Dhofar 081: A new lunar highland meteorite

Abstract— The lunar meteorite Dhofar 081, found as a single fragment of 174 g in the Dhofar region of Oman, is a shocked feldspathic fragmental highland breccia dominated by anorthosite‐rich lithic and mineral clasts embedded into a fine‐grained mostly shock melted clastic matrix. Major mineral phases in the bulk rock are Ca‐rich plagioclase (An_96.5–99.5), pyroxene (FS_21.9–46.2Wo_3.0–41.4), and olivine (Fa_29.3–47.8); accessory phases include Fe‐Ni metal, ilmenite, and Ti‐Cr‐rich spinel. Dhofar 081 contains subordinate crystalline fragments of large anorthosites, intersertal impact‐melt rocks, microporphyritic impact‐melt breccias, dark fine‐grained impact‐melt breccias, large cataclastic feldspars, and irregularly shaped brown glass clasts. Mafic components are rare and no genuine regolith components were found in the sections studied. Minerals in Dhofar 081 show homogeneously distributed shock features: intergranular recrystallization, strong fracturing and mosaicism in feldspar as well as a high density of mostly irregular fractures in pyroxene and olivine. Localized impact melting caused by one or several impacts led to a strong lithification. Based on these effects an equilibration shock pressure of about 15–20 GPa is estimated for the strongest shock event in Dhofar 081. Devitrification of the “glassy” material in the rock indicates thermal annealing after shock melting suggesting that the 15–20 GPa shock event predated the ejection event. According to the concentrations of implanted solar noble gases Dhofar 081 represents a polymict clastic breccia deposit with possibly a minor regolith component. A similar noble gas record of Dhofar 081 and MacAlpine Hills 88104/05 suggests the possibility of a source crater pairing of both meteorites. As indicated by noble gas measurements pairing of Dhofar 081 with the other lunar meteorites found in Oman, Dhofar 025 and Dhofar 026, is unlikely.     

Comment on: “New” lunar meteorites: Impact melt and regolith breccias and large‐scale heterogeneities of the upper lunar crust,by P. H. Warren,F. Ulff‐Møller,and G. W. Kallemeyn

Abstract We described lunar meteorite Dhofar 026 (Cohen et al. 2004) and interpreted this rock as a strongly shocked granulitic breccia (or fragmental breccia consisting almost entirely of granulitic‐breccia clasts) that was partially melted by post‐shock heating. Warren et al. (2005) objected to many aspects of our interpretation: they were uncertain whether or not the bulk rock had been shocked; they disputed our identification of the precursor as granulitic breccia; and they suggested that mafic, igneous‐textured globules within the breccia, which we proposed were melted by post‐shock heating, are clasts with relict textures. The major evidence for shock of the bulk rock is the fact that the plagioclase in the lithologic domains that make up 80–90% of the rock is devitrified maskelynite. The major evidence for a granulitic‐breccia precursor is the texture of the olivine‐plagioclase domain that constitutes 40—45% of the rock; Warren et al. apparently overlooked or ignored this lithology. Textures of the mafic, igneous‐textured globules, and especially of the vesicles they contain, demonstrate that these bodies were melted and crystallized in situ. Warren et al. suggested that the rock might have originally been a regolith breccia, but the textural homogeneity of the rock and the absence of solar wind—derived noble gases preclude a regolith‐breccia precursor. Warren et al. classified the rock as an impact‐melt breccia, but they did not identify any fraction that was impact melt.     

The regolith portion of the lunar meteorite Sayh al Uhaymir 169

Abstract— –Sayh al Uhaymir (SaU) 169 is a composite lunar meteorite from Oman that consists of polymict regolith breccia (8.44 ppm Th), adhering to impact‐melt breccia (IMB; 32.7 ppm Th). In this contribution we consider the regolith breccia portion of SaU 169, and demonstrate that it is composed of two generations representing two formation stages, labeled II and III. The regolith breccia also contains the following clasts: Ti‐poor to Ti‐rich basalts, gabbros to granulites, and incorporated regolith breccias. The average SaU 169 regolith breccia bulk composition lies within the range of Apollo 12 and 14 soil and regolith breccias, with the closest correspondence being with that of Apollo 14, but Sc contents indicate a higher portion of mare basalts. This is supported by relations between Sm‐Al₂O₃, FeO‐Cr₂O₃‐TiO₂, Sm/Eu and Th‐K₂O. The composition can best be modeled as a mixture of high‐K KREEP, mare basalt and norite/troctolite, consistent with the rareness of anorthositic rocks. The largest KREEP breccia clast in the regolith is identical in its chemical composition and total REE content to the incompatible trace‐element (ITE)‐ rich high‐K KREEP rocks of the Apollo 14 landing site, pointing to a similar source. In contrast to Apollo 14 soil, SaU 169 IMB and SaU 169 KREEP breccia clast, the SaU 169 regolith is not depleted in K/Th, indicating a low contribution of high‐Th IMB such as the SaU 169 main lithology in the regolith. The data presented here indicate the SaU 169 regolith breccia is from the lunar front side, and has a strong Procellarum KREEP Terrane signature.     

Petrography and geochemistry of lunar meteorites Dhofar 1673, 1983, and 1984

The Dhofar 1673, Dhofar 1983, and Dhofar 1984 meteorites are three lunar regolith breccias classified based on their petrography, mineralogy, oxygen isotopes, and bulk chemistry. All three meteorites are dominated by feldspathic lithic clasts; however, impact melt rock clasts and spherules are also found in each meteorite. The bulk chemistry of these samples is similar to other feldspathic highland meteorites with the Al₂O₃ content only slightly lower than average. Within the lithic clasts, the Mg # of mafic phases versus the anorthite content of feldspars is similar to other highland meteorites and is found to plot intermediate of the ferroan‐anorthositic suite and magnesian suite. The samples lack any KREEPy signature and have only minor indications of a mare basalt component, suggesting that the source region of all three meteorites would have been distal from the Procellarum KREEP Terrane and could have possibly been the Feldspathic Highland Terrane. All three meteorites were found within 500 m of each other in the Dhofar region of Oman. This, together with their similar petrography, stable isotope chemistry, and geochemistry indicates the possibility of a pairing.     

Multiple lithic clasts in lunar breccia Northwest Africa 7948 and implication for the lithologic components of lunar crust

This study presents the petrography, mineralogy, and bulk composition of lunar regolith breccia meteorite Northwest Africa (NWA) 7948. We identify a range of lunar lithologies including basaltic clasts (very low-titanium and low-titanium basalts), feldspathic lithologies (ferroan anorthosite, magnesian-suite rock, and alkali suite), granulites, impact melt breccias (including crystalline impact melt breccias, clast-bearing impact melt breccias, and glassy melt breccias), as well as regolith components (volcanic glass and impact glass). A compositionally unusual metal-rich clast was also identified, which may represent an impact melt lithology sourced from a unique Mg-suite parent rock. NWA 7948 has a mingled bulk rock composition (Al₂O₃ = 21.6 wt% and FeO = 9.4 wt%) and relatively low concentrations of incompatible trace elements (e.g., Th = 1.07 ppm and Sm = 2.99 ppm) compared with Apollo regolith breccias. Comparing the bulk composition of the meteorite with remotely sensed geochemical data sets suggests that the sample was derived from a region of the lunar surface distal from the nearside Th-rich Procellarum KREEP Terrane. Our investigations suggest that it may have been ejected from a nearside highlands-mare boundary (e.g., around Mare Crisium or Orientale) or a cryptomare region (e.g., Schickard-Schiller or Mare smythii) or a farside highlands-mare boundary (e.g., Mare Australe, Apollo basin in the South Pole–Aitken basin). The distinctive mineralogical and geochemical features of NWA 7948 suggest that the meteorite may represent lunar material that has not been reported before, and indicate that the lunar highlands exhibit wide geological diversity.     

Petrography,mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300

Abstract— We report here the petrography, mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300 (SaU 300). SaU 300 is dominated by a fine‐grained crystalline matrix surrounding mineral fragments (plagioclase, pyroxene, olivine, and ilmenite) and lithic clasts (mainly feldspathic to noritic). Mare basalt and KREEPy rocks are absent. Glass melt veins and impact melts are present, indicating that the rock has been subjected to a second impact event. FeNi metal and troilite grains were observed in the matrix. Major element concentrations of SaU 300 (Al₂O₃ 21.6 wt% and FeO 8.16 wt%) are very similar to those of two basalt‐bearing feldspathic regolith breccias: Calcalong Creek and Yamato (Y‐) 983885. However, the rare earth element (REE) abundances and pattern of SaU 300 resemble the patterns of feldspathic highlands meteorites (e.g., Queen Alexandra Range (QUE) 93069 and Dar al Gani (DaG) 400), and the average lunar highlands crust. It has a relatively LREE‐enriched (7 to 10 x CI) pattern with a positive Eu anomaly (?11 x CI). Values of Fe/Mn ratios of olivine, pyroxene, and the bulk sample are essentially consistent with a lunar origin. SaU 300 also contains high siderophile abundances with a chondritic Ni/Ir ratio. SaU 300 has experienced moderate terrestrial weathering as its bulk Sr concentration is elevated compared to other lunar meteorites and Apollo and Luna samples. Mineral chemistry and trace element abundances of SaU 300 fall within the ranges of lunar feldspathic meteorites and FAN rocks. SaU 300 is a feldspathic impact‐melt breccia predominantly composed of feldspathic highlands rocks with a small amount of mafic component. With a bulk Mg# of 0.67, it is the most mafic of the feldspathic meteorites and represents a lunar surface composition distinct from any other known lunar meteorites. On the basis of its low Th concentration (0.46 ppm) and its lack of KREEPy and mare basaltic components, the source region of SaU 300 could have been within a highland terrain, a great distance from the Imbrium impact basin, probably on the far side of the Moon.     

Geochemistry and 40Ar‐39Ar geochronology of impact‐melt clasts in feldspathic lunar meteorites: Implications for lunar bombardment history

Abstract— We studied 42 impact‐melt clasts from lunar feldspathic regolith breccias MacAlpine Hills (MAC) 88105, Queen Alexandra Range (QUE) 93069, Dar al Gani (DaG) 262, and DaG 400 for texture, chemical composition, and/or chronology. Although the textures are similar to the impactmelt clasts identified in mafic Apollo and Luna samples, the meteorite clasts are chemically distinct from them, having lower Fe, Ti, K, and P, thus representing previously unsampled impacts. The ⁴⁰Ar‐³⁹Ar ages on 31 of the impact melts, the first ages on impact‐melt samples from outside the region of the Apollo and Luna sampling sites, range from ～4 to ～2.5 Ga. We interpret these samples to have been created in at least six, and possibly nine or more, different impact events. One inferred impact event may be consistent with the Apollo impact‐melt rock age cluster at 3.9 Ga, but the meteorite impact‐melt clasts with this age are different in chemistry from the Apollo samples, suggesting that the mechanism responsible for the 3.9 Ga peak in lunar impact‐melt clast ages is a lunar‐wide phenomenon. No meteorite impact melts have ages more than 1s? older than 4.0 Ga. This observation is consistent with, but does not require, a lunar cataclysm.     

Lunar meteorite regolith breccias: An in situ study of impact melt composition using LA‐ICP‐MS with implications for the composition of the lunar crust

Dar al Gani (DaG) 400, Meteorite Hills (MET) 01210, Pecora Escarpment (PCA) 02007, and MacAlpine Hills (MAC) 88104/88105 are lunar regolith breccia meteorites that provide sampling of the lunar surface from regions of the Moon that were not visited by the US Apollo or Soviet Luna sample return missions. They contain a heterogeneous clast population from a range of typical lunar lithologies. DaG 400, PCA 02007, and MAC 88104/88105 are primarily feldspathic in nature, and MET 01210 is composed of mare basalt material mixed with a lesser amount of feldspathic material. Here we present a compositional study of the impact melt and impact melt breccia clast population (i.e., clasts that were generated in impact cratering melting processes) within these meteorites using in situ electron microprobe and LA‐ICP‐MS techniques. Results show that all of the meteorites are dominated by impact lithologies that are relatively ferroan (Mg#_<70), have high Sc/Sm ratios (typically >10), and have low incompatible trace element (ITE) concentrations (i.e., typically <3.2 ppm Sm, <1.5 ppm Th). Feldspathic impact melt in DaG 400, PCA 02007, and MAC 88104/05 are similar in composition to that estimated composition for upper feldspathic lunar crust ( Korotev et al. 2003 ). However, these melt types are more mafic (i.e., less Eu, less Sr, more Sc) than feldspathic impact melts returned by the Apollo 16 mission (e.g., the group 3 and 4 varieties). Mafic impact melt clasts are common in MET 01210 and less common in PCA 02007 and MAC 88104/05. We show that unlike the Apollo mafic impact melt groups ( Jolliff 1998 ), these meteorite impact melts were not formed from melting large amounts of KREEP‐rich (typically >10 ppm Sm), High Magnesium Suite (typically >70 Mg#) or High Alkali Suite (high ITEs, Sc/Sm ratios <2) target rocks. Instead the meteorite mafic melts are more ferroan, KREEP‐poor and Sc‐rich, and represent mixing between feldspathic lithologies and low‐Ti or very low‐Ti (VLT) basalts. As PCA 02007 and MAC 88104/05 were likely sourced from the Outer‐Feldspathic Highlands Terrane our findings suggest that these predominantly feldspathic regions commonly contain a VLT to low‐Ti basalt contribution.     

Lunar regolith breccia Dhofar 287B: A record of lunar volcanism

Abstract— Dhofar 287 (Dho 287), a recently found lunar meteorite, consists in large part (95%) of low‐Ti mare basalt (Dho 287A) and a minor, attached portion (?5%) of regolith breccia (Dho 287B). The present study is directed mainly at the breccia portion of this meteorite. This breccia consists of a variety of lithic clasts and mineral fragments set in a fine‐grained matrix and minor impact melt. The majority of clasts and minerals appear to have been mainly derived from the low‐Ti basalt suite, similar to that of Dho 287A. Very low‐Ti (VLT) basalts are a minor lithology of the breccia. These are significantly lower in Mg# and slightly higher in Ti compared to Luna 24 and Apollo 17 VLT basalts. Picritic glasses constitute another minor component of the breccia and are compositionally similar to Apollo 15 green glasses. Dho 287B also contains abundant fragments of Mg‐rich pyroxene and anorthite‐rich plagioclase grains that are absent in the lithic clasts. Such fragments appear to have been derived from a coarse‐grained, Mg#‐rich, Na‐poor lithology. A KREEP component is apparent in chemistry, but no highlands lithologies were identified. The Dho 287 basaltic lithologies cannot be explained by near‐surface fractionation of a single parental magma. Instead, magma compositions are represented by a picritic glass; a low‐Ti, Na‐poor glass; and a low‐Ti, Na‐enriched source (similar to the Dho 287A parental melt). Compositional differences among parent melts could reflect inhomogeneity of the lunar mantle. Alternatively, the low‐Ti, Na‐poor, and Dho 287A parent melts could be of hybrid compositions, resulting from assimilation of KREEP by picritic magma. Thus, the Dho 287B breccia contains lithologies from multiple magmatic eruptions, which differed in composition, formational conditions, and cooling histories. Based on this study, the Dho 287 is inferred to have been ejected from a region located distal to highlands terrains, possibly from the western limb of the lunar nearside, dominated by mare basalts and KREEP‐rich lithologies.     

Lunar meteorite Queen Alexandra Range 93069: A lunar highland regolith breccia with very low abundances of mafic components

Abstract— Lunar meteorite QUE 93069 found in Antarctica is a mature, anorthitic regolith breccia with highland affinities that was ejected from the Moon <0.3 Ma ago. The frequency distribution of mineral and lithic clasts gives information about the nature of the regolith and subregolith basement near the ejection site as well as about the abundances of rock types shocked to different degrees prior to the breccia formation. Thin section QUE 93069,37 consists of 67.5 vol% fine-grained (<～130 μm) constituents and 32.5 vol% mineral and lithic clasts and an impact melt vein. The most abundant types of these clasts are intragranularly recrystallized anorthosites and plagioclases (together 26.3 vol%) and feldspathic fine-grained to microporphyritic crystalline melt breccias (21.9 vol%). Mafic crystalline melt breccias are extremely rare (1.3 vol%). Granulitic lithologies are 10.4 vol%, recrystallized feldspathic melt breccias are 15.0 vol%, and glasses are 3.5 vol%. The impact melt vein cutting across the entire thin section was probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Lunar meteorite QUE 93069 has a higher abundance of clear glass, occurring within melt spherules, glassy fragments, and an impact melt vein than lunar meteorites ALHA81005, Y-791197, Y-82192/3, Y-86032, or MAC 88104/5. The high abundance of melt spherules indicates that this lunar meteorite contains the highest content of typical regolith components. Mafic crystalline melt breccias are much rarer in QUE 93069 than in all other lunar highland regolith breccias. The extremely low abundance of mafic components may constrain possible areas of the Moon, from which the breccia was derived. The source area of QUE 93069 must be a highland terrain lacking significant mafic impact melts or mare components.     

Anorthositic lunar regolith breccia Dhofar 1769—Clear indications for repeated mixing of impact melt lithologies

The lunar regolith breccia Dhofar 1769, which was found in 2012 as a single 125 g piece in the Zufar desert area of Oman, contains a relatively large, dark-colored impact melt breccia embedded in a fine-grained clastic matrix. The internal texture of the fragment indicates the repeated melt breccia formation on the lunar surface, their repeated brecciation, and mixing in second, third, and fourth generations of brecciated rock types. The chemical and mineralogical data reveal the incorporation of a feldspar-rich subophitic crystalline melt within a feldspar-rich microporphyritic crystalline melt breccia. This lithic paragenesis itself is embedded within a mafic, crystalline melt breccia. The entire breccia with the three different impact melts has been finally incorporated into the whole rock breccia. The three impact melts are mixtures of different source rocks and impact projectiles, based on the obtained minor and trace element compositions (in particular of Ni and the rare earth elements [REE]) of the impact melt lithologies. For all processes of impact melt formation, additional steps of their brecciation and re-lithification require a minimum number of seven impact processes.     

Petrology,chemistry, and isotopic compositions of the lunar highland regolith breccia Dar al Gani 262

Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm³and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio ⁴⁰Ar/³⁶Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived.     

On the relationship between the Apollo 16 ancient regolith breccias and feldspathic fragmental breccias,and the composition of the prebasin crust in the Central Highlands of the Moon

Abstract Two types of texturally and compositionally similar breccias that consist largely of fragmental debris from meteorite impacts occur at the Apollo 16 lunar site: Feldspathic fragmental breccias (FFBs) and ancient regolith breccias (ARBs). Both types of breccia are composed of a suite of mostly feldspathic components derived from the early crust of the Moon and mafic impact-melt breccias produced during the time of basin formation. The ARBs also contain components, such as agglutinates and glass spherules, indicating that the material of which they are composed occurred at the surface of the Moon as fine-grained regolith prior to lithification of the breccias. These components are absent from the FFBs, suggesting that the FFBs might be the protolith of the ARBs. However, several compositional differences exist between the two types of breccia, making any simple genetic relationship implausible. First, clasts of mafic impact-melt breccia occurring in the FFBs are of a different composition than those in the ARBs. Also the feldspathic “prebasin” components of the FFBs have a lower average Mg/Fe ratio than the corresponding components of the ARBs; the average composition of the plagioclase in the FFBs is more sodic than that of the ARBs; and there are differences in relative abundances of rare earth elements. The two breccia types also have different provenances: the FFBs occur primarily in ejecta from North Ray crater and presumably derive from the Descartes Formation, while the ARBs are restricted to the Cayley plains. Together these observations suggest that although some type of fragmental breccia may have been a precursor to the ARBs, the FFBs of North Ray crater are not a significant component of the ARBs and, by inference, the Cayley plains. The average compositions of the prebasin components of the two types of fragmental breccia are generally similar to the composition of the feldspathic lunar meteorites. With 30–31% Al₂O₃, however, they are slightly richer in plagioclase than the most feldspathic lunar meteorites (～29% Al₂O₃), implying that the crust of the early central nearside of the Moon contained a higher abundance of highly feldspathic anorthosite than typical lunar highlands, as inferred from the lunar meteorites. The ancient regolith breccias, as well as the current surface regolith of the Cayley plains, are more mafic than (1) prebasin regoliths in the Central Highlands and (2) regions of highlands presently distant from nearside basins because they contain a high abundance (～30%) of mafic impact-melt breccias produced during the time of basin formation that is absent from other regoliths.     

Geochemistry and petrology of lunar meteorite Queen Alexandra Range 94281, a mixed mare and highland regolith breccia,with special emphasis on very-low-titanium mafic components

Abstract— Queen Alexandra Range (QUE) 94281, a lunar meteorite recently discovered in Antarctica, is a glassy-matrix, clast-rich regolith breccia containing a mixture of mafic, volcanic-glass and gabbroic constituents and a diverse set of highland constituents. In thin section, the clast assemblage is dominated by coarse mineral debris from a shallow intrusive or hypabyssal setting, or from deep within a thick mare flow. Abundant coarse-grained pyroxene clasts have fine-scale exsolution lamellae and compositions similar to pyroxenes of known lunar very-low-Ti (VLT) basalts and other lunar meteorites of basaltic composition. Pyroxene compositions follow Fe-enrichment extending to hedenbergite, which is associated with fayalite and cristobalite, indicating slow cooling. We refer to the protolith of the crystalline VLT component as VLT gabbro. Fragments of pyroclastic glasses that have high Fe and low Ti concentrations, similar to the pyroclastic green glasses known from Apollo samples, are common. Lithic clasts include abundant subrounded, glassy to cryptocrystalline, aluminous (～17–30 wt% Al₂O₃) KREEP-poor melt breccias of highland origin and a variety of other feldspathic impactites. On the basis of composition of our subsamples, QUE 94281 consists of ～54 wt% mafic or “mare” components and 46 wt% feldspathic or “highland” components. The bulk composition of QUE 94281 is similar to that of Yamato (Y) 793274, but QUE 94281 has slightly greater concentrations of some siderophile elements and slightly lower concentrations of those elements contributed mainly by mafic constituents. Differences in siderophile element concentrations are consistent with longer surface exposure of QUE 94281. Minor differences in trace element variations of subsamples of the two meteorites suggest subtle differences in the composition of their highland constituents. Nonetheless, the overall similarity of compositions supports the possibility that they were ejected from the same source region on the Moon. The crystalline VLT component of QUE 94281 differs from those known from Apollo 17 and Luna 24 VLT lithologies and from that of basaltic breccia Elephant Moraine (EET) 87521. The VLT-gabbro component and the ferroan VLT volcanic glasses in QUE 94281 have compositions that may be petrogenetically related by derivation from a common picritic parent composition, represented by an ultramafic glass found in QUE 94281.     

Petrography,mineralogy, and trace element geochemistry of lunar meteorite Dhofar 1180

Abstract— Here we report the petrography, mineralogy, and trace element geochemistry of the Dhofar 1180 lunar meteorite. Dhofar 1180 is predominantly composed of fine‐grained matrix with abundant mineral fragments and a few lithic and glassy clasts. Lithic clasts show a variety of textures including cataclastic, gabbroic, granulitic, ophitic/subophitic, and microporphyritic. Both feldspathic and mafic lithic clasts are present. Most feldspathic lithic clasts have a strong affinity to ferroan anorthositic suite rocks and one to magnesian suite rocks. Mafic lithic clasts are moderately to extremely Fe‐rich. The Ti/[Ti+Cr]‐Fe/[Fe+Mg] compositional trend of pyroxenes in mafic lithic clasts is consistent with that of low‐Ti mare basalts. Glasses display a wide chemical variation from mafic to feldspathic. Some glasses are very similar to those from Apollo 16 soils. KREEP components are essentially absent in Dhofar 1180. One glassy clast is rich in K, REE and P, but its Mg/[Mg+Fe] is very low (0.25). It is probably a last‐stage differentiation product of mare basalt. Molar Fe/Mn ratios of both olivine and pyroxene are essentially consistent with a lunar origin. Dhofar 1180 has a LREE‐enriched (La 18 × CI, Sm 14 × CI) pattern with a small positive Eu anomaly (Eu 15 × CI). Th concentration is 0.7 ppm in Dhofar 1180. Petrography, mineralogy, and trace element geochemistry of Dhofar 1180 are different from those of other lunar meteorites, indicating that Dhofar 1180 represents a unique mingled lunar breccia derived from an area on the lunar nearside but far away from the center of the Imbrium Basin.     

The lithologic diversity of the Moon recorded in lunar meteorites Northwest Africa 7611 and 10480

Northwest Africa (NWA) 7611/10480 are lunar regolith breccia meteorites, composed of mineral fragments and various clasts including mare basalts, volcanic glasses, gabbroic lithologies, and a diverse variety of highland materials (ferroan anorthosite, Mg-suite, magnesian anorthosite, and alkali suite rocks) as well as different subvarieties of impact melt breccia. The Apollo two-component mixing model calculation reveals that the NWA 7611 source region contains 58 wt% mare materials and 42 wt% highland components, but the estimated mare components in NWA 10480 have a higher abundance (66 wt%). The predominantly very low-Ti (VLT) composition in both fine-grained basaltic and coarse-grained gabbroic lithologies indicates a provenance associated with a thick lava flow or a single magmatic system. The co-occurrence of zoning patterns and fine-scale exsolution lamellae in pyroxene debris supports a cryptomare deposit as the best candidate source. Phosphate Pb–Pb ages in matrix fragments, impact melt breccia, and basaltic clast indicate that the breccia NWA 7611 records geological events spanning approximately 4305–3769 Ma, which is consistent with the ages of ancient lunar VLT volcanism and the products of basin-forming impacts on the lunar nearside. The youngest reset age at ~3.2 Ga is potentially related to the strong shock lithification process of breccia NWA 7611. Moreover, the similar petrology, texture, geochemistry, cosmic-ray exposure data, and crystallization ages support that basaltic component in Yamato (Y)-793274, and Queen Alexandra Range (QUE) 94281, NWA 4884, and NWA 7611 clan came from the same basalt flow.     

Mineralogy,petrology, and shock history of lunar meteorite Sayh al Uhaymir 300: A crystalline impact‐melt breccia

Abstract— Sayh al Uhaymir (SaU) 300 comprises a microcrystalline igneous matrix (grain size <10 μm), dominated by plagioclase, pyroxene, and olivine. Pyroxene geothermometry indicates that the matrix crystallized at ?1100 °C. The matrix encloses mineral and lithic clasts that record the effects of variable levels of shock. Mineral clasts include plagioclase, low‐ and high‐Ca pyroxene, pigeonite, and olivine. Minor amounts of ilmenite, FeNi metal, chromite, and a silica phase are also present. A variety of lithic clast types are observed, including glassy impact melts, impact‐melt breccias, and metamorphosed impact melts. One clast of granulitic breccia was also noted. A lunar origin for SaU 300 is supported by the composition of the plagioclase (average An₉₅), the high Cr content in olivine, the lack of hydrous phases, and the Fe/Mn ratio of mafic minerals. Both matrix and clasts have been locally overprinted by shock veins and melt pockets. SaU 300 has previously been described as an anorthositic regolith breccia with basaltic components and a granulitic matrix, but we here interpret it to be a polymict crystalline impact‐melt breccia with an olivine‐rich anorthositic norite bulk composition. The varying shock states of the mineral and lithic clasts suggest that they were shocked to between 5–28 GPa (shock stages S1–S2) by impact events in target rocks prior to their inclusion in the matrix. Formation of the igneous matrix requires a minimum shock pressure of 60 GPa (shock stage >S4). The association of maskelynite with melt pockets and shock veins indicates a subsequent, local 28–45 GPa (shock stage S2–S3) excursion, which was probably responsible for lofting the sample from the lunar surface. Subsequent fracturing is attributed to atmospheric entry and probable breakup of the parent meteor.     

The case for an Imbrium origin of the Apollo thorium-rich impact-melt breccias

Abstract— Mafic, Th-rich impact-melt breccias, most of which are identified with the composition known as low-K Fra Mauro (LKFM), are the most common rock type in the nonmare regoliths of the Apollo lunar landing sites. The origin of mafic impact-melt breccias bears on many lunar problems: the nature of the late meteoroid bombardment (cataclysm); the spatial distribution of KREEP, both near the surface and at depth; the ages of the major basins; and the composition of the early crust of the nearside lunar highlands. Thus, it is crucial that the origin of mafic impact-melt breccias be accurately understood. Because of both intra- and intersite differences in compositions of mafic impact-melt breccia samples, apparent differences in crystallization age, and differences in siderophile-element ratios, previous studies have argued that either (1) most mafic impact-melt breccias are the products of several large craters local to the site at which they were found but that some are of basin origin or that (2) they are all from the Imbrium (Apollos 14 and 15), Nectaris (Apollo 16), and Serenitatis (Apollo 17) basins. Here, we reconsider the hypothesis that virtually all of the Th-rich, mafic impact-melt breccias from the Apollo missions are products of the Imbrium impact. Ejecta deposit modeling based on modern crater scaling indicates that the Imbrium event produced ejecta deposits that average hundreds of meters thick or more at all Apollo highland sites, which is thicker than some previous estimates. Substantial amounts of Imbrium ejecta should have been sampled at every Apollo highland site. We suggest that the mafic impact-melt breccias may be the principal form of those ejecta. The Imbrium projectile impacted into Th-rich material that we regard as part of a unique, mafic, lunar geochemical province we call the High-Th Oval Region. Based on the surface distribution of Th, only basins within the High-Th Oval Region excavated Th-rich material; the Th concentrations of the highlands as observed by the Apollo orbiting γ-ray experiments are consistent with the estimates from ejecta modeling. Of the younger basin-forming impacts, only Imbrium was large enough to produce the copious amount of melt required by the ubiquitous presence of mafic impact-melt breccias in the Apollo-sampled regolith. The High-Th Oval Region still may have been molten or hot at shallow depths ～4 Ga ago when the Imbrium projectile struck. We reason that compositional heterogeneity of ejected melt breccia is to be expected under these circumstances. We argue that siderophile-element “fingerprints” of mafic impact-melt breccias are not inconsistent with production of all common types by a single projectile. We suggest that the narrow range of ages of 3.7–4.0 Ga for all successfully dated mafic impact-melt breccias may reflect a single event whose age is difficult to measure precisely, rather than a number of discrete impact events closely spaced in time, such that reported age variations among mafic impact-melt breccias reflect the ability to measure ⁴⁰Ar/³⁹Ar ages with greater precision than the accuracy with which measured portions of mafic impact-melt breccias have recorded the time of their formation.     

“New” lunar meteorites: Implications for composition of the global lunar surface,lunar crust,and the bulk Moon

Abstract— New data for lunar meteorites and a synthesis of literature data have significant implications for the interpretation of global Th data and for the Moon's bulk composition. As presently calibrated (Prettyman et al. 2002), the Lunar Prospector gamma‐ray data imply that the average global surface Th = 1.58 μg/g. However, that calibration yields implausibly high concentrations for the three most Th‐poor documented sampling sites, it extrapolates to a nonzero Lunar Prospector Th, ?0.7 μg/g, at zero sample Th, and it results in a misfit toward too‐high Th when compared with the global regolith Th spectrum as constrained using mainly lunaite regolith breccias. Another problem is manifested by Th versus K systematics. Ground truth data plot consistently to the high‐Th/K side of the Prospector data trend, offset by a factor of 1.2. A new calibration is proposed that represents a compromise between the Th levels indicated by ground truth constraints and the Prettyman et al. (2002) calibration. Conservatively assuming that the Th versus K issue is mostly a K problem, the average global surface Th is estimated to be ?1.35 μg/g. The Moon's remarkable global asymmetry in KREEP abundance is even more pronounced than previously supposed. The surface Th concentration ratio between the hemisphere antipodal to the Procellarum basin and the hemisphere centered on Procellarum is reduced to 0.24 in the new calibration. This extreme disparity is most simply interpreted as a consequence of Procellarum's origin at a time when the Moon still contained at least a thin residual layer of a global magma ocean. Allowing for diminution of Th with depth, the extrapolated bulk crustal Th is ?0.73 μg/g. Further extrapolation to bulk Moon Th yields ?0.07 μg/g, which is nearly identical to the consensus estimate for Earth's primitive mantle. Assuming chondritic proportionality among refractory lithophile elements implies Al₂O₃ of approximately 3.8 wt%. The Moon's bulk mantle mg ratio is only weakly constrained by seismic and mare‐basaltic data. KREEP‐and mare‐free lunaite regolith samples, other thoroughly polymict lunar meteorites, and a few KREEP‐free Apollo highland samples manifest a remarkable anticorrelation on a plot of Al₂O₃ versus mg. This trend implies that an important component of the Moon is highly magnesian. The bulk Moon is inferred to have an Earth‐like oxide mg ratio of ?87–88 mol%. The close resemblance between the bulk Moon and Earth's primitive mantle extends to moderately volatile elements, most clearly Mn. Unless major proportions of Cr and V are sequestered into deep mantle spinel, remarkably Earth‐like depletions (versus chondrites) are also inferred for bulk Moon Cr and V.     

Impact melting of lunar meteorite Dhofar 458: Evidence from polycrystalline texture and decomposition of zircon

Abstract– Dhofar 458 is a lunar meteorite consisting mainly of olivine‐plagioclase intergrowths, pyroxene‐plagioclase intergrowths, and plagioclase fragments. Pyroxene‐plagioclase globules are also common. In this study, we report the discovery of a polycrystalline zircon in this lunar meteorite. The polycrystalline zircon contains small vesicles and rounded baddeleyite grains at its margin. The polycrystalline and porous texture of the zircon indicates high‐pressure shock‐induced melting and degassing. Baddeleyite grains are derived from decomposition of zircon under high postshock temperature. The shock features in zircon indicates that the shock pressure in Dhofar 458 was greater than approximately 60 GPa and the postshock temperature greater than approximately 1700 °C. The polycrystalline and degassing texture and decomposition zircon also strongly indicates that Dhofar 458 is a clast‐rich impact melt rock. During this shock event, most components were melted and grains of mafic minerals are interstitial to lath‐like plagioclase grains. Large fragments of olivine and chromite also formed polycrystalline texture at margins and chemically reequilibrated with surrounding melts. We suggest that pyroxene‐plagioclase globules could be remains of melted target clasts, whereas vesicles may form during shock‐induced degassing of the rock. The U‐Pb isotopic data plot on a well‐defined discordant line, yielding the age of the zircon of 3434 ± 15 Ma (2σ). This age is interpreted as the time of the impact event that melted Dhofar 458 and caused decomposition and recrystallization of this zircon in Dhofar 458, which reset this zircon’s U‐Pb age.