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1.
为研究重庆老龙洞地下河不同部位水体、表层沉积物有机氯农药分布特征,用气相色谱-微池电子捕获检测器(GC-μECD)分析了样品中OCPs含量。结果表明:研究区水样、表层沉积物中OCPs检出率均为100 %,其浓度在时间上存在季节差异,水体中OCPs、DDTs、HCHs含量丰水期小于枯水期,而在表层沉积物中则表现为OCPs、HCHs丰水期大于枯水期,DDTs丰水期小于枯水期;在空间上则表现为水体中有机氯农药总体下游大于上游,而沉积物中则与之相反。通过对比可知,岩溶洞穴环境由于缺乏光照,空气流动缓慢,生物活动不频繁,使水体中的HCHs不易降解,沉积物中的HCHs不易重新释放而浓度高于洞外。枯水期由于洞内流速较小且变幅不大,水体中的DDTs大量沉积因而其浓度低于洞口,而丰水期洞口因受大量雨水的稀释作用DDTs反而低于洞内的含量;洞内沉积物中的DDTs则因洞内环境恒定不易重新释放和枯水期水体中的大量沉积而一直高于洞外。洞穴环境、不同污水汇入对水体中DDTs和表层沉积物中DDTs、HCHs的组成结构均有不同程度的影响,而对水体中HCHs的组成结构影响不大。此外,地下河不同部位污染源的输入对有机氯污染物的组成结构也有影响。与国内外水体及表层沉积物中HCHs、DDTs相比较,研究区水体、表层沉积物中HCHs、DDTs浓度分别处于中等和偏高水平。   相似文献   

2.
In south‐central Pennsylvania, USA, is the world's only Upper Silurian/lower Devonian period shallow water marine reef, located deep within a cave and operated for the tourist trade. Other unusual features in the cave include black basaltic rock, the presence of nearly perfect clear calcite crystals and varied cave decorations. The reef is primarily composed of stromatoporoids with brachiopods and crinoids and is part of the Upper Silurian Jersey Shore Member of the Keyser Formation siliciclastics and carbonates. Just outside the cave itself is a transition to the Devonian New Creek and Corriganville formations, also siliciclastics and carbonates. In these formations are the only actual fossil corals in the vicinity of the cave discovered by Boy Scouts in 1928 by climbing through a natural entrance. ‘Wonderland Coral Caverns’ was opened to the public in the 1930s and closed in the 1980s until a safer entrance could be created. The cave is the result of the Alleghanian Orogeny in which Silurian and Devonian sedimentary strata were buried without metamorphism beneath the encroaching northwest African continental mass as the proto‐Atlantic Ocean and the Rheic Ocean closed. The mass eroded completely and the resulting sediments were transported to the west of modern day Pennsylvania, leaving a karst topography and a well preserved fossil reef.  相似文献   

3.
《Geodinamica Acta》2013,26(1-3):41-48
Clastic karst deposits occur at different positions within karst areas, whereas surface karst deposits, sediments of the crack filling facies, the cave entrance facies and the inner cave facies have to be distinguished. The karstification itself is of minor importance for the formation of clastic deposits. Except for incasional debris and impure limestones or marls the contribution of carbonate rocks to clastic karst deposits is low. The majority of clastic material is allogenic and siliciclastic.

Regarding the depositional processes cave sediments can be divided into fluvial cave deposits, gravitative or percolative deposits, decomposition deposits and rock breakdown. An actualistic approach could be a useful tool for the identification of fluvial cave deposits. By means of the depositional features of recent cave sediments and classical sedimentological features cave deposits of unknown origin can be classified.  相似文献   

4.
5.
The last hominin occupations of Gran Dolina cave at Atapuerca are represented by layer TD10‐1. This layer has yielded high densities of anthropogenic bone and lithic remains that suggest the existence of a referential hominin campsite. Micromorphological analysis was carried out in order to reconstruct site formation processes and to find traces of hominin activity in the sediments. Results show that TD10‐1 is an autochthonous deposit whose components are derived from a local, degraded cave entrance environment. The base of TD10‐1 represents a moist, semi‐sheltered environment associated with anthropogenic input and low sedimentary rates, while the rest of the deposit represents a non‐anthropogenic, more open environment with higher rates of sedimentation. The TD10‐1 archaeological assemblages have not undergone long transport or strong postdepositional disturbance. Further interdisciplinary analyses are needed to characterize the types and intensity of the hominin activities recorded in TD10‐1. © 2008 Wiley Periodicals, Inc.  相似文献   

6.
Evaporitic‐lagoonal marl and dolomite laminar fill sediments are preserved in relict dry caves of the Dead Sea Fault Escarpment (Israel) which has been tectonically active since the Late Neogene. The hosting caves are located within Turonian massive carbonate bedrock and at higher altitudes than previously documented fill sediments of the Dead Sea depression. Based on the relative altitudes of the cave sediments, the ‘reversed stratigraphy’ of the Dead Sea depression fill sediments, possible partial correlation of the cave sediments with other fill sedimentary units of the depression, and sedimentary, geochemical and mineralogical characteristics, it is concluded that: (i) the cave sediments are among the oldest of the depression fill; and (ii) the deposition of the cave sediments took place in hypersaline dolomite‐precipitating water bodies of Late Neogene age, during the initial morphotectonic stages of the depression formation. Variable and relatively low Sr/Ca and δ34S ratios of the cave sediments (assuming precipitation from sea water) suggest variable fresh water input into the depositional brine. The present altitudes of the cave sediments reflect Late Neogene levels of water bodies in the depression, modified by vertical post‐Late Neogene tectonic movements within the still active fault escarpment. According to these altitudes, a 50 to 250 m uplift of the western margins of the depression since the Late Miocene to Early Pliocene is inferred.  相似文献   

7.
Sur‐les‐Creux rockshelter is located in the Prealps of southwestern Switzerland. The sequence of deposits in the rockshelter is 80 cm thick and consists of weathered gravels in a phosphate‐rich matrix. A few Middle Palaeolithic artifacts and the bones of cave bear (Ursus spelaeus) were recorded in the fill. We present the results of sedimentological, geochemical, and micromorphological analyses of the rockshelter sediment. All analyses suggest an endokarstic origin of the sediments. The alteration cortices of the gravels imply in situ weathering over a long period. The phosphates are essentially biogenic and have an apatitelike nature. Phosphatization and intense mixing of the sediment are attributed to cave bear (digging of lairs, input of excrements, and carcasses). Only rare carnivore coprolites (lynx) were preserved in the cave deposits. © 2004 Wiley Periodicals, Inc.  相似文献   

8.
《Quaternary Science Reviews》2007,26(19-21):2526-2543
Occasional excavation of in situ and ex situ deposits at the formerly mined Gondolin paleocave system has yielded large and diverse samples of Plio-Pleistocene faunas, including isolated hominin and non-hominin primate remains. In 2003, new excavations into naturally decalcified, in situ sediments near the GD 1 datum point near the northwest corner of the cave system were undertaken. This paper describes the recovered faunal remains, taphonomy of the assemblage, and the geological and paleomagnetic context of the GD 1 deposits. The deposits represent a series of inter-stratified speleothem, in-washed sediments and talus deposits we suggest date to a time period prior to, and just after, the Olduvai normal-polarity event at around 1.7–1.8 Ma. Surface sediments and clasts were introduced into the cave by rain water runoff entering a vertically-oriented entrance that had formed along a rift in the area of GD 1. The faunal assemblage consists primarily of fragmentary diaphyseal fragments and isolated teeth. Taxonomically, the small collection of specifically identifiable bovid and equid fossils is generally consistent with remains previously excavated from in situ deposits in the Gondolin paleocave system (GD 2) and dated to around 1.8 Ma; however, the depositional histories of these two assemblages from Gondolin are remarkably different. The preservation and relative proportions of recovered skeletal elements at GD 1 is consistent with these materials having been initially accumulated outside the karstic system near the vertical cave entrance, and then later hydrologically sorted and deposited inside the cave. The sporadic to continuous water flow into the northwest corner of the cave system during the Pleistocene gradually decalcified the excavated fossilbearing breccias and further modified the composition and spatial distribution of the fossil assemblage by introducing potentially younger deposits and skeletal materials. This study highlights the variation in taphonomic processes that can occur within a single cave system, and the complex pre- and postdepositional geological and hydrological processes that can influence the taphonomic history of South African Plio-Pleistocene karstic fossil assemblages.  相似文献   

9.
Baiyun Cave in Naigu Shilin,Yunnan Karst,China   总被引:1,自引:3,他引:1  
The Baiyun cave is a 380 m long karst cave in the Naigu Shilin, situated 70 km southeast of Kunming, Yunnan Province, China. The prevailing orientations of the cave passages are N110°-120°E and N0°-10°W and those of the fissures in the cave are N30°-40°W and N20°-30°W. The cave is developed in the thick-bedded Lower Permian Qixia Formation. The cave has an active water flow and is currently at the near water-table stage. There are large amounts of different infills of cave sediments. The cave shows different stages of paragenesis. The palaeomagnetic analysis of cave sediments shows that their ages are younger than 780 ka B.P. (the Brunhes Chron). The upper part of the sampled profile belongs to the reverse Blake event (112.3-117.9 ka B.P.). The formation of the Baiyun cave is directly connected with the development of the Naigu Shilin. The formation of karst underground and surface features depends on the regional tectonic deformation and the Cenozoic extension of the study area.  相似文献   

10.
Comparisons of sedimentation rates obtained by 210Pb and pollen analyses of 1-m cores collected throughout the Potomac Estuary show good agreement in the majority of cores that can be analyzed by both methods. Most of the discrepancy between the methods can be explained by the analytical precision of the 210Pb method and by the exactness with which time horizons can be identified and dated for the pollen method. X-radiographs of the cores and the distinctness of the pollen horizons preclude significant displacement by reworking and/or mixing of sediments. Differences between the methods are greatest where uncertainties exist in assigning a rate by one or both methods (i.e., 210Pb trends and/or “possible” horizon assignments). Both methods show the same relative rates, with greater sediment accumulation more common in the upper and middle estuary and less toward the mouth. The results indicate that geochronologic studies of estuarine sediments should be preceded by careful observation of sedimentary structures, preferably by X-radiography, to evaluate the extent of mixing of the sediments. Time horizons, whether paleontologic or isotopic, are generally blurred where mixing has occurred, precluding precise identification. Whenever possible, two methods should be used for dating sediments because a rate, albeit erroneous, can be obtained isotopically in sediments that are mixed; accurate sedimentation rates are also difficult to determine where the time boundary is a zone rather than a horizon, where the historical record does not provide a precise date for the pollen horizon, or where scouring has removed some of the sediment above a dated pollen horizon.  相似文献   

11.
Chronological, sedimentological and geochemical analyses of a clastic infill from Kelly Hill Cave (5K1), Kangaroo Island, document a palaeoenvironmental record that spans from the Late Pleistocene to the middle Holocene. We AMS radiocarbon‐dated bone collagen and U–Th‐dated speleothem to determine that fossiliferous sediments were deposited between >20 ka and 7 ka ago. Most of the 15 sedimentary layers are dominated by sand‐ and silt‐sized quartz that is physically and geochemically comparable with surface soils in the Kelly Hill area. Late Pleistocene and Last Glacial Maximum strata are represented primarily by homogeneous, poorly sorted quartz‐rich sediments that contain little organic matter, but include a thin layer composed largely of silt‐sized clay pellets that resemble sediments deflated from playa lakes. Microstructures observed in petrographic slides indicate that, with the exception of one layer, all sediments experienced little reworking once deposited in the cave. Some layers display pedogenic microstructures such as redeposited clays and opaline silica infilling that indicate postdepositional modification; that is, cave‐floor soil development. Overlying Holocene‐aged sediments also consist mainly of quartz but have much greater organic matter content. Some of these sediments have been strongly influenced by re‐precipitated organic matter that appears to have been transported into the cave via vadose drip water. The presence of dissolved organic matter in soil/vadose waters suggests a high vegetation density and acidic soils, which are congruent with the more equitable climatic conditions characteristic of the Holocene. The sediments described here provide a valuable palaeoenvironmental record that will facilitate future interpretation of associated vertebrate fossils.  相似文献   

12.
Clastic sediments deposited in caves and rock shelters bear peculiar sedimentological characteristics and have seldom been considered as a high‐resolution proxy record of climatic or environmental changes. The Romito Cave has its entrance at 275 m above sea level, about 25 km from the Tyrrhenian coast of Calabria, southern Italy. New archaeological excavation performed since 2000 has revealed a sedimentary succession spanning the record of Gravettian to Late Epigravettian cultures (Late Pleistocene). The present study focuses on the lower part (2.5 m thick) of the succession, where three main unconformity‐bounded stratigraphic units have been recognised (labelled RM1–3). Each unit consists of water‐lain deposits indicating high‐ to low‐competence flow, capped with anthropogenic deposits. The gradual deactivation and reactivation of the water drainage between 23 475 ± 190 and 16 250 ± 500 cal. a BP is correlated with regional precipitation changes due to the onset of dry climatic conditions of the Last Glacial Maximum. However, the deactivation of cave drainage after the deposition of unit RM3, around 15 400 ± 500 cal. a BP, deviates from the regional hydrological trend of progressively increasing water discharges and is attributed to the drainage cut‐off by probable cave wall collapses. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

13.
As with many terrestrial areas, the British Quaternary sequence is characterised by incomplete, fragmentary records, whose correlation is based on stratigraphic or biostratigraphic techniques due to the lack of radiometric ages beyond the ~40 kyr limit of 14C dating. Speleothems (secondary cave calcite deposits) offer a significant advantage over many sources of palaeoenvironmental information; they can be dated to a high precision and accuracy by uranium‐thorium (238U‐230Th) thermal ionisation and inductively coupled plasma (ICP) mass spectrometry in the time period back to 500 kyr. They may also contain sufficient well‐preserved pollen representative of contemporary vegetation above the cave to allow palaeoenvironmental reconstruction. This study adopts the novel approach of combining pollen and thermal ionisation mass spectrometric (TIMS) U‐Th dating of British speleothems to produce well‐constrained palaeoenvironmental records. We report for the first time precisely dated records of pollen assemblages from speleothems suggesting the presence of thermophilous arboreal species in phases previously considered to have been consistently cool or cold and devoid of trees. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

14.
岩溶旅游洞穴碳酸盐岩沉积物景观容易受到污染、风化,为了探讨受污损洞穴碳酸盐沉积物的修复方法以确保岩溶旅游洞穴的可持续发展,对广西桂林七星岩No.15支洞距洞口约150 m长洞段的滴水物化指标、现代碳酸盐岩沉积物进行了为期4年的监测分析。结果表明:(1)该洞段的滴水主要源于抽取地下河水的水柜渗漏及降水补给,地下河水和滴水的电导率、[Ca2+] 、[HCO3-]在4个水文年中的变化趋势基本相同,雨季洞穴滴水电导率、[Ca2+] 、[HCO3-]等显著降低,降雨稀释效应明显;(2)现代洞穴碳酸盐岩沉积具有明显的季节性变化,雨季洞穴滴水量/速率、碳酸钙沉积速率加快,最大沉积量达0.8 g/半月,洞穴入口约150 m长洞段快速滴水碳酸盐最大沉积量达2~4 g/半月,旱季碳酸盐沉积速率减少,最大沉积量仅为0.4 g/半月;(3)抽取岩溶地下水经由地表补给洞穴滴水可提高滴水的电导率、[Ca2+] 、[HCO3-]及CaCO3饱和度,促使大量碳酸盐(CaCO3)快速沉积,实现对洞穴受风化、污染景观的修复,新沉积的碳酸钙(CaCO3)还可以将基岩裂隙和洞穴内破损、破裂的钟乳石重新“粘结”起来,利于洞穴的稳定性。   相似文献   

15.
Recent sedimentological and palynological research on subfossil Holocene banded sediments from the Severn Estuary Levels suggested seasonality of deposition, registered by variations in mineral grain‐size and pollen assemblages between different parts of the bands. Here we provide data that strengthen this interpretation from sampling of modern sediments and pollen deposition on an active mudflat and saltmarsh on the margin of the Severn Estuary, and comparison with a vegetation survey and contemporary records of climate, river and tidal regimes. The results of grain‐size analysis indicate deposition of comparatively coarse‐grained silts during the relatively cool and windy conditions of winter and comparatively fine‐grained sediments during relatively warm and calm summer months. Pollen analysis demonstrates the significance of long‐term storage of pollen grains and fern spores in the estuarine waterbody, superimposed on which seasonal variations in pollen inputs from local and regional vegetation remain detectable. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

16.
We provide geochemical analyses and grain size data for a clearly layered, 80 cm thick sedimentary deposit close to a roof collapse in Blanche Cave near Naracoorte in SE South Australia. This deposit contains aeolian material deposited between 40 ka and 14 ka cal BP and which yields airborne sediments spanning the Last Glacial Maximum, a period of time with little information for the Australian continent. The deposit also contains abundant vertebrate fossil material derived from owl pellets, accumulation and pitfall entrapment. Below the studied profile, large vertebrate remains are found but are not discussed here. No Holocene sedimentation occurred at the site examined in the cave, and the top of the sequence is capped with a layer that has been anthropologically disturbed and contains exotic Pinus pollen. Chronologies of the deposit were obtained using two dating techniques: single stage accelerator mass spectrometer (SSAMS) 14C analysis of 23 charcoal samples and optically stimulated luminescence (OSL) dating of quartz from 6 sediment samples. The 14C chronology is preferred to describe the history of the deposits since the OSL chronology, which consistently overestimates the associated radiocarbon dates, may be inaccurate due to complexities in calculating dose rates, and may in addition represent the timing of sediment deposition through the cave opening rather than sediment transport to the deposit site. Morphological analysis of single quartz grains and grain size analysis indicate different provenance that is confirmed through the geochemical analyses of bulk sediment. Major elements were measured by X-ray Fluorescence (XRF), trace and rare earth elements by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA ICP-MS), and Neodymium isotopic ratios were obtained using a Thermal Ionisation Mass Spectrometer (TIMS).Our results indicate that the aeolian material deposited in Blanche Cave over the 40–14 ka cal BP period originated from different sources across South Australia, although Nd isotopes clearly indicate a close association with sediments of the Kanmantoo Group outcropping along the eastern portion of the Mount Lofty Ranges and the Padthaway Ridge further south, both being located to the NW and NNW of the cave. During the latter part of Marine Isotope Stage 3, conditions were wetter and windblown sediment came from the coastal region just north and south of the Coorong Lagoon, with winds originating from the north-northwest. At that time, woody taxa appear to have vegetated the landscape. During the drier phases, especially the Last Glacial Maximum, sediment came from further inland, thus suggesting a different predominant wind direction, more from the northwest. The deglaciation saw material originating from a more northerly direction.  相似文献   

17.
The chemical index of alteration has been used widely for reconstruction of the palaeoclimate. However, the mechanisms and environmental factors controlling the chemical index of alteration of sediments are not yet fully understood. In this study, autocorrelations of the chemical index of alteration in nine sedimentary profiles, from both the land and the sea, spanning different geological times, are discussed. The sediments of these profiles have different origins (dust, fluvial or ocean sediments) and are from various climate situations and sedimentary environments. Autocorrelations of chemical index of alteration series are ubiquitously evident in all profiles. It is suggested here that autocorrelations may be caused by post‐depositional changes such as persistent weathering and diagenesis. As a result, the chemical index of alteration may not reflect climatic conditions during the time of sediment deposition. This study strongly recommends the confirmation of the reliability and veracity of the chemical index of alteration before it is adopted to evaluate the weathering degree of parent rocks and to reconstruct the past climate. Significant autocorrelations in loess profiles were specifically observed, suggesting that the existing understanding of loess deposition in terms of climate conditions requires re‐examination, and that previous reconstructions of rapid climate changes (for example, in centennial‐millennial scales) should be treated with caution.  相似文献   

18.
A detailed geomorphological study was performed in the Atxurra-Armiña cave system (northern Iberian Peninsula) to decode landscape evolution, palaeoenvironmental changes and human use of a cave within an Inner Archaeological Context. The results show an average incision rate of the river of <0.083 mm a–1 for at least the last 419 ka, with interruptions due to sedimentary inputs. Moreover, allostratigraphic units comprising fluviokarstic deposits at the base and flowstone formation at the top have been shown to be climatically controlled, formed either during glacial–interglacial cycles or during interstadial cycles. Finally, when the cave was used by humans in the Late Magdalenian, the lower entrance was closed, and they must therefore have entered the cave through the upper entrance. To reach the sectors selected to decorate the panels, they probably travelled from the upper cave level, as the current crawlway was wider than today, according to our U/Th dating. Once these visitors reached the panels, the floor in the main gallery would have been around 15 cm lower than at present. However, the morphology of the conduit was similar; this has significant implications for understanding and interpreting the human use of the cave during the Palaeolithic.  相似文献   

19.
Dolomitization often plays a critical role in the pore network development of platform carbonates, with implications for reservoir quality distribution. Understanding both the hydrological system driving dolomitization and the chemistry of the fluids involved is fundamental to constrain predictions of the geometry and the petrophysical properties of dolomite bodies. Here, the role of secular variations in seawater Mg/Ca as a control on dolomitization and early porosity modification was evaluated using one‐dimensional reactive transport models and fluids based on modern (aragonite sea), Mississippian and Aptian (calcite sea) seawaters. The sensitivity of dolomitization to a range of extrinsic controls (brine salinity, temperature, fluid flow rate and pCO2) and to intrinsic reactivity of the sediments (effective reactive surface area) was also explored. Simulations suggest faster calcite replacement by dolomite for seawaters with higher Mg/Ca, indicating that dolomitization potential is determined more by Mg/Ca rather than saturation index. Increasing evaporative concentration enhances reaction rate independent of the effect of enhanced density‐driven fluid flux. In addition to brine composition, effective surface area of precursor sediments and temperature exert a critical control on replacement rate, while secular variations of pH and carbonate alkalinity associated with changes in pCO2 are only secondary controls. Above flow rates of 0·01 m yr?1 replacive dolomitization is reaction‐limited rather than flux limited, favouring alteration of fine‐grained carbonates and suggesting that preferential alteration of grainstone units is rare unless head gradients are low. Post‐replacement dolomite cementation is flux dependent, and thus favoured in areas of high head gradient and high permeability sediments and, contrary to replacement, supersaturation is a more important driver than Mg/Ca. While uncertainties remain regarding low‐temperature dolomitization kinetics, the capability of numerical simulations to decouple individual controls provides new insights which can be used, in conjunction with traditional comparative sedimentology, to generate more rigorous conceptual models for individual reservoir settings.  相似文献   

20.
介绍了广西乐业县大石围天坑群中蚂蜂洞、里郎洞新第三纪堆积孢粉组合特征,并由此探讨了大石围天坑四层不同高程上的洞穴的发育时代。蚂蜂洞和里郎洞新第三纪堆积是迄今广西所发现的海拔高程最高的第三纪地质剖面,其孢粉主要以被子类桤木粉属( Alnipollenites )、栎粉属( Quercoidites )、桦粉属( Betulaepollenites )、栗粉属( Cupuliteroipollenites ) , 裸子类双束松粉属( Pinuspollenites ) , 蕨类水龙骨单缝孢属( Polypodiaceaaesporites )、桫椤孢属( Cyathidites )为主,反映当时主要为亚热带温暖、阴湿的森林气候环境。根据与蚂蜂洞的相对位置,推测较之高的南东支洞、最高层洞形成时代应早于新第三纪,比之低的中洞应形成于早— 中更新世,而地下河则在全新世时期形成。   相似文献   

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