New LA-ICPMS U–Pb ages of detrital zircons from the Highland Complex: insights into late Cryogenian to early Cambrian (ca. 665–535 Ma) linkage between Sri Lanka and India

ABSTRACT

Here we report new LA-ICPMS U–Pb zircon geochronology of ultrahigh temperature (UHT) metasedimentary rocks and associated crystallized melt patches, from the central Highland Complex (HC), Sri Lanka. The detrital zircon ²⁰⁶Pb/²³⁸U age spectra range between 2834 ± 12 and 722 ± 14 Ma, evidencing new and younger depositional ages of sedimentary protoliths than those known so far in the HC. The overgrowth domains of zircons in these UHT granulites yield weighted mean ²⁰⁶Pb/²³⁸U age clusters from 665.5 ± 5.9 to 534 ± 10 Ma, identified as new metamorphic ages of the metasediments in the HC. The zircon ages of crystallized in situ melt patches associated with UHT granulites yield tight clusters of weighted mean ²⁰⁶Pb/²³⁸U ages from 558 ± 1.6 to 534 ± 2.4 Ma. Thus, using our results coupled with recently published geochronological data, we suggest a new geochronological framework for the evolutionary history of the metasedimentary package of the HC. The Neoarchean to Neoproterozoic ages of detrital zircons indicate that the metasedimentary package of the HC has derived from ancient multiple age provenances and deposited during the Neoproterozoic Era. Hence, previously reported upper intercept ages of ca. 2000–1800 Ma from metaigneous rocks should be considered as geochronological evidence for existence of a Palaeoproterozoic igneous basement which possibly served as a platform for the deposition of younger supracrustal rocks, rather than timing of magmatic intrusions into the already deposited ancient sediments, as has been conventionally interpreted. The intense reworking of entire Palaeoproterozoic basement rocks in the Gondwana Supercontinent assembly may have caused sediments of multiple ages and provenances to incorporate within supra-crustal sequences of the HC. Further, our data supports a convincing geochronological correlation between the HC of Sri Lanka and the Trivandrum Block of Southern India, disclosing the Gondwanian linkage between the HC of Sri Lanka and Southern Granulite Terrain of India.     

Geochronology and geochemistry of the late Neoproterozoic A-type granitic clasts in the southwestern Tarim Craton: petrogenesis and tectonic implications

ABSTRACT

Due to sparse data for deciphering the late Neoproterozoic tectonic history, there is still considerable debate on whether long-lasting superplume-related or long-duration subduction-related dynamics dominated the Tarim Craton. In this contribution, our field investigations detail the late Neoproterozoic siliciclastic successions, and we report the first granitic conglomerates with zircon U–Pb ages of 753.9 ± 3.7 Ma in the SW Tarim Craton. Importantly, detrital zircons from the thick Cryogenian sedimentary basin also contain a major zircon population at ca. 750 Ma. Together with seismic data, this suggests a large ca. 750 Ma magmatic event in the SW Tarim Craton. Geochemically, the granitic clasts exhibit A-type granite features with high SiO₂, high alkali but extremely low K, high FeO^T/MgO and Ga/Al, and high high-field strength elements (HFSEs) (i.e. Nb, Hf, and Ta) with significant depletion in Rb, K, Sr, P, Eu, and Ti, and significant negative Eu anomalies (Eu* = 0.13–0.36), showing ferroan granite affinities. Including the detrital zircons, the ca. 750 Ma zircons have a large range of negative εHf(t) values (?19.46 to ?1.16). Elemental and zircon Hf isotope data suggest that the granites were derived from Palaeoproterozoic reworked continental crust and are probably related to crustal thinning and extension. By comparison with previous studies, we conclude that Rodinia breakup was diachronous in the outer parts of the supercontinent.     

南辽河群盖县组的重新厘定:来自辽南地区黄花甸-苏子沟一带变质砂岩碎屑锆石U-Pb年代学证据

传统认为辽河群顶部的盖县组广泛分布于辽南地区。本文对岫岩县黄花甸-苏子沟一带的南辽河群盖县组变质长石石英砂岩和变质石英砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学研究。其中变质长石石英砂岩中碎屑锆石普遍发育核-边结构,核部具有清晰的振荡环带;变质石英砂岩中碎屑锆石基本无核-边结构,具有清晰或者略模糊的振荡环带。锆石微量元素分析结果显示,具有振荡环带锆石微区具有轻稀土元素(LREE)亏损、重稀土元素(HREE)相对富集的配分曲线特征,Ce正异常和Eu负异常明显,Th/U和Zr/Hf比值较高,表明其岩浆成因。变质长石石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于2506～1748Ma之间,且呈现～2178Ma和～1863Ma两个年龄主峰,表明主要物质来源为同时期花岗质岩石(条痕状花岗岩和斑状花岗岩);变质石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于3546～1950Ma之间,呈现～2149Ma年龄主峰值,表明主要物质来源为条痕状花岗岩,另有少量太古宙基底物质的加入。研究区变质长石石英砂岩～1.86Ga的年龄峰值与辽河群其它变沉积岩明显不同,表明沉积时代一定晚于～1.86Ga,即形成于辽河群古元古代变质作用之后。综合研究区盖县组变质长石石英砂岩与辽河群其它变沉积岩碎屑锆石U-Pb年龄的差异,我们建议将盖县组部分变沉积岩从辽河群中解体出来。     

Permian age of the Wudaogou Group in eastern Yanbian: detrital zircon U–Pb constraints on the closure of the Palaeo-Asian Ocean in Northeast China

The Wudaogou Group in eastern Yanbian, Northeast China, plays a key role in constraining the timing and eastward termination of the Solonker–Xra Moron River–Changchun Suture, where the Palaeo-Asian Ocean closed. The Wudaogou Group consists of schist, gneiss, amphibolite, metasedimentary, and metavolcanic rocks, all of which underwent greenschist- to epidote–amphibolite-facies regional metamorphism, with some hornfels resulting from contact metamorphism. To determine the age of deposition, the timing and grade of metamorphism, and the tectonic setting of the Wudaogou Group, we investigated the petrography and geochronology of the metamorphic rocks in this group. Zircons from the metasedimentary rocks of this group can be divided into metamorphic zircons and detrital zircons of magmatic origin. U–Pb ages of metamorphic zircons dated by LA-ICP-MS vary from 249 ± 4 to 266 ± 4 Ma, approximating the age of regional metamorphism in the eastern Yanbian area. Detrital zircons yield U–Pb ages ranging from 253 ± 5 to 818 ± 5 Ma, and indicate that the provenance of the Wudaogou Group experienced four tectonic–thermal events between 818 and 253 Ma: Neoproterozoic (ca. 818–580 Ma), Cambro–Ordovician (ca. 500–489 Ma), Devonian–Carboniferous (ca. 422–300 Ma), and middle–late Permian (ca. 269–253 Ma). The youngest detrital zircon, with a U–Pb age of 253 ± 5 Ma, defines the maximum depositional age of the Wudaogou Group. The presence of the Cambro-Ordovician and Neoproterozoic detrital zircons implies that the source of the Wudaogou Group had an affinity with Northeast China, which leads us to conclude that the Solonker–Xra Moron River–Changchun Suture extends from Wangqing to Hunchun in eastern Yanbian, and that the Palaeo-Asian Ocean may have closed at the end of the Permian or Early Triassic period.     

Dating of detrital zircons from the Dabure clastic rocks: the discovery of Neoproterozoic strata in southern Qiangtang,Tibet

ABSTRACT

This article reports the results of field mapping and the petrology of clastic rocks in the Dabure area, southern Qiangtang, Tibet, together with the results of U–Pb dating of detrital zircons from these rocks. The Dabure clastic rocks are characterized by low compositional and textural maturity, and they have been affected by lower greenschist facies metamorphism. The deposits exhibit the typical features of turbidites. Altogether, 279 detrital zircons were selected for U–Pb dating, and the ages fall into five groups: 550–650, ~800, 900–1100, 1600–1800, and 2300–2500 Ma. In general, the ages of the detrital zircons that are older than ~550 Ma are similar to those found elsewhere in the southern Qiangtang and Himalayan terranes. The most reliable youngest age of a detrital zircon from the Dabure clastic rocks is ~550 Ma. In the southern part of the Tibet Plateau, strata with the same ages and lithologies as the Dabure clastic rocks are widespread, especially in the Himalayan terrane. Combining our data with previous work on the basalts in the Dabure area (the Dabure basalts), we tentatively suggest that the Dabure clastic rocks represent the late Ediacaran (~550 Ma) sedimentary record for the Qiangtang terrane, and that before the late Neoproterozoic the southern Qiangtang terrane was possibly connected to the Himalayan terrane.     

Geochronology (SHRIMP II) of zircons from Archean stratotectonic associations of Karelian greenstone belts: Significance for stratigraphic and geodynamic reconstructions

Individual grains of zircon from the Archean Kostomuksha, North Karelian and Matkalakhta greenstone belts, which are situated respectively in western, northern and eastern Karelia, are studied using the ion microprobe SHRIMP II. As a result, the oldest ²⁰⁷Pb/²⁰⁶Pb ages of 3151 ± 4.6 and 3329 ± 16 Ma are first determined for detrital zircons from northern and eastern Karelia. The ²⁰⁷Pb/²⁰⁶Pb ages estimated for two subsequent metamorphic events of Archean Eon in eastern Karelia correspond to 3.25 and 3.17–3.10 Ga. The age value of 2711 ± 9.6 Ma is determined for silicic volcano-plutonic complex and quartz stockwork in northern Karelia and the date 2821 ± 15 Ma for magmatic rocks of eastern Karelia. Silicic volcanics from an oceanic plateau section in the Kostomuksha belt are dated at 2791.7 ± 6.1 Ma for the first time in the Archean of Fennoscandia. The oldest detrital zircons from siliciclastic metasediments determine the stabilization time of Archean continental nuclei in East Fennoscandia. The younger generation of greenstone belts is exemplified in the Karelian craton by the Matkalakhta and Kostomuksha structures comprising rock associations less than 2.82 Ga old, mafic rocks of the Kontokki Group included. Geological history of these belts corresponds to geodynamic mesocycle 90–110 Ma long and to the Archean global epoch of metallogeny, which was responsible for origin of most valuable deposits of base and precious metals.     

U-Pb SHRIMP and Nd isotopic data from the western Bohemian Massif (Bayerischer Wald,Germany): Implications for Upper Vendian and Lower Ordovician magmatism

U-Pb SHRIMP dating of zircons of metamagmatites from the Bayerischer Wald (Germany) reveals a complex evolution of this section of the Moldanubian Zone exposed in the western Bohemian Massif of the central European Variscan belt. In the south-western part of the Bayerischer Wald Upper Vendian magmatism is constrained by pooled ²⁰⁶Pb/²³⁸U mean ages of 555±12, 549±7 and 549±6 Ma from metarhyolites and a metabasite. Inherited zircon cores were not observed. Zircon overgrowths, yielding pooled ²⁰⁶Pb/²³⁸U ages of 316±10 and 319±5 Ma, provide evidence for Variscan metamorphic zircon growth; cathodoluminescence imaging reveals a two-stage metamorphic overprint.In contrast, Lower Ordovician magmatism and anatexis are documented in the north-eastern parts of the Bayerischer Wald by metagranitoids (480±6, 486±7 Ma), an eclogitic metabasite (481±8 Ma) and a leucosome (491 to 457 Ma). Inherited zircon cores are found in Lower Ordovician metagranitoids and the leucosome, indicating a Palaeoproterozoic-Archaean (ca. 2.7, 2.0 Ga) source region, presumably of Gondwana affinity (West African craton), and documenting Cadomian magmatism (ca. 640 Ma). Post-Cadomian metamorphism is inferred from concordant ages of 433±4 and 431±7 Ma.Upper Vendian magmatism is assumed at an active continental margin with ensialic back-arc development (ε_Nd(t) –3.01 to +1.22); the lack of inherited zircon is due to either derivation from juvenile (?volcanic arc) material or complete isotopic resetting of pre-existing zircon. An active continental margin setting, possibly with some lateral variation (accretion/collision) is envisaged for the Lower Ordovician, producing granitoids, rhyolites and leucosomes (ε_Nd(t) -0.5 to -6.27); MORB-type metabasites may be related to ZEV or Mariánské Lázně Complex metabasites. A tentative palaeogeographic reconstruction puts the “Bayerischer Wald” in close relationship with the Habach terrane (proto-Alps), as the “eastern” extension of terranes of the northern Gondwana margin.     

北秦岭西段冥古宙锆石(4.1～3.9Ga)年代学新进展

2007年王洪亮等报道在北秦岭西段火山岩中获得一粒年龄为4079±5Ma的冥古宙捕虏锆石。之后,对这一发现开展了深入的调查研究,我们除利用SHIMP技术方法对原4079Ma的锆石进行验证外,新获得了两粒~(207)Pb/~(206)Pb年龄为4007±29Ma和3908±45Ma捕获的变质成因锆石,表明早在4.0Ga已经有变质作用的发生,这或许说明在冥古宙时期地球已经具有相当规模和厚度的地壳。同时开展的岩石学研究表明,蕴含古老锆石的母岩属于火山碎屑熔岩类而不是火山熔岩。     

Identification of repeated Alpine (ultra) high-pressure metamorphic events by U–Pb SHRIMP geochronology and REE geochemistry of zircon: the Rhodope zone of Northern Greece

U–Pb sensitive high resolution ion microprobe (SHRIMP) zircon geochronology, combined with REE geochemistry, has been applied in order to gain insight into the complex polymetamorphic history of the (ultra) high pressure [(U)HP] zone of Rhodope. Dating included a paragneiss of Central Rhodope, for which (U)HP conditions have been suggested, an amphibolitized eclogite, as well as a leucosome from a migmatized orthogneiss at the immediate contact to the amphibolitized eclogite, West Rhodope. The youngest detrital zircon cores of the paragneiss yielded ca. 560 Ma. This date indicates a maximum age for sedimentation in this part of Central Rhodope. The concentration of detrital core ages of the paragneiss between 670–560 Ma and around 2 Ga is consistent with a Gondwana provenance of the eroded rocks in this area of Central Rhodope. Metamorphic zircon rims of the same paragneiss yielded a lower intercept ²⁰⁶Pb/²³⁸U age of 148.8±2.2 Ma. Variable post-148.8 Ma Pb-loss in the outermost zircon rims of the paragneiss, in combination with previous K–Ar and SHRIMP-data, suggest that this rock of Central Rhodope underwent an additional Upper Eocene (ca. 40 Ma) metamorphic/fluid event. In West Rhodope, the co-magmatic zircon cores of the amphibolitized eclogite yielded a lower intercept ²⁰⁶Pb/²³⁸U age of 245.6±3.9 Ma, which is interpreted as the time of crystallization of the gabbroic protolith. The metamorphic zircon rims of the same rock gave a lower intercept ²⁰⁶Pb/²³⁸U age of 51.0±1.0 Ma. REE data on the metamorphic rims of the zircons from both the paragneiss of Central Rhodope and the amphibolitized eclogite of West Rhodope show no Eu anomaly in the chondrite-normalized patterns, indicating that they formed at least under HP conditions. Flat or nearly flat HREE profiles of the same zircons are consistent with the growth of garnet at the time of zircon formation. Low Nb and Ta contents of the zircon rims in the amphibolitized eclogite indicate concurrent growth of rutile. Based on the REE characteristics, the 148.8±2.2 Ma age of the garnet–kyanite paragneiss, Central Rhodope and the 51.0±1.0 Ma age of the amphibolitized eclogite, West Rhodope are interpreted to reflect the time close to the (U)HP and HP metamorphic peaks, respectively, with a good approximation. The magmatic zircon cores of the leucosome in the migmatized orthogneiss, West Rhodope, gave a lower intercept ²⁰⁶Pb/²³⁸U age of 294.3±2.4 Ma for the crystallization of the granitoid protolith of the orthogneiss. Two oscillatory zircon rims around the Hercynian cores, yielded ages of 39.7±1.2 and 38.1±0.8 Ma (2σ errors), which are interpreted as the time of leucosome formation during migmatization. The zircons in the leucosome do not show the 51 Ma old HP metamorphism identified in the neighboring amphibolitized eclogite, possibly because the two rock types were brought together tectonically after 51 Ma. If one takes into account the two previously determined ages of ca. 73 Ma for (U)HP metamorphism in East Rhodope, as well as the ca. 42 Ma for HP metamorphism in Thermes area, Central Rhodope, four distinct events of (U)HP metamorphism throughout Alpine times can be distinguished: 149, 73, 51 and 42 Ma. Thus, it is envisaged that the Rhodope consists of different terranes, which resulted from multiple Alpine subductions and collisions of micro-continents, rather similar to the presently accepted picture in the Central and Western Alps. It is likely that these microcontinents were rifted off from thinned continental margins of Gondwana, between the African and the European plates before the onset of Alpine convergence.     

Zircon from the East Orebody of the Bayan Obo Fe–Nb–REE deposit,China, and SHRIMP ages for carbonatite-related magmatism and REE mineralization events

Extremely U-depleted (<1 ppm) zircons from H8 banded ores in the East Orebody of the Bayan Obo REE–Nb–Fe deposit are presented, with mineral compositions, textures, ²³²Th–²⁰⁸Pb SHRIMP ages and petrological context. Cores of East Orebody zircon contain up to 7 wt% HfO₂ and are zoned, depicting bipyramidal crystal forms. A distinct generation of patchy, epitaxial rim zircon, similarly depleted in U, is intergrown with rare earth ore minerals (bastnäsite, parisite, monazite). Overprinting aegirine textures indicate paragenetically late, reactive Na-rich fluids. Chondrite-normalized REE patterns without Eu anomalies match closely with those from the Mud Tank and Kovdor carbonatitic zircons. Increased HREE in rims ((Lu/Gd)_N 43–112) relative to cores ((Lu/Gd)_N 6–7.5) and the localized presence of xenotime are attributable to reactive, mineralizing fluid compositions enriched in Y, REE and P. Cathodoluminescence further reveals HREE fractionation in rims, evidenced by a narrow-band Er³⁺ emission at 405 nm. The extreme depletion of U in core and rim zircon is characteristic for this mineral deposit and is indicative of a persistent common source. U depletion is also a characteristic for zircons from carbonatitic or kimberlitic systems. ²³²Th–²⁰⁸Pb (SHRIMP II) geochronological data reveal the age of zircon cores as 1,325 ± 60 Ma and a rim-alteration event as 455.6 ± 28.27 Ma. The combined findings are consistent with a protolithic igneous origin for zircon cores, from a period of intrusive, alkaline–carbonatitic magmatism. Fluid processes responsible for the REE–Nb mineralizations affected zircon rim growth and degradation during the widely reported Caledonian events, providing a new example in a localized context of HREE enrichment processes.     

Metamorphic phase equilibria modelling and zircon U–Pb geochronology of ultrahigh-temperature cordierite granulites from the Madurai Block,India: implications for hot Gondwana crust

The Madurai Block (MB) is the largest Precambrian crustal block in the Southern Granulite Terrane (SGT) of India and hosts rare cordierite- and orthopyroxene-bearing granulites. Investigations based on field study, petrology, metamorphic P–T estimation, and detrital zircon geochronology of these granulites are crucial for understanding the ultrahigh-temperature (UHT) metamorphism and crustal evolution in this block. Here we investigate the petrology and zircon U–Pb geochronology of two new localities of cordierite granulites at Kottayam (southern MB; SMB) and Munnar (central MB; CMB). Petrographic observations and phase equilibria modelling results indicate that these rocks experienced UHT metamorphism with the peak temperature exceeding 950℃ and involving clockwise P–T paths. The prograde mineral assemblages define the P–T conditions of 6.8–8.7 kbar and 750–875℃. The peak conditions are estimated using pseudosection modelling and geothermometry, which yield P–T estimates of 7.1–9.1 kbar and 955–985℃. The retrograde cooling and decompression are inferred at 860–790℃ and <6.5 kbar, respectively. Partial melting played an important role during metamorphism and contributed to the overgrowth around detrital zircons. The melt production process was probably related to biotite dehydration melting, and was mainly triggered by heating, with or without the effect of decompression. Detrital zircons in cordierite granulite samples from the two localities show similar age distributions and have dominantly Neoproterozoic ages (1024–760 Ma). The zircon cores show oscillatory zoning with a wide range of Th/U ratios (0.01–0.96), implying complex protoliths from multiple Neoproterozoic provenances from both southern and central domains of the MBs. Zircon rims and homogeneous bright zircons yield mean ages of 549 ± 5 Ma, 536 ± 6 Ma, and 544 ± 6 Ma, which are interpreted to represent zircon overgrowths during the post-peak cooling and decompression process. The timing of peak UHT metamorphism is constrained as 549–599 Ma, which coincides with the assembly of the Gondwana supercontinent.     

Timing the tectonic mingling of ultramafic rocks and metasediments in the southern section of the coastal accretionary complex of central Chile

Uranium-lead ages are reported for zircons from ultramafic bodies and metamorphic host rocks of the Western Series that outcrop at La Cabaña, in the southern section of the coastal accretionary complex of central Chile. Metasedimentary mica schists hosting the ultramafic bodies contain a main detrital zircon population of Devonian age (365–380 Ma) clustering around ~368 Ma, differing significantly from neighbouring areas where Devonian zircons are scarce. Zircons from the metasomatic reaction zones (albitites and chloritites), formed during the emplacement and alteration of the ultramafic bodies, are mainly Ordovician (~478 Ma) and lack Devonian zircons, resembling a typical detrital zircon pattern from other locations in the Western Series. Zircons from the chloritite reaction zone of the Lavanderos serpentinite, the easternmost ultramafic body in La Cabaña, are in textural equilibrium with metamorphic ilmenite. Some of these zircons yield an average age of 283.4 ± 7 Ma (n = 6) which is identical, within error, to a previously reported K-Ar fuchsite cooling age of 282 ± 6 Ma from the reaction zone. Most zircons extracted from chromitite boulders have euhedral oscillatory-zoned growth patterns with a similar range of ages than those reported for the Western Series (324–1090 Ma; n = 12), except for two zircons with cloudy appearance and high U/Th ratios which yielded an average age of 285.5 ± 7 Ma. The presence of Early Permian zircons (~280–290 Ma) in all studied rocks suggests remobilization of Zr, possibly triggered by metasomatic fluids released during the disequilibrium reaction associated with the tectonic emplacement of the ultramafic rocks into the metasedimentary rock. Simultaneously with the formation of metasomatic zircons, Palaeozoic and Mesoproterozoic zircons from the metasedimentary rocks were mechanically incorporated into the ultramafic rocks, thus providing a record of the timing of crustal emplacement of the ultramafic rocks into the accretionary complex.     

Ordovician high-grade metamorphism of a newly recognised late Neoproterozoic terrane in the northern Harts Range,central Australia

Granulite facies rocks from the northernmost Harts Range Complex (Arunta Inlier, central Australia) have previously been interpreted as recording a single clockwise cycle of presumed Palaeoproterozoic metamorphism (800–875 °C and >9–10 kbar) and subsequent decompression in a kilometre‐scale, E‐W striking zone of noncoaxial, high‐grade (c. 700–735 °C and 5.8–6.4 kbar) deformation. However, new SHRIMP U‐Pb age determinations of zircon, monazite and titanite from partially melted metabasites and metapelites indicate that granulite facies metamorphism occurred not in the Proterozoic, but in the Ordovician (c. 470 Ma). The youngest metamorphic zircon overgrowths from two metabasites (probably meta‐volcaniclastics) yield ²⁰⁶Pb/²³⁸U ages of 478±4 Ma and 471±7 Ma, whereas those from two metapelites yield ages of 463±5 Ma and 461±4 Ma. Monazite from the two metapelites gave ages equal within error to those from metamorphic zircon rims in the same rock (457±5 Ma and 462±5 Ma, respectively). Zircon, and possibly monazite ages are interpreted as dating precipitation of these minerals from crystallizing melt within leucosomes. In contrast, titanite from the two metabasites yield ²⁰⁶Pb/²³⁸U ages that are much younger (411±5 Ma & 417±7 Ma, respectively) than those of coexisting zircon, which might indicate that the terrane cooled slowly following final melt crystallization. One metabasite has a second titanite population with an age of 384±7 Ma, which reflects titanite growth and/or recrystallization during the 400–300 Ma Alice Springs Orogeny. The c. 380 Ma titanite age is indistinguishable from the age of magmatic zircon from a small, late and weakly deformed plug of biotite granite that intruded the granulites at 387±4 Ma. These data suggest that the northern Harts Range has been subject to at least two periods of reworking (475–460 Ma & 400–300 Ma) during the Palaeozoic. Detrital zircon from the metapelites and metabasites, and inherited zircon from the granite, yield similar ranges of Proterozoic ages, with distinct age clusters at c. 1300–1000 and c. 650 Ma. These data imply that the deposition ages of the protoliths to the Harts Range Complex are late Neoproterozoic or early Palaeozoic, not Palaeoproterozoic as previously assumed.     

Igneous and metamorphic geochronologic evolution of granitoids in the central Eastern Segment,southern Sweden

The Eastern Segment abutting the Transscandinavian Igneous Belt (TIB) mostly consists of rocks with overlapping igneous ages. In the Eastern Segment west of Lake Vättern, granitoids of clear TIB affinity exhibit strong deformational fabrics. This article presents U–Pb zircon ages from 21 samples spanning the border zone between these deformed TIB rocks in the east, and more thoroughly reworked rocks in the west. Magmatic ages fall in the range 1710–1660 million years, irrespective of the degree of deformation, confirming the overlapping crystallization ages between deformed TIB rocks and orthogneisses of the Eastern Segment. A common history is further supported by leucocratic rocks of similar ages. Prolonged orogenic (magmatic) activity is suggested by continued growth of zircon at 1.66–1.60 Ga. Six of the weakly gneissic rocks show zircons with cathodoluminescence-dark patches and embayments, possibly partly replacing metamict parts of older magmatic crystals, with ²⁰⁷Pb/²⁰⁶Pb ages dominantly between 1460 and 1400 million years, whereas three of the gneisses have zircon rims with calculated ages of 1440–1430 million years. Leucosome formation took place at 1443 ± 9 and 1437 ± 6 Ma. The minimum age of SE–NW folds was determined by an undeformed 1383 ± 4 million years crosscutting aplitic dike. Sveconorwegian zircon growth was not found in any of the samples from the studied area. To our knowledge, 1.46–1.40 Ga metamorphism affecting the U–Pb zircon system has not previously been reported this far northeast in the Eastern Segment. We suggest that the E–W- to SE–NW-trending deformation fabrics in our field area were produced during the Hallandian–Danopolonian orogeny and escaped later, penetrative Sveconorwegian reworking.     

Zircon response to high-grade metamorphism as revealed by U–Pb and cathodoluminescence studies

Correct interpretation of zircon ages from high-grade metamorphic terrains poses a major challenge because of the differential response of the U–Pb system to metamorphism, and many aspects like pressure–temperature conditions, metamorphic mineral transformations and textural properties of the zircon crystals have to be explored. A large (c. 450?km²) coherent migmatite complex was recently discovered in the Bohemian Massif, Central European Variscides. Rocks from this complex are characterized by granulite- and amphibolite-facies mineral assemblages and, based on compositional and isotopic trends, are identified as the remnants of a magma body derived from mixing between tonalite and supracrustal rocks. Zircon crystals from the migmatites are exclusively large (200–400?μm) and yield ²⁰⁷Pb/²⁰⁶Pb evaporation ages between 342–328?Ma and single-grain zircon fractions analysed by U–Pb ID-TIMS method plot along the concordia curve between 342 and 325?Ma. High-resolution U–Pb SHRIMP analyses substantiate the existence of a resolvable age variability and yield older ²⁰⁶Pb/²³⁸U ages (342–330?Ma, weighted mean age?=?333.6?±?3.1?Ma) for inner zone domains without relict cores and younger ²⁰⁶Pb/²³⁸U ages (333–320?Ma, weighted mean age?=?326.0?±?2.8?Ma) for rim domains. Pre-metamorphic cores were identified only in one sample (²⁰⁶Pb/²³⁸U ages at 375.0?±?3.9, 420.3?±?4.4 and 426.2?±?4.4?Ma). Most zircon ages bracket the time span between granulite-facies metamorphism in the Bohemian Massif (~345?Ma) and the late-Variscan anatectic overprint (Bavarian phase, ~325?Ma). It is argued that pre-existing zircon was variously affected by these metamorphic events and that primary magmatic growth zones were replaced by secondary textures as a result of diffusion reaction processes and replacement of zircon by dissolution and recrystallization followed by new zircon rim growth. Collectively, the results show that the zircons equilibrated during high-grade metamorphism and record partial loss of radiogenic Pb during post-peak granulite events and new growth under subsequent anatectic conditions.     

Emplacement age and thermal footprint of the diamondiferous Ellendale E9 lamproite pipe, Western Australia

The diamondiferous Ellendale 9 (E9) pipe is a funnel-shaped maar-diatreme volcano consisting of inward-dipping tuff sequences intruded by lamproite plugs and dykes. The host rocks for the E9 pipe are Permian sandstones. The multiple lithological contacts exposed within the mined maar volcano provide a natural laboratory in which to study the effect of volcanic processes on U–Th–Pb–He systematics. Zircon from the regional sandstone and E9 lamproite display a bimodal distribution of ages on (U–Th)/He–U/Pb plots. The zircon U/Pb ages for the E9 pipe (n?=?52) range from 440 to 2,725 Ma, while the cluster of (U–Th)/He ages for the lamproite dyke zircon indicate that dyke emplacement occurred at 20.6?±?2.8 Ma, concordant with a maximum emplacement age of about ≤22 Ma from phlogopite ⁴⁰Ar/³⁹Ar. These ages indicate a xenocrystic origin for the zircon entrained in the E9 dyke. The U/Pb ages of detrital zircon from the regional sandstone host (373–3,248 Ma; n?=?41) are indistinguishable from those of the lamproite zircon xenocrysts, whereas the detrital zircon in the host sandstone yield (U–Th)/He ages from 260 to 1,500 Ma. A thermochronology traverse across the E9 lamproite dyke reveals that the zircon (U–Th)/He ages in the host sandstone have not been significantly thermally reset during dyke emplacement, even at the contact. The capability of the zircon (U–Th)/He method to distinguish deep, mantle source lithologies from upper crustal source lithologies could be used in geochemical exploration for diamonds. Pre-screening of detrital samples using etching and helium assay methods will improve the efficiency and decrease the cost of greenfields exploration.     

Origin of the Yinshan epithermal-porphyry Cu–Au–Pb–Zn–Ag deposit,southeastern China: insights from geochemistry,Sr–Nd and zircon U–Pb–Hf–O isotopes

The Yinshan deposit is a large epithermal-porphyry polymetallic deposit, and the timing and petrogenesis of ore-hosting porphyries have been hotly debated. We present new results from geochemical, whole-rock Sr–Nd and zircon U–Pb–Hf–O isotopic investigations. Zircon U–Pb data demonstrate that the quartz porphyry, dacitic porphyry, and quartz dioritic porphyry formed at ?172.2 ± 0.4 Ma, ?171.7 ± 0.5 Ma, and ?170.9 ± 0.3 Ma, respectively. Inherited zircon cores show significant age spreads from ?730 to ?1390 Ma. Geochemically, they are high-K calc-alkaline or shoshonitic rocks with arc-like trace element patterns. They have similar whole-rock Nd and zircon Hf isotopic compositions, yet an increasing trend in ?_Nd(t) and ?_Hf(t) values typifies the suite. Older (inherited) zircons of the three porphyries display Hf compositions comparable to those of the Jiangnan Orogen basement rocks. In situ zircon oxygen isotopic analyses reveal that they have similar oxygen isotopic compositions, which are close to those of mantle zircons. Moreover, a decreasing trend of δ¹⁸O values is present. We propose that the ore-related porphyries of the Yinshan deposit were emplaced contemporaneously and derived from partial melting of Neoproterozoic arc-derived mafic (or ultra-mafic) rocks. Modelling suggests that the quartz porphyries, dacitic porphyries, and quartz dioritic porphyries experienced ?25%, ?10%, and ?10% crustal contaminations by Shuangqiaoshan rocks. Our study provides important constraints on mantle–crust interaction in the genesis of polymetallic mineralization associated with Mesozoic magmatism in southeastern China.     

Age,petrologic significance and provenance analysis of the Hamedan low-pressure migmatites; Sanandaj-Sirjan Zone,west Iran

ABSTRACT

Meta-pelitic rocks with interlayers of meta-psammites within the inner thermal aureole of the Alvand plutonic complex (Sanandaj-Sirjan Zone (SaSZ), western Iran) underwent partial melting; generating various types of migmatites. The mesosome of the Hamedan migmatites is classified into two groups: (1) cordierite-rich and Al-silicate-poor mesosomes and (2) cordierite-poor, Al-silicate-rich groups. Leucosomes are also variable, ranging from plagioclase-rich to K-feldspar-rich leucosomes. Mineral-chemical studies and thermobarometric estimations indicate temperature and pressure of 640–700°C and 3–5 kbar, respectively, for the formation of mesosomes. U–Pb zircon geochronology on 214 grains from the mesosome of migmatites indicates ages of 160–180 Ma (ca ~170 Ma) for zircon metamorphic rims and variable ages of 190–2590 Ma for the inherited detrital zircon cores. Inherited core ages show various age populations, but age populations at 200–600 Ma are more frequent. The age populations of the detrital zircons clarify that the provenance of the younger zircon grains (200–500 Ma) was more likely the Iranian plate, whereas the older grains (600 Ma to >2.5 Ga) may be sourced from both northern Gondwana (such as Arabian-Nubian Shield) and the neighbouring, old cratons like as Africa. We suggest that magmatic activities, especially mafic plutonism at ~167 Ma, are the main triggers for the heat source of metamorphism, partial melting, and migmatization. In contrast to a presumed idea for a Cretaceous regional metamorphic event in the NW parts of the SaSZ, this study attests that the metamorphism should be older and can be associated with Jurassic magmatic pulses.     

Timing of late Neoarchean to late Paleoproterozoic events in the North China Craton: SHRIMP U–Pb dating and LA-ICP-MS Hf isotope analysis of zircons from magmatic and metamorphic rocks in the Santunying area,eastern Hebei

Santunying is an important area for revealing nature of the late Neoarchean tectono-magmato-thermal events in the eastern Hebei part of the North China Craton. It is mainly composed of meta-intrusive rocks. Supracrustal rocks sporadically occur in the meta-intrusive rocks. The meta-intrusive rocks are subdivided into the Santunying tonalitic gneiss, Qiuhuayu tonalitic-trondhjemitic gneiss, Xiaoguanzhuang dioritic gneiss and Qingyangshu meta-gabbro. Respectively, SHRIMP U–Pb zircon dating on fourteen samples yielded weighted mean ²⁰⁷Pb/²⁰⁶Pb ages of 2525–2537, 2532–2546, 2530–2544 and ∼2531 Ma for magmatic zircons from them. Dioritic gneiss of the Xiaoguanzhuang gneiss contain abundant 2544–3487 Ma xenocrystic zircons. SHRIMP U–Pb dating on a garnet-biotite gneiss sample yielded a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2537 Ma for detrital zircons. All rocks underwent strong metamorphism, deformation and anatexis, resulting in formation of leucosomes and residues, with some leucosomes concentrating to form large veins. They record a strong late Neoarchean event by metamorphic zircon ages of 2489–2519 Ma. Some rocks also record metamorphic zircon ages of 1772–1843 Ma. Magmatic zircons from the magmatic rocks show large variations in ε_Hf(t) values ranging from −1.7 to +8.7. Combined with early studies, conclusions are: 1) Intrusive rocks with the involvement of mantle-derived materials have a narrow range of magmatic zircon ages from 2525 to 2546 Ma, and supracrustal rocks were formed during the same period. 2) Ancient crustal remnants (>2600 Ma) are present, consistent with the late Neoarchean arc magmatism involving older continental crust, similar to Phanerozoic Andean margins. 3) The Archean basement underwent a strong tectonothermal event at the end of the Neoarchean, with the metamorphic zircon ages being 10–30 million years younger than the timing of magmatism, a common feature of the North China Craton. 4) A late Paleoproterozoic tectonothermal event widely occurred in the western part of eastern Hebei, which is linked with regional ductile deformation.     

Late Mesozoic high-K calc-alkaline magmatism in Southeast China: the Tongling example

ABSTRACT

We report new zircon U–Pb ages, Hf isotopic and geochemical results for the Tongling granitic plutons of Southeast China. SHRIMP U–Pb ages for the Miaojia quartz monzodiorite porphyrite,the Tianebaodan and Tongguanshan quartz monzodiorites, the Xinqiaotou granodiorite porphyry, and the Shatanjiao and Nanhongchong granodiorite are 143 ± 2, 141 ± 1 and 142 ± 1, 147 ± 1, and 145 ± 1 and 139 ± 1 Ma, respectively. Combined with previous geochronological data, our results indicate that the porphyritic rocks are older than rocks of the same type lacking porphyritic texture. Geochemically, these high-K calc-alkaline intrusive rocks are characterized by arc-like trace element distribution patterns, with significant enrichment in LILE and LREE but depletion in HFSE. Lu–Hf isotopic compositions of zircons from the high-K calc-alkaline (HKCA) rocks have ε_Hf(t) values of magmatic 139–147 Ma zircons from ?8.1 to ?25.6, with two-stage model ages (t_DM2) of 1.71–2.67 Ga, whereas ε_Hf(t) values of inherited 582–844 Ma zircons range from 5.4 to ?9.5, with t_DM2 of 1.39–2.22 Ma, younger than t_DM2 values of igneous zircon, indicating that newly formed mantle material was added to the continental crust of the Yangtze Block. Moreover, ε_Hf(t) values of inherited zircon cores older than 1000 Ma are from ?7.8 to ?26, similar to magmatic zircons, and the t_DM2 values are all greater than 3.0 Ga (3.16–3.75 Ga), reflecting partial melting of ancient sialic material. We conclude that the plutonic melts were derived from both the enriched mantle and the ancient crust. The HKCA Tongling intrusions coincide temporally with the J₃–K₁ magmatic event that was widespread in Southeast China. This igneous activity may have accompanied sinistral slip along the Tan-Lu fault due to oblique subduction of the Palaeo-Pacific plate.