Distribution and mode of occurrences of radionuclides in phosphogypsum from the Aqaba and Eshidiya fertilizer plants, Jordan

Phosphogypsum is a waste by-product of the phosphate fertilizer industry that has relatively high concentrations of some U decay-series radionuclides such as ^226Ra and ^210Pb. The distribution and environmental mobility of radionuclides in phosphogypsum are an important concern because this gypsum by-product is used for wallboard, in agriculture and as a soil amendment. This study determined the distribution of ^226Ra, ^210Pb, within phosphogypsum stacks of varying age and among three size fractions （coarse： 〈0.212 mm; medium： 0.212-0.053 mm; fine： 〈0.053 mm）, in phosphogypsum derived from Aqaba and Eshidiya fertilizer plants. The results indicated that ^226Ra and ^210Pb were generally uniformly distributed in phosphogypsum stacks and showed no significant difference in the concentration of these elements with the age of stack. In the Aqaba phosphogypsum ^226Ra was slightly 10% enriched in the coarse fraction, while ^210Pb was 10% enriched in the free size fraction. In the Eshidiya phosphogypsum ^226Ra and ^210Pb contents were both relatively enriched （10%） in the fine size fraction.     

Bioavailability and mobility of trace metals in phosphogypsum from Aqaba and Eshidiya,Jordan

As, Cd, Cr, Cu, U, and Zn in Aqaba and Eshidiya phosphogypsum showed relative uniformity in particle size presented by coarse (>0.212 mm); medium (0.212–0.053 mm); and fine (<0.053 mm) in the stacks by age of deposition. Jordan phosphogypsum contains low concentrations of As, Cd, Cr, Cu, U, and Zn compared to those reported worldwide. The bioavailability and mobility of trace metals were estimated using aqua regia leaching experiments. Leaching results have shown that around 3% of the As, 1% of the Cd, 5% of the Cr, 9% of the Cu, 4% of the U, and 3% of the Zn are transferred to the surrounding aquatic environment and/or soils. Mobility of trace metals in phosphogypsum was classified into three degrees: elements with high mobility were Cu and U; those with moderate mobility were As and Zn; and those with low mobility were Cd and Cr. It can be concluded that As, Cd, Cr, Cu, U, and Zn were not only uniformly distributed in the stack, but they are not leached from the phosphogypsum stacks in any significant amount, and then they are not easily transferred to the surrounding aquatic environment and/or soils.     

Archaeoseismological investigation of the ancient Ayla site in the city of Aqaba,Jordan

Many tens of severe earthquake damage patterns were revealed at the ancient city of Ayla. The seismic deformation patterns are of various types, including systematic tilting of walls, systematic shifting and rotation of wall fragments and individual stones, arch deformations and joints crossing two or more stones. Features of later repair, supporting walls and secondary use of building stones suggest that the damage patterns can be explained by two historical devastating earthquakes: (I) revealed in the constructions built during the late Rashidun period (644–656 A.D.); (II) revealed in the structures restored and/or built during the Fatimid period (1050–1116 A.D.). The maximum observed intensity of both earthquakes at the studied site was not less than IX (EMS98 scale). The sources of the seismic events were probably the Dead Sea Transform and Wadi Araba Faults that cross the site obliquely. The last 1995 Nuweiba earthquake with maximum observed intensity VIII has also left its clear traces in the excavated ancient Ayla buildings. The severity of the destruction was significantly increased because of site effects.     

东林矿煤中砷的含量分布及赋存状态

燃煤引起人砷中毒在我国云贵川地区比较常见,因此有必要研究煤中砷的赋存状态。研究了重庆东林矿4号和6号主采煤层中砷的含量、分布规律及其赋存特征。研究表明:东林矿4号层煤中砷、总硫和灰分的平均含量均大于6号层。东林矿原煤中砷的含量范围为0.20~7.87 µg/g,平均值1.68 µg/g,明显低于重庆及重庆其他矿煤中砷的平均水平,没有明显富集。赋存特征分析表明,东林矿煤中砷具有明显的亲硫性,可能主要赋存于同生黄铁矿中,在硅酸盐矿物相中分布较少。     

Mineralogy, geochemistry, and origin of felsic dike swarms in Aqaba complex (Wadi Al-Yutum), South Jordan

The present work deals with the geologic setting and mineralogical and geochemical study of Late Precambrian magmatic rocks especially the felsic dike swarms of northeast Aqaba complex in South Jordan. The northeast Aqaba complex represents one of the most significant regions in the South Jordan basement. The basement rocks in the studied region are composed of schists, gneisses, migmatites, met gabbros, diorite, and granite. It is invaded by post-orogenic dike swarms. The post-orogenic dike swarms have been recognized as felsic dikes of dacite, rhyodacite, and rhyolite composition. They are composed of plagioclase, K-feldspar, quartz, biotite, and hornblenble with a porphyritic texture. Chemically, they are enriched in compatible elements especially in the large ion lithophile elements such as K, Rb, and Ba. The values of A/NK are more than A/CNK, indicating that dacitic dike swarms have metaluminous nature. Meanwhile, the values of A/NK are less than A/CNK in rhyodacitic and rhyolitic dike swarms of prealuminous nature. This felsic dike can be related to an intercontinental setting that was accompanied by a chemical evolution of the extensional movements and is formed by partial melting of crustal rocks, which are already known from other areas in the northeast portion of the Arabian-Nubian Shield.     

Vulnerability mapping of shallow groundwater aquifer using SINTACS model in the Jordan Valley area, Jordan

Jordan Valley is one of the important areas in Jordan that involves dense agricultural activities, which depend on groundwater resources. The groundwater is exploited from an unconfined shallow aquifer which is mainly composed of alluvial deposits. In the vicinity of the Kafrein and South Shunah, the shallow aquifer shows signs of contamination from a wide variety of non-point sources. In this study, a vulnerability map was created as a tool to determine areas where groundwater is most vulnerable to contamination. One of the most widely used groundwater vulnerability mapping methods is SINTACS, which is a point count system model for the assessment of groundwater pollution hazards. SINTACS model is an adaptation for Mediterranean conditions of the well-known DRASTIC model. The model takes into account several environmental factors: these include topography, hydrology, geology, hydrogeology, and pedology. Spatial knowledge of all these factors and their mutual relationships is needed in order to properly model aquifer vulnerability using this model. Geographic information system was used to express each of SINTACS parameters as a spatial thematic layer with a specific weight and score. The final SINTACS thematic layer (intrinsic vulnerability index) was produced by taking the summation of each score parameter multiplied by its specific weight. The resultant SINTACS vulnerability map of the study area indicates that the highest potential sites for contamination are along the area between Er Ramah and Kafrein area. To the north of the study area there is a small, circular area which shows fairly high potential. Elsewhere, very low to low SINTACS index values are observed, indicating areas of low vulnerability potential.     

Radiochemistry of sediments from the southern Dead Sea, Jordan

 A sediment core from the southern Dead Sea was analyzed using gamma spectroscopy as well as ²¹⁰Pb dating in order to ascertain if any radioactive contamination could be detected and to determine the sedimentation rates in the area. Results of this study show no presence of man-made radionuclides in the area. Sedimentation rates were determined to be between 0.25 and 0.4 g/cm²/year. (∼0.5 cm/year), which is in line with what would be expected assuming carbonate layers are annual varves. Received: 31 January 1997 · Accepted: 11 March 1997     

Mobilization, redistribution and bioavailability of potentially toxic elements in Shidiya phosphorites, Southeast Jordan

Shidiya Phosphorites, Southeast Jordan, provide a typical example of natural geological materials depleted with potentially toxic elements as compared to other phosphate deposits from all over the World. Nevertheless, the environmental concern as to whether processing and fertilizer production might affect the potentially toxic element concentrations in these phosphates positively or negatively has to be avoided. In order to do so, this study was designed to provide information on the redistribution pathways of the measured toxic elements during the several processing steps, including crushing, screening, washing, flotation and drying processes. It aimed also at providing information on the redistribution pathways during the different phosphate fertilizer production steps. The bioavailability of potentially toxic elements in acidic and alkaline environments has also been assessed.     

Electrical geophysical and hydrogeological investigations of groundwater aquifers in Ruseifa municipal landfill, Jordan

The effect of the Ruseifa municipal landfill on the shallow groundwater aquifers in the area was investigated in two separate sites. The first one was not used since 1994, whereas the other is still being used for dumping. Fourteen electrical resistivity soundings were performed to detect the leachate and its effect on the quality of the groundwater. Results indicated that the solid waste thickness of the landfill was ranged from 3 to 20 m with resistivity value less than 10 Ω m. Based on the resistivity decreases of values less than 5 Ω m, the leachate was detected in the landfill sites at depths ranged from 10 to 50 m. However, the flow direction of the leachate at depth ranging 10–20 m in the terminated site was toward north, whereas the flow direction of the leachate in the site still used for dumping was toward east–northeast which causes the major source of groundwater pollution.     

Petrography, chemistry and genesis of phosphorite concretions in the Eocene Umm Rijam Chert limestone Formation, Ma'an area, south Jordan

Phosphorite concretions are recorded for the first time within the lower part of the Umm Rijam Chert Limestone Formation (Eocene) in the Ma'an area, southern Jordan. The phosphorite concretions are typically hosted and encountered as individual layer in moderately lithified sediments of marl, chalk and chalky marl. The phosphorite concretions are present in thin layer (10–30 cm thick). They are localized on a hardground surface that formed as a result of cementation of soft ground by bioclastic materials. Light grey and brownish to black colors are encountered with isometric, ellipsoid, elongated, subangular to subrounded phosphorite concretions (up to 6 cm in length). Most of the phosphorite concretions preserve bioturbation structures; they also include fecal pellets of various sizes. The main biogenic components are fragments of macrofossils (bivalves) and microfossils (planktonic foraminifera) in different proportions. Petrographic examinations reveal that the phosphorite concretions are composed of cryptocrystalline apatite that characteristically appears in cross-polarized light almost as isotropic phosphate and minor anisotropic phosphate. Apatite and calcite are the main mineral constituents of the phosphorite concretions identified by XRD. The apatite is identified as francolite (carbonate-flour-apatite). Chemical analyses of the phosphorite concretions using X-ray florescence indicate that the P₂O₅ content ranges from 18.8 to 31.19%, whereas SEM–EDS analyses indicate that the phosphorus proportion is around 14% by volume. It could be argued that the phosphorite concretions were transported after being reworked, or were derived from carbonate and chalk pebbles that were later phosphatized and subjected to erosion, forming residual lag deposit along the hardground surface.     

云南安宁磷矿区水系沉积物磷赋存形态及分布特征

磷污染是水污染的重要组成部分,因其可造成水体富营养化、水质下降,从而引起人们的广泛关注。研究沉积物中不同磷赋存形态及其分布特征有助于了解沉积物中磷的行为特征及迁移能力,从而为水体富营养化防治提供支撑。磷矿的开采、冶炼对矿区内水资源环境可能产生严重影响,本文以安宁磷矿区内河流、水库为研究区域,分析了不同水系沉积物磷元素赋存形态及分布特征,并对其生态风险进行评估。采用X射线荧光光谱法测定研究区水系沉积物总磷（TP）含量,并基于顺序提取及Hupfer改进的磷形态分析方法,将研究区各水系沉积物中磷分为弱吸附态磷（NH4Cl-P）、可还原态磷（BD-P）、金属氧化物结合态磷（NaOH-P）、钙结合态磷（Ca-P）、残渣态磷（Res-P）等5种形态,采用单因子污染指数法对其进行生态风险评估。结果表明：研究区水系沉积物样品中TP含量范围为567.6~48115.5mg/kg,NH4Cl-P含量范围为0.07~115.2mg/kg,BD-P含量范围为8.84~802.5mg/kg,NaOH-P含量范围为21.3~3129.5mg/kg, Ca-P含量范围为12~45098mg/kg,Res-P含量范围为28.5~515.4mg/kg。研究区各水系沉积物样品磷形态具有相似的分布特征,即磷主要以Ca-P和NaOH-P形态存在,其他磷形态的相对含量大小顺序为NH4Cl-P     

辽河油田稠油中贵金属分布和赋存状态研究

以辽河油田稠油为研究对象,通过原子吸收光谱、实沸点蒸馏等手段,研究了辽河油田稠油中Au、Ag、Pt和Pb等贵金属在不同馏分中的分布特征.结果表明,经过实沸点蒸馏后,贵金属不同沸程温度的原油馏分中含量和分布存在很大差异,Au、Ag、Pt、Pd主要集中在渣油馏分中,在沸点》508℃的渣油馏分中Au、Ag、Pt、Pd的比例分别是93.4%、76.9%、73.4%和68.0%;采用选择性萃取的方法对金在稠油中的存在形态的初步研究发现,金在稠油中主要以有机配合物和少量无机配合物形式存在.     

Paleoclimatic and archeological implications of Pleistocene and Holocene environments in Azraq, Jordan

Wetlands are a key archive for paleoclimatic and archeological work, particularly in arid regions, as they provide a focus for human occupation and preserve environmental information. The sedimentary record from 'Ayn Qasiyya, a spring site on the edge of the Azraq Qa, provides a well-dated sequence through the last glacial–interglacial transition (LGIT) allowing environmental changes in the present-day Jordanian desert to be investigated robustly through this time period for the first time. Results show that the wettest period at the site preceded the last glacial maximum, which itself was characterised by marsh formation and a significant Early Epipaleolithic occupation. A sedimentary hiatus between 16 and 10.5 ka suggests a period of drought in the region although seasonal rains and surface waters still allowed seasonal occupation of the Azraq region. Archeological evidence suggests that conditions had improved by the Late Epipaleolithic, about the time of the North Atlantic Younger Dryas. The changes between wet and dry conditions at the site show similarities to patterns in the eastern Mediterranean and in Arabia suggesting the Jordan interior was influenced by changes in both these regions through the LGIT climatic transition.     

Geochemistry and pollution of shallow aquifers in the Mafraq area, North Jordan

 Chemical data are used to clarify the hydrogeological regime in the Mafraq area in northern Jordan, as well as to determine the status of water quality in the area. Groundwater from the shallow aquifer in the Mafraq area can be divided into two major groups according to geographical locations and chemical compositions. Water in the basaltic eastern part of the study area is characterized by the dominance of chloride, sulfate, sodium, and potassium, whereas waters in the limestone aquifers in the west are dominated by the same cations but have higher concentrations of bicarbonate. Stable isotopes show that the shallow aquifers contain a single water type which originated in a distinct climatic regime. This water type deviates from the Global Meteoric Water Line (MWL), as well as from the eastern Mediterranean meteoric water line. The waters are poor in tritium, and thus can be considered generally older than 50 years. Chemical mass balance models suggest that water is moving from the west towards the north of the study area. This suggests that waters from the different basins are separated from each other. Degradation of water quality can be attributed to agricultural fertilizers in most cases, although the waste-water treatment plant at Khirbet es Samra is a contributor to pollution in the southwestern part of the study area. Received: 20 August 1997 · Accepted: 3 February 1998     

K-Ar dating,X-Ray diffractometry,optical and scanning electron microscopy of glauconies from the early Cretaceous Kurnub Group of Jordan

The glaucony of the early Cretaceous Kurnub Group in Jordan has been isotopically dated using the K–Ar method. The glaucony occurs in an arenaceous dolomite unit, referred to here to as glaucony marker unit (GMU), located in the upper part of the Kurnub Group, that persists throughout Jordan. The glaucoliths of the heavy fraction are dark green in colour, ovoidal or mammilated, with a mainly cracked smooth surface, whereas the light fraction glaucoliths are light green in colour, irregular in shape and have a rough or porous surface. Both fractions exhibit boxwork and rosette microstructure, whereas lamellar microstructure is restricted to the heavy glaucoliths. X-ray diffraction and chemical analysis placed the glauconies of the GMU of the Kurnub Group in Odin and Matter's evolved to highly evolved class corresponding to glauconitic mica and suggested that they should be well-closed chronometers. On the other hand, petrographic investigation proved these glauconies to be unaltered, whereas the other altered ones are discarded from the age determination. The unweathered, highly evolved, heavy glauconies that are neither tectonized nor deeply buried best fulfil recommendations regarding appropriate samples for K–Ar dating. The apparent age constrained, within the analytical uncertainty limits, from the most evolved glaucony is 96·1±1·1 Ma and suggests that the GMU is of Albian age. The other less evolved glauconies, which are still within the evolved to highly evolved class of Odin and Matter, yield a mean apparent age of 93·6±1·0 Ma, which is probably slightly younger than the true depositional age by 2–3 Ma due to genetic and historical uncertainties, as indicated by the petrographic and sedimentological data. Thus the upper part of the Kurnub Group, where the GMU is located, is of Albian age. © 1998 John Wiley & Sons, Ltd.     

Evaluation of groundwater in a three-aquifer system in Ramtha area, Jordan: recharge mechanisms, hydraulic relationship and geochemical evolution

The groundwater wells in the Ramtha region of Jordan are tapping three aquifers: the upper, intermediate and deep aquifers. The upper aquifer groundwater is tritiated and its stable isotopic composition varies over a wide range. This signifies short residence times and local recharge from an elevation around 600 m above sea level. The groundwater of the upper aquifer has an elevated level of , which is attributed to anthropogenic sources. The intermediate and deep aquifers are untritiated and have long residence times. The stable isotope results signify a recharge elevation for the intermediate aquifer higher than that for the upper aquifer. Stable isotopes in groundwater from both aquifers clustered along the eastern meteoric water line and demonstrate association with the dominant climate of Jordan. The groundwater of the intermediate aquifer is classified as Ca²⁺- , which reflects circulation through a carbonate aquifer. There is evidence that leakage from the upper aquifer has influenced the isotopic and chemical makeup of the groundwater in an intermediate aquifer well. The groundwater of the deep aquifer has the highest temperature in the basin and its isotopic composition is much more depleted than both the upper and intermediate aquifers and plots on the global meteoric water line.

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Résumé  Les puits de la région de Ramtha en Jordanie captent trois aquifères : les aquifères supérieur, intermédiaire et profond. L’eau de l’aquifère supérieur est tritiée et sa composition en isotopes stables varie dans un large intervalle. Ceci signifie des temps de séjour courts et une recharge locale à une altitude d’environ 600 mètres au-dessus du niveau de la mer. L’eau de l’aquifère supérieur a une teneur en élevée, qui est attribuée à des origines anthropiques. Les aquifères intermédiaire et profond ne sont pas tritiés et ont des temps de séjour longs. Les valeurs des isotopes stables indiquent une altitude de recharge pour l’aquifère intermédiaire plus élevée que pour l’aquifère supérieur. Les isotopes stables de l’eau des deux aquifères groupés le long de la droite des eaux météoriques orientale démontrent une relation avec le climat prédominant en Jordanie. L’eau de l’aquifère intermédiaire est de type Ca²⁺-, ce qui traduit une circulation dans un aquifère carbonaté. Il est évident qu’un apport de l’aquifère supérieur a influencé la composition isotopique et chimique da l’eau d’un puits dans l’aquifère intermédiaire. L’eau de l’aquifère profond a la température la plus élevée dans le bassin et sa composition isotopique est bien plus déprimée que dans les deux aquifères supérieur et intermédiaire et se situe sur la droite globale de l’eau météorique.

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Resumen  Las perforaciones en la región de Ramtha de Jordania atraviesan tres acuíferos: los acuíferos superior, intermedio y profundo. El agua del acuífero superior contiene tritio y su composición isotópica varía en un rango amplio. Esto se interpreta como aguas de corto período de residencia recargadas localmente en una zona elevada a unos 600 m sobre el nivel del mar. El agua del acuífero superior posee elevadas concentraciones de , de origen antropogénico. Las aguas de los acuíferos intermedio y profundo no contienen tritio y su período de residencia es largo. Los resultados de las concentraciones de isótopos estables sugieren que la recarga del acuífero intermedio proviene de alturas mayores que las correspondientes al acuífero superior. Los datos de isótopos estables de ambos acuíferos se agrupan a lo largo de la Línea Meteórica Este, y demuestra su asociación con el clima predominante en Jordania. El agua subterránea del acuífero intermedio se clasifica como Ca²⁺-, lo que refleja su circulación a través de un acuífero carbonático. Hay evidencias que las filtraciones desde el acuífero superior han influenciado las características químicas e isotópicas del acuífero intermedio. Las aguas del acuífero profundo son las de mayor temperatura en la cuenca, su composición isotópica es más reducida que aquella de los acuíferos superior e intermedio, y su posición gráfica se aproxima a la Línea Meteórica Mundial.

     

Noble gases reveal the complex groundwater mixing pattern and origin of salinization in the Azraq Oasis,Jordan

Azraq Oasis in the eastern Jordanian desert is an important freshwater resource of the country. Shallow groundwater reserves are heavily exploited since the 1980s and in consequence the groundwater table dropped significantly. Furthermore, some wells of the major well field drilled into the shallow aquifer show an increasing mineralization over the past 20 years. A previous study using conventional tracers did not result in a satisfactory explanation, from where the salt originates and why only a few wells are affected. In this study, the application of dissolved noble gases in combination with other tracer methods reveals a complex mixing pattern leading to the very localized salinization within the well field. It is found that primarily the wells affected by salinization 1) contain distinctly more radiogenic ⁴He than the other wells, indicating higher groundwater age, and 2) exhibit ³He/⁴He ratios that argue for an imprint of deep fluids from the Earth's mantle.However, the saline middle aquifer below is virtually free of mantle helium, which infers an upstream from an even deeper source through a nearby conductive fault. The local restriction of the salinization process is explained by the wide range of permeabilities of the involved geologic units. As the wells abstract water from the whole depth profile, they initially pump water mainly from the well conductive top rock layer. As the groundwater table dropped, this layer fell progressively dry and, depending on the local conductivity profile, some wells began to incorporate more water from the deeper part of the shallow aquifer into the discharge. These are the wells affected by salinization, because according to the presented scheme the deep part of the shallow aquifer is enriched in both salt and mantle fluids.     

Vertical variation of phosphorus forms in surface sediments from Wuli Bay, Taihu Lake, China

1IntroductionPhosphorus,an essential nutrient for the primaryproductivity in freshwater systems,is an important fac-tor controlling lacustrine eutrophication.Although ex-ternal input of phosphorus has been assumed as the vi-tal responsibility for the eutrophication of lakes(ZhuJun et al.,2005),the remobilization of phosphorus insediments has a distinct influence on it as well(Bostr m et al.,1982).The concentrations of totalphosphorus(Ptotal)in the sediments are often related tothe trophic st…     

Origin,age and petrogenesis of Neoproterozoic composite dikes from the Arabian‐Nubian Shield,SW Jordan

The evolution of a Pan‐African (c. 900–550 Ma) suite of composite dikes, with latite margins and rhyolite interiors, from southwest Jordan is discussed. The dikes cut the Neoproterozoic calc‐alkaline granitoids and high‐grade metamorphic rocks (c. 800–600 Ma) of the northern Arabian‐Nubian Shield in Jordan and have been dated by the Rb‐Sr isochron method at 566±7 Ma. The symmetrically distributed latite margins constitute less than one‐quarter of the whole dike thickness. The rhyolite intruded a median fracture within the latite, while the latter was still hot but completely solidified. The dikes are alkaline and bimodal in composition with a gap in SiO₂ between 61 and 74 wt%. Both end members display similar chondrite‐normalized rare earth element patterns. The rhyolites display the compositional signature of A‐type granites. The (La/Lu)_N values are 6.02 and 4.91 for latites and rhyolites, respectively, and the rhyolites show a pronounced negative Eu anomaly, in contrast to the slight negative Eu anomaly of the latites. The chemical variability (e.g. Zr/Y, Zr/Nb, K/Rb) within and between latites and rhyolites does not support a fractional crystallization relationship between the felsic and mafic members of the dikes. We interpret the magma genesis of the composite dikes as the result of intrusion of mantle‐derived mafic magma into the lower crust in an extensional tectonic regime. The mafic magma underwent extensive fractional crystallization, which supplied the necessary heat for melting of the lower crust. The products of the initial stages of partial melting (5–10%) mixed with the fractionating mafic magma and gave rise to the latite melts. Further partial melting of the lower crust (up to 30%) produced a felsic melt, which upon 50% fractional crystallization (hornblende 15%, biotite 5%, feldspars 60%, and quartz 20%) gave rise to the rhyolitic magma. Copyright © 2004 John Wiley & Sons, Ltd.