploration. Using these data, the conventional and unconventional wells were divided into four categories: (1) conventional wells drilled before 1950, (2) conventional wells drilled between 1950 and 1970, (3) conventional wells drilled after 1970 and shale gas wells (all drilled after 2000). Very little information was available for wells drilled before 1950. More information was available for the wells drilled from 1950 to 1970 which is considered a transition period between old and modern technology. Conventional and unconventional wells drilled after 1970 were generally well documented and their attributes corresponded to API standards. A decision tree, inspired from the methodology proposed by Watson and Bachu (SPE Drill Complet 24(1):115–126, 2009.  https://doi.org/10.2118/106817-PA), was then created to assess the potential of leakage of each of the conventional and unconventional wells using the compiled attributes. The factors defining the probability of well leakage were wellbore deviation, height of cement in casing annuli (partially or fully cemented), type of abandonment plugs (cement or mechanical plugs) and drilling date (before or after 1970). Among the 85 wells assessed by this tree, the probability of leakage was higher than 50% for 55 wells (65% of wells). Wellbore deviation and lack of information on the construction and abandonment methods were respectively the primary and secondary causes of high probability of leakage of these wells.     

Lithospheric mantle signatures as revealed by zircon Hf isotopes of Late Triassic post‐collisional plutons from the central Korean peninsula,and their tectonic implications

The Mesozoic tectonic architecture of the Korean peninsula is largely governed by the continental collision between the North and South China blocks. Zircon Hf isotopic compositions presented in this study and whole‐rock geochemical and Sr‐Nd isotope data in the literature collectively suggest that the lithophile‐elements‐enriched signature of the Late Triassic post‐collisional plutons from the Gyeonggi massif in central Korea is a primary feature inherited from the metasomatized mantle lithosphere. Highly negative zircon ε_Hf (t) values (?23 to ?19) of plutons from the middle and eastern parts of the massif indicate an ancient metasomatism of their mantle source. Distinctly higher zircon ε_Hf (t) values (?15 to ?12) from the southwestern plutons are ascribed to a contribution from an accreted component of the South China‐like block. The involvement of asthenospheric mantle is not recognized in zircons from either group. The implications of these isotopic features are discussed in the context of Mesozoic collisional tectonics.     

40Ar/39Ar thermochronology along a western Québec transect of the Grenville Province, Canada

Ar/Ar thermochronology on 24 hornblendes, 3 biotites, 2 muscovites and 2 K-feldspars, collected along a 400 km-long NW-SE geotraverse through the Grenville Province in western Québec, is employed to provide time constraints on the intermediate and low temperature stages of cooling of part of the Grenville orogen. In the Grenville Front zone, the c. 1000 Ma time of exhumation previously established from thermobarometric and isotopic studies, is supported by the hornblende age data presented here. From 60 km to 160 km SE of the Front, reworked Archaean migmatites of the parautochthonous Réservoir Dozois terrane (RDT; 1004 Ma-old metamorphic monazites) contain hornblendes with 972– 950 Ma cooling ages. Assuming metamorphic geotherms between 25 and 30 °C km?1, calculated cooling and unroofing rates are about 6 °C Ma?1 and 0.33 km Ma?1 in the P–T range 725 °C–800 MPa and 450 °C–400 MPa. Hornblendes from monocyclic rocks of the Mont-Laurier and Morin terranes (MLT and MT; monazite ages c. 1165 Ma) give ages of about 1040 and 1010 Ma, respectively. Calculation of cooling-unroofing rates from peak metamorphic conditions in this area is hampered by thermal perturbations associated with the still poorly dated Grenville collision which took place approximately between 1060 and 1020 Ma. Cooling ages of c. 900 Ma for muscovite and biotite and 860–810 Ma for K-feldspar, show that cooling rates decreased to around 1.5 °C Ma?1 under retrograde greenschist facies conditions in the MLT. On a time vs. distance diagram, the hornblende data define several distinct age ranges, suggesting that each terrane had a characteristic thermal history. Thus, cooling was diachronous and probably non-homogeneous throughout this segment of the Grenville orogen. The time-lag between the cooling history of the parautochthon (972–950 Ma) and the allochthons (1040–1010 Ma) is compatible with an earlier (pre-1040 Ma) peak of metamorphism in the allochthons. The Réservoir Cabonga allochthon was transported toward the NNW from its probable root zone in the MLT during the 1060–1020 Ma Grenvillian collision as a partially cooled slab. The remobilization of the Archaean parautochthon is attributed to this collision. In the Grenville Front zone, slightly older cooling ages and cooling rates initially faster than in the remaining part of the parautochthon are probably as a result of rapid (tectonic?) exhumation shortly after collision. The minor delay (20–30 Ma) in unroofing of the MT compared to the adjacent MLT is most likely related to post-1040 Ma extensional displacement along the Labelle shear zone. In terranes like those described above where metamorphism is diachronous, determination of cooling rates and the history of exhumation may be meaningless without a firm control on the regional structure. However, identification of contrasting cooling histories contributes to unravelling the independent movement of terranes.     

Development of low–centred ice–wedge polygons in the northernmost Ungava Peninsual, Queébec, Canada

Morphological and vegetation mapping and stratigraphic studies were carried out on a 60 by 250 m low–centered polygon field on a flood–plain of the Riviére Deception in the continuous permafrost zone of northernmost Ungava. Analyses of grain size, water and ice content, deformation structures, and macrorests were carried out on drill–core samples, up to a maximum depth of 3.19 m, and radiocarbon dates were obtained from several peat horizons. Five different vegetational habits were identified: uplifted banks, ice–wedge fissures, hummocky centres, wet polygon centres, and water ponds. The stratigraphic analyses revealed many sand layers and organic layers, alternating with a few layers of segregated ice. In the raises banks, brown fen peats represent former wet conditions prior to bank uplift. Total ice volumes of the core samples from polygon centres and banks averaged 60%, and were generally in the form of pore ice. Segregated ice was concentrated in ice wedges. The Low gradient of the polygon field and the shallow active layer are responsible for impded drainage. The origins of this isolated low–centred polygon field are discussed in terms of special local terrain conditions. River flooding since glacio–isostatic emergence at 6000 BP repeatedly spread alluvial sands onto the low flood–plain, which thus became progressively built up to its present elevation. Peat layers buried by these alluvial sands have permitted the changing local drainage conditions to be radiocarbon–dated for the last 2600 years for the core sites. Impeded drainage, low winter temperatures, probable thin snow cover, rapid sedimentation of flood–plain sands, and high volumetric ice contents have created the critical thermal regime necessary for repeated frost cracking in a polygonal pattern, with concomitant ice–wedge dev–elopment. Ice wedges developed at least as early as 2200 BP, causing the formation of low banks. Further growth of ice wedges deformed the peat and sand layers on the bank margins and led to the rise of the latter to heights of 0.5 to 1 m above the intervening low wet polygon centres. More water was then collected in the depressions, leading to a transformations of the vegetation cover from mossy heath to sphagnum bog, wet fen, sedge-covered ponds, and eventually in some cases to open-water pools. The stratigraphic evidence suggests that several generations of high banks formed and disappeared and that their position has changed. Deformation by continued ice–wedge growth has been insignificant since 1000 BP, However. A relatively thick surface peat layer also indicates that sand layers have not been contributed to the polygon field by flooding since ? 500 BP.     

Late Wisconsinan deglaciation and proglacial lakes development in the Charlevoix region,southeastern Québec,Canada

The Charlevoix region, in southeastern Québec, is characterized by a dramatic landscape formed by the junction of the Laurentian Highlands, the Charlevoix Astrobleme and the St Lawrence Estuary. At the Last Glacial Maximum (LGM), the region was completely covered by the Laurentide Ice Sheet (LIS). The complex topography of the region was the stage of many of the major deglacial events of southern Quebec (e.g. Goldthwait Sea Invasion, St Lawrence Ice‐Stream, Saint‐Narcisse Episode). We present a detailed reconstruction of the pattern of retreat of the LIS in the Charlevoix region based on the interpretation of ice‐marginal features (e.g. moraines, fans) and glaciolacustrine landforms and deposits, two extensive field campaigns, and the interpretation of high‐resolution 3D digital aerial photographs and LiDAR data. Our results indicate five moraine complexes in the region: the Rochette, the Brûlée, the Sainte‐Anne, the Saint‐Narcisse and the Mars‐Batiscan complexes. Deltas, fans, fine‐grained sediments, littoral deposits, drainage breaches and deposits were used to identify 91 palaeo‐proglacial lakes. The identification of these lakes and their relation to moraine complexes enabled the reconstruction of six stages of lake development during the Charlevoix deglaciation. The development of proglacial lakes occurred in all types of terrain (highlands, lowlands, transitory levels above marine limit). We conclude that local topography had a decisive effect on promoting both moraine deposition and lake development. We suggest that similar topographical regions (hilly‐mountainous) that were affected by major ice‐margin stabilizations during glacial retreat should have experience small lakes dominating valleys and topographical lows.     

Peatland development at the arctic tree line (Québec, Canada) influenced by flooding and permafrost

In this study, we documented the Holocene history of a peat plateau at the arctic tree line in northern Québec using stratigraphic and macrofossil analyses to highlight the effects of geomorphic setting in peatland development. Paludification of the site began about 6800 cal yr BP. From 6390 to 4120 cal yr BP, the peatland experienced a series of flooding events. The location of the peatland in a depression bounded by two small lakes likely explains its sensitivity to runoff. The proximity of a large hill bordering the peatland to the south possibly favored the inflow of mineral-laden water. The onset of permafrost aggradation in several parts of the peatland occurred after 3670 cal yr BP. Uplifting of the peatland surface caused by permafrost stopped the flooding. According to radiocarbon dating of the uppermost peat layers, permafrost distribution progressed from the east to the west of the peatland, indicating differential timing for the initiation of permafrost throughout the peatland. Most of the peatland was affected by permafrost growth during the Little Ice Age. Picea mariana macroremains at 6450 cal yr BP indicate that the species was present during the early stages of peatland development, which occurred soon after the sea regression.     

Use of micro-XRF chemical analysis for mapping volcanogenic massive sulfide related hydrothermal alteration: Application to the subaqueous felsic dome-flow complex of the Cap d'Ours section,Glenwood rhyolite,Rouyn-Noranda,Québec,Canada

A new analytical method using micro-X-ray fluorescence (XRF) is presented for the in situ analysis of major elements in rock samples. This approach has allowed for a separate study of hydrothermal alteration of matrix versus fragments in volcaniclastic material (i.e. flow breccia). This is particularly important for volcanogenic massive sulfide (VMS) exploration in subaqueous felsic dome-flow complexes, where brecciated facies are omnipresent and the imprint of hydrothermal alteration is typically heterogeneous. In this study, eleven elements are measured with a 1.7 by 1.3 mm window considered to be representative of each sample, based on replicate analyses. An average is calculated for the analyzed window and yields a nearly complete analysis with the exception of loss of ignition (LOI). Micro-XRF data were validated using whole rock XRF analyses performed on the same sample block. The application of this chemical method has been tested successfully on thin sections from the Cap d'Ours section of the Glenwood rhyolite in the Rouyn-Noranda region of Québec, Canada. With 58 samples spaced at approximately 50 m intervals, two styles of alteration zoning were recognized: (1) a lateral and concordant zoning expressed by vent-proximal silicification in the west grading toward vent-distal chlorite–sericite alteration to the east, and (2) vertical and discordant zoning expressed by stronger sericitization in the upper part of later volcanic quartz- and feldspar-phyric endogenous lobes. The former is typical of cooling induced by seawater interaction at the lava–water interface at temperatures greater than 400 °C, whereas the latter is related to lower temperature (< 300 °C) hydrothermal mineralization associated with endogenous lobe emplacement within the volcanic pile. The presented results clearly demonstrate the potential use of the micro-XRF data for characterizing weak to intense hydrothermal alteration in highly fragmented volcanic rocks.