Magmatic history during late Carboniferous to early Permian in the North of the central Xing’an-Mongolia Orogenic Belt: a case study of the Houtoumiao pluton,Inner Mongolia

We undertake zircon U–Pb dating, Hf isotopes, and geochemical analyses of the Houtoumiao pluton in the Xilinhot microcontinent (XLMC) in the central Inner Mongolia with an aim of determining their ages, petrogenesis, and sources, which are important for understanding the late Palaeozoic tectonic evolution of the Xing’an-Mongolia Orogenic Belt. The Houtoumiao pluton consists of medium-grained granodiorite, coarse- and medium-grained syenogranite. Mafic microgranular enclaves (MMEs) are common in the Houtoumiao pluton. Zircon U–Pb dating has yielded ages of 303 ± 2 and 301 ± 2 Ma for the granodiorite, 295 ± 2 Ma for the syenogranite, and 292 ± 1 Ma for the MMEs. The granodiorite and syenogranite have features of high-K high silica content, rich in Rb, U, and Th, but low content of HFSE, belong to calc-alkaline series. The P₂O₅ concentration decreases with the increasing SiO₂ content, suggesting I-type affinity. The MMEs, which are characterized by low SiO₂, relatively high and variable TiO₂, Al₂O₃, FeO^T, MgO, CaO, Ni, and Cr contents, also have much higher total rare earth element concentrations that the REE patterns are subparallel to those of the host rocks. Zircons from the host rocks have ε_Hf(t) values from +3.91 to +7.73 and T_DM2 values of 820–1067 Ma, suggesting that the granitoids were probably dominated by remelting of juvenile crust materials. The MMEs are of ε_Hf(t) value ranging from +6.23 to +11.04 and T_DM1 values from 490 to 693 Ma, suggesting that the primary magma probably was derived from partial melting of a depleted lithospheric mantle, the mafic mineral fractional crystallization and crustal contamination occurred during the magma evolution. Combined with previous studies on the contemporaneous magma-tectonic activities in the Uliastai Continental Margin and XLMC, we suggest that the Houtoumiao pluton formed in a post-orogenic setting.     

Zircon U–Pb geochronology,major-trace elements and Sr–Nd isotope geochemistry of Mashhad granodiorites (NE Iran) and their mafic microgranular enclaves: evidence for magma mixing and mingling

ABSTRACT

Mashhad granitoids and associated mafic microgranular enclaves (MMEs), in NE Iran record late early Mesozoic magmatism, was related to the Palaeo-Tethys closure and Iran-Eurasia collision. These represent ideal rocks to explore magmatic processes associated with Late Triassic closure of the Palaeo-Tethyan ocean and post-collisional magmatism. In this study, new geochronological data, whole-rock geochemistry, and Sr–Nd isotope data are presented for Mashhad granitoids and MMEs. LA–ICP–MS U–Pb dating of zircon yields crystallization ages of 205.0 ± 1.3 Ma for the MMEs, indicating their formation during the Late Triassic. This age is similar to the host granitoids. Our results including the major and trace elements discrimination diagrams, in combination with field and petrographic observations (such as ellipsoidal MMEs with feldspar megacrysts, disequilibrium textures of plagioclase), as well as mineral chemistry, suggest that MMEs formed by mixing of mafic and felsic magmas. The host granodiorite is a felsic, high K calc-alkaline I-type granitoid, with SiO₂ = 67.5–69.4 wt%, high K₂O (2.4–4.2 wt%), and low Mg# (42.5–50.5). Normalized abundances of LREEs and LILEs are enriched relative to HREEs and HFSEs (e.g. Nb, Ti). Negative values of whole-rock εNd_(t) (?3 to ?2.3) from granitoids indicate that the precursor magma was generated by partial melting of enriched lithospheric mantle with some contributions from old lower continental crust. In the MMEs, SiO₂ (53.4–58.2 wt%) is lower and Ni (3.9–49.7 ppm), Cr (0.8–93.9 ppm), Mg# (42.81–62.84), and εNd_(t) (?2.3 to +1.4) are higher than those in the host granodiorite, suggesting a greater contribution of mantle-derived mafic melts in the genesis of MMEs.     

Eocene I-type magmatism in the Eastern Pontides,NE Turkey: insights into magma genesis and magma-tectonic evolution from whole-rock geochemistry,geochronology and isotope systematics

ABSTRACT

The Eastern Pontides orogenic belt in NE Turkey hosts numerous I-type plutons of Eocene epoch. Here, we report new U–Pb SHRIMP zircon ages and in situ zircon Lu-Hf isotopes along with bulk-rock geochemical and Sr-Nd-Pb-O isotope data from the Kemerlikda??, Ayd?ntepe and Pelitli plutons and mafic microgranular enclaves (MMEs) to constrain their parental melt source(s) and evolutionary processes. U-Pb SHRIMP zircon dating yielded crystallization ages between 45 and 44 Ma for the studied plutons and their MMEs. The plutons range from gabbro to granite and have I-type, medium to high-K calc-alkaline, and metaluminous to slightly peraluminous characteristics. On the primitive mantle-normalized multi-trace-element variations, the plutons and their MMEs are characterized by signi?cant enrichment in LILE/HFSE. Chondrite-normalized REE patterns of the plutons and their MMEs are close to each other and show moderate enrichment with variable negative Eu anomalies. The studied plutons have fairly homogeneous isotope composition (⁸⁷Sr/⁸⁶Sr_(i) = 0.70502 to 0.70560; εNd_(i) = +0.9 to – 1.4; δ¹⁸O = +5.0 to +8.7‰, εHf_(i) = – 2.2 to +13.5). The MMEs show medium to high-K calc-alkaline and metaluminous character. Although the isotope signatures of the MMEs (⁸⁷Sr/⁸⁶Sr_(i) = 0.70508 to 0.70542; εNd_(i) = +0.9 to ?1.1; δ¹⁸O = +5.8 to +8.0, εHf_(i) = +4.3 to +10.4) are very similar to those of the host rocks. Fractionation of plagioclase, amphibole, pyroxene and Fe-Ti oxides played an important role in the evolution of the plutons. The isotopic composition of the studied plutons and MMEs are similar to I-type plutons derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. The parental magma(s) of the studied plutons were generated from the enriched lithospheric mantle and then modified by fractional crystallisation, and lesser assimilation and mixing/mingling in the crustal magma chambers.     

同源岩浆不同期次之间混合产生的暗色包体——以北拉萨地块中部晚白垩世桑心日岩体为例

本文在研究西藏北拉萨块体中段桑心日岩体中的暗色包体时发现了一种具有特殊岩石成因的暗色包体。暗色包体呈椭球状,在暗色包体和寄主岩的接触面上通常形成一个明显的可能由风化作用造成的间隙面。暗色包体为二长玢岩-花岗闪长玢岩,寄主岩为花岗岩,暗色包体明显较寄主岩更基性,更富Na_2O、CaO、MgO和Fe_2O_3~T。暗色包体和寄主岩具有明显不同的稀土元素特征,暗色包体的稀土元素含量变化较大,最基性样品具有最高的稀土含量,随着基性程度的降低稀土元素含量明显下降。随着岩浆的进一步演化,岩浆向花岗岩方向演化,稀土含量又逐步升高。寄主岩和暗色包体具有基本一致的微量元素组成,具有典型的弧岩浆岩的特征,富集Rb、Cs、K等大离子亲石元素和Th、U,亏损Nb、Ta、Ti等高场强元素。此外,暗色包体和寄主岩具有明显的Ba、Sr的负异常。暗色包体成岩年龄为75. 6±1. 2Ma,寄主岩的成岩年龄为71. 8±0. 6Ma,暗色包体成岩年龄较寄主岩早约4Myr。两者具有一致的锆石原位Lu-Hf同位素特征。综合以上岩相学、年代学、元素地球化学和同位素地球化学证据,我们认为桑心日暗色包体和寄主岩来源于同源母岩浆,初始岩浆在母岩浆房中经历了不同程度的含钾角闪石结晶分离作用,并沿早期较弱的构造裂隙侵入到地壳的某一层位,随着构造活动进一步加剧,经过进一步分异母岩浆大规模上侵,并将早先侵位处于半塑性状态的暗色包体侵吞、裹挟至近地表。桑心日暗色包体最可能的成因模式可以解释为同源岩浆不同期次间的物理混合。     

Fractional crystallization and magma mixing: evidence from porphyritic diorite-granodiorite dykes and mafic microgranular enclaves within the Zhoukoudian pluton,Beijing

The Zhoukoudian pluton in the North China craton is a circular granodiorite intrusion containing porphyritic diorite dykes (PDDs), porphyritic granodiorite dykes (PGDs) and abundant mafic microgranular enclaves (MMEs), which provide an excellent opportunity to study fractional crystallization and magma mixing. The PDDs and PGDs are located in the western part of the pluton with the PDDs intruded by the PGDs. The dykes have similar mineral assemblages although plagioclase in the PDDs has higher anorthite content than the PGDs. Linear relationships between the SiO₂ and most major and trace element contents, as well as a positive trend of initial ⁸⁷Sr/⁸⁶Sr ratios and a negative trend of epsilon Nd values with increasing SiO₂ contents for the dykes suggest that both types were formed by assimilation and fractional crystallization of a common parental magma. Major oxide mass balance and trace element Rayleigh fractionation modeling points to early separation of garnet (11 %), clinopyroxene (27 %), orthopyroxene (16 %), plagioclase (25 %), biotite (19 %), and apatite (2 %) and late fractionation of hornblende (25 %), plagioclase (46 %), biotite (25 %), apatite (1 %), and magnetite (3 %). Most MMEs occur within the transitional granodiorite of the Zhoukoudian pluton. Zoned MMEs, dyke-like MME swarms, local presence of concave margins, veins and enclaves of host granodiorite within some MMEs, and several MMEs surrounded by the biotite-rich granodiorite support their formation by multiple magma mixing events, which finally resulted in different whole-rock major oxides and compatible elements, but homogeneous mineral major oxides (except zoned plagioclase), whole-rock incompatible elements and Sr-Nd isotopes between the MMEs and their host granodiorite. We suggest that multiple magma mixing events might also cause complexly zoned plagioclase in the Zhoukoudian pluton. Relative calcic, irregular or patchy cores and dusty zoned mantles from the zoned plagioclase crystals and their relatively low anorthite content indicate multiple mixing events between mafic/intermediate and felsic magmas. The mafic/intermediate end-members could be represented by the diabase dykes and the PDDs. Therefore, the dykes and MMEs in the Zhoukoudian pluton are genetically linked.     

Subduction-related mafic to felsic magmatism in the Malayer–Boroujerd plutonic complex,western Iran

The Malayer–Boroujerd plutonic complex (MBPC) in western Iran, consists of a portion of a magmatic arc built by the northeast verging subduction of the Neo-Tethys plate beneath the Central Iranian Microcontinent (CIMC). Middle Jurassic-aged felsic magmatic activity in MBPC is manifested by I-type and S-type granites. The mafic rocks include gabbroic intrusions and dykes and intermediate rocks are dioritic dykes and minor intrusions, as well as mafic microgranular enclaves (MMEs). MBPC Jurassic-aged rocks exhibit arc-like geochemical signatures, as they are LILE- and LREE-enriched and HFSE- and HREE-depleted and display negative Nb–Ta anomalies. The gabbro dykes and intrusions originated from metasomatically enriched garnet-spinel lherzolite [Degree of melting (f_mel) ~ 15%] and exhibit negative Nd and positive to slightly negative ε_Hf(T) (+ 3.0 to ? 1.6). The data reveal that evolution of Middle Jurassic magmatism occurred in two stages: (1) deep mantle-crust interplay zone and (2) the shallow level upper crustal magma chamber. The geochemical and isotopic data, as well as trace element modeling, indicate the parent magma for the MBPC S-type granites are products of upper crustal greywacke (f_mel: 0.2), while I-type granites formed by partial melting of amphibolitic lower crust (f_mel: 0.25) and mixing with upper crustal greywacke melt in a shallow level magma chamber [Degree of mixing (f_mix): 0.3]. Mixing between andesitic melt leaving behind a refractory dense cumulates during partial crystallization of mantle-derived magma and lower crustal partial melt most likely produced MMEs (f_mix: 0.2). However, enriched and moderately variable ε_Nd(T) (? 3.21 to ? 4.33) and high (⁸⁷Sr/⁸⁶Sr)_i (0.7085–0.7092) in dioritic intrusions indicate that these magmas are likely experienced assimilation of upper crustal materials. The interpretations of magmatic activity in the MBPC is consistent with the role considered for mantle-derived magma as heat and mass supplier for initiation and evolution of magmatism in continental arc setting, elsewhere.     

Chemical composition of rock-forming minerals and crystallization physicochemical conditions of the Middle Eocene I-type Haji Abad pluton,SW Buin-Zahra,Iran

The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe³⁺?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H₂O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent.     

Geochronology,geochemistry, and petrogenesis of the Maçka subvolcanic intrusions: implications for the Late Cretaceous magmatic and geodynamic evolution of the eastern part of the Sakarya Zone,northeastern Turkey

The Maçka subvolcanic intrusions (MSIs) in the eastern part of the Sakarya zone, northeastern Turkey, play a critical role in understanding the petrogenetic and geodynamic processes that took place during the growth of Late Cretaceous arc crust of this region. U–Pb zircon (79.97 ± 0.97 Ma) and two ⁴⁰Ar–³⁹Ar amphibole ages (average 81.37 ± 0.5 Ma) indicate that the MSIs were emplaced in Late Cretaceous (Campanian) time into the coeval volcanic rocks. A slightly younger zircon fission track (FT) age (73 ± 9 Ma) points to a rapid exhumation and cooling after crystallization. The intrusions are observed in areas less than 1 km² in the field and contain abundant mafic microgranular enclaves (MMEs). The host rocks (HRs) are entirely composed of tonalite (SiO₂ = 63–65 wt.%, Mg# = 43–52), and the MMEs are gabbro-diorite in composition (SiO₂ = 53–57 wt.%, Mg# = 45–48). Both the HRs and the MMEs are I-type, high-K calc-alkaline in composition and display a metaluminous character. They are characterized by geochemical features typical for magmas of subduction-related environments. Chondrite-normalized REE patterns are moderately fractionated [(La/Yb)_N = 6–11] and display slightly negative Eu anomalies (Eu/Eu* = 0.7–0.9), with weak concave-upward REE patterns, suggesting that amphibole fractionation played a role during their evolution. The MMEs have slightly different I_Sr (0.7081–0.7085) and ε_Nd (?5.0 to ?5.4) values compared with those of their HRs (I_Sr = 0.7084–0.7087 and ε_Nd = ?5.7 to ?6.9), indicating that variable amounts of crustal and mantle components were involved in the generation of parental magma to these rocks. All of these data, combined with those of previous regional studies, suggest that the MSIs are hybrid in origin, produced by the mixing of enriched lithospheric mantle- and lower crust-derived melts in an extensional arc setting that was caused by slab rollback.     

Magma mixing/mingling in the Eocene Horoz (Nigde) granitoids, Central southern Turkey: evidence from mafic microgranular enclaves

Mafic microgranular enclaves (MMEs) are widespread in the Horoz pluton with granodiorite and granite units. Rounded to elliptical MMEs have variable size (from a few centimetres up to metres) and are generally fine-grained with typical magmatic textures. The plagioclase compositions of the MMEs range from An₁₈?CAn₆₄ in the cores to An₁₇?CAn₂₉ in the rims, while that of the host rocks varies from An₁₇ to An₅₅ in the cores to An₀₇ to An₃₃ in the rims. The biotite is mostly eastonitic, and the calcic-amphibole is magnesio-hornblende and edenite. Oxygen fugacity estimates from both groups?? biotites suggest that the Horoz magma possibly crystallised at fO₂ conditions above the nickel?Cnickel oxide (NNO) buffer. The significance of magma mixing in their genesis is highlighted by various petrographic and mineralogical characteristics such as resorption surfaces in plagioclases and amphibole; quartz ocelli rimmed by biotite and amphibole; sieve and boxy cellular textures, and sharp zoning discontinuities in plagioclase. The importance of magma mixing is also evident in the amphiboles of the host rocks, which are slightly richer in Si, Fe³⁺ and Mg in comparison with the amphiboles of MMEs. However, the compositional similarity of the plagioclase and biotite phenocrysts from MMEs and their host rocks suggests that the MMEs were predominantly equilibrated with their hosts. Evidence from petrography and mineral chemistry suggests that the adakitic Horoz MMEs could be developed from a mantle-derived, water-rich magma (>3 mass%) affected by a mixing of felsic melt at P >2.3?kbar, T >730°C.     

Mineralogy, whole-rock and Sr-Nd isotope geochemistry of mafic microgranular enclaves in Cretaceous Dagbasi granitoids, Eastern Pontides, NE Turkey: Evidence of magma mixing, mingling and chemical equilibration

Rocks of the Late Cretaceous Dagbasi Pluton (88-83 Ma), located in the eastern Pontides, include mafic microgranular enclaves (MMEs) ranging from a few centimetres to metres in size, and from ellipsoidal to ovoid in shape. The MMEs are composed of gabbroic diorite, diorite and tonalite, whereas the felsic host rocks comprise mainly tonalite, granodiorite and monzogranite based on both mineralogical and chemical compositions. MMEs are characterized by a fine-grained, equigranular and hypidiomorphic texture. The common texture of felsic host rocks is equigranular and also reveals some special types of microscopic textures, e.g., oscillatory-zoned plagioclase, poikilitic K-feldspar, small lath-shaped plagioclase in large plagioclase, blade-shaped biotite, acicular apatite, spike zones in plagioclase and spongy-cellular plagioclase textures and rounded plagioclase megacrysts in MMEs. Compositions of plagioclases (An₃₃-An₆₀), hornblendes (Mg#=0.77-1.0) and biotites (Mg#=0.61-0.63) of MMEs are slightly distinct or similar to those of host rocks (An_12-57; hbl Mg#=0.63-1.0; Bi Mg#=0.50-0.69), which suggest partial to complete equilibration during mafic-felsic magma interactions.The felsic host rocks have SiO₂ between 60 and 76 wt% and display low to slightly medium-K tholeiitic to calc-alkaline and peraluminous to slightly metaluminous characteristics. Chondrite-normalized rare-earth element (REE) patterns are fractionated (La_cn/Lu_cn=1.5-7.3) with pronounced negative Eu anomalies (Eu/Eu*=0.46-1.1). Initial ε_Nd(i) values vary between −3.1 and 1.6, initial ⁸⁷Sr/⁸⁶Sr values between 0.7056 and 0.7067.Compared with the host rocks, the MMEs are characterized by relatively high Mg-number of 22-52, low contents of SiO₂ (53-63 wt%), low ASI (0.7-1.1) and low to medium-K tholeiitic to calc-alkaline, metaluminous to peraluminous composition. Chondrite-normalized REE patterns are relatively flat [(La/Yb)_cn=1.4-3.9; (Tb/Yb)_cn=0.9-1.5] and show small negative Eu anomalies (Eu/Eu*=0.63-1.01). Isotope signatures of these rocks (⁸⁷Sr/⁸⁶Sr_(i)=0.7054-0.7055; ε_Nd(i)=-1.0 to 1.9) are largely similar to the host rocks. Gabbroic diorite enclaves have relatively low contents of SiO₂, ASI; high Mg#, CaO, Al₂O₃, TiO₂, P₂O₅, Sr and Nb concentrations compared to dioritic and tonalitic enclaves.The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, interacted with a crustal melt that originated from dehydration melting of the mafic lower crust at deep crustal levels. The existence of compositional and textural disequilibrium and the nature of chemical and isotopic variation in these rock types indicate that magma mixing/mingling between an evolved mafic and a granitic magma was involved in their genesis. Microgranular enclaves are thus interpreted to be globules of a more mafic magma probably from an enriched lithospheric mantle source. Al-in-amphibole estimates the pluton emplacement at ca. 0.3-3.8 kbar, and therefore, magma mixing and mingling must have occurred at 3.8 kbar or below this level.     

Chalcophile element geochemistry of the Baima layered intrusion, Emeishan Large Igneous Province, SW China: implications for sulfur saturation history and genetic relationship with high-Ti basalts

The Permian Baima mafic layered intrusion, believed to be related to the S-undersaturated Emeishan high-Ti basalts, hosts a giant Fe–Ti-V oxide deposit in the lower part of the intrusion. Uniformly high Cu/Pd (1.9 × 10⁶–6.1 × 10⁴) and low Pd/Zr (<0.1) indicate that the Baima parental magma experienced prior sulfide segregation. Mantle-liked δ³⁴S values and low S/Se values indicate negligible external sulfur addition. Primitive mantle-normalized PGE patterns and MELTS calculations indicate that extensive fractional crystallization (~59 %) of chromite, olivine and pyroxene at depth drove the primitive picritic magma to S saturation. Strong positive correlation between IPGE and PPGE and between PGE and V, Cr and S suggest that magmatic sulfide is the dominant mineral controlling the distribution of PGE in the Baima intrusion. A positive correlation between S and Cr, FeO_T + TiO₂ and V content, together with MELTS calculations, indicate that the parental magma of the Baima intrusion reached a second stage of S saturation in the shallower Baima magma chamber, which was likely triggered by decreasing Fe²⁺ accompanying magnetite precipitation. Primitive mantle-normalized PGE patterns for Baima intrusion rocks display similar trends to high-Ti basalts inside the Panxi area, suggesting that they are comagmatic, and following a similar differentiation trend. However, the lavas erupted before they reached sulfide saturation. The more evolved nature of high-Ti basalts outside the Panxi area indicate that they experienced more extensive pre-eruption fractional crystallization. Further fractional crystallization process led these lavas show more PGE fractionated feature.     

Magma mixing origin for the post-collisional adakitic monzogranite of the Triassic Yangba pluton, Northwestern margin of the South China block: geochemistry, Sr–Nd isotopic, zircon U–Pb dating and Hf isotopic evidences

Petrogenesis of high Mg# adakitic rocks in intracontinental settings is still a matter of debate. This paper reports major and trace element, whole-rock Sr–Nd isotope, zircon U–Pb and Hf isotope data for a suite of adakitic monzogranite and its mafic microgranular enclaves (MMEs) at Yangba in the northwestern margin of the South China Block. These geochemical data suggest that magma mixing between felsic adakitic magma derived from thickened lower continental crust and mafic magma derived from subcontinental lithospheric mantle (SCLM) may account for the origin of high Mg# adakitic rocks in the intracontinental setting. The host monzogranite and MMEs from the Yangba pluton have zircon U–Pb ages of 207 ± 2 and 208 ± 2 Ma, respectively. The MMEs show igneous textures and contain abundant acicular apatite that suggests quenching process. Their trace element and evolved Sr–Nd isotopic compositions [(⁸⁷Sr/⁸⁶Sr)_i = 0.707069–0.707138, and ε_Nd(t) = −6.5] indicate an origin from SCLM. Some zircon grains from the MMEs have positive ε_Hf(t) values of 2.3–8.2 with single-stage Hf model ages of 531–764 Ma. Thus, the MMEs would be derived from partial melts of the Neoproterozoic SCLM that formed during rift magmatism in response to breakup of supercontinent Rodinia, and experience subsequent fractional crystallization and magma mixing process. The host monzogranite exhibits typical geochemical characteristics of adakite, i.e., high La/Yb and Sr/Y ratios, low contents of Y (9.5–14.5 ppm) and Yb, no significant Eu anomalies (Eu/Eu* = 0.81–0.90), suggesting that garnet was stable in their source during partial melting. Its evolved Sr–Nd isotopic compositions [(⁸⁷Sr/⁸⁶Sr)_i = 0.7041–0.7061, and ε_Nd(t) = −3.1 to −4.3] and high contents of K₂O (3.22–3.84%) and Th (13.7–19.0 ppm) clearly indicate an origin from the continental crust. In addition, its high Mg# (51–55), Cr and Ni contents may result from mixing with the SCLM-derived mafic magma. Most of the zircon grains from the adakitic monzogranite show negative ε_Hf(t) values of −9.4 to −0.1 with two-stage Hf model ages of 1,043–1,517 Ma; some zircon grains display positive ε_Hf(t) of 0.1–3.9 with single-stage Hf ages of 704–856 Ma. These indicate that the source region of adakitic monzogranite contains the Neoproterozoic juvenile crust that has the positive ε_Hf(t) values in the Triassic. Thus, the high-Mg adakitic granites in the intracontinental setting would form by mixing between the crustal-derived adakitic magma and the SCLM-derived mafic magma. The mafic and adakitic magmas were generated coevally at Late Triassic, temporally consistent with the exhumation of deeply subducted continental crust in the northern margin of the South China Block. This bimodal magmatism postdates slab breakoff at mantle depths and therefore is suggested as a geodynamic response to lithospheric extension subsequent to the continental collision between the South China and North China Blocks.     

Early Cretaceous Magma Mingling in Xiaocuo, Southeastern China Continental Margin: Implications for Subduction of Paleo-Pacific Plate

Magma mingling has been identified within the continental margin of southeastern China.This study focuses on the relationship between mafic and felsic igneous rocks in composite dikes and plutons in this area,and uses this relationship to examine the tectonic and geodynamic implications of the mingling of mafic and felsic magmas.Mafic magmatic enclaves(MMEs) show complex relationships with the hosting Xiaocuo granite in Fujian area,including lenticular to rounded porphyritic microgranular enclaves containing abundant felsic/mafic phenocrysts,elongate mafic enclaves,and back-veining of the felsic host granite into mafic enclaves.LA-ICP-MS zircon U-Pb analyses show crystallization of the granite and dioritic mafic magmatic enclave during ca.132 and 116 Ma.The host granite and MMEs both show zircon growth during repeated thermal events at-210 Ma and 160-180 Ma.Samples from the magma mingling zone generally contain felsic-derived zircons with well-developed growth zoning and aspect ratios of 2-3,and maficderived zircons with no obvious oscillatory zoning and with higher aspect ratios of 5-10.However,these two groups of zircons show no obvious trace element or age differences.The Hf-isotope compositions show that the host granite and MMEs have similar ε_(Hf)(t) values from negative to positive which suggest a mixed source from partial melting of the Meso-Neoproterozoic with involvement of enriched mantlederived magmas or juvenile components.The lithologies,mineral associations,and geochemical characteristics of the mafic and felsic rocks in this study area indicate that both were intruded together,suggesting Early Cretaceous mantle—crustal interactions along the southeastern China continental margin.The Early Cretaceous magma mingling is correlated to subduction of Paleo-Pacific plate.     

Petrogenesis of Late Triassic mafic enclaves and host granodiorite in the Eastern Kunlun Orogenic Belt,China: Implications for the reworking of juvenile crust by delamination-induced asthenosphere upwelling

Late Triassic granitoids containing abundant mafic microgranular enclaves (MMEs) occur widely in the Eastern Kunlun Orogenic Belt (EKOB). In this work, we present mineral chemistry, zircon U-Pb ages and L-Hf isotopes, whole-rock chemistry and S-Nd isotope compositions of the MMEs and host granodiorite from the Huda pluton in the Elashan area within the easternmost domain of the EKOB. These rocks contain inherited (Meso- to Neoproterozoic) and xenocrystic (ca. 240 Ma) zircon grains that yield apparent older ages, whereas the magmatic zircons from MMEs and granodiorite yield similar weighted mean ages around 224 Ma, which are interpreted as their crystallization ages. The MMEs have low SiO₂ but high TiO₂, TFe₂O₃, CaO, MgO and MnO concentrations with relatively high Mg^# values (48–54) and 100MnO/(MnO + MgO + TFe₂O₃) ratios (1.2–1.6). They display identical Sr-Nd-Hf isotope compositions to the host granite. Combined with petrological evidence, we suggest that the MMEs are cognate cumulates that formed by pressure quenching during the late stage of magma evolution from the same parental magma of the host granodiorite, rather than a magma mixing origin. The granodiorite is calc-alkaline to high-K calc-alkaline, metaluminous I-type granite. They show relatively low SiO₂ and MnO, but high MgO, Al₂O₃, CaO and TFe₂O₃ contents with Mg^# values of 45–50. They are enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), such as Rb, Th, K and Pb, and are depleted in P and high field strength elements (HFSE) including Nb, Ta and Ti. These rocks display slightly negative Eu anomalies and low Sr/Y and La/Yb ratios. Together with the rim-ward chemically evolved nature of some phenocrysts, the comparatively high initial Sr isotope (0.70888–0.70912), low whole-rock ε_Nd(t) (−5.6 to −6.0) and zircon ε_Hf(t) (−3.3 to −0.1) values, and low Nb/Th (0.11–0.26) and Ta/U (0.53–0.68) ratios, we suggest that the granodiorite magma was sourced from the lower crust. Considering their comparatively young two-stage Nd and Hf model ages (1.42–1.49 Ga and 1.13–1.42 Ga, respectively) and same trace element character with the juvenile crust beneath the EKOB, we interpret the juvenile lower crust as the dominant source rocks for the granodiorite. Based on our data and regional geological evidence, we suggest that the partial melting of juvenile crust resulted from delamination-related asthenosphere mantle upwelling. The latter process resulted in extensive melting of the lower crust, producing a major Late Triassic magmatic flare-up event in the EKOB.     

Petrogenesis of the Upper Jurassic Monopigadon pluton related to the Vardar/Axios ophiolites (Macedonia,northern Greece) and its geotectonic significance

The origin, evolution and geotectonic setting of the Upper Jurassic Monopigadon granitoid pluton (Chalkidiki, Central Macedonia) are studied. The pluton is composed of slightly peraluminous to peraluminous high-K calc-alkaline biotite granodiorite (BGrd), biotite granite (BGr), leucogranite (LGr) and aplites (Apl). Enclosed rocks (Enc) are mostly xenoliths, surmicaceous enclaves and biotite clots occurring frequently in BGrd and BGr. Serpentinite bodies as well as amphibolite and calc-silicate hornfelses are exposed as inliers in the pluton. The granitoids are characterized by relatively low Sr contents (<180 ppm) and low Sr/Y ratio (0.4–6.4). REE are enriched in the granitic rocks (La_CN=89–148, Lu_CN=6–25) and the enclaves (La_CN=19–55, Lu_CN=15–18). The (La/Lu)_CN ratio ranges from 10.5 to 4.9 in BGrd, from 11.1 to 3.8 in BGr and from 11.3 to 25.7 in LGr. The BGrd and BGr show similar LILE-enriched, spiked patterns with negative anomalies at Ba, Ta, Nb, Sr and Ti and a positive anomaly at Pb, while the patterns of LGr show higher Ta, Nb, Sr, Ti negative and Pb positive anomalies. Sr initial isotopic ratios vary from 0.7147 to 0.7174 in BGrd, are relatively constant at 0.7105–0.7113 in BGr, and range from 0.7213 to 0.7340 in LGr, while they are lower in the enclaves (0.7087–0.7094). BGrd shows the lowest ε_Nd values (?8.31 to ?6.43), while it ranges from ?6.11 to ?4.26 in BGr and from ?3.37 to ?0.89 in LGr. Late Triassic to Late Jurassic intrusion zircon ages are reported for the Monopigadon pluton, which is unconformably overlain by Kimmeridgian–Tithonian limestones, whereas fragments of the plutonic rocks occur in the limestones. The geochemical variability of the BGrd is reproduced by two different AFC models having the same parental magma and assimilation/fractionation ratio but different assimilated end members. Geochemical modelling suggests that the BGr variability could be reproduced by two different FC models having the same parental magma but with different fractionating assemblages. The BGrd and BGr have similar sources and they likely originated by partial melting of middle-lower crustal rocks with intermediate-basaltic compositions, such as amphibolites, andesites and basalts. Felsic garnet granulites and metapelites are candidate source rocks for LGr. It is suggested that the Monopigadon plutonic rocks originated by melting of an inhomogeneous crust in a volcanic arc environment due to the heating of mantle-derived magmas, which, however, had not mixed or mingled with the crustal melts.     

Double injection events of mafic magma into supersolidus Yucheon granites to produce two types of mafic enclaves in the Cretaceous Gyeongsang Basin,SE Korea

Petrographic and geochemical features of the Cretaceous Yucheon granites and their mafic microgranular/magmatic enclaves (MMEs), SE Korea, reveal that the MMEs originated from magma mixing. Mesoscopic and microscopic features indicate that mechanical mixing operated heterogeneously to produce the MMEs with a wide range of sizes and textures. Chemical compositions of amphibole, biotite, and plagioclase rims of both the MMEs and host granites are almost identical, indicating that chemical homogenization took place to some extent after the mechanical mixing. Plagioclase cores, however, have various compositions depending on the host rocks and/or sampling locations, suggesting their sluggish re-equilibration. The MMEs are divided into Type A (low TiO₂, very fine-grained, chilled margins) and Type B (high TiO₂, fine- to medium-grained, no chilled margins). The lower TiO₂ MMEs cooled more rapidly and interacted with granitic magma for a shorter period of time than the higher TiO₂ MMEs. Additionally, the former are less enriched in HREEs than the latter. Zoned plagioclase has two zones of increased An content. These features are indicative of double injection events of mafic magma. A previous model explains the magma mixing as resulting from the generation of a slab window due to Kula-Pacific ridge subduction. The model cannot, however, explain the eastward younging of the granites in Korea, necessitating a new, more elaborate model of Cretaceous geodynamics and magmatism in East Asia.     

Mineral growth in melt conduits as a mechanism for igneous layering in shallow arc plutons: mineral chemistry of Fisher Lake orbicules and comb layers (Sierra Nevada,USA)

Different processes have been proposed to explain the variety of igneous layering in plutonic rocks. To constrain the mechanisms of emplacement and crystallization of ascending magma batches in shallow plutons, we have studied comb layers and orbicules from the Fisher Lake Pluton, Northern Sierra Nevada. Through a detailed study of the mineralogy and bulk chemistry of 70 individual layers, we show that comb layers and orbicule rims show no evidence of forming through a self-organizing, oscillatory crystallization process, but represent crystallization fronts resulting from in situ crystallization and extraction of evolved melt fractions during decompression-driven crystallization, forming a plagioclase-dominated cres-cumulate at the mm- to m-scale. We propose that the crystal content of the melt and the dynamics of the magmatic system control the mechanisms responsible for vertical igneous layering in shallow reservoirs. As comb layers crystallize on wall rocks, the higher thermal gradients will increase the diversity of comb layering, expressed by inefficient melt extraction, thereby forming amphibole comb layers and trapped apatite + quartz saturated evolved melt fractions. High-An plagioclase (An₉₀–An_97.5) is a widespread phase in Fisher lake comb layers and orbicule rims. We show that a combination of cooling rate, latent heat of crystallization and pressure variations may account for high-An plagioclase in shallow melt extraction zones.     

我国东北小古里河-科洛-五大连池-二克山火山带钾质矿物成因及地质意义

东北黑龙江小古里河-科洛-五大连池-二克山火山岩带是我国近代保存最好的火山群之一,此带火山岩的岩石化学特点全都强碱富钾,K₂O/Na₂O>1.2,属于一套高钾过碱性火山岩。通过对东北钾质火山岩及金云母橄榄岩地幔捕虏体中钾质矿物金云母、白榴石的成分、结晶环境与岩浆成分及来源关系的研究,认为在岩石圈伸展构造背景下,地幔金云母橄榄岩的低度部分熔融形成钾质岩浆,钾质岩浆上升到地壳浅部经历了白榴石的结晶作用。岩浆演化晚期,因钾质矿物大量晶出导致岩浆相对富钠而出现他形霞石和方钠石等填隙矿物。火山岩及地幔捕虏体中富挥发分矿物金云母、白榴石、磷灰石、霞石和方钠石还提供了钾质岩浆富含H₂O、F、Cl、P等挥发分的证据。     

冈底斯带西段那木如岩体始新世岩浆作用及构造意义

冈底斯带西段狮泉河南部那木如岩体岩性变化较大,其中产出大量基性岩透镜体及暗色微细粒包体,空间上与花岗岩类呈渐变过渡接触关系。本文在详细野外调研的基础上,对狮泉河-札达一带那木如花岗岩及其中基性岩石进行了系统的岩石学、地球化学和同位素年代学研究。结果表明,那木如岩体主体岩性为黑云母花岗岩,其SiO₂为65%~76%,全碱含量较高,花岗岩中K₂O+Na₂O=5.50%~8.71%,基性岩石中则4.42%~6.7%。花岗岩类稀土元素最高含量为284.8×10^-6,最低只有105.4×10^-6;而基性岩类最高为120.4×10^-6,最低72.48×10^-6。两者稀土元素分配曲线均呈右倾平缓样式,花岗岩具有不明显Eu负异常,微量元素显示出花岗岩类和基性岩类具有相似的蛛网分布样式。两者均明显富K而亏损Nb、Ti等不活泼的HFS元素,显示出明显的岩浆混合作用趋势。4件花岗岩和基性岩样品所显示的LA-ICP-MS法锆石U-Pb年龄分别为46.11±0.78Ma、45.47±0.4Ma、46.7±2.9Ma和45.4±1.4Ma,变化在45.4~46.7Ma范围内,表明始新世早期(~46Ma)区域发生了岩浆混合作用。这一时限与冈底斯中、东部岩浆作用时代(40~52Ma)非常一致,表明始新世早期整个冈底斯发生了规模巨大的岩浆事件,暗示着印度-欧亚大陆碰撞作用在东西方向上所表现出的同时性。     

Petrogenesis of mafic microgranular enclaves (MMEs) in the oligocene-miocene granitoid plutons from northwest Anatolia,Turkey

Mafic microgranular enclaves (MMEs) in host granitoids can provide important constraints on the deep magmatic processes. The Oligocene-Miocene granitoid plutons of the NW Anatolia contain abundant MMEs. This paper presents new hornblende Ar-Ar ages and whole-rock chemical and Sr-Nd isotope data of the MMEs from these granitic rocks. Petrographically, the MMEs are finer-grained than their host granites and contain the same minerals as their host rocks (amphibole + plagioclase + biotite + quartz + K-feldspar), but in different proportions. The Ar-Ar ages of the MMEs range from 27.9 ± 0.09 Ma to 19.3 ± 0.01 Ma and are within error of their respective host granitoids. The MMEs are metaluminous and calc-alkaline, similar to I-type granites. The Sr-Nd isotopes of MMEs are 0.7057 to 0.7101 for ⁸⁷Sr/⁸⁶Sr and 0.5123 to 0.5125 for ¹⁴³Nd/¹⁴⁴Nd, and are similar to their respective host granitoids. These lithological, petrochemical and isotopic characteristics suggest that the MMEs in this present study represent chilled early formed cogenetic hydrous magmas produced during a period of post-collisional lithospheric extension in NW Anatolia. The parental magma for MMEs and host granitoids might be derived from partial melting of underplated mafic materials in a normally thickened lower crust in a post-collisional extensional environment beneath the NW Anatolia. Delamination or convective removal of lithospheric mantle generated asthenospheric upwelling, providing heat and magma to induce hydrous re-melting of underplated mafic materials in the lower crust.