基于地下电性结构探讨中国东北活动火山形成机制

东北地区是我国现代火山活动最强烈的地区之一，也是许多学者十分关注的地区。本文回顾了前人提出的关于该地区火山成因的研究成果；通过分析在东北活动火山区大地电磁观测研究的地壳上地幔结构和采用大地电磁网观测研究的地幔1000km以上的电性结构成果，发现长白山天池火山区存在地壳岩浆囊，其它活动火山没有发现地壳岩浆囊，但都存在通往地幔的岩浆通道；东北地区在80～120km左右和200～250km可能存在与地幔岩浆囊相关的地幔高温流体。基于电性结构的研究成果，作者提出了一种东北地区可能的活动火山成因假说。认为东北火山的成因可能与西太平洋板块俯冲到中国东北地区的地幔过渡带后产生脱水有密切关系。这种水以矿物组分或流体方式向上运移，在地幔200-250km和80～120km左右聚集，80～120km的聚集区可能是火山喷发的物质来源。     

琼北第四纪火山区电各向异性结构及其地质意义

琼北地区广泛发育第四纪火山,然而其稳定性及与长流-仙沟断裂的关系仍存在争议.在琼北第四纪火山区,获得了覆盖雷虎岭火山系统的184个大地电磁测深数据.相位张量分析指示了电各向异性的存在,采用一维各向异性反演获得了地下电各向异性结构.结果显示浅部（~1~5 km）最小电阻率方向近平行于长流-仙沟断裂;而深部（~5~15 km）近南北向,与断裂斜交.研究表明长流-仙沟断裂不是深大断裂,且并不控制深部岩浆路径;深部各向异性可能反映了一个存储含盐流体的高孔隙度区域,其来源于更深位置的部分熔融,而这指示雷虎岭火山系统当前处于休眠状态.      

内蒙东部晚第四纪火山活动与新构造

本文所指的晚第四纪包括晚更新世和全新世。内蒙东部晚第四纪火山活动强烈,北起大兴安岭北部的鄂伦春诺敏河火山群、经阿尔山-柴河、锡林浩特-阿巴嘎火山群,南抵察右后旗乌兰哈达火山群,断续延伸约1000km,分布着约390余座大小不一、形态各异的火山,构成了内蒙东部壮观的北北东向第四纪火山喷发带。火山类型包括玛珥式、夏威夷式、斯通博利式、亚布里尼式和冰岛式,以斯通博利式最为发育。爆破式火山作用包括射汽、射汽-岩浆爆发和岩浆爆发。火山岩类型主要为碱性玄武岩及其火山碎屑物(岩),火山岩具初期裂谷构造属性。火山活动主体受北北东向基底断裂控制,但就具体火山群而言,又多处于北东和北西向基底深断裂交会处。区内新构造与火山活动密切相关,深部岩浆的上侵,可能是控制本区新构造活动的主因。尤其是全新世火山的空间展布,显示了内蒙东部新构造的活动性。     

Magmatic fluids of Tatun volcanic group,Taiwan

Two distinctive magmatic fluids were recognized in the Tatun volcanic group (TVG), Taiwan. One is a relatively reduced fluid represented by the fumarolic gases at Hsiao-you-ken (HYK) geothermal field. Another is an oxidized fluid containing high concentrations of HCl represented by the fumarolic gases at Da-you-ken (DYK). An intermediate gas was recognized at Gung-tze-ping (GTP) and She-hung-ping (SHP). The fumarolic gases at HYK and GTP possess the features of so-called primary steam generated on mixing of magmatic gas and meteoric groundwater. The fumarolic gases at DYK are a simple mixture between magmatic gas and water vapor of meteoric origin. The CO₂/H₂O molar ratio of the magmatic component in the fumarolic gases at DYK was estimated to be 0.018, meanwhile it was estimated to be 0.027 for the fumarolic gases at HYK and GTP, suggesting the magma beneath DYK is depleted in volatiles relative to the magma beneath HYK and GTP. The estimated CO₂/H₂O ratio for the magmatic component is comparable to that of some active volcanoes in Japan, suggesting the enrichment of volatiles in the magmas beneath TVG.     

The magmatic to hydrothermal transition and its bearing on ore-forming systems

The exsolution of volatile phases from silicate magmas controls physical and chemical magma properties and influences large-scale geologic phenomena and processes having major societal and economic implications including the release of climate-altering gases to the atmosphere, the explosivity of volcanic eruptions, hydrothermal alteration, and the generation of magmatic–hydrothermal mineralization. These volatile phases exsolve from a wide variety of magmas and cover a very broad spectrum of compositions.

The transition from the orthomagmatic to the hydrothermal stages has important bearing on these fundamentally important geologic phenomena, and this report summarizes the published results of a dozen scientific investigations on the magmatic–hydrothermal transition as applied to volcanic eruption and magmatic–hydrothermal mineralization. These studies involve a variety of analytical and experimental methodologies, and many focus on fluid and melt inclusions from mineralized magmatic systems. A primary goal of each study is to better understand the role of magmatic volatiles and the importance of the magmatic–hydrothermal transition on these geologic processes.     

Aleutian tholeiitic and calc-alkaline magma series I: The mafic phenocrysts

Diagnostic mafic silicate assemblages in a continuous spectrum of Aleutian volcanic rocks provide evidence for contrasts in magmatic processes in the Aleutian arc crust. Tectonic segmentation of the arc exerts a primary control on the variable mixing, fractional crystallization and possible assimilation undergone by the magmas. End members of the continuum are termed calc-alkaline (CA) and tholeiitic (TH). CA volcanic rocks (e.g., Buldir and Moffett volcanoes) have low FeO/MgO ratios and contain compositionally diverse phenocryst populations, indicating magma mixing. Their Ni and Cr-rich magnesian olivine and clinopyroxene come from mantle-derived mafic olivine basalts that have mixed with more fractionated magmas at mid-to lower-crustal levels immediately preceding eruption. High-Al amphibole is associated with the mafic end member. In contrast, TH lavas (e.g., Okmok and Westdahl volcanoes) have high FeO/MgO ratios and contain little evidence for mixing. Evolved lavas represent advanced stages of low pressure crystallization from a basaltic magma. These lavas contain groundmass olivine (FO 40–50) and lack Ca-poor pyroxene. Aleutian volcanic rocks with intermediate FeO/MgO ratios are termed transitional tholeiitic (TTH) and calc-alkaline (TCA). TCA magmas are common (e.g., Moffett, Adagdak, Great Sitkin, and Kasatochi volcanoes) and have resulted from mixing of high-Al basalt with more evolved magmas. They contain amphibole (high and low-Al) or orthopyroxene or both and are similar to the Japanese hypersthene-series. TTH magmas (e.g., Okmok and Westdahl) contain orthopyroxene or pigeonite or both, and show some indication of upper crustal mixing. They are mineralogically similar to the Japanese pigeonite-series. High-Al basalt lacks Mg-rich mafic phases and is a derivative magma produced by high pressure fractionation of an olivine tholeiite. The low pressure mineral assemblage of high-Al basalt results from crystallization at higher crustal levels.     

Geophysical and petrological modelling of the structure and composition of the crust and upper mantle in complex geodynamic settings: The Tyrrhenian Sea and surroundings

Information on the physical and chemical properties of the lithosphere–asthenosphere system (LAS) can be obtained by geophysical investigation and by studies of petrology–geochemistry of magmatic rocks and entrained xenoliths. Integration of petrological and geophysical studies is particularly useful in geodynamically complex areas characterised by abundant and compositionally variable young magmatism, such as in the Tyrrhenian Sea and surroundings.A thin crust, less than 10 km, overlying a soft mantle (where partial melting can reach about 10%) is observed for Magnaghi, Vavilov and Marsili, which belong to the Central Tyrrhenian Sea backarc volcanism where subalkaline rocks dominate. Similar characteristics are seen for the uppermost crust of Ischia. A crust about 20 km thick is observed for the majority of the continental volcanoes, including Amiata–Vulsini, Roccamonfina, Phlegraean Fields–Vesuvius, Vulture, Stromboli, Vulcano–Lipari, Etna and Ustica. A thicker crust is present at Albani – about 25 km – and at Cimino–Vico–Sabatini — about 30 km. The structure of the upper mantle, in contrast, shows striking differences among various volcanic provinces.Volcanoes of the Roman region (Vulsini–Sabatini–Alban Hills) sit over an upper mantle characterised by V_s mostly ranging from about 4.2 to 4.4 km/s. At the Alban Hills, however, slightly lower V_s values of about 4.1 km/s are detected between 60 and 120 km of depth. This parallels the similar and rather homogeneous compositional features of the Roman volcanoes, whereas the lower V_s values detected at the Alban Hills may reflect the occurrence of small amounts of melts within the mantle, in agreement with the younger age of this volcano.The axial zone of the Apennines, where ultrapotassic kamafugitic volcanoes are present, has a mantle structure with high-velocity lid (V_s ∼ 4.5 km/s) occurring at the base of a 40-km-thick crust. Beneath the Campanian volcanoes of Vesuvius and Phlegraean Fields, the mantle structure shows a rigid body dipping westward, a feature that continues southward, up to the eastern Aeolian arc. In contrast, at Ischia the upper mantle contains a shallow low-velocity layer (V_s = 3.5–4.0 km/s) just beneath a thin but complex crust. The western Aeolian arc and Ustica sit over an upper mantle with V_s ∼ 4.2–4.4 km/s, although a rigid layer (V_s = 4.55 km/s) from about 80 to 150 km occurs beneath the western Aeolian arc. In Sardinia, no significant differences in the LAS structure are detected from north to south.The petrological–geochemical signatures of Italian volcanoes show strong variations that allow us to distinguish several magmatic provinces. These often coincide with mantle sectors identified by V_s tomography. For instance, the Roman volcanoes show remarkable similar petrological and geochemical characteristics, mirroring similar structure of the LAS. The structure and geochemical-isotopic composition of the upper mantle change significantly when we move to the Stromboli–Campanian volcanoes. The geochemical signatures of Ischia and Procida volcanoes are similar to other Campanian centres, but Sr–Pb isotopic ratios are lower marking a transition to the backarc mantle of the Central Tyrrhenian Sea. The structural variations from Stromboli to the central (Vulcano and Lipari) and western Aeolian arc are accompanied by strong variations of geochemical signatures, such as a decrease of Sr-isotope ratios and an increase of Nd-, Pb-isotope and LILE/HFSE ratios. The dominance of mafic subalkaline magmatism in the Tyrrhenian Sea basin denotes large degrees of partial melting, well in agreement with the soft characteristics of the uppermost mantle in this area. In contrast, striking isotopic differences of Plio-Quaternary volcanic rocks from southern to northern Sardinia does not find a match in the LAS geophysical characteristics.The combination of petrological and geophysical constraints allows us to propose a 3D schematic geodynamic model of the Tyrrhenian basin and bordering volcanic areas, including the subduction of the Ionian–Adria lithosphere in the southern Tyrrhenian Sea, and to place constraints on the geodynamic evolution of the whole region.     

Neogene-Quaternary Volcanic forms in the Carpathian-Pannonian Region: a review

Neogene to Quaternary volcanic/magmatic activity in the Carpathian-Pannonian Region (CPR) occurred between 21 and 0.1 Ma with a distinct migration in time from west to east. It shows a diverse compositional variation in response to a complex interplay of subduction with rollback, back-arc extension, collision, slab break-off, delamination, strike-slip tectonics and microplate rotations, as well as in response to further evolution of magmas in the crustal environment by processes of differentiation, crustal contamination, anatexis and magma mixing. Since most of the primary volcanic forms have been affected by erosion, especially in areas of post-volcanic uplift, based on the level of erosion we distinguish: (1) areas eroded to the basement level, where paleovolcanic reconstruction is not possible; (2) deeply eroded volcanic forms with secondary morphology and possible paleovolcanic reconstruction; (3) eroded volcanic forms with remnants of original morphology preserved; and (4) the least eroded volcanic forms with original morphology quite well preserved. The large variety of volcanic forms present in the area can be grouped in a) monogenetic volcanoes and b) polygenetic volcanoes and their subsurface/intrusive counterparts that belong to various rock series found in the CPR such as calc-alkaline magmatic rock-types (felsic, intermediate and mafic varieties) and alkalic types including K-alkalic, shoshonitic, ultrapotassic and Na-alkalic. The following volcanic/subvolcanic forms have been identified: (i) domes, shield volcanoes, effusive cones, pyroclastic cones, stratovolcanoes and calderas with associated intrusive bodies for intermediate and basic calclkaline volcanism; (ii) domes, calderas and ignimbrite/ash-flow fields for felsic calc-alkaline volcanism and (iii) dome flows, shield volcanoes, maars, tuffcone/tuff-rings, scoria-cones with or without related lava flow/field and their erosional or subsurface forms (necks/ plugs, dykes, shallow intrusions, diatreme, lava lake) for various types of K- and Na-alkalic and ultra-potassic magmatism. Finally, we provide a summary of the eruptive history and distribution of volcanic forms in the CPR using several sub-region schemes.     

长白山地区新生代火山岩及其幔源包体的矿物化学及矿物包裹体研究

长白山地区新生代火山岩主要为玄武岩类、粗面岩类和碱性流纹岩类。其中奶头山期碱性玄武岩中含有幔源的尖晶石二辉橄榄岩包体和辉石岩包体。幔源包体及不同期次火山岩的主要矿物是橄榄石、单斜辉石、斜方辉石、尖晶石、斜长石、碱性长石。不同寄主岩石中的矿物组成及其化学成分具有一定的变化，反映了岩浆分异演化的特征；矿物及火山熔岩中的包裹体成分及玻璃熔体结构的激光拉曼光谱分析结果表明，地下深处的岩浆含有较多的挥发分，岩浆上升过程中发生了强烈的出溶作用；岩浆由起源经分异演化上升到地壳浅部直至喷发，幔源的挥发分减少，而浅成或壳源的挥发分增多，特别是在岩浆喷发过程中，地下水或大气成分起了重要作用。     

Earthquake swarms in continental rifts — A comparison of selected cases in America, Africa and Europe

The occurrence of earthquake swarms is typically related to magmatic activity in volcanoes, yet swarms are also common in other intracontinental regions such as continental rifts. We present here a summary of geophysical observations that have been made in earthquake swarm areas of the Rio Grande, Kenya, and Eger rifts, focusing on characteristic parameters for the origin and generation of the swarm earthquakes.Our compilation of seismological parameters such as spatial distribution and focal parameters of hypocenters, magnitude statistics, and the location of the swarm centres in the rift environments reveals major similarities. The earthquake swarms take place at shallow depth between 0 and 10 km. The maximum magnitudes are mostly less than 4.5. The b-values, indicating the magnitude frequency relation of the seismicity, are about 0.8. They are hence not deviating from a normal non-volcanic intraplate environment, but are considerably lower than those of volcanic earthquake swarms. Focal mechanism studies give uniform pictures of stress field orientation and faulting style for the swarm areas. In all three rifts, the centres of swarm activity seem to be restricted to rift valley sections that may be influenced by large-scale fracture or shear zones that intersect the rifts. We conclude that these deep-reaching zones of weakness allow intrusions of upper mantle material into crustal layers, where magma-related fluids or fluctuations of the magma bodies themselves cause the generation of earthquake swarms.     

Petrogenesis of a voluminous Quaternary adakitic volcano: the case of Baru volcano

The origin of adakite magmas remains controversial because initially the term adakite had petrogenetic significance implying an origin by direct melting of the eclogitized subducting oceanic crust. Many models have been produced for their origin, and until now there has not been a straightforward method to discriminate between these models in a given adakite suite. Here, we use detailed chronological and geochemical studies of selected adakitic edifices that allows for the determination of the magmatic output rate parameter (Qe), which has been correlated with the rates of magma generation deep within subduction zones. By providing temporal and eruption rate estimates, we provide constraints on the possible petrogenetic processes involved in the generation of adakite-like signatures. Adakite magmas derived from the melting of the subducting slab should be volumetrically insignificant when compared to the adakite-like magmas produced by typical arc magma generation processes. In this study, we use this observation and the extraordinary stratigraphic exposure from Miocene to present in an adakitic volcano in Panama and to study the temporal and chemical variation in erupted magmas to estimate rates of magma generation. Detailed chemical and geochronological analyses of Baru volcano indicate that the volcanic edifice was constructed in its entirety during the Quaternary and magmas display adakite-like features such as steep rare earth elements patterns, pronounced depletions in the heavy rare earth elements, low Y, high Sr, and high Sr/Y. The magmatic output rates (Qe) that we have calculated show that compared to other typical adakitic volcanoes, most of the volcanic edifice of Baru volcano was constructed extremely rapidly (<~213 k.a.) and in time frames that are similar to typical arc volcanoes. The observed chemical and mineralogical variation, coupled with the high magma production rates, indicate that Baru volcano is more representative of a typical arc volcano than a small-volume melt of the subducting oceanic crust. The technique we outline may have broader application in determining the petrogenetic conditions of other adakite suites.     

Geochronology and evolution of quaternary volcanism at the Keli Highland,Greater Caucasus

The paper reports newly obtained stratigraphic, petrographic, and isotope-geochronological data on modern moderately acid lavas from the Keli Highland at the Greater Caucasus and presents a geological map of the territory, in which 35 volcanoes active in Late Quaternary time were documented by the authors. The total duration of volcanic activity at the highland was estimated at 250 ka. The volcanic activity was discrete and occurred in three phases: Middle Neopleistocene (245−170 ka), Late Neopleistocene (135−70 ka), and Late Neopleistocene-Holocene (<30 ka). Newly obtained lines of evidence indicate that certain volcanoes erupted in the latest Neopleistocene-Holocene. The first phase of volcanic activity was connected mainly with lava volcanoes, and eruptions during the later phases of volcanic activity in this part of the Greater Caucasus produced mainly lavas. The most significant eruptions are demonstrated to occur in the territory during the second phase. The major evolutionary trends of volcanic processes during the final phase in the Keli Highland are determined. It was also determined that the overwhelming majority of volcanoes that were active less than 30 ka B.P. are spatially restricted to long-liven local magmatic zones, which were active during either all three or only the final two phases of activity. These parts of the territory are, perhaps, the most hazardous in terms of volcanic activity.     

Late Pleistocene Tendürek Volcano (Eastern Anatolia,Turkey). II. Geochemistry and petrogenesis of the rocks

The series of two papers presents a comprehensive isotope-geochronological and petrologicalgeochemical study of the Late Quaternary Tendürek Volcano (Eastern Turkey), one of the greatest volcanoes within the Caucasian–Eastern Anatolian segment of the Alpine foldbelt. The second article discusses the results of petrogenetic modeling, role of AFC-processes in the petrogenesis of magmas and the nature of mantle source of the Tendürek Volcano. Based on geochronological data, geochemical and isotopegeochemical (Sr-Nd-Pb) characteristics of the studied rocks we suggest the petrological model which well describe the evolution of magmatic system of the Tendürek Volcano during the whole period of its activity. The data obtained indicate that the igneous rocks of the Tendürek Volcano belong to the same homodromous volcanic series (trachybasalt–tephrite–phonotephrite–tephriphonolite–trachyandesite–trachyte–phonolite), which are dominated by the intermediate and moderately-acid varieties of the eruption products. The leading role in the petrogenesis of the lavas was played by the fractional crystallization processes, which, according to isotope-geochemical data, were sometimes complicated by the assimilation of upper crustal material. The mantle reservoir responsible for the magmatic activity within the major part of the Eastern Anatolia in the Late Quaternary time was represented by the OIB-type mantle. It was subject to slight metasomatic changes as a result of earlier deepening and remelting of the Arabian Plate slab, which was subducted under the region through the end of the Miocene. The depth of the magma-generating source is estimated at around 80 km, which corresponds to the upper part of the asthenospheric wedge under the region, based on geophysical data.     

Geochemical and isotopic insights into the assembly,evolution and disruption of a magmatic plumbing system before and after a cataclysmic caldera-collapse eruption at Ischia volcano (Italy)

New geochemical and isotopic data on volcanic rocks spanning the period ~75–50 ka BP on Ischia volcano, Italy, shed light on the evolution of the magmatic system before and after the catastrophic, caldera-forming Monte Epomeo Green Tuff (MEGT) eruption. Volcanic activity during this period was influenced by a large, composite and differentiating magmatic system, replenished several times with isotopically distinct magmas of deep provenance. Chemical and isotopic variations highlight that the pre-MEGT eruptions were fed by trachytic/phonolitic magmas from an isotopically zoned reservoir that were poorly enriched in radiogenic Sr and became progressively less radiogenic with time. Just prior to the MEGT eruption, the magmatic system was recharged by an isotopically distinct magma, relatively more enriched in radiogenic Sr with respect to the previously erupted magmas. This second magma initially fed several SubPlinian explosive eruptions and later supplied the climactic, phonolitic-to-trachytic MEGT eruption(s). Isotopic data, together with erupted volume estimations obtained for MEGT eruption(s), indicate that >5–10 km³ of this relatively enriched magma had accumulated in the Ischia plumbing system. Geochemical modelling indicates that it accumulated at shallow depths (4–6 km), over a period of ca. 20 ka. After the MEGT eruption, volcanic activity was fed by a new batch of less differentiated (trachyte-latite) magma that was slightly less enriched in radiogenic Sr. The geochemical and Sr–Nd-isotopic variations through time reflect the upward flux of isotopically distinct magma batches, variably contaminated by Hercynian crust at 8–12 km depth. The deep-sourced latitic to trachytic magmas stalled at shallow depths (4–6 km depth), differentiated to phonolite through crystal fractionation and assimilation of a feldspar-rich mush, or ascended directly to the surface and erupted.     

Normal faults associated with volcanic activity arc

Volcanic centers (volcanoes, fumaroles or solfatara fields), epicenters of strong shallow earthquakes (with focal depths up to 20 km) and epicenters of intermediate depth strong earthquakes (with focal depths between 120 and 160 km) in the southern Aegean volcanic arc can be grouped into five, well defined, linear clusters trending about N60°E. This lineation of shallow earthquakes and volcanic activity is attributed to five corresponding normal faults which are named after the five corresponding volcanic centers (Sousaki, Methana, Milos, Santorini and Nisyros). This is supported by a similar trend of the geomorphological features (grabens and islands) and of geophysical features (Bouguer anomalies), as well as by other seismological data (fault plane solutions and the origins of tsunamis) and geological information on the Santorini caldera. The greater volcanic activity in the eastern volcanic centers (Santorini and Nysiros) compared to the western volcanic centers (Sousaki, Methana and Milos) is attributed to the higher rate of extensional crustal deformation. In the eastern part of the volcanic arc it is 26 mm/yr: in the west it is 2 mm/yr. The delineation of the epicenters of the intermediate depth earthquakes along the same five lines indicates the existence of five corresponding rupture zones in the lower (leading) part of the descending lithospheric slab (at depths of 120–180 km). These deep zones are probably the sources of hot material which is ascending vertically upwards and intrudes into the crust along its fracture zones. The orientation of these zones explains the focusing of the macro-seismic results of these deep shocks at narrow regions of the sedimentary arc (Peloponnesus, Crete, etc).     

The andesite aqueduct: perspectives on the evolution of intermediate magmatism in west-central (105–99°W) Mexico

Intermediate calc-alkaline magma (52-65% SiO₂) in western-central Mexico is the focus of this paper, and the typically porphyritic andesites (57-65% SiO₂) form large central volcanoes, whereas basaltic andesites (52-57% SiO₂) are less porphyritic, and they are found as cones and flows but are absent from central volcanoes. Several studies of experimental phase equilibria on these lavas relate water concentration to the phenocryst assemblages and to the degree of crystallinity, so that the abundance, composition and variety of phenocrysts can be used to constrain the amount of water dissolved in the magmas. Thus, the plagioclase-rich andesites of Volcan Colima, Mexico, become so as a result of decompressional crystallisation at ~950 °C (the pyroxene phenocryst temperature), and lose their dissolved water (2.5 to 4.5 wt% H₂O) which is inversely proportional to the modal abundance of plagioclase. The feeding magma to V. Colima, North America's most productive central volcano, is represented by hornblende lamprophyre, a lava type without plagioclase phenocrysts which requires at least 6 wt% water to reproduce the phenocryst assemblage. Thus, degassing of the V. Colima magmas, and of those of the other central volcanoes in the western-central Mexican volcanic belt, contributes essentially all their dissolved water to the conduit or to the atmosphere. The source of this magmatic water is related to the source of the intermediate magmas. For some this must lie in the mantle, as the incorporation of hornblende-lherzolite nodules in a hydrous andesite with hornblende phenocrysts could only have occurred while ascending through the mantle. Consistent with a mantle source is the composition of the olivine phenocrysts in Mexican lavas with 10 to 5% MgO, which is in the mantle range of Fo_88-92. Accordingly, basaltic andesites and andesites with >5% MgO are candidates for a mantle source. The equilibration of intermediate magmas with the mantle, as illustrated by the experiments of various workers, requires that the magmas be hydrous at pressure. An additional constraint is that the activity of silica in the mantle must be equal to that in the hydrous magma at equilibrium. Using published and new experiments to define RTln%_SiO2 in hydrous liquids, this quantity is shown to vary as a function of liquid composition (H₂O, MgO, Na₂O+K₂O), and it approaches zero for quartz-saturated hydrous liquids. Using appropriate values of RTln%_SiO2 for three intermediate lavas, the amount of water required to equilibrate with an olivine-orthopyroxene mantle source is calculated, and within error indicates that only the most silica-rich magma is at water saturation in the mantle, in agreement with published experimental work. Hydrous intermediate magmas, ascending from their hornblende-lherzolite source regions (~1 to 1.5 GPa) along the hydrous adiabat, may not encounter any phase boundaries until 0.2-0.4 GPa because of the increase in the thermal stability of hornblende in water-undersaturated magmas. Therefore, the phenocryst assemblages of hornblende-free andesites equilibrate at low pressures. The virtual absence of basalt in west-central Mexico (<4 Ma) is considered to be related to the large increase in crystallinity found in isobaric hydrous experiments crystallising hornblende at pressures close to those at the base of the crust. As a large proportion of the ferromagnesian components of basalt is acceptable to hornblende, it does not take a significant cooling interval (~40-50 °C) below the liquidus for hydrous basaltic magma to acquire >50% crystallinity, evidently also an eruptible limit for V. Colima andesitic lavas. If the lower limit of water dissolved in Mexican intermediate magmas is accepted as that required for phenocryst equilibration (~6 wt% water), and the upper limit as saturation in the mantle source at 1 GPa (~16 wt%) then, with an estimate of the volcanic and plutonic magma delivery rate (km³/10⁶ year) per km of volcanic arc, the flux of water returned from the mantle along the 35,000-km, global subduction-related arc system can be estimated. Measurements of the volcanic flux are woefully few, and estimates from Mexico, the Lesser Antilles and central America show a range from 4 to 20 km³/10⁶ year2km which, if subtracted from the isotopically constrained continental growth rate, gives the plutonic flux rate. This suggests that, of the magma flux ascending to the continental crust, only about a fifth reaches the surface. If the dissolved magmatic water limits are coupled with the volcanic and plutonic emplacement rates, then the amount of water returned by magmatism to the crust is crudely in balance with that subducted.     

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.     

Mafic potassic lavas of the Quaternary West Eifel volcanic field

Major and trace element analyses for 103 volcanoes of the Quaternary West Eifel volcanic field show the lavas to be dominantly primitive (MgO>7 wt.%) and potassic (Na₂O/K₂O∼1). The rocks are divided into (1) a foidite (F)-suite, volumetrically dominant and consisting of four types: leucitites and nephelinites, melilite-bearing foidites, olivine-free foidites, sodalite-bearing melilite-free foidites, and (2) a younger olivine-nephelinite and basanite (ONB)-suite, concentrated in the southeastern part of the field. Dominantly cpx-phyric F-suite magmas differ from the dominantly ol-phyric ONB-suite mainly in higher K₂O/ Na₂O and CaO/Al₂O₃-ratios, higher Rb, Cu, H₂O, CO₂ and LREE concentrations and slightly lower Sr, Ni and Y contents. Most magmas have fractionated small amounts of olivine, clinopyroxene, and minor phlogopite. Systematic compositional variations within volcanoes or volcano groups are rare. Five more differentiated volcanoes (2 tephrites, 3 phonolites) occur in the center of the field. Their magmas are interpreted to have formed by fractionation within crustal magma chambers. Chemical differences between primary magmas (43% of volcanoes sampled) within both suites can be explained by different degrees of crystal fractionation at high pressures in the ascending magma column and possibly by varying degrees of partial melting (about 2–8%) in a garnetlherzolite mantle source. Distinct isotope ratios, parallel element variations, and different ratios of similarly incompatible elements, however, indicate a heterogeneous mantle beneath the West Eifel. The F-suite magmas originated from a mantle source more strongly enriched in alkalis and incompatible elements than the ONB-suite mantle source. The following model is proposed, based also on experimental studies and geophysical data: Within a large low velocity body of garnet-lherzolite, enriched in fluids and LIL elements (metasomatized mantle) between about 50 and 150 km depth, two different magma types were produced at different depths. Above a detachment level at about 50 km depth, these magmas rose to different stagnation levels or rapidly directly to the surface along vertical, dominantly NW-SE orientated fissures. The F-suite magmas probably formed in a phlogopite-bearing, CO₂-rich, strongly metasomatized source at about 100 km, the ON-Bmagmas from an amphibole-bearing, CO₂-poorer melting anomaly at about 60–75 km depth.     

Geophysical exploration on the subsurface geology of La Garrotxa monogenetic volcanic field (NE Iberian Peninsula)

We applied self-potential (SP) and electrical resistivity tomography (ERT) to the exploration of the uppermost part of the substrate geology and shallow structure of La Garrotxa monogenetic volcanic field, part of the European Neogene–Quaternary volcanic province. The aim of the study was to improve knowledge of the shallowest part of the feeding system of these monogenetic volcanoes and of its relationship with the subsurface geology. This study complements previous geophysical studies carried out at a less detailed scale and aimed at identifying deeper structures, and together will constitute the basis to establish volcanic susceptibility in La Garrotxa. SP study complemented previous smaller-scale studies and targeted key areas where ERT could be conducted. The main new results include the generation of resistivity models identifying dykes and faults associated with several monogenetic cones. The combined results confirm that shallow tectonics controlling the distribution of the foci of eruptive activity in this volcanic zone mainly correspond to NNW–SSE and accessorily by NNE–SSW Neogene extensional fissures and faults and concretely show the associated magmatic intrusions. These structures coincide with the deeper ones identified in previous studies, and show that previous Alpine tectonic structures played no apparent role in controlling the loci of this volcanism. Moreover, the results obtained show that the changes in eruption dynamics occurring at different vents located at relatively short distances in this volcanic area are controlled by shallow stratigraphical, structural and hydrogeological differences underneath these monogenetic volcanoes.     

Lateral flow of African mantle below the nearby Tyrrhenian plate: geochemical evidence

The Quaternary magmatism of the Southern Tyrrhenian basin represents a rare example of an active volcanic arc system where ocean island basalt (OIB) and island arc basalt (IAB) magmas coexist. Although there is general agreement on the importance of the Ionian oceanic lithosphere subduction in the genesis of the IAB magmatism, the tectono‐magmatic processes producing the coexisting OIB magmas are still poorly understood. Here we show that the geochemistry of the Quaternary Southern Tyrrhenian OIB‐type magmatism (i.e. Ustica island and Prometeo, a previously unknown submarine lava field) is very similar to that of OIB‐type volcanoes situated on the nearby African plate (i.e. Etna and Hyblean Plateau). Among the possible geodynamic scenarios proposed to explain the coexistence of OIB and IAB magmas in arc settings, we consider the development of a tear at the edge of the Ionian plate as the more likely mechanism to favour the flow of African asthenospheric mantle below the Tyrrhenian plate.