Large-scale bedforms along a tideless outer shelf setting in the western Mediterranean

High-resolution multibeam swath-bathymetry and sediment samples were collected across the outer shelf region of the Columbretes Islands (southern Ebro continental shelf, western Mediterranean Sea). Bathymetric data from the submerged part of the Columbretes volcanic system revealed the presence of three main relict sand bodies along the outer shelf, at 80–116 m depth range, above which asymmetric and slightly asymmetric large and very large 2D and 3D subaqueous dunes were observed. These bed features were recognized, mapped and quantified with the aim of evaluating their potential formation mechanisms in relation to the local hydrodynamic and morphologic settings of the area. Dunes range from 150 to 760 m in wavelength and from tens of centimeters to 3 m in height, and are among the longest ever recognized in an outer shelf region. These bedforms are mostly composed of medium-sized sandy sediments, presumably coming from the degraded relict sand bodies on top of which they have developed, mixed with fine fractions from the recent draping holocenic sediments. The orientation of the dunes is SSW, progressively turning W towards the southernmost sector of the area, following the trend of the shelf-edge. Contemporary hydrodynamic measurements at the Ebro continental shelf-edge show that recorded currents are insufficient to form the observed bedforms and that stronger currents are required for sediment mobilization and dune formation. Based on their morphology and orientation, it is proposed that these bedforms are produced by the action of the southward-flowing Liguro-Provençal-Catalan (LPC) geostrophic current. The LPC probably reaches high near-bottom currents during energetic hydrodynamic events through interactions with the seafloor morphology of the study area. Subaqueous dunes are expected to be basically inactive features with respect to present-day processes, although they can be reactivated during high-energy events. The small Δh/λ ratio measured in the dune fields of the Columbretes shelf revealed that the dune heights fall below the values predicted by the Flemming (1988) global equation, as observed in other outer shelf settings also dominated by unidirectional flows. This may suggest a different morphodynamic character of large dunes formed on outer shelves in a micro-tidal regime.     

Seafloor evidence for ice shelf flow across the Alaska–Beaufort margin of the Arctic Ocean

New imagery of ～14 100 km² of seafloor along a 640 km stretch of the Alaska and Beaufort margins (ABM) in water depths from 250 to 2800 m depicts a repetitive association of glaciogenic bedforms (lineations and iceberg scours), broad erosional bathymetric features and adjacent downslope turbidite gullies. These bedforms have styles, depths and orientations similar to features discovered earlier on the Chukchi Borderland, up to 800 km northwest of the ABM. Lineations occur across the surface of a flattened bathymetric bench interpreted to have formed by an ice shelf sliding along the continental slope and scraping the seafloor at temporary grounding locations. The glacial geology of surrounding areas suggests that an ice shelf probably flowed from the mouths of overdeepened glacial troughs in the Canadian Arctic Archipelago westward along the ABM and across the Chukchi Borderland. This curved pathway indicates an obstruction to ice flow in the central Canada Basin, possibly caused by either a basin‐wide ice shelf or by a pile‐up of mega‐bergs originating from the Eurasian side of the Arctic Ocean. The ice shelf that affected the ABM may have formed between Oxygen Isotopic Stage 4 to 5b, possibly correlating to an inferred intra‐Stage 5 widespread Beringian glaciation. Evidence for glaciogenic features on the ABM corroborates suggestions that large ice volumes and extents existed in the Arctic during Pleistocene glacial periods. These findings have far‐reaching implications for Arctic climate studies, ocean circulation, sediment stratigraphy and the stability of circum‐Arctic continental ice masses. Copyright © 2007 John Wiley & Sons, Ltd.     

Pollen record of the last 280 ka from deep sea sediments of the northern South China Sea

Environmental history of the northern continental shelf of the South China Sea during the last 280 ka BP, e.g. Marine Isotope Stages 1–8 (MIS 1–8) was reconstructed based on pollen record from the top 225m of ODP 1144 Site. During the interglacial periods, pollen assemblages are predominated by pine similar to those of the present day indicating that the environment of the interglacial periods was more or less close to that of today. Nevertheless, those from glacial periods are characterized by a large amount of herbaceous pollen, e.g.Artemisia, Gramineae, Cyperaceae, etc. inferring that grassland covered the merged continental shelf when the sea level lowered and the continental shelf was exposed. The exposed areas of the shelf were insignificant before MIS 5, but enlarged since MIS 4 and reached its maximum during MIS 2 according to ratios of pollen percentages between pine and herbs. The history of different exposure of the shelf can be compared with transgression records of the coastal areas of China and might result from neotectonic movement of Chinese continent. Some changes also took place in the components of grassland growing on the shelf during glaciations. Gramineae is the main element at MIS 8. ThenArtemisia increased upwards the profile and at last became the main component at the Last Glacial Maximum (MIS 2). Such changes in vegetation might be in response to cooler and drier climate.     

The sea-floor morphology of a Mediterranean shelf fed by small rivers, northern Alboran Sea margin

Depositional geometries and distribution patterns of shelf sediment wedges mainly derived from small rivers located in the northern margin of the Alboran Sea, Western Mediterranean Basin, are reported in this study, in order to understand: (1) their generation under particular physiographic and climatic conditions of river basins; (2) the interaction of shallow-water wedges with submarine valleys. A high amount of data has been used in this study, including river discharge and wave climate data, multibeam bathymetry, high-resolution seismic profiles and surficial sediment samples.The eastern shelf of the study area comprises the prodeltaic wedge off the Guadalfeo River and its eastward continuation, interrupted by the deeply indented Carchuna Canyon head. In contrast, the western shelf receives the contributions of a smaller river, the Verde River, whose associated prodeltaic wedge is limited to the inner shelf. Morphological features of both prodeltas are similar and differ from other Mediterranean prodeltaic bodies, resembling fan deltas. Those similarities include very steep foresets and bottomsets, very shallow and close to the coast offlap break, coarse sediment composition, lobate shape and common occurrence of crenulated sea floor. All these features point out to an origin linked to the activity of high-density sediment flows, rapid sedimentation and limited lateral redistribution. Those processes are favoured by the existence of an abrupt onshore physiography, a regional climate with a marked seasonality that conditioned torrential fluvial regimes and high availability of loose sand and gravel.Shelf sediment by-pass is a likely process during the Holocene in the eastern shelf, as suggested by the identification of two types of submarine valleys: (1) numerous gullies occur from the distal toe of the Guadalfeo River prodelta to the slope; (2) submarine canyon heads affect to the Holocene sedimentary wedge in the eastern sector of the study area. In the western shelf, however, the influence of shelf sedimentation processes on deeper domains is minimal, due to shelf widening, prevalence of relict features and absence of submarine valleys.     

Post-glacial sediment dynamics in the Irish Sea and sediment wave morphology: Data–model comparisons

The irregular seafloor of the narrow Irish Sea on the NW European Shelf has been documented over several decades. From recently collected swath bathymetry data, very large trochoidal, nearly symmetrical sediment waves are observed in many parts of the Irish Sea and appear similar to those described from other continental shelf seas in North America that were covered by glacigenic sediments during the Last Glacial Maximum. Swath multibeam and single beam bathymetry data, backscatter intensity, shallow seismic imagery, video footage and sediment cores from the Irish Sea high sediment waves have been integrated to identify their genesis with reference to present and past hydrodynamic variability. From cross-sectional profiles over asymmetrical sediment waves in the Irish Sea the direction of asymmetry is used to map residual bed stress directions and associated bedload transport paths. Irish Sea peak bed stress vectors were generated using a two-dimensional palaeo-tidal model for the NW European shelf seas and compare well with the observations. Tidally induced bed stresses are modelled to have increased between 7–10 ka BP, to be nearly symmetrical in magnitude and to have reversed in dominant direction on a millennial scale. These environmental conditions during the post-glacial marine transgression are suggested here to help comprehend the construction of the very large sediment waves, with local variations due to differences in sediment grain size, sediment supply, water depth and intensified currents due to seafloor slopes. Model parameterisation using an open ocean boundary with time-dependent tidal changes and the implementation of high-resolution bathymetric information will improve future models of small-scale bed shear stress patterns and improve the predictive value of such modelling efforts.     

Dense shelf water cascades and sedimentary furrow formation in the Cap de Creus Canyon,northwestern Mediterranean Sea

To investigate the processes by which sediment is transported through a submarine canyon incised in a continental margin affected by recurrent dense shelf water cascading events, several instrumented moorings were deployed in the Cap de Creus Canyon from September 2004 to September 2005. This was done as part of the EuroSTRATAFORM Program that investigated sediment transport and accumulation processes in the Gulf of Lions. Results obtained in this observational study confirm that major cascading events can effectively contribute to the rapid export of sediment from the shelf and upper slope to deeper environments, and suggest that the associated strong currents carrying coarse particles are able to erode the canyon floor and generate sedimentary furrows. During winter 2004–2005, persistent northerly winds and the absence of river floods contributed to decrease the buoyancy of coastal waters and to dramatically enhance the intensity of dense shelf water cascades in the Gulf of Lions. Under such conditions, cascading continuously affected the entire Cap de Creus upper canyon section for more than a month and sustained cold temperatures and down-canyon steady currents >60 cm/s (up to 100 cm/s), showing periodic fluctuations that lasted between 3 and 6 days. Increases in suspended sediment concentrations were associated with dense shelf water cascading outbursts, but the magnitude of the concentration peaks decreased with time, suggesting a progressive exhaustion of the resuspendable sediments from the shelf and canyon floor. Grain size analyses of the particles caught by a near-bottom sediment trap show that dense shelf water cascades are able to transport coarse sediments (up to 65% sand) in suspension (and presumably as bed load), which have the potential to abrade the seafloor and generate erosive bed forms. The orientation of a large field of “wide” (i.e., widths about 1/2 spacing indicative of erosive formation) sedimentary furrows recently observed in the Cap de Creus Canyon clearly coincides with the preferential direction of highest velocities measured by the moored current meters, indicating a causative relationship between contemporary dense shelf water cascades and furrow formation.     

Wave- and current-induced bottom shear stress distribution in the Gulf of Lions

Simulations of both currents and waves were performed throughout the year 2001 to assess the relative contribution of each to their overall erosive potential on the Gulf of Lions shelf. Statistical analysis of bottom shear stress (BSS) was compared to sediment grain-size distribution on the bottom. The hydrodynamic features of the bottom layer coincide with the distribution of surficial sediments, and three areas with different hydro-sedimentary characteristics were revealed. (i) The sandy inner shelf (<30 m) area is a high-energy-wave dominated area but may be subjected to intense current-induced BSS during on-shore winds along the coast and during continental winds mainly in the up-welling cells. (ii) The middle shelf (30–100 m) is a low-energy environment characterised by deposition of cohesive sediments, where the wave effect decreases with depth and current-induced BSS cannot reach the critical value for erosion of fine-grained sediments. (iii) The outer shelf, which has a higher bottom sand fraction than the middle shelf, may be affected by strong south-westward currents generated by on-shore winds, which can have an erosive effect on the fine-grained sediments.     

Sediment mass and distribution in the South China Sea since the Oligocene

The sediment macro-distribution patterns and their evolutionary characteristics in the South China Sea (SCS) are discussed based on a quantification of the sediment mass from the be- ginning of seafloor spreading in the Oligocene to the Present. Above the pre-Oligocene base, the total sediment mass for the whole SCS is estimated to be 1.44×1016 t, with the highest average accumulation rate of ~22 g·cm-2·ka-1 in the Oligocene. Having no large abyssal fans but fast accumulation in sedimentary basins on the continental shelf and slope, the SCS shows quite different sedimentary characters not only from the open ocean but also from small backarc basins along the marginal West Pacific, apparently controlled by the coupling between local tectonics and global climate changes.     

Records of natural fire and climate history during the last three glacial-interglacial cycles around the South China Sea Charcoal record from the ODP 1144

The history of natural fire and its relationship to climate during the last three glacial-interglacial cycles in the Southern coast areas of China and the northern continental shelf of the South China Sea (SCS) are discussed based on the statistic study of charcoal particles and associated pollen data from ODP 1144 Site (20° 3′N, 117° 25’E, 2037 m in water depth). According to the results of the charcoal and pollen study, the sediments from the upper 225 m are divided into 8 zones (C1–C8), which might be correlated with the Marine Isotope Stage 1–8 (MIS1-8) respectively. Our study indicates that during the last glacial period (MIS2, 4), the influx of charcoal particle was much higher than that from the interglacial period, suggesting strong occurrence of natural fire and dry climate. During MIS 6 and MIS 8 (C6, C8), although the influx of fine charcoal particles was quite high, the influx of the coarse and medium charcoal particle were much low, which might be due to the smaller source area of fire probably resulting from the limited exposure of the continental shelf before MIS5. During the interglacial period (MIS1, 5, 7), the influxes of charcoal particles were much lower, implying dropping of intensity of the natural fire and then a humid climate. Another reason is that the continental shelf was submerged into the sea during the interglacial periods, and the source areas of fire were reduced then. Although the influx of the fine charcoal particles was much lower during MIS3, the influx of the coarse and medium charcoal particles were almost equal to those of MIS4 (C4), which suggests that the intensity of the natural fire remained quite high and the climate was considerably dry during that period.     

High-Resolution Seismic Characterization of Shallow Gas Accumulations in the Southern Shelf of Marmara Sea,Turkey

High-resolution seismic survey was conducted to investigate acoustic characteristics of gassy sediments along the southern shelf of the Sea of Marmara. The acoustic turbidity zones outlined within the study area are generally below 2–9 m (2-10 ms TWT) the seafloor whilst this vertical distance varies between 9 and 21 m (10–25 ms TWT) for acoustic blanket type reflections. The gassy sediments cover an area of sea floor of about 45, 110, and 75 km² in front of Gönen River, Kocasu River, and Gemlik Bay, respectively. The gassy sediments in the center of Gemlik Bay exhibited an elliptical geometry similar to its basin while the others have deltaic forms in front of the rivers. The sea bottom and near surface sedimentary units are made-up of organic-rich sediments, mostly transported by the southern rivers. The gas observed in sediments is thought to be of biogenic origin, which may be caused by degradation of organic matter in the sediment.     

南海北部琼东南海域活动冷泉特征及形成模式

近年来,活动冷泉的研究越来越受到关注.本文利用多波束数据、多道地震数据以及底质取样结果研究琼东南海域活动冷泉系统,分析活动冷泉的羽状流特征、海底地貌与底质特征以及流体活动构造特征.多波束水体数据上,观测到多个延伸高度超过750 m的气泡羽状流,海底流体活动非常强烈;多道地震上识别出麻坑、流体运移通道、气烟囱等流体渗漏相关的构造,与其他海域观测到的反射特征不同,羽状流的下方流体运移通道呈强振幅"串珠"反射;重力活塞取样在两个站位上获得浅表层块状天然气水合物.其中一个站位位于活动冷泉附近,天然气水合物赋存于海底以下8 m左右.基于以上三方面的数据,笔者提出了一个用于描述活动冷泉系统的形成模式,游离气通过气烟囱向上运移到达浅层,一部分在天然气水合物稳定带内形成天然气水合物,另一部分穿透天然气水合物稳定带到达海底,形成活动冷泉的羽状流.     

Sedimentary indicators of water movement in the western approaches to the English Channel

The continental shelf to the southwest of the British Isles is an area of intense tidal current activity. Although most of the sediment is coarse, it still contains a small proportion of fine (<63 μm) material, consisting mainly of biogenic debris. Coccoliths in particular are both common and widespread and they are found in the adjacent slope sediments. The results presented here show that coccolithophorid diversity is high in the deeper parts of Whittard Canyon, the abyssal plain, and on a small area of shelf. Diversity decreases away from the ocean towards the land. Coccoliths and coccospheres have also been recorded from surface water samples. Apart from the landward movement of oceanic water shown by the coccolithophorids, movement of material on the bottom from shelf to slope is shown by the distribution of benthic diatom frustules and mollusc shell chips cut by clionid sponges. Thus, a study of the fine sediment reveals details of sediment transport and water movement.     

深海海底沉积物声学特性原位测量试验研究

由于实验室测试环境条件与深海海底的原位温压环境存在较大的差异,取样测量的沉积物声学参数通常偏离海底原位状态的真实值.该文利用深水型压载式沉积声学原位测量系统,在水深超过5000 m的西太平洋海域开展了沉积物声学原位测量试验,准确获取了深海底原位状态下沉积物的声速和声衰减系数,并同步采集了沉积物柱状样品.结果显示,实验室测量的沉积物声速、声衰减系数均高于原位测量结果.通过温压校正和数据—模型对比表明,实验室声速比与原位声速比存在较大的差异,难以通过温压校正模型和频散模型完全改正,这可能与深海沉积物的结构扰动有关.较之浅海沉积物,软弱的深海沉积物结构更易受到采样过程的扰动,因而深海沉积物的声学特性测量更为困难,这表明在深海海底声学研究采用原位测量技术具有必要性.该研究标志着我国海底声学研究由浅海走向深海,对推动海底声学的深入研究具有重要意义.     

A simple method to analyse non-cohesive sediment mobility in coastal environment

This paper presents a method to investigate the relative influence of waves, wind-induced currents and tidal currents on sediment mobility in coastal environment. It is based on the assumption that, knowing high uncertainties linked to sediment dynamics studies, simple sediment mobility indicators are sufficient tools to provide useful information. This method is based on five main steps: (1) assessing hydrodynamic conditions and related errors spatially and temporally for an area; (2) evaluating the bottom shear stress induced by these hydrodynamic conditions; (3) providing simple sediment mobility indicators; (4) analysing the sensitivity of these indicators to the existing hydrodynamic uncertainties; (5) interpreting indicators knowing their limits (identified in the sensitivity analysis). This methodology is applied to a test site on the inner shelf, seaward of the Pertuis Charentais region in France. Using wave (SWAN) and sea-level and currents (MARS-2DH) modelling, we study the spatial distribution of the relative contribution of waves, tides and wind-induced current in the non-cohesive sediment mobility under storm conditions. The deduced sediment dynamics indicators reveal the dominant action of waves in sediment initiation in the offshore area, in water depths of up to 60 m. The sensitivity study, performed in order to evaluate the validity of results, shows that the sediment mobility indicators still provide relevant information, even for hydrodynamic uncertainties of ±20% or furthermore when only a qualitative sedimentological knowledge of the area is available.     

Preliminary Map of Soil's Predominant Periods in Barcelona Using Microtremors

—?In order to evaluate soil effects in the urban area of Barcelona, the Nakamura's technique has been used to estimate the predominant periods of soils. Noise measurements for 195 sites were performed using a strong motion accelerograph and a velocimeter. In this work, the resulting preliminary map of predominant periods is presented. The obtained predominant periods are coherent with the geological and geotechnical features of the area. The analysis of the information has allowed the distinctions among several types of soil and underlying materials. A predominant period of about 0.06?s is evaluated for sites located over outcrop Paleozoic rock in the Tibidabo-Collserola Mountains. For sites consisting of material named tricycle, that is the most extensive and also the most heterogeneous zone, predominant period range from 0.10?s up to 2.0?s depending on the thickness of the surface materials and the kind and thickness of the underlying materials. In the Besós river two zones are observed: the riverside with periods between 0.50?s and 0.83?s and a second area with periods between 1.0 and 2.1?s. In the Llobregat river delta the obtained periods are quite homogeneous with values around 0.72?s. Other predominant periods are found in some tertiary rock outcrop.     

张裂型盆地地热参数的垂向变化与琼东南盆地热流分布特征

海洋热流数据是开展海洋地球动力学研究和油气资源评价的基础数据.为深入认识琼东南盆地的地热特征,本文首先利用耦合沉积作用与岩石圈张裂过程的数值模型分析了张裂型盆地主要地热参数的垂向变化特征;并通过钻孔资料的详细分析,获得了琼东南盆地44口钻孔的热流数据;结合海底地热探针获取的热流数据,对琼东南盆地地热特征及其主要影响因素进行了简要分析.结果表明:沉积作用的热披覆效应对表层热流有较明显的抑制作用,由于沉积物生热效应与披覆效应的共同作用,同一钻孔处海底表层热流与钻孔深度3000~4000m处热流或与海底间的平均热流差异很小,可以一起用于分析琼东南盆地的热流分布特征;莺歌海组、乐东组热导率随深度变化小于黄流组及其下地层热导率的变化,钻孔沉积层平均热导率约为1.7 W·(m·K)-1,钻孔地层生热率一般低于2.5μW·m-3,平均生热率为1.34μW·m-3,平均地温梯度主要介于30~45℃/km,热流介于50~99mW·m-2,陆架区热流主要集中于60~70mW·m-2,深水区钻孔具有较高的地温梯度和热流值;从北部陆架与上陆坡区往中央坳陷带,热流值从50~70mW·m-2,增高为65~85mW·m-2,并且往东有升高趋势,在盆地东部宝岛凹陷、长昌凹陷与西沙海槽北部斜坡带构成一条热流值高于85mW·m-2的高热流带.进一步分析认为,琼东南盆地现今热流分布特征是深部热异常、强烈减薄岩石圈的裂后冷却作用、晚期岩浆热事件、地壳与沉积层的生热贡献以及沉积作用的热披覆效应等多种主要因素综合作用的结果.     

Sediment characteristics and internal architecture of offshore sand ridges on a tideless continental shelf (western Mediterranean)

An integrated approach combining swath bathymetry, an extensive dataset of vibrocores and high-resolution seismic reflection data was used to assess the origin and evolution of offshore sand ridges on a tideless continental shelf (Gulf of Valencia, western Mediterranean). The sand ridges are located in the mid-outer shelf at 55–85 m water depth, obliquely oriented to the shoreline. They are 1.5 to 7 m high, with a wavelength between 600 and 1,100 m and a mean height-to-wavelength ratio of 0.004. The sand ridges are composed of well-sorted medium sand and are partially covered by a mud layer, evidencing a moribund stage. They overlie an erosion surface that locally crops out at the seafloor and is interpreted as the Holocene wave-ravinement surface. In the sediment cores, this surface corresponds to an erosional lag composed of coarse sand and gravel with pebbles. Small topographic irregularities on this surface are interpreted as shoreline-associated features that may act as the precursor for ridge development. Their preservation within the sand ridges could be related to the hardness of these features. Internally, the sand ridges display high-angle dipping reflections, indicating ridge migration towards the southeast in the direction of the present-day sediment transport direction. The presence of interbedded mud layers, associated with these reflections, indicates intermittent episodes of mud deposition when active. The internal architecture of some small ridges also provides new insights into their transition from an active to moribund state, as evidenced by a change in the geometry of the internal units from progradational to aggradational, finally being overlain by onlapping finer deposits over the flanks and in the troughs. The Gulf of Valencia sand ridge field constitutes a valuable potential sand resource of 22 million m³ of well-sorted medium and coarse sand with limited mud content, which must be preserved as a strategic sand reservoir. © 2020 John Wiley & Sons, Ltd.     

Mechanisms leading to the frequent occurrences of hypoxia and a preliminary analysis of the associated acidification off the Changjiang estuary in summer

Based on literature data and shipboard observations, this study investigated the main environmental characteristics of the seafloor topography, current field, front, and upwelling that are closely related to hypoxia occurrence off the Changjiang estuary. The physical processes of the plume front and upwelling off the Changjiang estuary in summer were coupled. The vertical distribution pattern of the plume front was closely related to the upwelling. By reviewing and analyzing the historical summer hypoxia events off the Changjiang estuary, we statistically demonstrated the spatial structure of the horizontal distribution of the hypoxic zone and investigated the location of occurrence zone of the hypoxia. We found that the dissolved oxygen (DO) concentration on the inner continental shelf off the estuary showed a “V” shape in relation to station depth. Therefore, we noted that the hypoxic water on the inner continental shelf mostly occurred on the slopes with steep seafloor topography. Base on the current understanding of the hypoxic mechanisms off the Changjiang estuary, we analyzed the biogeochemical mechanisms that could cause the steep terrain off the Changjiang estuary to become the main areas prone to summer hypoxia and explained the internal relations between the location of the hypoxic zone on the slopes and the plume front and upwelling. The plume front and upwelling off the Changjiang estuary and their coupling were important driving forces of summer hypoxia. The continuous supply of nutrients affected by the interaction of the plume front extension of the Changjiang Diluted Water (CDW) and upwelling and the favorable light conditions were important mechanisms causing the phytoplankton blooms and benthic hypoxia off the Changjiang estuary in summer. By analyzing oxygen utilization, organic carbon mineralization, and nutrient regeneration in the hypoxic zone, we observed that the significant oxygen utilization process off the Changjiang estuary in summer also mainly occurred near the steep slopes with front and upwelling features and confirmed the apparent nutrient loss in the benthic hypoxic zone. Meanwhile, our analysis revealed that the sediment resuspension in the benthic boundary layer in the mud areas off the Changjiang estuary could also affect the oxygen utilization and mineralization of organic carbon and nutrient recycling and regeneration. This study also demonstrated that the steep terrain off the Changjiang estuary was the main location for summer acidification, and the coupling between the plume front and upwelling on the steep slopes was an important physical driving force inducing summer benthic acidification. Finally, we discussed issues to address in future studies of the hypoxic zone and water acidification off the Changjiang estuary.     

Mechanisms leading to the frequent occurrences of hypoxia and a preliminary analysis of the associated acidification off the Changiiang estuary in summer

Based on literature data and shipboard observations,this study investigated the main environmental characteristics of the seafloor topography,current field,front,and upwelling that are closely related to hypoxia occurrence off the Changjiang estuary.The physical processes of the plume front and upwelling off the Changjiang estuary in summer were coupled.The vertical distribution pattern of the plume front was closely related to the upwelling.By reviewing and analyzing the historical summer hypoxia events off the Changjiang estuary,we statistically demonstrated the spatial structure of the horizontal distribution of the hypoxic zone and investigated the location of occurrence zone of the hypoxia.We found that the dissolved oxygen(DO)concentration on the inner continental shelf off the estuary showed a"V"shape in relation to station depth.Therefore,we noted that the hypoxic water on the inner continental shelf mostly occurred on the slopes with steep seafloor topography.Base on the current understanding of the hypoxic mechanisms off the Changjiang estuary,we analyzed the biogeochemical mechanisms that could cause the steep terrain off the Changjiang estuary to become the main areas prone to summer hypoxia and explained the internal relations between the location of the hypoxic zone on the slopes and the plume front and upwelling.The plume front and upwelling off the Changjiang estuary and their coupling were important driving forces of summer hypoxia.The continuous supply of nutrients affected by the interaction of the plume front extension of the Changjiang Diluted Water(CDW)and upwelling and the favorable light conditions were important mechanisms causing the phytoplankton blooms and benthic hypoxia off the Changjiang estuary in summer.By analyzing oxygen utilization,organic carbon mineralization,and nutrient regeneration in the hypoxic zone,we observed that the significant oxygen utilization process off the Changjiang estuary in summer also mainly occurred near the steep slopes with front and upwelling features and confirmed the apparent nutrient loss in the benthic hypoxic zone.Meanwhile,our analysis revealed that the sediment resuspension in the benthic boundary layer in the mud areas off the Changjiang estuary could also affect the oxygen utilization and mineralization of organic carbon and nutrient recycling and regeneration.This study also demonstrated that the steep terrain off the Changjiang estuary was the main location for summer acidification,and the coupling between the plume front and upwelling on the steep slopes was an important physical driving force inducing summer benthic acidification.Finally,we discussed issues to address in future studies of the hypoxic zone and water acidification off the Changjiang estuary.     

Spatial distribution and ecotoxicity of petroleum hydrocarbons in sediments from the Galicia continental shelf (NW Spain) after the Prestige oil spill

The distribution of aliphatic and aromatic hydrocarbons was determined in surface sediments collected at 36 stations along the Galicia continental shelf (NW Spain), following the Prestige oil spill. Sampling was performed in December 2002, just after the accident, and in February and September 2003. Concentrations of PAHs (summation operator 13 parent components) were in the range of 0.9-422 microg/kgdw, the highest values being close to coastal urban areas (e.g. Pontevedra and A Coru?a), whereas in the stations of the area most heavily impacted by the spill (off Costa da Morte) concentrations were in the range of 14.8-89.6 microg/kgdw, with a certain predominance of alkylated compounds, which may suggest a mixture of petrogenic and pyrolytic sources. The detailed study of petrogenic molecular markers (e.g. steranes and triterpanes) showed the occurrence of an old (weathered) petrogenic chronic pollution in the shelf sediments but not of the Prestige oil, with the possible exception of few stations in the area of Costa da Morte. This was attributed to the heavy nature of the spilled oil that was barely dispersed in the water column and mainly stranded on the coast or sedimented in the form of oil patches. The addition of increasing amounts of fuel oil to a representative sediment sample showed that the molecular indices were indicative of the presence of the Prestige oil when the amount was above 1g/kg of sediment. The toxicity of selected samples (showing the higher PAH concentrations) was tested using the bivalve embryogenesis bioassay. Embryogenesis success reached high values in all cases (80-88%, with 86% in the control), indicating a lack of toxicity in the sediments and supporting the conclusion that the patchiness of the fuel eventually reaching the seafloor reduced its impact on the benthic communities of the Galician shelf.