Using chlorofluorocarbons (CFCs) and tritium (3H) to estimate groundwater age and flow velocity in Hohhot Basin,China

The concentrations of chlorofluorocarbons (CFC‐11, CFC‐12 and CFC‐113) and tritium (³H) content in groundwater were used to date groundwater age, delineate groundwater flow systems and estimate flow velocity in the Hohhot basin. The estimated young groundwater age is fallen in the bracket of 21 ~ 50 a and indicates the presence of two different age profiles and flow systems in the shallow groundwater system. Older age waters occur under the topographically low areas, where the aquifer is double‐layer aquifer system consisting of shallow unconfined‐semi‐confined aquifer and deep confined aquifer. This reflects long flow paths associated with regional flow. Groundwater (range from 21 to 34 years) in the north piedmont and east hilly areas, where the aquifer is a single‐layer aquifer consisting of alluvial fans, are typically younger than those in the low areas. The combination of CFCs dating with hydrogeological information indicates that both local and regional flow systems are present at the basin. The regional groundwater flow mainly flows from the north and east to the southwest, the local groundwater flow system occurs nearby the Hohhot city. The mean regional groundwater flow velocity of the shallow groundwater is estimated about 0.73 km/a. These findings can aid in refining hydrogeological conceptual model of the study area. Copyright © 2012 John Wiley & Sons, Ltd.     

Using chlorofluorocarbons (CFCs) and tritium to improve conceptual model of groundwater flow in the South Coast Aquifers of Laizhou Bay,China

The southern coastal plain of Laizhou Bay, which is the area most seriously affected by salt water intrusion in north China, is a large alluvial depression, which represents one of the most important hydrogeological units in the coastal region of northern China. Chlorofluorocarbons (CFCs, including CFC‐11, CFC‐12 and CFC‐113) and tritium were used together for dating groundwater up to 50 years old in the study area. There are two cones of depression, caused by intensive over‐exploitation of fresh groundwater in the south and brine water in the north. The assigned CFC apparent ages for shallow groundwater range from 8 a to >50 a. A binary mixing model based on CFC‐113 and CFC‐12 concentrations in groundwater was used to estimate fractions of young and pre‐modern water in shallow aquifers and to identify groundwater mixing processes during saltwater intrusion. Discordance between concentrations of different CFC compounds indicate that shallow groundwater around the Changyi cone of depression is vulnerable to contamination. Pumping activities, CFC contamination, mixing and/or a large unsaturated zone thickness (e.g. >20 m) may be reasons for some groundwater containing CFCs without tritium. Saline intrusion mainly occurs because of large head gradients between fresh groundwater in the south and saline water bodies in the north, forming a wedge of saline water below/within fresh aquifer layers. Both CFC and tritium dates indicate that the majority of the saline water is from >50 a, with little or no modern seawater component. Based on the distribution of CFC apparent ages, tritium contents plus chemical and physical data, a conceptual model of groundwater flow along the investigated Changyi‐Xiaying transect has been developed to describe the hydrogeological processes. Three regimes are identified from south to north: (i) fresh groundwater zone, with a mixing fraction of 0.80–0.65 ‘young’ water calculated with the CFC binary mixing model (groundwater ages <34 a) and 1.9–7.8TU of tritium; (ii) mixing zone characterized by a mixing fraction of 0.05–0.65 young groundwater (ages of 23–44 a), accompanied by local vertical recharge and upward leakage of older groundwater; and (iii) salt water zone, mostly comprising waters with ages beyond the dating range of both CFCs and tritium. Some shallow groundwater in the north of the Changyi groundwater depression belongs to the >50a water group (iii), indicating slow velocity of groundwater circulation and possible drawing in of saline or deep groundwater that is tracer‐free. Copyright © 2012 John Wiley & Sons, Ltd.     

Environmental isotopic and hydrochemical characteristics of groundwater systems in Daying and Qicun geothermal fields,Xinzhou Basin,Shanxi, China

The conceptual hydrogeological model of the low to medium temperature Daying and Qicun geothermal fields has been proposed, based on hydrochemical characteristics and isotopic compositions. The two geothermal fields are located in the Xinzhou basin of Shanxi, China and exhibit similarities in their broad‐scale flow patterns. Geothermal water is derived from the regional groundwater flow system of the basin and is characterized by Cl·SO₄‐Na type. Thermal water is hydrochemically distinct from cold groundwater having higher total dissolved solids (TDS) (>0·8 g/l) and Sr contents, but relatively low Ca, Mg and HCO₃ contents. Most shallow groundwater belongs to local flow systems which are subject to evaporation and mixing with irrigation returns. The groundwater residence times estimated by tritium and ¹⁴C activities indicate that deep non‐thermal groundwater (130–160 m) in the Daying region range from modern (post‐1950s) in the piedmont area to more than 9·4 ka BP (Before Present) in the downriver area and imply that this water belong to an intermediate flow system. Thermal water in the two geothermal fields contains no detectable active ¹⁴C, indicating long residence times (>50 ka), consistent with this water being part of a large regional flow system. The mean recharge elevation estimated by using the obtained relationship Altitude (m) = ? 23·8 × δ²H (‰ ) ? 121·3, is 1980 and 1880 m for the Daying and Qicun geothermal fields, respectively. The annual infiltration rates in the Daying and Qicun geothermal fields can be estimated to be 9029 × 10³ and 4107 × 10³ m³/a, respectively. The variable ⁸⁶Sr/⁸⁷Sr values in the thermal and non‐thermal groundwater in the two fields reflect different lithologies encountered along the flow path(s) and possibly different extents of water‐rock interaction. Based on the analysis of groundwater flow systems in the two geothermal fields, hydrogeochemical inverse modelling was performed to indicate the possible water‐rock interaction processes that occur under different scenarios. Copyright © 2010 John Wiley & Sons, Ltd.     

Tracking Groundwater Discharge to a Large River using Tracers and Geophysics

Few studies have investigated large reaches of rivers in which multiple sources of groundwater are responsible for maintaining baseflow. This paper builds upon previous work undertaken along the Fitzroy River, one of the largest perennial river systems in north‐western Australia. Synoptic regional‐scale sampling of both river water and groundwater for a suite of environmental tracers (⁴He, ⁸⁷Sr/⁸⁶Sr, ²²²Rn and major ions), and subsequent modeling of tracer behavior in the river, has enabled definition and quantification of groundwater input from at least three different sources. We show unambiguous evidence of both shallow “local” groundwater, possibly recharged to alluvial aquifers beneath the adjacent floodplain during recent high‐flow events, and old “regional” groundwater introduced via artesian flow from deep confined aquifers. We also invoke hyporheic exchange and either bank return flow or parafluvial flow to account for background ²²²Rn activities and anomalous chloride trends along river reaches where there is no evidence of the local or regional groundwater inputs. Vertical conductivity sections acquired through an airborne electromagnetic (AEM) survey provide insights to the architecture of the aquifers associated with these sources and general groundwater quality characteristics. These data indicate fresh groundwater from about 300 m below ground preferentially discharging to the river, at locations consistent with those inferred from tracer data. The results demonstrate how sampling rivers for multiple environmental tracers of different types—including stable and radioactive isotopes, dissolved gases and major ions—can significantly improve conceptualization of groundwater—surface water interaction processes, particularly when coupled with geophysical techniques in complex hydrogeological settings.     

Evaluation of nitrate levels in groundwater under agricultural fields in two pilot areas in central Chile: A hydrogeological and geochemical approach

The aim of this study is to evaluate the impact of the application of industrial fertilizers and liquid swine manure in groundwater in two pilot agricultural areas, San Pedro and Pichidegua, which have been under long‐term historic use of fertilizers. A comprehensive hydrogeological investigation was carried out to define the geology and the groundwater flow system. Chemical and isotopic tools were used to evaluate the distribution and behavior of the nitrate in the groundwater. The isotopic tools included δ¹⁸O, δ²H, and ³H, which provide information about the origin and residence time of the groundwater; δ¹⁵N‐NO₃^? and δ¹⁸O‐NO₃^?, which provide information about nitrate sources and processes that can affect nitrate along the groundwater flow system. The application rate of liquid manure and other fertilizers all together with land uses was also evaluated. The hydrogeological investigation identified the presence of a confined aquifer underneath a thick low‐permeability aquitard, whose extension covers most of the two study areas. The nitrate concentration data, excepting a few points in zones located near recharge areas in the upper part of the basins and lower areas at the valley outlets (San Pedro), showed nitrate concentration below 10 mgN/L at the regional scale. The isotope data for nitrate showed no influence of the liquid swine manure in the groundwater at the regional scale, except for the high part of the basins and the outlet of the San Pedro valley, which are areas fertilized by manure. This data showed that the regional aquifer on both pilot study areas is protected by the thick low‐permeability aquitard, which is playing an important role on nitrate attenuation. Evidence of denitrification was also found on both shallow and deep groundwater in the Pichidegua site. This study showed that a comprehensive hydrogeological characterization complemented by chemical and isotope data is key for understanding nitrate distribution and concentration in aquifers from areas with intensive agriculture activities.     

Groundwater flow and implications for groundwater contamination north of Prewitt,New Mexico,U.S.A.

In the southern San Juan Basin, New Mexico, strata of Permian and younger age dip gently toward the center of the basin. Most previous investigators believed that recharge to these strata occurred by precipitation on the outcrops and groundwater flowed downdip to the north and northeast. Recent water-level measurements in an undeveloped part of the basin near Prewitt, New Mexico, show that groundwater at shallow depths in alluvium and bedrock flows southward, opposite to the dip direction, and toward a major ephemeral drainage in a strike valley. North of this area, groundwater in deep bedrock aquifers does appear to flow northward. This information suggests that there are two groundwater circulation patterns; a shallow one controlled by topography and a deeper one controlled by geologic structure.Significant amounts of recharge to sandstone aquifers by infiltration through outcrops is unlikely due to the near-vertical exposures on cliffs, the gentle dip of the strata, and small annual precipitation. Numerical model results suggest that recharge to bedrock aquifers may be from downward leakage via aquitards over large areas and leakage from narrow alluvial aquifers in the subcrop area. The recharge mechanism is controlled by the hydraulic conductivity of the strata.As the flow path is controlled by hydraulic conductivity contrasts, geologic structure, and topography, contamination movement from surface impoundments is likely to be difficult to predict without a thorough hydrogeological site investigation.     

Identifying the flow pattern and natural recharge at a strategic groundwater resource in the Dornogobi Province,Mongolia

The strategic project of economic development in the Dornogobi Province in Mongolia is dependent on water supply. Thus a comprehensive hydrogeological characterization was focused on the Upper Cretaceous multi-aquifer system north of Sainshand city. A conceptual model was developed to discover the groundwater flow pattern essential to correct the setting of the numerical model of groundwater flow created using MODFLOW to assess the natural recharge of the aquifer. The conceptualization was based on geological and hydrogeological characterization. However, the evaluation of hydrochemistry proved to be the key factor revealing the principal feature of the groundwater flow pattern, which is the presence of preferential flow zones. These zones allow for intensive transfer of relatively fresh Na(Mg,Ca)?HCO₃-dominated groundwater into discharge areas, where it leaks into the Quaternary aquifer. The numerical model suggested an enormous natural recharge of 22 100 m³/d, originating in 64% of the preferential flow zones.     

The Manawatu aquifers,North Island,New Zealand: Clarification of hydrogeology using a multidisciplinary environmental tracer approach

A recently developed approach to carbon isotope methodology (process recognition via isotope diagrams) is applied in a multidisciplinary study of precipitation‐recharged aquifers of the lowlands–plains area of the Manawatu (south‐west North Island). Urban and rural areas rely on groundwater from the upper levels of a deep basin sequence comprising marine and terrestrial sediments of Pleistocene age. Hydrochemical and isotopic (¹⁸O, ³H, ¹³C and ¹⁴C) data are merged with known details of geology and hydrogeology to reveal two separate confined aquifers within the depth range to 200 m. The shallower of these, below unconfined, locally recharged groundwater, is recharged on the foothills of the Ruahine Range to the north‐east of the study area; flow direction is NE–SW. The deeper confined aquifer is recharged on the Tararua Range to the immediate east; flow direction essentially is transverse (SE–NW) to that in the shallower aquifer. Two processes are identified as dominant contributors to concentration and isotopic composition of dissolved inorganic carbon (DIC), namely addition of CO₂ from decay of organic materials and carbonate dissolution. Limitations of carbon isotope methods in determining residence times are illustrated by the data. Although the confined groundwater is essentially tritium‐free, only a few samples showed conclusive evidence of significant ageing on the time‐scale of ¹⁴C. Copyright © 2001 John Wiley & Sons, Ltd.     

Delineating coastal groundwater discharge processes in a wetland area by means of electrical resistivity imaging, 224Ra and 222Rn

Coastal groundwater discharge (CGD) plays an important role in coastal hydrogeological systems as they are a water resource that needs to be managed, particularly in wetland areas. Despite its importance, identifying and monitoring CGD often presents physical and logistical constraints, restraining the application of more traditional submarine groundwater discharge surveying techniques. Here we investigate the capability of electrical resistivity imaging (ERI) in the Peníscola wetland (Mediterranean coast, Spain). ERI surveying made it possible to identify and delineate an ascending regional groundwater flow of thermal and Ra‐enriched groundwater converging with local flows and seawater intrusion. The continuous inputs of Ra‐rich groundwater have induced high activities of Ra isotopes and ²²²Rn into the marsh area, becoming among the highest previously reported in wetlands and coastal lagoons. Geoelectrical imaging enabled inferring focused upward discharging areas, leaking from the aquifer roof through a confining unit and culminating as spring pools nourishing the wetland system. Forward modelling over idealized subsurface configurations, borehole datasets, potentiometric records from standpipe piezometers, petrophysical analysis, and four natural and independent tracers (²²⁴Ra, ²²²Rn, temperature and salinity) permitted assessing the geoelectrical model and a derived hydrogeological pattern. The research highlights the potential of ERI to improve hydrogeological characterization of subsurface processes in complex contexts, with different converging flows. Additionally, a hydrogeological conceptual model for a groundwater‐fed coastal wetland was proposed, based on the integration of surveying datasets. Copyright © 2013 John Wiley & Sons, Ltd.     

Structural and Hydrogeological Controls on Hydrocarbon and Brine Migration into Drinking Water Aquifers in Southern New York

Environmental concerns regarding the potential for drinking water contamination in shallow aquifers have accompanied unconventional energy development in the northern Appalachian Basin. These activities have also raised several critical questions about the hydrogeological parameters that control the naturally occurring presence and migration of hydrocarbon gases in shallow aquifers within petroliferous basins. To interrogate these factors, we analyzed the noble gas, dissolved ion, and hydrocarbon gas (molecular and isotopic composition) geochemistry of 98 groundwater samples from south‐central New York. All samples were collected ?1km from unconventional drilling activities and sample locations were intentionally targeted based on their proximity to various types of documented fault systems. In agreement with studies from other petroliferous basins, our results show significant correlations between elevated levels of radiogenic [⁴He], thermogenic [CH₄], and dissolved ions (e.g., Cl, Br, Sr, Ba). In combination, our data suggest that faults have facilitated the transport of exogenous hydrocarbon‐rich brines from Devonian source rocks into overlying Upper Devonian aquifer lithologies over geologic time. These data conflict with previous reports, which conclude that hydrodynamic focusing regulates the occurrence of methane and salt in shallow aquifers and leads to elevated levels of these species in restricted flow zones within valley bottoms. Instead, our data suggest that faults in Paleozoic rocks play a fundamental role in gas and brine transport from depth, regulate the distribution of their occurrence in shallow aquifers, and influence the geochemistry of shallow groundwater in this petroliferous basin.     

Etiology of Salinity and Water Origin,the Main Dilemma of Badab Sourt,a Unique Travertine Spring

Badab Sourt travertine‐depositing springs in the north of Iran, naturally create a unique surreal landscape containing a range of stepped travertine terraces, similarly found only in a few other places on earth. This site comprises of three travertine saline springs with different values of salinity and discharge (SP₁, SP₂, and SP₃) and one non‐travertine fresh karstic spring (SP₄) within a distance of about 300 m. The etiology behind this salinity and the water origin are the main research's dilemma that were investigated using geological, hydrochemical, and stable isotopic techniques. Based on the topography and isotopic results, the carbonate formations in northern (Khoshyeilagh and Mobarak) and southern (Cretaceous limestone) parts of the springs potentially provide the initial hydraulic gradient for deep circulation of the water and CO₂. However, geological studies indicate that the hydraulic connectivity of the Cretaceous formation to the travertine springs is interrupted by impermeable geological formations. Based on the proposed conceptual hydrogeological model and mass balance calculations, the SP₄ spring is locally recharged from the nearby karstic area of Khoshyeilagh formation through shallow, short and steep groundwater flow circulation that is completely different from the travertine springs. The travertine spring (SP₁) is recharged from more distant areas having higher altitudes on Mobarak and Khoshyeilagh limestone and circulate more deeply before emerging on the surface. The SP₂ and SP₃ springs can derive from the mixing of the saline water (SP₁) and fresh water (SP₄). The dissolution of interlayers of halite in Shemshak formation is concluded as the main source of salinity. This is the first research article in detail to survey hydrogeology of the travertine springs in Iran.     

Hydrogeological and hydrogeochemical control of groundwater salinity in an arid inland basin: Dunhuang Basin,northwestern China

High groundwater salinity has become a major concern in the arid alluvial plain of the Dunhuang Basin in northwestern China because it poses a significant challenge to water resource management. Isotopic and geochemical analyses were conducted on 55 water samples from springs, boreholes and surface water to identify potential sources of groundwater salinity and analyse the processes that control increasing salinity. The total dissolved solid (TDS) content in the groundwater ranged from 400 to 41 000 mg/l, and high TDS values were commonly associated with shallow water tables and flow‐through and discharge zones in unconfined aquifers. Various groundwater contributions from rainwater, agricultural irrigation, river water infiltration and lateral inflows from mountains were identified by major ions and δD and δ¹⁸O. In general, HCO₃^? and SO₄^2? were the dominant anions in groundwater with a salinity of <2500 mg/l, whereas Cl^? and SO₄^2? were the dominant anions in groundwater with a salinity of >2500 mg/l. The major ion concentrations indicated that mineral weathering, including carbonate and evaporite dissolution, primarily affected groundwater salinity in recharge areas. Evapotranspiration controlled the major ion concentration evolution and salinity distribution in the unconfined groundwaters in the flow‐through and discharge areas, although it had a limited effect on groundwater in the recharge areas and confined aquifers. Agricultural irrigation increased the water table and enhanced evapotranspiration in the oasis areas of the basin. TDS and Cl became more concentrated, but H and O isotopes were not enriched in the irrigation district, indicating that transpiration dominated the increasing salinity. For other places in the basin, as indicated by TDS, Cl, δD and δ¹⁸O characteristics, evaporation, transpiration and water–rock interactions dominated at different hydrogeological zones, depending on the plant coverage and hydrogeological conditions. Groundwater ages of ³H, and δD and δ¹⁸O compositions and distributions suggest that most of the groundwaters in Dunhuang Basin have a paleometeoric origin and experienced a long residence time. These results can contribute to groundwater management and future water allocation programmes in the Dunhuang Basin. Copyright © 2015 John Wiley & Sons, Ltd.     

Conceptualizing leakage and storage contributions from long open interval wells in regional deep basin flow models

Deep basin aquifers are increasingly used in water‐stressed areas, though their potential for sustainable development is inhibited by overlying aquitards and limited recharge rates. Long open interval wells (LOIWs)—wells uncased through multiple hydrostratigraphic units—are present in many confined aquifer systems and can be an important mechanism for deep basin aquifers to receive flow across aquitards. LOIWs are a major control on flow in the deep Cambrian–Ordovician sandstone aquifers of the upper Midwest, USA, providing a source of artificial leakage from shallow bedrock aquifers and equilibrating head within the sandstone aquifers despite differential pumpage. Conceptualizing and quantifying this anthropogenic flow has long been a challenge for groundwater flow modellers, particularly on a regional scale. Synoptic measurements of active production wells and well completion data for northeast Illinois form the basis for a transient, head‐specified MODFLOW model that determines mass balance contributions to the region and estimates LOIW leakage to the aquifers. Using this insight, transient LOIW leakage was simulated using transiently changing K_V zones in a traditional, Q‐specified MODFLOW‐USG model, a novel approach that allows the K_V in a cell containing a LOIW to change transiently by use of the time‐variant materials (TVM) package. With this modification, we achieved a consistent calibration through time, averaging 19.9 m root mean squared error. This model indicates that artificial leakage via LOIWs contributed a minimum of 10–13% of total flow to the sandstone aquifers through the entire history of pumping, up to 50% of flow around 1930. Removal from storage exceeds 40% of flow during peak withdrawals, much of this flow sourced from units other than the primary sandstone aquifers via LOIWs. As such, understanding the timing and magnitude of LOIW leakage is essential for predicting future water availability in deep basin aquifers.     

Modification of the SWAT model to simulate regional groundwater flow using a multicell aquifer

The soil and water assessment tool (SWAT) has been widely used and thoroughly tested in many places in the world. The application of the SWAT model has pointed out that 2 of the major weaknesses of SWAT are related to the nonspatial reference of the hydrologic response unit concept and to the simplified groundwater concept, which contribute to its low performance in baseflow simulation and its inability to simulate regional groundwater flow. This study modified the groundwater module of SWAT to overcome the above limitations. The modified groundwater module has 2 aquifers. The local aquifer, which is the shallow aquifer in the original SWAT, represents a local groundwater flow system. The regional aquifer, which replaces the deep aquifer of the original SWAT, represents intermediate and regional groundwater flow systems. Groundwater recharge is partitioned into local and regional aquifer recharges. The regional aquifer is represented by a multicell aquifer (MCA) model. The regional aquifer is discretized into cells using the Thiessen polygon method, where centres of the cells are locations of groundwater observation wells. Groundwater flow between cells is modelled using Darcy's law. Return flow from cell to stream is conceptualized using a non‐linear storage–discharge relationship. The SWAT model with the modified aquifer module, the so‐called SWAT‐MCA, was tested in 2 basins (Wipperau and Neetze) with porous aquifers in a lowland area in Lower Saxony, Germany. Results from the Wipperau basin show that the SWAT‐MCA model is able (a) to simulate baseflow in a lowland area (where baseflow is a dominant source of streamflow) better than the original model and (b) to simulate regional groundwater flow, shown by the simulated groundwater levels in cells, quite well.     

Palaeosol Control of Arsenic Pollution: The Bengal Basin in West Bengal,India

Groundwater in the Bengal Basin is badly polluted by arsenic (As) which adversely affects human health. To provide low‐As groundwater for As mitigation, it was sought across 235 km² of central West Bengal, in the western part of the basin. By drilling 76 boreholes and chemical analysis of 535 water wells, groundwater with <10 µg/L As in shallow aquifers was found under one‐third of a study area. The groundwater is in late Pleistocene palaeo‐interfluvial aquifers of weathered brown sand that are capped by a palaeosol of red clay. The aquifers form two N‐S trending lineaments that are bounded on the east by an As‐polluted deep palaeo‐channel aquifer and separated by a shallower palaeo‐channel aquifer. The depth to the top of the palaeo‐interfluvial aquifers is mostly between 35 and 38 m below ground level (mbgl). The palaeo‐interfluvial aquifers are overlain by shallow palaeo‐channel aquifers of gray sand in which groundwater is usually As‐polluted. The palaeosol now protects the palaeo‐interfluvial aquifers from downward migration of As‐polluted groundwater in overlying shallow palaeo‐channel aquifers. The depth to the palaeo‐interfluvial aquifers of 35 to 38 mbgl makes the cost of their exploitation affordable to most of the rural poor of West Bengal, who can install a well cheaply to depths up to 60 mbgl. The protection against pollution afforded by the palaeosol means that the palaeo‐interfluvial aquifers will provide a long‐term source of low‐As groundwater to mitigate As pollution of groundwater in the shallower, heavily used, palaeo‐channel aquifers. This option for mitigation is cheap to employ and instantly available.     

Environmental isotopes and hydrochemical study applied to surface water and groundwater interaction in the Awash River basin

An environmental isotope and hydrochemical study was carried out to conceptualize the surface water and groundwater interaction and to explore the groundwater flow pattern in relation to the geological setting. More emphasis is given to the Afar Depression where groundwater is a vital source of water supply. Conventional field hydrogeological study and river discharge records support the isotope and hydrochemical analysis. The region is tectonically active, comprising rift volcanic terrain bordered by highlands. The result revealed that recent meteoric water is the major source of recharge. Three distinct groundwater zones were identified associated with the highlands, transitional escarpment and the rift. Towards the rift, the ionic concentration and isotopic enrichment (δ²H and δ^18degO) increases following the groundwater flow paths, which is strongly controlled by axial rift faults. The groundwater flow converges to the seismically active volcano–tectonic depressions with internal drainage and to the Awash River. Within the Afar Depression, at least four groundwater regimen are identified: (1) fresh and shallow groundwater associated with alluvial deposits ultimately recharged by isotopically depleted recent highland rainfall and the evaporated Awash River; (2) cold and relatively younger groundwater within localized fractured volcanics showing mixed origin in axial fault zones; (3) old groundwater with very high ionic concentration and low isotopic signature localized in deep volcanic aquifers; and (4) old and hot saline groundwaters connected to geothermal systems. The study demonstrated that dependable groundwater can only be obtained from the first two aquifer types in aerially restricted zones in flat plains following river courses, local wadis and volcano–tectonic depressions. The conventional hydrogeological survey and discharge records indicate substantial channel losses from the Awash River, which becomes a more dominant source of recharge in central and lower Awash valleys. Copyright © 2007 John Wiley & Sons, Ltd.     

Aquifer interactions with a polluted mountain river of Nicaragua

The interactions between a stream and nearby shallow aquifers were investigated in a mountain basin being polluted by mercury released during mining in central Nicaragua. Hourly data series of water levels and temperatures were analysed using cross‐correlation. Resistivity imaging was used to map the subsurface and to complement the hydrological data interpretation. The results show the complex hydrogeological conditions that characterize the region, with weathering and fractured rock as main contributors to groundwater transport. The resistivity images suggest the presence of two vertical dykes perpendicular to the stream, and zones rich in clay. The data series indicate a rapid response from the aquifers to recharge events, followed by immediate discharge on a yearly basis. Furthermore, alternating periods of stream infiltration and aquifer discharge were identified. This work demonstrates that surface water pollution is a threat to groundwater quality in the area. Copyright © 2007 John Wiley & Sons, Ltd.     

Hydrological and isotopic characterization of river water,groundwater, and groundwater recharge in the Heihe River basin,northwestern China

We used hydrochemistry and environmental isotope data (δ¹⁸O, δD, tritium, and ¹⁴C) to investigate the characteristics of river water, groundwater, and groundwater recharge in China's Heihe River basin. The river water and groundwater could be characterized as Ca²⁺? Mg²⁺? HCO₃^?? SO₄^2? and Na⁺? Mg²⁺? SO₄^2?? Cl^? types, respectively. Hydrogeochemical modelling using PHREEQC software revealed that the main hydrogeochemical processes are dissolution (except for gypsum and anhydrite) along groundwater flow paths from the upper to middle Heihe reaches. Towards the lower reaches, dolomite and calcite tend to precipitate. The isotopic data for most of the river water and groundwater lie on the global meteoric water line (GMWL) or between the GMWL and the meteoric water line in northwestern China, indicating weak evaporation. No direct relationship existed between recharge and discharge of groundwater in the middle and lower reaches based on the isotope ratios, d‐excess, and ¹⁴C values. On the basis of tritium in precipitation and by adopting an exponential piston‐flow model, we evaluated the mean residence time of shallow groundwater with high tritium activities, which was around 50 years (a). Furthermore, based on the several popular models, it is calculated that the deep groundwaters in piedmont alluvial fan zone of the middle reaches and in southern part of the lower reaches are modern water, whereas the deep groundwaters in the edge of the middle reaches and around Juyan Lake in the lower reaches of Heihe river basin are old water. Copyright © 2010 John Wiley & Sons, Ltd.     

The impact of the South–North Water Transfer Project (CTP)'s central route on groundwater table in the Hai River basin,North China

The central route of the South–North Water Transfer Project (CTP) is designed to divert approximately 9.5 billion m³ of water per year from the Han River, a major tributary of the Yangtze River, to the Hai River basin in the north China. The main purpose of this study is to assess the impact of CTP on groundwater table in the Hai River basin. Our study features a large‐scale distributed hydrological model that couples a physically based groundwater module, which is sub‐basin‐based, with a conceptual surface water module, which is grid‐based. There are several grids in each sub‐basin and water exchange among grid that are considered. Our model couples surface water module and groundwater module and calculates human water use at the same time. The simulation results indicate that even with the water supply by CTP, the groundwater table will continue to decline in the Hai River basin. However, the CTP water can evidently reduce the decline rate, helping alleviate groundwater overexploitation in Hai River region. Copyright © 2013 John Wiley & Sons, Ltd.     

Simulation of groundwater flow in a crystalline rock aquifer system in Southern Ghana – An evaluation of the effects of increased groundwater abstraction on the aquifers using a transient groundwater flow model

Monitored groundwater level data, well logs, and aquifer data as well as the relevant surface hydrological data were used to conceptualise the hydrogeological system of the Densu Basin in Southern Ghana. The objective was to numerically derive the hydraulic conductivity field for better characterization of the aquifer system and for simulating the effects of increasing groundwater abstraction on the aquifer system in the basin. The hydraulic conductivity field has been generated in this study through model calibration. This study finds that hydraulic conductivity ranges between a low of 2 m/d in the middle sections of the basin and about 40 m/d in the south. Clear differences in the underlying geology have been indicated in the distribution of aquifer hydraulic conductivities. This is in consonance with the general assertion that the hydrogeological properties of the aquifers in the crystalline basement terrains are controlled by the degree of fracturing and/or weathering of the country rock. The transient model suggest aquifer specific storage values to range between 6.0 × 10^?5 m^?1 and 2.1 × 10^?4 m^?1 which are within acceptable range of values normally quoted for similar lithologies in the literature. There is an apparent subtle decrease in groundwater recharge from about 13% of the annual precipitation in 2005 to about 10.3% of the precipitation in 2008. The transient model was used to simulate responses of the system to annual increment of groundwater abstraction by 20% at the 2008 recharge rates for the period 2009 – 2024. The results suggest that the system will not be able to sustain this level of abstraction as it would lead to a basin wide drawdown in the hydraulic head by 4 m by the end of the prediction period. It further suggests a safe annual increment in groundwater abstraction by 5% under business as usual recharge conditions. Identification and protection of groundwater recharge areas in the basin are recommended in order to safeguard the integrity of the resource under the scenario of increased abstraction for commercial activities in the basin. Copyright © 2012 John Wiley & Sons, Ltd.