Chronology of Late Weichselian glaciation in the western part of the East European Plain

A database consisting of radiocarbon (¹⁴C), optically stimulated luminescence (OSL), thermoluminescence (TL) and beryllium (¹⁰Be) dates was used for timing the advance of the Late Weichselian Scandinavian Ice Sheet (SIS), determining the age of the Last Glacial Maximum (LGM) and the rate of deglaciation. The study area encompasses the southeastern sector of the last SIS between the Baltic Sea and the LGM position in the western part of the East European Plain, covering the Karelian Ice‐Stream Complex (ISC) area in the east and the Baltic ISC area in the west. The linear advance and recession rates of the last SIS were estimated to be between 110 and 330 m a^?1 and between 50 and 170 m a^?1, respectively. The onset of the last SIS in the Karelian ISC area reached the western shores of Latvia not before 26 OSL ka, and in the Baltic ISC area, on the southern shores of the Gulf of Finland, not before 21 OSL ka. The last SIS reached close to the LGM position earliest in NW Belarus, not earlier than 22.6 cal. ¹⁴C ka BP, and latest in the NE of Belarus, not earlier than 19.1 cal. ¹⁴C ka BP. The Baltic ISC area between the LGM position and the western shores of Latvia was deglaciated in about 8 ka, and in the Karelian ISC area, between the LGM position and the southern shores of the Gulf of Finland, in about 2.6 ka. The whole area between the LGM position and the Baltic Sea was deglaciated between 14.2 ¹⁰Be ka and 13.3 cal. ¹⁴C ka BP.     

Permeability of Sands in the Coastal Areas of the Southern Baltic Sea: Mapping a Grain-size Related Sediment Property

We compared measurements of vertical permeability, grain size distribution, and porosity from sandy surface sediments in the southern Baltic Sea. Using this information we constructed maps reflecting the permeability within the study area. We found that the formula suggested by Krumbein and Monk (1942) overestimates measured permeabilites on average by a factor 2.6 for the area investigated. The results of a formula including porosity, as in the Carman-Kozeny relation (Carman, 1937), deviated even more from our observations. Vertical heterogeneity of the sediments between 0–10 cm depth and the content of fine particulate material were likely responsible for this phenomenon.Our findings suggest that sediments, classified by averagegrain size based nomenclature as sands, cannot generally be assumed to be highly permeable. Nevertheless, maps constructed mirror the distribution of the average grain size in two data sets we used. For the shallow southern Baltic and an assumed threshold for permeability-effects of2.5 × 10^-12 m², wecalculate >41% of the sea floor to be permeable. An additional 27% may be permeable, but were excluded from calculations due to poor sorting.     

Aeolian sediment transport and deposition in a modern high‐latitude glacial marine environment

Aeolian sand and dust in polar regions are transported offshore over sea ice and released to the ocean during summer melt. This process has long been considered an important contributor to polar sea floor sedimentation and as a source of bioavailable iron that triggers vast phytoplankton blooms. Reported here are aeolian sediment dispersal patterns and accumulation rates varying between 0·2 g m^?2 yr^?1 and 55 g m^?2 yr^?1 over 3000 km² of sea ice in McMurdo Sound, south‐west Ross Sea, adjacent to the largest ice free area in Antarctica. Sediment distribution and the abundance of southern McMurdo Volcanic Group‐derived glass, show that most sediment originates from the McMurdo Ice Shelf and nearby coastal outcrops. Almost no sediment is derived from the extensive ice free areas of the McMurdo Dry Valleys due to winnowed surficial layers shielding sand‐sized and silt‐sized material from wind erosion and because of the imposing topographic barrier of the north‐south aligned piedmont glaciers. Southerly winds of intermediate strength (ca 20 m sec^?1) are primarily responsible for transporting sediment northwards and offshore. The results presented here indicate that sand‐sized sediment does not travel more than ca 5 km offshore, but very‐fine sand and silt grains can travel >100 km from source. For sites >10 km from the coast, the mass accumulation rate is relatively uniform (1·14 ± 0·57 g m^?2 yr^?1), three orders of magnitude above estimated global atmospheric dust values for the region. This uniformity represents a sea floor sedimentation rate of only 0·2 cm kyr^?1, well below the rates of >9 cm kyr^?1 reported for biogenic‐dominated sedimentation measured over much of the Ross Sea. These results show that, even for this region of high‐windblown sediment flux, aeolian processes are only a minor contributor to sea floor sedimentation, excepting areas proximal to coastal sources.     

Nd isotope signature of Holocene Baltic Mn/Fe precipitates as monitor of climate change during the Little Ice Age

Neodymium (Nd) isotope profiles were analyzed on two Baltic Mn/Fe precipitates (99/2 and TL1) from shallow water (20 m) of the Mecklenburg Bay. The age range of these Mn/Fe precipitates determined by ²²⁶Ra_ex/Ba dating reaches from recent growth back to ∼4300 and 1000 yr BP, respectively. Over this time range, the Nd isotope composition varies from ε_Nd (0) = −13.1 to −17.5 in the selected Baltic precipitates indicating substantial changes in the Nd isotope composition of the Baltic Sea. The lowest ε_Nd values were recorded during the time interval of the Little Ice Age (LIA, AD ∼1350 to 1850). These minimum values indicate either an increase of the input of less radiogenic Nd from Scandinavian Archean-Proterozoic sources (ε_Nd about −22) to the Baltic Sea or a decrease of the input of more radiogenic Nd from continental European sources (ε_Nd about −12) and/or North Sea water (ε_Nd about −10). Variations of both, erosive continental input and North Sea inflow may indicate a direct response of the Nd isotope signal in the Baltic Sea to climate changes during the LIA and be related to cyclic shifts in the atmospheric circulation triggered by the North Atlantic Oscillation (NAO). Another aspect that possibly influenced the input of trace elements and Nd isotopes into the Baltic Sea is the population development in the circum Baltic area during the LIA. The lowest ε_Nd values also correspond to the medieval demographic crises that led to a significant decrease of agricultural activity and farmland. The reduction of soil erosion and enhanced regrowth of natural vegetation may have changed the amount and proportions of dissolved and suspended particulate matter transported into the Baltic Sea by rivers which in turn may have resulted in a change of the Nd isotope composition of Baltic Sea water.     

大连周边海域航空重力调查方法及重要成果

为加强海洋地质调查工作,中国地质调查局组织实施了海洋航空地球物理探测及应用项目,在大连海域及其周边,应用GT-1A航空重力测量系统,开展了1∶20万航空重力调查工作,获取了高质量的航空重力数据9.4万测线km,原始测量总精度达到1.27×10^-5 m/s²; 形成了一套覆盖渤海东部、北黄海、辽东半岛和山东半岛的航空重力系列图件,填补了研究区内航空重力资料的空白。通过综合解释与研究,在基底构造形态分析、主要构造单元边界厘定、断裂构造分布特征研究以及局部构造异常圈定等方面取得了重要成果,为研究区海洋区域地质调查、渤海和北黄海的油气资源调查、海陆过渡区关键地质问题的解决提供了重要依据。     

An illustrated key and (palaeo)ecological primer for Postglacial to Recent Ostracoda (Crustacea) of the Baltic Sea

Frenzel, P., Keyser, D. & Viehberg, F.A. 2010: An illustrated key and (pala6e6o)ecological primer for Postglacial to Recent Ostracoda (Crustacea) of the Baltic Sea. Boreas, Vol. 39, pp. 567–575. 10.1111/j.1502‐3885.2009.00135.x. ISSN 0300‐9483 This synopsis of Baltic Sea brackish water Ostracoda gives an overview of all known Recent species for the first time. It also includes Holocene taxa now extinct in the area. There are 131 species, two of which are recorded only from Yoldia stage (Preboreal) sediments. The illustrated key is based exclusively on valve morphology, providing a taxonomical base for geoscience and biological studies using ostracods from the Baltic Sea area. A list of ecological tolerances and preferences as well as the latitudinal distribution of all species is intended as a reference for palaeoenvironmental analyses. Salinity, temperature and oxygen tolerance values as well as preferences for latitudinal distribution, water depth and energy, habitat and substrate are given. The data are based on quantitative sampling in the southern, central and western Baltic Sea and on information gained from literature.     

Marine conditions in central Sweden during the early Preboreal as inferred from a stable oxygen isotope gradient

The marine benthic fauna and the δ¹⁸O_c of foraminifers and ostracods from six sites situated on a west–east transect through central Sweden have been analysed in order to estimate the palaeosalinity and palaeocirculation in this shallow‐marine environment. The measurements have been undertaken on material from the early Preboreal, when the Baltic Basin was in contact with the North Sea through straits in central Sweden. The δ¹⁸O_c values have a more negative value towards the east, indicating decreasing salinity. This was the result of limited possibilities for marine water to penetrate into the Baltic Basin and the mixing with freshwater from the melting Fennoscandian ice‐sheet. Four water masses existed in the area: a surface layer of freshwater, marine water from the North Sea, brackish–marine intermediate water on the Swedish west coast and brackish Yoldia Sea water in the Baltic Basin. The chronology is based on radiocarbon dates of marine fossils and, at one site, on the occurrence of the Vedde Ash (10 400–10 300 ¹⁴C yr BP). This is the first record from marine settings in Sweden. Copyright © 2001 John Wiley & Sons, Ltd.     

Stress analysis and tectonic trends of southern Sinai Peninsula, using potential field data analysis and anisotropy technique

The aim of the present work is to evaluate the stress direction and the tectonic trends of the study area using magnetic anisotropy and potential field data interpretations (Bouguer and aeromagnetic). The specific objective of the gravity and aeromagnetic interpretation is to establish the trend and depth of the structural configuration of the basement rocks. Horizontal gradient techniques could to delineate directions of deep sources and enabled tracing several faults, lineaments and tectonic boundaries of basement rocks. The trend analysis shows N40°?C50°W, N10°?C20°W and N10°?C20°E which may be related to the Gulf of Suez, Red Sea and Gulf of Aqaba stresses. However, Euler Deconvolution technique was applied using the aeromagnetic data to provide reliable information about penetrated source depth (100 m and ??10.0 km) and trends of the subsurface sources (principally in NW and NE directions). Moreover, representative 72 oriented rock samples have been collected from seven sites in the study area. The rock magnetic properties and magnetic anisotropy analysis have been determined for all the studied samples. The interpretation clearly defined magnetic lineation at all sites and anisotropy of magnetic susceptibility (AMS) parameters. The stress direction of the studied area has been evaluated using magnetic anisotropy and geophysical analysis. Generally the estimated geophysical data analysis (Bouguer and aeromagnetic) are well consistent with the AMS interpretations of this study. The results indicated that the directions of predominant faults and foliations are NW-SE (related to the Gulf of Suez and Red Sea rifting) which indicate that the main stress and tectonic trend is NE-SW, which is more predominant in southern Sinai region. Moreover, it is clear that, the studied area was affected also by less predominant sources trended in NE-SW direction, which related to the tectonic activity of Gulf of Aqaba. The least predominant is north 40°?C50° east that is probably due to the Syrian Arc system. Finally, our results are extremely coincided with the previous stress directions derived from geological, seismological and tectonic analysis in northern Red Sea rift, Gulf of Suez and Sinai regions.     

Ferromanganese nodules of the Baltic Sea: Composition,helium isotopes,and growth rate

Results of the study of shallow-water ferromanganese nodules in the Gulf of Finland of the Baltic Sea, which are of practical interest for metallurgical and chemical industries, are discussed. The nodules contain the following elements: Mn, Fe, Si, Al, Na, Mg, Ti, K, V, Cu, Ni, Zn, P, and Ba. Contents of Mn (～30%) and Fe (～10%) are virtually similar to those in deep-sea oceanic nodules. However, concentrations of Ti, Cu, and Ni are notably lower than average values in oceanic nodules. The helium isotopic composition was studied to reveal cosmic dust in the nodule substance. The measured ³He and ⁴He concentrations are ～10^?12 and ～10^?5 cm³/g, respectively. The isotope ratio ³He/⁴He is approximately 10^?7. More than 60% ³He is of cosmic (solar) origin, whereas ⁴He is of terrigenous (radiogenic) origin. Based on the cosmic duct concentration and the space tracer method, the FMN growth rate is estimated at 8–9 mm/ka at the nodule age varying from ～800 to 1500 yr. The growth rate of nodule has negative correlation with its size. Based on literature data, the growth rate of FMN from the western Baltic Sea is twice as high. An independent calculation of the FMN growth rate based on the diffusion-sorption mechanism (DSM) yielded 8.1 mm/ka, which is very close to the result based on the space tracer method. This value is proposed as the average growth rate of the studied nodules. Comparison with our previous measurements of growth rates for oceanic nodules showed that these values differ only slightly and are equal to n mm/ka, where n < 10. It is inferred that the formation mechanism of both marine and oceanic nodules is based on the same principles that control the generation of mobile forms of Mn in the bottom layer of sediments, i.e., principles related to bioproductivity of sea and ocean basins. Fluxes of lithogenic forms of Mn are of minor importance.     

2 1/2 and 3 dimensional interpretation of magnetic anomalies in the central-southern Pyrenees (Spain)

Abstract

Available aeromagnetic data have been used to interprete magnetic anomalies using 2 1/2 and 3 D techniques in an area that includes parts of the Axial Zone and of the South Pyrenean Thrust Sheets in the Spanish Pyrenees. The interpretation has been made with the help of field magnetic susceptibility measurements. The dip of the Ebro Basin basement to the north has been inferred for part of the magnetic profile. Large magnetically disturbing bodies with the top at about sea level can be interpreted as a stack of Paleozoic basement thrusts or, alternatively, as an accumulation of Triassic volcanic rocks. Some smaller anomalies are clearly associated with outcropping or buried basaltic rocks (ophites). The disposition of major magnetic anomalies suggests that shear movement may have affected part of the studied area.     

Distribution,production and consumption of nitrous oxide in the Baltic Sea

Nitrous oxide supersaturation was measured in the Bothnian Bay, Bothnian Sea and four depth zones of the Baltic proper along with O₂, NO^?₃, NO^?₂ and other parameters useful in interpreting the sources of the N₂O. In the Baltic Sea supersaturation of N₂O (123%) was found in the surface water of 0 to 0.5 m. The supersaturation resulted in a flux of N₂O to the atmosphere of 2.8 × 10^?2Tg N · yr^?1 which was 5% of the estimated total nitrogen loss for the Baltic. For the entire photic zone (0 to 20 m) the N₂O saturation was 135%. The source of the N₂O is not clear, as the nitrification and denitrification were ruled out as sources. The N₂O saturation was the lowest (118%) in the intermediate zone. Nitrification appears to be the likely N₂O sorce in this region. At the halocline zone, an increasing oversaturation of N₂O (200 to 300%) correlated with decreasing O₂ concentrations and increasing NO^?₃ concentrations, indications of nitrification. Of the NH⁺₄ that was oxidized to NO^?₃, 0.56% was produced as N₂O. In the deep water zone, the supersaturation of N₂O remained very high (150 to 200%). Sufficient O₂, high NO^?₃ and the presence of nitrifying activity suggested nitrification as most likely source, however in deeper waters of this zone where oxygen was less than 2% saturation the N₂O production could be due to denitrification. In anoxic waters the N₂O concentrations rapidly decreased to zero suggesting N₂O consumption by denitrification, further evidenced by a developing nitrate anomaly.     

Benthic Phosphorus Dynamics in the Gulf of Finland, Baltic Sea

Benthic fluxes of soluble reactive phosphorus (SRP) and dissolved inorganic carbon (DIC) were measured in situ using autonomous landers in the Gulf of Finland in the Baltic Sea, on four expeditions between 2002 and 2005. These measurements together with model estimates of bottom water oxygen conditions were used to compute the magnitude of the yearly integrated benthic SRP flux (also called internal phosphorus load). The yearly integrated benthic SRP flux was found to be almost 10 times larger than the external (river and land sources) phosphorus load. The average SRP flux was 1.25?±?0.56?mmol?m^?2?d^?1 on anoxic bottoms, and ?0.01?±?0.08?mmol?m^?2?d^?1 on oxic bottoms. The bottom water oxygen conditions determined whether the SRP flux was in a high or low regime, and degradation of organic matter (as estimated from benthic DIC fluxes) correlated positively with SRP fluxes on anoxic bottoms. From this correlation, we estimated a potential increase in phosphorus flux of 0.69?±?0.26?mmol?m^?2?d^?1 from presently oxic bottoms, if they would turn anoxic. An almost full annual data set of in situ bottom water oxygen measurements showed high variability of oxygen concentration. Because of this, an estimate of the time which the sediments were exposed to oxygenated overlying bottom water was computed using a coupled thermohydrodynamic ocean?Csea and ecosystem model. Total phosphorus burial rates were calculated from vertical profiles of total phosphorus in sediment and sediment accumulation rates. Recycling and burial efficiencies for phosphorus of 97 and 3%, respectively, were estimated for anoxic accumulation bottoms from a benthic mass balance, which was based on the measured effluxes and burial rates.     

Relationship between the Extent of Igneous Rocks and Deep Structures as Determined by Gravitational and Magnetic Data in the South China Sea

The distribution of oil and gas resources in the South China Sea and adjacent areas is closely related to the structural pattern that helped to define the controlling effect of deep processes on oil-bearing basins.Igneous rocks can record important information from deep processes.Deep structures such as faults,basin uplift and depression,Cenozoic basement and magnetic basement are all the results of energy exchange within the earth.The study of the relationship between igneous rocks and deep structures is of great significance for the study of the South China Sea.By using the minimum curvature potential field separation technique and the correlation analysis technique of gravitational and magnetic anomalies,the fusion of gravitational and magnetic data reflecting igneous rocks can be obtained,through which the igneous rocks with high susceptibility/high density or high susceptibility/low density can be identified.In this study area,igneous rocks do not develop in the Yinggehai basin,Qiongdongnan basin,Zengmu basin and Brunei-Sabah basin whilst igneous rocks with high susceptibility/high density or high susceptibility/low density are widely-developed in other basins.In undeveloped igneous areas,faults are also undeveloped the Cenozoic thickness is greater,the magnetic basement depth is greater and the Cenozoic thickness is highly positively correlated with the magnetic basement depth.In igneously developed regions,the distribution pattern of the Qiongtai block is mainly controlled by primary faults,while the distribution of the Zhongxisha block,Xunta block and Yongshu-Taiping block is mainly controlled by secondary faults,the Cenozoic thickness having a low correlation with the depth of the magnetic basement.     

Crustal architecture of the Thomson Orogen in Queensland inferred from potential field forward modelling

The basement rocks of the poorly understood Thomson Orogen are concealed by mid-Paleozoic to Upper Cretaceous intra-continental basins and direct information about the orogen is gleaned from sparse geological data. Constrained potential field forward modelling has been undertaken to highlight key features and resolve deeply sourced anomalies within the Thomson Orogen. The Thomson Orogen is characterised by long-wavelength and low-amplitude geophysical anomalies when compared with the northern and western Precambrian terranes of the Australian continent. Prominent NE- and NW-trending gravity anomalies reflect the fault architecture of the region. High-intensity Bouguer gravity anomalies correlate with shallow basement rocks. Bouguer gravity anomalies below –300 µm/s² define the distribution of the Devonian Adavale Basin and associated troughs. The magnetic grid shows smooth textures, punctuated by short-wavelength, high-intensity anomalies that indicate magnetic contribution at different crustal levels. It is interpreted that meta-sedimentary basement rocks of the Thomson Orogen, intersected in several drill holes, are representative of a seismically non-reflective and non-magnetic upper basement. Short-wavelength, high-intensity magnetic source bodies and colocated negative Bouguer gravity responses are interpreted to represent shallow granitic intrusions. Long-wavelength magnetic anomalies are inferred to reflect the topography of a seismically reflective and magnetic lower basement. Potential field forward modelling indicates that the Thomson Orogen might be a single terrane. We interpret that the lower basement consists of attenuated Precambrian and mafic enriched continental crust, which differs from the oceanic crust of the Lachlan Orogen further south.     

A possible Caledonide arm through the Barents Sea imaged by OBS data

The assembly of the crystalline basement of the western Barents Sea is related to the Caledonian orogeny during the Silurian. However, the development southeast of Svalbard is not well understood, as conventional seismic reflection data does not provide reliable mapping below the Permian sequence. A wide-angle seismic survey from 1998, conducted with ocean bottom seismometers in the northwestern Barents Sea, provides data that enables the identification and mapping of the depths to crystalline basement and Moho by ray tracing and inversion. The four profiles modeled show pre-Permian basins and highs with a configuration distinct from later Mesozoic structural elements. Several strong reflections from within the crystalline crust indicate an inhomogeneous basement terrain. Refractions from the top of the basement together with reflections from the Moho constrain the basement velocity to increase from 6.3 km s⁻¹ at the top to 6.6 km s⁻¹ at the base of the crust. On two profiles, the Moho deepens locally into root structures, which are associated with high top mantle velocities of 8.5 km s⁻¹. Combined P- and S-wave data indicate a mixed sand/clay/carbonate lithology for the sedimentary section, and a predominantly felsic to intermediate crystalline crust. In general, the top basement and Moho surfaces exhibit poor correlation with the observed gravity field, and the gravity models required high-density bodies in the basement and upper mantle to account for the positive gravity anomalies in the area. Comparisons with the Ural suture zone suggest that the Barents Sea data may be interpreted in terms of a proto-Caledonian subduction zone dipping to the southeast, with a crustal root representing remnant of the continental collision, and high mantle velocities and densities representing eclogitized oceanic crust. High-density bodies within the crystalline crust may be accreted island arc or oceanic terrain. The mapped trend of the suture resembles a previously published model of the Caledonian orogeny. This model postulates a separate branch extending into central parts of the Barents Sea coupled with the northerly trending Svalbard Caledonides, and a microcontinent consisting of Svalbard and northern parts of the Barents Sea independent of Laurentia and Baltica at the time. Later, compressional faulting within the suture zone apparently formed the Sentralbanken High.     

Apport de la modélisation géophysique pour la compréhension de la structuration du pas de Calais

This study is based on an analysis of seismic, gravimetric and magnetic data to model the structure of the Dover Straits area. The Dover Straits are set in a transitional position within the Brabant para-autochthon, which lies between the Ardennes allochthon to the south and the Brabant Massif to the north. The seismic profiles show that this area is characterised by several superimposed Mesozoic basins, whose evolution has been controlled by the reactivation of Lower Palaeozoic faults. In common with the adjacent Weald–Wessex and southern North Sea basins, the Dover Straits area records a Jurassic extensional phase and a post-Cretaceous tectonic inversion. The geophysical modelling reveals the presence of a basement to these Mesozoic basins that exhibits Ordovician to Silurian structures, which cannot be detected on the seismic reflection profiles. In contrast to earlier interpretations, the modelling presented here suggests that the Brabant Massif continues southward beyond the Dover Straits and under the Brabant para-autochthon. Gravity data also provides evidence for the presence of granitic body at depth, in the vicinity of Km 27 on the seismic profile, which may have driven the uplift of the Silurian rocks in the area of the Straits. Similar granitic intrusions have been proposed to explain gravity anomalies along the Rhenohercynian Margin in Belgium, eastern and southern England. The geophysical modelling demonstrates the continuity of the basement and Mesozoic basin structures across the Dover Straits, suggesting a common geological evolution of the adjacent southern England–northern France regions. To cite this article: B. Minguely et al., C. R. Geoscience 337 (2005).     

The geology of the southeastern Baltic Sea: a review

The Baltic Sea, particularly its southeastern part, is discussed in the paper. Investigations of regional character as well as specialized studies in the area are reviewed. General historical works are mentioned briefly. Previous surveys since the 1950s are presented by the subject studied. The compilation of geological structure of the SE Baltic Sea bottom and adjacent land of Balticum (Baltic States: Estonia, Latvia, Lithuania) is based on considerable amounts of summarized materials. The crystalline basement, sedimentary cover and Quaternary deposits are characterized in the comprehensive survey of geological structure. From a stratigraphical point of view, geological sequence of the platformal cover is comparatively complete: deposits of all geological systems (from the Archean to Cenozoic) are present in the Baltic Syneclise. Considering geotectonical cycles, the sedimentary cover of the syneclise is subdivided into four structural complexes. The thickness and distribution of Quaternary deposits are closely related to the recent bottom relief of the Baltic Sea that in turn is inherited from the Pre-Quaternary surface. Buried palaeo-valleys are characteristic of the Pre-Quaternary surface in the Baltic region and the Baltic Sea bottom. The Quaternary is characterized by layers of various geneses and by sharp changes of their thicknesses.     

Phosphorus recycling and burial in Baltic Sea sediments with contrasting redox conditions

In this study, redox-dependent phosphorus (P) recycling and burial at 6 sites in the Baltic Sea is investigated using a combination of porewater and sediment analyses and sediment age dating (²¹⁰Pb and ¹³⁷Cs). We focus on sites in the Kattegat, Danish Straits and Baltic Proper where present-day bottom water redox conditions range from fully oxygenated and seasonally hypoxic to almost permanently anoxic and sulfidic. Strong surface enrichments of Fe-oxide bound P are observed at oxic and seasonally hypoxic sites but not in the anoxic basins. Reductive dissolution of Fe-oxides and release of the associated P supports higher sediment-water exchange of PO₄ at hypoxic sites (up to ∼800 μmol P m⁻² d⁻¹) than in the anoxic basins. This confirms that Fe-bound P in surface sediments in the Baltic acts as a major internal source of P during seasonal hypoxia, as suggested previously from water column studies. Most burial of P takes place as organic P. We find no evidence for significant authigenic Ca-P formation or biogenic Ca-P burial. The lack of major inorganic P burial sinks makes the Baltic Sea very sensitive to the feedback loop between increased hypoxia, enhanced regeneration of P and increased primary productivity. Historical records of bottom water oxygen at two sites (Bornholm, Northern Gotland) show a decline over the past century and are accompanied by a rise in values for typical sediment proxies for anoxia (total sulfur, molybdenum and organic C/P ratios). While sediment reactive P concentrations in anoxic basins are equal to or higher than at oxic sites, burial rates of P at hypoxic and anoxic sites are up to 20 times lower because of lower sedimentation rates. Nevertheless, burial of reactive P in both hypoxic and anoxic areas is significant because of their large surface area and should be accounted for in budgets and models for the Baltic Sea.     

MIS 3 marine and lacustrine sediments at Kriegers Flak,southwestern Baltic Sea

Anjar, J., Larsen, N. K., Björck, S., Adrielsson, L. & Filipsson, H. L. 2010: MIS 3 marine and lacustrine sediments at Kriegers Flak, southwestern Baltic Sea. Boreas, 10.1111/j.1502‐3885.2010.00139.x. ISSN 0300‐9483. Sediment cores from the Kriegers Flak area in the southwestern Baltic Sea show a distinct lithological succession, starting with a lower diamict that is overlain by a c. 10 m thick clay unit that contains peat, gyttja and other organic remains. On top follows an upper diamict that is inter‐layered with sorted sediments and overlain by an upward‐coarsening sequence with molluscs. In this paper we focus on the clay unit, which has been subdivided into three subunits: (A) lower clay with benthic foraminifera and with diamict beds in the lower part; (B) thin beds of gyttja and peat, which have been radiocarbon‐dated to 31–35 ¹⁴C kyr BP (c. 36–41 cal. kyr BP); and (C) upper clay unit. Based on the preliminary results we suggest the following depositional model: fine‐grained sediments interbedded with diamict in the lower part (subunit A) were deposited in a brackish basin during a retreat of the Scandinavian Ice Sheet, probably during the Middle Weichselian. Around 40 kyr BP the area turned into a wetland with small ponds (subunit B). A transgression, possibly caused by the damming of the Baltic Basin during the Kattegat advance at 29 kyr BP, led to the deposition of massive clay (subunit C). The data presented here provide new information about the paleoenvironmental changes occurring in the Baltic Basin following the Middle Weichselian glaciation.     

Stream chloride concentrations as a function of land use: a comparison of an agricultural watershed to an urban agricultural watershed

The concentration of chloride (Cl^?) in streams in northern regions has increased as a result of applications of deicers. This study focused on quantifying the relationship between land use and stream Cl^? concentrations. The study area comprises two adjacent watersheds in central Illinois, with similar geology and climate but different land uses (agricultural and urban). GIS analysis delineated watershed land use and calculated road surface areas. Stream water samples were collected and analyzed for anionic composition. During the winter months, streams dominated with urban land use experienced a 20-fold increase in Cl^? concentrations (range between 36 and 1350 mg L^?1); Cl^? concentrations in agricultural dominated streams also increased, but the increase was smaller (3X) and concentrations remained low (between 11 and 58 mg L^?1). As road salts are not the sole source of Cl^? in a stream, Cl^? and bromide (Br^?) mass ratios (Cl/Br) and Cl^? and sodium (Na) molar ratios ([Cl]/[Na]) were used to identify potential sources of Cl^?. The ratios indicate urbanized watersheds were impacted by road salts; agricultural watersheds ratios indicate other anthropogenic sources. A nonlinear relationship between urban land use and stream Cl^? concentrations indicates urban land use as low as 23% results in elevated Cl^? concentrations (greater than 150 mg L^?1) in stream waters.