Advances in studying interactions between aerosols and monsoon in China

Scientific issues relevant to interactions between aerosols and the Asian monsoon climate were discussed and evaluated at the 33rd “Forum of Science and Technology Frontiers” sponsored by the Department of Earth Sciences at the Chinese Academy of Sciences. Major results are summarized in this paper. The East Asian monsoon directly affects aerosol transport and provides a favorable background circulation for the occurrence and development of persistent fog-haze weather. Spatial features of aerosol transport and distribution are also influenced by the East Asian monsoon on seasonal, inter-annual, and decadal scales. High moisture levels in monsoon regions also affect aerosol optical and radiative properties. Observation analyses indicate that cloud physical properties and precipitation are significantly affected by aerosols in China with aerosols likely suppressing local light and moderate rainfall, and intensifying heavy rainfall in southeast coastal regions. However, the detailed mechanisms behind this pattern still need further exploration. The decadal variation in the East Asian monsoon strongly affects aerosol concentrations and their spatial patterns. The weakening monsoon circulation in recent decades has likely helped to increase regional aerosol concentrations. The substantial increase in Chinese air pollutants has likely decreased the temperature difference between land and sea, which favors intensification of the weakening monsoon circulation. Constructive suggestions regarding future studies on aerosols and monsoons were proposed in this forum and key uncertain issues were also discussed.     

Studies of aerosols advected to coastal areas with the use of remote techniques

This paper presents the results of the studies of aerosol optical properties measured using lidars and sun photometers. We describe two case studies of the combined measurements made in two coastal zones in Crete in 2006 and in Rozewie on the Baltic Sea in 2009. The combination of lidar and sun photometer measurements provides comprehensive information on both the total aerosol optical thickness in the entire atmosphere as well as the vertical structure of aerosol optical properties. Combination of such information with air mass back-trajectories and data collected at stations located on the route of air masses provides complete picture of the aerosol variations in the study area both vertically and horizontally. We show that such combined studies are especially important in the coastal areas where depending on air mass advection directions and altitudes the influence of fine or coarse mode (in this case possibly sea-salt) particles on the vertical structure of aerosol optical properties is an important issue to consider.     

The pattern of surface wind flow in Antarctica

Summary The main characteristics of surface winds are tabulated for 34 Antarctic stations. Using these data, supplemented by traverse records, the average wind flow is interpolated for each region and presented as a map showing the pattern of surface wind flow for the whole continent. Attention is focused on the flow in relation to surface contours. Statistics are presented for surface slope, wind speed, temperature, seasonal variations of speed and temperature, diurnal variation (including power spectra) of the wind speed and times of maximum and minimum speed at coastal and inland stations, wind frequency versus direction, the occurrence of calms, the deviation of the plateau wind from the downslope direction, the wind direction near the front of ice shelves, the proportion of cloud cover, and wind chill factors. In all cases data are grouped according to the environs of the stations in an attempt to isolate systematic differences depending on location: coastal stations near the foot of the ice slope and fully exposed to katabatic flow, coastal stations on offshore islands, coastal stations on peninsulas, coastal stations on extensive rock areas, ice shelf stations and inland stations.     

Studies of aerosol optical depth with the use of Microtops II sun photometers and MODIS detectors in coastal areas of the Baltic Sea

In this paper we describe the results of a research campaign dedicated to the studies of aerosol optical properties in different regions of both the open Baltic Sea and its coastal areas. During the campaign we carried out simultaneous measurements of aerosol optical depth at 4 stations with the use of the hand-held Microtops II sun photometers. The studies were complemented with aerosol data provided by the MODIS. In order to obtain the full picture of aerosol situation over the study area, we added to our analyses the air mass back-trajectories at various altitudes as well as wind fields. Such complex information facilitated proper conclusions regarding aerosol optical depth and Ångström exponent for the four locations and discussion of the changes of aerosol properties with distance and with changes of meteorological factors. We also show that the Microtops II sun photometers are reliable instruments for field campaigns. They are easy to operate and provide good quality results.     

Study of sensible fluxes from different climatic stations

Summary Two methods of the evaluation of sensible heat flux are briefly presented from the view point of their application to micrometeorology. The comparison of sensible fluxes for coastal and inland stations is presented, in order to explain the influence of the marine atmosphere on these fluxes. They reach a maximum value in summer at the coastal stations, due to maximum wind speed and high convective activity developed by the influence of the marine atmosphere.     

A Study of Chloride Aerosol, Total Aerosol and Ice Nuclei in the Indian Regions

--Atmospheric aerosols were sampled from aircraft at various levels over Rihand in northern India during the monsoon season of 1974 and at surface levels at Calcutta, Delhi, Varanasi and Jodhpur during different seasons of 1970 and 1971. Millipore filter assembly was used for this purpose. Chloride nuclei, total aerosol and ice nuclei concentrations were evaluated from millipore filters. At Rihand/Varanasi, during the monsoon, the chloride size spectrum was broader and the distribution bimodal at cloud base level while the spectra were narrower and the distributions unimodal at other levels. At Rihand, chloride mass and larger giant chloride number were considerably higher, total aerosol higher while ice nuclei concentrations were lower on the days with moderate rain as compared to those with light rain. Calcutta (maritime) showed maximum while Varanasi (well-inland) showed minimum chloride number concentrations. As compared with Calcutta, Delhi (continental) had lower chloride and total aerosol, and markedly higher ice nuclei concentrations. Varanasi (high rainfall region) showed all the values, except for small-sized chlorides, notably higher with respect to Jodhpur (low rainfall region). Ice nuclei concentration was lowest in winter and highest in summer at Delhi. Variations of the aerosols during different parts of the day/night are also discussed.     

The role of playas in pedogenic gypsum crust formation in the Central Namib Desert: a theoretical model

The formation of Namibia's extensive pedogenic gypsum crusts (CaSO₄·2H₂O) is interpreted in a new light. It is suggested that gypsum primarily precipitates at isolated points of evaporitic concentration, such as inland playas, and that deflation of evaporitic‐rich gypsum dust from these playas contributes to the formation of pedogenic gypsum duricrusts on the coastal gravel plains of the Namib Desert surrounding these playas. This study establishes the nature, extent and distribution of playas in the Central Namib Desert and provides evidence for playa gypsum deflation and gravel plain deposition. Remote sensing shows the distribution of playas, captures ongoing deflation and provides evidence of gypsum deflation. It is proposed that, following primary marine aerosol deposition, both inland playas and coastal sabkhas generate gypsum which through the process of playa deflation and gravel plain redeposition contributes to the extensive pedogenic crusts found in the Namib Desert region. Copyright © 2001 John Wiley & Sons, Ltd.     

Empirical and Numerical Modeling of T-phase Propagation from Ocean to Land

—?T-phase propagation from ocean onto land is investigated by comparing data from hydrophones in the water column with data from the same events recorded on island and coastal seismometers. Several events located on Hawaii and the emerging seamount Loihi generated very large amplitude T phases that were recorded at both the preliminary IMS hydrophone station at Point Sur and land-based stations along the northern California coast. We use data from seismic stations operated by U. C. Berkeley along the coast of California, and from the PG&;E coastal California seismic network, to estimate the T-phase transfer functions. The transfer function and predicted signal from the Loihi events are modeled with a composite technique, using normal mode-based numerical propagation codes to calculate the hydroacoustic pressure field and an elastic finite difference code to calculate the seismic propagation to la nd-based stations. The modal code is used to calculate the acoustic pressure and particle velocity fields in the ocean off the California coast, which is used as input to the finite difference code TRES to model propagation onto land. We find both empirically and in the calculations that T phases observed near the conversion point consist primarily of surface waves, although the T phases propagate as P waves after the surface waves attenuate. Surface wave conversion occurs farther offshore and over a longer region than body wave conversion, which has the effect that surface waves may arrive at coastal stations before body waves. We also look at the nature of T phases after conversion from ocean to land by examining far inland T phases. We find that T phases propagate primarily as P waves once they are well inland from the coast, and can be observed in some cases hundreds of kilometers inland. T-phase conversion at tenuates higher frequencies, however we find that high frequency energy from underwater explosion sources can still be observed at T-phase stations.     

The forced and free response of the South China Sea to the large-scale monsoon system

Non-tidal sea level anomalies (SLAs) can be produced by many different dynamical phenomena over many time scales, and they can induce serious damages in coastal regions especially during extreme events. In this work, we focus on the SLAs in the South China Sea (SCS) to understand whether and how they can be related to the large-scale, seasonal monsoon system which dominates the SCS circulation and dynamics. We have two major objectives. The first one is to understand whether the NE (winter) and SW (summer) monsoons can be responsible for the persistent SLAs, both positive and negative, observed at the SCS ends along the main monsoon path. The second objective is to understand the SCS response as a free system upon onset/relaxation or sudden changes in the forcing wind. It is well known that sudden changes in the forcing mechanism induce free oscillations, or seiches, in closed, semi-enclosed basins and harbors, and we want to identify the possible seiche modes of the SCS. To our knowledge, these two objectives have not been previously addressed. We address these objectives both through observational analysis and modeling simulations. Multi-year tide-gauge data from stations along the coastal regions of the SCS are analyzed examining their spatial correlations. Strong negative correlations are found between the northeast and southwest stations at the two ends of the SCS under the path of the NE/SW monsoons. They correspond to wind-induced positive/negative sea level set-ups lasting for the entire monsoon season and changing sign from winter to summer. Short periods of negative correlations are also found between the SLAs at eastern and western stations during El Niño years in which the monsoons are weaker and have an enhanced E/W component inducing corresponding sea level set-ups. The tide-gauge station at Tanjong Pagar at the southwest SCS end near Singapore is chosen to study four extreme SLAs events in the observational record during 1999. Modeling simulations are carried out to reproduce them. The observed and modeled extreme SLAs agree quite well, both in the amplitude of the highest peak and in phase. Three main peaks are identified in the observational energy spectrum of the de-tided SLAs at the same station in 1999. Using Merian’s formula to evaluate the periods of seiches in idealized basins Wilson (Adv Hydrosci 8:1–94, 1972) the first two peaks (24.4 h and 11.9 h) are found to correspond to the first two seiche modes in the direction of the main, longer axis of the SCS. The third peak (8.5 h) is found to correspond to the seiche in the transversal, shorter axis. Finally, modeling simulations are carried out by suddenly dropping a circular bump of water in the quiescent basin at different locations to excite the seiches. The periods of the modeled peaks agree quite well with the observational ones, the first two periods being actually identical.     

Aerosol properties over an urban site in central East China derived from ground sun-photometer measurements

Sun-photometer measurements at Hefei, an urban site located in central East China, were examined to investigate the variations of aerosol loading and optical properties. It is found that aerosol optical thickness (AOT) keeps higher in winter/spring and gets relatively lower in summer/autumn. The large AOT in winter is caused by anthropogenic sulfate/nitrate aerosols, while in spring dust particles elevate the background aerosol loading and the excessive fine-mode particles eventually lead to severe pollution. There is a dramatic decline of AOT during summer, with monthly averaged AOT reaching the maximum in June and soon the minimum in August. Meanwhile, aerosol size decreases consistently and single scattering albedo (SSA) reaches its minimum in July. During summertime large-sized particles play a key role to change the air from clean to mild-pollution situation, while the presence of massive small-sized particles makes the air being even more polluted. These complicated summer patterns are possibly related to the three key processes that are active in the high temperature/humidity environment concentrating on sulfate/nitrate aerosols, i.e., gas-to-particle transformation, hygroscopic growth, and wet scavenging. Regardless of season, the increase of SSA with increasing AOT occurs across the visible and near-infrared bands, suggesting the dominant negative/cooling effect with the elevated aerosol loading. The SSA spectra under varying AOT monotonically decrease with wavelength. The relatively large slope arises in summer, reinforcing the dominance of sulfate/nitrate aerosols that induce severe pollution in summer season around this city.     

Turbidity measurements at coastal and inland sites in India

Analysis of turbidity measurements using a Volz sunphotometer, at three sites in India, two of them coastal and one inland, is reported. The sites are rural, far from industrial activity. After making an error analysis of the measurement technique the seasonal variations in turbidity parameters are interpreted in relation to the concurrent changes in relevant meteorological parameters like wind speed, wind direction, temperature and humidity. At coastal sites, the turbidity and the atmospheric salt concentration are found to be well correlated though the correlation coefficient varies between sites.     

Developmental disorders in larvae of eelpout (Zoarces viviparus) from German and Swedish Baltic coastal waters

Pregnant eelpout were collected for several years at German and Swedish Baltic coastal stations with different impact of pollutants and the prevalence of fry abnormalities compared between sites. Mortality of apparently normal developed larvae was observed with high variability in both German and Swedish sites. Malformation of larvae was a prominent disorder at all German stations with a prevalence ranging from about 50% up to a maximum of 90% in almost all analysed samples. At the Swedish stations malformation rates were significantly lower (range: 0-6%). Growth retardation of fry was clearly more prominent in eelpout from German coastal waters as well. Taken together the field data suggests that impaired larval development was associated with the state of environmental pollution at the sampling locations.     

Some aspects of the monsoon circulation and monsoon rainfall

Summary The south Asian summer monsoon from June to September accounts for the greater part of the annual rainfall over most of India and southeast Asia. The evolution of the summer and winter monsoon circulations over India is examined on the basis of the surface and upper air data of stations across India. The salient features of the seasonal reversals of temperature and pressure gradients and winds and the seasonal and synoptic fluctuations of atmospheric humidity are discussed. The space-time variations of rainfall are considered with the help of climatic pentad rainfall charts and diagrams. The rainfall of several north and central Indian stations shows a minimum around mid-August and a maximum around mid-February which seem to be connected with the extreme summer and winter positions of the ITCZ and the associated north-south shifts in the seasonal circulation patterns. Attention is drawn to the characteristic features of the monsoon rainfall that emerge from a study of daily and hourly rainfall of selected stations. Diurnal variations of temperature, pressure, wind and rainfall over the monsoon belt are briefly treated.     

Saprobiologische Untersuchungen der Kleinalgenflora in einem Brackgewässer (Darß-Zingster Boddenkette)

On the basis of investigations into periphyton for three years as well as selected physical and chemical criteria of water quality at eight stations with different wastewater load there were classified initially 52 algal taxa with respect to their saprobic indicative values: 4 oligoto β-mesosaprobic, 23 β-mesosaprobic, 19 β- to α-mesosaprobic, 6 α-mesosaprobic. Their distribution and ecological demands are shortly discussed. The degree of saprobity, expressed as the index of saprobity according to PANTLE and BUCK proves to be very suitable for the documentation of ecological changes at wastewater inlet points and their environment. Finally, proposals for an ecological classification of coastal waters by their trophic state and anthropogenic load are derived from the results of investigation by analogy with the corresponding classification of stagnant inland waters.     

Stable isotopic characteristic of Taiwan's precipitation: A case study of western Pacific monsoon region

The stable oxygen and hydrogen isotopic features of precipitation in Taiwan, an island located at the western Pacific monsoon area, are presented from nearly 3,500 samples collected during the past decade for 20 stations. Results demonstrate that moisture sources from diverse air masses with different isotopic signals are the main parameter in controlling the precipitation's isotope characteristics. The air mass from polar continental (Pc) region contributes the precipitation with high deuterium excess values (up to 23‰) and relatively enriched isotope compositions (e.g., ? 3.2‰ for δ¹⁸O) during the winter with prevailing northeasterly monsoon. By contrast, air masses from equatorial maritime (Em) and tropical maritime (Tm) supply the precipitation with low deuterium excess values (as low as about 7‰) and more depleted isotope values (e.g., ? 8.9‰ and ? 6.0‰ for δ¹⁸O of Tm and Em, respectively) during the summer with prevailing southwesterly monsoon. Thus seasonal differences in terms of δ¹⁸O, δD, and deuterium excess values are primarily influenced by the interactions among various precipitation sources. While these various air masses travel through Taiwan, secondary evaporation effects further modify the isotope characteristics of the inland precipitation, such as raindrop evaporation (reduces the deuterium excess of winter precipitation) and moisture recycling (increases the deuterium excess of summer precipitation). The semi-quantitative estimations in terms of evaluation for changes in the deuterium excess suggest that the raindrop evaporation fractions for winter precipitation range 7% to 15% and the proportions of recycling moisture in summer precipitation are less than 5%. Additionally, the isotopic altitude gradient in terms of δ¹⁸O for summer precipitation is ? 0.22‰/100 m, greater than ? 0.17‰/100 m of winter precipitation. The greater isotopic gradient in summer can be attributed to a higher temperature vs. altitude gradient relative to winter. The observed spatial and seasonal stable isotopic characteristics in Taiwan's precipitation not only contribute valuable information for regional monsoon research crossing the continent–ocean interface of East Asia, but also can serve as very useful database for local water resources management.     

Relations between oxygen stable isotopic ratios in precipitation and relevant meteorological factors in southwest China

The correlations of isotopic ratios in precipitation with temperature, air pressure and humidity at dif- ferent altitudes, in southwest China, are analyzed. There appear marked negative correlations for the δ 18O in precipitation with precipitation amount, vapor pressure and atmospheric precipitable water (PW) at Mengzi, Simao and Tengchong stations on synoptic timescale; the marked negative correlations between the δ 18O in precipitation and the diurnal mean temperature at 400 hPa, 500 hPa, 700 hPa and 850 hPa are different from the temperature effect in middle-high-latitude inland. Moreover, the notable positive correlation between the δ 18O in precipitation and the dew-point deficit △Td at different altitudes is found at the three stations. On annual timescale, the annual precipitation amount weighted mean δ 18O display the negative correlations not only with annual precipitation but also with annual mean temperature at 500 hPa. It can be deduced that, in the years with abnormally strong summer monsoon, more warm and wet air from low-latitude oceans is transported northward along the vapor channel located in southwest China and generates abnormally strong rainfall on the way. Meanwhile, the ab- normally strong condensation process will release more condensed latent heat into atmosphere, and lead to the rise of atmospheric temperature during rainfall, but decline of the δ 18O in precipitation. On the contrary, in the years with abnormally weak summer monsoon, the abnormally weak condensation process will release less condensed latent heat into atmosphere, and lead to the decline of atmos- pheric temperature during rainfall, but increase of the δ 18O in precipitation.     

Seasonal variations of deuterium and oxygen‐18 isotopes and their response to moisture source for precipitation events in the subtropical monsoon region

Deuterium and oxygen‐18 are common environmental tracers in water used to investigate hydrological processes such as evaporation and groundwater recharge, and to trace moisture source. In this study, we collected event precipitation from 01 January 2010 to 28 February 2011 at a site in Changsha, Yangtze River Basin to estimate the influence of moisture source and atmospheric conditions on stable isotope compositions. The local meteoric water line, established as δD = (8.45 ± 0.13) δ¹⁸O + (17.7 ± 0.9) (r² = 0.97, n = 189), had a higher slope and intercept than global meteoric water line. Temperature–δ¹⁸O exhibited complex correlations, with positive correlations during Nov.–Apr. superior to during Jun.–Sep., which was attributed to distinctive moisture sources, but vague the overall period; amount effect examined throughout the year. Linear regressions between δ¹⁸O and δD value in different precipitation event size classes revealed progressively decreasing slope and intercept values with decreasing precipitation amount and increasing vapour pressure deficit, indicating that small rainfall events (0–5 mm) were subject to secondary evaporation effects during rainwater descent. In contrast, snowfall and heavy precipitation events exhibited high slope and intercepts for the regression equation between δ¹⁸O and δD. High concentrations of heavy isotopes were associated with precipitation events sourced from remote westerly air masses, degenerated tropical marine air masses from the Bay of Bengal (BoB), and inland moisture in the pre‐monsoon period, as determined from backward trajectories assessed in the HYSPLIT model. Meanwhile, low concentrations of heavy isotopes were found to correspond with remote maritime moisture from BoB, the South China Sea, and the west Pacific at three different air pressures in summer monsoon and post‐monsoon using HYSPLIT and records of typhoon paths. These findings suggest that stable isotope compositions in precipitation events are closely associated with the meteorological conditions and respond sensitively to moisture source in subtropical monsoon climates. Copyright © 2013 John Wiley & Sons, Ltd.     

A novel method for distinguishing fog and haze based on PM2.5, visibility,and relative humidity

Haze and fog are both low visibility events, but with different physical properties. Haze is caused by the increase of aerosol loading or the hygroscopic growth of aerosol at high relative humidity, whereas visibility degradation in fog is due to the light scattering of fog droplets, which are transited from aerosols via activation. Based on the difference of physical properties between haze and fog, this study presents a novel method to distinguish haze and fog using real time measurements of PM2.5, visibility, and relative humidity. In this method, a criterion can be developed based on the local historical data of particle number size distributions and aerosol hygroscopicity. Low visibility events can be classified into haze and fog according to this criterion.     

Results of the studies of monsoon circulation with radon as a tracer

Radon-222 activity levels have been measured at deck level in regions of the Arabian Sea, Indian Ocean, and Bay of Bengal during the summer monsoon periods of 1973, 1977, and 1979, as part of the Monex programme. The aim of the measurements was to find the source regions of the monsoon air and the variations in its composition under different synoptic conditions. The radon data confirm that the monsoon air is predominantly of southern-hemisphere origin, with a small continental component. The continental component, as indicated by radon values, increases at higher latitudes and seems to vary with different circulation patterns in the synoptic scale. The use of radon as a tracer in monsoon studies is thus demonstrated.     

Seasonal variations of stable isotope in precipitation and moisture transport at Yushu,eastern Tibetan Plateau

Precipitation δ 18O at Yushu, eastern Tibetan Plateau, shows strong fluctuation and lack of clear seasonality. The seasonal pattern of precipitation stable isotope at Yushu is apparently different from either that of the southwest monsoon region to the south or that of the inland region to the north. This different seasonal pattern probably reflects the shift of different moisture sources. In this paper, we present the spatial comparison of the seasonal patterns of precipitation δ 18O, and calculate the moisture transport flux by using the NCAR/NCEP reanalysis data. This allows us to discuss the relation between moisture transport flux and precipitation δ 18O. This study shows that both the southwest monsoon from south and inland air mass transport from north affected the seasonal precipitation δ 18O at Yushu, eastern Tibetan Plateau. Southwest monsoon brings the main part of the moisture, but southwest transport flux is weaker than in the southern part of the Tibetan Plateau. However, contribution of the inland moisture from north or local evaporation moisture is enhanced. The combined effect is the strong fluctuation of summer precipitation δ 18O at Yushu and comparatively poor seasonality.