Dynamic river–groundwater exchange in the presence of a saline,semi‐confined aquifer

Understanding groundwater–surface water exchange in river banks is crucial for effective water management and a range of scientific disciplines. While there has been much research on bank storage, many studies assume idealized aquifer systems. This paper presents a field‐based study of the Tambo Catchment (southeast Australia) where the Tambo River interacts with both an unconfined aquifer containing relatively young and fresh groundwater (<500 μS/cm and <100 years old) and a semi‐confined artesian aquifer containing old and saline groundwater (electrical conductivity > 2500 μS/cm and >10 000 years old). Continuous groundwater elevation and electrical conductivity monitoring within the different aquifers and the river suggest that the degree of mixing between the two aquifers and the river varies significantly in response to changing hydrological conditions. Numerical modelling using MODFLOW and the solute transport package MT3DMS indicates that saline water in the river bank moves away from the river during flooding as hydraulic gradients reverse. This water then returns during flood recession as baseflow hydraulic gradients are re‐established. Modelling also indicates that the concentration of a simulated conservative groundwater solute can increase for up to ~34 days at distances of 20 and 40 m from the river in response to flood events approximately 10 m in height. For the same flood event, simulated solute concentrations within 10 m of the river increase for only ~15 days as the infiltrating low‐salinity river water drives groundwater dilution. Average groundwater fluxes to the river stretch estimated using Darcy's law were 7 m³/m/day compared with 26 and 3 m³/m/day for the same periods via mass balance using Radon (²²²Rn) and chloride (Cl), respectively. The study shows that by coupling numerical modelling with continuous groundwater–surface water monitoring, the transient nature of bank storage can be evaluated, leading to a better understanding of the hydrological system and better interpretation of hydrochemical data. Copyright © 2015 John Wiley & Sons, Ltd.     

Reducing monitoring gaps at the aquifer–river interface by modelling groundwater–surface water exchange flow patterns

This study investigates spatial patterns and temporal dynamics of aquifer–river exchange flow at a reach of the River Leith, UK. Observations of sub‐channel vertical hydraulic gradients at the field site indicate the dominance of groundwater up‐welling into the river and the absence of groundwater recharge from surface water. However, observed hydraulic heads do not provide information on potential surface water infiltration into the top 0–15 cm of the streambed as these depths are not covered by the existing experimental infrastructure. In order to evaluate whether surface water infiltration is likely to occur outside the ‘window of detection’, i.e. the shallow streambed, a numerical groundwater model is used to simulate hydrological exchanges between the aquifer and the river. Transient simulations of the successfully validated model (Nash and Sutcliff efficiency of 0·91) suggest that surface water infiltration is marginal and that the possibility of significant volumes of surface water infiltrating into non‐monitored shallow streambed sediments can be excluded for the simulation period. Furthermore, the simulation results show that with increasing head differences between river and aquifer towards the end of the simulation period, the impact of streambed topography and hydraulic conductivity on spatial patterns of exchange flow rates decreases. A set of peak flow scenarios with altered groundwater‐surface water head gradients is simulated in order to quantify the potential for surface water infiltration during characteristic winter flow conditions following the observation period. The results indicate that, particularly at the beginning of peak flow conditions, head gradients are likely to cause substantial increase in surface water infiltration into the streambed. The study highlights the potential for the improvement of process understanding of hyporheic exchange flow patterns at the stream reach scale by simulating aquifer‐river exchange fluxes with a standard numerical groundwater model and a simple but robust model structure and parameterization. Copyright © 2011 John Wiley & Sons, Ltd.     

Surface water–groundwater exchange dynamics in a tidal freshwater zone

In coastal rivers, tides can propagate for tens to hundreds of kilometres inland beyond the saltwater line. Yet the influence of tides on river–aquifer connectivity and solute transport in tidal freshwater zones (TFZs) is largely unknown. We estimate that along the TFZ of White Clay Creek (Delaware, USA), 11% of river water exchanges through tidal bank storage zones. Additional hyporheic processes such as flow through bedforms likely contribute even more exchange. The turnover length associated with tidal bank storage is 150 km, on the order of turnover lengths for all hyporheic exchange processes in non‐tidal rivers of similar size. Based on measurements at a transect of piezometers located 17 km from the coast, tides exchange 0.36 m³ of water across the banks and 0.86 m³ across the bed per unit river length. Exchange fluxes range from ?1.66 to 2.26 m day^?1 across the bank and ?0.84 to 1.88 m day^?1 across the bed. During rising tide, river water infiltrates into the riparian aquifer, and the downstream transport rate in the channel is low. During falling tide, stored groundwater is released to the river, and the downstream transport rate in the channel increases. Tidal bank storage zones may remove nutrients or other contaminants from river water and attenuate nutrient loads to coasts. Alternating expansion and contraction of aerobic zones in the riparian aquifer likely influence contaminant removal along flow paths. A clear need exists to understand contaminant removal and other ecosystem services in TFZs and adopt best management practices to promote these ecosystem services. Copyright © 2015 John Wiley & Sons, Ltd.     

Heat as a groundwater tracer in shallow and deep heterogeneous media: Analytical solution,spreadsheet tool,and field applications

Groundwater flow advects heat, and thus, the deviation of subsurface temperatures from an expected conduction‐dominated regime can be analysed to estimate vertical water fluxes. A number of analytical approaches have been proposed for using heat as a groundwater tracer, and these have typically assumed a homogeneous medium. However, heterogeneous thermal properties are ubiquitous in subsurface environments, both at the scale of geologic strata and at finer scales in streambeds. Herein, we apply the analytical solution of Shan and Bodvarsson ( 2004 ), developed for estimating vertical water fluxes in layered systems, in 2 new environments distinct from previous vadose zone applications. The utility of the solution for studying groundwater‐surface water exchange is demonstrated using temperature data collected from an upwelling streambed with sediment layers, and a simple sensitivity analysis using these data indicates the solution is relatively robust. Also, a deeper temperature profile recorded in a borehole in South Australia is analysed to estimate deeper water fluxes. The analytical solution is able to match observed thermal gradients, including the change in slope at sediment interfaces. Results indicate that not accounting for layering can yield errors in the magnitude and even direction of the inferred Darcy fluxes. A simple automated spreadsheet tool (Flux‐LM) is presented to allow users to input temperature and layer data and solve the inverse problem to estimate groundwater flux rates from shallow (e.g., <1 m) or deep (e.g., up to 100 m) profiles. The solution is not transient, and thus, it should be cautiously applied where diel signals propagate or in deeper zones where multi‐decadal surface signals have disturbed subsurface thermal regimes.     

Stream and bed temperature variability in a coastal headwater catchment: influences of surface‐subsurface interactions and partial‐retention forest harvesting

Stream temperature was recorded between 2002 and 2005 at four sites in a coastal headwater catchment in British Columbia, Canada. Shallow groundwater temperatures, along with bed temperature profiles at depths of 1 to 30 cm, were recorded at 10‐min intervals in two hydrologically distinct reaches beginning in 2003 or 2004, depending on the site. The lower reach had smaller discharge contributions via lateral inflow from the hillslopes and fewer areas with upwelling (UW) and/or neutral flow across the stream bed compared to the middle reach. Bed temperatures were greater than those of shallow groundwater during summer, with higher temperatures in areas of downwelling (DW) flow compared to areas of neutral and UW flow. A paired‐catchment analysis revealed that partial‐retention forest harvesting in autumn 2004 resulted in higher daily maximum stream and bed temperatures but smaller changes in daily minima. Changes in daily maximum stream temperature, averaged over July and August of the post‐harvest year, ranged from 1.6 to 3 °C at different locations within the cut block. Post‐harvest changes in bed temperature in the lower reach were smaller than the changes in stream temperature, greater at sites with DW flow, and decreased with depth at both UW and DW sites, dropping to about 1 °C at a depth of 30 cm. In the middle reach, changes in daily maximum bed temperature, averaged over July and August, were generally about 1 °C and did not vary significantly with depth. The pre‐harvest regression models for shallow groundwater were not suitable for applying the paired‐catchment analysis to estimate the effects of harvesting. However, shallow groundwater was warmer at the lower reach following harvesting, despite generally cooler weather compared to the pre‐harvest year. Copyright © 2012 John Wiley & Sons, Ltd.     

Scales and magnitude of hyporheic,river–aquifer and bank storage exchange fluxes

Many studies have investigated the exchange processes that occur between rivers and groundwater systems and have successfully quantified the water fluxes involved. Specifically, these exchange processes include hyporheic exchange, river–aquifer exchange (groundwater discharge and river loss) and bank storage exchange. Remarkably, there are relatively few examples of field studies where more than one exchange process is quantified, and as a consequence, the relationships between them are not well understood. To compare the relative magnitudes of these common exchange processes, we have collected data from 54 studies that have quantified one or more of these exchange flux types. Each flux value is plotted against river discharge at the time of measurement to allow the different exchange flux types to be compared. We show that there are positive relationships between the magnitude of each exchange flux type and increasing river discharge across the different studies. For every one order of magnitude increase in river discharge, the hyporheic, river–aquifer and bank storage exchange fluxes increase by factors of 2.7, 2.9 and 2.5, respectively. On average, hyporheic exchange fluxes are almost an order of magnitude greater than river–aquifer exchange fluxes, which are, in turn, approximately four times greater than bank storage exchange fluxes for the same river discharge. Unless measurement approaches that can distinguish between different types of exchange flux are used, there is potential for hyporheic exchange fluxes to be misinterpreted as river–aquifer exchange fluxes, with possible implications for water resource management decisions. Copyright © 2015 John Wiley & Sons, Ltd.     

Coupled groundwater flow and heat transport simulation for estimating transient aquifer–stream exchange at the lowland River Spree (Germany)

Subsurface flow and heat transport near Freienbrink, NE Germany, was simulated in order to study groundwater–surface water exchange between a floodplains aquifer and a section of the lowland River Spree and an adjacent oxbow. Groundwater exfiltration was the dominant process, and only fast surface water level rises resulted in temporary infiltration into the aquifer. The main groundwater flow paths are identified based on a 3D groundwater flow model. To estimate mass fluxes across the aquifer–surface water interfaces, a 2D flow and heat transport modelling approach along a transect of 12 piezometers was performed. Results of steady‐state and transient water level simulations show an overall high accuracy with a Spearman coefficient ρ = 0.9996 and root mean square error (RMSE) = 0.008 m. Based on small groundwater flow velocities of about 10^?7 to 10^?6 ms^?1, mean groundwater exfiltration rates of 233 l m^?2 d^?1 are calculated. Short periods of surface water infiltration into the aquifer do not exceed 10 days, and the infiltration rates are in the same range. The heat transport was modelled with slightly less accuracy (ρ = 0.8359 and RMSE = 0.34 °C). In contrast to the predominant groundwater exfiltration, surface water temperatures determine the calculated temperatures in the upper aquifer below both surface water bodies down to 10 m during the whole simulation period. These findings emphasize prevailing of heat conduction over advection in the upper aquifer zones, which seems to be typical for lowland streams with sandy aquifer materials and low hydraulic gradients. Moreover, this study shows the potential of coupled numerical flow and heat transport modelling to understand groundwater–surface water exchange processes in detail. Copyright © 2013 John Wiley & Sons, Ltd.     

Coupled surface water–groundwater model and its application in the arid Shiyang River basin,China

The planning and management of water resources in the Shiyang River basin, China require a tool for assessing the impact of groundwater and stream use on water supply reliabilities and improving many environment‐related problems such as soil desertification induced by recent water‐related human activities. A coupled model, integrating rule‐based lumped surface water model and distributed three‐dimensional groundwater flow model, has been established to investigate surface water and groundwater management scenarios that may be designed to restore the deteriorated ecological environment of the downstream portion of the Shiyang River basin. More than 66% of the water level among 24 observation wells have simulation error less than 1·0 m. The overall trend of the temporal changes of simulated and observed surface runoff at the Caiqi gauging station remains almost the same. The calibration was considered satisfactory. Initial frameworks for water allocation, including agricultural water‐saving projects, water diversion within the basin and inter‐basin water transfer, reducing agricultural irrigation area and surface water use instead of groundwater exploitation at the downstream were figured out that would provide a rational use of water resources throughout the whole basin. Sixteen scenarios were modelled to find out the most appropriate management strategies. The results showed that in the two selected management options, the groundwater budget at the Minqin basin was about 1·4 × 10⁸ m³/a and the ecological environment would be improved significantly, but the deficit existed at the Wuwei basin and the number was about 0·8 × 10⁸ m³/a. Water demand for domestic, industry and urban green area would be met in the next 30 years, but the water shortage for meeting the demand of agricultural water use in the Shiyang River basin was about 2·2 × 10⁸ m³/a. It is suggested that more inter‐basin water transfer should be required to obtain sustainable water resource use in the Shiyang River basin. Copyright © 2009 John Wiley & Sons, Ltd.     

Field assessment of surface water–groundwater connectivity in a semi‐arid river basin (Murray–Darling,Australia)

In semi‐arid and arid river basins, understanding the connectivity between rivers and alluvial aquifers is one of the key challenges for the management of groundwater resources. The type of connection present (gaining, losing‐connected, transitional and losing‐disconnected) was assessed at 12 sites along six Murray–Darling Basin river reaches. The assessments were made by measuring the hydraulic head in the riparian zone near the rivers to evaluate if the water tables intersected the riverbeds and by measuring fluid pressure (ψ) in the riverbeds. The rationale for the latter was that ψ will always be greater than or equal to zero under connected conditions (either losing or gaining) and always lesser than or equal to zero under losing‐disconnected conditions. A mixture of losing‐disconnected, losing‐connected and gaining conditions was found among the 12 sites. The losing‐disconnected sites all had a riverbed with a lower hydraulic conductivity than the underlying aquifer, usually in the form of a silty clay or clay unit 0.5–2 m in thickness. The riparian water tables were 6 to 25 m below riverbed level at the losing‐disconnected sites but never lower than 1 m below riverbed level at the losing‐connected ones. The contrast in water table depth between connected and disconnected sites was attributed to the conditions at the time of the study, when a severe regional drought had generated a widespread decline in regional water tables. This decline was apparently compensated near losing‐connected rivers by increased infiltration rates, while the decline could not be compensated at the losing‐disconnected rivers because the infiltration rates were already maximal there. Copyright © 2012 John Wiley & Sons, Ltd.     

Heterogeneity in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream

Spatial and temporal variability in ground water–surface water interactions in the hyporheic zone of a salmonid spawning stream was investigated. Four locations in a 150‐m reach of the stream were studied using hydrometric and hydrochemical tracing techniques. A high degree of hydrological connectivity between the riparian hillslope and the stream channel was indicated at two locations, where hydrochemical changes and hydraulic gradients indicated that the hyporheic zone was dominated by upwelling ground water. The chemistry of ground water reflected relatively long residence times and reducing conditions with high levels of alkalinity and conductivity, low dissolved oxygen (DO) and nitrate. At the other locations, connectivity was less evident and, at most times, the hyporheic zone was dominated by downwelling stream water characterized by high DO, low alkalinity and conductivity. Substantial variability in hyporheic chemistry was evident at fine (<10 m) spatial scales and changed rapidly over the course of hydrological events. The nature of the hydrochemical response varied among locations depending on the strength of local ground water influence. It is suggested that greater emphasis on spatial and temporal heterogeneity in ground water–surface water interactions in the hyporheic zone is necessary for a consideration of hydrochemical effects on many aspects of stream ecology. For example, the survival of salmonid eggs in hyporheic gravels varied considerably among the locations studied and was shown to be associated with variation in interstitial chemistry. River restoration schemes and watershed management strategies based only on the surface expression of catchment characteristics risk excluding consideration of potentially critical subsurface processes. Copyright © 2002 John Wiley & Sons, Ltd.     

Groundwater–surface‐water interactions in a braided river: a tracer‐based assessment

Natural tracers (alkalinity and silica) were used to infer groundwater–surface‐water exchanges in the main braided reach of the River Feshie, Cairngorms, Scotland. Stream‐water samples were collected upstream and downstream of the braided section at fortnightly intervals throughout the 2001–2002 hydrological year and subsequently at finer resolution over two rainfall events. The braided reach was found to exert a significant downstream buffering effect on the alkalinity of these waters, particularly at moderate flows (4–8 m³ s^?1/?Q_30–70). Extensive hydrochemical surveys were undertaken to characterize the different source waters feeding the braids. Shallow groundwater flow systems at the edge of the braided floodplain, recharged by effluent streams and hillslope drainage, appeared to be of particular significance. Deeper groundwater was identified closer to the main channel, upwelling through the hyporheic zone. Both sources contributed to the significant groundwater–surface‐water interactions that promote the buffering effect observed through the braided reach. Their impact was less significant at higher flows (>15 m³ s^?1/>Q₁₀) when acidic storm runoff from the peat‐covered catchment headwaters dominated, as well as under baseflow conditions (<4 m³ s^?1/<Q₇₀), when upstream alkalinity was already buffered owing to headwater groundwater sources assuming dominance. The significant temporally and spatially dynamic influence of these groundwater–surface‐water interactions was therefore seen to have important implications for both catchment functioning and instream ecology. Copyright © 2004 John Wiley & Sons, Ltd.     

Paleomagnetism of Jurassic to Miocene sediments from the Apenninic carbonate platform (southern Apennines, Italy): evidence for a 60° counterclockwise Miocene rotation

The tectonic evolution of the Apennine belt/southern Tyrrhenian Sea system is addressed through a paleomagnetic study of Lias to Langhian sediments from the Apenninic carbonate platform (southern Apennines, Italy). Reliable paleomagnetic data gathered from 21 sites document a regional-scale post-Langhian 80° counterclockwise (CCW) rotation. Since previous studies of the Plio-Pleistocene clays spread over the orogen had shown a ∼20°CCW rotation, we conclude that the southern Apennines rotated by 60° during Middle-Late Miocene. Our data provide evidence that the southeastward drift of Calabrian block (and synchronous spreading of the southern Tyrrhenian Sea) induced ‘saloon door’ like deformation of the southern Apennines and Sicily, which underwent similar magnitude (although opposite in sign) orogenic rotations. A paleomagnetically derived paleogeographic reconstruction shows that at 15 Ma (Late Langhian) the Alpine-Apennine belt collided with a NNE-oriented carbonate platform corridor surrounded by oceanic basins. We speculate that both the end of the Corsica-Sardinia rotation and the eastward jump of the locus of back-arc extension (from the Liguro-Provençal to the Tyrrhenian Sea) may have been consequences of this event.     

Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.     

Variability in the vertical hyporheic water exchange affected by hydraulic conductivity and river morphology at a natural confluent meander bend

River confluences and their associated tributaries are key morphodynamic nodes that play important roles in controlling hydraulic geometry and hyporheic water exchange in fluvial networks. However, the existing knowledge regarding hyporheic water exchange associated with river confluence morphology is relatively scarce. On January 14 and 15, 2016, the general hydraulic and morphological characteristics of the confluent meander bend (CMB) between the Juehe River and the Haohe River in the southern region of Xi'an City, Shaanxi Province, China, were investigated. The patterns and magnitudes of vertical hyporheic water exchange (VHWE) were estimated based on a one‐dimensional heat steady‐state model, whereas the sediment vertical hydraulic conductivity (K_v) was calculated via in situ permeameter tests. The results demonstrated that 6 hydrodynamic zones and their extensions were observed at the CMB during the test period. These zones were likely controlled by the obtuse junction angle and low momentum flux ratio, influencing the sediment grain size distribution of the CMB. The VHWE patterns at the test site during the test period mostly showed upwelling flow dominated by regional groundwater discharging into the river. The occurrence of longitudinal downwelling and upwelling patterns along the meander bend at the CMB was likely subjected to the comprehensive influences of the local sinuosity of the meander bend and regional groundwater discharge and finally formed regional and local flow paths. Additionally, in dominated upwelling areas, the change in VHWE magnitudes was nearly consistent with that in K_v values, and higher values of both variables generally occurred in erosional zones near the thalweg paths of the CMB, which were mostly made up of sand and gravel. This was potentially caused by the erosional and depositional processes subjected to confluence morphology. Furthermore, lower K_v values observed in downwelling areas at the CMB were attributed to sediment clogging caused by local downwelling flow. The confluence morphology and sediment K_v are thus likely the driving factors that cause local variations in the VHWE of fluvial systems.     

Spatial relationship of groundwater–phosphorus interaction in the Kissimmee river basin,South Florida

Fluctuations of groundwater levels were used to predict soluble phosphorus concentrations. In‐situ observations showed a decrease in soluble phosphorus during groundwater recession and an increase with groundwater rise. A spatial analysis of the simulated soluble phosphorus and groundwater levels indicated similarity of patterns (spatial correlation) 99% of the time. A geographically weighted multivariate analysis of soluble phosphorus using groundwater levels, phosphorus levels of the Kissimmee River, and distance from the Kissimmee River as predictors showed a goodness of fit (R²) ranging from 0.2 to 0.7. Results indicated no significant difference between the simulated and observed soluble phosphorus levels at a p value of 0.01. Among the parameters, the groundwater level explained 70% of the soluble phosphorus variability. The distance to surface waterbodies and their phosphorus levels had significant weights only within a 5‐km range from the waterbody. A model generalization is further required to simulate the spatiotemporal groundwater–phosphorus dynamics over meaningful temporal ranges – at least for 3 to 5 years – for conclusiveness of the data. Copyright © 2014 John Wiley & Sons, Ltd.     

First‐order exchange coefficient coupling for simulating surface water–groundwater interactions: parameter sensitivity and consistency with a physics‐based approach

Distributed hydrologic models capable of simulating fully‐coupled surface water and groundwater flow are increasingly used to examine problems in the hydrologic sciences. Several techniques are currently available to couple the surface and subsurface; the two most frequently employed approaches are first‐order exchange coefficients (a.k.a., the surface conductance method) and enforced continuity of pressure and flux at the surface‐subsurface boundary condition. The effort reported here examines the parameter sensitivity of simulated hydrologic response for the first‐order exchange coefficients at a well‐characterized field site using the fully coupled Integrated Hydrology Model (InHM). This investigation demonstrates that the first‐order exchange coefficients can be selected such that the simulated hydrologic response is insensitive to the parameter choice, while simulation time is considerably reduced. Alternatively, the ability to choose a first‐order exchange coefficient that intentionally decouples the surface and subsurface facilitates concept‐development simulations to examine real‐world situations where the surface‐subsurface exchange is impaired. While the parameters comprising the first‐order exchange coefficient cannot be directly estimated or measured, the insensitivity of the simulated flow system to these parameters (when chosen appropriately) combined with the ability to mimic actual physical processes suggests that the first‐order exchange coefficient approach can be consistent with a physics‐based framework. Copyright © 2009 John Wiley & Sons, Ltd.     

The role of recharge and evapotranspiration as hydraulic drivers of ion concentrations in shallow groundwater on Everglades tree islands,Florida (USA)

Recently, evapotranspiration has been hypothesized to promote the secondary formation of calcium carbonate year‐round on tree islands in the Everglades by influencing groundwater ions concentrations. However, the role of recharge and evapotranspiration as drivers of shallow groundwater ion accumulation has not been investigated. The goal of this study is to develop a hydrologic model that predicts the chloride concentrations of shallow tree island groundwater and to determine the influence of overlying biomass and underlying geologic material on these concentrations. Groundwater and surface water levels and chloride concentrations were monitored on eight constructed tree islands at the Loxahatchee Impoundment Landscape Assessment (LILA) from 2007 to 2010. The tree islands at LILA were constructed predominately of peat, or of peat and limestone, and were planted with saplings of native tree species in 2006 and 2007. The model predicted low shallow groundwater chloride concentrations when inputs of regional groundwater and evapotranspiration‐to‐recharge rates were elevated, while low evapotranspiration‐to‐recharge rates resulted in a substantial increase of the chloride concentrations of the shallow groundwater. Modeling results indicated that evapotranspiration typically exceeded recharge on the older tree islands and those with a limestone lithology, which resulted in greater inputs of regional groundwater. A sensitivity analysis indicated the shallow groundwater chloride concentrations were most sensitive to alterations in specific yield during the wet season and hydraulic conductivity in the dry season. In conclusion, the inputs of rainfall, underlying hydrologic properties of tree islands sediments and forest structure may explain the variation in ion concentration seen across Everglades tree islands. Copyright © 2012 John Wiley & Sons, Ltd.     

Using selected pharmaceutical compounds as indicators for surface water and groundwater interaction in the hyporheic zone of a low permeability riverbank

This study investigates the applicability of selected pharmaceutical compounds (e.g. sulfamethoxazole, carbamazepine, ibuprofen) as anthropogenic indicators for the interaction of surface water and groundwater in the hyporheic zone of an alluvial stream. Differences in transport behaviour and the resulting distribution of the pharmaceuticals in the riverine groundwater were evaluated. The investigated field site in the Grand Duchy of Luxembourg, Europe is represented by low permeable sediments and confined aquifer conditions. Water samples from single‐screen and multilevel observation wells installed in the riverbank at the field site were taken and analysed for selected pharmaceuticals and major ions for a period of 6 months. Surface water and groundwater levels were recorded to detect effluent and influent aquifer conditions. Nearly all pharmaceuticals that were detected in the stream were also found in the riverine groundwater. However, concentrations were significantly lower in groundwater than in surface water. A classification into mobile and sorbing/degradable pharmaceuticals based on their transport relevant properties was made and verified by the field data. Gradients with depth for some of these pharmaceuticals were documented and a more detailed understanding of the system stream/riverbank was obtained. It was demonstrated that the selected pharmaceutical compounds can be used as anthropogenic indicators at the investigated field site. However, not all compounds seem to be suitable indicators as their transport behaviour is not fully understood. Copyright © 2012 John Wiley & Sons, Ltd.     

Groundwater–surface water interactions in a lowland watershed: source contribution to stream flow

The lower coastal plain of the Southeast USA is undergoing rapid urbanisation as a result of population growth. Land use change has been shown to affect watershed hydrology by altering stream flow and, ultimately, impairing water quality and ecologic health. However, because few long‐term studies have focused on groundwater–surface water interactions in lowland watersheds, it is difficult to establish what the effect of development might be in the coastal plain region. The objective of this study was to use an innovative improvement to end‐member mixing analysis (EMMA) to identify time sequences of hydrologic processes affecting storm flow. Hydrologic and major ion chemical data from groundwater, soil water, precipitation and stream sites were collected over a 2‐year period at a watershed located in USDA Forest Service's Santee Experimental Forest near Charleston, South Carolina, USA. Stream flow was ephemeral and highly dependent on evapotranspiration rates and rainfall amount and intensity. Hydrograph separation for a series of storm events using EMMA allowed us to identify precipitation, riparian groundwater and streambed groundwater as main sources to stream flow, although source contribution varied as a function of antecedent soil moisture condition. Precipitation, as runoff, dominated stream flow during all storm events while riparian and streambed groundwater contributions varied and were mainly dependent on antecedent soil moisture condition. Sensitivity analyses examined the influence of 10% and 50% increases in analyte concentration on EMMA calculations and found that contribution estimates were very sensitive to changes in chemistry. This study has implications on the type of methodology used in traditional forms of EMMA research, particularly in the recognition and use of median end‐member water chemistry in hydrograph separation techniques. Potential effects of urban development on important hydrologic processes (groundwater recharge, interflow, runoff, etc.) that influence stream flow in these lowland watersheds were qualitatively examined. Copyright © 2011 John Wiley & Sons, Ltd.     

The impact of the South–North Water Transfer Project (CTP)'s central route on groundwater table in the Hai River basin,North China

The central route of the South–North Water Transfer Project (CTP) is designed to divert approximately 9.5 billion m³ of water per year from the Han River, a major tributary of the Yangtze River, to the Hai River basin in the north China. The main purpose of this study is to assess the impact of CTP on groundwater table in the Hai River basin. Our study features a large‐scale distributed hydrological model that couples a physically based groundwater module, which is sub‐basin‐based, with a conceptual surface water module, which is grid‐based. There are several grids in each sub‐basin and water exchange among grid that are considered. Our model couples surface water module and groundwater module and calculates human water use at the same time. The simulation results indicate that even with the water supply by CTP, the groundwater table will continue to decline in the Hai River basin. However, the CTP water can evidently reduce the decline rate, helping alleviate groundwater overexploitation in Hai River region. Copyright © 2013 John Wiley & Sons, Ltd.