U-Pb Age Determination for Seven Standard Zircons using Inductively Coupled Plasma–Mass Spectrometry Coupled with Frequency Quintupled Nd-YAG (λ = 213 nm) Laser Ablation System: Comparison with LA-ICP-MS Zircon Analyses with a NIST Glass Reference Material

This paper evaluates the analytical precision, accuracy and long‐term reliability of the U‐Pb age data obtained using inductively coupled plasma–mass spectrometry (ICP‐MS) with a frequency quintupled Nd‐YAG (λ = 213nm) laser ablation system. The U‐Pb age data for seven standard zircons of various ages, from 28 Ma to 2400 Ma (FCT, SL13, 91500, AS3, FC1, QGNG and PMA7) were obtained with an ablation pit size of 30 μm diameter. For ²⁰⁷Pb/²⁰⁶Pb ratio measurement, the mean isotopic ratio obtained on National Institute of Standards and Technology (NIST) SRM610 over 4 months was 0.9105 ± 0.0014 (n = 280, 95% confidence), which agrees well with the published value of 0.9096. The time‐profile of Pb/U ratios during single spot ablation showed no significant difference in shape from NIST SRM610 and 91500 zircon standards. These results encouraged the use of the glass standard as a calibration standard for the Pb/U ratio determination for zircons with shorter wavelength (λ = 213 nm) laser ablation. But ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²³⁵U ages obtained by this method for seven zircon standards are systematically younger than the published U‐Pb ages obtained by both isotope dilution–thermal ionization mass spectrometry (ID‐TIMS) and sensitive high‐resolution ion‐microprobe (SHRIMP). Greater discrepancies (3–4% younger ages) were found for the ²⁰⁶Pb/²³⁸U ages for SL13, AS3 and 91500 zircons. The origin of the differences could be heterogeneity in Pb/U ratio on SRM610 between the different disks, but a matrix effect accuracy either in the ICP ion source or in the ablation‐transport processes of the sample aerosols cannot be neglected. When the ²⁰⁶Pb/²³⁸U (= 0.2302) newly defined in the present study is used, the measured ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²³⁵U ages for the seven zircon standards are in good agreement with those from ID‐TIMS and SHRIMP within ±2%. This suggests that SRM610 glass standard is suitable for ICP‐MS with laser ablation sampling (LA‐ICP‐MS) zircon analysis, but it is necessary to determine the correction factor for ²⁰⁶Pb/²³⁸U by measuring several zircon standards in individual laboratories.     

The contribution of the sensitive high-resolution ion microprobe (SHRIMP) to lunar geochronology

The sensitive high-resolution ion microprobe (SHRIMP) developed at the Australian National University (ANU) was the first of the high-resolution ion microprobes. The impact of this instrument on geochronological research over the last twenty years has been immense. This is particularly so for lunar geochronology where it has opened up avenues of research that were not possible using conventional TIMS techniques. The great advantage of SHRIMP is that it provides a means for determining precise U–Pb isotopic ratios on selected micron-size areas on polished grains of zircon and other U-bearing minerals. One of the first projects undertaken on the newly invented SHRIMP I was an investigation of U–Pb ages of lunar zircon. Using SHRIMP, multiple analyses could be made on areas of individual zircons to test the stability of U–Pb systems in shocked grains. Also, by analysing grains “in situ”, textural relationships between the analysed zircon and the components of the sample breccia could be used in the interpretation of the SHRIMP data. As a result of this research it was realised that most lunar zircons have ages up to 500 Ma older than the Imbrium and Serenitatis impacts at ca. 3.9 Ga, demonstrating that the zircons have not been affected by the these impact events although heating and shock effects have profoundly disturbed other dating systems. This has opened the way for research into the early lunar magmatic and bombardment record. For example, recent SHRIMP results have revealed profound differences in the ages of zircons from breccias from the Apollo 14 and Apollo 17 sample sites, raising new questions about the evolution of lunar magmatism. Also, multiple SHRIMP analyses on complex lunar zircons have shown that these grains can record U–Pb disturbance by later impact events. SHRIMP U–Pb age determinations on phosphates in lunar meteorites has identified lunar events not recognised in samples from the Apollo program. SHRIMP-based research on lunar materials is ongoing and, in combination with other chemical and structural evidence, continues to stimulate new ideas on the early evolution of the Moon.     

Monazite trumps zircon: applying SHRIMP U–Pb geochronology to systematically evaluate emplacement ages of leucocratic,low-temperature granites in a complex Precambrian orogen

Although zircon is the most widely used geochronometer to determine the crystallisation ages of granites, it can be unreliable for low-temperature melts because they may not crystallise new zircon. For leucocratic granites U–Pb zircon dates, therefore, may reflect the ages of the source rocks rather than the igneous crystallisation age. In the Proterozoic Capricorn Orogen of Western Australia, leucocratic granites are associated with several pulses of intracontinental magmatism spanning ~800 million years. In several instances, SHRIMP U–Pb zircon dating of these leucocratic granites either yielded ages that were inconclusive (e.g., multiple concordant ages) or incompatible with other geochronological data. To overcome this we used SHRIMP U–Th–Pb monazite geochronology to obtain igneous crystallisation ages that are consistent with the geological and geochronological framework of the orogen. The U–Th–Pb monazite geochronology has resolved the time interval over which two granitic supersuites were emplaced; a Paleoproterozoic supersuite thought to span ~80 million years was emplaced in less than half that time (1688–1659 Ma) and a small Meso- to Neoproterozoic supersuite considered to have been intruded over ~70 million years was instead assembled over ~130 million years and outlasted associated regional metamorphism by ~100 million years. Both findings have consequences for the duration of associated orogenic events and any estimates for magma generation rates. The monazite geochronology has contributed to a more reliable tectonic history for a complex, long-lived orogen. Our results emphasise the benefit of monazite as a geochronometer for leucocratic granites derived by low-temperature crustal melting and are relevant to other orogens worldwide.     

U‐Pb Detrital Zircon Analysis – Results of an Inter‐laboratory Comparison

Inter‐laboratory comparison of laser ablation ICP‐MS and SIMS U‐Pb dating of synthetic detrital zircon samples provides an insight into the state‐of‐the art of sedimentary provenance studies. Here, we report results obtained from ten laboratories that routinely perform this type of work. The achieved level of bias was mostly within ± 2% relative to the ID‐TIMS U‐Pb ages of zircons in the detrital sample, and the variation is likely to be attributed to variable Pb/U elemental fractionation due to zircon matrix differences between the samples and the reference materials used for standardisation. It has been determined that ~ 5% age difference between adjacent age peaks is currently at the limit of what can be routinely resolved by the in situ dating of detrital zircon samples. Precision of individual zircon age determination mostly reflects the data reduction and procedures of measurement uncertainty propagation, and it is largely independent of the instrumentation, analytical technique and reference samples used for standardisation. All laboratories showed a bias towards selection of larger zircon grains for analysis. The experiment confirms the previously published estimates of the minimum number of grains that have to be analysed in order to detect minor zircon age populations in detrital samples.     

Accuracy of Laser Ablation U-Pb Zircon Dating: Results from a Test Using Five Different Reference Zircons

Using a state‐of‐the‐art 193 nm‐LA‐MC‐ICP‐MS system and with careful control of analytical procedures, the long term external reproducibility and accuracy of the ages Phanerozoic zircons measured over a period of months using calibrator bracketing for the ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²⁰⁶Pb ages were ca. 1% (2 RSD) if a single reference zircon was used for the matrix‐matched calibration. When different reference zircons were used for the calibration, suspicious systematic shifts in the obtained ages were observed and thus a reduction in the overall accuracy of the dating method became obvious. Such shifts were within a few percent range of the U‐Pb and Pb/Pb ages and seemed to vary independently of zircon age and composition. A “test of accuracy” experiment was conducted reducing instrumental effects as far as possible by analysing five different reference zircons mounted on a single mount eight times during the same session. An identical protocol was used for all analyses, with unchanged instrument parameters and with ion beam intensities kept as identical as possible. For data reduction, every zircon served consecutively as the reference zircon for calibration, with the others in the batch treated as unknowns. The known reference age and the four calculated ages obtained using the four other RMs for calibration were then compared. Even using such a strict analytical protocol, shifts in ²⁰⁶Pb/²³⁸U, ²⁰⁷Pb/²³⁵U and ²⁰⁷Pb/²⁰⁶Pb ratios were still present. They varied non‐systematically and ranged from ?4.35% to 3.08% for the investigated age range (1065 Ma to 226 Ma). Assuming the absence of instrumental effects (i.e., memory, dead‐time correction, non‐linearity of ion counters and interdetector calibration, crystallographic orientation, ablation cell geometry and setup, gas flows), the observed shifts were attributed to matrix and/or ablation related effects. It is proposed that non‐spectral matrix effects in the Ar plasma torch resulted in non‐uniform signal enhancement (or depression?) leading to shifts both in elemental and Pb isotopic ratios. Additionally, the ablated particle size distribution could be an important factor controlling plasma conditions and thus mass bias and fractionation. Until such effects are well understood and controlled, it would seem that any LA‐ICP‐MS zircon U‐Pb and ²⁰⁷Pb/²⁰⁶Pb age determination cannot be meaningfully interpreted at below a ca. 3% to 4% (2 RSD) confidence level.     

Ages of internal granitoids in the Southern Cross region,Yilgarn Craton,Western Australia,and their crustal evolution and tectonic implications

Southern Cross, where gold deposits are sited in narrow greenstone belts surrounding granitoid domes, was one of the earliest gold mining centres in Western Australia. SHRIMP U–Pb zircon and Pb‐isotope studies of the largest granitoid dome, the Ghooli Dome (80 × 40 km), provide important constraints on the crustal evolution and structural history of the central part of the Archaean Yilgarn Craton, Western Australia, which includes Southern Cross. The north‐northwest‐south‐southeast‐oriented ovoid Ghooli Dome has a broadly concentric foliation that is subhorizontal or gently dipping in its central parts and subvertical along its margins. Foliated granitoids in the dome are dated at ca 2724 ± 5 and 2688 ± 3 Ma using the SHRIMP U–Pb zircon and Pb–Pb isochron methods, respectively. These new data, together with the published SHRIMP U–Pb zircon age of 2691 ± 7 Ma at another locality, 20 km from the centre of the Koolyanobbing Shear Zone, suggest that the Ghooli Dome was emplaced at ca 2.72–2.69 Ga. Because the Ghooli Dome and the other domes, which are enveloped by narrow greenstone belts, are cut by the >650 km‐long and 6–15 km‐wide Koolyanobbing Shear Zone, the ca 2.69 Ga age is interpreted as the maximum age of the last major movement on this structure. The pre‐2.69 Ga history, if any, of the shear zone remains unknown. The shear zone is intruded by an undeformed porphyritic granitoid which has a SHRIMP U–Pb zircon age of 2656 ± 4 Ma. This age is, thus, the minimum age of major movement along this shear zone. Post‐gold mineralisation pegmatitic‐leucogranite from the Nevoria gold mine has a SHRIMP U–Pb zircon age of 2634 ± 4 Ma, with xenocrystic zircon cores of ca 2893 ± 6 Ma, constraining the minimum age of gold mineralisation there to ca 2.63 Ga. The ca 2.72–2.69 Ga granitoids also contain ca 2.98 and 2.78 Ga xenocrystic zircon cores, suggesting an extensive crustal prehistory for their source. Whereas there is a general temporal relationship between the periods of older (ca 3.0 Ga) and younger (ca 2.80 and 2.73 Ga) volcanism and the older (2.98, 2.78 and 2.72–2.69 Ga) granitoid intrusions, there is no known volcanism temporally associated with the 2.65–2.63 Ga granitoid intrusions in the Yilgarn Craton. Other heat sources and/or tectonic processes, required for the generation of these intrusions, are interpreted to be related to a lithospheric delamination event related to continental collision.     

SHRIMP zircon U–Pb age and tectonic significance of the Palaeoproterozoic Boolaloo Granodiorite in the Ashburton Province,Western Australia

The age of the Ashburton Province, comprising an older divergent‐margin megasequence and a younger convergent‐margin megasequence, is poorly constrained. The Boolaloo Granodiorite, which intruded the divergent‐margin megasequence on the western margin of the Ashburton Province, has given a SHRIMP zircon U–Pb age of 1786 ± 5 Ma, and therefore post‐dates convergent‐margin, backarc basin sequences, with established conventional zircon U7sbnd;Pb ages of ca 1843–1828 Ma. However, it pre‐dated deformation of convergent‐margin, remnant‐ocean sequences. Similarly aged (ca 1797–1791 Ma) granitoids are present in the adjacent Gascoyne Province, thereby identifying a magmatic fold‐thrust belt that abutted a remnant ocean in the Ashburton Province.     

Sm–Nd and U–Pb dating of high-pressure granulites from the Złote and Rychleby Mts (Bohemian Massif, Poland and Czech Republic)

In the Orlica‐?nie?nik complex at the NE margin of the Bohemian Massif, high‐pressure granulites occur as isolated lenses within partially migmatized orthogneisses. Sm–Nd (different grain‐size fractions of garnet, clinopyroxene and/or whole rock) and U–Pb [isotope dilution‐thermal ionization mass spectrometry (ID‐TIMS) single grain and sensitive high‐resolution ion microprobe (SHRIMP)] ages for granulites, collected in the surroundings of ?ervený D?l (Czech Republic) and at Stary Giera?tów (Poland), constrain the temporal evolution of these rocks during the Variscan orogeny. Most of the new ages cluster at c. 350–340 Ma and are consistent with results previously reported for similar occurrences throughout the Bohemian Massif. This interval is generally interpreted to constrain the time of high‐pressure metamorphism. A more complex evolution is recorded for a mafic granulite from Stary Giera?tów and concerns the unknown duration of metamorphism (single, short‐lived metamorphic cycle or different episodes that are significantly separated in time?). The central grain parts of zircon from this sample yielded a large spread in apparent ²⁰⁶Pb/²³⁸U SHRIMP ages (c. 462–322 Ma) with a distinct cluster at c. 365 Ma. This spread is interpreted to be indicative for variable Pb‐loss that affected magmatic protolith zircon during high‐grade metamorphism. The initiating mechanism and the time of Pb‐loss has yet to be resolved. A connection to high‐pressure metamorphism at c. 350–340 Ma is a reasonable explanation, but this relationship is far from straightforward. An alternative interpretation suggests that resetting is related to a high‐temperature event (not necessarily in the granulite facies and/or at high pressures) around 370–360 Ma, that has previously gone unnoticed. This study indicates that caution is warranted in interpreting U–Pb zircon data of HT rocks, because isotopic rejuvenation may lead to erroneous conclusions.     

北祁连西段熬油沟辉长岩的锆石SHRIMP U-Pb年龄及地质意义

从北祁连熬油沟辉长岩中选出的锆石的外部形态、内部结构单一。SHRIMP测年共测定8个点,每个点的Th/U值都非常高,大都在0.8以上。8个点的206Pb/238U表面年龄在误差范围内完全一致,加权平均值为503.7Ma±6.4Ma,这一结果与前人在同一地点采集的辉绿岩墙样品的锆石SHRIMP U-Pb测年结果有较大的差异。结合研究区内已有的研究成果认为:①熬油沟地区的辉长辉绿岩形成于早古生代,并不是中元古代早期。②辉长岩中的锆石成因单一,其测试年龄结果的地质意义明确;而同源岩浆侵入体的辉绿岩往往容易从围岩中捕获大量锆石,使得锆石成因复杂,年龄测试结果复杂。因此,与辉绿岩相比,辉长岩锆石SHRIMP U-Pb年代学研究可以获得更为可靠的、地质意义明确的年龄信息。     

Early Neoarchean Magmatic and Paleoproterozoic Metamorphic Events in the Northern North China Craton: SHRIMP Zircon Dating and Hf Isotopes of Archean Rocks from the Miyun Area, Beijing

The Miyun area of Beijing is located in the northern part of the North China Craton(NCC)and includes a variety of Archean granitoids and metamorphic rocks.Magmatic domains in zircon from a tonalite reveal Early Neoarchean(2752±7 Ma) ages show a small range in ε_(Hf)(t) from 3.1 to 7.4and t_(DM1)(Hf) from 2742 to 2823 Ma,similar to their U-Pb ages,indicating derivation from a depleted mantle source only a short time prior to crystallization.SHRIMP zircon ages of granite,gneiss,amphibolite and hornblendite in the Miyun area reveal restricted emplacement ages from 2594 to2496 Ma.They also record metamorphic events at ca.2.50 Ga,2.44 Ga and 1.82 Ga,showing a similar evolutionary history to the widely distributed Late Neoarchean rocks in the NCC.Positive ε_(Hf)(t) values of 1.5 to 5.9,with model ages younger than 3.0 Ga for magmatic zircon domains from these Late Neoarchean intrusive rocks indicate that they are predominantly derived from juvenile crustal sources and suggest that significant crustal growth occurred in the northern NCC during the Neoarchean.Late Paleoproterozoic metamorphism developed widely in the NCC,not only in the Trans-North China Orogen,but also in areas of Eastern and Western Blocks,which suggest that the late Paleoproterozoic was the assembly of different micro-continents,which resulted in the final consolidation to form the NCC,and related to the development of the Paleo-Mesoproterozoic Columbia or Nuna supercontinent.     

Qingbaikouan and Crygenian in South China: Constraints by SHRIMP Zircon U-Pb dating

The Qingbaikouan System is the lowest unit of the Neoproterozoic Erathem in Chinese stratigraphic succession,and it now provides a precise geochronological framework and geological time scale for mapping and stratal correlation in China.However,a sensitive high-resolution ion microprobe （SHRIMP） U-Pb zircon age date （1368±12 Ma） obtained from a bentonite in the Qingbaikouan Xiamaling Formation indicates that it belongs to the Mesoproterozoic Erathem instead.This change is a milestone in understanding the Precambrian Stratigraphic Time Scale in China,and it has had great influence on Precambrian correlations in Asia.Otherwise,a large amount of geochronological work has been done in the ＂Jiangnan Orogen Belt＂ of South China,and new isotopic data have redefined the traditional recognition of metamorphosed Mesoproterozoic strata from the Sibao orogeny to the Neoproterozoic Erathem.Based on SHRIMP zircon U-Pb age data,the authors regard the Sibao orogeny （equal to the Wuling orogeny） as a movement at ca 820 Ma,meaning that the Sibao orogeny was not equivalent to the Grenvillian orogeny.Finally,we report here the first SHRIMP U-Pb age of the boundary between the top of the Qingbaikouan Gongdong Formation （786.8±5.6 Ma） and the bottom of the Chang＇an （diamictite） Formation （778.4±5.2 Ma）,which is the age of the lowest diamictite of the Nanhuan System in China.     

Ages and Sources of Ore‐Related Porphyries at Yongping Cu–Mo Deposit in Jiangxi Province,Southeast China

Whole‐rock geochemistry, zircon U–Pb and molybdenite Re–Os geochronology, and Sr–Nd–Hf isotopes analyses were performed on ore‐related dacite porphyry and quartz porphyry at the Yongping Cu–Mo deposit in Southeast China. The geochemical results show that these porphyry stocks have similar REE patterns, and primitive mantle‐normalized spectra show LILE‐enrichment (Ba, Rb, K) and HFSE (Th, Nb, Ta, Ti) depletion. The zircon SHRIMP U–Pb geochronologic results show that the ore‐related porphyries were emplaced at 162–156 Ma. Hydrothermal muscovite of the quartz porphyry yields a plateau age of 162.1 ± 1.4 Ma (2σ). Two hydrothermal biotite samples of the dacite porphyry show plateau ages of 164 ± 1.3 and 163.8 ± 1.3 Ma. Two molybdenite samples from quartz+molybdenite veins contained in the quartz porphyry yield Re–Os ages of 156.7 ± 2.8 Ma and 155.7 ± 3.6 Ma. The ages of molybdenite coeval to zircon and biotite and muscovite ages of the porphyries within the errors suggest that the Mo mineralization was genetically related to the magmatic emplacement. The whole rocks Nd–Sr isotopic data obtained from both the dacite and quartz porphyries suggest partial melting of the Meso‐Proterozoic crust in contribution to the magma process. The zircon Hf isotopic data also indicate the crustal component is the dominated during the magma generation.     

鲁东地区侵入岩形成时代和期次划分——锆石SHRIMPU—Pb年龄的证据

鲁东地区前寒武纪侵入岩其侵入活动集中于新太古代和新元古代,均遭受不同程度的区域变质和韧性剪切带的改造,形成一套花岗质片麻岩类。新太古代早期TTG质花岗岩分布于胶北隆起区莱州一栖霞一带,经受了区域变质作用,形成一套灰色片麻岩,锆石内核SHRIMPU—Pb年龄2726—2707Ma基本代表岩浆结晶年龄,锆石变质边为2500Ma;古元古代侵入岩——莱州基性一超基性岩组合形成于1900～1850Ma左右,锆石SHRIMPU—Pb年龄（1852±9）Ma,（1868±11）Ma;新元古代侵入岩主要为花岗闪长质-二长花岗质片麻岩,出露于胶南-威海造山带,锆石U～Pb定年结果集中为892～605Ma,其中荣成超单元锆石SHRIMPU—Pb年龄720～780Ma。中生代侵入岩以花岗岩类为主,集中出露于半岛北部和东南沿海一带。燕山早期侵入岩文登超单元、垛崮山超单元、玲珑超单元锆石SHRIMPU—Pb同位素年龄值集中在167～150Ma;燕山晚期侵入岩大店超单元锆石SHRIMPU～Pb年龄120±4Ma,崂山超单元锆石SHRIMPU～Pb同位素年龄值为（120±2）～（114±2）Ma。     

Testing inferences from palaeocurrents: application of zircon double‐dating to Miocene sediments from the Hengchun Peninsula,Taiwan

Detrital zircon provenance studies that combine low‐temperature fission‐track and high‐temperature U–Pb single‐grain age dating are powerful in constraining sediment provenance by documenting the tectonothermal evolution of the sediment source(s). We apply these techniques to Miocene (12–6 Ma) sandstones of the Hengchun Peninsula, southern Taiwan, which, based on diametrically opposite palaeocurrents, have a controversial provenance. U–Pb grain ages range from the Miocene (8 Ma) to Archaean (2.5 Ga). Cretaceous thermal cooling is recorded by detrital zircon fission tracks at Loshui and Lilongshan. Permian fission‐track grain ages account for <33% of zircon ages from Loshui, while at Lilongshan, Jurassic/Triassic grain ages account for 33–66% of all zircon fission‐track ages. Minor (<12%) Miocene age components are detected in both formations. These new data suggest that the primary sources of these Miocene sediments were similar. A simple model is proposed invoking sediment reworking in this complex tectonic setting. Terra Nova, 00, 000–000, 2010     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

鲁西铜石岩体的锆石SHRIMP U-Pb年龄及其地质意义

首次报道了鲁西地区铜石岩体的锆石SHRIMPU Pb年龄结果。通过对斑状细粒闪长岩中单颗粒锆石 1 8个样品点的分析 ,获得了两组谐和年龄数据 ,其中有 1 0个分析点的2 0 6Pb/ 2 3 8U年龄为 1 6 7.9～ 1 83Ma ,加权平均值为 (1 75 .7± 3.8)Ma ;另外 8个分析点的2 0 7Pb/ 2 0 6Pb年龄为 2 5 0 2～ 2 5 5 4Ma ,加权平均值为 (2 5 1 8± 1 1 )Ma。二长斑岩样品仅获得 2个2 0 7Pb/ 2 0 6Pb年龄数据 ,在 2 4 85～ 2 5 1 2Ma之间。(1 75 .7± 3.8)Ma指示了铜石岩体的结晶年龄为中侏罗世 ,(2 5 1 8± 1 1 )Ma代表了岩体侵位过程中捕获的新太古代五台期锆石的年龄。根据SHRIMPU Pb年龄结果 ,认为鲁西地区存在燕山早期构造岩浆热事件 ,与之有关的归来庄金矿也在此时期形成     

The Use of Multiple Reference Samples for the Monitoring of Ion Microprobe Performance During Zircon 207Pb/206Pb Age Determinations

Data from a series of extended analytical sessions using a range of different zircon reference samples have been used to investigate the periodic derivation of abnormal ²⁰⁷Pb/²⁰⁶Pb ages during microbeam analysis%For the Canberra SHRIMP II, this phenomenon probably results from the presence of a signal at mass 204 that is alien to the Pb spectrum; isotopic fractionation is unlikely to be a significant contributor. In contrast, abnormal ²⁰⁷Pb/²⁰⁶Pb ages obtained from SHRIMP I at the same research centre require a different, but as yet unknown explanation. Assessment of the reasons for atypical ^207Pb/²⁰⁶Pb measurements and the means of correcting for them should therefore be independently assessed for individual analytical instruments. The use of reference samples with very different ages is an effective way of doing this, because older reference samples are more useful for documenting isotopic fractionation, whereas younger ones are more sensitive indicators of isobaric interference.     

Late Jurassic–Early Cretaceous Plutonism in the Northern Part of the Precambrian North China Craton: SHRIMP Zircon U–Pb Dating of Diorites and Granites from the Yunmengshan Geopark, Beijing

The Yunmengshan Geopark in northern Beijing is located within the Yanshan range. It contains the Yunmengshan batholith, which is dominated by two plutons: the Yunmengshan gneissic granite and the Shicheng gneissic diorite. Four samples of the Yunmengshan gneissic granite give SHRIMP zircon U–Pb ages from 145 to 141 Ma, whereas four samples of the Shicheng gneissic diorite have ages from 159 Ma to 151 Ma. Dikes that cut the Yunmengshan diorite record SHRIMP zircon U–Pb age of 162±2 and 156±4 Ma. The cumulative plots of zircons from the diorites show a peak age of 155 Ma, without inherited zircon cores, and the peak age of 142 Ma for granite is interpreted as the emplacement age of the Yunmengshan granitic pluton, whose igneous zircons contain inherited zircon cores. The data presented here show that there were two pulses of magmatism: early diorites, followed c13 Ma later by true granites, which incorporated material from an older continental crust.     

SHRIMP Dating and Recrystallization of Metamorphic Zircons from a Granitic Gneiss in the Sulu UHP Terrane

An unusual zircon SHRIMP dating result of a granitic gneiss from the Qinglongshan eclogite-gneiss roadcut section is presented in this paper. The very peculiar and complicated internal structures, as well as the very low Th/U ratios (0.01-0.08) of the zircons indicate that they were formed by metamorphic recrystallization. Strongly in contrast with previously published zircon U-Pb ages of the Dabie-Sulu UHP metamorphic rocks where protolith ages of 600-800 Ma are commonly recorded, only metamorphic age of 218±5 Ma, defined by 18 analytical spots either in rim or in core of zircons, are recorded in this granitic gneiss. This age represents the time of the complete metamorphic recrystallization overprint on primary magmatic zircons. The recrystallization was derived by the UHP metamorphism, and was strengthened by the early stage of retrograde metamorphic fluid activity.     

A U‐Pb zircon study of the Mesoproterozoic Charleston Granite,Gawler Craton,South Australia

The Charleston Granite from the Gawler Craton, South Australia, has been dated by the ion‐microprobe U‐Pb zircon method at 1585 ± 5 Ma (2σ). This confirms previous interpretations of population‐style U‐Pb zircon analyses which record a slightly older age due to the presence of inherited zircon. Inherited cores are present in many zircon crystals, and while the age of some cores can not be accurately determined due to extreme loss of radiogenic Pb, others have ages of ～ 1780, ～ 1970, and > 3150 Ma. These cores record a diverse crustal heritage for the Charleston Granite and indicate that ancient crustal material (> 3150 Ma) is present at depth in the Gawler Craton. This is also suggested by available Nd isotopic data for both the Charleston Granite and other Gawler Craton Archaean rocks. The Rb‐Sr and K‐Ar biotite ages from the Charleston Granite of 1560 to 1570 Ma are close to the U‐Pb zircon crystallization age and suggest that the granite has not experienced sustained thermal disturbance (> 250° C) since emplacement and cooling. However, a much younger Rb‐Sr total‐rock age of 1443 ± 26 Ma probably reflects low‐temperature disturbance to the Sr isotope system in feldspar.