A new model of the hydrogen and helium-broadened microwave opacity of ammonia based on extensive laboratory measurements

Close to 2000 laboratory measurements of the microwave opacity and refractivity of gaseous NH₃ in an H₂/He atmosphere have been conducted in the 1.1-20 cm wavelength range (1.5-27 GHz) at pressures from 30 mbar to 12 bar and at temperatures from 184 to 450 K. The mole fraction of NH₃ ranged from 0.06 to 6% with some additional measurements of pure NH₃. The high accuracy of these results have enabled development of a new model for the opacity of NH₃ in a H₂/He atmosphere under jovian conditions. The model employs the Ben-Reuven lineshape applied to the published inversion line center frequencies and intensities of NH₃ (JPL Catalog—[Pickett, H.M., Poynter, R.L., Cohen, E.A., Delitsky, M.L., Pearson, J.C., Müller, H.S.P., 1998. J. Quant. Spectrosc. Radiat. Trans. 60, 883-890]) with empirically-fitted line parameters for H₂ and He broadening, and for the self-broadening of some previously unmeasured ammonia inversion lines. The new model for ammonia opacity will provide reliable results for temperatures from 150 to 500 K, at pressures up to 50 bar and at frequencies up to 40 GHz. These results directly impact the retrieval of jovian atmospheric constituent abundances from the Galileo Probe radio signal absorption measurements, from microwave emission measurements conducted with Earth-based radio telescopes and with the future NASA Juno mission, and studies of Saturn's atmosphere conducted with the Cassini Radio Science Experiment and the Cassini RADAR 2.1 cm passive radiometer.     

Vertical profile of H2SO4 vapor at 70-110 km on Venus and some related problems

The vertical profile of H₂SO₄ vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H₂O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H₂O and H₂SO₄ and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H₂SO₄ vapor mixing ratio is ∼10⁻¹² at 70 and 110 km with a deep minimum of 3 × 10⁻¹⁸ at 88 km. The H₂O-H₂SO₄ system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H₂SO₄ is 1.6 × 10⁵ cm⁻² s⁻¹ at 70 km and 23 cm⁻² s⁻¹ at 90 km. The calculated abundance of H₂SO₄ vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 10⁶ and 10⁹, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H₂SO₄ (impossible for a source of SO_X), and cross sections for H₂SO₄·H₂O (impossible above the pure H₂SO₄) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SO_X at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SO_X on Venus remains unclear and probably does not exist.     

Vertical cloud structure of Uranus from UKIRT/UIST observations and changes seen during Uranus’ northern spring equinox from 2006 to 2008

Long-slit spectroscopy observations of Uranus by the United Kingdom Infrared Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s northern spring equinox in December 2007.The observed reflectance spectra in the Long J (1.17-1.31 μm) and H (1.45-1.65 μm) bands, obtained with the slit aligned along Uranus’ central meridian, have been fitted with an optimal estimation retrieval model to determine the vertical cloud profile from 0.1 to 6-8 bar over a wide range of latitudes. Context images in a number of spectral bands were used to discriminate general zonal cloud structural changes from passing discrete clouds. From 2006 to 2007 reflection from deep clouds at pressures between 2 and 6-8 bar increased at all latitudes, although there is some systematic uncertainty in the absolute pressure levels resulting from extrapolating the methane coefficients of Irwin et al. (Irwin, P.G.J., Sromovsky, L.A., Strong, E.K., Sihra, K., Teanby, N.A., Bowles, N., Calcutt, S.B., Remedios, J.J. [2006] Icarus, 181, 309-319) at pressures greater than 1 bar, as noted by Tomasko et al. and Karkoschka and Tomasko (Tomasko, M.G., Bezard, B., Doose, L., Engel, S., Karkoschka, E. [2008] Planet. Space Sci., 56, 624-647; Karkoschka, E., Tomasko, M. [2009] Icarus). However, from 2007 to 2008 reflection from these clouds throughout the southern hemisphere and from both northern and southern mid-latitudes (30° N,S) diminished. As a result, the southern polar collar at 45°S has diminished in brightness relative to mid-latitudes, a similar collar at 45°N has become more prominent (e.g. Rages, K.A., Hammel, H.B., Sromovsky, L. [2007] Bull. Am. Astron. Soc., 39, 425; Sromovsky, L.A., Fry, P.M., Ahue, W.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R., van Dam, M.A. [2008] vol. 40 of AAS/Division for Planetary Sciences Meeting Abstracts, pp. 488-489; Sromovsky, L.A., Ahue, W.K.M., Fry, P.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R. [2009] Icarus), and the lowering reflectivity from mid-latitudes has left a noticeable brighter cloud zone at the equator (e.g. Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557;Karkoschka, E., Tomasko, M. [2009] Icarus). For such substantial cloud changes to have occurred in just two years suggests that the circulation of Uranus’ atmosphere is much more vigorous and/or efficient than is commonly thought. The composition of the main observed cloud decks between 2 and 6-8 bar is unclear, but the absence of the expected methane cloud at 1.2-1.3 bar (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987] J. Geophys. Res., 92, 14987-15001) is striking (as previously noted by, among others, Sromovsky, L.A., Irwin, P.G.J., Fry, P.M. [2006] Icarus, 182, 577-593; Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557; Sromovsky, L.A., Fry, P.M. [2008] Icarus, 193, 252-266; Karkoschka, E., Tomasko, M. [2009] Icarus) and suggests that cloud particles may be considerably different from pure condensates and may be linked with stratospheric haze particles drizzling down from above, or that tropospheric hazes are generated near the methane condensation level and then drizzle down to deep pressures as suggested by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus).The retrieved cloud structures were also tested for different assumptions of the deep methane mole fraction, which Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus) find may vary from ∼1-2% in polar regions to perhaps as much as 4% equatorwards of 45°N,S. We found that such variations did not significantly affect our conclusions.     

The source of widespread 3-μm absorption in Jupiter’s clouds: Constraints from 2000 Cassini VIMS observations

The Cassini flyby of Jupiter in 2000 provided spatially resolved spectra of Jupiter’s atmosphere using the Visual and Infrared Mapping Spectrometer (VIMS). A prominent characteristic of these spectra is the presence of a strong absorption at wavelengths from about 2.9 μm to 3.1 μm, previously noticed in a 3-μm spectrum obtained by the Infrared Space Observatory (ISO) in 1996. While Brooke et al. (Brooke, T.Y., Knacke, R.F., Encrenaz, T., Drossart, P., Crisp, D., Feuchtgruber, H. [1998]. Icarus 136, 1-13) were able to fit the ISO spectrum very well using ammonia ice as the sole source of particulate absorption, Sromovsky and Fry (Sromovsky, L.A., Fry, P.M. [2010]. Icarus 210, 211-229), using significantly revised NH₃ gas absorption models, showed that ammonium hydrosulfide (NH₄SH) provided a better fit to the ISO spectrum than NH₃, but that the best fit was obtained when both NH₃ and NH₄SH were present in the clouds. Although the large FOV of the ISO instrument precluded identification of the spatial distribution of these two components, the VIMS spectra at low and intermediate phase angles show that 3-μm absorption is present in zones and belts, in every region investigated, and both low- and high-opacity samples are best fit with a combination of NH₄SH and NH₃ particles at all locations. The best fits are obtained with a layer of small ammonia-coated particles (r ∼ 0.3 μm) overlying but often close to an optically thicker but still modest layer of much larger NH₄SH particles (r ∼ 10 μm), with a deeper optically thicker layer, which might also be composed of NH₄SH. Although these fits put NH₃ ice at pressures less than 500 mb, this is not inconsistent with the lack of prominent NH₃ features in Jupiter’s longwave spectrum because the reflectivity of the core particles strongly suppresses the NH₃ absorption features, at both near-IR and thermal wavelengths. Unlike Jupiter, Saturn lacks the broad 3-μm absorption feature, but does exhibit a small absorption near 2.965 μm, which resembles a similar jovian feature and suggests that both planets contain upper tropospheric clouds of sub-micron particles containing ammonia as a minor fraction.     

Revised vertical cloud structure of Uranus from UKIRT/UIST observations and changes seen during Uranus’ Northern Spring Equinox from 2006 to 2008: Application of new methane absorption data and comparison with Neptune

Long-slit spectroscopy observations of Uranus by the United Kingdom InfraRed Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s Northern Spring Equinox in December 2007.These spectra were analysed and presented by Irwin et al. (Irwin, P.G.J., Teanby, N.A., Davis, G.R. [2009]. Icarus 203, 287-302), but since publication, a new set of methane absorption data has become available (Karkoschka, E., Tomasko, M. [2010]. Methane absorption coefficients for the jovian planets from laboratory, Huygens, and HST data. Icarus 205, 674-694.), which appears to be more reliable at the cold temperatures and high pressures of Uranus’ deep atmosphere. We have fitted k-coefficients to these new methane absorption data and we find that although the latitudinal variation and inter-annual changes reported by Irwin et al. (2009) stand, the new k-data place the main cloud deck at lower pressures (2-3 bars) than derived previously in the H-band of ∼3-4 bars and ∼3 bars compared with ∼6 bars in the J-band. Indeed, we find that using the new k-data it is possible to reproduce satisfactorily the entire observed centre-of-disc Uranus spectrum from 1 to 1.75 μm with a single cloud at 2-3 bars provided that we make the particles more back-scattering at wavelengths less than 1.2 μm by, for example, increasing the assumed single-scattering albedo from 0.75 (assumed in the J and H-bands) to near 1.0. In addition, we find that using a deep methane mole fraction of 4% in combination with the associated warm ‘F’ temperature profile of Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92, 14987-15001), the retrieved cloud deck using the new (Karkoschka and Tomasko, 2010) methane absorption data moves to between 1 and 2 bars.The same methane absorption data and retrieval algorithm were applied to observations of Neptune made during the same programme and we find that we can again fit the entire 1-1.75 μm centre-of-disc spectrum with a single cloud model, providing that we make the stratospheric haze particles (of much greater opacity than for Uranus) conservatively scattering (i.e. ω = 1) and we also make the deeper cloud particles, again at around the 2 bar level more reflective for wavelengths less than 1.2 μm. Hence, apart from the increased opacity of stratospheric hazes in Neptune’s atmosphere, the deeper cloud structure and cloud composition of Uranus and Neptune would appear to be very similar.     

Keck adaptive optics images of Jupiter’s north polar cap and Northern Red Oval

We present observations at near-infrared wavelengths (1-5 μm) of Jupiter’s north polar region and Northern Red Oval (NN-LRS-1). The observations were taken with the near-infrared camera NIRC2 coupled to the adaptive optics system on the 10-m W.M. Keck Telescope on UT 21 August 2010. At 5-μm Jupiter’s disk reveals considerable structure, including small bright rings which appear to surround all small vortices. It is striking, though, that no such ring is seen around the Northern Red Oval. In de Pater et al. [2010a. Icarus 210, 742-762], we showed that such rings also exist around all small vortices in Jupiter’s southern hemisphere, and are absent around the Great Red Spot and Red Oval BA. We show here that the vertical structure and extent of the Northern Red Oval is very similar to that of Jupiter’s Red Oval BA. These new observations of the Northern Red Oval, therefore, support the idea of a dichotomy between small and large anticyclones, in which ovals larger than about two Rossby deformation radii do not have 5-μm bright rings. In de Pater et al. [2010a. Icarus 210, 742-762], we explained this difference in terms of the secondary circulations within the vortices. We further compare the brightness distribution of our new 5-μm images with previously published radio observations of Jupiter, highlighting the depletion of NH₃ gas over areas that are bright at 5 μm.     

Post-equinox observations of Uranus: Berg’s evolution, vertical structure, and track towards the equator

We present observations of Uranus taken with the near-infrared camera NIRC2 on the 10-m W.M. Keck II telescope, the Wide Field Planetary Camera 2 (WFPC2) and the Wide Field Camera 3 (WFC3) on the Hubble Space Telescope (HST) from July 2007 through November 2009. In this paper we focus on a bright southern feature, referred to as the “Berg.” In Sromovsky et al. (Sromovsky, L.A., Fry, P.M., Hammel, H.B., Ahue, A.W., de Pater, I., Rages, K.A., Showalter, M.R., van Dam, M. [2009]. Icarus 203, 265-286), we reported that this feature, which oscillated between latitudes of −32° and −36° for several decades, suddenly started on a northward track in 2005. In this paper we show the complete record of observations of this feature’s track towards the equator, including its demise. After an initially slow linear drift, the feature’s drift rate accelerated at latitudes ∣θ∣ < 25°. By late 2009 the feature, very faint by then, was spotted at a latitude of −5° before disappearing from view. During its northward track, the feature’s morphology changed dramatically, and several small bright unresolved features were occasionally visible poleward of the main “streak.” These small features were sometimes visible at a wavelength of 2.2 μm, indicative that the clouds reached altitudes of ∼0.6 bar. The main part of the Berg, which is generally a long sometimes multipart streak, is estimated to be much deeper in the atmosphere, near 3.5 bars in 2004, but rising to 1.8-2.5 bars in 2007 after it began its northward drift. Through comparisons with Neptune’s Great Dark Spot and simulations of the latter, we discuss why the Berg may be tied to a vortex, an anticyclone deeper in the atmosphere that is visible only through orographic companion clouds.     

A survey of small fast rotating asteroids among the near-Earth asteroid population

A survey of 62 small near-Earth asteroids was conducted to determine the rotation state of these objects and to search for rapid rotation. Since results for 9 of the asteroids were previously published (Pravec, P., Hergenrother, C.W., Whiteley, R.J., Šarounová, L., Kušnirák, P., Wolf, M. [2000]. Icarus 147, 477-486; Pravec, P. et al. [2005] Icarus 173, 108-131; Whiteley, R.J., Tholen, D.J., Hergenrother, C.W. [2002a]. Icarus 157, 139-154; Hergenrother, C.W., Whiteley, R.J., Christensen, E.J. [2009]. Minor Planet Bull. 36, 16-18.), this paper will present results for the remaining 53 objects. Rotation periods significantly less than 2 h are indicative of intrinsic strength in the asteroids, while periods longer than 2 h are typically associated with gravitationally bound aggregates. Asteroids with absolute magnitude (H) values ranging from 20.4 to 27.4 were characterized. The slowest rotator with a definite period is 2004 BW₁₈ with a period of 8.3 h, while 2000 DO₈ and 2000 WH₁₀ are the fastest with periods of 1.3 min. A minimum of two-thirds of asteroids with H > 20 are fast rotating and have periods significantly faster than 2.0 h. The percentage of rapid rotators increases with decreasing size and a minimum of 79% of H ? 24 objects are rapid rotators. Slowly-rotating objects, some with periods as long as 10-20 h, make up a small though significant fraction of the small asteroid population. There are three fast rotators with relatively large possible diameters (D): 2001 OE₈₄ with 470 ? D ? 820 m (Pravec, P., Kušnirák, P., Šarounová, L., Harris, A.W., Binzel, R.P., Rivkin, A.S. [2002b]. Large coherent Asteroid 2001 OE84. In: Warmbein, B. (Eds.), Proceedings of Asteroids, Comets, Meteors - ACM 2002. Springer, Berlin, pp. 743-745), 2001 FE₉₀ with 265 ? D ? 594 m (Hicks, M., Lawrence, K., Rhoades, H., Somers, J., McAuley, A., Barajas, T. [2009]. The Astronomer’s Telegrams, # 2116), and 2001 VF₂ with a possible D of 145 ? D ? 665 m. Using the diameters derived from nominal absolute magnitudes and albedos, the remainder of the fast rotating population is completely consistent with D ? 200 m. Even when taking into account the largest possible uncertainties in the determination of diameters, the remainder must all have D ? 400 m. With the exceptions of 2001 OE₈₄, this result agrees with previous upper diameter limits for fast rotators in Pravec and Harris (Pravec, P., Harris, A.W. [2000]. Icarus 148, 589-593) and Whiteley et al. (Whiteley, R.J, Tholen, D.J., Hergenrother, C.W. [2002a]. Icarus 157, 139-154.     

Viking observation of water vapor on Mars: Revision from up-to-date spectroscopy and atmospheric models

A reanalysis of the Mars Atmospheric Water Detector (MAWD, Viking 1 and 2 Orbiters) Planetary Data System (PDS) data set (Jakosky, B.M., Farmer, C.B. [1982]. J. Geophys. Res. 87 (B4), 2999-3019) is presented taking into account a new spectroscopic database and improved atmospheric model assumptions. Starting from HITRAN 2004 edition and later (Rothman, L.S., and 29 colleagues [2005]. J. Quant. Spectrosc. Radiat. Trans. 96, 139-204), the number of lines in the 1.38-μm band has been significantly increased, and their parameters have been modified. The implication of this new spectroscopic data and atmospheric model based on Martian Climate Database (MCD, Forget, F., Hourdin, F., Fournier, R., Hourdin, C., Talagrand, O., Collins, M., Lewis, S.R., Read, P.L., Huot, J.-P. [1999]. J. Geophys. Res. 104 (E10), 24155-24176) gives a significant impact on the H₂O retrieval: the total H₂O abundance after the reanalysis has decreased twofold in all seasons and most of geographic locations. Overall decrease is associated with larger cumulative strength of the band in HITRAN 2004; low saturation height of water profiles imposed by MCD significantly contributes to decrease of summer polar maximum. Revised MAWD data are compared with later H₂O measurements on Mars Global Surveyor (MGS) and Mars-Express (MEX). A good agreement with SPICAM/MEX near-IR (1.38-μm band) measurements is found. However, both sets of near-IR measurements are systematically below TES/MGS results obtained in thermal infrared, with a factor of 1.5-2.0. This difference might be associated with remaining ambiguity of the near IR spectral data, and of line broadening in CO₂ in both spectral ranges. The reanalyzed MAWD data are in much better agreement with later measurements suggesting more homogeneous, and significantly dryer water cycle on Mars, with no signature of change between the Viking epoch (MY12-14) and MGS-Mars-Express measurements (MY24-29).     

Comparison of PFS and TES observations of temperature and water vapor in the martian atmosphere

The interval from L_s = 330° in Mars Year (MY) 26 until L_s = 84° in MY 27 has been used to compare and validate measurements from the Mars Global Surveyor Thermal Emission Spectrometer (TES) and the Mars Express Planetary Fourier Spectrometer (PFS). We studied differences between atmospheric temperatures observed by the two instruments. The best agreement between atmospheric temperatures was found at 50 Pa between 40°S and 40°N latitude, where differences were within ±5 K. For other atmospheric levels, differences as large as ∼25 K were observed between the two instruments at some locations. The largest temperature differences occurred mainly over the Hellas Planitia, Argyre Planitia, Tharsis and Valles Marineris regions.On this basis we report on the variability of the martian atmosphere during the 5.5 martian years of Mars climatology obtained by combining the two data sets from TES and PFS. Atmospheric temperatures at 50 Pa responded to the global-scale dust storms of MY 25 and in MY 28 raising temperatures from ∼220 K to ∼250 K during the daytime. An atmospheric temperature of ∼140 K at 50 Pa was observed poleward of 70°N during northern winter and poleward of 60°S during southern winter each year in both the PFS and TES results. Water vapor observed by the two spectrometers showed consistent seasonal and latitudinal variations.     

Reconciling the centimeter- and millimeter-wavelength ammonia absorption spectra under jovian conditions: Extensive millimeter-wavelength measurements and a consistent model

Over 1000 laboratory measurements of the 2-4 mm-wavelength opacity of ammonia have been made under simulated jovian atmospheric conditions using a high-precision laboratory system developed at Georgia Tech. These laboratory measurements of the opacity of ammonia were made of various gas mixtures of hydrogen (∼77.5-85.5%), helium (∼12.5-13.5%), and ammonia (1-10%) at pressures between 1 and 3 bars and temperatures between 200 and 300 K. Laboratory measurements were also made of the opacity of pure ammonia at pressures between 0.05 and 1 bar and temperatures between 200 and 300 K. Using these millimeter-wavelength measurements and close to 2000 cm-wavelength measurements made by Hanley et al. (2009), a new consistent model has been developed to accurately characterize the absorption spectra of ammonia in a hydrogen/helium atmosphere in the 1 mm to 30 cm wavelength range. This model can be used in the 1-30 cm wavelength range at pressures up to 20 bars and temperatures from 200 to 500 K and in the 1 mm to 1 cm wavelength range at pressures up to 3 bars and temperatures from 200 to 300 K. These measurements and the accompanying model will enable better interpretation of the centimeter- and millimeter-wavelength emission spectra of the jovian planets.     

The deep water abundance on Jupiter: New constraints from thermochemical kinetics and diffusion modeling

We have developed a one-dimensional thermochemical kinetics and diffusion model for Jupiter’s atmosphere that accurately describes the transition from the thermochemical regime in the deep troposphere (where chemical equilibrium is established) to the quenched regime in the upper troposphere (where chemical equilibrium is disrupted). The model is used to calculate chemical abundances of tropospheric constituents and to identify important chemical pathways for CO-CH₄ interconversion in hydrogen-dominated atmospheres. In particular, the observed mole fraction and chemical behavior of CO is used to indirectly constrain the jovian water inventory. Our model can reproduce the observed tropospheric CO abundance provided that the water mole fraction lies in the range (0.25-6.0) × 10⁻³ in Jupiter’s deep troposphere, corresponding to an enrichment of 0.3-7.3 times the protosolar abundance (assumed to be H₂O/H₂ = 9.61 × 10⁻⁴). Our results suggest that Jupiter’s oxygen enrichment is roughly similar to that for carbon, nitrogen, and other heavy elements, and we conclude that formation scenarios that require very large (>8× solar) enrichments in water can be ruled out. We also evaluate and refine the simple time-constant arguments currently used to predict the quenched CO abundance on Jupiter, other giant planets, and brown dwarfs.     

The jovian anticyclone BA: II. Circulation and interaction with the zonal jets

In this second part of our study of the large jovian anticyclone BA we present detailed measurements of its internal circulation and numerical models of its interaction with the zonal jets and nearby cyclonic regions. We characterized the flow using high-resolution observations obtained by the Cassini spacecraft in December 2000 (9 months after the genesis of BA as a result of the merger of two large White Ovals), by the ACS camera onboard HST in January 2005 and April 2006 and by the New Horizons spacecraft in February 2007. Cloud motions were derived from high-resolution images using an automatic correlator that provides a large sampling of the motions in images separated by short time intervals (30 min-2 h). The internal wind structure did not change when the oval changed its color reddening in late 2005-early 2006 and all four datasets from 2000 to 2007 consistently show a similar wind regime: an asymmetric intense anticyclonic vortex with faster winds in its Southern portion with mean speeds of 110 m/s and peak velocities of 135 m/s. These speeds are slightly higher than those measured in the three White Ovals predecessors of BA by the Voyagers [Mitchell, J.L., Beebe, R.F., Ingersoll, A.P., Garneau, G.W., 1981. J. Geophys. Res. 86, 8751-8757] and Galileo [Vasavada, A.R., and 13 colleagues, 1998. Icarus 135, 265-275] but not as much as it has been recently reported [Simon-Miller, A.A., Chanover, N.J., Orton, G.S., Sussman, M., Tsavaris, I.G., Karkoschka, E., 2006. Icarus 185, 558-562; Cheng, A.F., and 14 colleagues, 2008. Astronom. J. 135, 2446-2452]. The asymmetry of the velocities in the vortex is a consequence of the interaction of BA with the zonal circulation and emerges as a natural result in high-resolution simulations of the vortex dynamics using the EPIC model.     

O2 1.27 μm emission maps as derived from OMEGA/MEx data

We present a method to derive the 2D maps of the O₂ (a¹Δ_g) airglow emission at 1.27 μm from the OMEGA/MEx nadir observations. The OMEGA imaging capabilities allow monitoring the 2D distribution, daily and seasonal variation of the O₂ emission intensities with a detection limit of 4 MR. The highest values, of the order of ∼31 MR, are found on the south pole for 11 h < LT < 13 h, during the early spring (186° < Ls < 192°) of martian year (MY) 27, according to the Mars Year numbering scheme of Clancy et al. [Clancy, R.T., Wolff, M.J., Christensen, P.R., 2003. Mars aerosol studies with the MGS TES emission phase function observations: Optical depths, particle sizes, and ice cloud types versus latitude and solar longitude. J. Geophys. Res. 108. doi: 10.1029/2003JE002058]. In the polar regions the day-by-day variability, associated with polar vortex turbulences, is obtained of the order of 30-50% as predicted by the model [Lefévre, F., Lebonnois, S., Montmessin, F., Forget, F., 2004. Three-dimensional modeling of ozone on Mars. J. Geophys. Res. 109, E07004. doi: 10.1029/2004JE002268] and found by SPICAM [Perrier, S., Bertaux, J.-L., Lebonnois, S., Korablev, O., Fedorova, A., 2006. Global distribution of total ozone on Mars from SPICAM/MEX UV measurements. J. Geophys. Res. 111, E09S06. doi: 10.1029/2006JE002681]. In the considered set of data a maximum of the O₂ emission is observed between 11 h and 15 h LT in the latitude range 70-85° during early spring on both hemispheres, while for the southern autumn-winter season a maximum is found between 50° and 60° in the southern hemisphere for MY28. Increase of intensity of the O₂ emission observed from Ls 130° to 160° at southern high latitudes may be explained by increase of solar illumination conditions in the maps acquired during the considered period.Atmospheric waves crossing the terminator on the southern polar regions are observed for the first time during the MY28 early spring. The spatial scale of the waves ranges from 100 to 130 km, and the intensity fluctuations are of the order of 4MR.This study confirms the high potentiality of O₂ (a¹Δ_g) day glow as a passive tracer of the martian atmosphere dynamics at high latitudes.     

Infrared imaging spectroscopy of Mars: H2O mapping and determination of CO2 isotopic ratios

High-resolution infrared imaging spectroscopy of Mars has been achieved at the NASA Infrared Telescope Facility (IRTF) on June 19-21, 2003, using the Texas Echelon Cross Echelle Spectrograph (TEXES). The areocentric longitude was 206°. Following the detection and mapping of hydrogen peroxide H₂O₂ [Encrenaz et al., 2004. Icarus 170, 424-429], we have derived, using the same data set, a map of the water vapor abundance. The results appear in good overall agreement with the TES results and with the predictions of the Global Circulation Model (GCM) developed at the Laboratory of Dynamical Meteorology (LMD), with a maximum abundance of water vapor of 3±1.5×¹⁰⁻⁴(17±9 pr-μm). We have searched for CH₄ over the martian disk, but were unable to detect it. Our upper limits are consistent with earlier reports on the methane abundance on Mars. Finally, we have obtained new measurements of CO₂ isotopic ratios in Mars. As compared to the terrestrial values, these values are: (¹⁸O/¹⁷O)[M/E] = 1.03 ± 0.09; (¹³C/¹²C)[M/E] = 1.00 ± 0.11. In conclusion, in contrast with the analysis of Krasnopolsky et al. [1996. Icarus 124, 553-568], we conclude that the derived martian isotopic ratios do not show evidence for a departure from their terrestrial values.     

Formation of Jupiter using opacities based on detailed grain physics

Numerical simulations, based on the core-nucleated accretion model, are presented for the formation of Jupiter at 5.2 AU in three primordial disks with three different assumed values of the surface density of solid particles. The grain opacities in the envelope of the protoplanet are computed using a detailed model that includes settling and coagulation of grains and that incorporates a recalculation of the grain size distribution at each point in time and space. We generally find lower opacities than the 2% of interstellar values used in previous calculations (Hubickyj, O., Bodenheimer, P., Lissauer, J.J. [2005]. Icarus 179, 415-431; Lissauer, J.J., Hubickyj, O., D’Angelo, G., Bodenheimer, P. [2009]. Icarus 199, 338-350). These lower opacities result in more rapid heat loss from and more rapid contraction of the protoplanetary envelope. For a given surface density of solids, the new calculations result in a substantial speedup in formation time as compared with those previous calculations. Formation times are calculated to be 1.0, 1.9, and 4.0 Myr, and solid core masses are found to be 16.8, 8.9, and 4.7 M_⊕, for solid surface densities, σ, of 10, 6, and 4 g cm⁻², respectively. For σ = 10 and σ = 6 g cm⁻², respectively, these formation times are reduced by more than 50% and more than 80% compared with those in a previously published calculation with the old approximation to the opacity.     

H2O2 production by high-energy electrons on icy satellites as a function of surface temperature and electron flux

Chemistry on the icy surface of Europa is heavily influenced by the incident energetic particle flux from the jovian magnetosphere. The majority (>75%) of this energy is in the form of high energy electrons (extending to >10 MeV). We have simulated the electron irradiation environment of Europa with a vacuum system containing a high-energy electron gun for irradiation of ice samples formed on a gold mirror cooled with a cryostat. Pure water films of ∼2.6 μm thickness were grown at 100 K and then either cooled (to 80 K), warmed (to 120 K) or left at 100 K and subsequently irradiated with 10 keV electrons. The production of hydrogen peroxide (H₂O₂) was monitored by observation of the 2850 cm⁻¹ (3.5 μm) band. Equilibrium concentrations of H₂O₂, in units of percent by number H₂O₂ relative to water, were found to be 0.043% (80 K), 0.029% (100 K), and 0.0063% (120 K). These values are 33%, 22%, and 5%, respectively, that of the reported surface concentration on the leading hemisphere of Europa (Carlson, R.W., Anderson, M.S., Johnson, R.E., Smythe, W.D., Hendrix, A.R., Barth, C.A., et al. [1999]. Science 283(5410), 2062-2064) and less than the equilibrium concentrations formed by ion irradiation. In addition to the ice film temperature, the current of electrons was varied between different experiments to determine the production and destruction of H₂O₂ as a function of both electron flux and ice temperature. Variation in current was found to have little effect on the results other than accelerating arrival at radiolytic equilibrium.     

Radar observations of Asteroids 64 Angelina and 69 Hesperia

We report new radar observations of E-class Asteroid 64 Angelina and M-class Asteroid 69 Hesperia obtained with the Arecibo Observatory S-band radar (2480 MHz, 12.6 cm). Our measurements of Angelina’s radar bandwidth are consistent with reported diameters and poles. We find Angelina’s circular polarization ratio to be 0.8 ± 0.1, tied with 434 Hungaria for the highest value observed for main-belt asteroids and consistent with the high values observed for all E-class asteroids (Benner, L.A.M., Ostro, S.J., Magri, C., Nolan, M.C., Howell, E.S., Giorgini, J.D., Jurgens, R.F., Margot, J.L., Taylor, P.A., Busch, M.W., Shepard, M.K. [2008]. Icarus 198, 294-304; Shepard, M.K., Kressler, K.M., Clark, B.E., Ockert-Bell, M.E., Nolan, M.C., Howell, E.S., Magri, C., Giorgini, J.D., Benner, L.A.M., Ostro, S.J. [2008b]. Icarus 195, 220-225). Our radar observations of 69 Hesperia, combined with lightcurve-based shape models, lead to a diameter estimate, D_eff = 110 ± 15 km, approximately 20% smaller than the reported IRAS value. We estimate Hesperia to have a radar albedo of , consistent with a high-metal content. We therefore add 69 Hesperia to the Mm-class (high metal M) (Shepard, M.K., Clark, B.E., Ockert-Bell, M., Nolan, M.C., Howell, E.S., Magri, C., Giorgini, J.D., Benner, L.A.M., Ostro, S.J., Harris, A.W., Warner, B.D., Stephens, R.D., Mueller, M. [2010]. Icarus 208, 221-237), bringing the total number of Mm-class objects to eight; this is 40% of all M-class asteroids observed by radar to date.     

Solar activity variations of thermospheric temperatures on Mars and a problem of CO in the lower atmosphere

Long-term MGS drag density observations at 390 km reveal variations of the density with season L_S (by a factor of 2) and solar activity index F_10.7 (by a factor of 3 for F_10.7 = 40-100). According to Forbes et al. (Forbes, J.M., Lemoine, F.G., Bruinsma, S.L., Smith, M.D., Zhang, X. [2008]. Geophys. Res. Lett. 35, L01201, doi:10.1029/2007GL031904), the variation with F_10.7 reflects variations of the exospheric temperature from 192 to 284 K. However, the derived temperature range corresponds to variation of the density at 390 km by a factor of 8, far above the observed factor of 3. The recent thermospheric GCMs agree with the derived temperatures but do not prove their adequacy to the MGS densities at 390 km. A model used by Forbes et al. neglects effects of eddy diffusion, chemistry and escape on species densities above 138 km. We have made a 1D-model of neutral and ion composition at 80-400 km that treats selfconsistently chemistry and transport of species with F_10.7, T_∞, and [CO₂]_80 km as input parameters. Applying this model to the MGS densities at 390 km, we find variation of T_∞ from 240 to 280 K for F_10.7 = 40 and 100, respectively. The results are compared with other observations and models. Temperatures from some observations and the latest models disagree with the MGS densities at low and mean solar activity. Linear fits to the exospheric temperatures are T_∞ = 122 + 2.17F_10.7 for the observations, T_∞ = 131 + 1.46F_10.7 for the latest models, and T_∞ = 233 + 0.54F_10.7 for the MGS densities at 390 km. Maybe the observed MGS densities are overestimated near solar minimum when they are low and difficult to measure. Seasonal variations of Mars’ thermosphere corrected for the varying heliocentric distance are mostly due to the density variations in the lower and middle atmosphere and weakly affect thermospheric temperature. Nonthermal escape processes for H, D, H₂, HD, and He are calculated for the solar minimum and maximum conditions.Another problem considered here refers to Mars global photochemistry in the lower and middle atmosphere. The models gave too low abundances of CO, smaller by an order of magnitude than those observed. Our current work shows that modifications in the boundary conditions proposed by Zahnle et al. (Zahnle, K., Haberle, R.M., Catling, D.C., Kasting, J.F. [2008]. J. Geophys. Res. 113, E11004, doi:10.1029/2008JE003160) are reasonable but do not help to solve the problem.