Hybridization of mafic microgranular enclaves: mineral and whole-rock chemistry evidence from the Karamadazı Granitoid, Central Turkey

On the Eastern Tauride Belt, the Cretaceous calc-alkaline Karamadazı Granitoid consists of quartz diorite containing mafic microgranular enclaves (MME) and leucocratic granite. The quartz diorite consists of plagioclase (An_8-65), hornblende, biotite, K-feldspar, quartz, epidote and titanite. Subrounded MME in the quartz diorite are holocrystalline, fine-grained, quartz diorite to diorite in composition, and display a similar mineral assemblage to their host. Large crystals in MME and quartz diorite show various disequilibrium microstructures indicative of hybridization. Plagioclase crystals exhibit inverse, normal, and oscillatory zoning with maximum core-to-rim An content increase up to 38% in the enclave and 40% in the quartz diorite. Both hornblende and augite exhibit normal and reverse zoning even in the same sample. The new field, textural, mineral compositional, and geochemical evidence leads to the conclusion that MME could have formed through injection of successive pulses of basic magma into upward mobile magma chambers containing cooler, partially crystalline quartz diorite magma. The quartz diorites show similarity to high-Al TTG (tonalites–trondhjemites–granodiorites), with their high Na₂O, Sr, LREE, and low Mg#, Cr, HREE contents, and are suggested to be produced by extensive interaction between the crustal and mantle-derived melts through mixing at depth. In contrast, leucogranites have geochemical characteristics distinct from the quartz diorites and MME, and are probably not involved in MME genesis.     

Mafic microgranular enclaves in Late Paleozoic granitoids in the Burgasy quartz syenite massif, western Transbaikalia: Composition and petrogenesis

The paper presents original data on the inner structure, mineralogy, and geochemistry of the Late Paleozoic Burgasy quartz syenite massif in western Transbaikalia and mafic microgranular enclaves (MME) in its rocks. The composition of the mafic microgranular enclaves is close to that of phase-1 monzonitoids of this pluton, but the enclaves are not xenoliths of these rocks but were produced by the crystallization of an individual portion of dispersed hybridized basalt melt. The basaltoid nature of the enclaves follows, first of all, from the relict assemblage of calcic plagioclase (An _73–60) and clinopyroxene and from the magmatic dolerite and microgabbro textures of the rocks. The monzonitoid composition of the enclaves was caused by hybridism, which was responsible for the crystallization of quartz, potassic feldspar, and sodic plagioclase due to the introduction of silica, potassium, and some other components. Hybridism was restricted to a boundary crystallization layer in the deep portion of the magmatic chamber (near its bottom). The scatter of the enclaves throughout the whole volume of the pluton is explained by the density inversion of the hybrid layer and material transfer by convective flows. The mafic enclaves crystallized from basaltic melt of within-plate geochemical type. In spite of intense hybridism, the enclaves preserved typical compositional signatures of mafic magma related to the generation of granites in western Transbaikalia in the Late Paleozoic. The basaltoid nature of the mafic enclaves of the Burgasy Massif testifies that magma was simultaneously generated in the mantle and crust during the development of the Late Paleozoic province in the area.     

Coeval felsic and Mafic Magmas in neoarchean calc-alkaline magmatic arcs,Dharwar craton,Southern India: Field and petrographic evidence from mafic to Hybrid magmatic enclaves and synplutonic Mafic dykes

We present field and petrographic data on Mafic Magmatic Enclaves (MME), hybrid enclaves and synplutonic mafic dykes in the calc-alkaline granitoid plutons from the Dharwar craton to characterize coeval felsic and mafic magmas including interaction of mafic and felsic magmas. The composite host granitoids comprise of voluminous juvenile intrusive facies and minor anatectic facies. MME, hybrid enclaves and synplutonic mafic dykes are common but more abundant along the marginal zone of individual plutons. Circular to ellipsoidal MME are fine to medium grained with occasional chilled margins and frequently contain small alkali feldspar xenocrysts incorporated from host. Hybrid magmatic enclaves are intermediate in composition showing sharp to diffused contacts with adjoining host. Spectacular synplutonic mafic dykes commonly occur as fragmented dykes with necking and back veining. Similar magmatic textures of mafic rocks and their felsic host together with cuspate contacts, magmatic flow structures, mixing, mingling and hybridization suggest their coeval nature. Petrographic evidences such as disequilibrium assemblages, resorption, quartz ocelli, rapakivi-like texture and poikilitically enclosed alkali feldspar in amphibole and plagioclase suggest interaction, mixing/mingling of mafic and felsic magmas. Combined field and petrographic evidences reveal convection and divergent flow in the host magma chamber following the introduction of mafic magmas. Mixing occurs when mafic magma is introduced into host felsic magma before initiation of crystallization leading to formation of hybrid magma under the influence of convection. On the other hand when mafic magmas inject into host magma containing 30–40% crystals, the viscosities of the two magmas are sufficiently different to permit mixing but permit only mingling. Finally, if the mafic magmas are injected when felsic host was largely crystallized (~70% or more crystals), they fill early fractures and interact with the last residual liquids locally resulting in fragmented dykes. The latent heat associated with these mafic injections probably cause reversal of crystallization of adjoining host in magma chamber resulting in back veining in synplutonic mafic dykes. Our field data suggest that substantial volume of mafic magmas were injected into host magma chamber during different stages of crystallization. The origin of mafic magmas may be attributed to decompression melting of mantle associated with development of mantle scale fractures as a consequence of crystallization of voluminous felsic magmas in magma chambers at deep crustal levels.     

小兴安岭东南晚奥陶世鹤林侵入杂岩体成因探讨

小兴安岭东南晚奥陶世鹤林侵入杂岩体岩性变化较大,由角闪辉长岩—(石英)闪长岩—英云闪长岩—二长花岗岩组成,不同岩石类型在野外宏观上呈相互侵入、包裹和渐变的接触关系;在(石英)闪长岩、英云闪长岩和二长花岗岩中均发育微细粒闪长质包体,包体多具明显塑性流变特点的浑圆外形和典型岩浆结构、针状磷灰石及捕获的寄主岩钾长石、石英斑晶,为MME型岩浆混合成因包体;杂岩体相对富集LILE(Ba、Sr、Rb)、HFS(U、Th、Zr、Ce)元素等,显示出壳源特点,而较高的εNd(t)值(-2.38~-3.77)显示以幔源为主的特点。研究表明杂岩体具明显的壳幔岩浆混合成因的岩相学、岩石化学和地球化学特征,形成于基性岩浆底侵作用下的陆缘弧型活动大陆边缘构造环境。     

The morphology and chemistry of K-feldspar megacrysts from Ikizdere Pluton: evidence for acid and basic magma interactions in granitoid rocks, NE-Turkey

Ikizdere Pluton consists of granite, granodiorite, tonalite, monzonite, quartz monzonite containing pinkish colored K-feldspar megacrysts (KFMs). The crystal sizes of the KFMs range from 1 to 4 cm. The lath-shaped megacrysts are uniformly (i.e., randomly) distributed in the host plutonic rocks and have mafic and felsic inclusions whose crystal sizes are smaller than 1 mm. The crystal inclusions are biotite, slightly annitic in composition with X_Mg[=Fe_tot/(Fe_tot+Mg)]=0.50-0.58, amphibole (magnesio-hornblende, X_Mg[=Mg/(Mg+Fe_tot)]=0.70-0.79), iron-titanium oxide (low titanium magnetit and ilmenite), plagioclase (Ab₇₅₋₂₅An₆₅₋₃₅) and as minor quartz. The compositions of the KFMs range from Or₉₅Ab₅An₀ to Or₈₂Ab₁₇An₁. BaO contents of the megacrysts increase from core to rim. The mafic and felsic inclusions are compositionally similar those of the host rocks.The chemical and textural features of K-feldspar are typical for megacrysts that grew as phenocrysts in dynamic granitoidic magma systems. The overgrowth of KFMs and mafic magma injections (magma mixing) may be related to temperature, pressure and compositional fluctuations in the magma chamber. Remnant of earlier formed K-feldspar crystals remain in the felsic magma system, while the mafic injection can decompose some earlier precipitated KFMs. The remnant of K-feldspar remaining after mafic injection are overgrown by rapid diffusion of Ba, K and Na elements in liquid phase, during the later stages of crystallization of the host magma.     

Petrogenesis of the ü?kap?l? Granitoid and its Mafic Enclaves in Elmal? Area (Ni?de, Central Anatolia, Turkey)

The Late Cretaceous ükapili Granitoid including mafic microgranular enclaves intruded into metapelitic and metabasic rocks, and overlain unconformably by Neogene ignimbrites in the Ni de area of Turkey. It is mostly granite and minor granodiorite in composition, whereas its enclaves are dominantly gabbro with a few diorites in composition. The ükapili Granitoid is composed mainly of quartz, K-feldspar, plagioclase, biotite, muscovite and minor amphibole while its enclaves contain mostly plagioclase, amphibole, minor pyroxene and biotite. The ükapili Granitoid has calcalkaline and peraluminous (A/CNK= 1.0-1.3) geochemical characteristics. It is characterized by high LILE/HFSE and LREE/HREE ratios ((La/Lu) N = 3-33), and has negative Ba, Ta, Nb and Eu anomalies, resembling those of collision granitoids. The ükapili Granitoid has relatively high 87Sr/86Sr (i) ratios (0.711189-0.716061) and low εNd (t) values (-5.13 to -7.13), confirming crustal melting. In contrast, the enclaves are tholeiitic and metaluminous, and slightly enriched in LILEs (K, Rb) and Th, and have negative Ta, Nb and Ti anomalies; propose that they were derived from a subduction-modified mantle source. Based on mineral and whole rock chemistry data, the ükapili granitoid is H-(hybrid) type, post-collision granitoid developed by mixing/mingling processes between crustal melts and mantle-derived mafic magmas.     

Enclaves in granitoids of north of Jonnagiri schist belt,Kurnool district,Andhra Pradesh: Evidence of magma mixing and mingling

Calc-alkaline, metaluminous granitoids in the north of Jonnagiri schist belt (JSB) are associated with abundant mafic rocks as enclave. The enclaves represent xenoliths of the basement, mafic magmatic enclaves (MME) and synplutonic mafic dykes. The MME are mostly ellipsoidal and cuspate shape having lobate margin and diffuse contact with the host granitoids. Sharp and crenulated contacts between isolated MME and host granitoids are infrequent. The MME are fine-grained, slightly dark and enriched in mafic minerals compare to the host granitoids. MME exhibits evidences of physical interaction (mingling) at outcrop scale and restricted hybridization at crystal scale of mafic and felsic magmas. The textures like quartz ocelli, sphene (titanite) ocelli, acicular apatite inclusion zone in feldspars and K-feldspar megacrysts in MME, megacrysts across the contact of MME and host and mafic clots constitute textural assemblages suggestive of magma mingling and mixing recorded in the granitoids of the study area. The quartz ocelli are most likely xenocrysts introduced from the felsic magma. Fast cooling of mafic magma resulted in the growth of prismatic apatite and heterogeneous nucleation of titanite over hornblende in MME. Chemical transfer from felsic magma to MME forming magma envisage enrichment of silica, alkalis and P in MME. The MME show low positive Eu anomalies whereas hybrid and host granitoids display moderate negative Eu-anomalies. Synplutonic mafic dyke injected at late stage of crystallising host felsic magma, display back veining and necking along its length. The variable shape, dimensions, texture and composition of MME, probably are controlled by the evolving nature and kinematics of interacting magmas.     

Mafic magmatic enclaves and mafic rocks associated with some granitoids of the central Sierra Nevada batholith, California: nature, origin, and relations with the hosts

The calc-alkaline granitoids of the central Sierra Nevada batholith are associated with abundant mafic rocks. These include both country-rock xenoliths and mafic magmatic enclaves (MME) that commonly have fine-grained and, less commonly, cumulate textures. Scarce composite enclaves consist of either xenoliths enclosed in MME, or of MME enclosed in other MME with different grain size and texture. Enclaves are often enclosed in mafic aggregates and form meter-size polygenic swarms, mostly in the margins of normally zoned plutons. Enclaves may locally divert schlieren layering. Mafic dikes, which also occur in swarms, are undisturbed, composite, or largely hybridized. In central Sierra Nevada, with the exception of xenoliths that completely differ from the other rocks, host granitoids, mafic aggregates, MME, and some composite dikes exhibit a bulk compositional diversity and, at the same time, important mineralogical and geochemical (including isotopic) similarities. MME and host granitoids display distinct major and trace element compositions. However, strong correlations between MME–host granitoid pairs indicate interactions and parallel evolution of MME and enclosing granitoid in each pluton. Identical mafic mineral compositions and isotopic features are the result of these interactions and parallel evolution. Mafic dikes have broadly the same major and trace element compositions as the MME although variations are large between the different dikes that are at distinctly different stages of hybridization and digestion by the host granitoids. The composition of the granitoids and various mafic rocks reflects three distinct stages of hybridization that occurred, respectively, at depth, during ascent and emplacement, and after emplacement. The occurrence and succession of hybridization processes were tightly controlled by the physical properties of the magmas. The sequential thorough or partial mixing and mingling were commonly followed by differentiation and segregation processes. Unusual MME that contain abundant large crystals of hornblende resulted from disruption of early cumulates at depth, whereas those richer in large crystals of biotite were formed by disruption of late mafic aggregates or schlieren layerings at the level of emplacement. MME and host granitoids are considered cogenetic, because both are hybrid rocks that were produced by the mixing of the same two components in different proportions. The felsic component was produced by partial melting of preexisting crustal materials, whereas the dominant mafic component was probably derived from the upper mantle. However, in the lack of a clear mantle signature, the origin of the mafic component remains questionable.     

Magma mixing and mingling textures in granitoids: examples from the Galway Granite, Connemara, Ireland

Summary ?Many granitoid intrusions display textural evidence for the interaction of mafic and silicic magmas during their genesis. The ∼ 400 Ma Galway Granite exhibits excellent evidence for magma mixing and mingling both at outcrop/map scale (magma mingling and mixing zones), and at thin-section/crystal scale (mixing textures). These textures – quartz ocelli, rapakivi feldspars, acicular and mixed apatite morphologies, inclusion zones in feldspars, anorthite ‘spikes’ in plagioclase, sphene ocelli, K-feldspar megacrysts in mafic microgranular enclaves (MME), and mafic clots – constitute a textural assemblage whose origin can be explained in terms of magma mixing and mingling models. Furthermore, textures from this assemblage have been recorded throughout the Galway batholith indicating that magma mingling and mixing played a key role during its evolution. Received November 18, 2000; revised version accepted November 6, 2001     

Grain to outcrop-scale frozen moments of dynamic magma mixJing in the syenite magma chamber,Yelagiri Alkaline Complex,South India

Magma mixing process is unusual in the petrogenesis of felsic rocks associated with alkaline complex worldwide. Here we present a rare example of magma mixing in syenite from the Yelagiri Alkaline Complex, South India. Yelagiri syenite is a reversely zoned massif with shoshonitic (Na₂O + K₂O=5–10 wt.%, Na₂O/K₂O = 0.5–2, TiO₂ <0.7 wt.%) and metaluminous character. Systematic modal variation of plagioclase (An_11–16 Ab_82–88), K-feldspar (Or_27–95 Ab_5–61), diopside (En_34–40Fs_11–18Wo_46–49), biotite, and Ca-amphibole (edenite) build up three syenite facies within it and imply the role of in-situ fractional crystallization (FC). Evidences such as (1) disequilibrium micro-textures in feldspars, (2) microgranular mafic enclaves (MME) and (3) synplutonic dykes signify mixing of shoshonitic mafic magma (MgO = 4–5 wt.%, SiO₂ = 54–59 wt.%, K₂O/Na₂O = 0.4–0.9) with syenite. Molecular-scale mixing of mafic magma resulted disequilibrium growth of feldspars in syenite. Physical entity of mafic magma preserved as MME due to high thermal-rheological contrast with syenite magma show various hybridization through chemical exchange, mechanical dilution enhanced by chaotic advection and phenocryst migration. In synplutonic dykes, disaggregation and mixing of mafic magma was confined within the conduit of injection. Major-oxides mass balance test quantified that approximately 0.6 portions of mafic magma had interacted with most evolved syenite magma and generated most hybridized MME and dyke samples. It is unique that all the rock types (syenite, MME and synplutonic dykes) share similar shoshonitic and metaluminous character; mineral chemistry, REE content, coherent geochemical variation in Harker diagram suggest that mixing of magma between similar composition. Outcrop-scale features of crystal accumulation and flow fabrics also significant along with MME and synplutonic dykes in syenite suggesting that Yelagiri syenite magma chamber had evolved through multiple physical processes like convection, shear flow, crystal accumulation and magma mixing.     

Granite,gabbro and mafic microgranular enclaves in the Gejiu area,Yunnan Province,China: a case of two-stage mixing of crust- and mantle-derived magmas

Geochronological, geochemical, whole-rock Sr–Nd, and zircon Hf isotopic analyses were carried out on the Jiasha Gabbro, mafic microgranular enclaves (MME) and host Longchahe Granite samples from the Gejiu area in the southeast Yunnan province, SW China, with the aim of characterizing their petrogenesis. Compositional zoning is evident in the gabbro body as the cumulate textures and mineral proportions in the gabbro interior are distinct from the gabbro margin. The Longchahe Granite largely comprises metaluminous quartz monzonite with distinctive K-feldspar megacrysts, but also contains a minor component of peraluminous leucogranite. The MME have spheroidal to elongated/lenticular shapes with sharp, crenulated and occasionally diffuse contacts with the host granite, which we attribute to the undercooling and disaggregation of mafic magma globules within the cooler host felsic magma. Field observations, geochronology, geochemistry, Sr–Nd and zircon Hf isotopic compositions point to a complex petrogenesis for this granite–MME–gabbro association. Zircon ²⁰⁶Pb/²³⁸U ages determined by LA-ICP-MS for a mafic enclave, its host granite and the gabbro body are 83.1 ± 0.9 Ma, 83.1 ± 0.4 Ma and 83.2 ± 0.4 Ma, respectively, indicating coeval crystallization of these igneous rock units. Crystal fractionation processes can explain much of the compositional diversity of the Jiasha Gabbro. The geochemical features of the gabbro, such as high Mg^# (up to 70) and Cr (up to 327 ppm), enrichment in LILEs (e.g., Rb, Ba, K₂O) and LREEs, and depletion in HFSE (e.g., Nb, Ta, Ti), together with initial ⁸⁷Sr/⁸⁶Sr ratios of 0.708–0.709 and negative εNd(t) values (−5.23 to −6.45), indicate they were derived from a mantle source that had undergone previous enrichment, possibly by subduction components. The Longchahe Granite has a large range of SiO₂ (59.87–74.94 wt%), is distinctly alkaline in composition, and has Sr–Nd–Hf isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i > 0.712, εNd(t) = −6.93 to −7.62 and εHf(t) = −5.8 to −9.9) that are indicative of derivation from a crustal source. However, the most primitive rocks of Longchahe Granite are compositionally distinct from any feasible crustal melt. We interpret the spectrum of rock types of the Longchahe Granite to have formed via mixing between crustally derived peraluminous leucogranite magma and mantle-derived magma of similar heritage to the Jiasha Gabbro. We speculate that this mixing event occurred early in the magmatic history of these rocks at relatively high temperature and/or deep in the crust to allow efficient physical mixing of magmas. Saturation and accumulation of K-feldspar and zircon in the mixed magma is invoked to explain the megacrystic K-feldspar and elevated K₂O and Zr content of some of the granitic rocks. A later episode of magma mixing/mingling is preserved as the MME that have geochemical and isotopic compositions that, for the most part, are intermediate between the granite and the gabbro. The MME are interpreted to be fractionated melts of mafic magma related to gabbro that were subsequently injected into the cooler, partly crystalline granitic magma. Mingling and mixing processes within the convectively dynamic upper crustal magma chamber resulting in a hybrid (MME) magma. During this second mixing episode, element interdiffusion, rather than bulk physical mixing, is interpreted to be the dominant mixing process.     

Grain-size-sensitive creep of plagioclase accompanied by solution–precipitation and mass transfer under mid-crustal conditions

We report here on a study of three deformed granitoids: two mylonites and an ultramylonite from the inner ductile shear zone of the Ryoke metamorphic belt, SW Japan. Monophase layers composed of quartz, plagioclase or K-feldspar are present in all samples. The plagioclase-rich layers consist of grains 6–10 μm in size, and sometimes include patchy K-feldspar and quartz, indicating solution-precipitation. In the mylonite, the fine-grained plagioclase is mainly An_23–25 and, the composition of plagioclase porphyroclast is An_21–39 without any significant maximum. The An compositions together with textural observations indicate that fine-grained plagioclase nucleated from solution with mass transfer during deformation. In the ultramylonite, fine-grained plagioclase is widely changed to be An_15–37, indicating that the grain-size-reduction process includes fracturing of original plagioclase porphyroclasts in addition to the solution–precipitation process, which results in the composition concentrated around An₃₀. In all samples, the crystallographic orientations of fine-grained plagioclases are almost random and do not correlate with neighbouring porphyroclasts. Grain-size-sensitive creep occurred during rock deformation subsequent to the process of solution–precipitation that involved mass transfer via fluids.     

Mineralogy, whole-rock and Sr-Nd isotope geochemistry of mafic microgranular enclaves in Cretaceous Dagbasi granitoids, Eastern Pontides, NE Turkey: Evidence of magma mixing, mingling and chemical equilibration

Rocks of the Late Cretaceous Dagbasi Pluton (88-83 Ma), located in the eastern Pontides, include mafic microgranular enclaves (MMEs) ranging from a few centimetres to metres in size, and from ellipsoidal to ovoid in shape. The MMEs are composed of gabbroic diorite, diorite and tonalite, whereas the felsic host rocks comprise mainly tonalite, granodiorite and monzogranite based on both mineralogical and chemical compositions. MMEs are characterized by a fine-grained, equigranular and hypidiomorphic texture. The common texture of felsic host rocks is equigranular and also reveals some special types of microscopic textures, e.g., oscillatory-zoned plagioclase, poikilitic K-feldspar, small lath-shaped plagioclase in large plagioclase, blade-shaped biotite, acicular apatite, spike zones in plagioclase and spongy-cellular plagioclase textures and rounded plagioclase megacrysts in MMEs. Compositions of plagioclases (An₃₃-An₆₀), hornblendes (Mg#=0.77-1.0) and biotites (Mg#=0.61-0.63) of MMEs are slightly distinct or similar to those of host rocks (An_12-57; hbl Mg#=0.63-1.0; Bi Mg#=0.50-0.69), which suggest partial to complete equilibration during mafic-felsic magma interactions.The felsic host rocks have SiO₂ between 60 and 76 wt% and display low to slightly medium-K tholeiitic to calc-alkaline and peraluminous to slightly metaluminous characteristics. Chondrite-normalized rare-earth element (REE) patterns are fractionated (La_cn/Lu_cn=1.5-7.3) with pronounced negative Eu anomalies (Eu/Eu*=0.46-1.1). Initial ε_Nd(i) values vary between −3.1 and 1.6, initial ⁸⁷Sr/⁸⁶Sr values between 0.7056 and 0.7067.Compared with the host rocks, the MMEs are characterized by relatively high Mg-number of 22-52, low contents of SiO₂ (53-63 wt%), low ASI (0.7-1.1) and low to medium-K tholeiitic to calc-alkaline, metaluminous to peraluminous composition. Chondrite-normalized REE patterns are relatively flat [(La/Yb)_cn=1.4-3.9; (Tb/Yb)_cn=0.9-1.5] and show small negative Eu anomalies (Eu/Eu*=0.63-1.01). Isotope signatures of these rocks (⁸⁷Sr/⁸⁶Sr_(i)=0.7054-0.7055; ε_Nd(i)=-1.0 to 1.9) are largely similar to the host rocks. Gabbroic diorite enclaves have relatively low contents of SiO₂, ASI; high Mg#, CaO, Al₂O₃, TiO₂, P₂O₅, Sr and Nb concentrations compared to dioritic and tonalitic enclaves.The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, interacted with a crustal melt that originated from dehydration melting of the mafic lower crust at deep crustal levels. The existence of compositional and textural disequilibrium and the nature of chemical and isotopic variation in these rock types indicate that magma mixing/mingling between an evolved mafic and a granitic magma was involved in their genesis. Microgranular enclaves are thus interpreted to be globules of a more mafic magma probably from an enriched lithospheric mantle source. Al-in-amphibole estimates the pluton emplacement at ca. 0.3-3.8 kbar, and therefore, magma mixing and mingling must have occurred at 3.8 kbar or below this level.     

Intermittent generation of mafic enclaves in the 1991–1995 dacite of Unzen Volcano recorded in mineral chemistry

Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO₂ contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO₂ contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO₂?=?53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca?+?Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas.     

南秦岭西坝花岗质岩体矿物学特征及成岩意义

西坝花岗质岩体位于南秦岭构造-岩浆带中部,为南秦岭印支期花岗岩带五龙岩体群的重要组成部分,与双王金矿有密切的空间关系。该岩体主要由石英二长闪长岩和花岗闪长岩组成,岩体中发育较多的镁铁质包体。通过对岩体及镁铁质包体的系统的矿物学特征研究发现,本区花岗质岩体属于I型花岗岩类,成岩物质主要来源于地壳,并且有地幔物质的加入。岩体及镁铁质包体显示有多种壳-幔岩浆混合的岩相学证据:如包体的冷凝边、斜长石环带成分显示核部和边缘偏基性,而幔部偏酸性,包体中见大量的长针状磷灰石及角闪石,包体中有两种产状的角闪石等。根据矿物温度压力计计算,西坝岩体的结晶温度为646.72~703.84℃,压力为1.67×108~3.66×108Pa,平均为3.12×108Pa。岩体形成于相对高氧逸度(lgfO2为-16.16×105~-17.06×105Pa)、中等水逸度(fH2O为46.82×105~136.85×105Pa)和氢逸度(fH2为0.32×105~0.91×105Pa)环境。岩体的这种高氧逸度条件有利于金进入熔体相或流体相,是金矿形成的有利条件。     

Generation of Porphyritic and Equigranular Mafic Enclaves During Magma Recharge Events at Unzen Volcano, Japan

Mafic to intermediate enclaves are evenly distributed throughoutthe dacitic 1991–1995 lava sequence of Unzen volcano,Japan, representing hundreds of mafic recharge events over thelife of the volcano. This study documents the morphological,textural, chemical, and petrological characteristics of theenclaves and coexisting silicic host lavas. The eruptive productsdescribed in this study appear to be general products of magmamingling, as the same textural types are seen at many othervolcanoes. Two types of magmatic enclaves, referred to as Porphyriticand Equigranular, are easily distinguished texturally. Porphyriticenclaves display a wide range in composition from basalt toandesite, are glass-rich, spherical and porphyritic, and containlarge, resorbed, plagioclase phenocrysts in a matrix of acicularcrystals and glass. Equigranular enclaves are andesitic, non-porphyritic,and consist of tabular, medium-grained microphenocrysts in amatrix glass that is in equilibrium with the host dacite magma.Porphyritic enclaves are produced when intruding basaltic magmaengulfs melt and phenocrysts of resident silicic magma at theirmutual interface. Equigranular enclaves are a product of a moreprolonged mixing and gradual crystallization at a slower coolingrate within the interior of the mafic intrusion. KEY WORDS: mafic enclaves; quenched mafic inclusions; magma mingling; Unzen volcano; Unzen Scientific Drilling Project; resorbed plagioclase     

内蒙古解放营子花岗闪长岩岩浆混合机制——来自斜长石和角闪石的矿物化学证据

为揭示华北克拉通北缘中晚三叠世解放营子花岗闪长岩的岩浆混合机制,对寄主岩石和镁铁质包体中斜长石和角闪石开展了电子探针分析.分析结果显示,多斑和少斑包体边部的斜长石斑晶发育An值增加的突变环带,环带的An值为32～46,明显高于核部和边部斜长石的An值(18～31),而核部的An值与寄主岩石中斜长石的An值一致,该特征指...     

Microtextural and mineral chemical analyses of andesite–dacite from Barren and Narcondam islands: Evidences for magma mixing and petrological implications

Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains. In this study, we use the results of mineral chemical analyses of the calc-alkaline rock suite of rocks as proxies for magma mixing and mingling processes. Plagioclase, the most dominant mineral, shows zoning which includes oscillatory, patchy, multiple and repetitive zonation and ‘fritted’ or ‘sieve’ textures. Zoning patterns in plagioclase phenocrysts and abrupt fluctuations in An content record different melt conditions in a dynamic magma chamber. ‘Fritted’ zones (An₅₅) are frequently overgrown by thin calcic (An₇₂) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing processes. We conclude that hybrid magma formed from the mixing of mafic and felsic magma by two-stage processes – initial intrusion of hotter mafic melt (andesitic) followed by cooler acidic melt at later stage.     

湘中紫云山岩体暗色微粒包体的成因:岩相学、全岩及矿物地球化学证据

暗色微粒包体广泛分布于湘中紫云山岩体中的似斑状角闪石黑云母花岗闪长岩中,但其研究程度较低.对具有火成结构的暗色微粒包体及其寄主岩进行了岩相学、全岩及长石、辉石、黑云母的矿物地球化学研究,探讨其岩石成因及构造意义.寄主岩的全岩主量、微粒元素较为均一,而暗色微粒包体变化较大,且后者相对贫SiO₂而富Na₂O,但总体上二者均具有准铝质、钙碱性、镁质的特征,均富集轻稀土和大离子亲石元素,而亏损重稀土和高场强元素.寄主岩和暗色微粒包体的斜长石、辉石和黑云母均分别属于中长石、次透辉石－低铁次透辉石和铁质黑云母的范畴,显示相似的矿物地球化学特征.详尽的岩相学和地球化学特征表明,寄主岩属于I型和ACG型花岗岩,具有明显壳幔混合的特点;而暗色微粒包体形成时处于液态并具有流动性,与寄主岩间存在明显的机械和化学混合作用,并具有早期为骤冷快速结晶、晚期缓慢结晶这两期过程.因此,紫云山岩体中出现大量暗色微粒包体,是印支晚期湘中地区在强烈挤压之后的松弛阶段,由于软流圈物质上涌,并与其诱发的壳源酸性岩浆混合作用的产物.