The Late Early Cretaceous Mo Mineralization in the South China Mo Province: Constraints from U–Pb and Re–Os Geochronology of the Lufeng Porphyry Mo Deposit

Compared to other Mo provinces, few studies focused on the South China Mo Province(SCMP), especially for Early Cretaceous Mo mineralization. The Lufeng porphyry Mo deposit in the SCMP is characterized by disseminated and veinlet-type mineralization in granite porphyry, gneiss, and rhyolite. In this study, six molybdenite samples yield a Re–Os isochron age of 108.0±1.8 Ma, which is consistent with the zircon U–Pb age of the granite porphyry(108.4±0.8 Ma). The coincidence of magmatic and hydrothermal activities indicates that Mo mineralization was associated with the intrusion of granite porphyry during the late Early Cretaceous. A compilation of U–Pb and Re–Os chronological data suggests that an extensive and intensive Mo mineralization event occurred in the SCMP during the late Early Cretaceous. The marked difference in molybdenite Re contents between Cu-bearing(85–536 ppm) and Cu-barren(1.3–59 ppm) Mo deposits of the late Early Cretaceous indicates that the ore-forming materials were derived from strong crust–mantle interactions. Together with regional petrological and geochemical data, this study suggests that late Early Cretaceous Mo mineralization in the SCMP occurred in an extensional setting associated with the roll-back of the Paleo-Pacific slab.     

西藏中冈底斯成矿带查个勒铅锌矿床含矿斑岩年代学及其地质意义

查个勒铅锌矿床是西藏中冈底斯成矿带中段新发现的一个大型斑岩-矽卡岩型矿床,但其成岩成矿时代一直缺乏年代学约束。本文对该矿床含矿斑岩进行了LA-ICP-MS锆石U-Pb定年、辉钼矿Re-Os定年、主量和微量元素分析及Sr-Nd-Hf同位素组成研究,获得中冈底斯成矿带中段铜钼铅锌银矿化时代。含矿斑岩LA-ICP-MS锆石U-Pb年龄为64.6~62.9 Ma,代表岩浆的结晶年龄;辉钼矿Re-Os等时线年龄为(62.3±1.4)Ma,代表查个勒主成矿年龄,与其构造岩浆事件一致;结合区域林子宗群大规模火山活动(65~45 Ma)以及以亚贵拉铅锌矿床(68.6~ 65.0 Ma)为代表的成矿作用,表明在印度与欧亚大陆主碰撞过程中均可产生不同规模的成矿作用。查个勒含矿斑岩具富硅、富钾,贫钛、贫磷特征,铝饱和指数(A/CNK)为1.12 ~ 1.60,富集大离子亲石元素Rb、Th、U,亏损高场强元素Nb、Zr等,与冈底斯成熟大陆地壳物质相比具相对高的ε_Nd(t)值(-6.64 ~ -5.79)和相对低的(⁸⁷Sr/⁸⁶Sr)_i值(0.711 813~0.717 307),并具不均一的锆石ε_Hf(t)值(-7.02~-1.27)以及古老的锆石Hf同位素地壳模式年龄(T^C_DM=1 093~1 419 Ma),属于过铝质S型花岗岩类。本文认为中冈底斯成矿带中段古新世岩浆活动和成矿作用,很可能与雅鲁藏布江洋盆闭合之后的印-亚大陆碰撞诱发幔源岩浆底侵导致的冈底斯地体古老地壳物质部分熔融有关,岩浆在上升过程中有不同程度的分离结晶。     

Geochronology of the Xingshan molybdenum deposit,Jilin Province,NE China,and its Hf isotope significance

The Xingshan porphyry Mo deposit is located in the Lesser Xing’an Range–Zhangguangcai Range metallogenic belt, NE China. Mineralization occurred in granodioritic porphyry and monzogranite, which have zircon U–Pb ages of 171.7 ± 2.2 Ma and 170.9 ± 4.6 Ma, respectively. Molybdenite Re–Os dating indicates that Mo mineralization occurred at 167.3 ± 2.5 Ma. These geochronological data suggest that the magmatic and hydrothermal activities of the Xingshan Mo deposit happened during the Middle Jurassic in Mesozoic. Positive ε_Hf values (6.2–11.6) and young T_DM2 (473–826 Ma) of the monzogranite (XS-3) and granodioritic porphyry (XS-5) indicate that the source materials of Xingshan ore-bearing rocks are the juvenile crust, which mainly accreted on the Songnen block during the Meso-Neoproterozoic. Xingshan porphyry Mo deposits resulted from the magmatism and tectonism induced by the subduction of Paleo-Pacific Ocean.     

Triassic magmatism and Mo mineralization in Northeast China: geochronological and isotopic constraints from the Laojiagou porphyry Mo deposit

The Laojiagou Mo deposit is a newly discovered porphyry Mo deposit located in the Xilamulun Mo metallogenic belt, Northeast China. Mo mineralization mainly occurred within the monzogranite and monzogranite porphyry. Re–Os isochron dating of molybdenites indicate a mineralization age of 234.9 ± 3.1 Ma. Zircon LA–ICP–MS U–Pb analysis for monzogranite porphyry and monzogranite yield ²⁰⁶Pb/²³⁸U ages of 238.6 ± 1.8 and 241.3 ± 1.5 Ma, respectively, indicating that Laojiagou Mo mineralization is related to Middle Triassic magmatism. Hf isotopic compositions of zircons from both monzogranite porphyry and monzogranite are characterized by positive ε_Hf(t) values [ε_Hf(t) = 2.9–7.3 and 1.5–7.9, respectively] and young T_DM2 model ages, which implies that the magma was derived from juvenile crust created during accretion of the Central Asian Orogenic Belt (CAOB). Identification of the Laojiagou Mo deposit adds another important example of Triassic Mo mineralization in the Xilamulun Mo metallogenic belt where most Triassic Mo deposits in northeast China cluster around the northern margin of North China Craton. Based on the regional geological setting and geochronological and Hf isotope characteristics, we propose that Triassic Mo deposits and related magmatic rocks in northeast China formed during the last stages of evolution of the CAOB. These deposits formed during post-collisional extension after the closure of the Palaeo-Asian Ocean and amalgamation of the North China–Mongolian Block with the Siberian Craton.     

Geological and geochronological constraints on the genesis of the giant Tongkuangyu Cu deposit (Palaeoproterozoic), North China Craton

ABSTRACT

The Zhongtiao Mountain region is endowed with some of the largest Cu deposits in northern China, among which the Tongkuangyu Cu deposit contains 70% of the total reserves of copper. The orebodies in this deposit are confined to metamorphosed volcanic tuff and monzogranitic porphyry which are enclosed within metasediments. Metamorphism and deformation resulted in intense modification of the deposit, leading to debates surrounding its genesis. In this study, we investigate the lithology, hydrothermal alteration, and mineralization in the deposit. Secondary ion mass spectrometer and laser ablation ICPMS zircon U–Pb dating show that the meta-monzogranitic porphyry was emplaced contemporaneous with the surrounding lithologies at 2180–2190 Ma as a sill, and that the basic volcanic rocks erupted slightly earlier at ~2220 Ma. The Re–Os geochronological data on molybdenite from the deposit constrain the timing of copper mineralization to 2122 ± 12 Ma. Together with published information from previous studies on this region, we infer that during ~2100–2200 Ma the Zhongtiao Mountain region experienced continental or back-arc rifting. We exclude a porphyry copper model for the deposit and favour sediment-hosted stratiform explanation for this deposit.     

华北克拉通北缘白乃庙组变质火山岩锆石定年与岩石地球化学特征

白乃庙组绿片岩是白乃庙铜金矿床赋存层位,矿区构造上位于华北克拉通北缘古生代陆缘增生带内。岩石学、岩石地球化学特征指示该绿片岩原岩为中基性火山岩。对白乃庙组变质火山岩的锆石LA-MC-ICP-MS UPb年代学研究表明,该火山岩形成年龄为449±3Ma(n=33,MSWD=4.0),为晚奥陶世岩浆活动的产物。白乃庙组变质火山岩具有低的SiO2(43.47%~54.64%)、TiO2(0.60%~1.31%)和P2O5(0.08%~0.35%),宽的MgO(3.98%~12.99%)含量,属于钙碱性系列岩石,岩石富集大离子亲石元素K、Sr等,亏损高场强元素Nb、Ta,Zr、Hf也表现为轻微的亏损。轻重稀土分馏明显,具有不同程度的Eu异常(Eu/Eu*=0.7~1.2)和轻微负的Ce异常(Ce/Ce*=0.74~1.01)。岩石地球化学特征表明白乃庙变质火山岩经历了一定程度的结晶分异,橄榄石和单斜辉石为主要的结晶相。该变质火山岩具有较低的Ti/Y(2.5~5.0)和Zr/Y(189~355)值、低的176 Hf/177 Hf比值和较宽的εHf(t)值,暗示源区可能为岩石圈地幔,且受到了地壳的混染。Nb和Ta强烈亏损、极低的Nb/Ta值(0.08~1.09)以及Ce的负异常表明与大洋板块的俯冲作用有关,岩浆源区可能已受到俯冲组分的影响。构造环境判别显示白乃庙变质火山岩为与消减作用有关的大陆弧岩浆岩。锆石二阶段Hf模式年龄(tDM2)变化范围为1073~1470Ma,平均值为1285Ma(n=30),暗示华北板块北缘在中—新元古代时期曾发生过一次重要的构造热事件。     

内蒙古小东沟斑岩型钼矿床辉钼矿铼-锇同位素年龄及地质意义

为了进一步查明小东沟斑岩型钼矿床的形成时间,对主要钼矿体6件辉钼矿样品进行了铼-锇同位素分析,所获同位素等时线年龄为135.5±1.5Ma(2σ),其MSWD值为1.4。鉴于辉钼矿呈浸染状和团块状分布于斑状花岗岩株中,并且与石英和钾长石呈共生结构关系,可以推测小东沟地区钼矿床和斑状花岗岩株的形成时间均为早白垩纪,属燕山期构造-岩浆活动的产物。     

华北克拉通北缘及邻区印支期岩浆活动与钼和金成矿作用

对华北克拉通北缘及邻区19处钼矿床和5处金矿床的产出环境、形成时代和成矿机理及其与印支期侵入岩的关系进行了讨论。尽管各个矿床所处的地理位置不同,但是它们大都在前寒武纪或早古生代地层中产出,并且与印支期侵入岩具有密切的时空分布关系。印支期钼矿床的形成作用可以从早三叠世一直持续到晚三叠世,大规模成矿作用高峰期为230~220 Ma。相比之下,金矿床的形成时间明显早于钼矿床,同位素年龄数据集中分布在245~239 Ma。研究结果表明,自早三叠世开始,华北克拉通北缘及邻区曾发生过多期大规模伸展构造作用,并且形成若干条近东西向展布的裂陷带。张裂构造作用所诱发的富碱性岩浆作用及相关流体活动为钼或金矿床的形成提供了动力和物质来源,因此,印支期侵入岩发育区是寻找隐伏钼或金矿床的有利地区。     

Geological Characteristics and Ore‐forming Time of the Dexing Porphyry Copper Ore Mine in Jiangxi Province

The Dexing porphyry copper ore mine is located in the Qin-Hang metallogenic belt between the Yangtze block and the Cathaysia block. It is a giant porphyry copper mine in China, including 3 ore districts: Tongchang, Fujiawu and Zhushahong. Our analyses of Re in molybdenite indicate that the ore-forming material of the copper ore deposits in Dexing should be mainly mantle-derived. Our study fills in a gap in the study of formation time of the Dexing copper mine, and further proves that the copper ore deposits in the three ore districts should be formed simultaneously, about 170 Ma, belonging to the early Yanshan period, and that the formation time of the copper ore deposits should be consistent with the formation time of granodiorite porphyry in which the copper ore deposits are hosted. Promising areas for seeking porphyry copper ore deposits is predicated to be the west or southwest of Dexing.     

Re-Os Geochronology of Molybdenite from Yuanzhuding Porphyry Cu-Mo Deposit in South China

The Yuanzhuding porphyry Cu-Mo deposit, discovered in 2008, is located within the southern segment of the Chenzhou-Huaiji fault belt, South China. The deposit is hosted within the Upper Cambrian neritic facies sandstone and shale formation that is the strata of the axis and wings of within the Yuanzhuding anticline. Both of the porphyry and exo-contact zone contain Cu-Mo mineralization. Economic orebodies occur mainly in the exo-contact zone around the porphyry. We dated 11 molybdenite samples obtained from two borehole cores of the deposit, using the Re-Os method. Analyses of eight molybdenite samples from borehole ZK12-112 yield a Re-Os isochron age of 157.3 ± 4.3 Ma (2σ), and analyses of 11 samples from boreholes ZK12-112 and ZK16-104 yield a Re-Os isochron age of 155.6 ± 3.4 Ma (2σ). These isochron ages are within the error of the Re-Os model ages, demonstrating that the age results are reliable and that the Yuanzhuding porphyry Cu-Mo deposit formed during the late Middle Jurassic. The formation age of the Yuanzhuding Cu-Mo deposit is similar to the age of intermediate-acid rocks and W-Sn polymetallic deposits along the Chenzhou-Huaiji fault belt. This concordance suggests the same geodynamic process to the igneous activity and related mineralization, raising the potentiality of the porphyry Cu-Mo mineralization in the belt.     

Early Cretaceous magmatism and ore mineralization in Northeast China: examples from Taolaituo Mo and Aobaotu Pb–Zn deposits

The recently discovered Taolaituo porphyry Mo deposit and Aobaotu hydrothermal vein Pb–Zn deposit are both located in the Great Xing’an Range, Northeast China. Here we present new zircon U–Pb ages, whole-rock geochemical and Pb isotopic data, and molybdenite Re–Os ages for these two deposits. The Mo mineralization in the Taolaituo area occurred in quartz porphyry, which yields zircon U–Pb ages ranging from 138.5 ± 0.8 to 139.1 ± 0.5 Ma. Fine-grained granite representing pre-mineralization magmatic activity was formed at 145.2 ± 0.5 Ma. Molybdenite Re–Os dating indicates that Mo mineralization occurred at 133.8 ± 1.2 Ma. In the Aobaotu deposit, the ore-related granodioritic porphyry has a zircon U–Pb age of 140.0 ± 0.4 Ma. These geochronological data indicate that these magmatic and hydrothermal activities occurred during the Early Cretaceous. The mineralogical and geochemical features of the Taolaituo and Aobaotu granitoids suggest they can be classified as A₁-type within-plate anorogenic granites and I-type granites, respectively. The Pb isotopic compositions suggest a mixed crust–mantle origin of the granitoids in these two deposits. The Taolaituo granitoids were formed by the partial melting of lower crust and crust–mantle interaction, with subsequent fractionation of apatite, feldspar, Ti-bearing phases and allanite or monazite. In contrast, the Aobaotu granites were derived primarily from lithospheric mantle that had been transformed or affected by the addition of subduction-related components. Combined with the regional geology, tectonic evolution and available age data from the literature, our results suggest that the Early Cretaceous (140–100 Ma) was likely to be the most important peak period for metallogenic mineralization in Northeast China. The Taolaituo and Aobaotu deposits formed under an extensional environment at an active continental margin in response to subduction of the Palaeo-Pacific oceanic plate.     

Isotope geochemistry and Re–Os geochronology of the Yanjiagou Mo deposit in the central North China Craton

The Yanjiagou deposit, located in the central North China Craton (NCC), is a newly found porphyry‐type Mo deposit. The Mo mineralization here is spatially associated with the Mapeng batholith. In this study, we identify four stages of ore formation in this deposit: pyrite phyllic stage (I), quartz–pyrite stage (II), quartz–pyrite–molybdenite stage (III), which is the main mineralization stage, and quartz–carbonate stage (IV). We present sulphur and lead isotope data on pyrite, and rhenium and osmium isotopes of molybdenite from the porphyry deposit and evaluate the timing and origin of ore formation. The δ³⁴S values of the pyrite range from ‐1.1‰ to −0.6‰, with an average of −0.875‰, suggesting origin from a mixture of magmatic/mantle sources and the basement rocks. The Pb isotope compositions of the pyrite show a range of 16.369 to 17.079 for ²⁰⁶Pb/²⁰⁴Pb, 15.201 to 15.355 for ²⁰⁷Pb/²⁰⁴Pb, and 36.696 to 37.380 for ²⁰⁸Pb/²⁰⁴Pb, indicating that the ore‐forming materials were derived from a mixture of lower crust (or basement rocks) and mantle. Rhenium contents in molybdenite samples from the main ore stage are between 74.73 to 254.43 ppm, with an average of 147.9 ppm, indicating a mixed crustal‐mantle source for the metal. Eight molybdenite separates yield model ages ranging from 124.17 to 130.80 Ma and a mean model age of 128.46 Ma. An isochron age of 126.7 ± 1.1 Ma (MSWD = 2.1, initial ¹⁸⁷Os = 0.0032 ± 0.0012 ppb) is computed, which reveals a close link between the Mo mineralization and the magmatism that generated the Mapeng batholith. The age is close to the zircon U–Pb age of ca. 130 Ma from the batholith reported in a recent study. The age is also consistent with the timing of mineralization in the Fuping ore cluster in the central NCC, as well as the peak time of lithosphere thinning and destruction of the NCC. We evaluate the spatio‐temporal distribution of the Mo deposits in the NCC and identify three important molybdenum provinces along the northern and southern margins of the craton formed during three distinct episodes: Middle to Late Triassic (240–220 Ma), Early Jurassic (190–175 Ma), and Late Jurassic to Early Cretaceous (150–125 Ma). The third period is considered to mark the most important metallogenic event, coinciding with the peak of lithosphere thinning and craton destruction in the NCC. Copyright © 2014 John Wiley & Sons, Ltd.     

华北克拉通北缘侏罗纪造山过程及关键时限的沉积证据

宁武-静乐盆地与浑源盆地位于华北克拉通中北部,侏罗纪地层序列完整,物源指向于阴山-燕山造山带中段,通过对盆地内侏罗纪沉积特征的研究,可以演绎华北克拉通北缘侏罗纪的造山过程。在盆地沉积分析的基础上,通过宁武-静乐盆地中侏罗统云岗组顶部的凝灰质泥晶碳酸盐岩及浑源盆地上侏罗统髫髻山组玄武-安山岩锆石U-Pb同位素测年,结合国际地层年代表推荐年龄及中侏罗统的沉积速率,对整个侏罗纪沉积序列转换的关键时限进行了限定。研究认为：中侏罗统云岗组底部砾岩沉积时期,侏罗纪沉积演化序列经历了早期湖进至晚期湖退的转换过程,暗示着区域应力场由早期的拉张向晚期的挤压转换,孕育着侏罗纪造山运动的开始,具体时限大约为168 Ma;中侏罗统云岗组顶部凝灰质泥晶碳酸盐岩沉积时期,沉积地层的颜色由其下的灰绿色突变为其上的紫红色,孕育着湖盆地形的突然抬升,区域氧化性增强,气候环境的突变,侏罗纪造山运动进入了快速发展阶段,具体时限为161.0～159.0 Ma;中/晚侏罗世沉积序列具有继承性的发育特征,随着湖盆地形的进一步抬升,侏罗纪沉积范围迅速退至造山带前缘,以砾岩沉积为主,为同期造山运动的产物,侏罗纪造山运动进入了高峰期,具体时限为159.0～153.0 Ma;晚侏罗世晚期,区域上以玄武-安山岩及凝灰质角砾岩沉积为主,侏罗纪造山运动进入了造山期后的调整阶段。     

Re–Os Geochronology of Molybdenite from Yinyan Porphyry Sn Deposit in South China

The Yinyan Sn deposit, one of the three typical porphyry Sn deposits in China, is located in the western Guangdong province of the Cathaysia Block. Rhenium and osmium isotopes of molybdenites from the Yinyan deposit were first used to constrain the age of mineralization. Rhenium concentrations in molybdenite samples range from 0.13 to 1.3 µg g^?1, indicating a crustal source for the ore‐forming materials. The Re–Os dating yield model ages ranging from 78.1 to 79.52 Ma, with an average of 78.65 ± 0.98 Ma, and give an isochron age of 78.8 ± 2.6 Ma. Evidently, isochron age is consistent with model ages in the error within the allowable range, so we can constrain the precise age of Yinyan Sn deposit at the Late Cretaceous. Based on the geological history and spatial‐temporal distribution of the Sn deposits, it is proposed that the formation of Sn deposits in the Cathaysia Block were related to lithospheric extension that are associated with a change in the polarity of the subduction of the Paleo‐Pacific Plate from oblique subduction to parallel the eastern margin of the Eurasian Plate after 135 Ma.     

华北板块北缘东段中三叠世构造演化——来自辽宁法库地区侵入岩的证据

本文对华北板块北缘东段辽宁北部法库地区中三叠世风歧堡岩体和靠陵沟岩体进行了岩相学、锆石U-Pb年代学、地球化学及Lu-Hf同位素研究。LA-ICP-MS锆石U-Pb测年结果显示,风歧堡岩体和靠陵沟岩体加权平均年龄分别为（241±1） Ma和（243±1） Ma,侵位时代为中三叠世。风歧堡岩体的Ba和Sr质量分数分别为（290.00×10^-6~484.00×10^-6）和（129.00×10^-6~338.00×10^-6）,Sr/Y值为13.27~28.17,Sr/Yb值为117.50~250.28;靠陵沟岩体具有较高的Ba质量分数（899.00×10^-6~1 300.00×10^-6）和Sr质量分数（772.00×10^-6~997.00×10^-6）,以及较高的Sr/Y值（67.47~78.21）和Sr/Yb值（661.81~781.32）,Y、Rb和Yb质量分数较低,分别为11.00×10^-6~14.70×10^-6、55.80×10^-6~78.40×10^-6、1.17×10^-6~1.39×10^-6,地球化学特征上具有高Ba-Sr花岗岩的特征。此外,凤歧堡岩体样品富集大离子亲石元素Rb和K,亏损高场强元素Nb、P、Ti和大离子亲石元素Ba;靠陵沟岩体样品富集大离子亲石元素Ba、K、Sr,亏损高场强元素Nb、P、Ti。凤歧堡和靠陵沟岩体样品Nb/Ta值（4.18~10.26）和Zr/Hf值（30.39~38.76）与地壳平均值相近,Ni、Co和Cr质量分数较低;岩石地球化学特征表明法库地区中三叠世花岗质岩浆源岩为壳源岩石。中三叠世—晚三叠世早期,华北板块北缘东段处于造山地壳加厚阶段。研究区中三叠世花岗岩的ε_Hf（t）值均为正值,亏损地幔二阶段模式年龄（T_DM2）为949~555 Ma,结合岩石地球化学特征,中三叠世花岗质岩浆源岩为造山地壳加厚过程中新元古代新生下地壳部分熔融的产物。     

柴北缘赛坝沟金矿床花岗斑岩脉的成因及动力学背景: 来自年代学和地球化学的证据

青海乌兰县赛坝沟金矿床位于柴北缘结合带东部,为一中型石英脉型金矿。为进一步确定该矿床形成年龄和成因,对矿区内与成矿关系密切的花岗斑岩脉进行锆石U-Pb年代学和岩石地球化学研究。花岗斑岩LA-ICP-MS锆石U-Pb年龄为(372.4±4.1) Ma,是晚泥盆世岩浆活动的产物。花岗斑岩具高硅、富碱的特征,分异指数(DI)为81.40~84.54,固结指数(SI)为3.56~8.17,表明岩石结晶分异程度较高;微量元素原始地幔标准化图解显示La、Hf、Rb、Th相对富集,而Nb、Ta、P、Ti、Ba、Sr相对亏损;稀土元素球粒陨石标准化配分曲线呈右倾的轻稀土元素富集型,且具轻微Eu元素负异常。综合判别图解分析,认为花岗斑岩属过铝质钙碱性的I型花岗岩。赛坝沟金矿床花岗斑岩形成时间与柴北缘中晚泥盆世陆内伸展时间一致,整体形成于柴北缘中晚泥盆世陆内伸展阶段的后造山构造环境中。脉岩紧邻矿体产出并充填在构造裂隙中,其形成与成矿年龄相接近,因此可将赛坝沟金矿形成时间上限限定在372.4 Ma。后期找矿勘查工作应重点围绕花岗斑岩脉展开。     

华北克拉通北缘鸡冠山斑岩钼矿床成矿年代及印支期成矿事件

鸡冠山斑岩钼矿床是华北克拉通北缘少为人知的中生代西拉沐伦钼矿带中最大的钼矿床之一。它与鸡冠山次火山杂岩有关,杂岩体受NW向、NE向及NEE向三组断裂控制。锆石SHRIMP U-Pb定年表明,发育钼矿化的矿区内最晚的花岗斑岩侵位于245±2.7Ma。这表明,鸡冠山钼矿化发生在印支期。结合已有资料分析,认为华北克拉通北缘曾在印支期发生重要的岩浆-成矿事件。     

华北克拉通北缘寒武系层序地层划分

华北克拉通北缘寒武系碳酸盐岩作为区域油气勘探的重要目标,其沉积环境演化和层序地层格架的研究对区域地层及有利储层定位具有重要指导意义,也为华北地区寒武系油气勘探提供线索。以大量露头剖面实测分析为基础,结合典型井录井、测井、微观显微镜下分析以及地化测试等数据资料,在年代地层框架下进行旋回性地层分析研究,对华北克拉通北缘寒武系岩性、岩相以及地层叠置样式进行详细剖析,研究沉积趋势变化,总结寒武系层序地层划分样式。研究认为：在全球海平面变化控制下,华北地区自府君山组开始,发育广泛的由南向北的持续海侵,在陆源碎屑供给以及碳酸盐岩加积作用的相互制约下,华北地区表现为碳酸盐台地的形成-发展-镶边过程;以张夏组为界,中-下寒武统表现为缓坡-陆棚的沉积环境,上寒武统为具镶边的台地沉积背景;在不同层位不同层序边界类型（I型、Ⅱ型、Ⅲ型）的分隔作用下,将华北克拉通北缘寒武系划分为7个可区域性对比的三级层序,各三级层序高水位体系域多表现厚层清水碳酸盐岩沉积的特点,且受不同程度白云石化作用,成为区域寒武系重要的有利油气储集层。     

东秦岭东沟超大型斑岩钼矿SHRIMP锆石U-Pb和辉钼矿Re-Os年龄及其地质意义

东沟钼矿是在东秦岭钼矿带中于近年新发现的超大型斑岩钼矿床。对其含矿斑岩和矿石进行了成岩成矿年龄精测。采用SHRIMP锆石U-Pb测年技术,对东沟含矿铝质A型花岗斑岩体进行了年代学研究,获得成岩年龄为112±1Ma;采用ICP-MS法测定东沟钼矿中辉钼矿Re-Os同位素年龄,获得模式年龄为116.5±1.7~115.5±1.7Ma;两种方法获得的年龄相近,表明成岩与成矿大致同时形成。东沟斑岩钼矿与东秦岭金堆城、南泥湖、上房沟、雷门沟等斑岩钼矿具有20Ma以上的时差,反映它们形成于不同的地球动力学背景。     

内蒙古小东沟斑岩型钼矿床的成矿时代及成矿物质来源

小东沟斑岩型钼矿床位于大兴安岭南段,距北部的西拉木伦河大断裂仅25 km。对小东沟岩体进行了Sr-Nd同位素和铅同位素分析,87Sr/86Sr(t)为0.705 0~0.705 5,εNd(t)为-2.4~-2.8;对主要钼矿体的6件辉钼矿样品进行了铼-锇同位素分析,所获同位素等时线年龄为(138.1±2.8)M a,表明小东沟钼矿床形成于早白垩世。铅同位素分析结果表明小东沟斑岩型钼矿床的成岩成矿物质具有不同来源,成岩物质来自俯冲洋壳衍生的新生地壳物质,而成矿物质来自地幔分异的产物(流体),属于壳源岩浆+幔源流体的组合。结合区域构造演化历史,对小东沟斑岩型钼矿的成因做出如下解释:在早白垩世,大兴安岭开始隆升,岩石圈拆沉,软流圈(层)物质上涌、基性岩浆的底侵以及地幔流体的加入,引起下地壳岩石的熔融,随后更多的地幔含矿流体进入到岩浆房。岩浆携带来自地幔的含矿流体,沿着区域性的EW、NE向深大断裂上侵定位,并在此过程中演化形成富硅、富钾质的花岗岩,最后沿近NS向的断裂侵位到二叠纪地层中,沉淀形成矿床。