Human actions were responsible for both initiation and termination of varve preservation in Lake Vesijärvi,southern Finland

Journal of Paleolimnology - The influence of lake restoration efforts on lake bottom-water conditions and varve preservation is not well known. We studied varved sediments deposited during the last...     

Mining pollution triggered a regime shift in the cladoceran community of Lake Kirkkojärvi,southern Finland

Mining is one of the key industries in the world and mine water pollution is a serious threat to aquatic ecosystems. Historical monitoring data on the pollution history and impacts in aquatic ecosystems, however, are rarely available, so paleolimnological methods are required to explore the consequences of past pollution. We studied the history of cladoceran community dynamics in Lake Kirkkojärvi, southern Finland, including the periods before, during and after mining. We analyzed the geochemical composition and cladoceran subfossil remains in a ²¹⁰Pb-dated sediment core to evaluate the magnitude, rate, and direction of cladoceran community changes through time. The cladoceran community was altered significantly by mining activity that occurred during the mid-twentieth century. During more recent times, however, eutrophication effects have overridden the impacts of mining. After mining ceased, the cladoceran community underwent an abrupt regime shift towards taxa that reflect more eutrophic conditions. This change was caused by intensive farming activity and fertilizer use over the past few decades. The recent history of Lake Kirkkojärvi is a textbook example of a regime shift triggered by multiple human-caused stressors. Our findings also highlight the utility of cladocerans as bio-indicators in pollution research and illustrate the sensitivity of aquatic ecosystems to anthropogenic modification.     

Holocene records of carbon and hydrogen isotope ratios of organic matter in annually laminated sediments of Lake Korttajärvi, central Finland

An 11.6 m long continuous succession of annually laminated sediments from Lake Korttajärvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake Päijänne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ¹³C and another HCl-HF-digested organic fraction was analyzed for both δ¹³C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttajärvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ¹³C_HCl-HF values of organic matter from ?31.6 to $-29.2\permilleAn 11.6 m long continuous succession of annually laminated sediments from Lake Korttaj?rvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake P?ij?nne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ¹³C and another HCl-HF-digested organic fraction was analyzed for both δ¹³C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttaj?rvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ¹³C_HCl-HF values of organic matter from −31.6 to , followed by a subtle decrease to . The changes in pH and δ¹³C_HCl-HF are closely related (r = − 0.91, P < 0.01), and apparently reflect changing environmental conditions in the lake and in its catchment area. δD values show a marked shift to higher values during the early Holocene, which may be partly related to a climatic amelioration leading to the Holocene Climatic Optimum in 6000–2500 BC. The Medieval Warm Period in AD 980–1250 is associated with a local maximum in δD, lending support for a significant warming during that time.     

Paleolimnological assessment of ecological integrity and eutrophication history for Lake Tiiläänjärvi (Askola,Finland)

In this study, we aim to reconstruct long-term limnoecological development of the clay-turbid Lake Tiiläänjärvi in Askola, southern Finland, using fossil Chironomidae assemblages. The study lake suffers from hypereutrophic conditions and late-winter and end-of-summer anoxia. The retrieved sediment record revealed a succession from oligo-mesotrophic (~AD 1940–2000) to eutrophic community (~AD 2000–2010) that finally reached hypereutrophic climax community in the most recent sediments. The initial state of the record was characterized by stable ecological conditions, but the biological integrity (community and functional diversity) was completely lost in the upper part of the sediment profile. The number of taxa markedly decreased following the nutrient enrichment and only one taxon (Chironomus plumosus-type), tolerant of temporary anoxia, remained in the surface sample. During the period of available observational data (since AD 1978), variance in midge community composition was mostly explained by limnological factors, namely total phosphorus (TP), whereas the influence of climate was statistically insignificant, thus enabling quantitative midge-based reconstruction of autumnal epilimnetic TP. The midge-based reconstruction showed an identical trend compared to sediment characteristics, which correspond to increased lake productivity and anthropogenic activities in the catchment. The inferred values for the initial state indicated mesotrophic conditions, which are typical for non-disturbed clay-turbid lakes in southern Finland, and a subsequent increase to eutrophic conditions, with hypereutrophic state reached at the top of the core. This development corresponds with the instrumentally monitored development. In addition, when the reconstruction was compared with the instrumental values, the inferences were mostly (75 % of the samples) within the error estimates of the model. The present results provide invaluable information on the limnoecological development of Lake Tiiläänjärvi, and more generally, support the theory that fossil remains of chironomids provide a useful tool for assessments of eutrophication history and biological integrity.     

Environmental history of an urban lake: a palaeolimnological study of Lake Jyväsjärvi, Finland

Sedimentary diatom frustules and chironomid remains, in addition to the chemical stratigraphy of 32 elements and organic pollutants such as resin acids, PCB, DDT and its metabolites, were studied from core samples taken from Lake Jyväsjärvi in Central Finland (64° 14 N, 25° 47 E). The sediment profile covered over 200 years, with the oldest samples representing a period of very low human interference. The town of Jyväskylä was established on the lake shore in 1837, and the lake received untreated municipal wastewater from the town up until, 1977. A paper mill started operations in 1872 and began discharging effluent into Lake Jyväsjärvi. In recent years this effluent loading has been reduced. Based on the biological and chemical properties of the sediment strata, five developmental phases were distinguished and named as follows: (1) a pre-industrial phase (approximately up until the 1860s); (2) a phase of early changes in the lake ecosystem (from the 1870s to ca. 1940s); (3) a phase of increasing eutrophication (from ca. 1950 to ca. 1965); (4) a phase of severe pollution (from ca. 1966 to the early-1990s); and (5) a phase of recovery, which proceeded more quickly during the late-1990s following long-term hypolimnetic aeration. It was estimated that the ecological status of the lake changed from good to moderate during the second phase. Due to the poor chemical status of the lake (including increased concentrations of harmful substances) and the pronounced changes in diatom and chironomid communities, the ecological status from 1950 to the early-1990s was classified as bad. The present ecological status, after a slow recovery of about 20 years, can be classified as moderate/poor. Chemical analysis of the sediment revealed that some elements (C, N, P, S, Ba, Cd, Cu, Fe, Pb, Ni and Zn) followed the known history of municipal waste water discharge into the lake, but Hg, Cr and persistent organic pollutants had different stratigraphies, and therefore mainly originated from other sources. Pronounced changes in profundal benthic communities (chironomids) started about 80 years later than those in diatoms, but later changes in chironomid assemblages were greater than those in diatoms.     

The effect of Holocene treeline fluctuations on the sediment chemistry of Lake Kilpisjärvi, Finland

The sediments of Lake Kilpisjärvi were described and analysed for element chemistry and pollen to study the effects of treeline fluctuations in the catchment. Lake Kilpisjärvi is one of the largest lakes in Finnish Lapland, with its catchment partly above the treeline and partly covered with mountain birch woodland. Although the presence of subfossil pine shows that the catchment was previously covered with mountain birch woodland during the Holocene, the present pine treeline has receded 70 km from the lake. Pollen analysis results show that pine immigrated to the area during the Atlantic chrone and that 7000 BP pine forests occupied much of the catchment. Pine started to decline around 3500 BP and vegetation in the catchment became more open. Alkaline and alkaline earth metals and some transition metals document the change from glaciolacustrine clay to more organic sediment. However, these geochemical trends give no indication of changes in erosion rate resulting from changes in catchment vegetation. These changes were detected by plotting suitable element ratios. In addition to the conventional Si/Al and Na/K ratios, the Ca _labile /Si ratio and especially the ratio of labile Ca to K were found to be useful. Of all the elements analysed, potassium showed the strongest reaction to changes in the balance between weathering and erosion. During the phase of denser forests, chemical weathering was dominant, whereas during phases of open catchment, physical erosion prevailed. The effects of changing climate and catchment vegetation were distinguished from other signals. For instance, iron and manganese were enriched at the top of the core due to diffusion and, at the same time, old precipitate layers persisted after burial to deeper levels in the sediment. These iron and manganese rich layers had an effect on the distributions of cobalt, zinc, and vanadium, showing increased concentrations of these elements. Other effects that made the interpretation of chemical records difficult were the effect of ongoing mineralization of organic matter in the top layers of sediment and the effect of biogenic silicon. Owing to the stable conditions of the lake, the desired chemical signals were detected, despite the masking trends.     

Comparative varve counting and magnetic properties of the 8400-yr sequence of an annually laminated sediment in Lake Valkiajärvi, Central Finland

Two varve counts made nearly 20 yrs apart and by different authors in the small and well sheltered meromictic lake of Valkiajärvi were compared with a view to establishing how similar, or otherwise, these two independent varve chronologies might be. The results were significant, the difference between the two varve counts being less than 2% for most of the sediment length, even though the average varve thickness was only 0.3 mm. The continuous and essentially uniform varve record - so far the longest in Finland - covers 8400 yrs and could be applied for accurate dating of palaeoenvironmental indicators in the sediment. As an example, we present a varve-dated pollen diagram for Lake Valkiajärvi.In addition, some magnetic parameters (susceptibility, ARM, SIRM) were measured on the sediment sequence to support the stratigraphic division and correlation of the cores, and to outline the development of the basin since the last deglaciation. Magnetic variables reflected mainly the variation in minerogenic material in the sediment, and were therefore related to changes in the catchment. The magnetic parameters also showed a drastic change some 6000 yrs ago, the reason for which, unfortunately, is still not fully understood.     

Trace metal and geochemical variability during 5,500 years in the sediment of Lake Lehmilampi,Finland

A high-resolution geochemical profile from a 5,500-year-old sediment core of Lake Lehmilampi in eastern Finland was analyzed to study long-term trends and variability in element concentrations and accumulation rates. The accumulation rates of all studied elements followed the same trend, responding to changes in the total sedimentation rate. Concentration profiles differed among elements and showed considerable variation over time. Principal components analysis (PCA) was used on the concentration data to identify groups of elements that have similar geochemical controls. The first principal component was influenced by changes in mineral matter accumulation, and it incorporated elements that are associated with stable allochthonous minerals (such as Mg, K, Cs, Rb, Li, Ti and Ga), as well as elements in forms that become diluted when mineral matter increases (e.g., S, Fe and Mn). The second and third principal components showed that a large proportion of the variance was accounted for by elements with continuously increasing or decreasing concentrations related to pedogenetical development of the catchment soil. In the case of Hg, Pb and Cd, however, accumulation rates increased faster at the surface than is simply accounted for by changes in total sedimentation rates. For Cu, Cr, Ni and Zn, concentrations increased over the past 150 years, but there were no indications of a significant addition due to atmospheric deposition. These elements had more variable concentrations before the mid nineteenth century than after, as did elements that are often used for normalization. These findings suggest that lake sediments may not properly reflect the history of atmospheric metal deposition in remote areas.     

Recent diatom assemblage changes in subarctic Lake Saanajärvi, NW Finnish Lapland, and their paleoenvironmental implications

Diatoms were analysed from a 30-cm long sediment core obtained from remote subarctic Lake Saanaärvi (69°03N, 20°52E) in order to trace possible changes in the lake. Diatom assemblages were relatively constant throughout the core, except in the top 4–5 cm (approx 1850 A.D.) where relative frequencies of Aulacoseira italica subsp. subarctica, A. lirata var. biseriata, Cyclotella comensis and C. glomerata increased markedly. No significant trends were observed in the weighted averaging (WA) reconstructed pH values. Several hypotheses, including (i) airborne pollution, (ii) climatic change, and (iii) catchment disturbances have been put forth to explain the recent changes in diatom assemblages. The diatom change coincides with a marked increase in mean annual temperature that has been documented in the area since the termination of the Little Ice Age. Our evidence favours climate change as the main causative mechanism for the observed diatom compositional changes, although other explanations cannot be ruled out.     

Pollution history from 256 BC to AD 2005 inferred from the accumulation of elements in a varve record of Lake Korttajärvi in Finland

In order to assess the importance of different pollution sources for the increase in element concentration and accumulation, historical changes in selected elements were studied in the annually laminated sediment of Lake Korttajärvi in Central Finland (62°20′N; 25°41′E). The sediment chronology based on varve counting (256 BC to AD 2005) provided a unique opportunity to explore and date signals of metal emissions, including the ancient metallurgical activities of the Roman Empire at the beginning of the Current Era. Records of this kind are mostly lacking in Finland and northernmost Europe. The stratigraphic sequence of element concentrations did not reflect any major changes in the lake, but changes in element accumulation rates provided distinct pollution signals caused by airborne fallout, catchment erosion, and to some extent municipal wastewater loading. The maximum bulk sedimentation recorded in the twentieth century was 11-fold and organic sedimentation 4-fold higher than the mean background sedimentation rate (256 BC to AD 1019). The increase in the accumulation rates of the majority of the elements, such as Cd, Sn, Pb, Si, Ni, B, Cu, Zn, Sr, Na, K, Sb, Ca, Cr, U and Mg, in descending order, was at least equal to that of bulk sedimentation or much greater, especially for Cd, Sn, and Pb. Changes in the accumulation of Co, Fe, Mn, Mo and As were small and mainly followed those of organic sedimentation. The earliest pollution signals were those of Pb recorded in AD 1055–1141. A weak signal of Pb pollution from the Roman Era was detected in metal concentrations, but this could not be confirmed by the accumulation rate data for Pb.     

The recording of floods and earthquakes in Lake Chichój,Guatemala during the twentieth century

Laguna Chichój (Lake Chichój) is the only deep permanent lake in the central highlands of Guatemala. The lake is located in the boundary zone between the North American and Caribbean plates. The lake has been struck by devastating earthquakes and tropical cyclones in historical times. We investigated the imprint of twentieth century extreme events on the sedimentary record of this tropical lake using a bathymetric survey of the lake, coring the lake floor, and providing a chronology of sediment accumulation. The lake occupies a series of circular depressions likely formed by the rapid dissolution of a buried body of gypsum. ²¹⁰Pb and ¹³⁷Cs inventories and varve counting indicate high rates of sedimentation (1–2 cm year^?1). The annually layered sediment is interrupted by turbidites of two types: a darker-colored turbidite, enriched in lake-derived biogenic constituents, and interpreted as a seismite, and a lighter-colored type, enriched in catchment-derived constituents, interpreted as a flood layer. Comparison of our ¹³⁷Cs-determined layer ages with a catalog of twentieth century earthquakes shows that an earthquake on the Motagua fault in 1976 generated a conspicuous darker-colored turbidite and slumped deposits in separate parts of the lake. The entire earthquake inventory further reveals that mass movements in the lake are triggered at Modified Mercalli Intensities higher than V. Tropical cyclonic depressions known to have affected the lake area had limited effect on the lake, including Hurricane Mitch in 1998. One storm however produced a significantly thicker flood layer in the 1940s. This storm is reportedly the only event to have generated widespread slope failures in the lake catchment. It is thus inferred that abundant landsliding provided large amounts of concentrated sediment to the lake, through hyperpycnal flows.     

Multiproxy evidence for the ‘Little Ice Age’ from Lake Hampträsk,Southern Finland

We studied a short sediment core from Lake Hampträsk, southern Finland, for evidence of the ‘Little Ice Age’ (LIA) in aquatic invertebrate communities. Subfossil chironomids, cladocerans, and chydorid ephippia were investigated, together with detrended correspondence analyses (DCAs) and loss-on-ignition (LOI). Our results show two cooler periods. The first cooling, indicated by increased numbers of chydorid ephippia and cold-water chironomid taxa, occurred ca. 1400 AD and the second, more drastic cooling, during the seventeenth century, when cold-water chironomids began to increase. Our data suggest that the cooling culminated around 1700 AD, when cold-stenothermic chironomids and chydorid ephippia attained maximal values and the LOI and diversity of invertebrates decreased to minimal values. After the LIA, the aquatic fauna appeared to respond to rising trophic state caused by enhanced land use in the catchment.     

On the organic compounds in water of Mochou Lake and Heart Lake in Larsemann Hills,Antarctica

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Sedimentation rates in the Wanggang salt marshes, Jiangsu

1 IntroductionLand-ocean interaction in coastalzone is one of the key m atters of the International G eosphereand Biosphere Program (IG BP). The key problem s of the second phase in the next decadeinclude the m aterial cycle, the system evolution process …     

Recent occurrence of large jökulhlaups at Lake Tuborg,Ellesmere Island,Nunavut

The varved sediment record from glacially-fed Lake Tuborg, Ellesmere Island, Nunavut, shows that only three large jökulhlaups have occurred there in the last millennium: 2003, 1993, and 1960. Detailed analyses of sediment microstructure and particle size, combined with in-situ hydrometeorological and limnological process studies, allowed jökulhlaup facies identification and discrimination from deposits from other processes. Deposits from large jökulhlaups are anomalously thick, typically lack internal structure, have sharp bases, and fine upwards. The ice-dammed lake above Lake Tuborg (the source of the jökulhlaups) likely changed its drainage style in 1960, from ice-dam overtopping to ice-dam flotation and glacial tunnel enlargement by melt widening, which allowed the lake to drain completely and catastrophically. Complete drainage of ice-dammed lakes by ice-dam flotation is rare in the region is due to the pervasiveness of cold-based ice. Twentieth century warming is likely responsible for some combination of dam thinning, lake expansion and deepening, and changing the thermal regime at the base of the dam. Anomalously thick individual varves were periodically deposited beginning in the nineteenth century, and their thickness increased with time. This likely reflects a combination of increased ice dam overtopping, subaqueous slope failures, sediment availability and rising air temperature. The varve record presented here significantly correlates with a previous, shorter record from Lake Tuborg. However, generally weak correlations are found between the new varve time series, regional records of air temperature, and glacial melt from ice cores on the Agassiz Ice Cap. It is hypothesized that on short timescales, sedimentation at the coring location reflects a complex and varying integration of multiple hydroclimatic, geomorphic and limnologic influences.     

Palaeoclimate inferred from δ18O and palaeobotanical indicators in freshwater tufa of Lake Äntu Sinijärv,Estonia

We investigated a 3.75-m-long lacustrine sediment record from Lake Äntu Sinijärv, northern Estonia, which has a modeled basal age >12,800 cal yr BP. Our multi-proxy approach focused on the stable oxygen isotope composition (δ¹⁸O) of freshwater tufa. Our new palaeoclimate information for the Eastern Baltic region, based on high-resolution δ¹⁸O data (219 samples), is supported by pollen and plant macrofossil data. Radiocarbon dates were used to develop a core chronology and estimate sedimentation rates. Freshwater tufa precipitation started ca. 10,700 cal yr BP, ca. 2,000 years later than suggested by previous studies on the same lake. Younger Dryas cooling is documented clearly in Lake Äntu Sinijärv sediments by abrupt appearance of diagnostic pollen (Betula nana, Dryas octopetala), highest mineral matter content in sediments (up to 90 %) and low values of δ¹⁸O (less than ?12 ‰). Globally recognized 9.3- and 8.2-ka cold events are weakly defined by negative shifts in δ¹⁸O values, to ?11.3 and ?11.7 ‰, respectively, and low concentrations of herb pollen and charcoal particles. The Holocene thermal maximum (HTM) is palaeobotanically well documented by the first appearance and establishment of nemoral thermophilous taxa and presence of water lilies requiring warm conditions. Isotope values show an increasing trend during the HTM, from ?11.5 to ?10.5 ‰. Relatively stable environmental conditions, represented by only a small-scale increase in δ¹⁸O (up to 1 ‰) and high pollen concentrations between 5,000 and 3,000 cal yr BP, were followed by a decrease in δ¹⁸O, reaching the most negative value (?12.7 ‰) recorded in the freshwater tufa ca. 900 cal yr BP.     

Aquatic macrophyte vegetation development in Kråkenes Lake, western Norway, during the late-glacial and early-Holocene

Macrofossil analyses were carried out on the late-glacial and early-Holocene sediments of the radiocarbon-dated master core at Kråkenes Lake, western Norway, to investigate the aquatic vegetation changes. Ranunculus sect. Batrachium and Nitella were the earliest pioneers after deglaciation ca. 12,300 ¹⁴C yr BP. The Allerød vegetational succession was very slow during ca. 1000 ¹⁴C yrs in a cool climate and conditions that were similar to those above tree-line in Norway today. The rapid cooling at the start of the Younger Dryas stadial caused extensive disturbance, and with the development of an active cirque glacier in the catchment, plants and animals were almost exterminated from the lake by inflow of permanently cold and turbid water. Rising temperatures caused the glacier to melt at the end of the Younger Dryas. The biotic response to the rapid warming was immediate, with pioneer Ranunculus sect. Batrachium and Nitella expanding within 1-3 decades, closely followed by other elodeids. The lake witnessed a remarkable isoetid succession, with phases dominated by Limosella aquatica, Subularia aquatica, Elatine hydropiper, Isoetes echinospora, and, later, I. lacustris. About 800 yrs into the Holocene most of the macrophytes declined. The short-lived isoetids became extinct, but other taxa probably survived vegetatively. The reasons for this decline are unknown, but are probably related to nutrient depletion in combination with other factors. About 550 yrs later, I. lacustris and Nymphaea colonised, and a stable flora and vegetation developed. This study illustrates the large and rapid changes that occurred over the first 1400 yrs of the Holocene in the macrophyte flora and vegetation in Kråkenes Lake before stability was attained, pointing to the value of a palaeoecological study in tracing aquatic successions over time, and highlighting our lack of knowledge of the underlying ecological factors responsible for such rapid and marked changes.     

Vegetation and sedimentation in the Lake Edward Basin, Uganda–Congo during the late Pleistocene and early Holocene

New palynological and sedimentological data obtained from the basal 3 m of core E96-2P from Lake Edward, Uganda–Congo record conditions wetter than present in the Edward basin from 11 000 to 6700 yr BP, in phase with other climate and vegetation records of northern hemispheric East Africa. Dominant pollen taxa include Celtis spp., Alchornea spp., Olea spp., and Moraceae indicating a moist semi-deciduous tropical forest. More xeric indicators such as Amaranthaceae and Asteraceae together with Poaceae comprise less than 5% of the pollen sum throughout this interval as compared with between 44 and 50% during a lake lowstand at 2000 cal yr BP and at the core top (near modern). The differences between these two assemblages suggest a 25 to 60% increase in annual precipitation during the early- to mid-Holocene as compared to modern (1500–2000 vs. 1200 mm/yr today). Early Holocene sediments in E96-2P are composed of laminated diatom oozes with moderately high total sulfur concentrations (2.8–4.7%) and no authigenic calcite, also indicative of conditions wetter than present. Between 9000 and 6700 yr BP, palynological and sedimentary proxies indicate sub-millennial-scale events related to changes in riverine discharge and runoff in the Edward basin. We attribute the variability in runoff, and hence precipitation, to Holocene variability in Indian or Atlantic Ocean SSTs or to shifts in the relative contribution of Indian and Atlantic moisture sources to the western Rift of equatorial Africa.     

Lead pollution history from 256 BC to AD 2005 inferred from the Pb isotope ratio (<Superscript>206</Superscript>Pb/<Superscript>207</Superscript>Pb) in a varve record of Lake Korttajärvi in Finland

The lead pollution history, based on the accumulation rate of total Pb and ratio of stable isotopes (²⁰⁶Pb/²⁰⁷Pb), was studied in the annually laminated sediment of a small lake in Finland (62°20′ N; 25°41′ E). The sediment chronology based on varve counting provided a unique opportunity to explore and date signals of Pb emissions, including the ancient metallurgical activities of the Roman Empire at the beginning of the Current Era. Changes in the ratio of stable isotopes gave a pronounced signal of the atmospheric Pb fallout in AD 32–392, although this was not distinguishable in the accumulation rate of total Pb, as it was observed in previous work. Calculated accumulations of the ancient pollution Pb were low, the highest values being 0.2–0.3 mg m² a⁻¹ in AD 144–392, corresponding 14–21% of the accumulation of total Pb. The accumulation of pollution Pb collapsed in the fifth century and remained at or close to the background level up to the eleventh century. After this, the accumulation rate of pollution Pb began to increase and reached 1.2 mg m² a⁻¹ in AD 1420–1439, corresponding to 44% of the total Pb accumulation. During five centuries, from AD 1420–1895, the average accumulation of pollution Pb was 2.6 mg m² a⁻¹, the variation being from 0.8 to 4.8 mg m² a⁻¹. The accumulation of Pb started to increase exponentially in the early twentieth century, and the highest accumulations of pollution Pb (11–22 mg m² a⁻¹, corresponding 50–76% of the annual accumulation of total Pb) were dated to AD 1926–1985. The banning of the use of leaded fuel has led to a pronounced decrease in the accumulation of pollution Pb since the 1980s, and the present accumulation rate represents the level that prevailed 80–120 years ago.     

Source of and potential bio-indicator for the heavy metal pollution in Ny-lesund,Arctic

Three kinds of tundra plant samples including Dicranum angustum(a type of boreal bryophyte),Puccinellia phryganodes(a type of fringy plant),Salix polaris(a type of vascular plant) and surface soil were samples in 200 at Ny-lesund of the Arctic.The levels of eight heavy metal elements(Hg,Pb,Cd,Cu,Zn,Ni,Fe and Mn) and three metal-like elements(As,Se,Sr) in the plant and soil samples of the areas within previous coal mining activities are significantly higher than those of other areas.The relative accumulation of these elements in these tundra plant samples is consistent with the one in the soil samples,especially in the areas affected by previous coal-mining activities.Thus,the pollution is apparently from local coal mining activity.Dicranum angustum has the highest concentrations among those elements,and it can be a good bio-indicator for heavy metal pollution in Ny-lesund.Though Ny-lesund is less polluted by heavy metal than nearby Northern European human living areas,but much more than the tundras of the Alaska,Greenland and the Antarctic.