Integrity of Clay Till Aquitards to DNAPL Migration: Assessment Using Current and Emerging Characterization Tools

Field investigations were carried out to determine the occurrence of tetrachloroethene (PCE) dense nonaqueous phase liquid (DNAPL), the source zone architecture and the aquitard integrity at a 30‐ to 50‐year old DNAPL release site. The DNAPL source zone is located in the clay till unit overlying a limestone aquifer. The DNAPL source zone architecture was investigated through a multiple‐lines‐of‐evidence approach using various characterization tools; the most favorable combination of tools for the DNAPL characterization was geophysical investigations, membrane interface probe, core subsampling with quantification of chlorinated solvents, hydrophobic dye test with Sudan IV, and Flexible Liner Underground Technologies (FLUTe) NAPL liners with activated carbon felt (FACT). While the occurrence of DNAPL was best determined by quantification of chlorinated solvents in soil samples supported by the hydrophobic dye tests (Sudan IV and NAPL FLUTe), the conceptual understanding of source zone architecture was greatly assisted by the indirect continuous characterization tools. Although mobile or high residual DNAPL (S _t > 1%) only occurred in 11% of the source zone samples (intact cores), they comprised 86% of the total PCE mass. The dataset, and associated data analysis, supported vertical migration of DNAPL through fractures in the upper part of the clay till, horizontal migration along high permeability features around the redox boundary in the clay till, and to some extent vertical migration through the fractures in the reduced part of the clay till aquitard to the underlying limestone aquifer. The aquitard integrity to DNAPL migration was found to be compromised at a thickness of reduced clay till of less than 2 m.     

Direct-Push Electrical Conductivity Logging for High-Resolution Hydrostratigraphic Characterization

Fine-scale hydrostratigraphic features often play a critical role in controlling ground water flow and contaminant transport. Unfortunately, many conventional drilling- and geophysics-based approaches are rarely capable of describing these features at the level of detail needed for contaminant predictions and remediation designs. Previous work has shown that direct-push electrical conductivity (EC) logging can provide information about site hydrostratigraphy at a scale of relevance for contaminant transport investigations in many unconsolidated settings. In this study, we evaluate the resolution and quality of that information at a well-studied research site that is underlain by highly stratified alluvial sediments. Geologic and hydrologic data, conventional geophysical logs, and particle-size analyses are used to demonstrate the capability of direct-push EC logging for the delineation of fine-scale hydrostratigraphic features in saturated unconsolidated formations. When variations in pore-fluid chemistry are small, the electrical conductivity of saturated media is primarily a function of clay content, and hydrostratigraphic features can be described at a level of detail (<2.5 cm in thickness) that has not previously been possible in the absence of continuous cores. Series of direct-push EC logs can be used to map the lateral continuity of layers with non-negligible clay content and to develop important new insights into flow and transport at a site. However, in sand and gravel intervals with negligible clay, EC logging provides little information about hydrostratigraphic features. As with all electrical logging methods, some site-specific information about the relative importance of fluid and sediment contributions to electrical conductivity is needed. Ongoing research is directed at developing direct-push methods that allow EC logging, water sampling, and hydraulic testing to be done concurrently.     

Influence of Hydraulic Fracturing on Overlying Aquifers in the Presence of Leaky Abandoned Wells

The association between hydrocarbon‐rich reservoirs and organic‐rich source rocks means unconventional oil and gas plays usually occur in mature sedimentary basins—where large‐scale conventional development has already taken place. Abandoned wells in proximity to hydraulic fracturing could be affected by increased fluid pressures and corresponding newly generated fractures that directly connect (frac hit) to an abandoned well or to existing fractures intersecting an abandoned well. If contaminants migrate to a pathway hydraulically connected to an abandoned well, upward leakage may occur. Potential effects of hydraulic fracturing on upward flow through a particular type of leaky abandoned well—abandoned oil and gas wells converted into water wells were investigated using numerical modeling. Several factors that affect flow to leaky wells were considered including proximity of a leaky well to hydraulic fracturing, flowback, production, and leaky well abandonment methods. The numerical model used historical records and available industry data for the Eagle Ford Shale play in south Texas. Numerical simulations indicate that upward contaminant migration could occur through leaky converted wells if certain spatial and hydraulic conditions exist. Upward flow through leaky converted wells increased with proximity to hydraulic fracturing, but decreased when flowback and production occurred. Volumetric flow rates ranged between 0 and 0.086 m³/d for hydraulic‐fracturing scenarios. Potential groundwater impacts should be paired with plausible transport mechanisms, and upward flow through leaky abandoned wells could be unrelated to hydraulic fracturing. The results also underscore the need to evaluate historical activities.     

Influence of Bedding and Mineral Composition on Mechanical Properties and Its Implication for Hydraulic Fracturing of Shale Oil Reservoirs

The premise of hydraulic fracturing is to have an accurate and detailed understanding of the rock mechanical properties and fracture propagation law of shale reservoirs. In this paper, a comprehensive evaluation of the mechanical properties of the shale oil reservoir in the south of Songliao Basin is carried out. Based on the experiments and the in-situ stress analysis, the fracture propagation law of three types of shale reservoirs is obtained, and the suggestions for fracturing are put forward. The results have shown that the fracture propagation of pure shale and low mature reservoir is easy to open along the bedding plane under compression loading, which is greatly influenced by the bedding. Sand-bearing shale is slightly better, the fractures of which are not easy to open along the bedding plane. The mechanical experimental results show that all the samples have the characteristics of low compressive strength, low Young''s modulus and strong anisotropy, indicating that the shale oil reservoir is certain plastic, which is related to its high clay mineral content and controlled by the bedding development. Compared with pure shale and low mature shale, the sand-bearing shale has less clay content and less developed bedding, which maybe the main reason for its slightly better brittleness. Overall, the expansion of hydraulic fracture is controlled by in-situ stress and bedding. Because of the development of bedding, it is easy to form horizontal fractures. Thus it is not suitable for horizontal well fracturing. Because of the high content of clay minerals, the applicability of conventional slick hydraulic fracturing fluid is poor. It is suggested to use vertical well or directional well to carry out volume fracturing. In this way, the effect of bedding can be effectively used to open and connect the bedding and form a larger fracture network.     

An Analytical Model for Hydraulic Fracturing in Shallow Bedrock Formations

A theoretical method is proposed to estimate post‐fracturing fracture size and transmissivity, and as a test of the methodology, data collected from two wells were used for verification. This method can be employed before hydrofracturing in order to obtain estimates of the potential hydraulic benefits of hydraulic fracturing. Five different pumping test analysis methods were used to evaluate the well hydraulic data. The most effective methods were the Papadopulos‐Cooper model (1967), which includes wellbore storage effects, and the Gringarten‐Ramey model (1974), known as the single horizontal fracture model. The hydraulic parameters resulting from fitting these models to the field data revealed that as a result of hydraulic fracturing, the transmissivity increased more than 46 times in one well and increased 285 times in the other well. The model developed by dos Santos (2008) , which considers horizontal radial fracture propagation from the hydraulically fractured well, was used to estimate potential fracture geometry after hydrofracturing. For the two studied wells, their fractures could have propagated to distances of almost 175 m or more and developed maximum apertures of about 2.20 mm and hydraulic apertures close to 0.30 mm. Fracturing at this site appears to have expanded and propagated existing fractures and not created new fractures. Hydraulic apertures calculated from pumping test analyses closely matched the results obtained from the hydraulic fracturing model. As a result of this model, post‐fracturing geometry and resulting post‐fracturing well yield can be estimated before the actual hydrofracturing.     

Where Does Water Go During Hydraulic Fracturing?

During hydraulic fracturing millions of gallons of water are typically injected at high pressure into deep shale formations. This water can be housed in fractures, within the shale matrix, and can potentially migrate beyond the shale formation via fractures and/or faults raising environmental concerns. We describe a generic framework for producing estimates of the volume available in fractures and undamaged shale matrix where water injected into a representative shale site could reside during hydraulic fracturing, and apply it to a representative site that incorporates available field data. The amount of water that can be stored in the fractures is estimated by calculating the volume of all the fractures associated with a discrete fracture network (DFN) based on real data and using probability theory to estimate the volume of smaller fractures that are below the lower cutoff for the fracture radius in the DFN. The amount of water stored in the matrix is estimated utilizing two distinct methods—one using a two‐phase model at the pore‐scale and the other using a single‐phase model at the continuum scale. Based on these calculations, it appears that most of the water resides in the matrix with a lesser amount in the fractures.     

Application of harmonic analysis of water levels to determine vertical hydraulic conductivities in clay-rich aquitards

A harmonic analysis method was used to determine vertical hydraulic conductivities (Kv) in geologic media between vertically separated piezometers using water level measurements. In this method, each water level time series was filtered and then decomposed using harmonic analysis into a sum of trigonometric components. The phase and amplitude of each harmonic function were calculated. These data were used to estimate Kv values between vertically separated data sets assuming one-dimensional transient flow. The method was applied to water level data collected from nested piezometers at two thick clay-rich till aquitards in Saskatchewan, Canada. At one site, routine water levels were measured in 12 piezometers (installed between 1 and 29 m below ground surface) since installation (1995). At the other site, water levels were measured in seven piezometers (installed between 4 and 53 m below ground surface) since installation (1998-1999). The Kv calculated using harmonic analysis decreased with depth below the water table at both sites, approaching matrix estimates of hydraulic conductivity between 10 and 11 m and between 21 and 43 m below ground surface. These depths reflected the depth of extensive vertical fracturing at the sites and showed that the depth of fracturing may be site specific.     

Vertical Hydraulic Gradient Estimation in Clay Till,Using MiHPT Advanced Direct-Push Technology

The vertical transport of contaminants from source areas is employed in many risk assessment models and screening tools in order to estimate the contaminant mass discharge (CMD) into underlying aquifers. The key parameters for estimating CMD are the contaminant source area and concentration, and the vertical water flux, the latter of which depends on the vertical hydraulic conductivity and the vertical hydraulic gradient in the subsurface. This study focuses on advancing the use of the combined membrane interface probe hydraulic profiling tool (MiHPT) to investigate the vertical hydraulic gradient across a clay till overlying a sandy aquifer at a contaminated site in Denmark. Only the HPT is necessary for the estimate of vertical hydraulic gradient. The hydraulic head, clay till thickness, and resulting vertical hydraulic gradients found using the MiHPT compared well with observations from nearby nested wells. The parameter with the largest discrepancy was the thickness of the clay till. The advantage of the MiHPT is its relatively quick depth discrete access to information regarding subsurface permeability, vertical hydraulic gradients and contaminant distribution across a site. In this case study, performance of additional dissipationtests during the HPT log to acquire determination of the vertical hydraulic gradient increased the cost by 3% compared to standard HPT logs.     

Conceptualization of the hydrogeological system of some sedimentary aquifers in Savelugu–Nanton and surrounding areas,Northern Ghana

Groundwater resources play a pivotal role in the rural water delivery system in Ghana. The hydrogeological system of Middle Voltaian terrain was simulated using available data on hydraulic heads and boundary conditions. The objective was to characterize the general groundwater flow pattern and provide local estimates of the distribution of hydraulic conductivity and recharge fields. The results suggest a predominant NE–SW flow direction, which ties in with the general regional structural trend and indicates that the hydrogeological conditions of the rocks are controlled by structural entities created in the wake of fracturing and/or weathering of the rocks whose primary permeabilities are considerably reduced because of high compaction and low‐grade metamorphism. Calibrated hydraulic conductivities range between 1.90 and 10.81 m/d. The spatial distribution appears to reflect the intensity of fracturing and/or weathering of the rock and the proportion of the clay fraction of the weathered zone. Vertical groundwater recharge has been estimated to range between 0.3% and 4.1% of the annual rainfall. This recharge rate is quite low and reflects the imperviousness of the thick overburden because of high clay content in some places and high compaction in others. Despite this apparently low recharge rate, groundwater resources potential in the area appear to be high, and increased abstraction from existing abstraction wells by up to 50% does not appear to register significant effects on groundwater budgets at the simulated recharge rates. This suggests that the well yields are much lower than the potential of the aquifer system. The apparently low yields might be associated with poor well development and the choice of inappropriate well completion materials. This study recommends a monitoring system to be developed for a much more regional groundwater flow simulation under transient conditions. Copyright © 2012 John Wiley & Sons, Ltd.     

Performance of Full‐Scale Enhanced Reductive Dechlorination in Clay Till

At a low permeability clay till site contaminated with chlorinated ethenes (Gl. Kongevej, Denmark), enhanced reductive dechlorination (ERD) was applied by direct push injection of molasses and dechlorinating bacteria. The performance was investigated by long‐term groundwater monitoring, and after 4 years of remediation, the development of degradation in the clay till matrix was investigated by high‐resolution subsampling of intact cores. The formation of degradation products, the presence of specific degraders Dehalococcoides spp. with the vinyl chloride (VC) reductase gene vcrA, and the isotope fractionation of trichloroethene, cis‐dichloroethene (cis‐DCE), and VC showed that degradation of chlorinated ethenes occurred in the clay till matrix as well as in sand lenses, sand stringers, and fractures. Bioactive sections of up to 1.8 m had developed in the clay till matrix, but sections, where degradation was restricted to narrow zones around sand lenses and stringers, were also observed. After 4 years of remediation, an average mass reduction of 24% was estimated. Comparison of the results with model simulation scenarios indicate that a mass reduction of 85% can be obtained within approximately 50 years without further increase in the narrow reaction zones if no donor limitations occur at the site. Long‐term monitoring of the concentration of chlorinated ethenes in the underlying chalk aquifer revealed that the aquifer was affected by the more mobile degradation products cis‐DCE and VC generated during the remediation by ERD.     

Natural hydraulic cracking: numerical model and sensitivity study

Natural hydrofracturing caused by overpressure plays an important role in geopressure evolution and hydrocarbon migration in petroliferous basins. Its mechanism is quite well understood in the case of artificial hydraulic fracturing triggered by high-pressure fluid injection in a well. This is not so for natural hydraulic fracturing which is assumed to initiate as micro-cracks with large influence on the permeability of the medium. The mechanism of natural hydraulic cracking, triggered by increasing pore pressure during geological periods, is studied using a fracturing model coupled to the physical processes occurring during basin evolution. In this model, the hydraulic cracking threshold is assumed to lie between the classical failure limit and the beginning of dilatancy. Fluid pressure evolution is calculated iteratively in order to allow dynamic adjustment of permeability so that the fracturing limit is always preserved. The increase of permeability is interpreted on the basis of equivalent fractures. It is found that fracturing is very efficient to keep a stress level at the rock’s hydraulic cracking limit: a fracture permeability one order of magnitude larger than the intrinsic permeability of the rock would be enough. Observations reported from actual basins and model results strongly suggest that natural hydraulic cracking occurs continuously to keep the pressure at the fracturing limit under relaxed stress conditions.     

Are Visible Fractures Accurate Predictors of Flow and Mass Transport in Fractured Till?

Tracer experiments conducted in the laboratory on undisturbed core samples (<7.3-cm-diameter) have been a standard method for estimating hydraulic and transport properties of fractured till since the 1980s. This study assesses the relationship between visible fractures on the top and bottom of core samples and the resulting hydraulic and mass transport properties of the core. We hypothesized that more visible fractures would indicate the presence of a well-connected fracture network, leading to greater hydraulic conductivity (K) values and earlier chemical breakthrough times. To test this hypothesis, water flow and bromide (Br-) tracer experiments were performed on 10, 16-cm diameter, 16-cm-tall samples of fractured Dows Formation till from central Iowa. Visually identifiable fractures were present on the top and bottom of every sample. Results indicate that the visual identification of fractures does not predict a connected fracture network, as some samples produced breakthrough curves showing rapid first arrival times and shapes characteristic of solute transport in a fractured medium, while others appeared similar to an unfractured medium. No correlation was found between the number of visible fractures and K (Pearson's r = 0.25), or Br- first arrival time (r = −0.33), but a strong negative correlation between K and first arrival time (r = −0.92). Results indicate that the sample volume was not large enough to reliably contain a connected fracture network. Thus, testing large volumes of till at the field scale coupled with fracture-flow modeling likely represents the best approach for estimating hydraulic and mass transport properties for fractured till.     

Numerical evaluation of the effect of fracture network connectivity in naturally fractured shale based on FSD model

In this paper, the effect of pre-existing discrete fracture network (DFN) connectivity on hydraulic fracturing is numerically investigated in a rock mass subjected to in-situ stress. The simulation results show that DFN connectivity has a significant influence on the hydraulic fracture (HF) & DFN interaction and hydraulic fracturing effectiveness, which can be characterized by the total interaction area, stimulated DFN length, stimulated HF length, leak-off ratio, and stimulated total length. In addition, even at the same fluid injection rate, simulation models exhibit different responses that are strongly affected by the DFN connectivity. At a low injection rate, total interaction area decreases with increasing DFN connectivity; at a high injection rate, total interaction area increases with the increase of DFN connectivity. However, for any injection rate, the stimulated DFN length increases and stimulated HF length decreases with the increase of connectivity. Generally, this work shows that the DFN connectivity plays a crucial role in the interaction between hydraulic fractures, the pre-existing natural fractures and hydraulic fracturing effectiveness; in return, these three factors affect treating pressure, created microseismicity and corresponding stimulated volume. This work strongly relates to the production technology and the evaluation of hydraulic fracturing effectiveness. It is helpful for the optimization of hydraulic fracturing simulations in naturally fractured formations.     

Contributions of non-tectonic micro-fractures to hydraulic fracturing—A numerical investigation based on FSD model

Shale gas has been discovered in the Upper Triassic Yanchang Formation, Ordos Basin, China. Due to the weak tectonic activities in which the shale plays, core observations indicate abundant random non-tectonic micro- fractures in the producing shales. The non-tectonic micro-fractures are different from tectonic fractures and are characterized by being irregular, curved, discontinuous, and randomly distributed. The role of micro-fractures in hydraulic fracturing for shale gas development is currently poorly understood yet potentially critical. Two-dimensional computational modeling studies have been used in an initial attempt toward understanding how naturally random fractured reservoirs respond during hydraulic fracturing. The aim of the paper is to investigate the effect of random non-tectonic fractures on hydraulic fracturing. The numerical models with random non-tectonic micro-fractures are built by extracting the fractures of rock blocks after repeated heating and cooling, using a digital image process. Simulations were conducted as a function of: (1) the in-situ stress ratio; (2) internal friction angle of random fractures; (3) cohesion of random fractures; (4) operational variables such as injection rate; and (5) variable injection rate technology. A sensitivity study reveals a number of interesting observations resulting from these parameters on the shear stimulation in a natural fracture system. Three types of fracturing networks were observed from the studied simulations, and the results also show that variable injection rate technology is most promising for producing complex fracturing networks. This work strongly links the production technology and geomechanical evaluation. It can aid in the understanding and optimization of hydraulic fracturing simulations in naturally random fractured reservoirs.     

Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

Late quaternary hydrothermal explosion breccias at Kawerau Geothermal Field,New Zealand

Two large (10⁶–10⁷ m³ erupted volume) hydrothermal explosions occurred from craters on the eastern margin of Kawerau Geothermal Field at c. 14,500 and 9,000 yrs B.P. Explosion products are interbedded within C14 dated pyroclastic fall deposits and contain clasts of hydrothermally altered ignimbrite, rhyolite and tuff, in a silty hydrothermal clay matrix. No magmatic ejecta are found. Some ejected blocks record earlier pre-eruption episodes of shallow hydraulic fracturing and silica cementation. Drillhole stratigraphy indicates that explosion extended to about 190 m below present ground level. The explosion is analysed as a rock/water interaction with eruptive energy provided by flashing of about half the available water. Although surface heat flow and shallow temperatures are now low at eastern Kawerau, the hydrothermal explosions demonstrate the previous existence of a high temperature shallow geothermal system, probably related to a major fault feeding water up through the basement.     

Seismic Site Classification and Correlation between Standard Penetration Test N Value and Shear Wave Velocity for Lucknow City in Indo-Gangetic Basin

Subsurface lithology and seismic site classification of Lucknow urban center located in the central part of the Indo-Gangetic Basin (IGB) are presented based on detailed shallow subsurface investigations and borehole analysis. These are done by carrying out 47 seismic surface wave tests using multichannel analysis of surface waves (MASW) and 23 boreholes drilled up to 30 m with standard penetration test (SPT) N values. Subsurface lithology profiles drawn from the drilled boreholes show low- to medium-compressibility clay and silty to poorly graded sand available till depth of 30 m. In addition, deeper boreholes (depth >150 m) were collected from the Lucknow Jal Nigam (Water Corporation), Government of Uttar Pradesh to understand deeper subsoil stratification. Deeper boreholes in this paper refer to those with depth over 150 m. These reports show the presence of clay mix with sand and Kankar at some locations till a depth of 150 m, followed by layers of sand, clay, and Kankar up to 400 m. Based on the available details, shallow and deeper cross-sections through Lucknow are presented. Shear wave velocity (SWV) and N-SPT values were measured for the study area using MASW and SPT testing. Measured SWV and N-SPT values for the same locations were found to be comparable. These values were used to estimate 30 m average values of N-SPT (N ₃₀) and SWV (V _s ³⁰ ) for seismic site classification of the study area as per the National Earthquake Hazards Reduction Program (NEHRP) soil classification system. Based on the NEHRP classification, the entire study area is classified into site class C and D based on V _s ³⁰ and site class D and E based on N ₃₀. The issue of larger amplification during future seismic events is highlighted for a major part of the study area which comes under site class D and E. Also, the mismatch of site classes based on N ₃₀ and V _s ³⁰ raises the question of the suitability of the NEHRP classification system for the study region. Further, 17 sets of SPT and SWV data are used to develop a correlation between N-SPT and SWV. This represents a first attempt of seismic site classification and correlation between N-SPT and SWV in the Indo-Gangetic Basin.     

Evaluation of vertical variations in hydraulic conductivity in unconsolidated sediments

Detailed information on vertical variations in hydraulic conductivity (K) is essential to describe the dynamics of groundwater movement at contaminated sites or as input data used for modeling. K values in high vertical resolution should be determined because K tends to be more continuous in the horizontal than in the vertical direction. To determine K in shallow unconsolidated sediments and in the vertical direction, the recently developed direct-push injection logger can be used. The information obtained by this method serves as a proxy for K and has to be calibrated to obtain quantitative K values of measured vertical profiles. In this study, we performed direct-push soil sampling, sieve analyses and direct-push slug tests to obtain K values in vertical high resolution. Using the results of direct-push slug tests, quantitative K values obtained by the direct-push injection logger could be determined successfully. The results of sieve analyses provided lower accordance with the logs due to the inherent limitations of the sieving method.     

Contribution of climatic and anthropogenic effects to the hydric deficit of peatlands

The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay‐rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two‐year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 1·10^?7 to 3·10^?9 m.s^?1) and does not form a hydraulic barrier. Moreover, the vertical hydraulic gradients are downward between the peat and the sand aquifer, leading to high flows of groundwater through the clay layer (20–48% of the precipitation). The observed hydric deficit of the peatland results from a combination of dry climatic conditions during the study period and groundwater extraction. The climatic effect is mainly expressed through drying out of the peatland, while the anthropogenic effect leads to an enhancement of the climatic effect on a global scale, and a modification of fluxes at a local scale. The drying out of the peatland can lead to its mineralisation, which thus gives rise to environmental impacts. The protection of such wetlands in the context of climate change should take account of anthropogenic pressures by considering the wetland‐aquifer interaction. Copyright © 2011 John Wiley & Sons, Ltd.     

Experimental of the influence of mineral composition and normal stress on the frictional slip of shale

Natural fractures are widely distributed in shale reservoirs. During the hydraulic fracturing process, frictional slip occurring on natural fractures can increase the reservoir permeability and is of great significance to improve the efficiency of reservoir stimulation. Shale contains a large amount of clay and organic matter, and its frictional behavior is different from that of other previously studied lithologies. In this paper, the frictional behavior of shale is analyzed, and the results show that the frictional behavior is controlled by the content of clay and organic matter. As the content of clay and organic matter increases, the micro support type transforms from the particle support mode by hard quartz mineral to matrix support mode by plastic clay and organic matter. Accordingly, the shear strength and friction coefficient of shale both decrease, and the shear type transforms from brittle to plastic.When the content of clay and organic matter is low, the asperity of friction surfaces will break in a brittle manner and the wear degree of surfaces is low. Therefore, fractures are still featured by moderate apertures after friction.The lower the content of clay and organic matter is, the easier the asperity of crack surfaces supports themselves,and the higher the fracture residual permeability is. Thus, promoting shear slip is the main measure of reservoir stimulation. However, when the content of clay and organic matter is high, the remaining post-slip fracture aperture is small. It is difficult to increase reservoir permeability through the frictional slip of natural fractures,and in this situation, the proppant support efficiency needs to be improved.