青海沱沱河地区那日尼亚铅锌矿床 地质与地球化学研究

那日尼亚铅锌矿床是在青藏高原近来发现的、与钾质火山岩岩浆活动有关的矿床.分析表明,新鲜赋矿火山岩siO2含量62.9％ ～～68.6％,K2O含量5.1％～5.8％,属钾玄岩系列,其轻稀土和大离子亲石元素相对富集,Nb、Ta、Ti等元素强烈亏损,Sr/Y-Y图解投影点落入已报道的藏北钾质-超钾质岩分布范围之内,指示岩浆起源于富集地幔或受下地壳物质混染的软流圈地幔.矿床的矿体呈脉状出现在粗面岩中,由一系列细脉状的矿石构成,硫化物主要是方铅矿和黄铁矿,也含少量闪锌矿和黄铜矿,脉石矿物以石英为主,并发育方解石、白云石、绢云母,围岩蚀变以白云母化和黄铁矿化为主.石英中流体包裹体为盐水体系,均一温度为170～～300℃、盐度为2％～9％NaCleq(质量分数),指示成矿流体可能来自岩浆活动驱动的地表水;方铅矿δ34S值介于-0.1～1.7之间,铅同位素组成落入藏北钾质-超钾质岩石的组成范围内,指示硫和铅均来自赋矿的钾质火山岩.那日尼亚铅锌矿床与沱沱河地区碳酸盐岩容矿铅锌矿床的地质和地球化学特征差别明显,两者不是一套成矿系统的产物.     

Late syn-to post-collisional magmatism in Madagascar:The genesis of the Ambalavao and Maevarano Suites

The East African Orogen involves a collage of Proterozoic microcontinents and arc terranes that became wedged between older cratonic blocks during the assembly of Gondwana.The Ediacaran-Cambrian Ambalavao and Maevarano Suites in Madagascar were emplaced during the waning orogenic stages and consist of weakly deformed to undeformed plutonic rocks and dykes of mainly porphyritic granite but also gabbro,diorite and charnockite.U-Pb geochronological data date emplacement of the Ambalavao Suite to between ca.580 Ma and 540 Ma and the Maevarano Suite to between ca.537 Ma and522 Ma.Major and trace element concentrations are consistent with emplacement in a syn-to postcollisional tectonic setting as A-type(anorogenic) suites.Oxygen(δ~(18)O of 5.27‰-7.45‰) and hafnium(ε_(Hf)(t) of-27.8 to-12.3) isotopic data from plutons in the Itremo and Antananarivo Domains are consistent with incorporation of an ancient crustal source.More primitive δ~(18)O(5.27‰-5.32‰) andε_(Hf)(t)(+0.0 to+0.2) isotopic values recorded in samples collected from the Ikalamavony Domain demonstrate the isotopic variation of basement sources present in the Malagasy crust.The Hf isotopic composition of Malagasy zircon are unlike more juvenile Ediacaran-Cambrian zircon sou rces elsewhere in the East African Orogen and,as such,Madagascar represents a distinct and identifiable detrital zircon source region in Phanerozoic sedimentary provenance studies.Taken together,these data indicate that high-T crustal anatexis,crustal assimilation and interaction of crustal material with mantle-derived melts were the processes operating during magma emplacement.This magmatism was coeval with polyphase deformation throughout Madagascar during the amalgamation of Gondwana and magmatism is interpreted to reflect lithospheric delamination of an extensive orogenic plateau.     

Petrology and geodynamic significance of the post-collisional Pan-African magmatism in the Eastern Saghro area (Anti-Atlas, Morocco)

The Saghro Group consists of a thick volcanic-sedimentary sequence with intercalated basaltic lavas, the first magmatic event in eastern Saghro area. Nd isotopes of basaltic pillow lavas show T_DM model ages ranging from 640 to 580 Ma, which represent a maximum age for basalt eruption.Granitoids within the Saghro Group consist of a charnockitic suite, tonalites, granodiorites and monzogranites. They are high-K calc-alkaline (HKCA) with a post-collisional character, and were emplaced at high-levels in the crust. Their ages of emplacement are within the 580–560 Ma bracket, implying that the entire Saghro Group is slightly older than or partly coeval to granitoid emplacement and implying a common geodynamical setting. Sr–Nd isotopic compositions and Nd T_DM model ages point to a mixed origin, combining a juvenile mantle source and an Eburnean crustal component, which could be the West African Craton (WAC). The juvenile component in the Saghro granitoids could be the depleted upper mantle that has sourced the earlier basalts.Field observations, geochemical and geochronological data together support that, during the Pan-African orogeny, the Anti-Atlas was subjected to a regional transpressional to transtensional event. This event would have been responsible for the dissection of the northern margin of the WAC into several blocks, the development of deep sedimentary basins and the emplacement of HKCA magmas.     

西藏轮郎铅锌矿床S、Pb同位素组成及对成矿物质来源的示踪

轮郎矽卡岩型铅锌矿床位于冈底斯斑岩铜矿带北侧的铅锌银成矿带。本文基于该矿床成矿地质条件,对矽卡岩型矿石中主要的金属矿物闪锌矿、方铅矿、磁黄铁矿和黄铁矿的S、Pb同位素特征进行研究,进一步探讨了矿床成矿物质来源,并与区域矿产特征进行对比。结果显示,矿石矿物的δ34S为-2.3‰~4.1‰,平均值为1.46‰,其频率直方图具有塔式分布特征,具幔源硫特征。矿石矿物的~(206)Pb/~(204)Pb为18.179~18.692,平均值为18.543;~(207)Pb/~(204)Pb为15.588~15.802,平均值为15.687;~(208)Pb/~(204)Pb为38.532~39.305,平均值为38.900;μ值在9.44~9.83之间,具有上地壳与地幔混合的造山带铅特征。轮郎矿床S、Pb同位素特征与冈底斯成矿带北亚带矽卡岩型矿床类似。成矿物质主要来源于念青唐古拉结晶基底片麻岩,部分来自造山带幔源物质。     

吉中-延边地区燕山期岩浆作用与矿床成矿系列研究

运用矿床的成矿系列理论,以构造岩浆演化为基础,对吉中-延边成矿带与燕山期岩浆作用有关的矿床成矿规律进行了分析总结。研究表明,受古太平洋板块俯冲方向、速度的制约,吉中—延边地区燕山期构造岩浆活动复杂,总体上可分为5次成岩成矿事件:①晚三叠世初基性超基性岩侵入,形成红旗岭铜镍矿床等岩浆型矿床;②晚三叠世—早侏罗世初,吉中地区高钾钙碱性岩浆活动,形成兰家金矿床等岩浆热液型矿床,延边地区中低钾钙碱性—高钾钙碱性岩浆活动,形成前山金矿床等火山-潜火山岩型矿床;③早侏罗世末—中侏罗世初,富铝酸性岩浆活动,形成大黑山钼矿床等斑岩型钼矿床;④中侏罗世末—晚侏罗世初,研究区以抬升剥蚀为主,成岩成矿作用较弱;⑤晚侏罗世末—早白垩世,吉中地区高钾钙碱性岩浆活动,形成二道甸子金矿床等岩浆热液型矿床,延边地区中低钾钙碱性—高钾钙碱性岩浆活动,形成小西南岔金铜矿床等火山-斑岩型矿床。在建立吉中—延边地区与燕山期岩浆作用有关的矿床成矿系列的基础上,进一步划分为6个矿床成矿亚系列,各亚系列在时间、空间上既有联系,又有区别,显示了成矿作用的复杂性。     

西藏多不杂铜矿床硫铅同位素地球化学示踪

多不杂铜矿床的发现是西藏地质找矿工作取得的重大突破,前人对其做了大量的研究,但始终未能合理解释该矿床的形成过程,究其原因主要是因为成矿物质和成矿流体来源认识上存在争议。本次研究指出了前人在多不杂铜矿床成因机制认识中存在的问题,并测试了岩矿石及单矿物的硫铅同位素组成。研究表明,矿床中硫主要来源于深源岩浆,幔源岩浆和流体在参与成岩成矿过程中伴随岩浆结晶成岩交代岩石而致自身流体性质演变,进而引发壳幔物质混染;铅同位素具有由岩浆作用形成的地壳与地幔混合的俯冲带铅的特征,伴随着含矿地幔流体的上升侵位,不可避免的混染了地壳铅,导致了多不杂铜矿床铅同位素组成的变化。综合分析认为该矿床的成矿物质和成矿流体主要来源于地幔,成矿动力主要来自深部地质过程,矿床的形成与地幔流体作用有关。     

青藏高原拉萨地块碰撞-后碰撞岩浆作用的三种类型及其对大陆俯冲和成矿作用的启示：Sr-Nd同位素证据

青藏高原拉萨地块是揭示印度与亚洲大陆碰撞的最重要的地区之一,其中广泛发育的碰撞-后碰撞岩浆作用记录了这一地区从特提斯洋俯冲消减到印度大陆陆内俯冲的全过程.本文基于对最新的Sr-Nd同位素资料的分析,从高原岩石圈的三种主要地球化学端元入手,分析了拉萨地块碰撞-后碰撞岩浆作用的类型及其在大陆俯冲与成矿作用方面的意义.青藏高原岩石圈可以分为三种主要的地球化学端元,一是青藏高原北部地球化学省（包括羌塘、可可西里和西昆仑）代表的青藏原始岩石圈地幔地球化学端元,42Ma以来在高原北部广泛分布的钾质岩浆岩的Nd-Sr同位素成分比较均一和稳定,同位素比值的范围较窄,^87Sr/^86Sr=0.707101～0.710536,εNd=-2～-9,tDM=0.7～1.3Ga;二是雅鲁藏布江蛇绿岩代表的新特提斯洋地幔端元,^87Sr/^86Sr=0.703000～0.706205,εNd=＋7.8～＋10,呈印度洋型MORB特征,属于印度洋型地幔域;三是喜马拉雅带地壳基底和花岗岩类显示的喜马拉雅地壳地球化学端元,εNd=-12～-25,^87Sr/^86Sr=0.733110～0.760000,具相对古老的Nd模式年龄,tDM=1.9～2.9Ga.拉萨地块碰撞-后碰撞岩浆作用可以划分出三种地球化学类型,即拉萨地块原地型、亲特提斯洋型和亲喜马拉雅型.这三种岩浆作用类型受控于上述三种地球化学端元在其源区的比例及相互作用.其中,拉萨地块原地型与青藏高原北部地球化学省特征一致,亲特提斯洋型代表了与新特提斯洋俯冲消减及其后的再循环有关的岩浆作用,亲喜马拉雅型岩浆岩的Sr-Nd同位素特征则可能指示了喜马拉雅大陆地壳端元的参与.超钾质火山岩是揭示印度大陆岩石圈向北俯冲的重要证据,印度大陆岩石圈俯冲作用可能同时控制了超钾质岩石和盐类矿床的产出,古老地壳物质作为源区参与了超钾质岩石和盐类矿床的成岩与成矿作用.拉萨地块中部地区的含矿斑岩属于亲特提斯洋型岩浆作用,因此具亲特提斯洋型特征的火山岩、浅成斑岩和深成侵入岩,是进一步寻找铜、钼、金矿床的重要目标.     

Petrogenesis of Cretaceous igneous rocks from the Duolong porphyry Cu–Au deposit,central Tibet: evidence from zircon U–Pb geochronology,petrochemistry and Sr–Nd–Pb–Hf isotope characteristics

The Duolong porphyry Cu–Au deposit (5.4 Mt at 0.72% Cu, 41 t at 0.23 g/t Au) was recently discovered in the southern Qiangtang terrane, central Tibet. Here, new whole‐rock elemental and Sr–Nd–Pb isotope and zircon Hf isotopic data of syn‐ and post‐ore volcanic rocks and barren and ore‐bearing granodiorite porphyries are presented for a reconstruction of magmas associated with Cu–Au mineralization. LA–ICP–MS zircon U–Pb dating yields mean ages of 117.0 ± 2.0 and 120.9 ± 1.7 Ma for ore‐bearing granodiorite porphyry and 105.2 ± 1.3 Ma for post‐ore basaltic andesite. All the samples show high‐K calc‐alkaline compositions, with enrichment of light rare earth elements (LREE) and large ion lithophile elements (LILE: Cs and Rb) and depletion of high field strength elements (HFSE: Nb and Ti), consistent with the geochemical characteristics of arc‐type magmas. Syn‐ and post‐ore volcanic rocks show initial Sr ratios of 0.7045–0.7055, ε_Nd(t) values of −0.8 to 3.6, (²⁰⁶Pb/²⁰⁴Pb)_t ratios of 18.408–18.642, (²⁰⁷Pb/²⁰⁴Pb)_t of 15.584–15.672 and positive zircon ε_Hf(t) values of 1.3–10.5, likely suggesting they dominantly were derived from metasomatized mantle wedge and contaminated by southern Qiangtang crust. Compared to mafic volcanic rocks, barren and ore‐bearing granodiorite porphyries have relatively high initial Sr isotopic ratios (0.7054–0.7072), low ε_Nd(t) values (−1.7 to −4.0), similar Pb and enriched zircon Hf isotopic compositions [ε_Hf(t) of 1.5–9.7], possibly suggesting more contribution from southern Qiangtang crust. Duolong volcanic rocks and granodiorite porphyries likely formed in a continental arc setting during northward subduction of the Bangong–Nujiang ocean and evolved at the base of the lower crust by MASH (melting, assimilation, storage and homogenization) processes. Copyright © 2014 John Wiley & Sons, Ltd.     

西藏甲玛铜多金属矿床S、Pb、H、O同位素特征及其指示意义

西藏甲玛铜多金属矿床是中国近年来发现的特大型铜铅锌多金属矿床之一,其产出的环境和形成机理为国内外矿床学家所关注。对甲玛铜多金属矿床中代表性岩（矿）石样品进行了S、Pb、H和O同位素分析,并从成矿系统中“源”的角度对其变化规律和成因意义进行了探讨。研究结果表明,甲玛铜多金属矿床的围岩和矿石中δ34S值变化于-4.9‰～0.5‰,在硫同位素直方图上呈塔式分布,成矿热液δ34SΣS在0值附近,与矿区内斑岩体的δ34S组成（-0.2‰～-0.7‰）十分接近。表明了矿石中硫的来源单一,主要来源于岩浆。矿石铅同位素变化范围较大,明显分为两组：第一组样品富放射性成因铅,其206Pb/204Pb变化范围为18.603～18.752,207Pb/204Pb变化范围为15.610～15.686,208Pb/204Pb变化范围为38.910～39.135;第二组样品具有低放射性成因铅特征,其206Pb/204Pb变化范围为18.130～18.270,207Pb/204Pb变化范围为15.470～15.480,208Pb/204Pb变化范围为38.140～38.850。各同位素比值相对稳定,变化范围较小。将含矿斑岩的岩石铅与矿石铅进行综合投图,两种类型的铅并非单阶段正常铅,而是混合铅,有放射性成因铅的加入。可能存在不同的源区或在演化过程中有不同源区物质的混入。氢氧同位素研究结果显示,氢同位素的来源主要为深部的花岗岩体,而氧同位素由于后期大气降水增多、水/岩比值升高,导致含矿石英脉中δ18OH2O降低。因此推断甲玛铜多金属矿床成矿流体早期以深源流体为主,随着成矿过程的演化,大气降水所占的比例也越来越大。     

Devonian alkaline magmatism in the northern North China Craton: Geochemistry,SHRIMP zircon U-Pb geochronology and Sr-Nd-Hf isotopes

The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton(NCC).The intrusion is mainly composed of quartz-monzonite.Here we report zircon SHRIMP U-Pb data from this intrusion which shows emplacement age of ca.381.5 Ma.The rock is metaluminous with high(Na_2O + K_2O) values ranging from 8.46 to 9.66 wt.%.The REE patterns of the rocks do not show any Eu anomaly whereas the primitive-mantle-normalized spider diagram shows strong positive Sr and Ba anomalies.The Wulanhada rocks exhibit high initial values of(~(87)Sr/~(86)Sr)_t = 0.70762-0.70809,low ε_(Nd)(t) =-12.76 to-12.15 values and negative values of ε_(Hf)(t) =-23.49 to-17.02 with small variations in(~(176)Hf/~(177)Hf),(0.281873-0.282049).These geochemical features and quantitative isotopic modeling results suggest that the rocks might have been formed through the partial melting of Neoarchean basic rocks in the lower crust of the NCC.The Wulanhada rocks,together with the Devonian alkaline rocks and mafic-ultramafic complex from neighboring regions,constitute a post-collisional magmatic belt along the northern NCC.     

西藏日阿窄铅多金属矿区古新世岩浆岩岩石成因及意义

日阿窄Pb多金属矿床位于南冈底斯中新世斑岩Cu-Mo-Au成矿带,发育花岗闪长岩、斑状花岗岩以及石英斑岩等多种岩浆岩。为研究矿区内岩浆活动及其成因意义,对区内岩浆岩进行了SHRIMP年代学、主微量元素以及Sr-Nd同位素地球化学研究,结果表明:花岗闪长岩(62. 70±0. 78Ma)、镁铁质包体、斑状花岗岩(60. 43±0. 86Ma)以及石英斑岩(60. 30±1. 20Ma)是南冈底斯古新世岩浆活动的产物,显示从基性到中酸性的演化趋势(Si O2=53. 43%～76. 46%)。岩浆岩Na2O+K2O含量介于4. 43%～6. 88%之间,铝饱和指数A/CNK集中于0. 90～1. 06,显示准铝质到过铝质、钙碱性-高钾钙碱性的I型花岗岩特征。稀土总量变化于98. 10×10~(-6)～100. 8×10~(-6)之间,具轻稀土相对富集的特点,同时具有明显的Nb、Ta、P、Ti等异常,暗示了其岩浆形成过程中可能经历了金红石、钛铁矿和磷灰石等的结晶分异过程。相比花岗闪长岩(δ_(Eu)=0. 80～0. 97),石英斑岩(δ_(Eu)=0. 38)显示更加亏损Eu、P和Ti,暗示了岩浆演化过程中的进一步结晶分异。岩石(~(87)Sr/~(86)Sr)i比值(0. 7046～0. 7056)、ε_(Nd)(t)值(-2. 9～-0. 2)揭示花岗闪长岩及其包体是由于新特提斯洋板片回撤时引起地幔软流圈上涌而诱发新生镁铁质下地壳部分熔融形成的岩浆,在经历了一定程度分离结晶作用后形成。石英斑岩具有相似的源区,但有更多的壳源组分的加入,推测为同一岩浆房进一步发生斜长石或钾长石结晶分异的产物。结合该带已报道的古新世Pb-Zn多金属矿床,提出可能是北部念青唐古拉多金属成矿带古新世-始新世岩浆成矿作用的向南延伸引起了日阿窄矿化,认为南部的中新世冈底斯斑岩Cu-Mo-Au成矿带可能具有发育与Fe-Cu相关的多金属矿床的潜力。     

Geochemistry,geochronology, and petrogenesis of mid-Cretaceous Talabuco volcanic rocks,central Tibet: implications for the evolution of the Bangong Meso-Tethys

The widespread mid-Cretaceous igneous rocks in the northern margin of the Lhasa Block play an important role in understanding deep geologic processes, matter exchange at depth, and tectonic evolution of the Tibetan Plateau. In this paper, we report new zircon U-Pb ages, whole-rock major and trace element data, and Sr-Nd-Pb-Hf isotope data from the Talabuco andesites and basalts, which were dated at ~111 Ma. These rocks belong to the high-K calc-alkaline and shoshonite series, and show enrichment in terms of large-ion-lithophile elements (LILEs, e.g. Rb, U, and Th) and light rare earth elements (LREEs), but depletion of high-field-strength elements (HFSEs, e.g. Nb and Ti). The (⁸⁷Sr/⁸⁶Sr)_i ratios of the Talabuco andesites range from 0.7043 to 0.7048, and the ε_Nd(t) contents range from 0.68 to 4.33. The ratios of ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb are 18.6064–18.8993, 15.6233–15.6707, and 38.8634–39.1720, respectively. The ¹⁷⁶Lu/¹⁷⁷Hf and ¹⁷⁶Hf/¹⁷⁷Hf ratios of one sample range from 0.00081 to 0.00206 and 0.28280 to 0.28296, respectively. The ε_Hf(t) values for this sample range from 3.4 to 9.1, and the two-stage model Hf age (T_DM2) is 0.59–0.95 Ga. Combined with previous studies, the geochemical and isotopic data reveal that the parental magma of the Talabuco andesites was probably derived by partial melting of EM II-type sub-continental lithospheric mantle (SCLM). The Talabuco andesites are most likely generated by fractionation of mafic magma contaminated by subducted oceanic sediment and represent product of arc magmatism due to northward subduction of the Yarlung Zangbo Neo-Tethyan slab or southward subduction of the Bangong Meso-Tethyan slab.     

冈底斯西段第四纪钾质火山岩的发现及赛利普组的建立

冈底斯西段赛利普一带分布有大面积的钾质火山岩,以前曾被划归上新世一早更新世赛利普群。作者对这套火山岩地层进行了详细野外调查并重新测制了火山岩地层剖面,在该套火山岩下伏及层间湖相碎屑沉积层中获得ESR年龄0．268Ma与0．349Ma。岩石学、岩石化学研究表明,这套火山岩是以安粗质熔岩为主的钾玄岩系列一钾质碱性玄武岩系列火山岩,岩石类型及岩石组合稳定,岩层产状平缓,岩石新鲜,层位相对清楚,故将其命名为赛利普组,属第四纪早一中更新世。这一发现对研究冈底斯构造带新生代以来岩浆活动、构造演化,进而探讨青藏高原隆升机制有着重要的地质意义。     

粤西阳春中生代钾玄质侵入岩及其构造意义:Ⅰ.岩石学和同位素地质年代学

粤西阳春地区马山二长岩的岩石化学组成特征为典型的钾玄质岩石,岗尾、轮水石英二长岩和花岗闪长岩属酸性一偏中性的钾玄质系列岩石(少数样品为高钾钙碱性岩石),而石菉花岗闪长岩则为典型的钙碱性系列岩石,这些岩体在岩石化学演化趋势上存在显著的差异,不属于同一个岩石成因系列.40Ar-39Ar和Rb-Sr同位素定年结果表明,马山和岗尾岩体的形成年龄分别为(164±2)Ma和(154±1)Ma.阳春地区从中侏罗世到早白垩世期间发生了3次主要的岩浆活动,从早到晚岩浆的K富集程度逐渐降低,岩浆岩成分从钾玄质系列过渡到钙碱系列.     

Petrology and geochronology of the Namche Barwa Complex in the eastern Himalayan syntaxis, Tibet: Constraints on the origin and evolution of the north-eastern margin of the Indian Craton

The Namche Barwa Complex (NBC) in the eastern Himalayan syntaxis, south Tibet, is generally interpreted as the north-eastern extremity of the exposed Greater Himalayan Sequence, comprising Neoproterozoic to early Paleozoic sedimentary strata along the northern margin of the Indian continent. Field and petrological investigations indicate that the NBC consists mainly of orthogneiss, paragneiss, amphibolites and calc-silicate rocks. U-Pb zircon data demonstrate that the protoliths of the orthogneiss formed during late Paleoproterozoic at ca. 1610 Ma and also in early Paleozoic at ca. 490-500 Ma. The amphibolites were derived from mafic magmatic rocks formed during 1645 to 1590 Ma. Zircons in the paragneisses have highly variable inherited zircon ages ranging from the Neoarchean to early Paleozoic, with four major age populations of 2490 Ma, 1640 Ma, 990 Ma and 480 Ma. The calc-silicate rock has zircons with early Paleozoic metamorphic age of 538 Ma. Almost all the rocks of the NBC have been metamorphosed during Cenozoic with the metamorphic zircon U-Pb ages ranging from 8 to 30 Ma and a peak at 23 Ma. These, together with previous results suggest that the NBC was originally derived from an Andean-type orogeny following the Columbia supercontinent assembly, and experienced multiple reworking during the Grenvillian, Pan-African and Himalayan orogenies. We conclude that the NBC in the eastern Himalayan syntaxis was derived from different provenance and tectonic setting as compared to those of the Greater Himalayan Sequence which constitutes the high-grade metamorphic core of the western and central Himalayan orogenic belt. We thus infer that the NBC was originally part of the eastern segment of the Central Indian Tectonic Zone.     

西藏哈姆曲锑(金)矿床曲珍矿段S、Pb同位素组成及意义

西藏哈姆曲锑(金)矿床位于雅鲁藏布江结合带西缘, 矿体主要赋存于晚白垩世侵入岩中, 糜棱岩化闪长玢岩是其主要的赋矿围岩.矿体受NNE—SSW向断裂控制, 主要呈脉状、层状、透镜状产出.在野外地质调查和分析矿床成矿地质条件的基础上, 对矿床辉锑矿进行了 S、Pb 同位素研究, 探讨了矿床的成矿物质来源.辉锑矿δ34S值在...     

陕西柞山地区穆家庄铜矿铅同位素地球化学与成矿物质来源

穆家庄铜矿床位于南秦岭造山带柞（水）山（阳）地区的泥盆系中.矿体产于红岩寺-黑山复式向斜南翼金井河-胡家沟次级背斜南翼近轴部断裂中,赋矿岩石为泥盆系青石垭组中上部白云质岩,其空间展布明显受背斜陡倾南翼（倒转翼）近轴部的层间断裂-裂隙带构造控制,矿石主要有团块状和网脉状,其后生成矿现象非常明显.本文从铅同位素地球化学出发,来探讨产于秦岭泥盆系中铜矿的成矿物质来源和矿床成因等问题.研究表明,穆家庄铜矿矿石铅和近矿围岩岩石铅具有极高的放射性成因铅特点.通过对矿石铅、近矿围岩岩石铅与测定的寒武系碳硅质岩岩石全岩铅进行综合对比,发现它们的组成特征类似,说明穆家庄铜矿铅源来自于寒武系.     

西藏则学地区热液脉型铅锌矿S、Pb同位素组成及其对成矿物质来源的启示

德新和轧轧龙铅锌矿是冈底斯西段银铅锌多金属成矿带典型的热液脉型铅锌矿床,关于其成矿物质来源及与纳如松多铅锌矿成因联系的研究鲜有开展。本研究利用单矿物和全岩稳定同位素方法对德新和轧轧龙铅锌矿的主要金属硫化物和含矿花岗斑岩进行了S、Pb同位素组成分析和示踪,结果显示德新铅锌矿硫化物δ34SVCDT为3.5‰～7.4‰,平均值为6.1‰;含矿花岗斑岩δ334SVCDT为4.4‰～6.2‰,平均值为5.7‰;轧轧龙铅锌矿金属硫化物δ334SVCDT为2.7‰～8.3‰,平均值为5.1‰;德新和轧轧龙铅锌矿铅同位素比值比较稳定,变化范围基本一致;铅同位素μ值为9.48～9.82,平均值为9.64;△β、△γ变化范围基本一致,均值相差较小,表明则学地区热液脉型铅锌矿金属硫化物和斑岩具有一致的S、Pb同位素组成,铅同位素具正常铅特征;暗示硫源可能主要由花岗岩类提供,铅源则可能主要来自上地壳物质。综合前人研究认为,德新、轧轧龙热液脉型铅锌矿和纳如松多铅锌矿具有一致的硫、铅同位素组成,三者应存在成因上的联系,可能属于同一成矿系统产物;花岗斑岩为则学地区热液脉状铅锌矿化提供了成矿物质。     

西藏冈底斯带侏罗纪岩浆作用的时空分布 及构造环境

在新近完成的1：25万区域地质调查资料和相关研究成果的基础上,初步研究了西藏冈底斯带侏罗纪岩浆作用的分布特点及其年代学,并利用已有的地球化学数据重点分析了早期关注程度较低的侏罗纪花岗岩类岩浆作用的性质。目前在冈底斯弧背断隆带未发现侏罗纪火山岩;在冈底斯东部地区,早侏罗世岩浆活动几乎同时发生于南冈底斯（叶巴组火山岩和鸟郁、尼木花岗岩类）、冈底斯弧背断隆带（宁中、金达、布久花岗岩类）和北冈底斯（聂荣花岗岩类）,中晚侏罗世接奴群和拉贡塘组火山岩断续分布于北冈底斯,晚侏罗世岩浆活动零星分布于沙莫勒一麦拉一洛巴堆～米拉山断裂以北。将冈底斯侏罗纪岩浆活动置于时空框架内分析发现,南冈底斯和北冈底斯在侏罗纪时主要受俯冲作用的影响．而冈底斯弧背断隆带和中冈底斯自早侏罗世以来除了受到俯冲作用的影响外,还受到自东向西逐步扩展的碰撞作用的影响。结合古地磁重建资料和其他新发现．认为冈底斯带侏罗纪这种岩浆活动的特点可用班公湖一怒江洋壳向南、新特提斯洋壳向北的双向剪刀式（剪刀口向西张开）俯冲模式来解释。     

西藏北冈底斯巴尔达地区岩浆作用的成因:地球化学、年代学及Sr-Nd-Hf同位素约束

前人对西藏冈底斯中北部白垩纪岩浆岩的岩石成因和地球动力学背景仍然存在很多解释。本文报道了位于北冈底斯(拉萨地块北部)东段巴尔达地区的岩浆岩锆石U-Pb定年、元素地球化学和Sr-Nd-Hf同位素数据,以对这一问题进行约束。巴尔达岩浆岩包括花岗闪长斑岩和安山玢岩。锆石U-Pb定年结果表明,巴尔达岩浆岩侵位于～114Ma,是北冈底斯早白垩世岩浆岩的典型代表之一。巴尔达岩浆岩两种岩石均为高钾钙碱性系列,其中花岗闪长斑岩的SiO2为64.45%～67.52%,全碱(K2O+Na2O)含量为6.23%～7.47%,铝饱和指数(A/CNK)为0.98～1.22,为兼具I型特点的S型花岗岩;安山玢岩SiO2为57.50%～62.15%,K2O含量为2.30%～3.60%,MgO含量为2.27%～4.40%。两种岩石均富集大离子亲石元素和Pb,亏损高场强元素和Ba等。与冈底斯成熟大陆地壳相比,巴尔达岩浆岩具有更高的εNd(t)值(-7.8～-6.8)和相对低的(87Sr/86Sr)t值(0.7094～0.7105),并且具有不均一的锆石εHf(t)值(-4.2～+3.3)和相对年轻的Hf模式年龄(639～975Ma)。锆石Hf同位素数据和锆石饱和温度(768～818℃)均显示幔源物质在巴尔达岩浆岩形成过程中发挥了重要作用。巴尔达岩浆岩可能是在南向俯冲的班公湖-怒江洋岩石圈断离背景下,由上涌的软流圈提供热量诱发岩石圈地幔熔融产生幔源基性熔体侵位到上部地壳,并引发周围酸性物质的熔融混合,混合过程中幔源组分的输入使S型熔体向I型熔体转化。