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1.
Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain 总被引:4,自引:0,他引:4
Fadong Li Guoying Pan Changyuan Tang Qiuying Zhang Jingjie Yu 《Environmental Geology》2008,55(5):1109-1122
Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population,
quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess
these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical
evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis
and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed
of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater
was recharged by precipitation and was characterized by Ca–HCO3 type water with depleted δ18O and δD (mean value of −8.8‰ δ18O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex
(Ca–Na–Mg–HCO3–Cl–SO4 type), and heavier δ18O and δD were observed (around −8‰ δ18O). Before the surface water with mean δ18O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion
exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred
water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study
area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ18O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal
end of the fan. The groundwater underwent chemical evolution from Ca–HCO3, Na–HCO3, to Na–SO4. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical
evolution, and groundwater flow paths in the complex alluvial fan aquifer system. 相似文献
2.
The 18O and 2H (HDO) compositions are summarized for sampled springs (n = 81) within the Elwha watershed (≈692 km2) on the northern Olympic Peninsula. Samples, collected during 2001–2009, of springs (n = 158), precipitation (n = 520), streams (n = 176), and firn (n = 3) assisted the determinations for meteoric composition of recharge waters. The local mean water line (LMWL) is defined
as δ2H = 8.2δ18O − 9.3 for the watershed. Recharge history is surmised from groundwater ages ranging from 5 ± 3 years (apparent 85Kr) to 9,490 ± 420 14C cal years BP. About 56% of the springs were recharged over the last 1,000 years while 13% of springs were recharged over
5,000 years ago. Spring HDO values fluctuate between −11.8 to −15.6‰ δ18O and −90.9 to −119.4‰ δ2H. Deuterium excess values predominate around 4–6‰. The HDO proxy records from springs suggest a pronounced paleoclimate shift
in air masses near 5,000 year BP on the Peninsula. 相似文献
3.
4.
Groundwater nitrate contamination and risk assessment in an agricultural area,South Korea 总被引:2,自引:1,他引:1
Jae-Yeol Cheong Se-Yeong Hamm Jeong-Hwan Lee Kwang-Sik Lee Nam-Chil Woo 《Environmental Earth Sciences》2012,66(4):1127-1136
The nitrate of groundwater in the Gimpo agricultural area, South Korea, was characterized by means of nitrate concentration,
nitrogen-isotope analysis, and the risk assessment of nitrogen. The groundwaters belonging to Ca–(Cl + NO3) and Na–(Cl + NO3) types displayed a higher average NO3
− concentration (79.4 mg/L), exceeding the Korean drinking water standard (<44.3 mg/L NO3
−). The relationship between δ18O–NO3
− values and δ15N–NO3
− values revealed that nearly all groundwater samples with δ15N–NO3
− of +7.57 to +13.5‰ were affected by nitrate from manure/sewage as well as microbial nitrification and negligible denitrification.
The risk assessment of nitrate for groundwater in the study area was carried out using the risk-based corrective action model
since it was recognized that there is a necessity of a quantitative assessment of health hazard, as well as a simple estimation
of nitrate concentration. All the groundwaters of higher nitrate concentration than the Korean drinking water standard (<44.3 mg/L NO3
−) belonged to the domain of the hazard index <1, indicating no health hazard by nitrate in groundwater in the study area.
Further, the human exposure to the nitrate-contaminated soil was below the critical limit of non-carcinogenic risk. 相似文献
5.
Hydrochemical characteristics of groundwater in the Zhangye Basin, Northwestern China 总被引:3,自引:0,他引:3
The Zhangye Basin, located in arid northwest China, is an important agricultural and industrial center. In recent years rapid
development has created an increased demand for water, which is increasingly being fulfilled by groundwater abstraction. Detailed
knowledge of the geochemical evolution of groundwater and water quality can enhance understanding of the hydrochemical system,
promoting sustainable development and effective management of groundwater resources. To this end, a hydrochemical investigation
was conducted in the Zhangye Basin. Types of shallow groundwater in the Zhangye Basin were found to be HCO3
−, HCO3
−–SO4
2−, SO4
2−–HCO3
−, SO4
2−–Cl−, Cl−–SO4
2− and Cl− . The deep aquifer groundwater type was found to be HCO3−–SO42− throughout the entire area. Ionic ratio and saturation index calculations suggest that silicate rock weathering and evaporation
deposition are the main processes that determine the ionic composition in the study area. The suitability of the groundwater
for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. In the study
area, the compositions of the stable isotopes δ18O and δD in groundwater samples were found to range from −4.00 to −9.28‰ and from −34.0 to −65.0‰, respectively. These values
indicate that precipitation is the main recharge source for the groundwater system; some local values indicate high levels
of evaporation. Tritium analysis was used to estimate the ages of the different groundwaters; the tritium values of the groundwater
samples varied from 3.13 to 36.62 TU. The age of the groundwater at depths of less than 30 m is about 5–10 years. The age
of the groundwater at depths of 30–50 m is about 10–23 years. The age of the groundwater at depths of 50–100 m is about 12–29 years.
For groundwater samples at depths of greater than 100 m, the renewal time is about 40 years. 相似文献
6.
Hydrochemistry of urban groundwater in Seoul, South Korea: effects of land-use and pollutant recharge 总被引:1,自引:0,他引:1
Byoung-Young Choi Seong-Taek Yun Soon-Young Yu Pyeong-Koo Lee Seong-Sook Park Gi-Tak Chae Bernhard Mayer 《Environmental Geology》2005,48(8):979-990
The ionic and isotopic compositions (δD, δ18O, and 3H) of urban groundwaters have been monitored in Seoul to examine the water quality in relation to land-use. High tritium contents
(6.1–12.0 TU) and the absence of spatial/seasonal change of O–H isotope data indicate that groundwaters are well mixed within
aquifers with recently recharged waters of high contamination susceptibility. Statistical analyses show a spatial variation
of major ions in relation to land-use type. The major ion concentrations tend to increase with anthropogenic contamination,
due to the local pollutants recharge. The TDS concentration appears to be a useful contamination indicator, as it generally
increases by the order of forested green zone (average 151 mg/l), agricultural area, residential area, traffic area, and industrialized
area (average 585 mg/l). With the increased anthropogenic contamination, the groundwater chemistry changes from a Ca–HCO3 type toward a Ca–Cl(+NO3) type. The source and behavior of major ions are discussed and the hydrochemical backgrounds are proposed as the basis of
a groundwater management plan. 相似文献
7.
Hydrogeochemical and isotopic investigation of the Bursa-Oylat thermal waters, Turkey 总被引:1,自引:1,他引:0
Suzan Pasvano?lu 《Environmental Earth Sciences》2011,64(4):1157-1167
The Oylat spa is located 80 km southeast of Bursa and 30 km south of Ineg?l in the Marmara region. With temperature of 40°C
and discharge of 45 l/s, the Oylat main spring is the most important hot water spring of the area. Southeast of the spa the
Forest Management spring has a temperature of 39.4°C and discharge of 2 l/s. The G?z spring 2 km north of the spa, which is
used for therapy of eye disease, and cold waters of the Saadet village springs with an acidic character are the further important
water sources of the area. EC values of Main spring and Forest Management hot spring (750–780 μS/cm) are lower than those
of Saadet and G?z spring waters (2,070–1,280 μS/cm) and ionic abundances are Ca > Na + K > Mg and SO4 > HCO3 > Cl. The Oylat and Sızı springs have low Na and K contents but high Ca and HCO3 concentrations. According to AIH classification, these are Ca–SO4–HCO3 waters. Based on the results of δ18O, 2H and 3H isotope analyses, the thermal waters have a meteoric origin. The meteoric water infiltrates along fractures and faults,
gets heated, and then returns to surface through hydrothermal conduits. Oylat waters do not have high reservoir temperatures.
They are deep, circulating recharge waters from higher enhanced elevations. δ13CDIC values of the Main spring and Forest Management hot spring are −6.31 and −4.45‰, respectively, indicating that δ13C is derived from dissolution of limestones. The neutral pH thermal waters are about +18.7‰ in δ34S while the sulfate in the cold waters is about +17‰ (practically identical to the value for the neutral pH thermal waters).
However, the G?z and Saadet springs (acid sulfate waters) have much lower δ34S values (~+4‰). 相似文献
8.
Groundwater origins and mixing pattern in the multilayer aquifer system of the Gafsa-south mining district: a chemical and isotopic approach 总被引:3,自引:2,他引:1
Younes Hamed Lassaad Dassi Meriem Tarki Riadh Ahmadi Khalid Mehdi Hamed Ben Dhia 《Environmental Earth Sciences》2011,63(6):1355-1368
Major ion geochemistry and environmental isotopes were used to identify the origins and the mineralisation processes of groundwater
flowing within the three aquifer levels of the multilayer system of the Gafsa-south mining district (Southwestern Tunisia).
It has been demonstrated that groundwaters are characterised by a Ca–Mg–SO4 water type. Geochemical pattern is mainly controlled by the dissolution of halite, gypsum and/or anhydrite as well as by
the incongruent dissolution of dolomite. δ18O and δ2H values are much lower than the isotopic signature of regional precipitation and fall close to the meteoric water lines,
indicating that groundwaters have not been significantly affected by evaporation or mineral–water reactions. The distribution
of stable and radiogenic isotopes (δ18O, δ2H, δ13C and 14C) within the aquifer levels suggests that the deep confined aquifer receives a significant modern recharge at higher altitudes,
while, the shallow unconfined aquifer has been mainly recharged under cooler paleoclimatic condition, likely during Late Pleistocene
and Early Holocene humid periods. However, waters from the intermediate confined/unconfined aquifer have composite isotopic
signatures, highlighting that they are derived from a mixture of the two first end-members. 相似文献
9.
Chloride and the environmental isotopes as the indicators of the groundwater recharge in the Gobi Desert,northwest China 总被引:5,自引:0,他引:5
The long term recharge in Gobi Desert from Hexi Corridor to Inner Mongolia Plateau was estimated to be 1 mm year−1 by using the chloride mass balance method from one unsaturated zone profile, which shows that no effective modern recharge
is taking place. A good rainfall database from Zhangye provides definition of the stable isotopic composition of modern rainfall.
The signature of groundwater from the late Pleistocene differs markedly from that of the Holocene, shown clearly by the compositions
of −10.5‰ δ18O as compared with values of −7‰ at the present day. It is apparent that the groundwaters in the Minqin Basin, Ejina Basin
and feeding the lake system of the Badain Jaran are part of a regional flow network related to a wetter past climate as source
of recharge. The recharge source in the past and to a limited extent in the more arid conditions of the present day included
the foothills of the mountains of the Tibetan Plateau. The tritium age determinations accurate to the year are impossible
and of no meaning to groundwater studies. A tritium value in the groundwater means multiple recharge ages in this region. 相似文献
10.
Amor Ben Moussa Sarra Bel Haj Salem Kamel Zouari Vincent Marc Fayçal Jlassi 《Environmental Earth Sciences》2011,62(6):1287-1300
Detailed hydrogeochemical and isotopic data of groundwaters from the Hammamet–Nabeul unconfined aquifer are used to provide
a better understanding of the natural and anthropogenic processes that control the groundwater mineralization as well as the
sources of different groundwater bodies. It has been demonstrated that groundwaters, which show Na–Cl and Ca–SO4–Cl water facies, are mainly influenced by the dissolution of evaporates, the dedolomitization and the cation-exchange process;
and supplementary by anthropogenic process in relation with return flow of irrigation waters. The isotopic signatures permit
to classify the studied groundwaters into two different groups. Non-evaporated groundwaters that are characterized by depleted
δ
18O and δ
2H contents highlighting the importance of modern recharge at higher altitude. Evaporated groundwaters with enriched contents
reflecting the significance infiltration of return flow irrigation waters. Tritium data in the studied groundwaters lend support
to the existence of pre-1950 and post-1960 recharge. Carbon-14 activities in shallow wells that provide evidence to the large
contamination by organic 14C corroborate the recent origin of the groundwaters in the study area. 相似文献
11.
Xin Liu Xianfang Song Yinghua Zhang Jun Xia Xuecheng Zhang Jingjie Yu Di Long Fadong Li Bing Zhang 《Environmental Earth Sciences》2011,63(5):1105-1118
Groundwater is of utmost significance to socio-economic development and ecological recovery for the Loess Plateau. However,
studies regarding the mechanism governing groundwater recharge over this area appear to be inadequate. This study is to examine
the spatio-temporal variations of δ2H and δ18O in precipitation and shallow groundwater. On the basis of this, the mechanisms governing shallow groundwater recharge were
explored. Precipitation and groundwater were sampled monthly from May to October during the period 2004–2006 at 13 sites in
the Chabagou Catchment (187 km2). In the Caopingxigou Experimental Watershed (0.1 km2), meteorological variables were observed and rainfall larger than 5 mm was sampled immediately after each rain event. Across
the area, 90% of the precipitation occurred from May to September primarily in the form of heavy rains or rainstorms with
great spatial variability. There were about 30 localized rains in each year. It was indicated that there existed notable seasonality
and pronounced spatial variability in precipitation isotopic compositions. Contributing factors and indications of isotopic
compositions, as well as their climatic indications such as monsoon intensities and mixing processes of water vapor, were
investigated. The δ2H–δ18O relation of groundwater was found to be δ2H = 3.22 × δ18O − 38.1, deviating from the local meteoric water line δ2H = 7.57 × δ18O + 3.9. The range of δ values in groundwater is shrunken to be 15–21% of that in individual precipitations, and groundwater in the middle reaches
shows a wider range of δ values. Isotopic results showed that groundwater originates from precipitation with hydrogen and oxygen isotopic compositions
being −69 and −9.7‰, respectively, and most groundwater experiences serious evaporation and adequate mixing with old water
during infiltration or percolation in the aerated zone. It was also founded that obvious fluctuations of isotopic compositions
in groundwater mainly appear in the middle reaches especially at sites that are close to valleys, suggesting varying sources
of groundwater from precipitation, precipitation runoff, isotopically enriched surface water and/or lateral recharge of adjacent
groundwater. 相似文献
12.
Hydrochemical evolution and water quality along the groundwater flow path in the Sandıklı plain, Afyon, Turkey 总被引:1,自引:0,他引:1
M. Afşin 《Environmental Geology》1997,31(3-4):221-230
An unconfined aquifer system suggests an open system in the study area. Hydrochemical evolution is related to the flow path
of groundwater. The groundwaters are divided into two hydrochemical facies in the study area, 1) Ca–Mg–HCO3 and 2) Ca–Mg–SO4HCO3. Facies 1 has shallow (young) waters which dominate in recharge areas during rapid flow conditions, whereas facies 2 may
show shallow and mixed waters which dominate intermediate or discharge areas during low flow conditions. Ionic concentrations,
TDS, EC and water quality are related to groundwater residence time and groundwater types. The groundwaters in the plain are
chemically potable and suitable for both domestic and agricultural purposes.
Received: 20 May 1996 · Accepted: 30 July 1996 相似文献
13.
Hydrogeochemistry and dissolved inorganic carbon isotopic composition on karst groundwater in Maolan, southwest China 总被引:1,自引:0,他引:1
The forest ecosystem in the Maolan karst forest, southwest China is the only concentrated, intact, and relatively stable karst
forest ecosystem which has survived in the area at the same latitude in the world, and is a valuable karst forest plant resource
as well. Groundwater samples from Maolan karst forest were collected from wells and springs during summer; and concentrations
of major ions and dissolved inorganic carbon (DIC) isotopic compositions were measured. The pH values range from 7.2 to 8.3
results from the dissolution of carbonate, HCO3
− is the dominant species of DIC in groundwater. Calcium and HCO3
−, followed by Mg2+ and SO4
2− dominate the chemical composition of major ions in the groundwaters. Groundwater samples have δ13C values in the range from −8.1‰ to −16.6‰, which are lower than that of the other karst city groundwaters in the southwest
China. Combining δ13CDIC ratios with measurements of HCO3
− and pH clearly distinguishes the principal processes underlying the geochemical evolution of groundwater in Carboniferous
carbonate aquifers, where processes can be both degradation of organic matters in the soil and the carbonate dissolution. 相似文献
14.
Influence of hydrogeochemical processes on temporal changes in groundwater quality in a part of Nalgonda district, Andhra Pradesh, India 总被引:4,自引:3,他引:1
Geochemical processes that take place in the aquifer have played a major role in spatial and temporal variations of groundwater
quality. This study was carried out with an objective of identifying the hydrogeochemical processes that controls the groundwater
quality in a weathered hard rock aquifer in a part of Nalgonda district, Andhra Pradesh, India. Groundwater samples were collected
from 45 wells once every 2 months from March 2008 to September 2009. Chemical parameters of groundwater such as groundwater
level, EC and pH were measured insitu. The major ion concentrations such as Ca2+, Mg2+, Na+, K+, Cl−, and SO4
2− were analyzed using ion chromatograph. CO3
− and HCO3
− concentration was determined by acid–base titration. The abundance of major cation concentration in groundwater is as Na+ > Ca2+ > Mg2+ > K+ while that of anions is HCO3
− > SO4
2− > Cl− > CO3
−. Ca–HCO3, Na–Cl, Ca–Na–HCO3 and Ca–Mg–Cl are the dominant groundwater types in this area. Relation between temporal variation in groundwater level and
saturation index of minerals reveals the evaporation process. The ion-exchange process controls the concentration of ions
such as calcium, magnesium and sodium. The ionic ratio of Ca/Mg explains the contribution of calcite and dolomite to groundwater.
In general, the geochemical processes and temporal variation of groundwater in this area are influenced by evaporation processes,
ion exchange and dissolution of minerals. 相似文献
15.
Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca–HCO3 (six), Na–Cl (four), and mixed (one). The evolution of water chemistry for Ca–HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na–Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4–53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca–HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na–Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.The online version of the original article can be found at 相似文献
16.
Mixing of shallow and deep groundwater as indicated by the chemistry and age of karstic springs 总被引:1,自引:0,他引:1
Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca–HCO3 (six), Na–Cl (four), and mixed (one). The evolution of water chemistry for Ca–HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na–Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4–53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca–HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na–Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.An erratum to this article can be found at 相似文献
17.
Multiple chemical constituents (nutrients; N, O, H, C stable isotopes; 64 organic wastewater compounds, 16 pharmaceutical
compounds) and microbiological indicators were used to assess the impact on groundwater quality from the land application
of approximately 9.5 million liters per day of treated municipal sewage effluent to a sprayfield in the 960-km2 Ichetucknee Springs basin, northern Florida. Enriched stable isotope signatures (δ18O and δ2H) were found in water from the effluent reservoir and a sprayfield monitoring well (MW-7) due to evaporation; however, groundwater
samples downgradient from the sprayfield have δ18O and δ2H concentrations that represented recharge of meteoric water. Boron and chloride concentrations also were elevated in water
from the sprayfield effluent reservoir and MW-7, but concentrations in groundwater decreased substantially with distance downgradient
to background levels in the springs (about 12 km) and indicated at least a tenfold dilution factor. Nitrate-nitrogen isotope
(δ15N–NO3) values above 10 ‰ in most water samples were indicative of organic nitrogen sources except Blue Hole Spring (δ15N–NO3 = 4.6–4.9 ‰), which indicated an inorganic source of nitrogen (fertilizers). The detection of low concentrations the insect
repellent N,N-diethyl-metatoluamide (DEET), and other organic compounds associated with domestic wastewater in Devil’s Eye Spring indicated
that leakage from a nearby septic tank drainfield likely has occurred. Elevated levels of fecal coliforms and enterococci
were found in Blue Hole Spring during higher flow conditions, which likely resulted from hydraulic connections to upgradient
sinkholes and are consistent with previoius dye-trace studies. Enteroviruses were not detected in the sprayfield effluent
reservoir, but were found in low concentrations in water samples from a downgradient well and Blue Hole Spring during high-flow
conditions indicating a human wastewater source. The Upper Floridan aquifer in the Ichetucknee Springs basin is highly vulnerable
to contamination from multiple anthropogenic sources throughout the springs basin. 相似文献
18.
National scale evaluation of groundwater chemistry in Korea coastal aquifers: evidences of seawater intrusion 总被引:3,自引:2,他引:1
Youngyun Park Jin-Yong Lee Jeong-Hee Kim Sung-Ho Song 《Environmental Earth Sciences》2012,66(3):707-718
Pollution of groundwater by seawater intrusion poses a threat to sustainable agriculture in the coastal areas of Korea. Therefore, seawater intrusion monitoring stations were installed in eastern, western, and southern coastal areas and have been operated since 1998. In this study, groundwater chemistry data obtained from the seawater intrusion monitoring stations during the period from 2007 to 2009 were analyzed and evaluated. Groundwater was classified into fresh (<1,500 μS/cm), brackish (1,500–3,000 μS/cm), and saline (>3,000 μS/cm) according to EC levels. Among groundwater samples (n = 233), 56, 7, and 37% were classified as the fresh, brackish, and saline, respectively. The major dissolved components of the brackish and saline groundwaters were enriched compared with those of the fresh groundwater. The enrichment of Na+ and Cl− was especially noticeable due to seawater intrusion. Thus, the brackish and saline groundwaters were classified as Ca–Cl and Na–Cl types, while the fresh groundwater was classified as Na–HCO3 and Ca–HCO3 types. The groundwater included in the Na–Cl types indicated the effects of seawater mixing. Ca2+, Mg2+, Na+, K+, SO4 2−, and Br− showed good correlations with Cl− of over r = 0.624. Of these components, the strong correlations of Mg2+, SO4 2−, and Br− with Cl− (r ≥ 0.823) indicated a distinct mixing between fresh groundwater and seawater. The Ca/Cl and HCO3/Cl ratios of the groundwaters gradually decreased and approached those of seawater. The Mg/Cl, Na/Cl, K/Cl, SO4/Cl, and Br/Cl ratios of the groundwaters gradually decreased, and were similar to or lower than those of seawater, indicating that Mg2+, Na+, K+, SO4 2−, and Br−, as well as Cl− in the saline groundwater can be enriched by seawater mixing, while Ca2+ and HCO3 − are mainly released by weathering processes. The influence of seawater intrusion was evaluated using threshold values of Cl− and Br−, which were estimated as 80.5 and 0.54 mg/L, respectively. According to these criteria, 41–50% of the groundwaters were affected by seawater mixing. 相似文献
19.
Galip Yuce 《Environmental Geology》2007,51(5):857-868
The aim of this study was to determine geochemical properties of groundwater and thermal water in the Misli Basin and to assess
thermal water intrusion into shallow groundwater due to over-extraction. According to isotope and hydrochemical analyses results,
sampled waters can be divided into three groups: cold, thermal, and mixed waters. Only a few waters reach water–rock chemical
equilibrium. Thermal waters in the area are characterized by Na+–Cl−–HCO3−, while the cold waters by CaHCO3 facies. On the basis of isotope results, thermal waters in the Misli basin are meteoric origin. In particular, δ18O and δ2H values of shallow groundwater vary from −10.2 to −12.2‰ and −71.2 to −82‰, while those of thermal waters range from −7.8
to −10.1‰ and from −67 to −74‰, respectively. The tritium values of shallow groundwater having short circulation as young
waters coming from wells that range from 30 to 70 m in depth vary from 10 to 14 TU. The average tritium activity of groundwater
in depths more than 100 m is 1.59 ± 1.16, which indicates long circulation. The rapid infiltration of the precipitation, the
recycling of the evaporated irrigation water, the influence of thermal fluids and the heterogeneity of the aquifer make it
difficult to determine groundwater quality changes in the Misli Basin. Obtained results show that further lowering of the
groundwater table by over-consumption will cause further intrusion of thermal water which resulted in high mineral content
into the fresh groundwater aquifer. Because of this phenomenon, the concentrations of some chemical components which impairs
water quality in terms of irrigation purposes in shallow groundwaters, such as Na+, B, and Cl−, are highy probably expected to increase in time. 相似文献
20.
Geochemical mixing models were used to decipher the dominant source of freshwater (rainfall, canal discharge, or groundwater
discharge) to Biscayne Bay, an estuary in south Florida. Discrete samples of precipitation, canal water, groundwater, and
bay surface water were collected monthly for 2 years and analyzed for salinity, stable isotopes of oxygen and hydrogen, and
Sr2+/Ca2+ concentrations. These geochemical tracers were used in three separate mixing models and then combined to trace the magnitude
and timing of the freshwater inputs to the estuary. Fresh groundwater had an isotopic signature (δ
18O = −2.66‰, δD −7.60‰) similar to rainfall (δ
18O = −2.86‰, δD = −4.78‰). Canal water had a heavy isotopic signature (δ
18O = −0.46‰, δD = −2.48‰) due to evaporation. This made it possible to use stable isotopes of oxygen and hydrogen to separate canal water
from precipitation and groundwater as a source of freshwater into the bay. A second model using Sr2+/Ca2+ ratios was developed to discern fresh groundwater inputs from precipitation inputs. Groundwater had a Sr2+/Ca2+ ratio of 0.07, while precipitation had a dissimilar ratio of 0.89. When combined, these models showed a freshwater input
ratio of canal/precipitation/groundwater of 37%:53%:10% in the wet season and 40%:55%:5% in the dry season with an error of
±25%. For a bay-wide water budget that includes saltwater and freshwater mixing, fresh groundwater accounts for 1–2% of the
total fresh and saline water input. 相似文献