浙江丽水地区磨石山群火山岩时代归属

为查明浙江丽水地区中生代磨石山群火山岩的时代,在区域地质调查、火山机构划分的基础上,选择该群代表性火山岩进行锆石年龄测定。结果表明,大爽组底部流纹质晶屑熔结凝灰岩的SHRIMP锆石U-Pb年龄为154.9±5.5 Ma、LA-ICP-MS锆石U-Pb加权平均年龄为152.0±7.0 Ma,属晚侏罗世基默里奇阶;高坞组流纹质晶屑熔结凝灰岩SHRIMP锆石U-Pb年龄为131.6±2.7 Ma,两个火山机构的西山头组流纹质晶屑凝灰岩LAICP-MS锆石U-Pb加权平均年龄分别为128.6±1.7 Ma和139.5±2.5 Ma。认为浙南磨石山群火山岩时代:大爽组为晚侏罗世,高坞组、西山头组、茶湾组和九里坪组为早白垩世。     

北秦岭造山带武关岩群年代学研究及其地质意义

武关岩体位于北秦岭武关镇,侵入于丹凤岩群之中,为原泥盆系刘岭群北侧解体出来的变质沉积-火山岩系岩体。锆石阴极发光(CL)及LA-ICP-MS同位素测年分析显示,武关岩体中斜长角闪岩锆石U-Pb年龄为(349±10) Ma,该年龄代表岩体的岩浆结晶年龄,即形成年龄。石榴子石黑云斜长片岩中碎屑锆石峰值年龄为850 Ma,最小年龄为324 Ma,反映武关岩群沉积岩的沉积时代应该晚于早古生代。     

赤峰地区中生代火山岩锆石U-Pb年代学证据

赤峰地区中生代火山岩由流纹岩、粗安质熔结凝灰岩、粗安岩组成。通过LA-ICP-MS技术对赤峰地区中生代火山岩进行锆石U-Pb同位素定年研究,该区中生代火山岩中的锆石呈半自形—自形晶,发育振荡环带,Th/U值较高(0.50～2.26),为岩浆成因。满克头鄂博组火山岩2个样品的锆石U-Pb年龄分别为(156±2)Ma(n=24)和(157±3)Ma(n=19),形成于晚侏罗世;玛尼吐组火山岩样品中的锆石U-Pb年龄为(147±2)Ma(n=18),形成时代属于晚侏罗世;白音高老组火山岩2个样品的锆石U-Pb年龄分别为(132±1)Ma(n=23)和(138±3)Ma(n=18),形成时代属于早白垩世。赤峰地区中生代火山岩应形成于太平洋板块向欧亚大陆板块俯冲后的伸展环境中。     

湘南宜章地区辉绿岩、花岗斑岩、安山岩的形成时代和成因——锆石U-Pb年龄和Hf同位素组成

湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf(t)值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。     

湘南宜章地区辉绿岩、花岗斑岩、安山岩的形成时代和成因——锆石U-Pb年龄和Hf同位素组成

湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf（t）值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。     

青海红沟地区哈曼大阪花岗岩体锆石LA-ICP-MS测年——对红沟铜矿床形成时代和成因的认识

哈曼大阪花岗岩体位于北祁连造山带-中祁连造山带接壤地带。结合阴极发光,对哈曼大阪花岗岩体花岗闪长岩中的锆石进行了LA-ICP-MSU-Pb同位素测年。获得单颗粒锆石的微区U-Pb年龄为478.8±1.2Ma。认为哈曼大阪花岗岩体形成时代为早奥陶世。获得的红沟铜矿直接赋矿围岩双峰式火山岩中基性火山岩的LA-ICP-MS锆石U-Pb同位素年龄为443.2±1.2Ma,认为红沟铜多金属矿床形成时代为晚奥陶世。因此,认为哈曼大阪花岗岩体与红沟铜矿没有成因上的联系。这一认识,对进一步深入研究祁连造山带陆缘裂谷环境的Cu多金属矿床的成矿时代及成因具有重要意义。     

西藏措勤惩香错地区林子宗群典中组火山岩锆石U-Pb年龄与岩石地球化学特征

对西藏措勤惩香错地区林子宗群典中组火山岩进行了岩石地球化学和LA-ICP-MS锆石U-Pb定年测试,2件样品（流纹岩、英安岩）LA-ICP-MS锆石U-Pb年龄分别为（65.58±0.33）Ma、（58.83±0.41）Ma,代表了该火山岩的形成年龄,时代为古新世。岩石地球化学特征显示为钙碱性,富集大离子亲石元素Rb、Th、Pb,亏损高场强元素Nb、Ta等,反映了弧火山岩的特征,说明该时期新特提斯洋仍处于俯冲消减阶段。     

西藏措勤惩香错地区林子宗群典中组火山岩锆石U-Pb年龄与岩石地球化学特征

对西藏措勤惩香错地区林子宗群典中组火山岩进行了岩石地球化学和LA-ICP-MS锆石U-Pb定年测试,2件样品（流纹岩、英安岩）LA-ICP-MS锆石U-Pb年龄分别为（65.58±0.33）Ma、（58.83±0.41）Ma,代表了该火山岩的形成年龄,时代为古新世。岩石地球化学特征显示为钙碱性,富集大离子亲石元素Rb、Th、Pb,亏损高场强元素Nb、Ta等,反映了弧火山岩的特征,说明该时期新特提斯洋仍处于俯冲消减阶段。     

西藏措勤惩香错地区林子宗群典中组火山岩锆石U-Pb年龄与岩石地球化学特征

对西藏措勤惩香错地区林子宗群典中组火山岩进行了岩石地球化学和LA-ICP-MS锆石U-Pb定年测试,2件样品（流纹岩、英安岩）LA-ICP-MS锆石U-Pb年龄分别为（65.58±0.33）Ma、（58.83±0.41）Ma,代表了该火山岩的形成年龄,时代为古新世。岩石地球化学特征显示为钙碱性,富集大离子亲石元素Rb、Th、Pb,亏损高场强元素Nb、Ta等,反映了弧火山岩的特征,说明该时期新特提斯洋仍处于俯冲消减阶段。     

西藏措勤惩香错地区林子宗群典中组火山岩锆石U-Pb年龄与岩石地球化学特征

对西藏措勤惩香错地区林子宗群典中组火山岩进行了岩石地球化学和LA-ICP-MS锆石U-Pb定年测试,2件样品（流纹岩、英安岩）LA-ICP-MS锆石U-Pb年龄分别为（65.58±0.33）Ma、（58.83±0.41）Ma,代表了该火山岩的形成年龄,时代为古新世。岩石地球化学特征显示为钙碱性,富集大离子亲石元素Rb、Th、Pb,亏损高场强元素Nb、Ta等,反映了弧火山岩的特征,说明该时期新特提斯洋仍处于俯冲消减阶段。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).