Improved understanding of spring and stream water responses in headwaters of the Indian Lesser Himalaya using stable isotopes,conductivity and temperature as tracers

Stable isotope data are presented for precipitation, spring and stream water in a headwater catchments in the Indian Lesser Himalaya. Isotopic contents of phreatic groundwater followed the local meteoric water line and showed minimal alteration by evaporation, suggesting fast recharge. Mean isotopic values for springs and the stream were close to the weighted annual mean for precipitation, indicating recharge was in synchrony with seasonal rainfall distribution. Precipitation exhibited isotopic declines of ?0.6‰ and ?0.2‰ δ¹⁸O per 100 m rise in elevation in July and August (monsoon), respectively. The time lag of one month between rainfall and spring discharge, combined with the isotopic lapse rate indicated a recharge elevation of 70–165 m above the spring outflow point, implying the water originated within the catchment. Time series of electrical conductivity and temperature of spring, seepage and stream waters confirmed the rapid recharge and limited storage capacity of the shallow aquifers.     

Trends in the chemistry of precipitation and surface water in a national network of small watersheds

Trends in precipitation and surface water chemistry at a network of 15 small watersheds (< 10 km²) in the USA were evaluated using a statistical test for monotonic trends (the seasonal Kendall test) and a graphical smoothing technique for the visual identification of trends. Composite precipitation samples were collected weekly and surface water samples were collected at least monthly. Concentrations were adjusted before trend analysis, by volume for precipitation samples and by flow for surface water samples. A relation between precipitation and surface water trends was not evident either for individual inorganic solutes or for solute combinations, such as ionic strength, at most sites. The only exception was chloride, for which there was a similar trend at 60% of the sites. The smoothing technique indicated that short-term patterns in precipitation chemistry were not reflected in surface waters. The magnitude of the short-term variations in surface water concentration was generally larger than the overall long-term trend, possibly because flow adjustment did not adequately correct for climatic variability. Detecting the relation between precipitation and surface water chemistry trends may be improved by using a more powerful sampling strategy and by developing better methods of concentration adjustment to remove the effects of natural variation in surface waters.     

Influence of sea salt on stream water chemistry in an upland afforested catchment

The chemistry of bulk precipitation and stream water was monitored in an acidic afforested catchment at Llyn Brianne in upland Wales between 1985 and 1990. Throughfall, stemflow and soil water chemistry were also monitored between 1988 and 1989. Marine-derived solutes dominated the ionic composition of precipitation and stream water, which had mean Cl concentrations of 113 μequiv. 1^?1 and 245 μequiv. 1^?1, respectively. The higher concentrations in stream water reflect occult and dry deposition on the forest canopy and the effect of interception and transpiration losses. Chloride variations in stream water (112-454μequiv. 1^?1) were damped compared with bulk precipitation (28-762μequiv. 1^?1) due to the mixing of event (‘new’) water with pre-event (‘old’) water in the catchment soils. A storm episode monitored in the catchment in April 1989 was associated with high sea salt inputs and Cl concentrations in throughfall (1466μequiv. 1^?1) and storm runoff were exceptionally high (392μequiv. 1^?1). The Cl signal in stream water during the episode was consistent with an event (‘new’) water contribution to the storm response. However, a short-term hydrochemical budget estimated that although Cl outputs from the catchment during the event (1.17 kg ha^?1) were equivalent to 8% of inputs in throughfall and stemflow, the storm runoff was equivalent to 32% of effective precipitation. This indicates that pre-event (‘old’) water was the dominant source (> 75%) of storm runoff. Although sea salt inputs during the event had a marked impact on stream water chemistry, the anomalously high levels of acidity sometimes associated with sea salt events were not observed in this particular study.     

Orogen‐scale drainage network evolution and response to erodibility changes: insights from numerical experiments

The continuous feedbacks among tectonics, surface processes, and climate are reflected in the distribution of catchments on active mountain ranges. Previous studies have shown a regularity of valley spacing across mountain ranges worldwide, but the origin of this geomorphological feature is currently not well known. In this work, we use a landscape evolution model to investigate the process of fluvial network organization and the evolution of regular ridge‐and‐valley patterns on simulated mountain ranges. In particular, we investigate the behavior of such patterns when subjected to a perturbation in landscape processes from a previous steady state, resulting from a sudden variation in the pattern of bedrock erodibility, from homogeneous to a gradient. We analyze the time evolution of the mean ratio λ' between the linear spacing of adjacent valleys and the half width of the mountain range. We show how a valley spacing ratio of ~0.5 is first achieved at steady state under uniform bedrock erodibility. After applying the gradient of bedrock erodibility across the landscape, we observe that λ' first increases and then decreases to a new steady‐state value that is smaller than the original value. A detailed analysis of the simulations, through observations of surface ‘snapshots’ at repeated time intervals, allows to gain some insight into the mechanisms governing this fluvial network reorganization process, driven by the migration of the main divide toward the side characterized by lower bedrock erodibility. On both sides of the range the new steady‐state valley spacing is obtained through mechanisms of catchment reorganization and competition between adjacent fluvial networks. In particular, catchment reorganization is characterized by the growth of smaller catchments between shrinking larger catchments on the side with lower erodibility, and the growth of larger catchments on the side with higher erodibility. Copyright © 2014 John Wiley & Sons, Ltd.     

Spatial scale effect on the upper soil effective parameters of a distributed hydrological model

Nonlinear dynamics and spatial variability in hydrological systems make the formulation of scaling theories difficult. Therefore, the development of knowledge related to scale effects, scaling techniques, parameterization and linkages of parameters across scales is highly relevant. The main purpose of this work is to analyse the spatial effect of the static storage capacity parameter H_u and the saturated hydraulic conductivity parameter k_s from microscale (sub‐grid level) to mesoscale (grid level) and its implication to the definition of an optimum cell size. These two parameters describe the upper soil water characteristics in the infiltration process conceptualization of the TETIS hydrological model. At microscale, the spatial heterogeneity of H_u and k_s was obtained generating random parameter fields through probability distribution functions and a spatial dependence model with pre‐established correlation lengths. The effective parameters at mesoscale were calculated by solving the inverse problem for each parameter field. Results indicate that the adopted inverse formulation allows transferring the nonlinearity of the system from microscale to the mesoscale via non‐stationary effective parameters. Their values at each cell and time step are in the range of zero to the mean value of the parameter at microscale. The stochastic simulations showed that the variance of the estimated effective parameters decreases when the ratio between mesoscale cell size and correlation length at microscale increases. For a ratio greater than 1, we found cell sizes having the characteristics of a representative elementary area (REA); in such case, the microscale variability pattern did not affect the system response at mesoscale. Copyright © 2011 John Wiley & Sons, Ltd.     

1974-2016年青海湖水面面积变化遥感监测

位于青藏高原东北部的青海湖是我国最大的咸水湖和内陆湖,也是青藏高原东北部的重要水汽源,青海湖面积的动态变化是气候和周围生态环境状况的重要体现.本研究利用长时间序列中分辨率遥感影像数据,通过人工提取湖岸水涯线信息对青海湖水面面积进行监测.结果显示：1974-2016年期间,青海湖面积总体上呈先减后增的变化趋势.2004年水面积最小,为4223.73 km²,比1974年减少253.80 km².其中1974-1987年期间面积骤减;2000 2009年期间青海湖水面面积变化幅度相对较小,平均变化幅度为6.85 km².2009-2016年7 a间,水面面积增加了128.27 km².2012年青海湖面积骤增,比2011年8月同期增加65.12 km²;同年6月和9月的面积变化为2002-2016年最大,达到59.18 km².湖东岸沙岛的湖岸线变化最为显著,1974-2004年岸线后退最大距离达4.59 km,2012年的年内最大变化距离为0.39 km.青海湖流域内降水补给增加,生态环境治理措施促使入湖河流径流量增大,是近年来湖水面积增加的主要原因.     

Contributing sources to baseflow in pre‐alpine headwaters using spatial snapshot sampling

Mountainous headwaters consist of different landscape units including forests, meadows and wetlands. In these headwaters it is unclear which landscape units contribute what percentage to baseflow. In this study, we analysed spatiotemporal differences in baseflow isotope and hydrochemistry to identify catchment‐scale runoff contribution. Three baseflow snapshot sampling campaigns were performed in the Swiss pre‐alpine headwater catchment of the Zwäckentobel (4.25 km²) and six of its adjacent subcatchments. The spatial and temporal variability of δ²H, Ca, DOC, AT, pH, SO₄, Mg and H₄SiO₄ of streamflow, groundwater and spring water samples was analysed and related to catchment area and wetland percentage using bivariate and multivariate methods. Our study found that in the six subcatchments, with variable arrangements of landscape units, the inter‐ and intra catchment variability of isotopic and hydrochemical compositions was small and generally not significant. Stream samples were distinctly different from shallow groundwater. An upper spring zone located near the water divide above 1,400 m and a larger wetland were identified by their distinct spatial isotopic and hydrochemical composition. The upstream wetland percentage was not correlated to the hydrochemical streamflow composition, suggesting that wetlands were less connected and act as passive features with a negligible contribution to baseflow runoff. The isotopic and hydrochemical composition of baseflow changed slightly from the upper spring zone towards the subcatchment outlets and corresponded to the signature of deep groundwater. Our results confirm the need and benefits of spatially distributed snapshot sampling to derive process understanding of heterogeneous headwaters during baseflow. Copyright © 2015 John Wiley & Sons, Ltd.     

Spatial and temporal variations of actual soil water repellency and their influence on surface runoff

The increase of surface runoff at the plot scale caused by soil water repellency is a generally accepted phenomenon. However, to improve the understanding of the effect of water repellency on runoff at the catchment scale, spatio‐temporal dynamics of water repellency have to be analysed in more detail. The experimental setup of this study allowed the investigation of the relationship between water repellency and runoff generation on Quaternary and Tertiary sandy substrates while ensuring similar conditions in terms of terrain characteristics, meteorological and vegetation‐free conditions on both areas. Measurements of water drop penetration time and contact angle were carried out over a period from September 2003 to December 2005. Spatial variability of actual soil water repellency was related to heterogeneity of substrate and geomorphologic units, variations in time were related with the seasons and their meteorological conditions. To relate variable degrees of actual water repellency to surface runoff generation, both variables were measured in parallel at the plot scale (1 m × 1 m) and at the hillslope scale from September 2004 to December 2005. Soil water repellency of the Tertiary sands showed a temporal variability depending on the season, with the highest degree during summer and autumn. Variation of hydrophobicity between the seasons caused higher runoff coefficients in summer and autumn. Spatial heterogeneity of the soil water repellency revealed lower values in fine‐textured erosion rills and higher values for interrills and top areas. The measured runoff coefficients decreased from the scale of microplots to the hillslope scale due to infiltration in hydrophilic rills on the hillslope. The results suggest that improved hydrological modelling approaches on water‐repellent soils can be based on a geomorphological subdivision of the catchment area and seasonally varying infiltration parameters. Copyright © 2007 John Wiley & Sons, Ltd.     

Response of surface water chemistry to reduced levels of acid precipitation: comparison of trends in two regions of New York,USA

In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984–2001 and 1992–2001) and surface water chemistry (1992–2001) were determined in two of the most acid‐sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO₄^2?), nitrate (NO₃^?), and base cation (C_B) concentrations and increasing pH during 1984–2001, but few significant trends during 1992–2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO₄^2? concentrations at all sites, and decreasing trends in NO₃^?, C_B, and H⁺ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid‐neutralizing capacity (ANC) increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO₄^2? trends, but it caused several significant non‐flow‐corrected trends in NO₃^? and ANC to become non‐significant, suggesting that trend results for flow‐sensitive constituents are affected by flow‐related climate variation. SO₄^2? concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation–surface water comparisons, reflecting a strong link between S emissions, precipitation SO₄^2? concentrations, and the processes that affect S cycling within these regions. NO₃^? and H⁺ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation–surface water comparisons, indicating that variation in local‐scale processes driven by factors such as climate are affecting trends in acid–base chemistry in these two regions. Copyright © 2005 John Wiley & Sons, Ltd.     

Coupling two radar backscattering models to assess soil roughness and surface water content at farm scale

Abstract

Remote sensing techniques are useful for agro-hydrological monitoring at the farm scale because the availability of spatially and temporally distributed data improves agricultural models for irrigation and crop yield optimization under water scarcity conditions. This research focuses on the surface water content retrieval using active microwave data. Two semi-empirical models were chosen as these showed the best performances in simulating cross and co-polarized backscatter. Thus, these models were coupled to obtain reliable assessments of both soil water content and soil roughness. The use of the coupled model enables one to avoid using roughness measured in situ. Remote sensing images and in situ data were collected between April and July 2006 within the European Space Agency-funded project AgriSAR 2006. The images data set includes L-band in HH, VV and VH polarizations acquired from the airborne E-SAR sensor, operated by the German Aerospace Centre. Results were validated using in situ soil water content and roughness measurements. The results show that reliable assessment of both soil roughness (r ² up to ?0.8) and soil water content (r ² ? 0.9) can be retrieved in fields characterized by low fractional coverage.

Editor D. Koutsoyiannis; Associate editor C. Onof

Citation Capodici, F., Maltese, A., Ciraolo, G., La Loggia, G., and D’Urso, G., 2013. Coupling two radar backscattering models to assess soil roughness and surface water content at the farm scale. Hydrological Sciences Journal, 58 (8), 1677–1689.     

Spatial scale impact on daily surface water and sediment fluxes in Thukela river,South Africa

The on- and off-site effects of soil erosion in many environments are well known, but there is still limited understanding of the soil loss fluxes in downstream direction due, among other factors, to scarce and poor quality. A four year study to (i) evaluate water and sediment fluxes at different spatio-temporal scales and (ii) interpret the results in terms of processes involved and the controlling factors, was conducted in Thukela basin, South Africa. Five hierarchically nested catchments; namely microcatchment (0.23 km²), subcatchment (1.20 km²), catchment (9.75 km²), sub-basin (253 km²) and basin (29,038 km²), were used in addition to fifteen (1 m²) microplots and ten (10 m²) plots on five locations within the microcatchment. The results showed 19% decrease of unit-area runoff (q) from 3.1 L m⁻² day⁻¹ at microplot to 2.5 L m⁻² day⁻¹ at plot scale followed by steeper (56%) decrease at microcatchment scale. The q decreased in downstream direction to very low level (q ≤ 0.26 L m⁻² day⁻¹). The changes in q were accompanied by initial 1% increase of soil loss (SL) from 18.8 g m⁻² day⁻¹ at microplot to 19.1 g m⁻² day⁻¹ at plot scale. The SL also decreased sharply (by 39 fold) to 0.50 g m⁻² day⁻¹ at microcatchment scale, followed by further decrease in downstream direction. The decrease of q with spatial scale was attributed to infiltration losses, while initial increase of SL signified greater competence of sheet than splash erosion. The decrease of SL beyond the plot scale was attributed to redistribution of the soil on the hillslope and deposition on the stream channel upstream of the microcatchment outlet. Therefore, erosion control strategies focussing on the recovery of vegetation on the slope and stabilisation of gullies are recommended.     

Preliminary analysis of spatiotemporal pattern of global land surface water

Land surface water (LSW) is one of the most important resources for human survival and development, and it is also a main component of global water recycling. A full understanding of the spatial distribution of land surface water and a continuous measuring of its dynamics can support to diagnose the global ecosystem and environment. Based on the Global Land 30-water 2000 and Global Land 30-water 2010 products, this research analyzed the spatial distribution pattern and temporal fluctuation of land surface water under scale-levels of global, latitude and longitude, continents, and climate zones. The Global Land 30-water products were corrected the temporal inconsistency of original remotely sensed data using MODIS time-series data, and then calculated the indices such as water area, water ration and coefficient of spatial variation for further analysis. Results show that total water area of land surface is about 3.68 million km² (2010), and occupies 2.73% of land area. The spatial distribution of land surface water is extremely uneven and is gathered mainly in mid- to high-latitude area of the Northern Hemisphere and tropic area. The comparison of water ratio between 2000 and 2010 indicates the overall fluctuation is small but spatially differentiated. The Global Land 30-water products and the statistics provided the fundamental information for analyzing the spatial distribution pattern and temporal fluctuation of land surface water and diagnosing the global ecosystem and environment.     

Combination of CFCs and stable isotopes to characterize the mechanism of groundwater–surface water interactions in a headwater basin of the North China Plain

Mountainous areas are characterized by steep slopes and rocky landforms, with hydrological conditions varying rapidly from upstream to downstream, creating variable interactions between groundwater and surface water. In this study, mechanisms of groundwater–surface water interactions within a headwater catchment of the North China Plain were assessed along the stream length and during different seasons, using hydrochemical and stable isotope data, and groundwater residence times estimated using chlorofluorocarbons. These tracers indicate that the river is gaining, due to groundwater discharge in the headwater catchment both in the dry and rainy seasons. Residence time estimation of groundwater using chlorofluorocarbons data reveals that groundwater flow in the shallow sedimentary aquifer is dominated by the binary mixing of water approximating a piston flow model along 2 flow paths: old water, carried by a regional flow system along the direction of river flow, along with young water, which enters the river through local flow systems from hilly areas adjacent to the river valley (particularly during the rainy season). The larger mixing ratio of young water from lateral groundwater recharge and return flow of irrigation during the rainy season result in higher ion concentrations in groundwater than in the dry season. The binary mixing model showed that the ratio of young water versus total groundwater ranged from 0.88 to 0.22 and 1.0 to 0.74 in the upper and lower reaches, respectively. In the middle reach, meandering stream morphology allows some loss of river water back into the aquifer, leading to increasing estimates of the ratio of young water (from 0.22 to 1). This is also explained by declining groundwater levels near the river, due to groundwater extraction for agricultural irrigation. The switch from a greater predominance of regional flow in the dry season, to more localized groundwater flow paths in the wet season is an important groundwater–surface water interactions mechanism, with important catchment management implications.     

The role of land surface versus drainage network characteristics in controlling water quality and quantity in a small urban watershed

The processes that control run‐off quantity and quality in urban watersheds are complex and not well understood. Although impervious surface coverage has traditionally been used to examine altered hydrologic response in urban watersheds, several studies suggest that other elements of the urban landscape, particularly those associated with urban infrastructure and the drainage system, play an equally important role. The relative importance of impervious surfaces, stormwater ponds, expansion of the drainage network, and drainage network structures in controlling hydrologic response was examined in the subwatersheds of the Kromma Kill, an urban watershed located in Albany County, NY. In this study, geographic information systems was used to compute geospatial land surface and drainage network properties of 5 Kromma Kill subwatersheds. In these same subwatersheds, water quantity (rainfall and run‐off) and quality (macroinvertebrates, nitrate, total nitrogen, dissolved oxygen, total dissolved solids, and nonpurgable organic carbon) parameters were measured. Strong and significant correlations were identified between land surface and drainage network properties and field observations. Causal relationships were then tested using the Environmental Protection Agency's Stormwater Management Model. Field and model analyses suggest that whereas percent imperviousness is a dominant control on water quality, drainage density and slope are equally important. However, for water quantity, whereas imperviousness is positively correlated with increased run‐off volumes, drainage network properties and slope are the dominant controls on run‐off volumes. Results have important implications for stormwater management plans, especially those aimed at reducing the effective impervious surface coverage of urban watersheds. Reducing the percentage of effective imperviousness in a watershed is not a “one size fits all” solution and can help to meet some management objectives, such as reducing nitrogen concentrations and improving water quality, but may not serve as the most effective, and therefore economical, solution for every management objective including reducing run‐off volumes.     

Application of inverse geochemical modelling for predicting surface water chemistry in Ekbatan watershed,Hamedan, western Iran

ABSTRACT

A study of surface water chemistry evolution was conducted by multivariate statistical analysis and inverse geochemical modelling using the PHREEQC computer program. Using hierarchical cluster analysis the 14 sampling sites were classified into three groups (recharge, transition and discharge areas). Water chemistry changed along a flow path so that waters with Ca–HCO₃ and Mg–Cl composition changed to Mg–Cl–HCO₃ waters. The order of abundance of the major cations was Mg > Ca > Na > K. Their average concentrations were 21, 19, 3.6 and 2.5 mg L^-1, respectively. Inverse geochemical modelling along flow paths indicated that the dissolution of sylvite and kaolinite, and precipitation of feldspars and andalusite, happened with Na entering the solution and Ca, Mg and K leaving the solution.

Editor D. Koutsoyiannis; Associate editor not assigned     

喀斯特地区梯级水库建造对水化学分布的影响

为深入了解河流梯级筑坝对喀斯特地区河流水化学分布的影响,于2017年1、4、7和10月别对乌江干流洪家渡水库(多年调节)、乌江渡水库(季调节)和索风营水库(日调节) 3个具有不同滞留时间的水库进行水样采集,分析入库水、坝前剖面水和下泄水的水化学特征,探讨河流梯级筑坝对水化学分布及风化速率估算的影响.研究结果表明:3个水库深层水比表层水HCO3-浓度分别高12.9%、5.5%和8.0%,Ca²⁺浓度分别高15.9%、2.4%和8.5%.河流梯级筑坝一定程度上改变了水体水化学组成,从而影响碳酸盐岩风化速率估算.整体上,洪家渡水库、索风营水库和乌江渡水库的全年风化速率变化范围分别为:-1.7%～15.4%、-5.6%～1.1%和-0.3%～3.4%.河流筑坝作用对风化速率估算及主量离子浓度的影响:HCO₃^-与Ca²⁺浓度分布均为:洪家水库>乌江渡水库>索风营水库,这与水体滞留时间长短规律一致,表明水体滞留时间影响着水化学的组成分布.同时水体离子浓度表现出明显的季节性差异,丰水期各水库变化率明显...     

Nutrient dynamics in an alpine headwater stream: use of continuous water quality sensors to examine responses to wildfire and precipitation events

Stream water quality can change substantively during diurnal cycles, discrete flow events, and seasonal time scales. In this study, we assessed event responses in surface water nutrient concentrations and biogeochemical parameters through the deployment of continuous water quality sensors from March to October 2011 in the East Fork Jemez River, located in northern New Mexico, USA. Events included two pre‐fire non‐monsoonal precipitation events in April, four post‐fire precipitation events in August and September (associated with monsoonal thunderstorms), and two post‐fire non‐monsoonal precipitation events in October. The six post‐fire events occurred after the Las Conchas wildfire burned a significant portion of the contributing watershed (36%) beginning in June 2011. Surface water nitrate (NO₃? N) concentrations increased by an average of 50% after pre‐fire and post‐fire non‐monsoonal precipitation events and were associated with small increases in turbidity (up to 15 NTU). Beginning 1 month after the start of the large regional wildfire, monsoonal precipitation events resulted in large multi‐day increases in dissolved NO₃? N (6 × background levels), dissolved phosphate (100 × background levels), specific conductance (5 × background levels), and turbidity (>100 × background levels). These periods also corresponded with substantial sags in dissolved oxygen (<4 mg l^?1) and pH (<6.5). The short duration and rapid rates of change during many of these flow events, particularly following wildfire, highlight the importance of continuous water quality monitoring to quantify the timing and magnitude of event responses in streams and to examine large water quality excursions linked to catchment disturbance. Copyright © 2015 John Wiley & Sons, Ltd.     

The controls on boreal peatland surface water chemistry in Northern Alberta,Canada

Spatial and temporal variability in surface water chemistry, organic soil chemistry and hydrologic indicators were investigated at three poor‐fen complexes in two boreal catchments in Northern Alberta to provide insight into the dominant controls on surface water chemistry. Improved understanding of these controls is required to enable prediction of runoff chemistry in the region under changing atmospheric deposition conditions. Surface water chemistry exhibited considerable variability; within each fen conductivity, dissolved organic carbon (DOC), and Cl⁻ tended to decrease and pH tended to increase with increasing distance from the lake edge. Variations in evaporative isotopic enrichment in ²H and ¹⁸O, expressed as deuterium excess, were used to distinguish between throughflow waters and those that were more evaporatively enriched. Throughflow surface waters were more acidic primarily due to higher concentrations of DOC and NO₃⁻. Exchangeable base saturation and pH of organic soils were strongly related to surface water chemistry at two of the fen complexes, demonstrating the capacity for cation exchange to influence surface water chemistry. Fen surface water concentrations of most elements and DOC increased during the summer period (between June and August), while pH of water decreased. Evaporative concentration of the surface waters was a dominant driver, with surface water temperature increasing at both catchments. Localized groundwater discharge was an important contributor of base cations to the fens, while the organic soils are sinks for atmospherically deposited SO₄²⁻, N and Cl⁻. Copyright © 2010 John Wiley & Sons, Ltd.     

三峡工程调节作用对洞庭湖水面面积(2000-2010年)的影响

以洞庭湖为研究对象,以11年(2000-2010年)Terra/MODIS 16 d最大值合成的植被指数数据产品集MOD13Q1和同期城陵矶水文监测站的水位数据为主要数据源,通过对NDVI和NIR分别设定阈值的方法,实现了洞庭湖水面面积的综合提取,分析了三峡工程建设背景下,洞庭湖水面面积的年际变化特征和年内变化规律,再结合城陵矶水位数据,对水位与水面面积之间的定量关系进行了深入分析.研究结果表明:三峡工程的运行,很大程度上控制着洞庭湖的入湖水量,对洞庭湖防汛工作有利;在气候变化、三峡水库的共同影响下,洞庭湖区水面面积整体上呈减少趋势;水面面积与水位的拟合结果显示两者具有良好的相关性,其中2000-2003年两者的确定性系数达到0.975.     

Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.