Spheroidal weathering of granite porphyry with well‐developed columnar joints by oxidation,iron precipitation,and rindlet exfoliation

Spheroidal weathering, one of the important rock weathering styles, has been attributed to chemical weathering by the water from joint surfaces, and mechanical aspects of the weathering have not been well addressed. We made an investigation on spheroidal weathering of Miocene granite porphyry with well‐developed columnar joints and found that this spheroidal weathering proceeds through chemical processes and accompanying mechanical processes. The investigation of the textures, physical properties, mineralogy, and chemistry of the porphyry revealed the presence of a brown band on the surface margins of corestones, representing the oxidation of pyrite and chlorite, and the precipitation of iron hydroxides, and the consequent generation of micro‐cracks within the band. During weathering, oxidation progresses inwards from joints that surround the rindlets, including both high‐angle columnar and low‐angle planar joints, and causes rounding of the unweathered interior portion of the rock. Microscopic observations of the brown band embedded with fluorescent resin show that pores are first filled with iron hydroxides, and that micro‐cracks then form parallel to the oxidation front in the outer portion of the brown band. Iron hydroxide precipitation increases the P‐wave velocity in the brown band, while micro‐crack formation decreases the tensile strength of the rock. Where the brown band has thickened to ~6 cm, the micro‐cracks are connected to one another to create continuous cracks, which separate the rindlets from the corestone. Micro‐crack formation parallel to the corestone surface may be attributed to compressive stresses generated by small amounts of volumetric expansion due to the precipitation of iron hydroxides in the brown band. Earth surface is under oxidizing environments so that precipitation of iron hydroxides commonly occurs; the spheroidal weathering in this paper is a typical example of the combination of chemical and mechanical processes under such environments. Copyright © 2016 John Wiley & Sons, Ltd.     

A new technique for non‐destructive field measurement of rock‐surface strength: an application of the Equotip hardness tester to weathering studies

Tafone‐like depressions have developed on the Aoshima sandstone blocks used for a masonry bridge pier in the coastal spray zone. A thin layer of partial granular disintegration was found on the surface in depressions. To evaluate quantitatively the strength of the thin weathered layer, the hardness was measured at the surface of the sandstone blocks using both an Equotip hardness tester and an L‐type Schmidt hammer. Comparison of the two testing results indicates that the Equotip hardness value is more sensitive in evaluating the strength of a thin layer of weathered surface rock than the Schmidt hardness value. By applying two methods, i.e. both the repeated impact method and the single impact method, the Equotip tester can evaluate the strengths of fresh internal and weathered surficial portions of rocks having a thin weathering layer. Comparison of the two strengths enables evaluation of strength reduction due to weathering. Copyright © 2007 John Wiley & Sons, Ltd.     

Cavernous weathering,dynamical instability and self‐organization

Cavernous weathering may be conceptualized as a self‐reinforcing process, characterized by positive feedback within the weathering system. A morphometric study of caverns in the Valley of Fire State Park, Nevada, USA, demonstrates the applicability of a dynamically unstable, or conditionally unstable, model of cavernous weathering systems. Outcrop surfaces displaying caverns tend to show increasing fragmentation of the surface in the early stages of cavernous weathering, succeeded by convergent evolution of the surface in which caverns tend to grow and coalesce. A paradoxical relationship exists between the weathering system output at the scale of individual forms and the outcrop scale: caverns tend toward minimum interior surface area by developing a spheroidal form, yet the outcrop surface tends toward maximum exposed surface area by increasing the degree of fragmentation of the surface. Copyright © 2004 John Wiley & Sons, Ltd.     

Origin of honeycombs and related weathering forms in Oligocene Macigno Sandstone,Tuscan coast near Livorno,Italy

Two types of cavernous‐weathering features are exposed in the Oligocene Macigno Sandstone along 5 km of the Tuscan coast south of Livorno, Italy. Honeycomb cells (type 1 features) are typical closely spaced, more or less circular pits of centimetre scale that have been eroded 2 to 6 cm below the general surface of bedding planes or joints. ‘Aberrant honeycomb’ cells (type 2 features) are highly elongate, polygonal, or irregular ?at depressions of decimetre scale surrounded by walls rarely higher than 2 cm, some of which pass into long, free‐standing walls or tendrils. Thus, not all type 2 ‘honeycomb’ cells are fully enclosed. We measured the geometry of 551 honeycomb cells and examined various rock properties (microscopic texture and fabric, mineralogy, porosity, permeability, and chemical composition) to isolate factors that control the size, shape, distribution, and pattern of the honeycombs. Our goal was to narrow potential origins of the features and to understand their formation. The ubiquitous occurrence of sea salt in the honeycombs and scanning electron microscope evidence of physical weathering of silicates, especially micas, favours an origin for the honeycombs chie?y by salt weathering. Honeycombs do not form in siltstone, iron‐oxide‐impregnated sandstone, calcite‐cemented concretions, or in case‐hardened joints. Thus, salt weathering of type 1 and 2 honeycombs is not effective in very low permeability rocks. We propose for type 1 honeycombs that seawater is drawn into micropores of the sandstone and evolves into self‐organized diffusion cells (Turing patterns). Selective evaporation at the stationary nodes of diffusion cells, which form at the same site over time, leads to the precipitation of salt, then grains spall off, and pits are formed. The deepest pits (>40 mm) formed where Turing patterns consistently formed at the same sites. Although the walls are more porous and weathered than the host sandstone, they become selectively case hardened by an unidenti?ed component of low abundance. Initial honeycomb cell shape and gravity locally in?uenced type 1 honeycomb shapes. We suggest that type 2 honeycombs develop where diffusion‐controlled Turing patterns lead to case‐hardening along linear trends; gravity and rock fabric are important locally in in?uencing the orientation of the walls. Only type 2 cells are forming today, suggesting recent environmental changes. Gravity is not a fundamental control on honeycomb shape; in places it is a contributing factor. Pre‐existing depressions (quarry tool marks) have strongly in?uenced honeycomb shape locally. Copyright © 2004 John Wiley & Sons, Ltd.     

Fungal weathering of basaltic rocks in a cold oceanic environment (Iceland): comparison between experimental and field observations

This paper presents evidence for strong biochemical weathering of basaltic outcrops induced by fungal communities in a cold environment. Weathering rind formation is considered to be a consequence of the biological activity. Comparisons between in vitro experiments and in situ observations allow a characterization of fungal effects on rocks and help to define the place of these micro‐organisms in the cold environment weathering chain. It is concluded that biological weathering is chronologically the first process of weathering, probably leading to the subsequent expression of cryogenic processes. Information presented here suggests the need for reconsideration of the traditional frost‐driven morphogenetic system normally considered for subpolar areas. Copyright © 2002 John Wiley & Sons, Ltd.     

Surface‐climate attributes at Injisuthi Outpost,Drakensberg, and possible ramifications for weathering

Aerial and sub‐aerial climatic data were collected from a station at 1920 m a.s.l. in the Injisuthi region of the South African Drakensberg. Sensors monitored air temperature, soil surface and rock surface temperature, for two rock types, over the summer and winter of 2001/2002. Rainfall was measured from the summer of 2001 to January 2004. These are the first rock and soil surface‐climate data to be collected for an exposed site at this altitude in the area. Rainfall over the two calendar years 2002 and 2003 was found to be below estimates for the region, but patterns imply numerous rock wetting and drying cycles in summer. At the site, air, rock and soil temperatures differ considerably on a diurnal basis with respect to both absolute temperature and daily ranges. Mean rock daily ranges, as conducive to possible thermal fatigue, are found to be similar in the summer and winter periods. Of the two rock types monitored, the darker coloured basalt attained higher maximum and marginally lower minimum temperatures than the sandstone. Soil frost did not occur at 2·5 cm depth, but rock did reach below ?6 °C in winter. Both rock types maintain relatively high rock temperatures in winter (exceeding 25 °C), thus chemical weathering is probably only moisture restricted during this dry period. Findings highlight the importance of directly monitoring rock temperature when attempting to discern the rock weathering environment. Copyright © 2006 John Wiley & Sons, Ltd.     

Techniques for measuring rock weathering: application to a dated fan segment sequence in southern Tunisia

There are a number of techniques for estimating the amount of weathering a clast has undergone. These usually have the objective of establishing an ordinal chronology of geomorphological surfaces, or investigation of site-specific conditions affecting weathering rates. Three such techniques are applied to a dated sequence of alluvial fan segments in southern Tunisia. Two of these techniques depend on measuring surface roughness (the micro-roughness meter and a displacement approach) and one uses the structural weakening of the rock fabric (Schmidt hammer). The micro-roughness meter enables calculation of standard deviation of surface height variation, root mean square roughness and surface autocorrelation function. Of these techniques, Schmidt hammer rebound values, standard deviation, root mean square roughness and the displacement technique show systematic changes on the three fan segments which are statistically significant at the 0·05 level. However, the amount of variance in all datasets is very large, indicating the need for caution in application of these techniques for relative dating. © 1998 John Wiley & Sons, Ltd.     

Preliminary study on weathering and pedogenesis of carbonate rock

South China is the largest continuous distribution area of carbonate rock in the world. The origin of the soils over the bedrock carbonate rock has long been a controversial topic. Here further exploration is made by taking five soil profiles as examples, which are developed over the bedrock dolomitite and limestone and morphologically located in upland in karst terrain in the central, west and north Guizhou as well as west Hunan, and proved to be the weathering profiles of carbonate rock by the research results of acid-dissolved extraction experiment of bedrock, mineralogy and trace element geochemistry. Field, mineralogical and trace element geochemical characteristics of weathering and pedogenesis for carbonate rock are discussed in detail. It is pointed out that weathering and pedogenesis of carbonate rock are important pedogenetic mechanisms for soil resources in karst area, providing a basis for further researches on the origin of soils widely overlying bedrock carbonate rocks in South China. Project supported by the National Natural Science Foundation of China (Grant No. 498330003) and National Key Basic Research Project (Grant No. 95pre-39).     

The influence of solar‐induced thermal stresses on the mechanical weathering of rocks in humid mid‐latitudes

The role of solar‐induced thermal stresses in the mechanical breakdown of rock in humid‐temperate climates has remained relatively unexplored. In contrast, numerous studies have demonstrated that cracks in rocks found in more arid mid‐latitude locations exhibit preferred northeast orientations that are interpreted to be a consequence of insolation‐related cracking. Here we hypothesize that similar insolation‐related mechanisms may be efficacious in humid temperate climates, possibly in conjunction with other mechanical weathering processes. To test this hypothesis, we collected rock and crack data from a total of 310 rocks at a forested field site in North Carolina (99 rocks, 266 cracks) and at forested and unforested field sites in Pennsylvania (211 rocks, 664 cracks) in the eastern United States. We find that overall, measured cracks exhibit statistically preferred strike orientations (47° ± 16), as well as dip angles (52° ± 24°), that are similar in most respects to comparable datasets from mid‐latitude deserts. There is less variance in strike orientations for larger cracks suggesting that cracks with certain orientations are preferentially propagated through time. We propose that diurnally repeating geometries of solar‐related stresses result in propagation of those cracks whose orientations are favorably oriented with respect to those stresses. We hypothesize that the result is an oriented rock heterogeneity that acts as a zone of weakness much like bedding or foliation that can, in turn, be exploited by other weathering processes. Observed crack orientations vary somewhat by location, consistent with this hypothesis given the different latitude and solar exposure of the field sites. Crack densities vary between field sites and are generally higher on north‐facing boulder‐faces and in forested sites, suggesting that moisture‐availability also plays a role in dictating cracking rates. These data provide evidence that solar‐induced thermal stresses facilitate mechanical weathering in environments where other processes are also likely at play. Copyright © 2015 John Wiley & Sons, Ltd.     

The effects of fire on rock weathering: some further considerations of laboratory experimental simulation

Fire in the natural environment is a widespread agent of geomorphological and biological change. Temperatures can exceed 1000°C. There is often a rapid rise from ambient conditions through a steep thermal gradient, promoting rock disintegration. Laboratory simulation studies have established that temperature changes which are representative of natural fires affect rock material properties, which can then be related to weathering susceptibility. This study extends previous work by more closely replicating the natural environment, (a) through the simulation of rainfall and (b) by encasing samples to reflect the exposure of a single rock face to a passing fire event. Rock samples collected on Cyprus were prepared and tested following previously reported procedures. Change in modulus of elasticity was monitored using a non-destructive ultrasonic method. The data corroborate previous work but with somewhat different degrees of change. The new results are more likely to be representative of natural conditions and real-world change. The rate of rock disintegration and effects such as case-hardening appear to be a function of rock thermal characteristics, material properties and environmental constraints such as diurnal temperature range. Copyright © 1999 John Wiley & Sons, Ltd.     

Rock surface millimetre‐scale roughness and weathering of supratidal Mallorcan carbonate coasts (Balearic Islands)

Quantitative data on rock surface millimetre‐scale roughness are presented concerning the splash and spray geomorphologic domains of two coastal profiles developed on Mediterranean carbonate rocks. Differences of the roughness characteristics are attributed to rock properties, weathering agents and bioerosion. In the splash zone, roughness is related to sparsely distributed patterns of bioerosion, salt weathering and wave attack. In the spray zone, smooth surfaces seem to be the response to the solution processes that predominate, exerting a more homogenous influence on rock surface evolution. Copyright © 2006 John Wiley & Sons, Ltd.     

Depth and character of rock weathering across a basaltic‐hosted climosequence on Hawai‘i

Using field observations and geochemical and digital terrain analyses, we describe the structure and thickness of the regolith across a climosequence on the island of Hawai‘i to gain insight into the relative roles of precipitation and the near‐surface hydrologic structure in determining weathering patterns. In the wet portion of the climosequence, where the long‐term water balance is positive, the regolith thickness reaches an observed maximum of ~40 m and appears limited by the geomorphic base‐level of the landscape. However, even within this thick regolith, distinct units of varying weathering intensity occur; the vertical ordering of which largely reflects differences in the initial permeability structure of the basalt flows rather than a systematic decrease in weathering intensity downwards from the ground surface. In the dry portion of the climosequence, where the long‐term water balance is negative, the regolith thickness is confined to ~1 m, is highly dependent on the inferred permeability structure of the basalt flows, and is independent of geomorphic base‐level. Weathering intensity also varies according to permeability structure and decreases in this thin regolith with distance beneath the ground surface. The abrupt change in regolith depth and character that coincides with the transition from net‐positive to net‐negative long‐term water balance implies that small changes in precipitation rates around a neutral water balance result in large changes in the distribution and depth of weathering. Together our observations indicate that the distribution and depth of weathering in basalts (and probably other lithologies) might be best understood by considering how precipitation interacts with the complicated near‐surface permeability structure over regolith‐forming timescales to weather rock in the vadose zone. Copyright © 2013 John Wiley & Sons, Ltd.     

Progressive failure of sheeted rock slopes: the 2009–2010 Rhombus Wall rock falls in Yosemite Valley,California, USA

Progressive rock‐fall failures in natural rock slopes are common in many environments, but often elude detailed quantitative documentation and analysis. Here we present high‐resolution photography, video, and laser scanning data that document spatial and temporal patterns of a 15‐month‐long sequence of at least 14 rock falls from the Rhombus Wall, a sheeted granitic cliff in Yosemite Valley, California. The rock‐fall sequence began on 26 August 2009 with a small failure at the tip of an overhanging rock slab. Several hours later, a series of five rock falls totaling 736 m³ progressed upward along a sheeting joint behind the overhanging slab. Over the next 3 weeks, audible cracking occurred on the Rhombus Wall, suggesting crack propagation, while visual monitoring revealed opening of a sheeting joint adjacent to the previous failure surface. On 14 September 2009 a 110 m³ slab detached along this sheeting joint. Additional rock falls between 30 August and 20 November 2010, totaling 187 m³, radiated outward from the initial failure area along cliff (sub)parallel sheeting joints. We suggest that these progressive failures might have been related to stress redistributions accompanying propagation of sheeting joints behind the cliff face. Mechanical analyses indicate that tensile stresses should occur perpendicular to the cliff face and open sheeting joints, and that sheeting joints should propagate parallel to a cliff face from areas of stress concentrations. The analyses also account for how sheeting joints can propagate to lengths many times greater than their depths behind cliff faces. We posit that as a region of failure spreads across a cliff face, stress concentrations along its margin will spread with it, promoting further crack propagation and rock falls. Published in 2012. This article is a US Government work and is in the public domain in the USA.     

Seismic response of linear and non‐linear asymmetric systems with non‐linear fluid viscous dampers

This investigation is concerned with the seismic response of one‐story, one‐way asymmetric linear and non‐linear systems with non‐linear fluid viscous dampers. The seismic responses are computed for a suite of 20 ground motions developed for the SAC studies and the median values examined. Reviewed first is the behaviour of single‐degree‐of‐freedom systems to harmonic and earthquake loading. The presented results for harmonic loading are used to explain a few peculiar trends—such as reduction in deformation and increase in damper force of short‐period systems with increasing damper non‐linearity—for earthquake loading. Subsequently, the seismic responses of linear and non‐linear asymmetric‐plan systems with non‐linear dampers are compared with those having equivalent linear dampers. The presented results are used to investigate the effects of damper non‐linearity and its influence on the effects of plan asymmetry. Finally, the design implications of the presented results are discussed. Copyright © 2005 John Wiley & Sons, Ltd.     

Evidence for freeze–thaw events and their implications for rock weathering in northern Canada

Discussions regarding weathering in cold environments generally centre on mechanical processes and on the freeze–thaw mechanism in particular. Despite the almost ubiquitous assumption of freeze–thaw weathering, unequivocal proof of interstitial rock water actually freezing and thawing is singularly lacking. Equally, many studies have used the crossing of 0 °C, or values close to that, as the basis for determining the number of ‘freeze–thaw events’. In order to assess the weathering regime at a site in northern Canada, temperatures were collected at the surface, 1 cm and 3 cm depth for sets of paving bricks, with exposures both vertical and at 45°, orientated to the four cardinal directions. Temperature data were collected at 1 min intervals for 1 year. These data provide unequivocal proof for the occurrence of the freezing and thawing of water on and within the rock (freeze–thaw events). The freeze event is evidenced by the exotherm associated with the release of latent heat as the water actually freezes. This is thought to be the ?rst record of such events from a ?eld situation. More signi?cantly, it was found that the temperature at which freezing occurred varied signi?cantly through the year and that on occasion the 1 cm depth froze prior to the rock surface. The change in freeze temperature is thought to be due to the chemical weathering of the material (coupled with on‐going salt inputs via the melting of snowfall), which, it is shown, could occur throughout the winter despite air temperatures down to ?30 °C. This ?nding regarding chemical weathering is also considered to be highly signi?cant. A number of thermal stress events were also recorded, suggesting that rock weathering in cold regions is a synergistic combination of various chemical and mechanical weathering mechanisms. Copyright © 2003 John Wiley & Sons, Ltd.     

Rock warming and drying under simulated intertidal conditions,part II: weathering and biological influences on evaporative cooling and near‐surface micro‐climatic conditions as an example of biogeomorphic ecosystem engineering

The way in which rocks and engineering materials heat‐up and dry‐out in the intertidal zone is of relevance to both weathering and ecology. These behaviours can be measured in the laboratory under controlled conditions designed to replicate those occurring in the field. Previous studies have demonstrated differences in thermal behaviours between rock types and through time as a result of soiling in terrestrial environments, but the influence of weathering and colonization on rock behaviours in the intertidal zone has not been previously assessed. We measured the warming and drying of blocks of rock (limestone and granite) and marine concrete during ‘low‐tide’ events simulated in the laboratory, before and after a period of exposure (eight months) on rock platforms in Cornwall, UK. As well as differences between the material types, temperatures of control (unexposed) and field‐exposed blocks differed in the order of 1 to 2 °C. Drying behaviours were also different after field exposure. Differences during the first few hours of exposure to air and heat were attributed to discolouration and albedo effects. Over longer periods of time, changes in the availability of near‐surface pore water as a result of micro‐scale bioerosion of limestone and the development of bio‐chemical crusts on marine concrete [observed using scanning electron microscopy (SEM)] are suggested as mechanisms enhancing and reducing, respectively, the efficiency of evaporative cooling. The retention of moisture by epilithic biofilms may also influence thermal and drying behaviours of granite. These observations represent one of the first examples of cross‐scalar biogeomorphic linkages in the intertidal zone. The significance of the results for the subsequent efficiency of weathering, and near‐surface micro‐climatic conditions experienced by colonizing organisms is discussed. The involvement of microorganisms in the creation of more (or less) ecologically stressful conditions through the alteration of substratum geomorphic properties and behaviours is suggested as an example of ‘biogeomorphic ecosystem engineering’. Copyright © 2011 John Wiley & Sons, Ltd.     

Strong variation in weathering of layered rock maintains hillslope‐scale strength under high precipitation

The evolution of volcanic landscapes and their landslide potential are both dependent upon the weathering of layered volcanic rock sequences. We characterize critical zone structure using shallow seismic V_p and V_s profiles and vertical exposures of rock across a basaltic climosequence on Kohala peninsula, Hawai’i, and exploit the dramatic gradient in mean annual precipitation (MAP) across the peninsula as a proxy for weathering intensity. Seismic velocity increases rapidly with depth and the velocity–depth gradient is uniform across three sites with 500–600 mm/yr MAP, where the transition to unaltered bedrock occurs at a depth of 4 to 10 m. In contrast, velocity increases with depth less rapidly at wetter sites, but this gradient remains constant across increasing MAP from 1000 to 3000 mm/yr and the transition to unaltered bedrock is near the maximum depth of investigation (15–25 m). In detail, the profiles of seismic velocity and of weathering at wet sites are nowhere monotonic functions of depth. The uniform average velocity gradient and the greater depths of low velocities may be explained by the averaging of velocities over intercalated highly weathered sites with less weathered layers at sites where MAP > 1000 mm/yr. Hence, the main effect of climate is not the progressive deepening of a near‐surface altered layer, but rather the rapid weathering of high permeability zones within rock subjected to precipitation greater than ~1000 mm/yr. Although weathering suggests mechanical weakening, the nearly horizontal orientation of alternating weathered and unweathered horizons with respect to topography also plays a role in the slope stability of these heterogeneous rock masses. We speculate that where steep, rapidly evolving hillslopes exist, the sub‐horizontal orientation of weak/strong horizons allows such sites to remain nearly as strong as their less weathered counterparts at drier sites, as is exemplified by the 50°–60° slopes maintained in the amphitheater canyons on the northwest flank of the island. Copyright © 2017 John Wiley & Sons, Ltd.     

Weathering of granite in Antarctica: I. Light penetration into rock and implications for rock weathering and endolithic communities

Where rocks are composed of translucent minerals, light penetrates the rock and, in so doing, impacts on the thermal conditions. Where minerals are not translucent all the heat transformation must be at the rock surface, and steep thermal gradients can occur. Where light does penetrate, a component of the incoming radiation is transformed to heat at differing depths within the rock, thereby decreasing the thermal gradient. Equally, light transmissive minerals facilitate endolithic communities, which can also play a role in rock weathering. The attribute of light transmission within rock and the impact this has on the resulting thermal conditions has not been considered within rock weathering studies. An attempt was made to monitor the amount of light penetrating the outer 2 mm of coarse granite under Antarctic summer conditions and to evaluate the thermal impact of this. It was found that the amount of light penetration at this site exceeded modeled or postulated values from biological studies and that it could significantly impact the thermal conditions within the outer shell of the rock. Although the resulting data highlighted a number of flaws in the experimental procedure, sufficient information was generated to provide the first assessment of the range of thermal responses due to light transmissive minerals in rock. Copyright © 2007 John Wiley & Sons, Ltd.