Calculation of single-scattering albedos: Comparison of Mie results with Hapke approximations

The grain size of water ice can be determined from its near-infrared spectrum, which has numerous diagnostic absorption bands of different opacities. Models that have been used to determine water ice grain size from infrared spectra of icy outer Solar System objects have shown discrepancies in modeled grain size of a factor of two or more. Here the single-scattering albedo calculated using the commonly used Hapke model given by Roush [Roush, T.L., 1994. Icarus 108, 243-254] is compared with the exact calculation for spheres from a Mie series. An earlier approximation of single-scattering albedo called the Hapke “slab” model is also used in the comparison. All three models are implemented using the same optical constants for water ice at ∼110 K. Results are displayed for a large range of grain sizes from 1 μm to 1 mm. In general neither Hapke model can mimic the Rayleigh effects from particles sized near the wavelength of light that the Mie model predicts. For 10 μm particles, the slab model matches the Mie calculation quite well, but larger sizes are more discrepant. The Hapke/Roush model grain size needs to be ∼2.5 times larger to mimic the Mie results, and there are additional discrepancies in the continuum levels and band strengths. The Mie calculation for spheres is recommended for analysis of unknown remote sensing measurements, as it can mimic the spectra of oblate, prolate, and hollow particles given by equivalent sphere theories.     

The Christiansen Effect in Saturn’s narrow dusty rings and the spectral identification of clumps in the F ring

Stellar occultations by Saturn’s rings observed with the Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini spacecraft reveal that dusty features such as the F ring and the ringlets in the Encke and the Laplace Gaps have distinctive infrared transmission spectra. These spectra show a narrow optical depth minimum at wavelengths around 2.87 μm. This minimum is likely due to the Christiansen Effect, a reduction in the extinction of small particles when their (complex) refractive index is close to that of the surrounding medium. Simple Mie-scattering models demonstrate that the strength of this opacity dip is sensitive to the size distribution of particles between 1 and 100 μm across. Furthermore, the spatial resolution of the occultation data is sufficient to reveal variations in the transmission spectra within and among these rings. In both the Encke Gap ringlets and F ring, the opacity dip weakens with increasing local optical depth, which is consistent with the larger particles being concentrated near the cores of these rings. The Encke Gap ringlets also show systematically weaker opacity dips than the F ring and Laplace Gap ringlet, implying that the former has a smaller fraction of grains less than ∼30 μm across. However, the strength of the opacity dip varies most dramatically within the F ring; certain compact regions of enhanced optical depth lack an opacity dip and therefore appear to have a greatly reduced fraction of grains in the few-micron size range. Such spectrally-identifiable structures probably represent a subset of the compact optically-thick clumps observed by other Cassini instruments. These variations in the ring’s particle size distribution can provide new insights into the processes of grain aggregation, disruption and transport within dusty rings. For example, the unusual spectral properties of the F-ring clumps could perhaps be ascribed to small grains adhering onto the surface of larger particles in regions of anomalously low velocity dispersion.     

The source of widespread 3-μm absorption in Jupiter’s clouds: Constraints from 2000 Cassini VIMS observations

The Cassini flyby of Jupiter in 2000 provided spatially resolved spectra of Jupiter’s atmosphere using the Visual and Infrared Mapping Spectrometer (VIMS). A prominent characteristic of these spectra is the presence of a strong absorption at wavelengths from about 2.9 μm to 3.1 μm, previously noticed in a 3-μm spectrum obtained by the Infrared Space Observatory (ISO) in 1996. While Brooke et al. (Brooke, T.Y., Knacke, R.F., Encrenaz, T., Drossart, P., Crisp, D., Feuchtgruber, H. [1998]. Icarus 136, 1-13) were able to fit the ISO spectrum very well using ammonia ice as the sole source of particulate absorption, Sromovsky and Fry (Sromovsky, L.A., Fry, P.M. [2010]. Icarus 210, 211-229), using significantly revised NH₃ gas absorption models, showed that ammonium hydrosulfide (NH₄SH) provided a better fit to the ISO spectrum than NH₃, but that the best fit was obtained when both NH₃ and NH₄SH were present in the clouds. Although the large FOV of the ISO instrument precluded identification of the spatial distribution of these two components, the VIMS spectra at low and intermediate phase angles show that 3-μm absorption is present in zones and belts, in every region investigated, and both low- and high-opacity samples are best fit with a combination of NH₄SH and NH₃ particles at all locations. The best fits are obtained with a layer of small ammonia-coated particles (r ∼ 0.3 μm) overlying but often close to an optically thicker but still modest layer of much larger NH₄SH particles (r ∼ 10 μm), with a deeper optically thicker layer, which might also be composed of NH₄SH. Although these fits put NH₃ ice at pressures less than 500 mb, this is not inconsistent with the lack of prominent NH₃ features in Jupiter’s longwave spectrum because the reflectivity of the core particles strongly suppresses the NH₃ absorption features, at both near-IR and thermal wavelengths. Unlike Jupiter, Saturn lacks the broad 3-μm absorption feature, but does exhibit a small absorption near 2.965 μm, which resembles a similar jovian feature and suggests that both planets contain upper tropospheric clouds of sub-micron particles containing ammonia as a minor fraction.     

Regolith depth growth on an icy body orbiting Saturn and evolution of bidirectional reflectance due to surface composition changes

Using a Markov chain model, we consider the regolith growth on a small body in orbit around Saturn, subject to meteoritic bombardment, and assuming all impact ejecta are re-collected. We calculate the growth of regolith and the fractional pollution, assuming an initial pure ice body and amorphous carbon as a pollutant. We extend the meteorite flux of Cuzzi and Estrada (Cuzzi, J., Estrada, P. [1998]. Icarus 132, 1-35) to larger sizes to consider the effect of disruption of the moonlet on other moonlets in the ensemble. This is a relatively small effect, completely negligible for moonlets of 1 m radius. For the given impact model, fractional pollution reaches 22% for 1 m bodies, but only 3% for 10 m bodies, 1.7% for 20 m bodies, and 1% for 30 m bodies after 4 byr. By considering an ensemble of moonlets, which have identical cross-sections for releasing and capturing ejecta, this analysis can be extended to a model of particles in Saturn’s rings, where the calculated spectra can be compared to observed ring spectra. The measured spectral reflectance of Saturn’s rings from Cassini observations therefore constrains the size and age of the ring particles. The comparison between 1 m, 10 m, 20 m, and 30 m particles confirms that for larger ring mass, the current rings would be less polluted; for the largest particles, we expect negligible changes in the UV spectrum after 4 byr of meteoritic bombardment. We consider two end members for mixing of the meteoritic material: areal and intimate. Given the uncertainties in the actual mixing of the meteoritic infall and in its composition (as a worst case, we assume the meteoritic material is 100% amorphous carbon, intimately mixed) initially pure ice 30 m ring particles would darken after 4 byr of exposure by 15%.     

Remote sensing D/H ratios in methane ice: Temperature-dependent absorption coefficients of CH3D in methane ice and in nitrogen ice

The existence of strong absorption bands of singly deuterated methane (CH₃D) at wavelengths where normal methane (CH₄) absorbs comparatively weakly could enable remote measurement of D/H ratios in methane ice on outer Solar System bodies. We performed laboratory transmission spectroscopy experiments, recording spectra at wavelengths from 1 to 6 μm to study CH₃D bands at 2.47, 2.87, and 4.56 μm, wavelengths where ordinary methane absorption is weak. We report temperature-dependent absorption coefficients of these bands when the CH₃D is diluted in CH₄ ice and also when it is dissolved in N₂ ice, and describe how these absorption coefficients can be combined with data from the literature to simulate arbitrary D/H ratio absorption coefficients for CH₄ ice and for CH₄ in N₂ ice. We anticipate these results motivating new telescopic observations to measure D/H ratios in CH₄ ice on Triton, Pluto, Eris, and Makemake.     

Radiation-induced amorphization of crystalline ice

We study radiation-induced amorphization of crystalline ice, analyzing the results of three decades of experiments with a variety of projectiles, irradiation energy, and ice temperature, finding a similar trend of increasing resistance of amorphization with temperature and inconsistencies in results from different laboratories. We discuss the temperature dependence of amorphization in terms of the ‘thermal spike’ model. We then discuss the common use of the 1.65 μm infrared absorption band of water as a measure of degree of crystallinity, an increasingly common procedure to analyze remote sensing data of astronomical icy bodies. The discussion is based on new, high quality near-infrared reflectance absorption spectra measured between 1.4 and 2.2 μm for amorphous and crystalline ices irradiated with 225 keV protons at 80 K. We found that, after irradiation with 10¹⁵ protons cm⁻², crystalline ice films thinner than the ion range become fully amorphous, and that the infrared absorption spectra show no significant changes upon further irradiation. The complete amorphization suggests that crystalline ice observed in the outer Solar System, including trans-neptunian objects, may results from heat from internal sources or from the impact of icy meteorites or comets.     

Europa’s ridged plains and smooth low albedo plains: Distinctive compositions and compositional gradients at the leading side-trailing side boundary

This investigation uses linear mixture modeling employing cryogenic laboratory reference spectra to estimate surface compositions and water ice grain sizes of Europa’s ridged plains and smooth low albedo plains. Near-infrared spectra for 23 exposures of ridged plains materials are analyzed along with 11 spectra representing low albedo plains. Modeling indicates that these geologic units differ both in the relative abundance of non-ice hydrated species and in the abundance and grain sizes of water ice. The background ridged plains in our study area appear to consist predominantly of water ice (∼46%) with approximately equal amounts (on average) of hydrated sulfuric acid (∼27%) and hydrated salts (∼27%). The solutions for the smooth low albedo plains are dominated by hydrated salts (∼62%), with a relatively low mean abundance of water ice (∼10%), and an abundance of hydrated sulfuric acid similar to that found in ridged plains (∼27%). The model yields larger water ice grain sizes (100 μm versus 50-75 μm) in the ridged plains. The 1.5-μm water ice absorption band minimum is found at shorter wavelengths in the low albedo plains deposits than in the ridged plains (1.498 ± .003 μm versus 1.504 ± .001 μm). The 2.0-μm band minimum in the low albedo plains exhibits a somewhat larger blueshift (1.964 ± .006 μm versus 1.983 ± .006 μm for the ridged plains).The study area spans longitudes from 168° to 185°W, which includes Europa’s leading side-trailing side boundary. A well-defined spatial gradient of sulfuric acid hydrate abundance is found for both geologic units, with concentrations increasing in the direction of the trailing side apex. We associate this distribution with the exogenic effects of magnetospheric charged particle bombardment and associated chemical processing of surface materials (the radiolytic sulfur cycle). However, one family of low albedo plains exposures exhibits sulfuric acid hydrate abundances up to 33% lower than found for adjacent exposures, suggesting that these materials have undergone less processing, thus implying that these deposits may have been emplaced more recently.Modeling identifies high abundances (to 30%) of magnesium sulfate brines in the low albedo plains exposures. Our investigation marks the first spectroscopic identification of MgSO₄ brine on Europa. We also find significantly higher abundances of sodium-bearing species (bloedite and mirabilite) in the low albedo plains. The results illuminate the role of radiolytic processes in modifying the surface composition of Europa, and may provide new constraints for models of the composition of Europa’s putative subsurface ocean.     

Far ultraviolet spectral properties of Saturn’s rings from Cassini UVIS

Spectra taken by the Cassini Ultraviolet Imaging Spectrograph (UVIS) of Saturn’s C ring, B ring, Cassini Division, and A ring have been analyzed in order to characterize ring particle surface properties and water ice abundance in the rings. UVIS spectra sense the outer few microns of the ring particles. Spectra of the normalized reflectance (I/F) in all four regions show a characteristic water ice absorption feature near 165 nm. Our analysis shows that the fractional abundance of surface water ice is largest in the outer B ring and decreases by over a factor of 2 across the inner C ring. We calculate the mean path length of UV photons through icy ring particle regolith and the scattering asymmetry parameter using a Hapke reflectance model and a Shkuratov reflectance model to match the location of the water ice absorption edge in the data. Both models give similar retrieved values of the photon mean length, however the retrieved asymmetry (g) values are different. The photon mean path lengths are nearly uniform across the B and A rings. Shortward of 165 nm the rings exhibit a slope that turns up towards shorter wavelengths, while the UV slope of 180/150 nm (reflectance outside the water absorption ratioed to that inside the absorption band) tracks I/F with maxima in the outer B ring and in the central A ring. Retrieved values of the scattering asymmetry parameter show the regolith grains to be highly backscattering in the FUV spectral regime.     

The size distribution of Jupiter's main ring from Galileo imaging and spectroscopy

Galileo's Solid State Imaging experiment (SSI) obtained 36 visible wavelength images of Jupiter's ring system during the nominal mission (Ockert-Bell et al., 1999, Icarus 138, 188-213) and another 21 during the extended mission. The Near Infrared Mapping Spectrometer (NIMS) recorded an observation of Jupiter's main ring during orbit C3 at wavelengths from 0.7 to 5.2 μm; a second observation was attempted during orbit E4. We analyze the high phase angle NIMS and SSI observations to constrain the size distribution of the main ring's micron-sized dust population. This portion of the population is best constrained at high phase angles, as the light scattering behavior of small dust grains dominates at these geometries and contributions from larger ring particles are negligible. High phase angle images of the main ring obtained by the Voyager spacecraft covered phase angles between 173.8° and 176.9° (Showalter et al., 1987, Icarus 69, 458-498). Galileo images extend this range up to 178.6°. We model the Galileo phase curve and the ring spectra from the C3 NIMS ring observation as the combination of two power law distributions. Our analysis of the main ring phase curve and the NIMS spectra suggests the size distribution of the smallest ring particles is a power law with an index of 2.0±0.3 below a size of ∼15 μm that transitions to a power law with an index of 5.0±1.5 at larger sizes. This combined power law distribution, or “broken power law” distribution, yields a better fit to the NIMS data than do the power law distributions that have previously been fit to the Voyager imaging data (Showalter et al., 1987, Icarus 69, 458-498). The broken power law distribution reconciles the results of Showalter et al. (1987, Icarus 69, 458-498) and McMuldroch et al. (2000, Icarus 146, 1-11), who also analyzed the NIMS data, and can be considered as an obvious extension of a simple power law. This more complex size distribution could indicate that ring particle production rates and/or lifetimes vary with size and may relate to the physical processes that control their evolution. The significant near arm/far arm asymmetry reported elsewhere (see Showalter et al., 1987, Icarus 69, 458-498; Ockert-Bell et al., 1999, Icarus 138, 188-213) persists in the data even after the main ring is isolated in the SSI images. However, the sense of the asymmetry seen in Galileo images differs from that seen in Voyager images. We interpret this asymmetry as a broad-scale, azimuthal brightness variation. No consistent association with the magnetic field of Jupiter has been observed. It is possible that these longitudinal variations may be similar to the random brightness fluctuations observed in Saturn's F ring by Voyager (Smith et al., 1982, Science 215, 504-537) and during the 1995 ring plane crossings (Nicholson et al., 1996, Science 272, 509-515; Bosh and Rivkin, 1996, Science 272, 518-521; Poulet et al., 2000, Icarus 144, 135-148). Stochastic events may thus play a significant role in the evolution of the jovian main ring.     

Spectral reflectance properties of carbonaceous chondrites: 2. CM chondrites

We have examined the spectral reflectance properties and available modal mineralogies of 39 CM carbonaceous chondrites to determine their range of spectral variability and to diagnose their spectral features. We have also reviewed the published literature on CM mineralogy and subclassification, surveyed the published spectral literature and added new measurements of CM chondrites and relevant end members and mineral mixtures, and measured 11 parameters and searched pair-wise for correlations between all quantities. CM spectra are characterized by overall slopes that can range from modestly blue-sloped to red-sloped, with brighter spectra being generally more red-sloped. Spectral slopes, as measured by the 2.4:0.56 μm and 2.4 μm:visible region peak reflectance ratios, range from 0.90 to 2.32, and 0.81 to 2.24, respectively, with values <1 indicating blue-sloped spectra. Matrix-enriched CM spectra can be even more blue-sloped than bulk samples, with ratios as low as 0.85. There is no apparent correlation between spectral slope and grain size for CM chondrite spectra - both fine-grained powders and chips can exhibit blue-sloped spectra. Maximum reflectance across the 0.3-2.5 μm interval ranges from 2.9% to 20.0%, and from 2.8% to 14.0% at 0.56 μm. Matrix-enriched CM spectra can be darker than bulk samples, with maximum reflectance as low as 2.1%. CM spectra exhibit nearly ubiquitous absorption bands near 0.7, 0.9, and 1.1 μm, with depths up to 12%, and, less commonly, absorption bands in other wavelength regions (e.g., 0.4-0.5, 0.65, 2.2 μm). The depths of the 0.7, 0.9, and 1.1 μm absorption features vary largely in tandem, suggesting a single cause, specifically serpentine-group phyllosilicates. The generally high Fe content, high phyllosilicate abundance relative to mafic silicates, and dual Fe valence state in CM phyllosilicates, all suggest that the phyllosilicates will exhibit strong absorption bands in the 0.7 μm region (due to Fe³⁺-Fe²⁺ charge transfers), and the 0.9-1.2 μm region (due to Fe²⁺ crystal field transitions), and generally dominate over mafic silicates. CM petrologic subtypes exhibit a positive correlation between degree of aqueous alteration and depth of the 0.7 μm absorption band. This is consistent with the decrease in fine-grained opaques that accompanies aqueous alteration. There is no consistent relationship between degree of aqueous alteration and evidence for a 0.65 μm region saponite-group phyllosilicate absorption band. Spectra of different subsamples of a single CM can show large variations in absolute reflectance and overall slope. This is probably due to petrologic variations that likely exist within a single CM chondrite, as duplicate spectra for a single subsample show much less spectral variability. When the full suite of available CM spectra is considered, few clear spectral-compositional trends emerge. This indicates that multiple compositional and physical factors affect absolute reflectance, absorption band depths, and absorption band wavelength positions. Asteroids with reflectance spectra that exhibit absorption features consistent with CM spectra (i.e., absorption bands near 0.7 and 0.9 μm) include members from multiple taxonomic groups. This suggests that on CM parent bodies, aqueous alteration resulted in the consistent production of serpentine-group phyllosilicates, however resulting absolute reflectances and spectral shapes seen in CM reflectance spectra are highly variable, accounting for the presence of phyllosilicate features in reflectance spectra of asteroids across diverse taxonomic groups.     

Spectral reflectance properties of carbonaceous chondrites: 1. CI chondrites

Existing reflectance spectra of CI chondrites (18 spectra of 3 CIs) have been augmented with new (18 spectra of 2 CIs) reflectance spectra to ascertain the spectral variability of this meteorite class and provide insights into their spectral properties as a function of grain size, composition, particle packing, and viewing geometry. Particle packing and viewing geometry effects have not previously been examined for CI chondrites. The current analysis is focused on the 0.3-2.5 μm interval, as this region is available for the largest number of CI spectra. Reflectance spectra of powdered CI1 chondrites are uniformly dark (<10% maximum reflectance) but otherwise exhibit a high degree of spectral variability. Overall spectral slopes range from red (increasing reflectance with increasing wavelength) to blue (decreasing reflectance with increasing wavelength). A number of the CI spectra exhibit weak (<5% deep) absorption bands that can be attributed to both phyllosilicates and magnetite. Very weak absorption bands attributable to other CI phases, such as carbonates, sulfates, and organic matter may be present in one or a few spectra, but their identification is not robust. We found that darker spectra are generally correlated with bluer spectral slopes: a behavior most consistent with an increasing abundance of fine-grained magnetite and/or insoluble organic material (IOM), as no other CI opaque phase appears able to produce concurrent darkening and bluing. Magnetite can also explain the presence of an absorption feature near 1 μm in some CI spectra. The most blue-sloped spectra are generally associated with the larger grain size samples. For incidence and emission angles <60°, increasing phase angle results in darker and redder spectra, particularly below ∼1 μm. At high incidence angles (60°), increasing emission angle results in brighter and redder spectra. More densely packed samples and underdense (fluffed) samples show lower overall reflectance than normally packed and flat-surface powdered samples. Some B-class asteroids exhibit selected spectral properties consistent with CI chondrites, although perfect spectral matches have not been found. Because many CI chondrite spectra exhibit absorption features that can be related to specific mineral phases, the search for CI parent bodies can fruitfully be conducted using such parameters.     

A spherical Monte-Carlo model of aerosols: Validation and first applications to Mars and Titan

The atmospheres of Mars and Titan are loaded with aerosols that impact remote sensing observations of their surface. Here we present the algorithm and the first applications of a radiative transfer model in spherical geometry designed for planetary data analysis. We first describe a fast Monte-Carlo code that takes advantage of symmetries and geometric redundancies. We then apply this model to observations of the surface of Mars and Titan at the terminator as acquired by OMEGA/Mars Express and VIMS/Cassini. These observations are used to probe the vertical distribution of aerosols down to the surface. On Mars, we find the scale height of dust particles to vary between 6 km and 12 km depending on season. Temporal variations in the vertical size distribution of aerosols are also highlighted. On Titan, an aerosols scale height of 80 ± 10 km is inferred, and the total optical depth is found to decrease with wavelength as a power-law with an exponent of −2.0 ± 0.4 from a value of 2.3 ± 0.5 at 1.08 μm. Once the aerosols properties have been constrained, the model is used to retrieve surface reflectance properties at high solar zenith angles and just after sunset.     

The near-IR spectrum of Titan modeled with an improved methane line list

We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10⁻⁴, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν₅ + 3ν₆ and 2ν₃ + 2ν₆ bands of CH₃D.     

Micrometer-sized ice particles for planetary-science experiments - I. Preparation, critical rolling friction force, and specific surface energy

Coagulation models assume a higher sticking threshold for micrometer-sized ice particles than for micrometer-sized silicate particles. However, in contrast to silicates, laboratory investigations of the collision properties of micrometer-sized ice particles (in particular, of the most abundant H₂O-ice) have not been conducted yet. Thus, we used two different experimental methods to produce micrometer-sized H₂O-ice particles, i.e. by spraying H₂O droplets into liquid nitrogen and by spraying H₂O droplets into a cold nitrogen atmosphere. The mean particle radii of the ice particles produced with these experimental methods are (1.49 ± 0.79) μm and (1.45 ± 0.65) μm. Ice aggregates composed of the micrometer-sized ice particles are highly porous (volume filling factor: ? = 0.11 ± 0.01) or rather compact (volume filling factor: ? = 0.72 ± 0.04), depending on the method of production. Furthermore, the critical rolling friction force of F_Roll,ice = (114.8 ± 23.8) × 10⁻¹⁰ N was measured for micrometer-sized ice particles, which exceeds the critical rolling friction force of micrometer-sized SiO₂ particles . This result implies that the adhesive bonding between micrometer-sized ice particles is stronger than the bonding strength between SiO₂ particles. An estimation of the specific surface energy of micrometer-sized ice particles, derived from the measured critical rolling friction forces and the surface energy of micrometer-sized SiO₂ particles, results in γ_ice = 0.190 J m⁻².     

Revised vertical cloud structure of Uranus from UKIRT/UIST observations and changes seen during Uranus’ Northern Spring Equinox from 2006 to 2008: Application of new methane absorption data and comparison with Neptune

Long-slit spectroscopy observations of Uranus by the United Kingdom InfraRed Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s Northern Spring Equinox in December 2007.These spectra were analysed and presented by Irwin et al. (Irwin, P.G.J., Teanby, N.A., Davis, G.R. [2009]. Icarus 203, 287-302), but since publication, a new set of methane absorption data has become available (Karkoschka, E., Tomasko, M. [2010]. Methane absorption coefficients for the jovian planets from laboratory, Huygens, and HST data. Icarus 205, 674-694.), which appears to be more reliable at the cold temperatures and high pressures of Uranus’ deep atmosphere. We have fitted k-coefficients to these new methane absorption data and we find that although the latitudinal variation and inter-annual changes reported by Irwin et al. (2009) stand, the new k-data place the main cloud deck at lower pressures (2-3 bars) than derived previously in the H-band of ∼3-4 bars and ∼3 bars compared with ∼6 bars in the J-band. Indeed, we find that using the new k-data it is possible to reproduce satisfactorily the entire observed centre-of-disc Uranus spectrum from 1 to 1.75 μm with a single cloud at 2-3 bars provided that we make the particles more back-scattering at wavelengths less than 1.2 μm by, for example, increasing the assumed single-scattering albedo from 0.75 (assumed in the J and H-bands) to near 1.0. In addition, we find that using a deep methane mole fraction of 4% in combination with the associated warm ‘F’ temperature profile of Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92, 14987-15001), the retrieved cloud deck using the new (Karkoschka and Tomasko, 2010) methane absorption data moves to between 1 and 2 bars.The same methane absorption data and retrieval algorithm were applied to observations of Neptune made during the same programme and we find that we can again fit the entire 1-1.75 μm centre-of-disc spectrum with a single cloud model, providing that we make the stratospheric haze particles (of much greater opacity than for Uranus) conservatively scattering (i.e. ω = 1) and we also make the deeper cloud particles, again at around the 2 bar level more reflective for wavelengths less than 1.2 μm. Hence, apart from the increased opacity of stratospheric hazes in Neptune’s atmosphere, the deeper cloud structure and cloud composition of Uranus and Neptune would appear to be very similar.     

Morphology, stratigraphy, and mineralogical composition of a layered formation covering the plateaus around Valles Marineris, Mars: Implications for its geological history

An extensive layered formation covers the high plateaus around Valles Marineris. Mapping based on HiRISE, CTX and HRSC images reveals these layered deposits (LDs) crop out north of Tithonium Chasma, south of Ius Chasma, around West Candor Chasma, and southwest of Juventae Chasma and Ganges Chasma. The estimated area covered by LDs is ∼42,300 km². They consist of a series of alternating light and dark beds, a 100 m in total thickness that is covered by a dark unconsolidated mantle possibly resulting from their erosion. Their stratigraphic relationships with the plateaus and the Valles Marineris chasmata indicate that the LDs were deposited during the Early- to Late Hesperian, and possibly later depending on the region, before the end of the backwasting of the walls near Juventae Chasma, and probably before Louros Valles sapping near Ius Chasma. Their large spatial coverage and their location mainly on highly elevated plateaus lead us to conclude that LDs correspond to airfall dust and/or volcanic ash. The surface of LDs is characterized by various morphological features, including lobate ejecta and pedestal craters, polygonal fractures, valleys and sinuous ridges, and a pitted surface, which are all consistent with liquid water and/or water ice filling the pores of LDs. LDs were episodically eroded by fluvial processes and were possibly modified by sublimation processes. Considering that LDs correspond to dust and/or ash possibly mixed with ice particles in the past, LDs may be compared to Dissected Mantle Terrains currently observed in mid- to high latitudes on Mars, which correspond to a mantle of mixed dust and ice that is partially or totally dissected by sublimation. The analysis of CRISM and OMEGA hyperspectral data indicates that the basal layer of LDs near Ganges Chasma exhibits spectra with absorption bands at ∼1.4 μm, and ∼1.9 μm and a large deep band between ∼2.21 and ∼2.26 μm that are consistent with previous spectral analysis in other regions of LDs. We interpret these spectral characteristics as an enrichment of LDs in opaline silica or by Al-phyllosilicate-rich layers being overlain by hydroxylated ferric sulfate-rich layers. These alteration minerals are consistent with the aqueous alteration of LDs at low temperatures.     

Retrieval and tentative indentification of the 3 μm spectral feature in Titan's haze

Recently, an unidentified 3.3-3.4 μm feature found in the solar occultation spectra of the atmosphere of Titan observed by Cassini/VIMS was tentatively attributed to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules, but without properly extracting the feature from adjacent influences of strong CH₄ and weak C₂H₆ absorptions (Bellucci et al., 2009). In this work, we retrieve the detailed spectral feature using a radiative transfer program including absorption and fluorescent emission of both molecules, as well as absorption and scattering by haze particles. The spectral features of the haze retrieved from the VIMS data at various altitudes are similar to each other, indicating relatively uniform spectral properties of the haze with altitude. However, slight deviations observed near 127 km and above 300 km suggest inhomogeneity at these altitudes. We find that the positions of the major spectral peaks occur at 3.33-3.37 μm, which are somewhat different from the typical 3.3 μm aromatic or 3.4 μm aliphatic C-H stretches usually seen in the spectra of dust particles of the interstellar medium and comets. The peaks, however, coincide with those of the solid state spectra of C₂H₆, CH₄, and CH₃CN; and a broad shoulder from 3.37 to 3.50 μm coincides with those of C₅H₁₂ and C₆H₁₂ as well as those of typical aliphatic C-H stretches. This result combined with high-altitude (∼1000 km) haze formation process recently reported by Waite et al. (2007) opens a new question on the chemical composition of the haze particles. We discuss the possibility that the 3 μm feature may be due to the solid state absorption bands of these molecules (or some other molecules) and we advocate additional laboratory measurements for the ices of hydrocarbon and nitrogen-bearing molecules present in Titan's atmosphere for the identification of this 3 μm feature.     

Galileo in-situ dust measurements in Jupiter’s gossamer rings

Galileo was the first artificial satellite to orbit Jupiter. During its late orbital mission the spacecraft made two passages through the giant planet’s gossamer ring system. The impact-ionization dust detector on board successfully recorded dust impacts during both ring passages and provided the first in-situ measurements from a dusty planetary ring. During the first passage—on 5 November 2002 while Galileo was approaching Jupiter—dust measurements were collected until a spacecraft anomaly at 2.33R_J (Jupiter radii) just 16 min after a close flyby of Amalthea put the spacecraft into a safing mode. The second ring passage on 21 September 2003 provided ring dust measurements down to about 2.5R_J and the Galileo spacecraft was destroyed shortly thereafter in a planned impact with Jupiter. In all, a few thousand dust impacts were counted with the instrument accumulators during both ring passages, but only a total of 110 complete data sets of dust impacts were transmitted to Earth. Detected particle sizes range from about 0.2 to 5 μm, extending the known size distribution by an order of magnitude towards smaller particles than previously derived from optical imaging [Showalter, M.R., de Pater, I., Verbanac, G., Hamilton, D.P., Burns, J.A., 2008. Icarus 195, 361-377; de Pater, I., Showalter, M.R., Macintosh, B., 2008. Icarus 195, 348-360]. The grain size distribution increases towards smaller particles and shows an excess of these tiny motes in the Amalthea gossamer ring compared to the Thebe ring. The size distribution for the Amalthea ring derived from our in-situ measurements for the small grains agrees very well with the one obtained from images for large grains. Our analysis shows that particles contributing most to the optical cross-section are about 5 μm in radius, in agreement with imaging results. The measurements indicate a large drop in particle flux immediately interior to Thebe’s orbit and some detected particles seem to be on highly-tilted orbits with inclinations up to 20°. Finally, the faint Thebe ring extension was detected out to at least 5R_J, indicating that grains attain higher eccentricities than previously thought. The drop interior to Thebe, the excess of submicron grains at Amalthea, and the faint ring extension indicate that grain dynamics is strongly influenced by electromagnetic forces. These findings can all be explained by a shadow resonance as detailed by Hamilton and Krüger [Hamilton, D.P., Krüger, H., 2008. Nature 453, 72-75].     

HST observations of spokes in Saturn's B ring

As part of a long-term study of Saturn's rings, we have used the Hubble Space Telescope's (HST) Wide Field and Planetary Camera (WFPC2) to obtain several hundred high resolution images from 1996 to 2004, spanning the full range of ring tilt and solar phase angles accessible from the Earth. Using these multiwavelength observations and HST archival data, we have measured the photometric properties of spokes in the B ring, visible in a substantial number of images. We determined the spoke particle size distribution by fitting the wavelength-dependent extinction efficiency of a prominent, isolated spoke, using a Mie scattering model. Following Doyle and Grün (1990, Icarus 85, 168-190), we assumed that the spoke particles were sub-micron size spheres of pure water ice, with a Hansen-Hovenier size distribution (Hansen and Hovenier, 1974, J. Atmos. Sci. 31, 1137-1160). The WFPC2 wavelength coverage is broader than that of the Voyager data, resulting in tighter constraints on the nature of spoke particles. The effective particle size was reff=0.57±0.05 μm, and the size distribution was quite narrow with a variance of b=0.09±0.03, very similar to the results of Doyle and Grün (1990, Icarus 85, 168-190), and consistent with predictions of plasma cloud models for spoke production from meteoritic impacts (Goertz and Morfill, 1983, Icarus 53, 219-229; Goertz, 1984, Adv. Space Res. 4, 137-141). In all, we identified 36 spokes or spoke complexes, predominantly on the morning (east) ansa. The photometric contrast of the spokes is strongly dependent on effective ring opening angle, Beff. Spokes were clearly visible on the north face of the rings in 1994, just prior to the most recent ring plane crossing (RPX) epoch, and on the south face shortly after RPX. However, spokes were both less abundant and fainter as the rings opened up, and no spokes were detected after 18 October 1998 (Beff=−15.43°), when a single faint spoke was seen on the morning ansa. The high resolution and photometric quality of the WFPC2 images enabled us to set a detection limit of ?1% in fractional brightness contrast for spokes for the post-1998 observations. We compare the observed trend of spoke contrast with Beff to radiative transfer calculations based on three models of the distribution of spoke material. In the first, the spoke “haze” is uniformly mixed with macroscopic B ring particles. No variation in spoke contrast is predicted for single-scattering, in this case, and only a modest decrease in contrast with Beff is predicted when multiple scattering is taken into account. In the second model, the spoke dust occupies an extended layer that is thicker than the B ring, which gives virtually identical results to a third case, when the haze layer lies exclusively above the ring. Multiple-scattering Monte Carlo calculations for these two extended haze models match the trend of spoke contrast exceptionally well. We compute the predicted spoke contrast for a wide variety of viewing geometries, including forward- and backscattering. Based on these results, spokes should be easily detectable during the Cassini mission when the rings are viewed at relatively small (|B|?10°) ring opening angles.