Geochemical Features and Tectonic Setting of Greenstones from Kunimiyama, Northern Chichibu Belt, Central Shikoku, Japan

Abstract. We report whole‐rock chemical data for the greenstones from the Kunimiyama area in the Northern Chichibu Belt and their implications on the tectonic setting of these rocks. The Kunimiyama greenstones are associated with stratiform fer‐romanganese deposits or bedded cherts in the northern part of the study area, but are closely associated with a thick limestone block or bedded cherts in the southern part. The constituent minerals of greenstones are albitized plagioclase, clinopy‐roxene, chlorite, calcite, epidote, pumpellyite, prehnite, quartz, celadonite, sericite and opaque minerals such as iron oxyhy‐droxide and hematite. These mineral assemblages, epidote + pumpellyite + chlorite and chlorite + pumpellyite + prehnite, suggest that the metamorphic grade of greenstones from the Kunimiyama area is prehnite‐pumpellyite facies. The whole‐rock chemical compositions of greenstones associated with ferromanganese deposits are generally similar to those of normal mid‐ocean ridge basalt (N‐MORB). In contrast, the chemical compositions of the greenstones associated with the limestone block are comparable to those of ocean island alkaline basalt. Greenstones associated with bedded cherts are of enriched MORB and ocean island basalt, as well as N‐MORB origins, suggesting they probably formed as a result of plume‐related MOR volcanism in the Panthalassa Ocean in Early Permian and by tectonic mixing of ocean island basalts with oceanic ridge crustal fragments during accretion/subduction processes. These geological and geochemical lines of evidence suggest that the Kunimiyama greenstones are allochthonous blocks of accreted oceanic crust and seamounts. The ferromanganese deposits are frequently accompanied by reddish greenstones. Compared to common greenish greenstones, the reddish greenstones are characterized by high MnO and rare earth element contents and distinct negative Ce anomalies, implying a slight contribution of hydro thermal component forming the ferromanganese deposits.     

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Geochemistry and Origin of Ananai Stratiform Manganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Major and trace element contents are reported for Permian manganese ore and associated greenstone from the Ananai manganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The manganese deposit occurs between greenstone and red chert, or among red chert beds. Chemical compositions of manganese ore are characterized by enrichments in Mn, Ca, P, Co, Ni, Zn, Sr and Ba, and negative Ce and positive Eu anomalies relative to post-Archean average Australian Shale (PAAS). Geochemical features of the manganese ore are similar to those of modern submarine hydrother-mal manganese deposits from volcanic arc or hotspot setting. In addition, geochemical characteristics of the greenstone closely associated with the Ananai manganese deposit are analogous to those of with-in plate alkaline basalt (WPA). Consequently, the Ananai manganese deposit was most likely formed by hydrothermal activity related to hotspot volcanism in the Panthalassa Ocean during the Middle Permian. This is the first report documenting the terrestrially-exposed manganese deposit that was a submarine precipitate at hotspot.     

北祁连西段石鸡河地区火山岩地球化学特征及其动力学意义

石鸡河一带是近年新发现的北祁连山多金属成矿带, 气侯和自然条件恶劣, 研究程度很低.该区地层岩性为阳起石岩、角岩和细碧岩; 岩石地球化学和Nd同位素数据显示岩石来源于亏损地幔, 具有N-MORB洋脊玄武岩特征; Sr同位素特征显示地层Sr同位素组成的改变是蚀变引起, 而不是由地壳物质加入引起的.Sm-Nd等时线年龄为481±20 Ma.提出了石鸡河地区地层形成于早奥陶世, 成岩环境为北祁连洋扩张环境, 而非区域资料上显示的残留海盆封闭、大陆碰撞造山环境.      

Chemical Composition of Ores from the Takara Volcanogenic Massive Sulfide Deposit, Central Japan

Abstract. The Takara volcanogenic massive sulfide (VMS) deposit occurs in Miocene formation of the Misaka Mountain, the South Fossa Magna region, central Japan. The tectonic setting of the Misaka Mountain is reconstructed to be a part of the paleo Izu-Ogasawara arc which collided with the Honshu arc and to form accreted body in the present position. The Takara deposit, therefore, is considered to have formed in the paleo Izu-Ogasawara arc.
The ores from the Takara deposit are classified into pyrite-type ore, chalcopyrite-type ore, and sphalerite-type ore on the basis of chemical composition and their mineral assemblages. Some pyrite-type ores are characterized by their high Au content. The Au content is hardly recognized in the chalcopyrite-type and sphalerite-type ores.
The ores from the Takara deposit have intermediate bulk chemical composition between those from the Besshi-type deposits and the Kuroko-type deposits that are two representative VMS deposits. However, the bulk chemical composition is closer to that from the Kuroko-type deposits. And moreover, chemical composition of tetrahedrite-tennantite series minerals (tetrahedrite) is similar to that from the Kuroko-type deposits. The bulk chemical composition (Cu, Zn, Co, Pb, and As contents) of ores is affected by the chemical composition of volcanic rocks associated with VMS deposits.     

西藏雅鲁藏布江缝合带西段东波蛇绿岩的构造背景特征

西藏东波蛇绿岩位于雅鲁藏布江缝合带西段,由地幔橄榄岩、辉石岩和辉长岩等组成。地幔橄榄岩主要为方辉橄榄岩、纯橄岩和少量二辉橄榄岩。岩体的边界出露玄武岩和硅质岩等。地幔橄榄岩中有少量辉石岩和辉长岩的脉岩,宽约1 m,走向北西,与岩体的构造线方向基本一致。各岩相岩石地球化学研究结果表明,东波蛇绿岩的岩相存在较大的差异,玄武岩具有与洋岛玄武岩(OIB)相似的地球化学特征,而地幔橄榄岩中辉石岩、辉长岩脉与洋中脊玄武岩(MORB)相似,形成于洋中脊环境,并受后期俯冲流体作用的改造。东波岩体中二辉橄榄岩具有与深海地幔橄榄岩较一致的轻稀土亏损特征,而方辉橄榄岩和纯橄岩的地球化学特征显示出岩体形成于MOR环境,后受到SSZ环境的改造。东波蛇绿岩的岩石地球化学特征显示其洋中脊叠加洋岛的构造背景。     

武当山十堰地区二叠纪E-MORB型玄武岩识别及构造意义

大比例尺构造—岩相填图和测试分析研究显示南秦岭武当山并非统一前寒武纪基底组成,在十堰和两郧断裂之间的黄龙—方滩及丹江口银洞山等地区识别和厘定出一套中生代混杂岩带,开展混杂岩带内物质组成和成因研究对正确认识武当山造山作用和区域构造演化有重要意义。本文重点对武当山十堰黄龙—方滩地区混杂岩带内玄武岩块体岩石成因及时代进行研究,岩石地球化学显示玄武岩块体为亚碱性拉斑玄武岩系列,具有中等Ti、Zr、Hf、Nd含量、弱轻稀土富集重稀土亏损的E-MORB(Enriched Mid-ocean ridge basalt,富集型洋中脊玄武岩)特征,其岩浆为尖晶石二辉橄榄岩低压、高度部分熔融形成,源区可能受富集地幔或俯冲作用等影响导致富集高场强不相容元素;锆石U-Pb测年表明其为中二叠世火山作用产物;区域地质特征及岩石成因研究共同指示该套E-MORB形成于洋中脊或附近海山环境。综上,武当山十堰地区中—晚二叠世存在洋盆,该成果为理解十堰黄龙—方滩混杂岩带成因机制和正确认识南秦岭显生宙构造属性提供了基础资料。     

Geochemistry of Pyrite from the Gangcha Gold Deposit, West Qinling Orogen, China: Implications for Ore Genesis

The Gangcha gold deposit was discovered in 2011 in the Xiahe-Hezuo region, West Qinling Orogen, China. Five types of pyrite have been identified in the ore according to the detailed mineral paragenetic studies. Geochemical data are presented for type I pyrite (py1) rim-core zonation and for the different types of pyrite based on in-situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and electron probe microanalysis (EPMA). The results show that pyrites are characterized with heterogeneous Au concentrations, which indicate that Au occurs mainly as micro- or nano-particle native inclusions. Time-resolved depth profiles demonstrate that As, Co and Ni occur as solid solutions in pyrite, whereas Cu, Pb, Zn and Ag occur mainly as inclusions. Trace element concentrations differ between rims and cores in py1, and the differences also exist within different pyrite types. These differences indicate complex chemical evolution of the ore-forming fluids, and the overall geology, geochronology, and stable isotope and pyrite data suggest that the ore-forming fluids were closely linked to magmatic activity during the Triassic Period in West Qinling orogenic belt.     

中条山铜矿峪铜矿区火山岩的地球化学特征及构造背景

对铜矿峪火山岩进行常量元素、微量元素及稀土元素研究表明,SiO2质量分数为47.22%～76.00%,平均66.21%,Al2O3含量为11.03%～20.03%,属铝饱和类型。通过常量元素投点图分析,属一种高钾系列火山岩。稀土元素特征表明,火山岩的源岩浆来源于上地慢。在微量元素的球粒陨石标准化图上,表现为不相容元素Rb、K、Ba、Th的高度富集,同时,具有Sr、Tb和Nb、Ti的亏损,其总体配分型式类似于板内拉斑玄武岩。     

REE Geochemistry of Fluorite from the Maoniuping REE Deposit, Sichuan Province, China： Implications for the Source of Ore-forming Fluids

Fluorite is one of the main gangue minerals in the Maoniuping REE deposit,Sichuan Province,China.Fluorite with different colors occurs not only within various orebodies,but also in wallrocks of the orefield.Based on REE geochemistry,fluorite in the orefield can be classified as the LREE-rich,LREE-flat and LREE-depleted types.The three types of fluorite formed at different stages from the same hydrothermal fluid source,with the LREE-rich fluorite forming at the relatively early stage,the LREE-flat fluorite in the middle,and the LREE-depleted fluorite at the latest stage.Various lines of evidence demonstrate that the variation of the REE contents of fluorite shows no relation to the color.The mineralization of the Maoniuping REE deposit is associated spatially and temporally with carbonatite-syenite magmatism and the ore-forming fluids are mainly derived from carbonatite and syenite melts.     

西准噶尔玛依拉山组志留纪玄武岩的地球化学特征及构造意义

西准噶尔地区中-上志留统玛依拉山组主要分布于玛依拉山一带,以玛依勒蛇绿岩的围岩产出,两者为断层接触,主要组成为灰绿-暗灰绿色凝灰质粉-细砂岩,砂岩和砂砾岩组合,夹硅质岩和玄武岩。对玄武岩进行详细的岩石地球化学研究表明,SiO2含量中等(47.1%～53.92%),高Fe2O3T(12.54%～17.82%)、Al2O3(13.3%～15.7%)、Na2O(3.84%～8.02%),低TiO2(0.45%～1.48%)、MgO(3.28%～5.77%,Mg#=27.01～41.96)、K2O(0.36%～0.7%),全碱K2O+Na2O含量为4.4%～8.39%,属于亚碱性拉斑玄武岩系列。稀土元素总量较低(∑REE=27.16×10-6～54.41×10-6),轻、重稀土分馏较为明显((La/Yb)N=1.53～2.74),无明显Eu异常(Eu/Eu*=0.96～1.16),稀土配分模式类似于E-MORB。相对富集LILE(如Rb、Ba、Th和K),亏损HFSE(如Zr、Ti),明显的Nb和Ta负异常,具有岛弧玄武岩的地球化学特征。综合研究认为玛依拉山组玄武岩形成于俯冲带上的弧后盆地环境,与玛依拉山蛇绿岩的形成环境不同,其岩浆来源于尖晶石二辉橄榄岩2%～10%的部分熔融,并有少量俯冲流体的参与。结合前人研究资料,认为西准噶尔在志留纪-石炭纪处在洋内弧演化阶段。     

西藏仲巴县天宫尼勒矽卡岩型铜金矿床锆石U-Pb年代学和岩石地球化学特征: 对成因及其成矿构造背景的指示

天宫尼勒铜金矿床位于冈底斯成矿带北部,是与花岗闪长岩关系密切的矽卡岩型矿床。花岗闪长岩锆石ICP-MSU-Pb年龄加权平均值为102.6±1.8Ma,指示该矿床形成于早白垩世。元素地球化学数据表明,花岗闪长岩具有高Al2O3,富Na2O,低TiO2等特点,属于准铝质、钙碱性岩石系列,微量元素富集大离子亲石元素(LILE),亏损高场强元素(HFSE)和重稀土元素,显示Nb和Ta的负异常,具有明显的岛弧型岩石的地球化学特征,岩石成因可能与班公湖-怒江洋壳板片俯冲所诱发的岩浆活动有关。结合区域构造演化,天宫尼勒铜金矿床形成于班公湖-怒江洋向南(即冈底斯地块)俯冲碰撞闭合之前的岛弧环境。     

Radiolarian Age of Red Chert from the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. The radiolarian age of red chert from the Kunimiyama area of the Northern Chichibu Belt was determined in order to constrain the depositional age of the Kunimiyama deposit that is among the largest ferromanganese deposits in Japan. Pseudoalbaillella cf scalprata Holdsworth and Jones, Pseudoalbaillella cf longicornis Ishiga and Imoto and Pseudoalbaillella sp. belonging to the Ps. lomentaria Zone are found in the red chert, indicating an age of middle Early Permian (middle Wolfcampian). The red chert occurs immediately above the ferromanganese deposit, and the boundary between them is gradual. Based on their mode of occurrence and geochemical features, it is most likely that radiolarian chert and ferromanganese precipitate accumulated simultaneously to produce red chert during the waning stage of submarine hydrothermal activity that was responsible for the Kunimiyama deposit. Consequently, the age of Kunimiyama stratiform ferromanganese deposit is constrained as middle Early Permian (middle Wolfcampian).     

中天山天湖东铁钼矿含矿片麻状花岗岩年代学、地球化学和锆石Hf同位素-对于中天山早古生代构造演化的启示

以中天山东段的天湖东铁钼矿含矿花岗岩为例,在LA-ICP-MS锆石U-Pb年代学测定其为早古生代花岗岩（（445.3±4.6） Ma）基础上,通过岩相学、地球化学及锆石原位Hf同位素组成等多方面研究,探讨该岩体的成岩作用及其构造背景。天湖东含矿片麻状花岗岩的主要矿物为斜长石、石英、钾长石,并含少量黑云母和角闪石等。全岩地球化学分析结果表明,该片麻状花岗岩高硅、弱富铝、富钙、富钠而贫钾,ASI值为0.68~0.82,属于准铝质钙碱性花岗岩,总体上富集大离子亲石元素（LILE）Rb、Ba等和轻稀土元素La、Ce、Nd等,而亏损高场强元素Nb、Ta、Ti、Yb等,轻重稀土分异明显,轻稀土分异较为明显,而重稀土分异不明显,表现出典型岛弧岩浆岩的地球化学特征。锆石的ε_Hf(445 Ma)值为-6.31~-1.77,二阶段Hf模式年龄（T_DM2）为1.538~1.825 Ga,表明该花岗岩的源区主要为壳源物质。综合分析上述资料,认为天湖东铁钼矿片麻状花岗岩是由俯冲过程中地壳物质重熔的产物。结合前人的研究和本课题组的新近研究成果认为,在早古生代时,中天山为岩浆弧构造环境,形成一系列的钙碱性岩浆岩,而该岩浆弧的形成可能是受到介于吐哈陆块和塔里木板块之间的古天山大洋在早古生代时期向南俯冲而形成的。     

鄂尔多斯盆地东胜地区直罗组砂岩的地球化学特征与物源分析

沉积岩物源分析对揭示盆地砂体展布、物质组成、储集层性质及砂岩型铀矿床铀源等科学问题具有重要的意义。对取自鄂尔多斯盆地东北部8个钻井中的中侏罗统直罗组砂岩进行了详细的岩石学和地球化学研究,试图鉴别岩石的源区和形成的构造环境。研究表明,砂岩以中粗粒杂砂岩为主,其w(SiO₂)值及w(Al₂O₃)/w(SiO₂)值中等到较高,w(K₂O)值相对较高,Fe₂O₃、MgO、TiO₂含量较低,暗示碎屑物质的富长英质、贫镁铁质特征。Nb、Ta、Ti、P等不活动元素的强烈亏损和K、Rb、Sr、Ba等LILE的富集,共同指示源区具有明显的俯冲带的特征;而w(TFe₂O₃+MgO)-w(TiO₂)、w(TFe₂O₃+MgO)-w(Al₂O₃)/w(SiO₂)、w(Th)-w(Sc)-w(Zr)/10、w(Th)-w(Co)-w(Zr)/10等判别特征则表明砂岩源区岩石可能形成于大陆弧-活动大陆边缘环境。而且,在球粒陨石标准化分配模式中,LREE强烈富集,HREE无明显分异、有着较平坦的曲线,Eu无异常或表现为弱的正、负异常;在PAAS标准化曲线中,轻重稀土均无明显分异,仅Eu表现为明显正异常。本区直罗组砂岩与华北北缘显生宙闪长岩-花岗闪长岩有着很强的亲缘性。     

青藏高原中部中生代OIB型玄武岩的识别:年代学、地球化学及其构造环境

目前对青藏高中部的蛇绿岩类型、形成环境及其深部地幔源区特征还缺乏很好的约束。在区域地质调查基础上,本文展示了青藏高原中部龙木错—双湖缝合带嘎错玄武岩、班公湖—怒江缝合带多玛、塔仁本玄武岩及那曲盆地西侧中生代玄武岩的单斜辉石Ar-Ar测年、锆石SHRIMP定年和地球化学及Sr,Nd,Pb同位素数据,以约束形成这些玄武岩的时代、构造环境和地幔源区特征。目前的数据表明:1羌塘双湖嘎错枕状玄武岩单斜辉石的中温坪年龄为232.5±2.4Ma,可能指示嘎错玄武岩浆活动发生于中三叠世晚期,班公湖—怒江缝合带多玛枕状玄武岩、塔仁本玄武岩浆活动时代大约在早白垩世中晚期(110Ma左右);2在这些蛇绿混杂岩带中的玄武岩显示OIB而不是MORB型地球化学特征,双湖嘎错玄武岩的地球化学特征介于峨眉山高Ti玄武岩与夏威夷碱性玄武岩之间;中晚三叠世那曲嘎加组玄武岩的地球化学特征非常类似于夏威夷碱性玄武岩;班公湖—怒江缝合带内的早白垩世多玛玄武岩和塔仁本玄武岩的地球化学特征在很大程度上可比于夏威夷碱性玄武岩;3双湖嘎错OIB型玄武岩可能形成于以增生楔为基底的裂谷环境而不是以洋壳为基底的大洋板内环境,那曲嘎加组OIB型玄武岩很可能形成于以弧内—弧前沉积物为基底的陆棚—陆坡环境下的裂谷背景,塔仁本和多玛OIB型玄武岩形成于以洋壳为基底的洋岛环境,这表明班公湖—怒江洋壳在大约110Ma时尚未彻底消亡,可能暗示班公湖—怒江洋盆的关闭时间明显晚于晚侏罗世—早白垩世早期闭合的早期认识;4地球化学指标显示青藏高原中部中生代玄武岩未受到地壳物质或很少受到陆下岩石圈物质改造,一些相对新鲜样品的Nd,Pb组成似乎可以用来代表其地幔源区的成分特点,其高206Pb/204Pb比值(>18.5)指示羌塘双湖中晚三叠世嘎错玄武岩、班公湖—怒江缝合带早白垩世洋岛玄武岩所代表的中生代特提斯地幔很可能不具“Dupal”异常。然而,由于研究程度的限制和缺乏更多的可靠数据,这种观察还需要进一步确认。     

Radiolarian Age of Manganese Ore and Red Chert from the Ananai Stratiform Manganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. We obtain radiolarian fossils such as Follicucullus monacanthus, Pseudoalbaillella aff. globosa, Pseudoalbaillella cf fusiformis , and Pseudoalbaillella spp. belonging to the Pseudoalbaillella globosa and Follicucullus monacanthus Zones from manganese ore and associated red chert of the Ananai stratiform manganese deposit in the Northern Chichibu Belt, central Shikoku. The depositional age of the Ananai ore deposit is constrained as Guadalupian (Middle Permian) that is between 270.6 and 260.4 Ma in the updated geologic time scale.     

西藏浦桑果铜多金属矿床侵入岩的地球化学特征及对构造环境的约束

浦桑果铜多金属矿床是在南木林火山盆地内新近发现的矽卡岩型铜多金属矿床。文章对矿区内的花岗闪长岩、花岗闪长斑岩和闪长玢岩进行了岩石地球化学研究,结果表明:这些岩石的ω(SiO2)介于59.08%～67.28%,ω(Al2O3)为15.38%～16.86%,ω(MgO)为1.52%～4.06%,ω(TFeO)介于1.2%～3.46%,均属钙碱性系列。稀土元素总量为22.0×10-6～148.56×10-6,LaN/YbN比值为17.98～37.57,为轻稀土元素富集。花岗闪长岩、花岗闪长斑岩和闪长玢岩均相对富集Cs、Rb、Sr等大离子亲石元素(LILE),亏损高场强元素(HFSE)Th、U、Nb等,强负铕异常或弱负铕异常,无铈异常或弱铈异常。岩石学、岩石化学、微量元素研究表明,花岗闪长斑岩和闪长玢岩形成于中生代雅鲁藏布新特提斯洋向北部拉萨地体俯冲的岛弧环境,花岗闪长岩形成于青藏高原碰撞后伸展作用环境。     

大别山皇城山银矿区及外围陈棚组火山岩U-Pb年代学、地球化学和成矿构造背景

皇城山银矿床是西大别山地区代表性的浅成低温热液矿床,受陈棚组火山机构的枝叉状裂隙构造控制.目前人们对该矿床成因、成矿时间和构造环境的理解尚不深刻,因此对相关火山岩进行了激光等离子质谱（LA-ICP-MS）锆石U-Pb测年、元素地球化学和Sr-Nd-Hf同位素研究,探讨了其岩石成因和构造属性.结果表明,皇城山矿区陈棚组熔结凝灰岩及外围流纹岩锆石U-Pb年龄分别为133.4±1.5 Ma（MSWD=1.3）和133.1±0.8 Ma（MSWD=0.59）,形成于早白垩世.陈棚组火山岩在较短时间内喷发形成,其喷发时限基本代表了皇城山银矿床形成时间.陈棚组流纹岩具高硅（SiO₂=73.83%~77.38%）、高钾（K₂O=4.65%~9.31%）特征,属于过铝质（A/CNK=1.09~1.31）和高钾钙碱性岩石系列.岩石具轻稀土富集,重稀土平坦,大离子亲石元素相对富集,Ba、Nb、Ta、P、Ti明显负异常和负Eu异常（δEu=0.33~0.88）特点.岩石锶同位素初始比值I_Sr为0.708 220~0.708 741,ε_Nd（t）值为-17.2~-18.5,Nd两阶段模式年龄T_DM2=2.32~2.43 Ga.锆石ε_Hf（t）值范围为-22.3~-26.1,Hf两阶段模式年龄T_DM2=2.29~2.49 Ga.主、微量元素和Sr-Nd-Hf同位素特征共同揭示陈棚组流纹岩为扬子陆壳北缘古老地壳物质重熔演化的产物.结合区域地质特征,陈棚组火山岩及其相关皇城山银矿床形成于大别山早白垩世加厚下地壳拆沉作用初期、挤压向伸展转化环境.      

松辽盆地开鲁坳陷钱家店地区姚家组砂岩地球化学特征及物源和构造背景分析

为了开展钱家店铀矿床砂岩型铀矿的进一步找矿工作,对采集到的上白垩统姚家组19件砂岩样品进行了主、微量和稀土元素分析,并结合前人成果,对姚家组的沉积物源及源岩构造背景进行了探讨。结果表明,姚家组砂岩主要为长石砂岩,矿物成分主要为石英、钾长石和斜长石等;其轻重稀土比为6.96~14.66,均值为10.17;LaN/YbN为7.58~20.95,均值为11.74,说明轻稀土元素相对重稀土元素明显富集,分馏明显。稀土元素配分模式曲线高度一致,也表明姚家组砂岩具有同源性;其ICV值为0.86~2.78,平均值1.34,大部分大于1,表现为未成熟的性质,为初次旋回的沉积物;修正后的CIA均值62.5,暗示源岩经历中等化学风化作用;砂岩碎屑为近源的第一次旋回沉积物,受沉积分选和再循环作用影响不大;姚家组源岩以火山弧物质和大陆上地壳长英质物质为主,源岩主要形成于大陆边缘和大陆岛弧环境;开鲁坳陷形成于早白垩世随着古太平洋板块向欧亚板块俯冲速度的减小而在东北地区出现的北西-南东向拉张构造环境中,并接受盆地西部大兴安岭南段海西期和燕山期岩浆岩、火山岩沉积。