Ediacaran terrane accretion within the Arabian–Nubian Shield

The Ad Dawadimi Terrane is an Ediacaran basin of the Arabian Nubian Shield (ANS), Saudi Arabia. This basin terrane is situated in the far eastern part of the ANS and represents the youngest accretion event of the exposed ANS. Therefore, the timing of events within the basin is key to understanding both the closure of the Mozambique Ocean and the amalgamation of Gondwana along the northern East African Orogen. Here we present U/Pb detrital zircon data for the Abt Formation, the principle basin sediments of the Ad Dawadimi Terrane, along with ⁴⁰Ar/³⁹Ar ages on muscovite and whole rock Sm/Nd data. These data indicate that deep-water deposition in the Abt Basin did not end until after ca. 620 Ma and that deformation and greenschist-facies metamorphism of the Abt Formation occurred at 620 ± 3 (2σ) Ma along an active margin. This is the youngest terrane amalgamation event reported so far in the Arabian–Nubian Shield, but we suggest even younger sutures lie further east beneath the Phanerozoic cover of eastern Saudi Arabia. Our results suggest that the Ediacaran basins of the eastern ANS were not part of the Huqf basin in Oman, which was instead part of a passive margin of Neoproterozoic India, separated from the active margin of Africa by the Mozambique Ocean that probably did not close until the late Ediacaran or early Cambrian.     

Ediacaran–Cambrian basin evolution in the Koonenberry Belt (eastern Australia): Implications for the geodynamics of the Delamerian Orogen

Contention surrounds the Ediacaran–Cambrian geodynamic evolution of the palaeo-Pacific margin of Gondwana as it underwent a transition from passive to active margin tectonics. In Australia, disagreement stems from conflicting geodynamic models for the Delamerian Orogen, which differ in the polarity of subduction and the state of the subduction hinge (i.e., stationary or retreating). This study tests competing models of the Delamerian Orogen through reconstructing Ediacaran–Cambrian basin evolution in the Koonenberry Belt, Australia. This was done through characterising the mineral and U–Pb detrital zircon age provenance of sediments deposited during postulated passive and active margin stages. Based on these data, we present a new basin evolution model for the Koonenberry Belt, which also impacts palaeogeographic models of Australia and East Gondwana. Our basin evolution and palaeogeographic model is composed of four main stages, namely: (i) Ediacaran passive margin stage with sediments derived from the Musgrave Province; (ii) Middle Cambrian (517–500 Ma) convergent margin stage with sediments derived from collisional orogens in central Gondwana (i.e., the Maud Belt of East Antarctica) and deposited in a backarc setting; (iii) crustal shortening during the c. 500 Ma Delamerian Orogeny, and; (iv) Middle to Late Cambrian–Ordovician stage with sediments sourced from the local basement and 520–490 Ma igneous rocks and deposited into post-orogenic pull-apart basins. Based on this new basin evolution model we propose a new geodynamic model for the Cambrian evolution of the Koonenberry Belt where: (i) the initiation of a west-dipping subduction zone at c. 517 Ma was associated with incipient calc-alkaline magmatism (Mount Wright Volcanics) and deposition of the Teltawongee and Ponto groups; (ii) immediate east-directed retreat of the subduction zone positioned the Koonenberry Belt in a backarc basin setting (517 to 500 Ma), which became a depocentre for continued deposition of the Teltawongee and Ponto groups; (iii) inversion of the backarc basin during the c. 500 Delamerian Orogeny was driven by increased upper and low plate coupling caused by the arrival of a lower plate asperity to the subduction hinge, and; (iv) subduction of the asperity resulted in renewed rollback and upper plate extension, leading to the development of small, post-orogenic pull-apart basins that received locally derived detritus.     

U-Pb zircon age from the base of the Ediacaran Doushantuo Formation in the Yangtze Gorges,South China： constraint on the age of Marinoan glaciation

The reported new U-Pb age by sensitive high-resolution ion microprobe (SHRIMP Ⅱ) on zircon was obtained from a tuff sample at the basal Doushantuo Formation in the Jiuqunao section, which situated at the western limb of the Huangling anticline in the Yangtze Gorges in Zigui, Hubei, South China. Eighteen spots of zircons were analyzed and they form two clusters: one includes three spots, with an inherited age of 784+ 15 Ma (MSWD=0.05); the other consists of 15 spots and gives a weighted mean ^206pb/^238U age of 628.3±5.8 Ma (MSWD=0.86). It is the first SHRIMP U-Pb zircon age obtained nearly the base of the Doushantuo Formation of Ediacaran and represents a maximum age of the Doushantuo Formation It also forms an age constraint on the upper limit age of the Nantuo (Marinoantype) glaciation.     

Environmental upheavals of the Ediacaran period and the Cambrian “explosion” of animal life

The second half of the Ediacaran period began with a large impact e the Acraman impact in South Australia, which was accompanied by a negative d13Ccarb anomaly and an extinction-radiation event involvi...     

Origins of cryptic variation in the Ediacaran–Fortunian rhyolitic ignimbrites of the Saldanha Bay Volcanic Complex,Western Cape,South Africa

The Saldanha eruption centre, on the West Coast of South Africa, consists of 542 Ma, intracaldera, S-type, rhyolite ignimbrites divided into the basal Saldanha Ignimbrite and the partly overlying Jacob’s Bay Ignimbrite. Depleted-mantle Nd model ages suggest magma sources younger than the Early Mesoproterozoic, and located within the Neoproterozoic Malmesbury Group and Swartland complex metasedimentary and metavolcanic rocks that form the regional basement. The Sr isotope systematics suggest that the dominant source rocks were metavolcaniclastic rocks and metagreywackes, and that the magmas formed from separate batches extracted from the same heterogeneous source. No apparent magma mixing trends relate the Saldanha to the Jacob’s Bay Ignimbrites, or either of these to the magmas that formed the Plankiesbaai or Tsaarsbank Ignimbrites in the neighbouring Postberg eruption centre. The magmas were extracted from their source rocks carrying small but significant proportions of peritectic and restitic accessory minerals. Variations in the content of this entrained crystal cargo were responsible for most of the chemical variations in the magmas. Although we cannot construct a cogent crystal fractionation model to relate these groups of magmas, at least some crystal fractionation occurred, as an overlay on the primary signal due to peritectic assemblage entrainment (PAE). Thus, the causes of the cryptic chemical variation among the ignimbrite magmas of the Saldanha centre are variable, but dominated by the compositions of the parent melts and PAE. The preservation of clear, source-inherited chemical signatures, in individual samples, calls into question the common interpretation of silicic calderas as having been formed in large magma reservoirs, with magma compositions shaped by magma mingling, mixing, and fractional crystallization. The Saldanha rocks suggest a more intimate connection between source and erupted magma, and perhaps indicate that silicic magmas are too viscous to be significantly modified by magma-chamber processes.     

U–Pb zircon age of the base of the Ediacaran System at the southern margin of the Qinling Orogen

Global abrupt climate change from Marinoan snowball Earth to greenhouse Earth, recorded as cap carbonate overlain on diamictite, had shed the first light on Cambrian bio-radiation. The most documented cap carbonate sections are typical with comprehensive δ¹³C negative values and ubiquitous sedimentary structures, such as tepee-like, sheet-crack etc., which are associated with successive glacial eustatic variation caused by isostatic rebound in shallow-water facies. Here we report a deep-water basinal cap carbonate section with strong negative δ¹³C values in the southern margin of the Qinling Orogen, Heyu, Chengkou County, Chongqing in China, which consists of massive dolostone with abundant carbonaceous laminae. However, it lacks the sedimentary structure as mentioned above and is overlain by thin-bedded silicious shales and cherts. A K-bentonite bed was discovered within the base of cap carbonates, about 0.7 m above the top of the Marinoan diamictite. Magmatic zircons that were separated from the K-bentonite bed yield a SIMS concordia U–Pb age of 634.1 ± 1.9 Ma (1σ, MSWD_CE = 0.31, Probability_CE = 1.000, n = 20). The age is in good agreement with previously reported TIMS U–Pb ages for the termination of Marinoan glaciation and provides a geochronological constraint for the Ediacaran successions in the Qinling Orogen.     

Tube growth patterns and microbial mat-related lifestyles in the Ediacaran fossil Cloudina,Gaojiashan Lagerstätte,South China

Cloudina are important Ediacaran index fossils, as they have a consistent terminal Neoproterozoic age and a worldwide distribution. The morphology of Cloudina has been reconstructed primarily on the basis of three-dimensionally preserved Chinese and Spanish specimens, but questions remain surrounding their phylogenetic placement. Understanding Cloudina paleoecology is an important aspect for the interpretation of these enigmatic organisms. Although their paleoecological dynamics remain unresolved, a possible “mat sticker” life mode has found support from recent taphonomic investigation of Paraguayan Cloudina specimens. Here, from analysis of fossil material from the upper part of the Ediacaran Dengying Formation (Gaojiashan and Lijiagou sections, Ningqiang area, southern Shaanxi Province, South China), we document complex tube growth patterns of Cloudina in addition to a close association of these fossils with preserved microbially induced sedimentary structures (specifically matgrounds). Sedimentological and taphonomic data of Cloudina-bearing carbonate sequences at the Gaojiashan section show a relationship between Cloudina and microbial mats, and further document erectly preserved Cloudina tubes. In conjunction with observations from the Paraguay material, the Dengying fossils described here provide supportive evidence for the paleoecological interpretation of Cloudina as inhabitants of a microbially bound carbonate substrate. The apical-most part of the tube (or cone) may have served as an attachment apparatus, situated within or beneath a microbial mat. Three-dimensionally phosphatized tubes of Cloudina from the Lijiagou section reveal that single tubes often have multiple growth orientations, which is demonstrated to have resulted from the curved growth of the tube walls (both cones and funnels). As these organisms exhibited a sessile, epibenthic life mode, the observed plasticity in growth direction and orientation may have been a competition-driven adaptation to ensure wider access to available food sources and potentially greater feeding efficiency. Although Cloudina have been found to co-occur in some deposits with biostromes and bioherms (e.g., stromatolites and thrombolites), sedimentological and taphonomic features of the Ningqiang Cloudina suggest that they inhabited a stratified carbonate substrate exhibiting matground features, but where biostromes and bioherms were absent.     

Cadomian volcanosedimentary complexes across the Ediacaran–Cambrian transition of the Eastern Pyrenees,southwestern Europe

International Journal of Earth Sciences - The volcanism hosted by the Ediacaran–Terreneuvian Canaveilles Group of the Eastern Pyrenees displays two distinct geochemical affinities: (1)...     

A New Diverse Macrofossil Lagersttte from the Uppermost Ediacaran of Southwestern China

A new macrofossil Lagersttte was discovered from the uppermost Ediacaran Jiucheng Member at Jinning and Jiangchuan of the eastern Yunnan,yielding numerous diverse well-preserved thallophyte macrofossils.These include the previously-known representatives of vendobionts, Vendotaenia and Tyrasotaenia,and the biggish multicellular benthos such as Chuaria-like and Tawuia- like fossils,as well as Longfengshaniaceaens with diverse holdfast structures.There are still some other problematic macrofossils with peculiar configurations as well as uncertain relatives.The distinct dominance of the giant,unbranching thallophytes occasionally with hoidfast structures distinguishes this assemblage from the other Ediacaran macrofossil Lagerstttes in the Doushantuo Formation at Miaohe,Wenghni and Lantian,and the contemporary assemblage in the Shibantan Member of Dengying Formation,Yangtze Gorges area.This paper outlines the characteristics of some of the multicellular macrofossils from the Jiucheng Member at Jiangchuan.They include some macrofossils with different types of holdfast structure,larger Chuaria-like and Tawuia-like morphology and questionable affinities as well.The discovery of greater diverse macrofossil assemblages from the Jiucheng Member of eastern Yunnan has further indicated that an important diversification and evolutionary radiation of metaphytes took place in the latest Ediacaran time.This radiation of large- scale,benthic metaphyte along with phytoplankton was likely important contributors to the early Cambrian explosion of metazoans.     

Detrital provenance evolution of the Ediacaran–Silurian Nanhua foreland basin,South China

We report here in-situ U–Pb and Hf isotopic results of detrital zircons from sixteen Cambrian–Silurian siliciclastic samples across the Nanhua foreland basin, South China. Together with published data from Ediacaran–Silurian sandstones in the region, we establish the temporal and spatial provenance evolution across the basin. Except for samples from northeast Yangtze, all other Ediacaran–Silurian samples exhibit a prominent population of 1100–900 Ma, moderate populations of 850–700 Ma and 650–490 Ma, and minor populations of 2500 Ma and 2000–1300 Ma, grossly matching that of crystalline and sedimentary rocks in northern India. Zircon Hf isotopes further reveal four episodes of juvenile crustal growth at 2.5 Ga, 1.8 Ga, 1.4 Ga and 1.0 Ga in the source regions. Utilizing the basin history and late Neoproterozoic to early Paleozoic paleogeography of South China, we conclude that the Ediacaran–Cambrian sediments in the Nanhua foreland basin were mainly sourced from northern India and adjacent orogens, and the Ordovician–Silurian sediments were derived from both locally recycled Ediacaran–Cambrian rocks and eroded Cathaysian basement. The Wuyi–Yunkai late-orogenic magmatic rocks also contributed to the Silurian sediments in the basin. The upper-Ordovician to Silurian samples in northeast Yangtze received higher proportions of local Cryogenian (850–700 Ma) magmatic rocks which were uplifted during late-Ordovician to Silurian time. We speculate that there was an Ediacaran–Cambrian collisional orogen between South China and northern India, shedding sediments to the early Nanhua foreland basin. Far-field stress during the late stage of this collisional orogeny triggered the Ordovician–Silurian intraplate Wuyi–Yunkai orogeny in South China, and erosion of the local Wuyi–Yunkai orogen further provided detritus to the late Nanhua foreland basin.     

A New Diverse Macrofossil Lagerst?tte from the Uppermost Ediacaran of Southwestern China

A new macrofossil Lagerstatte was discovered from the uppermost Ediacaran Jiucheng Member at Jinning and Jiangchuan of the eastern Yunnan, yielding numerous diverse well-preserved thallophyte macrofossils. These include the previously-known representatives of vendobionts, Vendotaenia and Tyrasotaenia, and the biggish multicellular benthos such as Chuaria-like and Tawuia- like fossiis, as well as Longfengshaniaceaens with diverse holdfast structures. There are still some other problematic macrofossils with peculiar configurations as well as uncertain relatives. The distinct dominance of the giant, unbranching thallophytes occasionally with holdfast structures distinguishes this assemblage from the other Ediacaran macrofossil Lagerstattes in the Doushantuo Formation at Miaohe, Wenghui and Lantian, and the contemporary assemblage in the Shibantan Member of Dengying Formation, Yangtze Gorges area. This paper outlines the characteristics of some of the multicellular macrofossils from the Jiucheng Member at Jiangchuan. They include some macrofossils with different types of holdfast structure, larger Chuaria-like and Tawuia-like morphology and questionable affinities as well. The discovery of greater diverse macrofossil assemblages from the Jiucheng Member of eastern Yunnan has further indicated that an important diversification and evolutionary radiation of metaphytes took place in the latest Ediacaran time. This radiation of largescale, benthic metaphyte along with phytoplankton was likely important contributors to the early Cambrian explosion of metazoans.     

Age and magnetic fabric of the Três Córregos granite batholith: evidence for Ediacaran transtension in the Ribeira Belt (SE Brazil)

Anisotropy of magnetic susceptibility (AMS) and U–Pb (SHRIMP) zircon ages in the eastern part of the Três Córregos batholith (Ribeira belt, SE Brazil) indicate a well-defined fabric pattern acquired between 600 and 595 Ma. The batholith consists mostly of porphyritic granites distributed in the Ribeirão Branco, Barra do Chapéu and Itaóca plutons. Late fluorite-bearing alkaline granites, some containing Sn-polymetallic greisen-type deposits, intruded the Ribeirão Branco pluton and the low-grade metasedimentary host rocks. The magnetic fabric of the Ribeirão Branco granite is dominantly oblate and oblique to the pluton elongation while that in Barra do Chapéu is mostly concentric. On both plutons, AMS records the preferred orientation of coarse, homogeneous Ti-poor magnetite grains. Such fabric patterns indicate a partitioned strain field dominated by strike-slip left-lateral shear deformation in the Ribeirão Branco and extension in the Barra do Chapéu pluton. The zircon ages of these plutons are 600 ± 6 Ma and 595 ± 4 Ma. Likewise, the ages of alkaline plutons were in the range of 597 and 595 Ma, registering a fast transition between the typical syntectonic batholithic magmatism to the late, highly evolved and specialized magmas. These results indicate that the Ribeira belt was deformed by transtension in the Middle Ediacaran. The geological setting is consistent with a continental arc with the Três Córregos batholith emplacing at the middle-upper crust.     

Late Ediacaran crustal thickening in Iran: Geochemical and isotopic constraints from the ~550 Ma Mishu granitoids (northwest Iran)

The aim of this article is to examine the geochemistry and geochronology of the Cadomian Mishu granites from northwest Iran, in order to elucidate petrogenesis and their role in the evolution of the Cadomian crust of Iran. The Mishu granites mainly consist of two-mica granites associated with scarce outcrops of tonalite, amphibole granodiorite, and diorite. Leucogranitic dikes locally crosscut the Mishu granites. Two-mica granites show S-type characteristics whereas amphibole granodiorite, tonalities, and diorites have I-type signatures. The I-type granites show enrichment in large-ion lithophile elements (e.g. Rb, Ba and K) and depletion in high field strength elements (e.g. Nb, Ti and Ta). These characteristics show that these granites have been formed along an ancient, fossilized subduction zone. The S-type granites have high K, Rb, Cs (and other large ion lithophile elements) contents, resembling collision-related granites. U–Pb zircon dating of the Mishu rocks yielded ²³⁸U/²⁰⁶Pb crystallization ages of ca. 550 Ma. Moreover, Rb–Sr errorchron shows an early Ediacaran age (547 ± 84 Ma) for the Mishu igneous rocks. The two-mica granites (S-type granites) show high ⁸⁷Sr/⁸⁶Sr_(i) ratios, ranging from 0.7068 to 0.7095. Their ?Nd values change between ?4.2 and ?4.6. Amphibole granitoids and diorites (I-type granites) are characterized by relatively low ⁸⁷Sr/⁸⁶Sr_(i) ratios (0.7048–0.7079) and higher values of ?Nd (?0.8 to ?4.2). Leucogranitic dikes have quite juvenile signature, with ?Nd values ranging from +1.1 to +1.4 and Nd model ages (T_DM) from 1.1 to 1.2 Ga. The isotopic data suggests interaction of juvenile, mantle-derived melts with old continental crust to be the main factor for the generation of the Mishu granites. Interaction with older continental crust is also confirmed by the presence of abundant inherited zircon cores. The liquid-line of descend in the Harker diagrams suggests fractional crystallization was also a predominant mechanism during evolution of the Mishu I-type granites. The zircon U–Pb ages, whole rock trace elements, and Sr–Nd isotope data strongly indicate the similarities between the Mishu Cadomian granites with other late Neoproterozoic–early Cambrian (600–520 Ma) granites across Iran and the surrounding areas such as Turkey and Iberia. The generation of the Mishu I-type granites could be related to the subduction of the Proto-Tethyan Ocean during Cadomian orogeny, through interaction between juvenile melts and old (Mesoproterozoic or Archaean) continental crust. The S-type granites are related to the pooling of the basaltic melts within the middle–upper parts of the thick continental crust and then partial melting of that crust.     

The geodynamic evolution of the Italian South Alpine basement from the Ediacaran to the Carboniferous: Was the South Alpine terrane part of the peri-Gondwana arc-forming terranes?

Zircon U-Pb LA-ICPMS ages were obtained from three metasedimentary and two metavolcanic samples from the Monte Cavallino (South Tyrol) and the Cima Vallona (Carnic Alps) tectono-metamorphic groups from the eastern South Alpine crystalline basement in NE Italy. These analyses were performed to constrain the maximum depositional ages of the South Alpine domain, and to compare the spatial and temporal provenance variations with those of adjacent terranes. The detrital zircon dataset from the metasedimentary rocks (416 grains) yield populations with age peaks at 2.7–2.9 Ga, 1.8–2.1 Ga, 1.2–0.85 Ga, and 0.65–0.45 Ga, with maximum depositional ages ranging from the latest Neoproterozoic to the Silurian. The metavolcanic zircon dataset (209 grains) documents the presence of a two Ordovician volcanic events in the South Alpine domain. The detrital zircon dataset implies that the clastic units of the South Alpine crystalline basement were (a) deposited on the peri-Gondwanan active continental margin and (b) were originally sourced from the Proterozoic and Paleozoic units of NW Gondwana and hence should no longer be considered as exotic elements. The age spectra of the three metasedimentary units highlight differences between the Ediacaran basement gneiss, the Ordovician greywacke, and the Silurian metaconglomerate, suggesting up-section age variations due to a temporal change in provenance. Collectively, these new detrital zircon U-Pb ages imply that the clastic units within the South Alpine domain recorded sedimentation at c. 550 Ma on the peri-Gondwanan active continental margin, followed by rift-related continental and marine sedimentation in a back-arc basin setting until at least the Silurian. The South Alpine domain ultimately rifted off from Gondwana due to back-arc spreading, and subsequently underwent Variscan metamorphism during accretion onto the Laurussia margin, which started at c. 380 Ma and lasted until at least c. 320 Ma.     

Three“first places”for Ediacaran Period

Definition of a new geologic period for the Iast interval of the Proterozoic Eon, the Ediacaran, was recently ratified by the IUGS. The Ediacaran Period is the first Proterozoic period to be recognized on the basis of chronostratigraphic criteria, the first internationally ratified, chronostratigraphically defined period of any age to be introduced in more than 120 years, and the first to be defined by a “golden spike” in the Southern hemisphere.     

Magma associations in Ediacaran granitoids of the Cachoeirinha‒Salgueiro and Alto Pajeú terranes,northeastern Brazil: Forty years of studies

Granitic magmatism in the Cachoeirinha‒Salgueiro and Alto Pajeú terranes in the Transversal Zone Domain of the Borborema Province, northeastern Brazil, occurred in three main time intervals: 650–620 Ma, 590–560 Ma and 545–520 Ma. The oldest one is characterized by intrusions of magmatic-epidote (mEp) bearing calc-alkalic (some with trondhjemitic affinities) and high-K calc-alkalic plutons, synkinematic to the main regional foliation, under contractional tectonic regime, and exhibits T_DM < 2.0 Ga and ƐNd (0.6 Ga) from −1 to −4, and δ¹⁸O (zircon) values from 7.1 to 10‰_VSMOW. O- and Nd-isotope data for the 650‒620 Ma group of plutons is compatible with partial fusion of subducted oceanic basaltic crust (mEp-bearing calc-alkalic tonalites/granodiorites, equivalent to adakites). Voluminous intrusions in the 590–560 Ma interval are represented by abundant mEp-free high-K calc-alkalic, peralkalic, ultrapotassic, mEp-bearing high-K calc-alkalic, and less abundant shoshonitic magmas. Nd-model ages for this group of plutons vary from 1.5 to 2.5 Ga and ƐNd (0.6 Ga) ranges from −8 to −20; δ¹⁸O (zircon) varies from 6.4 to 7.9‰_VSMOW. Values of δ¹⁸O (zircon) for the 590‒560 Ma old group of plutons coupled with Nd isotope data are compatible with remelting of crustal (negative ƐNd, 1.6 to 2.0 Ga old) source rocks. O- and Nd-isotope data for this group of plutons are compatible with underplating of basaltic magma in the base of the lower crust for the high-K calc-alkalic granitoids, coeval to transcurrent movements along sigmoidal shear zones. Intrusion of one shoshonitic (Serrote do Arapuá), one calc-alkalic (Riacho do Icó) plutons besides the peralkalic Manaíra-Princeza Isabel dike set have witnessed this transition from contractional to transcurrent movements along shear zones, around 610‒600 Ma.     

The Itaja�� foreland basin: a tectono-sedimentary record of the Ediacaran period, Southern Brazil

The Itajaí Basin located in the southern border of the Luís Alves Microplate is considered as a peripheral foreland basin related to the Dom Feliciano Belt. It presents an excellent record of the Ediacaran period, and its upper parts display the best Brazilian example of Precambrian turbiditic deposits. The basal succession of Itajaí Group is represented by sandstones and conglomerates (Baú Formation) deposited in alluvial and deltaic-fan systems. The marine upper sequences correspond to the Ribeir?o Carvalho (channelized and non-channelized proximal silty-argillaceous rhythmic turbidites), Ribeir?o Neisse (arkosic sandstones and siltites), and Ribeir?o do Bode (distal silty turbidites) formations. The Apiúna Formation felsic volcanic rocks crosscut the sedimentary succession. The Cambrian Subida leucosyenogranite represents the last felsic magmatic activity to affect the Itajaí Basin. The Brusque Group and the Florianópolis Batholith are proposed as source areas for the sediments of the upper sequence. For the lower continental units the source areas are the Santa Catarina, S?o Miguel and Camboriú complexes. The lack of any oceanic crust in the Itajaí Basin suggests that the marine units were deposited in a restricted, internal sea. The sedimentation started around 600?Ma and ended before 560?Ma as indicated by the emplacement of rhyolitic domes. The Itajaí Basin is temporally and tectonically correlated with the Camaqu? Basin in Rio Grande do Sul and the Arroyo del Soldado/Piriápolis Basin in Uruguay. It also has several tectono-sedimentary characteristics in common with the African-equivalent Nama Basin.     

Zircon U–Pb age constraints on the Paleoproterozoic sedimentary basement of the Ediacaran Porongos Group,Sul-Riograndense Shield,southern Brazil

Thick quartzites record significant information on cratonic environments during long geological periods. The capacity to resist weathering and deformation turn the quartzite covers especially useful in the provenance studies of Precambrian basins. Provenance of 194 detrital zircon grains from two samples of thick quartzite cover on the Paleoproterozoic Encantadas Complex displays mostly Paleoproterozoic (95%) and minor Archean (5%) sources. The results indicate that sediments were derived from the La Plata Craton with the maximum depositional age at 2.03 Ga possibly up to 1.7 Ga. In comparison, the adjacent Porongos Group has provenance data of 61 detrital zircon grains indicating mostly Mesoproterozoic (69%), subordinately Paleoproterozoic (26%) and minor Archean ages (5%). Considering previous published data, the Porongos Group is Ediacaran in age and probably chronocorrelated with sedimentary basins from the Tandilia Belt (Argentina). Therefore, the quartzite cover and the Porongos Group require distinct evolution in time and in tectonic environment.     

Fluctuations in late Neoproterozoic atmospheric oxidation — Cr isotope chemostratigraphy and iron speciation of the late Ediacaran lower Arroyo del Soldado Group (Uruguay)

Oxygenation of the Earth's atmosphere occurred in two major steps, near the beginning and near the end of the Proterozoic Eon (2500 to 542 Ma ago), but the details of this history are unclear. Chromium isotopes in iron-rich chemical sediments offer a potential to highlight fine-scale fluctuations in the oxygenation of the oceans and atmosphere and to add a further dimension in the use of redox-sensitive tracers to solve the question regarding fluctuations of atmospheric oxygen levels and their consequences for Earth's climate. We observe strong positive fractionations in Cr isotopes (δ⁵³Cr up to + 5.0‰) in iron-rich cherts and banded iron formation horizons within the Arroyo del Soldado Group (Ediacaran; Uruguay) that can be explained by rapid, effective oxidation of Fe(II)-rich surface waters. These fluctuations are correlated with variations in ratios of highly reactive iron (Fe_HR) to total iron (Fe_tot) which indicate a predominance of anoxic water columns (Fe_HR/Fe_tot > 0.38) during the onset of oxidation pulses. We favor the scenario by which isotopically heavy Cr(VI) entered the basin after pulses of oxidative weathering on land and in which Fe(II) accumulated in the water column. Neodymium isotopes reveal that these oxygenation pulses were followed by increased influxes to the basin of continental crust-derived detrital components of Paleoproterozoic (Nd T_DM model ages = 2.1–2.2 Ga) provenance typical of the Rio de la Plata Craton. The association of positive δ⁵³Cr–ferruginous (Fe_HR/Fe_tot > 0.38) stratigraphic intervals with low-diversity acritarch assemblages dominated by Bavlinella faveolata strongly support models postulating a stratified, eutrophic Neoproterozoic ocean. Thus, even within a few million years of the Precambrian–Cambrian boundary, paleoceanographic conditions resembled more those of Paleoproterozoic oceans than Phanerozoic and present oceans. This highlights the sheer magnitude of ecological changes at the Precambrian–Cambrian transition, changes which ultimately led to the demise of the Precambrian world and the birth of the metazoan-dominated Phanerozoic.