Granitic magmatism,basement ages,and provenance indicators in the Malay Peninsula: Insights from detrital zircon U–Pb and Hf-isotope data

The Malay Peninsula lies on two continental blocks, Sibumasu and East Malaya, which are intruded by granitoids in two provinces: the Main Range and Eastern. Previous models propose that Permian–Triassic granitoids are subduction-related and syn-to post-collisional. We present 752 U–Pb analyses that were carried out on zircons from river sands in the Malay Peninsula; of these, 243 grains were selected for Hf-isotope analyses. Our data suggest a more complex Sibumasu–East Malaya collision history. ¹⁷⁶Hf/¹⁷⁷Hf_i ratios reveal that Permian–Triassic zircons were sourced from three magmatic suites: (a) Permian crustally-derived granitoids, (b) Early-Middle Triassic granitoids with mixed mantle–crust sources, and (c) Late Triassic crustally-derived granitoids. This suggests three Permian–Triassic episodes of magmatism in the Malay Peninsula, two of which occurred in the Eastern Province. Although the exact timing of the Sibumasu–East Malaya collision remains unresolved, current data suggest that it occurred before the Late Triassic, probably in Late Permian–Early Triassic. Our data also indicate that Sibumasu and East Malaya basements are chronologically heterogeneous, but predominantly of Proterozoic age. Some basement may be Neoarchaean but there is no evidence for basement older than 2.8 Ga. Finally, we show that Hf-isotope signatures of Triassic zircons can be used as provenance indicators.     

New insights into peri-Gondwana paleogeography and the Gondwana super-fan system from detrital zircon U–Pb ages

We present a synopsis of detrital zircon U–Pb ages of sandstones from North Africa and neighboring Israel and Jordan, which allows us to identify zones with characteristic sediment provenance along the northern Gondwana margin (in present-day coordinates) in Cambrian–Ordovician times, and helps us to unravel the peri-Gondwana jigsaw puzzle. A special feature of the early Paleozoic cover sequence of North Africa is the eastward increase of 1.1–0.95 Ga detrital zircons, which become ubiquitous in the early Paleozoic sandstones of the Saharan Metacraton. Detrital zircons aged about 2.7–2.5, 2.15–1.75 and 0.75–0.53 Ga are also present. Early Paleozoic sandstones with similar provenance are known from peri-Gondwana terranes in the Eastern and Western Mediterranean and from NW Iberia. These terranes need not be transported from western Gondwana (Amazonia) as suggested previously. They were likely located to the north of the Saharan Metacraton during the early Paleozoic before they rifted off from Gondwana. Furthermore, we recognize an increase, as stratigraphic ages get younger, of ca. 1.0 Ga detrital zircons at some point between the Late Cambrian and late Middle Ordovician. We speculate that this might be linked to far-field tectonics and regional uplift in central Gondwana related to plate-tectonic reorganization along the Gondwana margin, leading to erosion of ca. 1.0 Ga basement and country rocks of the Transgondwanan supermountain and fluvial dispersal of detritus toward the Gondwana margin.     

The U–Pb ages and Hf isotopes of detrital zircons from Hainan Island,South China: implications for sediment provenance and the crustal evolution

In situ U–Pb dating and Hf isotopic of detrital zircons from beach sediments of Yalong Bay were analyzed to trace sedimentary provenance and reveal the crustal evolution of Hainan Island in South China. The grain size distribution of the sediments displays a clear single-peak feature, indicating the sediments were formed under the same condition of hydrodynamic force. The detrital zircons had Th/U ratios of greater than 0.1, and REE pattern displayed a positive Ce anomaly and a negative Eu anomaly, indicating that these zircons are predominantly of magmatic origin. The U–Pb spectrum of detrital zircons mainly peaked at the Yanshanian (96–185 Ma), Hercynian–Indosinian (222–345 Ma) and Caledonian (421–477 Ma). A portion of the detrital zircons were of Neoproterozoic origin (728–1,003 Ma), which revealed that the basement in the eastern region of Hainan Island was mainly of Neoproterozoic, with rare Archean materials. The positive ε _Hf(t) values (0 to +10.1) of the Neoproterozoic detrital zircons indicated that the juvenile crust grew in the southeastern Hainan Island mainly during the Neoproterozoic period. The Neoproterozoic orogeny in the southeastern part of the island (0.7–1.0 Ga) occurred later than in the northwestern region of the island (1.0–1.4 Ga). Importantly, the Grenvillian orogeny in the southeastern area of Hainan Island shared the same timing with that of the western Cathaysia Block; i.e., both areas concurrently underwent this orogenic event, thereby forming a part of the Rodinia supercontinent. Afterwards, the crust experienced remelting and reworking during the Caledonian Hercynian–Indosinianand Yanshanian accompanied by the growth of a small amount of juvenile crust.     

U–Pb detrital zircon evidence of transcontinental sediment dispersal: provenance of Late Mississippian Wedington Sandstone member,NW Arkansas

ABSTRACT

U–Pb ages of detrital zircons from the Wedington Sandstone member in northwest Arkansas provide evidence for Late Mississippian westward transcontinental sediment transport from the Appalachian foreland. The Late Mississippian Wedington Sandstone member of the Fayetteville Shale is a fine- to medium-grained quartzarenite. It separates the Fayetteville Shale into informal lower and upper intervals, and was deposited as a small constructive delta complex that prograded towards the south and southeast during the Late Mississippian. As a major influx of clastic sediments, the Wedington Sandstone member records the sediment source and dispersal in the mid-continent during the Late Mississippian. A total of 559 detrital zircon grains from six Wedington samples were recovered for U–Pb detrital zircon geochronological analysis. Results show that age distributions can be subdivided into six groups: ~350–500, ~900–1350, ~1360–1500, ~1600–1800, ~1800–2300, and > ~2500 Ma, and are characterized by a prominent peak for the age group of ~900–1350 Ma, a major peak at ~1600–1800 Ma, and a few other minor age clusters. Regional correlation and geological evidence from surrounding areas suggest that the transcontinental sediment dispersal started as early as the Late Mississippian. U–Pb detrital zircon age distribution suggests that the Wedington Sandstone member was likely derived from the Appalachian foreland with contributions from the Nemaha Ridge to the west where the Yavapai–Mazatzal sources were exposed during the Late Mississippian. Sediment was likely transported westward through or around the Illinois Basin, merged with mid-continent sediment, and then entered into its current location in northwest Arkansas. Transportation of this sediment from mixed sources continued along its course to the south, forming a delta on the Northern Arkansas Structural Platform.     

Sedimentological characteristics and new detrital zircon SHRIMP U–Pb ages of the Babulu Formation in the Fohorem area,Timor-Leste

Sedimentological characteristics and zircon provenance dating of the Babulu Formation in the Fohorem area, Timor-Leste, provide new insights into depositional process, detailed sedimentary environment and the distribution of source rocks in the provenance. Detrital zircon sensitive high-resolution ion microprobe (SHRIMP) U–Pb ages range from Neoarchean to Triassic, with the main age pulses being Paleozoic to Triassic. In addition, the maximum deposition ages based on the youngest major age peak (ca 256–238 Ma) of zircon grains indicate that the basal sedimentation of the Babulu Formation occurred after the early Upper Triassic. The formation consists predominantly of mudstone with minor sandstone, limestone and conglomerate that were deposited in a deep marine environment. These deposits are composed of six lithofacies that can be grouped into three facies associations (FAs) based on the constituent lithofacies and bedding features: basin plain deposits (FA I), distal fringe lobe deposits (FA II) and medial to distal lobe deposits (FA III). The predominance of mudstone (FA I) together with intervening thin-bedded sandstones (FA II) suggest that the paleodepositional environment was a low energy setting with slightly basin-ward input of the distal part of the depositional lobes. Discrete and abrupt occurrences of thick-bedded sandstone (FA III) within the FA I mudstone suggests that sandstone originated from a collapse of upslope sediments rather than a progressive progradation of deltaic turbidites. This combined petrological and geochronological study demonstrates that the Babulu Formation in the Fohorem area of the Timor-Leste was initiated as a submarine lobe system in a relatively deep marine environment during the Upper Triassic and represents the extension of the Gondwana Sequence at the Australian margin.     

U–Pb detrital zircon geochronology and its implications: The early Late Triassic Yanchang Formation,south Ordos Basin,China

U–Pb detrital zircon geochronology has been used to identify provenance and document sediment delivery systems during the deposition of the early Late Triassic Yanchang Formation in the south Ordos Basin. Two outcrop samples of the Yanchang Formation were collected from the southern and southwestern basin margin respectively. U–Pb detrital zircon geochronology of 158 single grains (out of 258 analyzed grains) shows that there are six distinct age populations, 250–300 Ma, 320–380 Ma, 380–420 Ma, 420–500 Ma, 1.7–2.1 Ga, and 2.3–2.6 Ga. The majority of grains with the two oldest age populations are interpreted as recycled from previous sediments. Multiple sources match the Paleozoic age populations of 380–420 and 420–500 Ma, including the Qilian–Qaidam terranes and the North Qilian orogenic belt to the west, and the Qinling orogenic belt to the south. However, the fact that both samples do not have the Neoproterozoic age populations, which are ubiquitous in these above source areas, suggests that the Late Triassic Yanchang Formation in the south Ordos Basin was not derived from the Qilian–Qaidam terranes, the North Qilian orogenic belt, and the Qinling orogenic belt. Very similar age distribution between the Proterozoic to Paleozoic sedimentary rocks and the early Late Triassic Yanchang Formation in the south Ordos Basin suggests that it was most likely recycled from previous sedimentary rocks from the North China block instead of sediments directly from two basin marginal deformation belts.     

U–Pb detrital zircon data of the Rio Fuerte Formation (NW Mexico): Its peri-Gondwanan provenance and exotic nature in relation to southwestern North America

U–Pb detrital zircon studies in the Rio Fuerte Group, NW Mexico, establish its depositional tectonic setting and its exotic nature in relation to the North American craton. Two metasedimentary samples of the Rio Fuerte Formation yield major age clusters at 453–508 Ma, 547–579 Ma, 726–606 Ma, and sparse quantities of older zircons. The cumulative age plots are quite different from those arising from lower Paleozoic miogeoclinal rocks of southwestern North America and of Cordilleran Paleozoic exotic terranes such as Golconda and Robert Mountains. The relative age-probability plots are similar to some reported from the Mixteco terrane in southern Mexico and from some lower Paleozoic Gondwanan sequences, but they differ from those in the Gondwanan-affinity Oaxaca terrane. Major zircon age clusters indicate deposition in an intraoceanic basin located between a Late Ordovician magmatic arc and either a peri-Gondwanan terrane or northern Gondwanaland. The U–Pb magmatic ages of 151 ± 3 Ma from a granitic pluton and 155 ± 4 Ma from a granitic sill permit a revision of the stratigraphic and tectonic evolution of the Rio Fuerte Group. A regional metamorphism event predating the Late Jurassic magmatism is preliminarily ascribed to the Late Permian amalgamation of Laurentia and Gondwana. The Late Jurassic magmatism, deformation, and regional metamorphism are related to the Nevadan Orogeny.     

Jurassic detrital zircon U–Pb and Hf isotopic geochronology of Luxi Uplift,eastern North China,and its provenance implications for tectonic–paleogeographic reconstruction

Relatively successive sequences of Late Mesozoic are preserved and exposed in Luxi Uplift (LU), eastern North China block (NCB), which is an important region to study the late Mesozoic tectonic evolution of the eastern NCB. In this study, in situ U–Pb ages and Hf isotopic analyses on detrital zircons from the sandstones of Jurassic Fangzi and Santai Formations in LU combining the analysis of sandstone detrital modes were performed, with an aim to trace the Jurassic sediment provenances and the tectonic–paleogeographic configuration of eastern NCB. Three sandstone samples (one from Fangzi Formation and two from Santai Formation) have very similar U–Pb age spectrums which can be divided into three major groups: Phanerozoic (I), Paleoproterozoic (II), and Neoarchean (III). Detrital zircons of Group II and Group III broadly match the age spectra of the basement of NCC which exposed extensively in the northern part. No middle Neoproterozoic magmatic zircons or Triassic metamorphic zircons were found in this study, ruling out the clastic provenance transported from the Sulu orogen to LU. Dominant zircon populations of Group Iare Late Paleozoic (250–393 Ma) recording the corresponding magmatic activities which are not found both in LU and its peripheral tectonic terranes, but can be well compared with that of the northern NCB (NNCB) and the Xing-Meng Orogenic Belt (XMOB). Furthermore, Hf isotope compositions of the Phanerozoic detrital zircons can be distinctly divided into two clusters with ε_Hf(t) values ranging from −1.0 to +12.7 and −21.9 to −3.0, respectively resemble those from the XMOB and NCB (mainly from NNCB). Sandstone detrital modes analysis indicates the provenance came from the areas that have been eroded deeply to expose the basement rocks which accords with the tectonic setting of the NNCB. This research proposes that an evident mountain or provenance region once increasingly developed along NNCB during Early to Late Jurassic (182–155 Ma) due to the continuous collision of the Siberia and North China–Mongolian plates, easily shed mass clastic materials southward into the inner NCB and became the major provenance of Jurassic sediments in LU.     

Detrital zircons U–Pb SHRIMP ages and provenance of La Modesta Formation,Patagonia Argentina

This paper summarizes the geology of the Paleozoic La Modesta Formation in Patagonia, Argentina, and presents new SHRIMP U–Pb dating of detrital zircons from muscovite-chlorite schist and tourmalinite. Also complementary geochemical and lead isotopic data are presented, indicating that the protoliths were formed from upper crustal rocks by the contribution of a large input from recycled (or felsic) sources. The maximum age of sedimentation of La Modesta Formation is about 446 ± 6 Ma. The basin closure (or eventually a paleocurrent shift) occurs at Lower Devonian before the exhumation of the Middle-Devonian granitoids of the Rio Deseado Complex (Deseado Massif). Many of the detrital zircons are igneous and record Ordovician ages, with a prominent Lower Ordovician-age peak at approximately 473 Ma. Most favourable candidates to provide the younger zircons in the basin would Ordovician granites of the Rio Deseado Complex (Deseado Massif) and Punta Sierra Plutonic Complex (Somun Cura Massif). Older zircons have peaks of different importance (including Brasiliano and Grenvillian ages) between 530 and 700, 750–1500, 1750–2000 and 2550–2700 Ma. La Modesta Formation is also a potential area of materials (detrital zircon) to the basin where the rocks of the Eastern Andean Metamorphic Complex and equivalent formations of the Andean region were generated.     

The provenance and tectonic affinity of the Paleozoic meta-sedimentary rocks in the Chinese Tianshan belt: New insights from detrital zircon U–Pb geochronology and Hf–isotope analysis

The tectonic evolution of the Chinese Tianshan Belt which is located in the southern margin of the Central Asian Orogenic Belt remains controversial. In order to reveal the evolutionary history of this belt, we investigate metasedimentary rocks from the Tianshanmiao of Harlik domain and Xingxingxia area of central Tianshan domain in this study. The Permian siltstones from Xingxingxia contain six zircon populations with ages peak at 280, 815 and 910, 1590, 1855 and 2340 Ma, suggesting a diverse provenance. The 2544–2294 Ma ages correlate with the generation of continental nuclei in Tarim. The tectonothermal events during 1855, 1590, 910 and 815 Ma may correspond to the assembly and breakup of the Columbia and Rodinia supercontinents, respectively. Similar Precambrian age spectra and “event signature” curves suggest that the central Tianshan was most likely a part of the Tarim block in the Proterozoic. The detrital zircon U–Pb ages of Ordovician meta-greywackes from the Tianshanmiao sequence reveal six zircon populations with peaks at 460, 933, 1382, 1850, 2000 and 2462 Ma, among which the zircons with dominant age peaks (460 Ma and 930 Ma, more than 70%) are euhedral, low sphericity and exhibit clear oscillatory zoning, suggesting local derivation from the proximal Ordovician and Neoproterozoic granitoids. The range of εHf(t) values (−5.4 to +21) of zircon grains from Ordovician rocks suggests that these were derived from depleted mantle or through partial melting of juvenile crust, similar to the case for the Early Paleozoic magmatism in Chinese Altai. Our detrital zircon data suggest that the provenance of the Harlik was neither the Tarim nor the Junggar, and instead, we propose a connection with the Chinese Altai-Tuva–Mongol Arc along the southern margin of the Siberia craton at ∼500 Ma. The Harlik domain drifted southward and then collided with the central Tianshan in the Carboniferous-Permian as a result of the closure of Paleo-Tianshan Ocean.     

SHRIMP U–Pb detrital zircon ages from Proterozoic and Early Palaeozoic sandstones and their bearing on the early geological evolution of Tasmania

Detrital zircons from 13 Late Mesoproterozoic to Early Neoproterozoic sandstones and two Palaeozoic sandstones from Tasmania were dated in order to improve constraints on depositional ages, to test correlation between Proterozoic inliers, and to characterise source regions. These include successions considered to be the oldest presently exposed in Tasmania. Typical features of the age distributions of the Proterozoic rocks are prominent data concentrations at 1800–1650 Ma and 1450–1400 Ma, and a minor spread of Archaean ages. Statistical testing of the similarity of the age profiles shows that widespread quartzarenaceous samples from the Detention Subgroup, Needles Quartzite and from the Tyennan region are strongly similar, consistent with broad correlation. Relatively large differences are seen between the Detention Subgroup and the conformable, stratigraphically higher Jacob Quartzite, which contains an additional spread of 1300–1000 Ma zircons suggestive of a Grenvillian source. Age profiles of the quartzarenites and quartzwacke turbidites (Oonah Formation and correlatives) cannot be readily differentiated. The Oonah Formation likewise includes samples with and without Grenvillian ages, and there is no 750 Ma zircon population that would be expected if the turbidites were genetically related to the Wickham Orogeny. The simplest interpretation is that the quartzarenites (Rocky Cape Group and correlatives) and the turbidites (Oonah Formation and correlates) are lateral equivalents, although a younger (post-Wickham Orogeny) age for the Oonah Formation cannot be discounted. A maximum age of ca 1000 Ma is inferred for the Oonah Formation, Rocky Cape Group and correlatives. A minimum age of ca 750 Ma is provided by the basal age of the overlying Togari Group and correlatives. In a metasediment from western King Island, the youngest detrital zircons are ca 1350 Ma, allowing a pre-Grenvillian depositional age as suggested by previous dating of metamorphic monazite. However, the age profile of this sample is not dissimilar to the other Tasmanian successions that are inferred to be 1000–750 Ma. The Wings Sandstone, of southern Tasmania, contains an unusual profile dominated by Grenvillian ages, consistent with an allochthonous origin. Basement ages that broadly match the age spectra of the Tasmanian Proterozoic sediments are found in southwestern Laurentia, consistent with mutual proximity in Rodinia reconstructions. The Palaeozoic sandstones, from the turbiditic Mathinna Supergroup of northeastern Tasmania, have zircon age profiles typical of the Lachlan Fold Belt, with a predominant latest Neoproterozoic-Early Cambrian component and a lesser, broad Proterozoic data concentration at ca 1000 Ma. Western Tasmania was not a significant part of the source area for these rocks.     

Geochemistry and detrital zircon U–Pb dating of Pliocene-Pleistocene sandstones of the Chittagong Tripura Fold Belt (Bangladesh): Implications for provenance

The Bengal Basin originated during the collision of India with Eurasia and Burma. The provenance analysis of the Chittagong Tripura Fold Belt (CTFB), which is the folded eastern flank of the Bengal Basin as well as the Neogene belt of the Indo-Burman Ranges (IBR) is key to better understand the possible sources of sediment input from the complex interplay of the Indian, Eurasian and Burma plates. We report new whole rock geochemical and detrital zircon U–Pb data from the upper Neogene sandstones of Tipam-Dupi Tila formations (Pliocene to Plio-Plestocene succession) from the CTFB. Detrital zircon U–Pb age spectra show three predominant peaks at <200 Ma, 480–650, ∼800–1000 Ma. The geochemical discriminations and elemental ratios of Eu/Eu* (∼0.70), La/Sc (∼16.13), La/Co (∼15.76), Th/Sc (∼2.95), La/Th (∼5.67), Th/Co (∼2.87), Cr/Th (∼4.63) as well as Chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomalies for the Tipam and Dupi Tila formations are suggestive of a dominantly felsic source area experiencing moderate to intensive chemical weathering (Chemical index of alteration, CIA - 57 to 81) and have a recycled provenance orogen related to active continental or passive margin settings. Integrated geochemical and zircon U–Pb studies reveal that the main sediment input might have been from the Himalayan orogen with significant arc-derived detritus, possibly from the Gangdese arc as well as from the Burma magmatic arc.     

Contrasting provenance of Late Archean metasedimentary rocks from the Wutai Complex, North China Craton: detrital zircon U–Pb, whole-rock Sm–Nd isotopic, and geochemical data

Detrital zircon U–Pb ages, whole-rock Nd isotopic, and geochemical data of metasedimentary rocks from the Wutai Complex in the Central Zone, North China Craton, have been determined. Compositionally, these rocks are characterized by a narrow variation in SiO₂/Al₂O₃ (2.78–3.96, except sample 2007-1), variable Eu anomalies, spanning a range from significantly negative Eu anomalies to slightly positive anomalies (Eu/Eu* = 0.58–1.12), and positive ε _Nd (t) values (0.1–1.97). The 18 detrital zircons of one sample yielded age populations of 2.53 Ga, 2.60 Ga, and 2.70–2.85 Ga. Geochemical data reveal intermediate source weathering, varying degrees of K-metasomatism in the majority of these metasedimentary rocks, whereas other secondary disturbances seem to be negligible. Detailed analysis in detrital zircon U–Pb geochronology, whole-rock Nd isotope, and geochemistry shows that these metasedimentary rocks are derived from a mixed provenance. The predominant derivation is from the late Archean granitoids and metamorphic volcanics in the Wutai Complex, and there is also input of older continental remnants, except TTG gneisses, from the Hengshan and Fuping Complexes. The sediments were probably deposited in fore-arc or/and intra-arc basins within an arc system.     

Collision-related genesis of the Sharang porphyry molybdenum deposit,Tibet: Evidence from zircon U–Pb ages,Re–Os ages and Lu–Hf isotopes

Sharang is a low-fluorine, calc-alkaline porphyry Mo deposit hosted mainly in a granite porphyry of a multi-stage plutonic complex in the northern Gangdese metallogenic belt, largely with stockwork and ribbon-textured mineralization. The observed age estimates suggest that the formation of the magmatic host complex (52.9–51.6 Ma) and the ore deposit itself (52.3 Ma) occurred during the main stage of the India–Asia collision. The host rocks are characterized by lower zircon ε_Hf(t) values than those of the pre-ore and post-ore rocks. This suggests that the Lhasa terrane basement might play an important role in the formation of Sharang ore-forming intrusions. In view of the framework of magmatic–metallogenic events we suggest that slab roll-back may have induced melting of juvenile crust and ancient continental complexes during the India–Asia collision. This proposal focuses exploration for additional molybdenum deposits on the collision zone.     

The Pacific Gondwana margin in the late Neoproterozoic–early Paleozoic: Detrital zircon U–Pb ages from metasediments in northwest Argentina reveal their maximum age,provenance and tectonic setting

U–Pb detrital zircon ages are reported from Puncoviscana Formation (late Neoproterozoic–Early Cambrian) and Mesón Group (Late Cambrian) greywackes of northwest Argentina, to constrain provenance and depositional environment.The new data are combined with previously-published detrital zircon ages, to show that Puncoviscana Formation age patterns contain two broad groups: late Mesoproterozoic–early Neoproterozoic (1150–850 Ma) and late Neoproterozoic–Early Cambrian (650–520 Ma); with their relative proportions varying inversely with youngest component age. The 1150–850 Ma age components are dominant in greywackes with oldest late Neoproterozoic components > 600 Ma. The former diminish considerably when late Neoproteozoic components become dominant and younger, to 520 Ma. A northernmost greywacke sample from Purmamarca, Jujuy, is distinctive: whilst its zircon age pattern partly resembles other Puncoviscana Formation samples, it contains no Cambrian–late Neoproterozoic ages, the youngest ages being early Neoproterozoic. This may reflect an early, Neoproterozoic, passive-margin depocentre for the Formation, or an older (early Neoproterozoic) succession within it, which may predate the Brasiliano orogeny in Brazil. The youngest age components, c. 520 Ma, in a greywacke from Rancagua (Cachi, Salta province), dominate an almost unimodal pattern suggestive of contemporary volcanic sources at a late Early Cambrian depocentre. Detrital zircon age patterns of the Mesón Group (Lizoite Formation) have major Cambrian–latest Neoproterozoic components resembling those of the Puncoviscana Formation, but its Mesoproterozoic component is diminished, and there are no significant age components of this age. Small youngest components at c. 500 Ma suggest a maximum Late Cambrian stratigraphic age. The Puncoviscana Formation detrital zircon patterns suggest a provenance in a continental hinterland having a stabilised, extensive late Mesoproterozoic orogen (with minor Paleoproterozoic and Archean precursors), and a more variable late Neoproterozoic orogen containing an evolving sequence of less extensive subcomponents. A direct relationship with the Brazilian Shield is suggested; with sediment supplies originating within active-margin orogens of the interior and collisional orogens at the suture between African and South American cratons, but ultimate deposition in passive-margin environments of western Gondwanaland.     

Provenance of Pleistocene Rhine River Middle Terrace sands between the Swiss–German border and Cologne based on U–Pb detrital zircon ages

Detrital zircon U–Pb age distributions derived from samples representing ancient or relatively young large-scale continental drainage networks are commonly taken to reflect the geochronological evolution of the tapped continental area. Here, we present detrital zircon U–Pb ages and associated heavy mineral data from Pleistocene Rhine River Middle Terrace sands and equivalents between the Swiss–German border and Cologne in order to test the commonly assumed Alpine provenance of the material. Samples from eight localities were analyzed for their heavy mineral assemblages. Detrital zircon U–Pb ages were determined by laser ablation inductively coupled mass spectrometry on selected samples from five locations along the Rhine River. The zircon age populations of all samples show a similar distribution, their main peaks being between 300 and 500 Ma. Minor age populations are recognized at 570 and 1,070 Ma. The 300–400 Ma maximum reflects the Variscan basement drained by or recycled into the Rhine River and its tributaries. The 400–500 Ma peak with predominantly Early Silurian ages points to Baltica or to the mid-German crystalline rise as original sources. One distinct peak at c. 570 Ma probably represents input from Cadomian terranes. The Precambrian U–Pb ages are compatible with derivation from sources in Baltica and in northern Gondwana. The heavy mineral populations of Middle Terrace sands and equivalents are characterized to a variable extend by garnet, epidote, and green hornblende. This association is often referred to as the Alpine spectrum and is considered to be indicative of an Alpine provenance. However, hornblende, epidote, and garnet are dominant heavy minerals of collisional orogens in general and may also be derived from Variscan and Caledonian units or from intermittent storage units. A remarkable feature of the detrital zircon age distribution in the Rhine River sediments from the Swiss–German border to Cologne is the absence of ages younger than 200 Ma and in particular of any ages reflecting the Alpine orogeny between c. 100 and 35 Ma. Sediments from rivers draining the equally collisional Himalaya orogen contain detrital zircons as young as 20 Ma. Our results question the assumption that Pleistocene Rhine River sediments were directly derived from the Alps. The lag time between the formation and deposition age of the youngest zircon in the studied Pleistocene Rhine River deposits is 200 Ma. Together with the absence of Alpine zircon ages, this stresses that detrital zircon age data from ancient sedimentary units found in poorly understood tectonic or paleogeographic settings need to be interpreted with great care, one could miss an entire orogenic cycle.     

U–Pb detrital zircon ages of sediments from the Firgoun and Niamey areas (eastern border of West African Craton,West Niger)

This study uses field observations and new U–Pb ages of detrital zircon grains from three samples to question the stratigraphic position of the Firgoun and Niamey siliciclastic sediments, presumed to be Neoproterozoic in age. Sharing several lithological similarities with the Late Cryogenian “Triad” of the Taoudenni, Gourma, and Volta basins, the uppermost siliciclastic sediments of the Firgoun and Niamey areas were likely also deposited during this period. This is corroborated by matrix-supported diamictites with faceted or striated pebbles as well as by structures resembling cryoturbation processes. However, the detrital zircon U–Pb age record that we present here for the lowermost deposits of Firgoun and Niamey provides mainly Paleoproterozoic ages, and very few Archean ages, altogether in a range from 1822 ± 9 to 3392 ± 9 Ma. Therefore, the new data only show that the Firgoun and Niamey sediments were deposited before about 1800 Ma. Nevertheless, the U–Th–Pb zircon age data allows examining the possible provenance of the sediments. We show that the latter was likely in the westerly close vicinity of the studied areas. The Archean zircons are likely inherited, and possibly originating from a more westerly source. The nearby source of the Niamey and Firgoun sediments suggests that a high topographic relief was still existing in the south-central part of the West African Craton in the Mid Neoproterozoic.     

From Gondwana to Europe: The journey of Elba Island (Italy) as recorded by U–Pb detrital zircon ages of Paleozoic metasedimentary rocks

Elba Island, located midway between Corsica and mainland Italy, is a small but important fragment of the Adria Plate. It has a rich sedimentary record preserved in a stack of tectonic nappes of both continental margin and oceanic origin. Especially the detrital zircons in early Paleozoic to early Mesozoic metasedimentary rocks provide an archive of many important geological events in the island's history. Elba Island and Adria originated along the northern margin of Gondwana, but drifted north in Silurian times to become part of Europe. A large new dataset of LA-ICP-MS and SIMS U–Pb zircon ages allows us to trace this history. Three main stratigraphic units have been investigated. The oldest Porto Azzurro Unit was deposited in the early Cambrian and has zircon age distributions indicating a typical northern African provenance, most likely sourced from the Saharan Metacraton. The Ortano Unit has a simple, mostly unimodal Ordovician age distribution that is entirely dominated by metavolcanic rocks and their erosional products; a sample of the metavolcanic Ortano Porphyroids provided a SIMS U–Pb zircon age of 460 ± 3 Ma. This phase of intense volcanism is related to the subduction of the Rheic Ocean beneath Gondwana, terminating with initial rifting and subsequent opening of the Paleotethys. This also marks the onset of the separation of a range of European terranes, including Adria and future Elba Island, from Gondwana. The Permo-Triassic Monticiano–Roccastrada Unit is the first to show a European provenance with the appearance of large amounts of Variscan and late to post-Variscan detritus. The presence of Variscan detrital zircons in the Permo-Triassic sediments is unexpected, since a Variscan age signature is so far not well recorded in the Adria Plate. This dataset is the most comprehensive detrital zircon dataset so far available for the Adria Plate and documents Adria's close affinity to Africa in the Lower Paleozoic, as well as its initial rifting within an active continental margin setting during the Ordovician and its final separation and independent evolution since late Palaeozoic times.     

Laser-ICP-MS U–Pb zircon ages and geochemical and Sr–Nd–Pb isotopic compositions of the Niyasar plutonic complex,Iran: constraints on petrogenesis and tectonic evolution

We conducted geochemical and isotopic studies on the Oligocene–Miocene Niyasar plutonic suite in the central Urumieh–Dokhtar magmatic belt, in order better to understand the magma sources and tectonic implications. The Niyasar plutonic suite comprises early Eocene microdiorite, early Oligocene dioritic sills, and middle Miocene tonalite + quartzdiorite and minor diorite assemblages. All samples show a medium-K calc-alkaline, metaluminous affinity and have similar geochemical features, including strong enrichment of large-ion lithophile elements (LILEs, e.g. Rb, Ba, Sr), enrichment of light rare earth elements (LREEs), and depletion in high field strength elements (HFSEs, e.g. Nb, Ta, Ti, P). The chondrite-normalized rare earth element (REE) patterns of microdiorite and dioritic sills are slightly fractionated [(La/Yb)_n = 1.1–4] and display weak Eu anomalies (Eu/Eu* = 0.72–1.1). Isotopic data for these mafic mantle-derived rocks display I_Sr = 0.70604–0.70813, ?_Nd (microdiorite: 50 Ma and dioritic sills: 35 Ma, respectively) = +1.6 and ?0.4, TDM = 1.3 Ga, and lead isotopic ratios are (²⁰⁶Pb/²⁰⁴Pb) = 18.62–18.57, (²⁰⁷Pb/²⁰⁴Pb) = 15.61–15.66, and (²⁰⁸Pb/²⁰⁴Pb) = 38.65–38.69. The middle Miocene granitoids (18 Ma) are also characterized by relatively high REE and minor Eu anomalies (Eu/Eu* = 0.77–0.98) and have uniform initial ⁸⁷Sr/⁸⁶Sr (0.7065–0.7082), a range of initial Nd isotopic ratios [?Nd(T)] varying from ?2.3 to ?3.7, and Pb isotopic composition (²⁰⁶Pb/²⁰⁴Pb) = 18.67–18.94, (²⁰⁷Pb/²⁰⁴Pb) = 15.63–15.71, and (²⁰⁸Pb/²⁰⁴Pb) = 38.73–39.01. Geochemical and isotopic evidence for these Eocene–Ologocene mafic rocks suggests that the magmas originated from lithospheric mantle with a large involvement of EMII component during subduction of the Neotethyan ocean slab beneath the Central Iranian plate, and were significantly affected by crustal contamination. Geochemical and isotopic data of the middle Miocene granitoids rule out a purely crustal-derived magma genesis, and suggest a mixed mantle–crustal [MASH (melting, assimilation, storage, and homogenization)] origin in a post-collision extensional setting. Sr–Nd isotope modelling shows that the generation of these magmas involved ～60% to 70% of a lower crustal-derived melt and ～30% to 40% of subcontinental lithospheric mantle. All Niyasar plutons exhibit transitional geochemical features, indicating that involvement of an EMII component in the subcontinental mantle and also continental crust beneath the Urumieh–Dokhtar magmatic belt increased from early Eocene to middle Miocene time.     

Late Permian–Triassic siliciclastic provenance,palaeogeography, and crustal growth of the Songpan terrane,eastern Tibetan Plateau: evidence from U–Pb ages,trace elements,and Hf isotopes of detrital zircons

In order to constrain the detrital provenance of the siliciclastic rocks, palaeogeographic variations, and crustal growth history of central China, we carried out simultaneously in situ U–Pb dating and trace element and Hf isotope analyses on 368 detrital zircons obtained from upper Permian–Triassic sandstones of the Songpan terrane, eastern Tibetan Plateau. Two groups of detrital zircons, i.e. magmatic and metamorphic in origin, have been identified based on cathodoluminescence images, zircon Ti-temperatures, and Th/U ratios. Our data suggest that the derivation of siliciclastic rocks in the Songpan terrane was mainly from the Qinling, Qilian, and Kunlun orogens, whereas the Yangtze and North China Cratons served as minor source areas during late Permian–Triassic times. The detrital zircons from Middle–Late Triassic siliciclastic rocks exhibit wide age spectra with two dominant populations of 230–600 Ma and >1600 Ma, peaking at ~1.8–1.9 Ga and ~2.4–2.5 Ga, suggestive of a derivation from the Qinling, Qilian, and Kunlun orogens and the Yangtze Craton being the minor source area. The proportions of detrital zircon populations from the northern Qinling, Qilian, and Kunlun orogens distinctly decreased during Middle–Late Triassic time, demonstrating that the initial uplift of the western Qinling occurred then and it could have blocked most of the detritus from the Qilian–northern Qinling orogens and North China Cratons into the main Songpan–Ganzi depositional basin. The relatively detrital zircon proportions of the Yangtze Craton source decreased during Early-Middle Late Triassic time, indicating that the Longmenshan orogen was probably being elevated, since the early Late Triassic and gradually formed a barrier between the Yangtze Craton and the Songpan terrane. In addition, our Lu–Hf isotopic results also reveal that the Phanerozoic magmatic rocks in central China had been the primary products of crustal reworking with insignificant formation of a juvenile crust.