Isotopic-geochemical study of nitrogen and carbon in peat from the Tunguska Cosmic Body explosion site

Isotopic-geochemical investigations were carried out on peat samples from the 1908 Tunguska Cosmic Body (TCB) explosion area. We analyzed two peat columns from the Northern peat bog, sampled in 1998, and from the Raketka peat bog, sampled during the 1999 Italian expedition, both located near the epicenter of the TCB explosion area. At the depth of the “catastrophic” layer, formed in 1908, and deeper, one can observe shifts in the isotopic composition of nitrogen (up to Δ¹⁵N = +7.2‰) and carbon (up to Δ¹³C = +2‰) and also an increase in the nitrogen concentration compared to those in the normal, upper layers, unaffected by the Tunguska event. One possible explanation for these effects could be the presence of nitrogen and carbon from TCB material and from acid rains, following the TCB explosion, in the “catastrophic” and “precatastrophic” layers of peat. We found that the highest quantity of isotopically heavy nitrogen fell near the explosion epicenter and along the TCB trajectory. It is calculated that 200,000 tons of nitrogen fell over the area of devastated forest, i.e., only about 30% of the value calculated by Rasmussen et al. (1984). This discrepancy is probably caused by part of the nitrogen having dispersed in the Earth’s atmosphere. The isotopic effects observed in the peat agree with the results of previous investigations [Kolesnikov et al 1998a], [Kolesnikov et al 1998b], [Kolesnikov et al 1999] and [Rasmussen et al 1999] and also with the increased content of iridium and other platinoids found in the corresponding peat layers of other columns [Hou et al 1998] and [Hou et al 2000]. These data favor the hypothesis of a cosmochemical origin of the isotopic effects.     

Finding of probable Tunguska Cosmic Body material:: isotopic anomalies of carbon and hydrogen in peat

Method of a search for traces of Tunguska Cosmic Body (TCB) material using layer-by-layer analysis of the isotopic composition of light elements in peat has been offered. Four peat columns sampled at the explosion epicentre indicated significant carbon and hydrogen isotopic effects in its near catastrophic layers. The shifts, opposite in direction, for carbon (Δ¹³C reaches +4.3‰) and hydrogen (ΔD reaches −22‰) cannot be attributed to any known terrestrial reasons (fall-out of terrestrial dust and fire soot; emission from the Earth of oil–gas streams; climate changes, humification of peat, and so on). Moreover, the isotopic effects are clearly associated with the area and with the time of the 1908 event. They are absent in the uppermost and the lowest peat layers and also in the control peat columns sampled at the remote places. Since calculated δ¹³C value for an admixture of carbon (+51–64‰) is very high, these effects may not be explained by contamination of peat with material similar to ordinary chondrites or achondrites, too. Such heavy carbon occurs in the most primitive CI and CM types of carbonaceous chondrites. However, C/Ir ratio in a cosmic admixture is 10,000 times as many as in CI chondrites that points to cometary nature of the TCB. The isotopic effects are in agreement with the increase of the Ir content observed in peat, but, at the same time, small content of Ir points to the low content of dust in the Tunguska comet that sharply differs it from Halleys comet.     

Platinum group element abundances in a peat layer associated with the Tunguska event, further evidence for a cosmic origin

We have measured excesses of Pd, Rh, Ru, REE, Co, Sr, and Y in a peat column from the Northern peat bog of the 1908 Tunguska explosion site. Earlier, in this peat column the presence of an Ir anomaly at the event layers (30- depth) has been found (Planet Space Sci. 48 (1998) 179). In these layers, Pd, Rh, Ru, Co, Sr, and Y show pronounced anomalies of a factor 4-7 higher than the background value. In the event layers there are also good correlations between the siderophile platinum group elements (Pd, Rh, Ru) and Co, indicators of cosmic material, which imply they might have the same source, i.e. the Tunguska explosive body. The patterns of CI-chondrite-normalized REE in the event layers are much flatter than those in normal peat layers and different from those in the nearby traps. Furthermore, in these layers the patterns of CI-chondrite-normalized PGEs and the element ratios (e.g. C/Pd, C/Rh, and between some siderophile elements) give evidence that the Tunguska explosive body was more likely a comet, although we cannot exclude the possibility that the impactor could be a carbonaceous asteroid. We have estimated the total mass of a solid component of the explosive body up to 10³-10⁶ tons.     

Discovery of probable Tunguska cosmic body material: anomalies of platinum group elements and rare-earth elements in peat near the Explosion Site (1908)

Ten Sphagnum fuscum peat samples collected from different depths of a core including the layer affected by the 1908 Tunguska explosion in the Tunguska area of Central Siberia, Russia, were analyzed by ICP-MS to determine the concentrations of Pd, Rh, Ru, Co, REE, Y, Sr, and Sc. The analytical results indicate that the Pd and Rh concentrations in the event- and lower layers were 14.0–19.9, and 1.23–1.56 ppb, respectively, about 3–9 times and 3 times higher than the background values in the normal layers. In addition, the patterns of CI-chondrite-normalized REE in the event layers were much flatter than in the normal layers, and differed from those in the nearby traps. Hence, it can be inferred from the characteristics of the elemental geochemistry that the explosion was probably associated with extraterrestrial material, and which, most probably, was a small comet core the dust fraction of which was chemically similar to carbonaceous chondrites (CI). In terms of the Pd and REE excess fluxes in the explosion area, it can be estimated that the celestial body that exploded over Tunguska in 1908 weighed more than 10⁶ t, corresponding to a radius of >60 m. If the celestial body was a comet, then its total mass was more than 2×10⁷ t, and it had >160 m radius, and released an energy of >10⁷ t TNT.     

Ecological catastrophe in connection with the impact of the Kaali meteorite about 800–400 B.C. on the island of Saaremaa,Estonia

Abstract— A sequence of peat enriched with impact ejecta (allochthonous minerals and iridium) from Piila bog, 6 km away from the Kaali impact crater (island of Saaremaa, Estonia), was examined using pollen, radiocarbon, loss‐on‐ignition, and x‐ray diffraction analyses to date and assess the environmental effect of the impact. The vegetation in the surroundings of the Piila bog before the Kaali impact was a fen surrounded by forest in natural conditions. Significant changes occur in pollen accumulation and composition of pollen in the depth interval 170–178 cm, which contains above background values of iridium (up to 0.53 ppb). Two samples from the basal silt layer inside the main crater at Kaali contain 0.8 ppb of iridium, showing that iridium was present in the impact ejecta. The impact explosion swept the surroundings clean of forest shown by the threefold decrease in the total pollen influx (especially tree pollen influx), increase in influx and diversity of herb taxa, and the relative dominance of pine. Increased input of mineral matter measured by loss‐on‐ignition and the composition mineral matter (increased input of allochthonous minerals) together with an extensive layer of charcoal and wood stumps in Piila bog at the same depth interval points to an ecological catastrophe, with local impact‐induced wildfires reaching at least 6 km northwest of the epicenter. The disappearance of cereals in the pollen record suggests that farming, cultivation and possibly human habitation in the region ceased for a period of ～100 years. The meteorite explosion at Kaali ranged between the effects of Hiroshima and Tunguska. The age of the Kaali impact event is placed between 800–100 B.C. based on radiocarbon dating of the peat enriched with impact ejecta in the Piila bog.     

Determination of the height of the “meteoric explosion”

When cosmic bodies of asteroidal and cometary origin, with a size from 20 to approximately 100 m, enter dense atmospheric layers, they are destroyed with a large probability under the action of aerodynamic forces and decelerated with the transfer of their energy to the air at heights from 20–30 to several kilometers. The forming shock wave reaches the Earth’s surface and can cause considerable damage at great distances from the entry path similar to the action of a high-altitude explosion. We have performed a numerical simulation of the disruption (with allowance for evaporation of fragments) and deceleration of meteoroids having the aforesaid dimensions and entering the Earth’s atmosphere at different angles and determined the height of the equivalent explosion point generating the same shock wave as the fall of a cosmic body with the given parameters. It turns out that this height does not depend on the velocity of the body and is approximately equal to the height at which this velocity is reduced by half. The obtained results were successfully approximated by a simple analytical formula allowing one to easily determine the height of an equivalent explosion depending on the dimensions of the body, its density, and angle of entry into the atmosphere. A comparison of the obtained results with well-known approximate analytical (pancake) models is presented and an application of the obtained formula to specific events, in particular, to the fall of the Chelyabinsk meteorite on February 15, 2013, and Tunguska event of 1908, is discussed.     

A multitracer study of peat profiles from Tunguska, Siberia

Two peat columns from Tunguska (Siberia) were analysed for pollen, spores, charcoal, trace elements and γ-emitters in order to identify the fingerprints of the impact of a still unidentified cosmic body (TCB), which occurred in the summer of 1908, and the level of environmental pollution in a background area of central Siberia. Peat layers were subject to non-destructive γ-ray spectrometry to derive radiochronology by the excess ²¹⁰Pb method. The age-to-depth relationship was crosschecked by using both 1963 horizon of ¹³⁷Cs associated to maximum global fallout deposition and palynological data profiles. Vertical distributions of trace elements in the peat columns were obtained by PIXE multielemental analysis allowing determination of the levels of environmental contamination in a background region of the Siberian taiga.The association of heavy metals such as Ni, Co and Cu in the profiles suggests the connection of the area with mining and metal smelting activity in the north of the region through atmospheric circulation. As concerns global scale contamination, the inventory of the artificial radionuclide ¹³⁷Cs (4.6 kBq m^− 2) shows a value typical of remote slightly contaminated areas resulting from global scale redistribution of radioactive fallout from Cold War nuclear weapon testing. The atmospheric inventory of the natural radionuclide ²¹⁰Pb, for which a mean annual flux of 200 Bq m^− 2 yr^− 1 has been calculated, is typical of continental regions.The influence of Tunguska Cosmic Body in the peat is recognizable by a large discontinuity in the palynological profile of the peat monolith at a depth coinciding with the 1908 layer as determined by the ²¹⁰Pb technique, showing a large peak of total pollen counting attributed to the impact of the shockwave on the area in which huge tree stands were destroyed. Following the event, tree pollen concentration decreases abruptly showing the temporary inception of a mire environment with an increase of Sphagnum spore concentrations. Results of elemental analysis so far available do not show anomalies in the concentration profiles at depths coinciding with the Tunguska event layer indicating the need for pre-concentration technique enabling the detection of element associations typical of extraterrestrial materials.     

On the problem of the Tunguska meteorite material

The approximate composition of the Tunguska meteorite remnants obtained by averaging the results of several measurements is presented. It is pointed out that the matter of the cosmic-body remnants was enriched with alkaline and alkaline-earth elements. The composition of the meteorite matter was extremely heterogeneous. The upper limit of the density of the Tunguska cosmic body has been estimated at 2.8 g/cm³. It is suggested that, due to interaction with the Earth’s atmosphere, the cosmic body disintegrated into fragments from 10^?7 to 10^?3 m in size, with the majority of the matter being ejected to the upper atmospheric layers. Calculations of the rate and the time of the sedimentation of particles in the atmosphere have shown that the change in atmosphere transparency is controlled by particles larger than 10^?5 m in radius.     

Evidence for a very high carbon/iridium ratio in the Tunguska impactor

Abstract— We have measured excess Ir and depletion of ¹⁴C, two independent indicators of cosmic material, in peat cores from the central Tunguska impact site. Both Ir and ¹⁴C show pronounced anomalies in the same stratigraphical depth interval. We have estimated an integral deposition of nonradioactive cosmogenic C of 6.8 ± 1.0 mg C cm^?2, and an integrated Ir deposition of 5.9 ± 1.2 pg Ir cm^?2. The very high C/Ir ratio and a deduced δ¹³C value of +55 ± 10% relative to V Pee Dee Belemnite (VPDB) of the impactor material found in this study points towards a cometary type impactor, rather than a chondritic or achondritic asteroidal type impactor.     

THE TUNGUSKA EVENT AND THE METEORS WITH TERMINAL FLARES

The comparison of the Tunguska body explosion with the effect of terminal flares of meteors and fireballs leads us to the conclusion that these events are of a similar nature but differ only by their scale. We consider that the dynamics of progressive breaking and evaporation of meteoric bodies during their entry into the terrestrial atmosphere could explain the terminal burst. An extremely porous body model for the Tunguska meteorite was analysed and rejected as unsatisfactory. The realistic values of the initial velocity (～30 km/sec) and of the inclination angle for the Tunguska's trajectory (5–15°) give orbital elements not in contradiction with the cometary origin of the Tunguska body.     

The dual origin of the terrestrial atmosphere

The origin of the terrestrial atmosphere is one of the most puzzling enigmas in the planetary sciences. It is suggested here that two sources contributed to its formation, fractionated nebular gases and accreted cometary volatiles. During terrestrial growth, a transient gas envelope was fractionated from nebular composition. This transient atmosphere was mixed with cometary material. The fractionation stage resulted in a high Xe/Kr ratio, with xenon being more isotopically fractionated than krypton. Comets delivered volatiles having low Xe/Kr ratios and solar isotopic compositions. The resulting atmosphere had a near-solar Xe/Kr ratio, almost unfractionated krypton delivered by comets, and fractionated xenon inherited from the fractionation episode. The dual origin therefore provides an elegant solution to the long-standing “missing xenon” paradox. It is demonstrated that such a model could explain the isotopic and elemental abundances of Ne, Ar, Kr, and Xe in the terrestrial atmosphere.     

An experimental study of the isotopic enrichment in Ar, Kr, and Xe when trapped in water ice

The isotopic enrichment of argon, krypton, and xenon, when trapped in water ice, was studied experimentally. The isotopes were found to be enriched according to their (m1/m2)1/2 ratio. These enrichment factors could be useful for comparison among the uncertain cosmic or solar isotopic ratios, the hopeful in situ cometary ratio, and those in Earth's atmosphere, in the context of cometary delivery of volatiles to Earth.     

Nitrate in the Greenland ice sheet in the years following the 1908 tunguska event

The Tunguska event on 30 June 1908 has been subjected to much speculation within different fields of research. Publication of the results of the 1961 expedition to the Tunguska area (Florensky, 1963) supports that a cometary impact caused the event. Based on this interpretation, calculations of the impactor energy release and explosion height have been reported by Ben-Menahem (1975), and velocity, mass, and density of the impactor by Petrov and Stulov (1975). Park (1978) and Turco et al., 1981, Turco et al., 1982, used these numbers to calculate a production of ca. 30 × 10⁶ tons of NO during atmospheric transit. This paper presents a high-resolution study of nitrate concentration in the Greenland ice sheet in ca. 10 years covering the Tunguska event. No signs of excess nitrate are found in three ice cores from two different sites in Greenland in the years following the Tunguska event. By comparing these results with results for other aerosols generally found in the ice, the lack of excess NO₃^? following the Tunguska event can be interpreted as indicating that the impactor nitrate production calculated by Park (1978) and Turco et al., 1981, Turco et al., 1982 are 1–2 orders of magnitude too high. To explain this it is suggested, from other lines of reasoning, that the impactor density determined by Petrov and Stulov (1975) probably is too low.     

The nature of the Tunguska meteorite

Abstract— Arguments in favor of the cometary origin of the Tunguska meteorite are adduced along with reasons against the asteroidal hypothesis. A critical analysis is given for the hypotheses by Sekanina (1983) and Chyba et al. (1993). On the basis of the azimuth and inclination of the trajectory of the Tunguska body with plausible values of the geocentric velocity, the semimajor axis of the orbit and its inclination to the ecliptic plane are calculated for this body. It is noted that the theory of the disintegration of large bodies in the atmosphere put forward by Chyba et al. (1993) is crude. Applying more accurate theories (Grigoryan, 1979; Hills and Goda, 1993) as well as taking into account the realistic shape of the body yield for the cometary body lower disruption heights than obtained by Chyba et al. Numerical simulations carried out by Svettsov et al. agree well with the cometary hypothesis and the analytical calculations based on Grigoryan's theory. The asteroidal hypothesis is shown not to be tenable: the complete lack of stony fragments in the region of the catastrophe, cosmochemical data (in particular, the results of an isotope analysis), and some other information contradict this hypothesis. It is shown that stony fragments that would have originated in the explosive disruption of the Tunguska body would not be vaporized by the radiation of the vapor cloud nor as a result of their fall to the Earth's surface.     

A NanoSIMS and Auger Nanoprobe investigation of an isotopically primitive interplanetary dust particle from the 55P/Tempel‐Tuttle targeted stratospheric dust collector

Abstract– An IDP nicknamed Andric, from a stratospheric dust collector targeted to collect dust from comet 55P/Tempel‐Tuttle, contains five distinct presolar silicate and/or oxide grains in 14 ultramicrotome slices analyzed, for an estimated abundance of approximately 700 ppm in this IDP. Three of the grains are ¹⁷O‐enriched and probably formed in low‐mass red giant or asymptotic giant branch (AGB) stars; the other two grains exhibit ¹⁸O enrichments and may have a supernova origin. Carbon and N isotopic analyses show that Andric also exhibits significant variations in its N isotopic composition, with numerous discrete ¹⁵N‐rich hotspots and more diffuse regions that are also isotopically anomalous. Three ¹⁵N‐rich hotspots also have statistically significant ¹³C enrichments. Auger elemental analysis shows that these isotopically anomalous areas consist largely of carbonaceous matter and that the anomalies may be hosted by a variety of components. In addition, there is evidence for dilution of the isotopically heavy components with an isotopically normal endmember; this may have occurred either as a result of extraterrestrial alteration or during atmospheric entry. Isotopically primitive IDPs such as Andric share many characteristics with primitive meteorites such as the CR chondrites, which also contain isotopically anomalous carbonaceous matter and abundant presolar silicate and oxide grains. Although comets are one likely source for the origin of primitive IDPs, the presence of similar characteristics in meteorites thought to come from the asteroid belt suggests that other origins are also possible. Indeed the distinction between cometary and asteroidal sources is somewhat blurred by recent observations of icy comet‐like planetesimals in the outer asteroid belt.     

Connection between micrometeorites and Wild 2 particles: From Antarctic snow to cometary ices

Abstract— We discuss the relationship between large cosmic dust that represents the main source of extraterrestrial matter presently accreted by the Earth and samples from comet 81P/Wild 2 returned by the Stardust mission in January 2006. Prior examinations of the Stardust samples have shown that Wild 2 cometary dust particles contain a large diversity of components, formed at various heliocentric distances. These analyses suggest large‐scale radial mixing mechanism(s) in the early solar nebula and the existence of a continuum between primitive asteroidal and cometary matter. The recent collection of CONCORDIA Antarctic micrometeorites recovered from ultra‐clean snow close to Dome C provides the most unbiased collection of large cosmic dust available for analyses in the laboratory. Many similarities can be found between Antarctic micrometeorites and Wild 2 samples, in terms of chemical, mineralogical, and isotopic compositions, and in the structure and composition of their carbonaceous matter. Cosmic dust in the form of CONCORDIA Antarctic micrometeorites and primitive IDPs are preferred samples to study the asteroid‐comet continuum.     

Noble gas space exposure ages of individual interplanetary dust particles

Abstract— The He, Ne, and Ar compositions of 32 individual interplanetary dust particles (IDPs) were measured using low‐blank laser probe gas extraction. These measurements reveal definitive evidence of space exposure. The Ne and Ar isotopic compositions in the IDPs are primarily a mixture between solar wind (SW) and an isotopically heavier component dubbed “fractionated solar” (FS), which could be implantation‐fractionated solar wind or a distinct component of the solar corpuscular radiation previously identified as solar energetic particles (SEP). Space exposure ages based on the Ar content of individual IDPs are estimated for a subset of the grains that appear to have escaped significant volatile losses during atmosphere entry. Although model‐dependent, most of the particles in this subset have ages that are roughly consistent with origin in the asteroid belt. A short (<1000 years) space exposure age is inferred for one particle, which is suggestive of cometary origin. Among the subset of grains that show some evidence for relatively high atmospheric entry heating, two possess elevated ²¹Ne/²²Ne ratios generated by extended exposure to solar and galactic cosmic rays. The inferred cosmic ray exposure ages of these particles exceeds 10⁷ years, which tends to rule out origin in the asteroid belt. A favorable possibility is that these ²¹Ne‐rich IDPs previously resided on a relatively stable regolith of an Edgeworth‐Kuiper belt or Oort cloud body and were introduced into the inner solar system by cometary activity. These results demonstrate the utility of noble gas measurements in constraining models for the origins of interplanetary dust particles.     

Searching for the Parent of the Tunguska Cosmic Body

We present the results of an extensive study of the Tunguska Cosmic Body (TCB) origin on dynamical grounds. To identify the TCB parent, or a plausible candidate, we applied the well-known concept of dynamical similarity whereby we have compared the geocentric and heliocentric dynamical parameters of a selected set of the Near Earth Objects (NEOs) and TCB particles. First, we made use the idea of Kresak by comparing geocentric coordinates of the TCB radiant with those of the NEOs. Second, we studied the long-term dynamical evolution of all NEOs and TCB particles searching for similarities between their heliocentric orbits. As a general result, we observed many more similar cases and a different pattern of the high orbital similarity among the TCB particles and the asteroid orbits than we did for comets.     

Minicomets in the Solar system and in the Earth’s atmosphere and related phenomena

We consider the history of discovery and justify the existence in the Solar system of a new class of bodies—minicomets, i.e., bodies of cometary nature and composition but of low mass. Two classes of minicomets are distinguished: icy ones similar to the Tunguska meteorite, and snow ones, which break up at high altitudes.     

A Jupiter fragmented comet: Cause of the K/T boundary record

The extended period of mass extinctions around the K/T boundary correlating with extraterrestrial amino acids in the sediment record constitutes strong evidence of a cometary cause. The input of extraterrestrial matter over 10⁵ yr supports the hypothesis of a giant comet, fragmented into subcomets on close encounter with Jupiter, and subsequently perturbed into Earth-crossing orbits. Copious amounts of dust were emitted via this and possibly successive fragmenting encounters, and via normal cometary evaporation. The dynamics of dust from the disintegrating comet fragments favours retention in Earth-crossing orbits of the sub-micron fraction of organic composition. The shroud of dust accreted in the Earth's upper atmosphere varied with time and imposed climatic stresses that caused species extinctions over 10⁵ yr. While the iridium peak in the sediments coincides with the Chicxulub crater impactor, other iridium detail suggests that some of the impactor material was reinjected into space and in part re-accreted by Earth from the interplanetary orbits.