Sedimentary palaeoenvironment,petrography, provenance and diagenetic inference of the Anacleto Formation in the Neuquén Basin,Late Cretaceous,Argentina

The Anacleto Formation is the uppermost unit of the Neuquén Group, which makes up the foreland stage infill of the Neuquén Basin, during Late Cretaceous. The detailed sedimentological study performed in the excellent outcrops of this formation on the eastern border of the basin allowed the identification of eight fluvial lithofacies, grouped into six facies associations. A meandering fluvial system with palaeo flows from the SW can be interpreted from distribution of facies associations, architectural framework, channel/floodplain ratio, etc. The compositional analysis of the sandstones was performed by mean of petrographic characterization and modal analysis. Sandstones of the Anacleto Fm are mainly subarkosic, arkosic, lithic arenites and, to a lesser extent, sublitoarenites (Q₅₄-F₂₅-R₂₁; Q₅₂-F₂₄-L₂₅). The composition suggests underlying igneous, metamorphic and sedimentary rocks in the main source area. Sedimentological and petrographic analyses, jointly with palaeocurrents orientations suggest that high areas of the North Patagonian Massif were the main source of the fluvial system. The diagenetic stages interpreted from the petrographic characters, SEM observations and X-ray diffraction determine eodiagenesis and telodiagenesis, which are consistent with the burial history of the Neuquén Group. Furthermore, palaeoclimatic considerations based on compositional analysis suggest semiarid to semihumid conditions for the deposition of the Anacleto Fm. These conditions are also supported by clay mineralogy that confirmed smectite as dominant species. A strong climatic seasonality is also deduced by the presence of calcrete levels and frequent discharge channels.     

An integrate analysis of an Hauterivian coral biostrome from the Agrio Formation,Neuquén Basin,west-central Argentina

A coral biostrome from the lower Hauterivian of the Neuquén Basin, west-central Argentina, was examined in detail. Taxonomic analysis established it as a monospecific assemblage of the scleractinian colonial coral Stereocaenia triboleti (Koby). Palaeoecological analysis of the species allows us to infer that it was an opportunistic species, capable of thriving in mixed carbonate-siliciclatic environments, on a soft substrate under a moderate to low sedimentation rate showing great regenerative capacity. Taphonomic analysis, together with lithofacies and microfacies analysis, allowed us to establish that the coral biostrome was deposited in a middle ramp setting under open marine and well-oxygenated conditions. Corals colonized a soft substrate during a transgressive phase and reaching its climax in the maximum flooding zone under lowest clastic input. They managed to form a low coral meadow of ramose forms of up to 30 cm in height. Coral remains were exposed on the interface after death and thus were subject to severe encrustation and bioerosion. The coral biostrome is interpreted as a mixed biogenic-sedimentologic skeletal concentration deposited by an interplay of an initial biogenic concentration through later episodes of physical reworking, probably storms, which yielded a largely parautochthonous fossil assemblage with minimum lateral transport. As sedimentation rate increased during a highstand interval, the coral-dominated community could not cope with it and was finally buried. The described coral biostrome recorded at the base of a shallowing-upwards cycle closely resembles coral biostromes described from the Hauterivian of Peru and Turkmenistan, and differs significantly from framework reef facies recorded in the Hauterivian of the Tethys region from the Paris Basin to Crimea.     

Anatomy and facies distribution of terminal lobes in ephemeral fluvial successions: Jurassic Tordillo Formation,Neuquén Basin,Argentina

In terminal fluvial-fan systems, characteristic proximal to distal variations in sedimentary architectures are recognized to arise from progressive downstream loss of water discharge related to both infiltration and evaporation. This work aims to elucidate downstream trends in facies and architecture across the medial and distal zones of terminal-fan systems, which record transitions from deposits of channel elements to lobe-like and sheet-like elements. This is achieved via a detailed characterization of ancient ephemeral fluvial deposits of the well-exposed Kimmeridgian Tordillo Formation (Neuquén Basin, Argentina). The fine sand-prone and silt-prone succession associated with the medial to distal sectors of the system has been studied to understand relationships between depositional processes and resulting architectures. Facies and architectural-element analyses, and quantification of resulting sedimentological data at multiple scales, have been undertaken to characterize sedimentary facies, facies transitions, bed types, architectural elements and larger-scale architectural styles. Eight bed types with distinct internal facies transitions are defined and interpreted in terms of different types of flood events. Channelized and non-channelized architectural elements are defined based on their constituent bed types and their external geometry. The most common elements are terminal lobes, which are composite bodies within which largely unconfined sandy deposits are stacked in a compensational manner; a hierarchical arrangement of internal components is recognized. Proximal feeder-channel avulsion events likely controlled the evolution of terminal-lobe elements and their spatiotemporal shifts. Stratigraphic relations between architectural elements record system-wide trends, whereby a proximal sector dominated by channel elements passes downstream via a gradational transition to a medial sector dominated by sandy terminal-lobe elements, which in turn passes further downstream to a distal sector dominated by silty terminal lobe-margin and fringing deposits. This work enhances current understanding of the stratigraphic record of terminal fluvial systems at multiple scales, and provides insight that can be applied to predict the facies and architectural complexity of terminal fluvial successions.     

Revision of Valanginian Steinmanellinae bivalves from the Neuquén basin,West-central Argentina,and their biostratigraphic implications

We present a new species of Steinmanella Crickmay from the Valanginian of the Neuquén Basin, west-central Argentina, and at the same time update a Valanginian–earliest Barremian bivalve zonation which is integrated into the local, Chilean and European standard ammonoid zonations. Steinmanella caicayensis sp. nov. presents a moderately inflated shell, a subtriangular outline, well-developed carinae and a straight to moderately convex anterior margin. Steinmanella is very abundant in the Tithonian–Barremian interval in the basin and thus provides an ideal opportunity to perform detailed taxonomic and stratigraphic studies; a former zonation based on these trigonioids is here revised and expanded with a thorough revision of Valanginian occurrences based on new material. Two new zones are proposed, namely the S. quintucoensis and S. caicayensis zones, encompassing Valanginian times. The proposed bivalve zonation encompassing the Valanginian–earliest Barremian time interval can be useful in correlating with other southwestern Gondwanan regions, such as Perú, Chile, South Africa, Tanzania, and India, where Steinmanella has been recorded.     

Retrowedge-related Carboniferous units and coeval magmatism in the northwestern Neuquén province, Argentina

The studied Carboniferous units comprise metasedimentary (Guaraco Norte Formation), pyroclastic (Arroyo del Torreón Formation), and sedimentary (Huaraco Formation) rocks that crop out in the northwestern Neuquén province, Argentina. They form part of the basement of the Neuquén Basin and are mostly coeval with the Late Paleozoic accretionary prism complex of the Coastal Cordillera, south-central Chile. U–Pb SHRIMP dating of detrital zircon yielded a maximum depositional age of 374?Ma (Upper Devonian) for the Guaraco Norte Formation and 389?Ma for the Arroyo del Torreón Formation. Detrital magmatic zircon from the Guaraco Norte Formation are grouped into two main populations of Devonian and Ordovician (Famatinian) ages. In the Arroyo del Torreón Formation, zircon populations are also of Devonian and Ordovician (Famatinian), as well as of Late Neoproterozoic and Mesoproterozoic ages. In both units, there is a conspicuous population of Devonian magmatic zircon grains (from 406?±?4?Ma to 369?±?5?Ma), indicative of active magmatism at that time range. The ε_Hf values of this population range between ?2.84 and ?0.7, and the TDM-(Hf) are mostly Mesoproterozoic, suggesting that the primary sources of the Devonian magmatism contained small amounts of Mesoproterozoic recycled crustal components. The chemical composition of the Guaraco Norte Formation corresponds to recycled, mature polycyclic sediment of mature continental provenance, pointing to a passive margin with minor inputs from continental margin magmatic rocks. The chemical signature of the Huaraco Formation indicates that a magmatic arc was the main provenance for sediments of this unit, which is consistent with the occurrence of tuff—mostly in the Arroyo del Torreón Formation and very scarcely in the Huaraco Formation—with a volcanic-arc signature, jointly indicating the occurrence of a Carboniferous active arc magmatism during the deposition of the two units. The Guaraco Norte Formation is interpreted to represent passive margin deposits of mostly Lower Carboniferous age (younger than 374?Ma and older than 326?Ma) that precede the onset of the accretionary prism in Chile and extend into the earliest stage of the accretion, in a retrowedge position. The Arroyo del Torreón and Huaraco formations are considered to be retrowedge basin deposits to the early frontal accretionary prism (Eastern Series) of Chile. The presence of volcanism with arc signature in the units provides evidence of a Mississippian magmatic arc that can be correlated with limited exposures of the same age in the Frontal Cordillera (Argentina). The arc would have migrated to the West (Coastal Batholith) during Pennsylvanian–Permian times (coevally with the later basal accretionary prism/Western Series). The source of a conspicuous population of Devonian detrital zircon interpreted to be of magmatic origin in the studied units is discussed in various possible geotectonic scenarios, the preferred model being a magmatic arc developed in the Chilenia block, related to a west-dipping subduction beneath Chilenia before and shortly after its collision against Cuyania/Gondwana, at around 390?Ma and not linked to the independent, Devonian–Mississippian arc, developed to the south, in Patagonia.     

Southern Hemisphere Early Cretaceous (Valanginian-Early Barremian) carbon and oxygen isotope curves from the Neuquén Basin,Argentina

The first carbon and oxygen isotope curves for the Valanginian to Early Barremian (Early Cretaceous) interval obtained from outcrops in the Southern Hemisphere are presented. They were obtained from well-dated (by ammonites) sediments from the Neuquén Basin, Argentina. Measurements were acquired by the innovative method of analysing fossil oyster laminae. The occurrence of the well-established mid-Valanginian positive carbon isotope excursion is documented, while less well-marked positive events may also correlate with peaks identified in the well-known successions of SE France. The mid-Valanginian positive carbon isotope event in the Neuquén Basin is possibly associated with organic-rich sediments. A similar relationship is seen in the European Alps and in oceanic cores in some areas of the world.     

Synsedimentary ash rains and paleoenvironmental conditions during the deposition of the Chachil Formation (Pliensbachian) at its type locality,Neuquén Basin,Argentina

A detailed sedimentological analysis of the so called “Chachil Limestones” at its type locality around the Mirador del Chachil area, southwestern Neuquén province, Argentina, is presented in this paper for the first time. It is based on a macro/microfacial analysis and their environmental interpretation by means on texture, fabric, bioclasts, intrabasinal and extrabasinal grain amounts, sedimentary structures, bioturbations and hydro-dynamism. Because of the recognition of different facies associations, but no pure limestones, it is more suitable to refer these sediments as the Chachil Formation. The depositional environment of this unit is interpreted to correspond to an internal platform dominated by tides, with carbonate sedimentation disturbed by repeated explosive volcanic episodes, which reduced the sedimentation space, causing retrogradation of the sedimentary system and coastal onlap. In addition, a new recalibration of the U-Pb zircon dating used for the geochronological analysis reveals a small change with regard to previous information that has been used to recalculate the data, is presented in this paper.     

Taxonomy and paleoecology of a new gastropod fauna from dysoxic outer ramp facies of the Lower Cretaceous Agrio Formation,Neuquén Basin,west-central Argentina

Four gastropod species are described from dysaerobic biofacies of the lower part of the Agua de la Mula Member of the Agrio Formation, Neuquén Basin: Metacerithium turriculatum (Forbes, 1845), Nerineopsis acutecarinatum (Behrendsen, 1891) and the new species Ampullina pichinka and Mesalia? kushea. They were active epifaunals and possibly deposit-feeders and/or browsers, and epifaunal to semi-infaunal possibly suspension- or deposit-feeder in the case of M.? kushea, thriving in soft to firm substrates. These gastropods, together with two aporrhaid species, are the dominant components of a typically small-sized, low-diversity macrobenthic fauna that occurs in dark, organic-rich shales. The facies in which this fauna is recorded are thought to represent a transition from lower to upper outer ramp marine settings, in the context of a second-order TST and early stages of a HST. They record a transition from lower dysoxic conditions in the lowest part of the Agua de la Mula Member to upper dysoxic conditions upwards. Two distinct gastropod biofacies were recognized corresponding to the two identified stages: biofacies A, dominated by Protohemichenopus neuquensis and N. acutecarinatum, more tolerant to dysoxic conditions, and biofacies B, dominated by M. turriculatum and Mesalia? kushea, less tolerant to oxygen deficiency.     

Magnetostratigraphy of the Upper Jurassic–Lower Cretaceous from Argentina: Implications for the J-K boundary in the Neuquén Basin

A systematic sedimentologic and paleomagnetic study was carried out in the Vaca Muerta Formation, cropping out in the northern Neuquén Basin, west-central Argentina. The studied section is c. 280 m-thick and represents a carbonate ramp system bearing ammonites that indicate Late Jurassic–Early Cretaceous ages. The Vaca Muerta Formation is one of the most important unconventional hydrocarbon reservoirs in the world and its thorough study has become a relevant target in Argentina. The J-K boundary is comprised within this unit, and although it is well-dated through biostratigraphy (mainly ammonites), the position of particularly the boundary is yet a matter of hot debate. Therefore, the systematic paleomagnetic and cyclostratigraphic study in the Vaca Muerta Formation was considered relevant in order to obtain the first Upper Jurassic–Lower Cretaceous magnetostratigraphy of the southern hemisphere on the first place and to precise the position of the J-K boundary in the Neuquén Basin, on the other. Biostratigraphy is well studied in the area, so that paleomagnetic sampling horizons were reliably tied, particularly through ammonites. Almost 450 standard specimens have been processed for this study distributed along 56 paleomagnetic sampling horizons that were dated using ammonites. Paleomagnetic behaviours showed to be very stable, and their quality and primary origin have been proved through several paleomagnetic field tests The resultant magnetostratigraphic scale is made up of 11 reverse and 10 normal polarity zones, spanning the Andean Virgatosphinctes mendozanus (lower Tithonian) to Spiticeras damesi Zones (upper Berriasian). These polarity zones were correlated with those of the International Geomagnetic Polarity Time Scale 2012 and 2016 through the correlation between Andean and Tethyan ammonite zones. Cyclostratigraphy on the other hand, proved to be quite consistent with the magnetostratigraphy. Through the correlation of the resultant paleomagnetic and cyclostratigraphic data, it was possible to date the section with unprecedented precision, and therefore, to establish the position of the Jurassic-Cretaceous boundary. The paleomagnetic pole calculated from the primary magnetization is located at: Lon = 191.6°E, Lat = 76.2°S, A₉₅ = 3.5°, indicating a c. 24° clockwise rotation for the studied section, which is consistent with structural data of the region.     

The oldest theropods from the Neuquén Basin: Predatory dinosaur diversity from the Bajada Colorada Formation (Lower Cretaceous: Berriasian–Valanginian), Neuquén,Argentina

Here, we describe new theropod materials (several isolated teeth, an axis, two caudal centra and a proximal left tibia) from the type locality of the Bajada Colorada Formation (Lower Cretaceous, Berriasian–Valanginian). Although fragmentary, the recovered material shows a diverse association of meat-eating dinosaurs for this poorly understood period of time. Three techniques were used to assess the phylogenetic position of the isolated teeth: multivariate (PCA), discriminant and phylogenetic analyses. The morphotypes 1, 2 and 3 (small non-recurved isolated crowns) were regarded as Theropoda indet., as our analyses failed to support a more precise classification. Two large almost complete ziphodont crowns, considered morphotype 4, were identified as belonging to megalosaurid tetanurans by phylogenetic, discriminant and multivariate analyses, thus likely representing the first record of this ancient family in South America, and the youngest worldwide. We refer the axis to a small abelisauroid ceratosaurian based on the following suite of characters; long and pointed epipophyses, a pneumatic foramen in the centrum, the invaginated spinopostzygapophyseal lamina, and the anteroposteriorly long, dorsally convex, and dorsally/posteriorly unexpanded neural spine. The caudal centra can be referred to a theropod, and tentatively to Abelisauroidea, suggesting that they may belong to the same taxon than that represented by the axis. The tibia lacks the incisura tibialis, presents a low, sharp and proximally positioned fibular crest, and has a deep lateral fossa, which is limited dorsally by a coarse, rounded in section and anteriorly directed crest. This combination of features allows to refer it to a large abelisaurid. The Bajada Colorada dinosaur record includes so far a small abelisauroid, a large abelisaurid, a probably medium to large megalosaurid tetanuran, diplodocid and dicraeosaurid sauropods. It shows some similarities with Middle and Upper Jurassic units in central Patagonia, Africa and Portugal, suggesting that no significant dinosaur faunal turnover took place through the Jurassic-Cretaceous event in the southern part of South America.     

Late Cretaceous (Campanian/Maastrichtian) freshwater to restricted marine mollusc fauna from the Loncoche Formation,Neuquén Basin,west-central Argentina

This study is the first detailed account of freshwater to restricted marine molluscs from the Upper Cretaceous sedimentary rocks in the northern sector of the Neuquén Basin. The fossils are from the Campanian–Maastrichtian Loncoche Formation in southern Mendoza, west-central Argentina, which records the initial connection of the Neuquén Basin to the Atlantic Ocean. Six species of bivalves (Diplodon bodenbenderi, Pleiodon? sp., Isognomon? mechanquilensis, Mactridae? indet., Panopea? sp., and Laternula sp.) and three of gastropods (Paleoanculosa macrochilinoides, Paleoanculosa ameghiniana, and a possible cerithioidean) are described. Specimens were collected from fine to coarse sandstones, which may be massive or with planar stratification, planar-cross stratification or trough-cross stratification, and a few from bioclastic limestones and mudstones. Although the sections are from 50 to 300 m thick, the specimens are found only in the lower 120 m. Molluscs represent autochthonous/parautochthonous assemblages composed of mostly non-broken gastropods and articulated bivalve specimens, some of which show signs of postmortem transport; however, they were not removed far from their original habitat. Review of the habitats of living genera supports the inference of dominantly freshwater palaeoenvironments in the lower and middle part of the Loncoche Formation, with restricted marine influence in the southernmost localities studied where there are a few samples that contain specimens belonging to predominantly marine groups (e.g., Laternula, Panopea).     

Paleoenvironmental framework of dinosaur tracksites and other ichnofossils in Early Cretaceous mixed siliciclastic-carbonate deposits in the Neuquén Basin,northern Patagonia (Argentina)

The study of the uppermost section of the Early Cretaceous Agrio Formation in northern Patagonia (Neuquén Basin) where dinosaur tracks assigned to cf. Therangospodus pandemicus are exposed (tracksites I and II) evidence mixed marginal marine siliciclastic-carbonate deposits. The succession was divided in two intervals. A lower one containing theropod tracks, recorded on top of subtidal oolithic limestones with tiny wave ripples suggesting shoreline fluctuations and subaerial exposure. Tidal influence is recognised by fining upward and prograding cycles starting with subtidal carbonates and ending with fine-grained siliciclastic deposits at the top, or rarely laminites. Dolomitization affects subtidal deposits generated in an alkaline media stressful for tracemakers. Intertidal facies include abundant heterolithic deposits, coquinas composed of gastropods encrusted by multilayered bryozoans and muddy levels with incipient mud cracking. Invertebrate ichnofossils recognized from tidally dominated deposits include Arenicolites, Kouphichnium, and Rhizocorallium. The upper interval is a transgressive–regressive cycle that starts with dark shales, deficiently oxygenated, and covered by prograding sandstones and finally sand flat deposits. This interval contains Gyrochorte, Hillichnus, and Ophiomorpha documented in wave-influenced sandstones. Dinosaur tracks as well as Hillichnus, attributed to tellinoid bivalves, and Kouphichnium assigned to xiphosurans, imply the activity of producers rarely recorded previously as body fossils in marginal marine deposits of southern South America. Previous paleogeographic schemes are questioned by our analysis, which shows evidence of extremely shallow and tide-controlled sedimentation, sometimes with subaerial exposure, with high cyclicity related to a marginal marine depositional setting and lack of significant erosion by the overlying unit, as traditionally was suggested.     

Radial patterns of bitumen dykes around Quaternary volcanoes,provinces of northern Neuquén and southernmost Mendoza,Argentina

Where the Neuquén Basin of Argentina abuts the Andes, hundreds of veins of solid hydrocarbon (bitumen) are visible at the surface. Many of these veins became mines, especially in the last century. By consensus, the bitumen has resulted from maturation of organic-rich shales, especially the Vaca Muerta Fm of Late Jurassic age, but also the Agrio Fm of Early Cretaceous age. To account for their maturation, recent authors have invoked regional subsidence, whereas early geologists invoked magmatic activity. During 12 field seasons (since 1998), we have tracked down the bitumen localities, mapped the veins and host rocks, sampled them, studied their compositions, and dated some of them. In the provinces of northern Neuquén and southernmost Mendoza, the bitumen veins are mostly sub-vertical dykes. They tend to be straight and continuous, crosscutting regional structures and strata of all ages, from Jurassic to Palaeocene. Most of the localities lie within 70 km of Tromen volcano, although four are along the Rio Colorado fault zone and another two are at the base of Auca Mahuida volcano. On both volcanic edifices, lavas are of late Pliocene to Pleistocene age. Although regionally many of the bitumen dykes tend to track the current direction of maximum horizontal tectonic stress (ENE), others do not. However, most of the dykes radiate outward from the volcanoes, especially Tromen. Thicknesses of dykes tend to be greatest close to Tromen and where the host rocks are the most resistant to fracturing. Many of the dykes occur in the exhumed hanging walls of deep thrusts, especially at the foot of Tromen. Here the bitumen is in places of high grade (impsonite), whereas further out it tends to be of medium grade (grahamite). A few bitumen dykes contain fragments of Vaca Muerta shale, so that we infer forceful expulsion of source rock. At Curacó Mine, some shale fragments contain bedding-parallel veins of fibrous calcite (beef) and these contain some bitumen, which is geochemically of low grade. In contrast, a large crosscutting bitumen dyke is of higher grade and formed later. At other localities, near basement faults, bitumen dykes have cap-rocks of hydrothermal calcrete. Other dykes or their wall rocks contain hydrothermal minerals. Finally, some dykes splay upward towards the current land surface. We conclude that (1) the bitumen dykes formed during volcanic activity in Pliocene–Pleistocene times, and that (2) heat advection by hydrothermal fluids helped to generate oil, which migrated upwards or downwards from the source rock and filled intrusive veins, before solidifying to bitumen, by loss of volatile elements. This unconventional hydrocarbon system may have significant implications for regional exploration in the foothills of the Andes.     

Tectonic repetitions of the Early Cretaceous Agrio Formation in the Chos Malal fold-and-thrust belt,Neuquén Basin,Argentina: Geometry,kinematics and structural implications for Andean building

The Neuquén Basin, developed in a retroarc setting in the central-west of Argentina, contains more than 6000 m of Mesozoic marine and continental sedimentary rocks. These rocks were deformed during the Andean orogeny leading to several thick and thin-skinned fold-and-thrust belts. The Early Cretaceous Agrio Formation is composed by a thick marine succession predominantly of black shales in which highlights a thin fluvial-aeolian sandy interval named Avilé Member. The Avilé Member, one of the most important hydrocarbon reservoirs of the Neuquén Basin, constitutes an excellent structural marker. At the Chos Malal fold-and-thrust belt, the strong mechanical anisotropy given by the contrasting lithology of the Avilé Member within the Agrio Formation favored the location of detachments along the shales and ramps affecting the sandstones during the Andean compression. Detailed field mapping at the Chacay Melehue area allowed us to recognize tectonic repetitions of the Avilé Member, which form imbrications in the simplest case whereas in other places constitute a more complex combination of imbrications, including fault-bend folding that duplicates stratigraphic sequences and fault-propagation folding that deforms more intensely the duplicated units. Along three structural cross-sections we illustrate the geometry of these tectonic repetitions of the Agrio Formation, which in the northern area have an eastward-vergence and in the central and southern regions show a clear westward-vergence. A tear fault along the arroyo Chacay Melehue could explain this vergence change. Forward modeling of the structures at the central cross-section, where a backthrust system produced imbrication, duplication and folding of the Agrio Formation, allows us to propose a balanced kinematic reconstruction of this complex structure and to compare the features produced at different stages of the deformation sequence with field observations. Our kinematic interpretation shows that the tectonic repetitions of the Agrio Formation involve 3 km of shortening above a basal detachment within the lowermost black shales. Based on a regional balanced cross-section constructed from the basement-cored Cordillera del Viento anticlinorium toward the east, across the thin-skinned sector of the Chos Malal FTB, it is possible to connect the backthrust system with east-vergent fault-bend folds that involve the stratigraphic units below the Agrio Formation. Finally, we propose a regional structural model considering the Cordillera del Viento as a basement wedge related to a low angle Andean thrust that is inserted into the sedimentary cover producing structures of different order, which evidence a strong relationship between thick and thin-skinned structures during the Andean orogeny.     

A high precision U–Pb radioisotopic age for the Agrio Formation,Neuquén Basin,Argentina: Implications for the chronology of the Hauterivian Stage

A new CA-ID TIMS U–Pb age of 130.39 ± 0.16 Ma is presented here from the Pilmatué Member of the Agrio Formation, lower Hauterivian of the Neuquén Basin in west-central Argentina. This high precision radioisotopic new age, together with the two former ones from the upper Hauterivian Agua de la Mula Member of the Agrio Formation and modern cyclostratigraphic studies in the classical sections of the Mediterranean Province of the Tethys indicate that the Hauterivian Stage spans some 6 Ma, starting ca. 132 Ma and ending ca. 126 Ma. These radioisotopic ages are tied to ammonite biostratigraphy and calcareous nannofossil bioevents and biozones recognized in the Neuquén Basin which in turn are correlated with the Mediterranean standard zones. A new geological time scale for the Valanginian–Hauterivian stages in the Mediterranean region integrating astrochronological and radiochronological data differs with the current official geological time scale which still maintains poorly constraint absolute ages for the Berriasian-Aptian interval.     

Detrital and volcanic zircon U–Pb ages from southern Mendoza (Argentina): An insight on the source regions in the northern part of the Neuquén Basin

The infill of the Neuquén Basin recorded the Meso-Cenozoic geological and tectonic evolution of the southern Central Andes being an excellent site to investigate how the pattern of detrital zircon ages varies trough time. In this work we analyze the U–Pb (LA–MC–ICP–MS) zircon ages from sedimentary and volcanic rocks related to synrift and retroarc stages of the northern part of the Neuquén Basin. These data define the crystallization age of the synrift volcanism at 223 ± 2 Ma (Cerro Negro Andesite) and the maximum depositional age of the original synrift sediments at ca. 204 Ma (El Freno Formation). Two different pulses of rifting could be recognized according to the absolute ages, the oldest developed during the Norian and the younger during the Rhaetian–Sinemurian. The source regions of the El Freno Formation show that the Choiyoi magmatic province was the main source rock of sediment supply. An important amount of detrital zircons with Triassic ages was identified and interpreted as a source area related to the synrift magmatism. The maximum depositional age calculated for the Tordillo Formation in the Atuel-La Valenciana depocenter is at ca. 149 Ma; as well as in other places of the Neuquén Basin, the U–Pb ages calculated in the Late Jurassic Tordillo Formation do not agree with the absolute age of the Kimmeridgian–Tithonian boundary (ca. 152 Ma). The main source region of sediment in the Tordillo Formation was the Andean magmatic arc. Basement regions were also present with age peaks at the Carboniferous, Neoproterozoic, and Mesoproterozoic; these regions were probably located to the east in the San Rafael Block. The pattern of zircon ages summarized for the Late Jurassic Tordillo and Lagunillas formations were interpreted as a record of the magmatic activity during the Triassic and Jurassic in the southern Central Andes. A waning of the magmatism is inferred to have happened during the Triassic. The evident lack of ages observed around ca. 200 Ma suggests cessation of the synrift magmatism. The later increase in magmatic activity during the Early Jurassic is attributed to the onset of Andean subduction, with maximum peaks at ca. 191 and 179 Ma. The trough at ca. 165 Ma and the later increase in the Late Jurassic could be explained by changes in the relative convergence rate in the Andean subduction regime, or by the shift to a more mafic composition of the magmatism with minor zircon fertility.     

Palynofacies analysis and palynology of the Agua de la Mula Member (Agrio Formation) in a sequence stratigraphy framework,Lower Cretaceous,Neuquén Basin,Argentina

Variations in the sedimentary organic matter were documented throughout the Agua de la Mula Member (late Hauterivian) of the Agrio Formation, at a combined section in the type area of the Agrio Formation; the base at Agrio del Medio and the middle to top at Bajada del Agrio. A main organic-rich interval was identified in the basal Agua de la Mula Member, dominated by marine-derived Amorphous Organic Matter (AOM), coinciding with the highest Total Organic Carbon (TOC) content, between 1.4 and 3.8 wt.%, suggesting dysoxic conditions. The rest of the Member is predominantly characterized by terrestrially-derived organic matter, mainly phytoclasts, with low TOC values, around 1% or lower, indicating predominantly oxic depositional settings. By integrating stacking pattern and shell beds analysis, four depositional sequences SQ1–SQ4 were recognized. The organic-rich, finely laminated bituminous black shales of the Spitidiscus riccardii zone constitute a mayor and rapid inundation defining a Transgressive System tract (TST), related to a third order asymmetrical mesosequence dominated by a thick High System Tract (HST). It represents the most widespread and important flooding episode within the Neuquén Basin during the late Hauterivian. Inside sequences of higher frequency (SQ1, SQ2, SQ3, SQ4) of probably fourth order were recognized and analysed including several ammonids zones (Spitidiscus riccardii, Crioceratites schlagintweiti, C. diamantensis and Paraspiticeras groeberi). With the exception of the oxygen-controlled, basinal and outer ramp settings indicated for the TST1, which is equivalent to the TST of a lower order sequence, and the lower TST2, respectively, the prevalence of well oxygenated, inner to middle ramp depositional environments, is suggested for the rest of the sedimentary succession and emphasized in HST of SQ2, SQ3 and SQ4. Thus, a shallowing-upward trend with improved oxygenation is recorded through the Agua de la Mula Member, reflected by decreasing TOC, AOM content and preservation state of the organic matter. Based on the whole rock fluorescence analysis of the two selected organic-rich intervals from the Spitidiscus riccardii and the lowermost Crioceratites diamantensis zones, the presence of hydrocarbons suggests a very early in situ generation.     

Structural style of the Chos Malal fold and thrust belt,Neuquén basin,Argentina: Relationship between thick- and thin-skinned tectonics

The Chos Malal fold and thrust belt (FTB) is a thick-skinned mountain belt formed by Mesozoic deposits of the Neuquén Basin during the Andean orogeny. Four structural cross-sections in the entire deformed area, supported by field and subsurface data, suggest a strong link between thick and thin-skinned structures. Major Andean thrusts branching from a detachment placed 12 km into the crust created large basement wedges, which were inserted in the cover producing minor order structures. The westernmost of these wedges is exposed forming the Cordillera del Viento, while others basement slices at depth were interpreted from seismic lines. These thick-skinned structures transferred deformation to the cover along the Auquilco Formation and contributed to create all thin-skinned structures surveyed in the Chos Malal FTB. We recognized half-graben geometries in the seismic lines, preserving their extensional configuration, which suggests that the main normal faults were not inverted. Shortenings calculated from the restoration of the four cross-sections are 16.9 km (29.7%), 16.9 km (29.7%), 14.7 km (26.9%) and 14.15 km (26.3%), which evidence a slight diminution of the contraction toward the south probably associated with the plunge of the Cordillera del Viento structure in this segment of the Chos Malal FTB.     

The Chachil Limestone (Pliensbachian–earliest Toarcian) Neuquén Basin,Argentina: U–Pb age calibration and its significance on the Early Jurassic evolution of southwestern Gondwana

New radiometric U–Pb ages obtained on zircon crystals from Early Jurassic ash layers found within beds of the Chachil Limestone at its type locality in the Chachil depocentre (southern Neuquén Basin) confirm a Pliensbachian age (186.0 ± 0.4 Ma). Additionally, two ash layers found in limestone beds in Chacay Melehue at the Cordillera del Viento depocentre (central Neuquén Basin) gave Early Pliensbachian (185.7 ± 0.4 Ma) and earliest Toarcian (182.3 ± 0.4 Ma) U–Pb zircon ages. Based on these new datings and regional geological observations, we propose that the limestones cropping out at Chacay Melehue are correlatable with the Chachil Limestone. Recent data by other authors from limestones at Serrucho creek in the upper Puesto Araya Formation (Valenciana depocentre, southern Mendoza) reveal ages of 182.16 ± 0.6 Ma. Based on these new evidences, we consider the Chachil Limestone an important Early Jurassic stratigraphic marker, representing an almost instantaneous widespread flooding episode in western Gondwana. The unit marks the initiation in the Neuquén Basin of the Cuyo Group, followed by widespread black shale deposition. Accordingly, these limestones can be regarded as the natural seal of the Late Triassic –earliest Jurassic Precuyano Cycle, which represents the infill of halfgrabens and/or grabens related to a strong extensional regime. Paleontological evidence supports that during Pliensbachian–earliest Toarcian times these limestones were deposited in western Gondwana in marine warm water environments.