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全反射X射线荧光光谱法同时测定天然水中多种元素 总被引:4,自引:0,他引:4
利用自行研制的有3个反射体的全反射X射线荧光分析仪,以Se作内标,同时测定天然水中的痕量Ni、Cu、Zn、Pb、Rb和Sr。对纳克级元素,方法的检出限为10-10~10-11g,水样分析结果与无火焰原子吸收法和ICP MS法相符,精密度好,对纳克级痕量元素测定的RSD(n=5)小于72%。 相似文献
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建立了X射线荧光光谱(XRFS)分析中修正比例常数法的理论和分析方法,主要用来测定8 ̄24K黄金首饰样品中的主、次元素含量。 相似文献
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X射线荧光光谱法直接测定地质样品中多种痕量元素 总被引:2,自引:0,他引:2
采用低压聚乙烯镶边垫底的粉末压饼法制样,X射线荧光光谱法直接测定了地质样品中痕量元素As、Ga、Sc、La、Y、Ce、W、Mo、Sn、Co和Pb。讨论了背景校正、谱线重叠校正、基体效应校正和仪器漂移校正等问题。利用理论α系数代替经验系数,使方法具有较高的准确度和较低的检出限。所测11个元素的检出限在(0.30~2.02)×10-6水平,精度(RSD,n=11)在0.95%~13.0%。方法经国家一级标准物质分析验证,结果与标准值相符。 相似文献
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密度校正法测定金饰品中的金 总被引:3,自引:0,他引:3
折书群 《有色金属矿产与勘查》1998,7(3):182-185
通过研究共存元素及基体效应,提出了用X射线荧光密度校正法(XRF)无损检验金饰品中金。该方法测定金的含量范围为10% ̄99%,精密度为0.2%。 相似文献
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酸分解试样,点滴麦勒膜制片,Ni元素作内标,使用X射线荧光光谱法同时测定金银标准样品中Au,Ag,Cu和Zn,分析范围为0.2%-100%。对于Au,Ag,Cu和Zn含量为83%,8.0%,6.2%,3.0%的试样,其RSD(n=6)分别为0.1%、1.1%、0.9%和1.1%。 相似文献
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X射线荧光靶线内标法测定金首饰中的银 总被引:8,自引:1,他引:7
采用X射线荧光靶线内标法测定黄金饰品中银含量,当w(Ag)<10%时,测定的标准偏差小于001%,测量平均值与标准值的偏差亦小于001%;当w(Ag)<8%时,测定的标准偏差小于004%,测量平均值与标准值的偏差小于007%。方法能较好地补偿了表面形状对测定结果的影响,适用w(Au)>92%的饰品中银的测定 相似文献
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美国环保局环境响应队(USEPA/ERT)已广泛应用野外便携式X射线荧光仪9FPXRF)在全国范围内对危险废物污染区的土壤和沉积物中的金属进行分析。USEPA/ERT有两种X荧光仪:Outokumpu电子公司(OEI)的X-MET880型Spectrace仪器公司生产的Spectrace9000型FPXRF分析仪。文中讨论了仪器的标定、精度的确定和检出限,阐述了就地分析和分析制备的土壤术方法。各种 相似文献
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X射线荧光光谱集成分析系统 总被引:4,自引:2,他引:2
选用了兼容性能好的386微机,在DOS操作系统和Windows3.1环境下,研究开发了X射线荧光光谱集成分析系统(XRFIAS),全面更新了理学公司3080系列仪器的计算机硬件和软件。采用了当前最流行的多窗口,全屏幕友好界面,在西文DOS操作系统下,显示汉字信息。有常规的(背景扣除,内标校正,谱重叠校正,基体校正)数据处理功能(多种校正模式)扩充了分析元素,内标元素、干扰元素的数量,新开发了共用背 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引:4,自引:0,他引:4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozach Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
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正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level 相似文献
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正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7), 相似文献
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正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci- 相似文献
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正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli- 相似文献
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正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.) 相似文献
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正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861 相似文献