Calcrete to kimberlite: A prospector’s hunt for “kimberlite traits” in calcretes

Occurrence of calcrete over kimberlite is known all over the world and calcrete can also develop over a wide variety of weathered rocks and/or soil under suitable condition of its formation. The objective of this study is to evaluate the mineralogy and mineral chemistry of kimberlite derived calcretes and highlights their role as an exploration tool in search of kimberlite. The present study reveals the presence of significant minerals, including diamonds, within the calcretes of “kimberlite traits”. Calcrete derived from granite and mafic (dolerite/gabbro) rocks are mineralogically very distinct with those derived from kimberlite. Calcrete can thus be a very useful prospecting tool in kimberlite and diamond exploration.     

The Nature of the “Voice of the Sea”

Strong vibrations of the Earth’s crust in the frequency range of 7–9 Hz, referred to as the “voice of the sea,” have been recorded in the course of processing synchronous experimental data obtained during recording of variations in the deformation of the Earth’s crust using a shore laser strainmeter, atmosphere pressure variations using a laser nanobarograph, and hydrosphere pressure variations using a laser meter for hydrospheric pressure and wind velocity variations. The nature of these vibrations and their transformation to adjacent geospheres have been discussed.     

The nature of terrestrial infragravitational “noise”

This paper is focused on analysis of comprehensive experimental research data on the infragravitational range of periods (from 20 s to 10–12 min) obtained by synchronous measurements of fluctuations in deformations of the Earth’s crust and atmospheric and hydrospheric pressure variations. It is established that the identified variations in the period range of 1–4 min are rarely observed in records of a laser nanobarograph and laser instrument for measuring hydrospheric pressure variations (laser hydrophone), while they are frequently observed in records of laser strainmeters at a variation period of 3–4 min. Oscillation excitation in the period ranges of 7–13 min, especially in the period ranges of 8–12 min, is largely related to atmospheric processes in the corresponding periods.     

The Nature of the Diamond Potential of “Cold” Paleogeotherms

It is known that the Р–Т parameters of diamond-bearing kimberlite xenoliths correspond to subductive paleogeotherms lying between the 36 and 41 mW/m² conductive models. There are some studies showing the correlation of diamond ability with oxygen fugacity and the fluid composition of mantle xenoliths. The most diamondiferous samples correspond to the water compositions of the calculated O–H–C fluid with a minimum atomic carbon content in it. From the calculations it follows that the fluid carbon atomic content increases with a temperature increase and with the pressure decreasing. The most minor C contents have the 35 mW/m² conductive model in comparison with the 40 and 45 mW/m² models. As a result, it is possible to conclude that the low temperature fields (less than 1100°C) of the “cold” geotherms have the highest diamondiferous ability.     

The “X component” of the radio background

The recent publication of evidence for a new mechanism producing background radio emission of the Galaxy at centimeter wavelengths (in addition to synchrotron radiation, free—free transitions in ionized gas, and the weak radio emission of standard dust) gave rise to a strong reaction among observers, and requires independent experimental verification. This signal is of special concern in connection with studies of the polarization of the cosmic microwave background (CMB) using new-generation experiments. We have derived independent estimates of the validity of the “spinning-dust” hypothesis (dipole emission of macromolecules) using multi-frequency RATAN-600 observations. Test studies in the Perseus molecular cloud show evidence for anomalous extended emission in the absence of strong radio sources (compact HII regions) that could imitate an anomalous radio spectrum in this region. A statistical analysis at centimeter wavelengths over the Ratan Zenith Field shows that the upper limit for the polarized noise from this new component in the spinning-dust hypothesis is unlikely to exceed 1 µK at wavelengths of 1 cm or shorter on the main scales of the EE mode of Sakharov oscillations. Thus, this emission should not hinder studies of this mode, at least to within several percent of the predicted level of polarization of the CMB emission.     

The system ilmenite–carbonatite–carbon in the origin of diamond: Correlation between the titanium content and diamond potential of kimberlite

Experimental studies of melting relations in the system ilmenite–K–Na–Mg–Fe–Ca carbonatite–carbon at 8 GPa and 1600°C provide evidence for the effect of liquid immiscibility between ilmenite and carbonatite melts. It is shown that the solubility of ilmenite in carbonatitic melts is negligible and does not depend on its concentration in experimental samples within 25–75 wt %. However, carbonatite–carbon melts are characterized by a high diamond-forming efficiency. This means that the correlation between the concentration of TiO₂ and diamond content is problematic for mantle chambers and requires further, more complex, experimental studies.     

The “Calamines” and the “Others”: The great family of supergene nonsulfide zinc ores

“Nonsulfides” is a term, which comprises a series of oxidized Zn(Pb)-ore minerals. It has also been used to define a special deposit type, mainly considered as derived from the weathering of Zn(Pb) sulfide concentrations. However, nonsulfide zinc deposits have been distinguished between supergene and hypogene, according to their mineralogy, geological characteristics and genetic setting. The supergene deposits formed by weathering and oxidation at ambient temperatures, whereas the hypogene ones are considered hydrothermal, or associated with metamorphic processes on primary sulfide ores.In this review paper, a comparison between a number of several nonsulfide deposits has been carried out: typical “Calamines”, peculiar “Calamines” and “Others”. The whole group comprises deposits of typical supergene origin, mixed supergene–hypogene mineralizations, and oxidized concentrations characterized by different metals only locally associated with zinc. The Zn–Pb nonsulfide concentrations hosted in carbonate rocks, which are mainly attributed to “wall-rock replacement” and “direct-replacement” supergene processes, are the typical “Calamines” (Liège district, Belgium; Iglesias district, Italy; Silesia–Cracow district, Poland). Peculiar “Calamine” deposits are those mineralizations that have been generally considered as supergene, but which are instead genetically related, at least partly, to hypogene processes (e.g. Angouran, Iran; Jabali, Yemen), though mineralogically and texturally similar to supergene nonsulfide deposits. The “Others” are prevailingly supergene nonsulfide zinc deposits not hosted in carbonate rocks (Skorpion, Namibia; Yanque, Peru), or characterized by other metals as main commodities, like lead (Magellan, Australia), silver (Sierra Mojada, Mexico; Wonawinta, Australia) or vanadium (Otavi Mountainland, Namibia).Minerals of current economic importance in most “Calamine” deposits are smithsonite, hydrozincite, and cerussite. This mineralogical association is generally simple but, when the “Calamines” are dolomite-hosted, one of the consequences of the “wall-rock replacement” process is the generation of a series of economically useless Zn- and Mg-bearing mixed carbonate phases. Secondary deposits hosted in silicatic (sedimentary or volcanic) rocks mainly contain hemimorphite and/or sauconite. Lead-, Ag- and V-rich nonsulfide ores are characterized by a more complex mineralogical association: mixed Pb-carbonates, Pb-sulfates, Pb-phosphates, Pb-arsenates, various Ag-sulfosalts, and Zn–Pb–Cu-vanadates.Carbon and oxygen stable isotope studies allow distinguishing between supergene and hypogene nonsulfide deposits, evaluating the effects of oxidative heating and even gaining indirect paleoclimatic information. The oxygen-isotope variation of the individual carbonate minerals within a deposit is relatively small, indicating constant formation temperatures and a single, meteoric fluid source. Carbon-isotope values are highly variable, thus suggesting several isotopically distinct carbon sources.Periods of paleoclimatic switch-overs from seasonally humid/arid to hyperarid have been considered as the most favorable conditions for the formation and preservation of supergene nonsulfide deposits. However, while several recent nonsulfide deposits throughout the world are positioned between 15° and 45° N latitude, thus pointing to a warm and humid weathering climate, others have been deposited in sub-Arctic regions.The economic value of the nonsulfide Zn(Pb–Ag–V) ores is highly variable, because more than in the case of metallic sulfide deposits, it resides not only on the geological setting, but also on their mineralogy that can directly influence processing and metallurgy.     

The phenomenon of “self-focusing” in the gaseous disk of the Galaxy

We consider perturbations in interstellar gas excited by the gravitational field of the spiral-density wave that is responsible for the Galactic arms, taking into account thermal effects. Under the conditions of fairly efficient cooling, the reaction of the gas to the perturbing field is non-trivial: the thickness of the gaseous layer is reduced in the region of the Galactic disk where the density of the gas is enhanced. We call this effect “self-focusing,” and explain it using observational results for the Galactic radio emission in the 21 cm line. Under our assumptions, we find the control parameter (δ) governing the relationship between perturbations of the thickness of the gaseous disk and the gas density in the vicinity of the Galactic equator, i.e., this parameter shows whether the correlation between these quantities is positive or negative, and provides important additional information on the thermal properties of the medium. It can be used as a diagnostic in joint studies of Galactic structure and large-scale features of the interstellar gas. Estimates for the typical Galactic parameters show that the effect of self-focusing should be clearly manifest in the Galaxy.     

The evaluation of “social risk” due to volcanic eruptions of Vesuvius

A re-evaluation of the demographic risk per number of inhabitants due to volcanic eruptions in the Vesuvius area was made on the basis of the Census data of 2001. We introduced other variables (population density and number of houses) which permit to upgrade the existing models. Using the Geographical Information Systems (GIS) and particularly ArcGIS 9.0 software we have elaborated a land use map, an urbanization map and a series of new risk maps which lead us to obtain a map of what we call “social risk” due to volcanic eruptions, derived from the combination of the data used and the overlay of the maps. We have proposed an integrated model which can be easily updated to follow the evolution of the volcanic risk in the overpopulated Vesuvius area, with the aim of supporting the planning of Civil Protection and Local Authorities, for an evacuation scenarios and the possibility of taking into account the potential infrastructural damages. This methodology can be tested in other volcanic regions.     

On the meaning of the terms “glaciation” and “interglacial” in the framework of studying paleoclimatic records from the Pleistocene continental and deep-water deposits

The terms “glaciation” and “interglacial” are considered from the point of view of palaeoclimatic proxies obtained from the Pleistocene deep-water and continental deposits. It is shown that the crucial factor in substantiation of these notions is determination of the cause-and-effect mechanism in the considered climatic oscillations. It is noted that oxygen isotope data on deep-water deposits have an undoubted advantage because a more accurate quantitative estimate of climatic oscillation parameters can be made on their basis. It is concluded that the role played by quantitative estimates of palaeoclimatic changes, represented by, first of all, amplitude and time characteristics of climatic oscillations, will become more significant as the methods of paleogeographic studies of both continental and deep-water deposits of the Pleistocene improve; in contrast, the formal determination of the rank of palaeoclimatic oscillations will become less significant. Special attention is paid to the cases of misfits between the Pleistocene deep-water and continental paleoclimatic records and to the necessity to make them consistently as good as possible, especially in the case of Early Pleistocene deposits.     

Melting phase relations of the Udachnaya-East Group-I kimberlite at 3.0–6.5 GPa: Experimental evidence for alkali-carbonatite composition of primary kimberlite melts and implications for mantle plumes

Experiments on the origin of the Udachnaya-East kimberlite (UEK) have been performed using a Kawai-type multianvil apparatus at 3–6.5 GPa and 900–1500 °C. The studied composition represents exceptionally fresh Group-I kimberlite containing (wt.%): SiO₂ = 25.9, TiO₂ = 1.8, Al₂O₃ = 2.8, FeO = 9.0, MgO = 30.1, CaO = 12.7, Na₂O = 3.4, K₂O = 1.3, P₂O₅ = 1.0, Cl = 0.9, CO₂ = 9.9, and H₂O = 0.5. The super-solidus assemblage consists of melt, olivine (Ol), Ca-rich (26.0–30.2 wt.% CaO) garnet (Gt), Al-spinel (Sp), perovskite (Pv), a CaCO₃ phase (calcite or aragonite), and apatite. The low pressure assemblage (3–4 GPa) also includes clinopyroxene. The apparent solidus was established between 900 and 1000 °C at 6.5 GPa. At 6.5 GPa and 900 °C Na–Ca carbonate with molar ratio of (Na + K)/Ca ≈ 0.44 was observed. The UEK did not achieve complete melting even at 1500 °C and 6.5 GPa, due to excess xenogenic Ol in the starting material. In the studied P–T range, the melt has a Ca-carbonatite composition (Ca# = molar Ca/(Ca + Mg) ratio = 0.62–0.84) with high alkali and Cl contents (7.3–11.4 wt.% Na₂O, 2.8–6.7 wt.% K₂O, 1.6–3.4 wt.% Cl). The K, Na and Cl contents and Ca# decrease with temperature. It is argued that the primary kimberlite melt at depths > 200 km was an essentially carbonatitic (< 5 wt.% SiO₂), but evolved toward a carbonate–silicate composition (up to 15–20 wt.% SiO₂) during ascent. The absence of orthopyroxene among the run products indicates that xenogenic orthopyroxene was preferentially dissolved into the kimberlite melt. The obtained subliquidus phase assemblage (Ol + Sp + Pv + Ca-rich Gt) at P–T conditions of the UEK source region, i.e. where melt was in the last equilibrium with source rock before magma ascent, differs from the Opx-bearing peridotitic mineral assemblage of the UEK source region. This difference can be ascribed to the loss of substantial amounts of CO₂ from the kimberlite magma at shallow depths, as indicated by both petrological and experimental data. Our study implies that alkali-carbonatite melt would be a liquid phase within mantle plumes generated at the core–mantle boundary or shallower levels of the mantle, enhancing the ascent velocity of the plumes. We conclude that the long-term activity of a rising hot mantle plume and associated carbonatite melt (i.e. kimberlite melt) causes thermo-mechanical erosion of the subcontinental lithosphere mantle (SCLM) roots and creates hot and deformed metasomatic regions in the lower parts of the SCLM, which corresponds to depths constrained by P–T estimates of sheared Gt-peridotite xenoliths. The sheared Gt-peridotites undoubtedly represent samples of these regions.     

A petrological and geochemical reappraisal of the Mesoproterozoic diamondiferous Majhgawan pipe of central India: evidence for transitional kimberlite – orangeite (group II kimberlite) – lamproite rock type

Summary The Mesoproterozoic diamondiferous Majhgawan pipe of central India is re-examined in the light of new and recently published petrological, geochemical and isotope data. This investigation reveals that its tectonic setting is similar to that of lamproites and orangeites (Group II kimberlite of southern Africa) and not that of a typical kimberlite. The petrography and mineralogy are comparable to lamproite and to some extent to orangeite, whereas the major element geochemistry is more akin to that of kimberlite. Trace element geochemistry is closer to that of lamproite but Nd isotope systematics are atypical of lamproite or orangeite. The inferred petrogenesis of the Majhgawan pipe is also similar to that of other such potassic metasomatised mantle magmas without any strong affinity to a particular clan/group.It is demonstrated in this study that the Majhgawan pipe shares the petrological, geochemical and isotope characteristics of all three rock types. It is therefore suggested to constitute a transitional kimberlite–orangeite (Group II kimberlite)–lamproite rock. The existence of such transitional magmas in space and time in other cratons, outside India, is also highlighted. The name majhgawanite is proposed for this rock – keeping in mind the antiquity of the Majhgawan pipe, its intriguing petrological and geochemical characteristics and also on the basis of Indias legacy for introducing diamond to the world – to designate such mafic potassic-ultrapotassic transitional rock types so as to distinguish them from the classical kimberlite, lamproite or orangeite.It is concluded that the correlations between kimberlite petrography, geochemistry and isotopic types (viz., Group I and II), as established for kimberlites in southern Africa, need not be necessarily valid elsewhere. Hence, the recommendations of I.U.G.S. on classification of kimberlite, orangeite and lamproite are clearly inadequate when dealing with the transitional mafic potassic ultrapotassic rocks. It is further stressed that mineralogical, geochemical and isotopic aspects of mafic potassic-ultrapotassic rocks need to be considered in unison before assigning any name as the nomenclature of such exotic and rare alkaline rock types invariably implies economic and tectono-magmatic (regional) significance.     

The first record of “spelaeoid” bears in Arctic Siberia

For a long time, “spelaeoid” (cave-bear-like) bears, Ursus (Spelearctos) spp., were believed to be almost purely European animals. Their geographic range has recently been extended to the east, in southern Siberia, Transbaikalia, Kirghizia, Mongolia and Korea. Two unexpected new findings, presented here in detail, significantly change existing views on the distribution of cave bears; both were found in North-Eastern Siberia, far beyond the Arctic Circle, more than 1500 km to the north-east of the previously accepted range.One of the fossils is a mandible, found near the town of Cherskiy at 68.73°N, 161.38°E. The analysis of local geology and accompanying mammal fossils suggests that it comes from the Olyorian Fauna (Early to early Middle Pleistocene). Morphologically, the Cherskiy mandible is closest to Ursus savini, a small middle Pleistocene cave bear from the British Cromer Forest-bed Formation, but differs in having a slightly more advanced dentition, and thus it is described as a new subspecies Ursus savini nordostensis. Another newly recognized fossil of the “spelaeoid” bear is an astragalus found at the Oskhordokh site at 67.54°N, 135.67°E, on a large gravel bar on the right bank of the Adycha River. This specimen is attributed to Ursus cf. deningeri.The paper also presents an interesting example of the interaction between classical and “molecular” palaeontology.The new finds significantly change existing ideas on the ecology and evolution of cave bears, some of the most remarkable members of the extinct Pleistocene megafauna.     

The Idea of Cover Design and Characteristics of “Cover Story” of Acta Geoscientica Sinica

期刊封面给予读者第一感官印象,封面设计对提高科技学术期刊的质量、树立期刊品牌形象有着极为重要的作用.期刊的封面设计应遵循规范性、专业性、稳定性和艺术性的原则.本文介绍和分析了《地球学报》封面的历史沿革;阐述了2008年新版《地球学报》封面设计的理念:遵循封面设计的原则、增强个性表达,凸显品牌特色、平稳过渡,融入中华文化元素;展现了《地球学报》“封面故事”特色.     

Petrogenesis of the diamondiferous Pipe-8 ultramafic intrusion from the Wajrakarur kimberlite field of Southern India and its relation to the worldwide Mesoproterozoic(～1.1 Ga) magmatism of kimberlite and related rocks

Detailed mineralogy,bulk rock major,trace and Sr-Nd isotope compositions,and ~(40)Ar/~(39)Ar dating of the Pipe-8 diamondiferous ultramafic intrusion in the Wajrakarur cluster of southern India,is reported.Based on the presence of Ti-rich phlogopite,high Na/K content in amphibole,Al-and Ti-rich diopside,a titanomagnetite trend in spinel and the presence of Ti-rich schorlomite garnet and carbonates in the groundmass,the Pipe-8 intrusion is here more precisely classified as an ultramafic lamprophyre(i.e.,aillikite).An aillikite affinity of the Pipe-8 intrusion is further supported by the bulk rock major and trace element and Sr-Nd isotope geochemistry.Sr-Nd isotope data are consistent with a common,moderately depleted upper mantle source region for both the Pipe-8 aillikite as well as the Wajrakarur kimberlites of southern India.A phlogopite-rich groundmass ~(40)Ar/~(39)Ar plateau age of 1115.8±7.9 Ma(2σ) for the Pipe-8 intrusion falls within a restricted 100 Ma time bracket as defined by the 1053-1155 Ma emplacement ages of kimberlites and related rocks in India.The presence of ultramafic lamprophyres,carbonatites,kimberlites,and olivine lamproites in the Wajrakarur kimberlite field requires low degrees of partial melting of contrasting metasomatic assemblages in a heterogeneous sub-continental lithospheric mantle.The widespread association of kimberlite and other mantle-derived magmatism during the Mesoproterozoic(ca.1.1 Ga) have been interpreted as being part of a single large igneous province comprising of the Kalahari,Australian,West Laurentian and Indian blocks of the Rodinia supercontinent that were in existence during its assembly.In India only kimberlite/lamproite/ultramafic lamprophyre magmatism occurred at this time without the associated large igneous provinces as seen in other parts of Rodinia.This may be because of the separated paleo-latitudinal position of India from Australia during the assembly of Rodinia.It is speculated that the presence of a large plume at or close to 1.1 Ga within the Rodinian supercontinent,with the Indian block located on its periphery,could be the reason for incipient melting of lithospheric mantle and the consequent emplacement of only kimberlites and other ultramafic,volatile rich rocks in India due to comparatively low thermal effects from the distant plume.     

The oxygen isotopic composition as an indicator of the genesis of “Basaltic” corundum

This paper reports an oxygen isotopic study of corundums and associated minerals from the Yogo lamprophyres (Montana, US), plagioclase-corundum inclusions in alkali basalt (Tunkin depression, Russia), and from modern alluvium of Podgelbanochnyi alkaline basaltic volcano (Primorye, Russia). It is shown that all sapphires genetically related to mafic magmatic rocks have a similar oxygen isotopic composition (the variations of δ¹⁸O are within 2.5‰) with most values plotting between +4.5 and +7.0‰ SMOW. The oxygen isotopic ratios in the associated minerals (olivines, pyroxenes, mica, and others) and host rocks are plotted in the same interval. This indicates that the sapphire crystallized during evolution of the parental mafic magma. However, there are xenogenic corundums, which were only transported by basaltic magma to the Earth’s surface. They have a sharply distinct oxygen isotopic composition, which suggests their disequilibrium with the host lavas, and, correspondingly, a different genetic nature.