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《Applied Geochemistry》1988,3(2):225-230
The detection of several unmined submarine exhalative sulfide deposits, most of which are concealed with no surface expression, was investigated using the distribution grain counts of tourmaline in stream sediment concentrates. The number of sulfide zones located using this method is comparable to that achieved using trace metal nalyses of fine-grained stream sediment andMnz.sbnd;Fe oxide coatings on stream pebbles. Because both dravite, associated with a sulfide zone, and schorl, from a pegmatite, are known to occur in the field area, it is likely that both will occur in stream sediment and will be included in tourmaline-grain-counts of sediment concentrates. Attempts to differentiate dravite and schorl in the sediment concentrates, based on microscopically observable physical properties, were unsuccessful, but semi-quantitative chemical analyses should readily accomplish this because of large differences in Mg and Fe concentrations.  相似文献   

3.
Chemical partitioning data are of fundamental interest to exploration geochemists. This paper is one of the few studies which has investigated the relative proportions of the rare elements in various soil extracts. The dispersion of trace elements from weathering pegmatites in Powhatan Country, Virginia, was found to be restricted to the immediate vicinity of the pegmatites. A sequential extraction procedure was used to measure the distribution of Be, La, Nb, Sn, U, Li, and Ni,among the following fractions of the B soil horizons: exchangeable, Fe and Mn oxyhydroxide, residual, and aqua regia digestion. The elements Sn, Be, Li, and U were found to be associated with soils over the complex Herbb No. 2 pegmatite, whereas La and Ni were generally associated with the background soils.A geochemical exploration model was developed using stepwise discriminant function analysis to determine the combination of elements and soil extracts that best differentiates between complex pegmatitic, simple pegmatitic, and background soils. Log-transformed aqua regia extract concentrations of Sn, La, U, and Li were the most effective variables when used to separate complex pegmatitic from simple pegmatitic soils.  相似文献   

4.
Cataclasis and frictional wear are the primary bulk deformation mechanisms along steeply dipping portions of the Saltville thrust in the southern Appalachian foreland zone, U.S.A. Fault character ranges from a single discrete sliding surface with negligible gouge, to a zone of several discrete sliding surfaces or a zone (up to 0.3 m thick) of pervasive cataclasite. Marked fracturing occurs up to 20 m above the fault, whereas minimal deformation is found in the footwall rocks. Hanging wall dolomites range from crush breccias (less than 5% matrix) to ultracataclasites (with 90% matrix), although cataclasites (50–70% matrix) are predominant. Foliated cataclasites occur where dolomite is thrust over shale. Progressive development of cataclastic fabrics is due to comminution by fracturing and grinding along intersecting fractures. Continued frictional grinding results in complete disruption of the original fabric to produce cataclasite and minor ultracataclasite. Grain alignment occurs by rigid body rotation with subsequent local enhancement by pressure-solution. Microstructural relations of the fault gouge suggest periodic fluctuations in fluid pressure, where λv (ratio of fluid to overburden pressure) probably ranged between 0.45 and 1. The Saltville thrust-sheet emplacement must have occurred in a caterpillar-like fashion involving aseismic and seismic shear. Shear stresses accompanying fault motion as determined from dolomite twin lamellae are in the order of 65 mPa.  相似文献   

5.
The Ratcliff Site in southwestern Virginia lies in a small second-order stream valley filled with approximately 3.5 m of organic-rich deposits that contain bones of mammoth, mastodon, deer (or antelope), logs, and plant macrofossils. Radiocarbon analyses indicate the age of the organic-rich sediment ranges from > 44,000 to 29,100 14C yr BP, a time period with no fossil remains reported in this region of the Appalachians. Analyses of field observations, textural data, organic carbon content, and plant macrofossils indicate that the organic-rich sediments contain interbedded standing-water and debris-flow deposits. Up to 6 m of oxidized debris-flow sediments bury the organic-rich sediments. The presence of Rubus parviflorus (Thimble Berry) throughout the deposit indicates the site had a boreal environment from > 44,000 to 29,100 14C yr BP. Plant macrofossil evidence indicates the uplands had stands of spruce/jack-pine forests while the valley contained ponds and associated wetlands. Three debris flows occurred at the site between approximately 38,000 and 29,000 14C yr BP, suggesting a recurrence interval for major storms of approximately 3000 yr, even though the apparent stability of the boreal environment implies a climate not conducive to catastrophic rainstorms. This conflicting combination of features suggests that during the middle Wisconsinan this area experienced generally cool climates, dominated by polar air masses, but was punctuated by relatively brief warm periods marked by incursions of tropical air masses.  相似文献   

6.
Suspended and equivalent active sediments were collected from streams at 84 sites at the eastern and western sides of a ridge with stratabound Zn mineralization, Rockingham County, Virginia (USA). The purpose was to evaluate the relative effectiveness of suspended and bottom sediment in the geochemical exploration for Mississippi-Valley type Zn ores. The orebody is composed of sphalerite and minor amounts of galena with some chalcopyrite, strikes parallel to the enclosing dolomite beds at N34°E, and cuts vertically across the 30°SE dip. Oxidation of the ore extends to about 100 m in depth.Zinc was effective in detecting the mineralized zone. Zinc in the suspensates provided a denser anomaly system (7 strong and 2 moderate samples) than Zn in the <150 μm size of the bottom sediment, either totally dissolved (4 strong and 1 moderate anomalies) or extracted with cold 3% HCl (5 strong and 3 moderate anomalies). The magnitude of the high values for suspensate Zn was considerably higher than those for the other sample types studied. Suspensate Zn was complemented by 3 strong suspensate Cu anomalies. The suspensate Zn anomaly dispersion was about 850 m, 400 m of which was upstream from the mineralization. Lead was detected only in the cold acid extraction and in combination with Cu and Zn gave an extensive overlapping multielement anomaly string that targeted the ore zone and had a dispersion downstream from the mineralization of more than 1000 m. The Pb anomalies extended about 900 m upstream and 400 m downstream from the ore zone. Together with suspensate Zn, the Pb anomalies suggest a continuation of mineralization upstrike from the known orebody.The major anomaly systems are along the eastern side of the ridge with comparatively few anomalies present in the drainage along the western side. The concentration of anomalies in the eastern drainage and anomaly disposition with respect to known mineralization result from structural control on the hydromorphic dispersion of metals from the orebody.  相似文献   

7.
Loading trends and sources of CI in the South Fork of the Shenandoah River, Virginia were analyzed for the period 1929–1982. CI has increased from approximately 2 mg/L (2,776 tons/yr) to over 10 mg/L (14,256 tons/yr). Natural CI is estimated to be 1.01 mg/L (1,388 tons/yr) with precipitation providing 0.99 mg/L and rocks 0.02 mg/L. From 1929 to 1949 CI concentrations were relatively constant and independent of discharge, conforming to the Type II curve of Davis and Zobrist (1978), indicative of natural or relatively uncontaminated streams. Since 1952 CI concentrations increased exponentially as river discharge decreases conforming to the Type I curve of Davis and Zobrist for polluted streams. Since 1965 anthropogenic CI loading at 12,868 tons/yr has remained relatively constant. Four major sources contribute 92.2 percent (11,871 tons/yr) of the anthropogenic CI: (1) deicing salts—4,149 tons/yr, (2) domestic sewage—3,015 tons/yr, (3) livestock and poultry wastes—2,458 tons/yr, and (4) commercial fertilizers—2,249 tons/yr.  相似文献   

8.
Cactus Hill is located in the Virginia Coastal Plain on a terrace above the Nottoway River. The site has a record of occupation that spans the Holocene and also offers evidence of humans late in the Pleistocene before Clovis time. Soil investigations identified several deposit types, and demonstrated that multisequal eolian sands forming the site's primary core are arrayed in spatially and temporally discrete horizons. Resting atop an ancient paleosol, the earliest sand stratum (19,540 ± 70 14C yr B.P.) is marked by a conspicuous but culturally sterile buried surface horizon. Eolian sand above this surface supports another sequum in which Clovis and underlying “Blade” artifacts are associated with a fainter surface horizon and pronounced subsoil lamellae. Early Archaic and successively younger artifacts occur above the Clovis level in a more weakly developed uppermost sequum. This soil and cultural stratigraphy, together with considerations of regional topography, demonstrate that the landscape has evolved incrementally since about the last glacial maximum. © 2004 Wiley Periodicals, Inc.  相似文献   

9.
The Pacific Border Ranges of the southern Alaskan Cordillera are composed of a number of allochthonous tectonostratigraphic terranes. Within these terranes are widespread volcanogenic, massive sulfide deposits in and adjacent to portions of accreted ophiolite complexes, bands and disseminations of chromite in accreted island-arc ultramafic rocks, and epigenetic, gold-bearing quartz veins in metamorphosed turbidite sequences. A geochemical pilot study was undertaken to determine the most efficient exploration strategy for locating these types of mineral deposits within the Pacific Border Ranges and other typical convergent continental margin environments.High-density sediment sampling was carried out in first- and second-order stream channels surrounding typical gold, chromite and massive sulfide occurrences. At each site, a stream-sediment and a panned-concentrate sample were collected. In the laboratory, the stream sediments were sieved into coarse-sand, fine- to medium-sand, and silt- to clay-size fractions prior to analysis. One split of the panned concentrates was retained for analysis; a second split was further concentrated by gravity separation in heavy liquids and then divided into magnetic, weakly magnetic and nonmagnetic fractions for analysis. A number of different techniques including atomic absorption spectrometry, inductively coupled plasma atomic emission spectrometry and semi-quantitative emission spectrography were used to analyze the various sample media.Comparison of the various types of sample media shows that in this tectonic environment it is most efficient to include a silt- to clay-size sediment fraction and a panned-concentrate sample. Even with the relatively low detection limits for many elements by plasma spectrometry and atomic absorption spectrometry, anomalies reflecting the presence of gold veins could not be identified in any of the stream-sediment fractions. Unseparated panned-concentrate samples should be analyzed by emission spectroscopy and atomic absorption spectrometry for Ag and Au. If, however, magnetic and nonmagnetic concentrate fractions are used in a reconnaissance program, semiquantitative emission spectrography is adequate for all analytical work.  相似文献   

10.
Statistical analysis of the radon-222 potential of rocks in Virginia,U.S.A.   总被引:1,自引:0,他引:1  
More than 3,200 indoor radon-222 (222Rn) measurements were made seasonally in an area of about 1,000 square kilometers of the Coastal Plain and Piedmont physiographic provinces in Virginia, U.S.A. Results of these measurements indicate that some geological units are associated, on the average, with twice as much indoor222Rn as other geological units, and that indoor222Rn varies seasonally. The Kruskal-Wallis test was used to test whether indoor222Rn concentrations for data gathered over the winter and summer seasons differ significantly by rock unit. The tests concluded that indoor222Rn concentrations for different rock units were not equal at the 5-percent significance level. The rocks associated with the highest median indoor222Rn concentration are specific rocks in the Mesozoic Culpeper basin, including shale and siltstone units with Jurassic diabase intrusives, and mica schists in the Piedmont physiographic province. The pre-Triassic Peters Creek Schist has the highest ranking in terms of indoor222Rn concentration. The rocks associated with the lowest indoor222Rn concentrations include coastal plain sediments, the Occoquan Granite, Falls Church Tonalite, Piney Branch Mafic and Ultramafic complex, and unnamed mafic and ultramafic inclusions, respectively. The rocks have been ranked according to observed222Rn concentration by transforming the average rank of indoor222Rn concentrations to z scores.  相似文献   

11.
Groundwater contamination is a well-known phenomenon, which occurs on local and regional scales in Izeh polje. The aims of this paper are investigation of the impact of human activities on the polje ecosystem, determination of the vulnerability of ground water, and to solve environmental problems. Nitrate contamination of groundwater in the Izeh polje was predicted using a solute transport model. The nitrate concentration in groundwater in most parts of Izeh polje is greater than maximum concentration permissible for drinking water, i.e., 45 mg/l. The main source of nitrate in the eastern underground areas of Izeh city is the domestic sewage. Bacterial pollution of shallow ground water in Izeh polje is severe and widespread. About 45% of ground water samples in May and September 2001 have positive MPN coliforms. Infiltration of polluted surface waters and decrease of water table depth, have lead to bacterial pollution of 80% of ground water samples in January 2002. The northeast, south and southwest areas of Izeh polje have higher pollution potential rather than its middle parts. The aquifer vulnerability indices in the middle, eastern, and northern parts of the polje are moderately lower as a result of decreased sediment size of the aquifer. The pollution in the polje depends on the amount and presence of pollutants. If they do exist, the possibility of pollution is considerable due to the coarseness of materials and shallow depth of groundwater table.  相似文献   

12.
Carbonaceous clay found in the palaeo-deposits of Meenachil River basin was analysed for the total organic carbon, nitrogen and textural characters. Radiocarbon dating of this clay formation and the embedded carbonized wood fragments was also done. The values obtained for the organic carbon, nitrogen and C/N ratio of the carbonaceous clay exhibited a very remarkable range, suggestive of different environmental conditions of formation. It is evident from the present study that since the lignin and cellulose are the dominant components of terrestrial higher plants, allochthonous and submerged organic matter have high C/N ratio. The radio carbon dating of the sediment and wood samples suggested that the palaeo-deposits of Meenachil River basin were formed as result of many transgrassive–regressive episodes, which had started even before the formation of Vembanad Lake. The formation of carbonaceous clay, as found sandwiched in palaeo-deposits, was due to the global eustatic sea-level fluctuations and tectonism.  相似文献   

13.
Summary Ferroan-gahnite, (Zn,Fe)Al2O4, is a common accessory mineral found in association with the metamorphosed volcanogenic massive sulfide ore bodies of the Mineral District, Virginia. Gahnite is present throughout the mineralized zones that contain pyrite, sphalerite, chalcopyrite, and sulfosalts. Although constituting only 1–2 modal percent of most samples and displaying not well-defined distribution pattern, gahnite is especially abundant at the margins of the mineralized zones and locally constitutes as much as 35 modal percent. The compositions vary slightly from one deposit to another but all lie within the range of 68 to 88 mol.% gahnite (ZnAl2O4), 8 to 25 mol.% hercynite (FeAl2O4), and 1–17 mol.% spinel (MgAl2O4). Gahnite occurs within a wide variety of mineral assemblages, with or without coexisting sphalerite.The reflectance and unit cell dimension are sensitive to composition and decrease with increasing gahnite component. The approximate 8% reflectance at 540 nm is intermediate between most silicates and ore minerals such as sphalerite and magnetite and thus provides a ready method for recognition in reflected light. The gahnite is believed to have formed during amphibolite grade regional metamorphism as a result of either sphalerite desulfidation or the reaction of original zinc oxide phases.
Gahnit in metamorphen schichtgebundenen Sulfid-Lagerstätten des Mineral-Distriktes, Virginia, U.S.A.
Zusammenfassung Eisenhaltiger Gahnite (Zn,Fe)Al2O4 ist in den metamorphen vulkanogenen massiven Sulfiderzkörpern Virginias als akzessorisches Mineral weit verbreitet. Er kommt durchwegs in den Pyrit, Zinkblende, Kupferkies und Sulfosalze enthaltenden mineralisierten Zonen vor. Obwohl die meisten Proben nur 1–2 Modal % Gahnit enthalten, und keine klar definierte Verteilung zu erkennen ist, tritt er besonders häufig an den Rändern der mineralisierten Zonen auf und erreicht lokal 35 Modal %. Die Zusammensetzung schwankt leicht von Vorkommen zu Vorkommen, liegt aber stets zwischen 68 und 88 Mol.% Gahnit (ZnAl2O4) 8 und 25 Mol.% Hercynit (FeAl2O4) und 1 und 17 Mol.% Spinell (MgAl2O4) Gahnit ist Bestandteil sehr verschiedener Mineralparagenesen mit und ohne Zinkblende.


With 7 Figures  相似文献   

14.
Soil and stream sediment sampling have been the primary geochemical exploration tools in the Appalachian piedmont to date. However, the great thicknesses of soil and saprolite found in the region coupled with the dense vegetation frequently encountered favor biogeochemistry as an alternative or supplemental method since deep-rooted plants sample closer to bedrock. To evaluate this method, an orientation survey was performed in which soils and vegetation at 17 sites north of Mineral, Virginia, were sampled and analyzed for Ag, Cd, Cu, Pb and Zn. The traverse included stations over the host rocks of massive sulfide mineralization, as well as over apparent “barren” country rock. Samples were analyzed by atomic absorption spectrophotometry using standard digestion and analytical techniques.Both A- and B-horizon soil metals generally appear to be reliable indicators of mineralization, with soils developed over sulfides showing up to three-fold enrichment in metal content relative to the average soils developed on the country rock. Correlation of metal concentrations in vegetation to soil metal concentrations reveal plant concentrations expressed on a dry-weight basis correlate stronger and more frequently to soil metals than do ash-weight concentrations. Copper shows some promise in selected organs and species, Ag appears fair but data are limited to one organ of one species, and plant Pb seems totally unresponsive to soil metal concentrations perhaps because foliar absorption is an important plant uptake mechanism here. However, Zn and Cd in organs of the oak group, especially mature leaves and twigs of the current year's growth show the greatest promise as prospecting tools. They correlate well with soil metals and when compared directly to the geology they reliably reflect mineralization. Although results using White oak were slightly less profound than those obtained from the Black-Red oak group, White oak may be preferred as it is a single, more widespread, easily-identifiable species. Copper and especially Zn although essential elements to plants, do not appear to be “difficult” elements for biogeochemical prospecting in the Appalachian piedmont.  相似文献   

15.
The Lueders Formation (mid-Permian) in Baylor County, Texas, is an intercalated suite of fluvial siliciclastic, shallow marine siliciclastic, and shallow marine carbonate strata. There are at least two generations of carbonate cements (probably originally composed of calcite) in the fluvial sandstones where fractured grains are observed. These cements represent the initial stages of caliche formation. Cementation is envisioned as a two step process. In the first step, calcite cements form from supersaturated fluids in a freshwater, vadose environment as a meniscus cement at grain contacts. Areas of cement formation are restricted to these sites because fluid distribution is restricted to these sites. Stresses generated by the growth of cements at grain contacts are transmitted through and concentrated at quartz/quartz grain point-contacts until the stress is sufficient to fracture quartz grains, even though the ultimate strength of calcite is less than that of quartz, per unit area. This process occurs too rapidly to be accommodated by pressure solution. In the second phase of cementation, cement nucleation is no longer restricted by vadose conditions. In this phase, calcite growth can no longer result in quartz grain breakage; rather, the quartz grains are dispersed in poikilotopic calcite cement.  相似文献   

16.
Abstract Metapelites in the Altavista area, southwest Virginia Piedmont, USA, underwent allochemical hydrothermal retrograde metamorphism in synmetamorphic shear zones. The metapelites of the Evington Group were metamorphosed in a prograde sequence of chlorite, staurolite, and sillimanite zones. Garnet–biotite geothermometry and phase relations support eastward increasing metamorphic grade, ranging from 570° C in the staurolite zone to 650° C in the sillimanite zone at c. 5.8 kbar. Sillimanite-zone rocks later underwent progressive retrogression around shear zones which acted as fluid conduits. Retrograde assemblages are successively zoned around the shear zones with staurolite-, chloritoid- and kyanite-bearing assemblages. The shear zones commonly contain kyanite or tourmaline veins. Applicable phase equilibria indicate that retrogression occurred during isobaric cooling through c. 200–270° C. Rock compositional changes with retrogression occurred in steps: SiO2 was gained in the early stages of the retrogression but lost in the late stages; Al2O3, K2O, and H2O were increasingly gained through the sequence; CaO was increasingly lost. Addition of H2O and decreasing temperatures resulted in new ferromagnesian minerals (staurolite, chloritoid, chlorite) and changes in H2O, SiO2, Al2O3, K2O, and CaO contents produced muscovite and sodic plagioclase. Subsequent to prograde metamorphism, deeply derived fluids migrated upwards along shear zones, providing fluid and energy for the retrograde reactions. The sheared rocks underwent fluid infiltration with fluid fluxes of 1.8 × 107–4.3 × 107 cm3/cm2 corresponding to minimum estimated fluid-to-rock ratios of 7.5–21 as a function of position within the shear zone. Fluid flow was from high to low temperature early and low to high temperature later in the retrogression.  相似文献   

17.
Measurements of palaeomagnetic inclination in sediments from the French Pays Basque, representing three of the major Pleistocene biostratigraphic subdivisions previously identified, confirm normal polarity in all cases. Taken together with the palaeobotanical, stratigraphic and geomorphological evidence they suggest that the Moulignan, Senixian and Ilbarritzian stages lie within the early part of the present Brunhes normal polarity epoch and probably correlate with some unknown part of the “Cromerian Complex”. The Bidartian is thought to lie within a normal polarity event during the Matuyama epoch and to correlate with part of the Tiglian ‘A’ sub-stage of the Netherlands.  相似文献   

18.
Power-law relationship between tidal prism (P) and the cross-sectional area of the entrance channel (A) is applicable to assess the equilibrium conditions of a tidal inlet system. The classic method of determining P-A relationships proposed by O’Brien depends on datasets from multi-tidal inlet systems, which has shown some limitations and is unable to assess equilibrium of a single tidal inlet. This paper focuses on establishing a new P-A relationship for a single tidal inlet. Our experimental result shows that in order to maintain the status, power n should be > 1, implying that the inlet width will narrow and current speed within the entrance will increase as tidal prism becomes smaller. A possible explanation for power n <,1.0, as many researchers argued before, is that the influence of tidal prism has been exaggerated. Meanwhile, the magnitude of coefficient C is dependent on many factors such as longshore drift, freshwater discharge, etc, resulting in a wide range of variation of C. It should be pointed out that P-A relationship given by the sediment dynamical approach is still a representative of average status for tidal inlets in equilibrium. As tide, wave, freshwater discharge and tidal inlet morphology change with time, actual P-A relationships will fluctuate also. The problems that need to be solved when applying sediment dynamic methods to P-A relationships include the cross-sectional distribution pattern of tidal current speeds in the entrance channel, the relationship between the tidal current and the tidal water level at the entrance, and the calculation of the ratio of width to depth. This paper will establish a sediment dynamical approach of P-A relationship for a single tidal inlet. The results are tested for P-A relationships of Yuehu Inlet, a small inlet-lagoon system located in Shandong Peninsula, China. __________ Translated from Oceanologia Et Limnologia Sinica, 2005, 36(3): 269–276 [译自: 海洋与湖沼]  相似文献   

19.
The Precambrian metamorphic complex in the southern portion of Wind River Canyon is interpreted as being a fragment of an Archaean greenstone belt. The sequence is composed of meta-sediments inferred to have been various types of pelites and psammites, including graywackes and shales, and a silicate facies banded-iron formation. Meta-volcanics are represented by massive amphibolites.The area has undergone three periods of roughly coaxial folding that represent a single tectonic pattern. A period of intrusion of leucogranite with associated pegmatites separates the first two periods of deformation. These rocks appear to have been derived anatectically from sialic material at greater depth, suggesting the possibility of a sialic basement on which the greenstone belt rocks accumulated. Boudinage of the country rocks can be correlated with either or both of the first two folding episodes, and boudinage of the intrusive rocks occurred with different styles in the axial surfaces of the second and third generation folds.One period of amphibolite-facies metamorphism corresponds to the first and second deformational phases. Minor retrograde effects, fracture fillings, and small-scale metasomatism occurred either in the waning stages of the metamorphism or during a minor subsequent thermal event.Numerous Archaean ages from the Wyoming Precambrian province place Wind River Canyon in a region where examples of such greenstone belts might be expected. As no young intrusive or tectonic events have been reported from the area, the youngest deformational features discussed are considered to be not much younger than reported radiometric dates and therefore not of regional significance.  相似文献   

20.
Tertiary sandstones collected from southwest Sarawak, Malaysia, were analyzed to decipher their provenance, weathering, and tectonic setting. The studied sandstones have a sublitharenite composition and are dominantly composed quartz with little mica and feldspar, and a small amount of volcanic fragments. These sandstones were generally derived from quartz-rich recycled orogenic sources. They have relatively high SiO2 content with low Na2O, CaO, MnO, and MgO contents. Values of Chemical Index of Alteration (CIA) of these rock samples vary from 71 to 93, with an average of 81, implying intense chemical alteration during weathering. A felsic igneous source is suggested by a low concentration of TiO2 compared to CIA, enrichment of Light Rare Earth Elements, depletion of Heavy Rare Earth Elements, and negative Eu anomalies. A felsic origin is further supported by a Eu/Eu* range of 0.65–0.85 and high Th/Sc, La/Sc, La/Co, and Th/Co ratios. This work presents the first reported geochemical data of Tertiary sandstones of the Sarawak Basin. These data led us to conclude that the sandstones were dislodged from recycled orogenic sources and deposited in a slowly subsiding rifted basin in a passive continental tectonic setting.  相似文献   

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