Ichnology of the Callovian-Oxfordian rocks of the Katrol hill range,Kachchh, western India

On the basis of distinct lithologic features such as composition, grain size, bedding characteristics and sedimentary structures, six facies were identified in Callovian to Oxfordian rocks exposed southwest of Bhuj, Kachchh. They are interbedded calcareous shale-siltstone (ICSSF), limestone (LF), ferruginous sandstone (FerSF), felspathic sandstone (FelSF), grey shale (GSF) and oolitic limestone (OLF) facies. The rich and highly diversified trace fossils reveal a wide range of animal behaviours represented by dwelling, feeding, crawling and resting structures. Horizontal feeding structures are found abundantly in all lithofacies indicating low wave and current energy and deposition of poorly sorted muddy to sandy sediments. A few coarse layers containing Arenicolites, Ophiomorpha and Skolithos indicate the presence of opportunistic animals (due to their first appearance under harsh conditions) under -intermittently moderate wave and current energy or storm wave conditions (due to coarse grain size and dominance/presence of only vertical trace fossils) in the shoreface zone. Taenidium occurs mainly in the lower shoreface to transitional zone suggesting low to moderate energy conditions. Thalassinoides occurs in middle to lower shoreface settings under relatively low-energy conditions. Zoophycos represents offshore environment, where it occupies the deepest bioturbation levels.The characteristic lithofacies and assemblages of trace fossils in the rocks of the Chari/Jumara Formation indicate a depositional environment fluctuating from the upper shoreface to offshore zone.     

Petrography and geochemistry of Jumara Dome sediments,Kachchh Basin: Implications for provenance,tectonic setting and weathering intensity

In the Kachchh Mainland, the Jumara Dome mixed carbonate-siliciclastic succession is represented by the Jhurio and Patcham formations and siliciclastic-dominating Chari Formation （Bathonian to Oxfordian）. The Ju- mara Dome sediments were deposited during sea-level fluctuating, and were interrupted by storms in the shallow marine environment. The sandstones are generally medium-grained, moderately sorted, subangular to subrounded and of low sphericity. The sandstones are mineralogically mature and mainly composed of quartzarenite and subar- kose. The plots of petrofacies in the Qt-F-L, Qm-F-Lt, Qp-Lv-Ls and Qm-P-K ternary diagrams suggest mainly the basement uplift source （craton interior） in rifted continental margin basin setting. The sandstones were cemented by carbonate, iron oxide and silica overgrowth. The Chemical Index of Alteration values （73% sandstone and 81% shale） indicate high weathering conditions in the source area. Overall study suggests that such strong chemical weathering conditions are of unconformity with worldwide humid and warm climates during the Jurassic period. Positive correlations between A1203 and Fe203, TiO2, Na20, MgO, K20 are evident. A high correlation coefficient between A1203 and K20 in shale samples suggests that clay minerals control the major oxides, The analogous con- tents of Si, A1, Ti, LREE and TTE in the shale to PAAS with slightly depleted values of other elements ascribe a PAAS like source （granitic gneiss and minor mafics） to the present study. The petrographic and geochemical data strongly suggest that the studied sandstones/shales were deposited on a passive margin of the stable intracratonic basin.     

Comparison of earthquake source characteristics in the Kachchh Rift Basin and Saurashtra horst,Deccan Volcanic Province,western India

Seismic source parameters of small to moderate sized intraplate earthquakes that occurred during 2002–2009 in the tectonic blocks of Kachchh Rift Basin (KRB) and the Saurashtra Horst (SH), in the stable continental region of western peninsular India, are studied through spectral analysis of shear waves. The data of aftershock sequence of the 2001 Bhuj earthquake (\(M_{w}\) 7.7) in the KRB and the 2007 Talala earthquake (\(M_{w}\) 5.0) in the SH are used for this study. In the SH, the seismic moment (\(M_{o})\), corner frequency \((f_{c})\), stress drop (\(\varDelta \sigma \)) and source radius (r) vary from \(7.8\times 10^{11}\) to \(4.0\times \)10\(^{16}\) N-m, 1.0–8.9 Hz, 4.8–10.2 MPa and 195–1480 m, respectively. While in the KRB, these parameters vary from \(M_{o} \sim 1.24 \,\times \, 10^{11}\) to \(4.1 \times 10^{16}\) N-m, \(f_{c }\sim \) 1.6 to 13.1 Hz, \(\varDelta \sigma \sim 0.06\) to 16.62 MPa and \(r \sim 100\) to 840 m. The kappa (K) value in the KRB (0.025–0.03) is slightly larger than that in the SH region (0.02), probably due to thick sedimentary layers. The estimated stress drops of earthquakes in the KRB are relatively higher than those in SH, due to large crustal stress concentration associated with mafic/ultramafic rocks at the hypocentral depths. The results also suggest that the stress drop value of intraplate earthquakes is larger than the interplate earthquakes. In addition, it is observed that the strike-slip events in the SH have lower stress drops, compared to the thrust and strike-slip events.     

Provenance,tectonic setting,source weathering and palaeoenvironmental implications of Middle-Upper Jurassic rocks of Ler dome,Kachchh, western India: Inferences from petrography and geochemistry

The Middle-Upper Jurassic sandstones and shales of Ler dome (Chari and Katrol Formations), Kachchh, western India, have been analyzed for modal, bulk mineralogy and geochemistry to deduce their provenance, tectonic setting, source area weathering and palaeoenvironmental conditions. The detrital modes of Ler dome sandstones indicate that they were emanated from recycled orogen (uplifted shoulders of rift) and stable cratonic source in passive margin setting. Rapid deposition of sediments from a granitic source area can be predicted from feldspar abundance. A highly mature heavy mineral assemblage characterized in the form of high Zircon-Tourmaline-Rutile (ZTR) index also endorses these findings. The X-ray diffraction patterns (XRD) and scanning electron microscope (SEM) data show the presence of clay minerals depicting moderate to extensive chemical weathering in an oxidizing environment with periodic cycles of transgression and regression. The chemical index of weathering, chemical index of alteration and plagioclase index of alteration suggest moderate to high and low to moderate weathering conditions for sandstone and shales, respectively, that took place in low to moderate relief. We postulate that Ler dome sediments are derivative of the eroded and weathered parts of the Aravalli craton located on east and northeast of the basin and the Nagarparkar Massif placed to the north and northwest.     

Facies analysis and depositional environment of the Jurassic, Jumara Dome sediments, Kachchh, western India

The study deals with the depositional environment of Jumara Dome sediments. The Jumara Dome is an important outcrop of Bathonian to Oxfordian sediments amongst the Kachchh Mainland exposures. On the basis of facies analysis three associations have been documented, namely, G-1 consisting of low energy facies comprising of cross-bedded sandstone, massive sandstone, grey shale and thin bedded sandstone, bioclastic — lithoclastic grainstone, bioclastic — lithoclastic packstone, microbioclastic packstone/wackestone, bioturbated laminated wackestone to mudstone and pelagic lime mudstone; G-II consisting of moderate energy facies comprising of laminated sandstone and grapestone or agglutinated grainstone; G-III consisting of high energy facies comprising of interbedded gypsiferous shale and sandstone/siltstone, oolitic grainstone to conglomerate and bioclastic grainstone. The facies associations reflect an ideal shallowing upward sequence representing slope, bioclast bar, lagoon and inner shelf. Presence of wide range of facies indicates that the rocks of the studied area were deposited during the fluctuating sea level, interrupted by the storms, in the shallow marine environment.     

Deciphering condensed sequences: A case study from the Oxfordian (Upper Jurassic) Dhosa Oolite member of the Kachchh Basin,western India

In large parts of the Kachchh Basin, a Mesozoic rift basin situated in western India, the Oxfordian succession is characterized by strong condensation and several depositional gaps. The top layer of the Early to Middle Oxfordian Dhosa Oolite member, for which the term ‘Dhosa Conglomerate Bed’ is proposed, is an excellent marker horizon. Despite being mostly less than 1 m thick, this unit can be followed for more than 100 km throughout the Kachchh Mainland. A detailed sedimentological analysis has led to a complex model for its formation. Signs of subaerial weathering, including palaeokarst features, suggest at least two phases of emersion of the area. Metre‐sized concretionary slabs floating in a fine‐grained matrix, together with signs of synsedimentary tectonics, point to a highly active fault system causing recurrent earthquakes in the basin. The model takes into account information from outcrops outside the Kachchh Mainland and thereby considerably refines the current understanding of the basin history during the Late Jurassic. Large fault systems and possibly the so‐called Median High uplift separated the basin into several sub‐basins. The main reason for condensation in the Oxfordian succession is an inversion that affected large parts of the basin by cutting them off from the sediment supply. The Dhosa Conglomerate Bed is an excellent example, demonstrating the potential of condensed units in reconstructing depositional environments and events that took place during phases of non‐deposition. Although condensed sequences occur frequently throughout the sedimentary record, they are particularly common around the Callovian to Oxfordian transition. A series of models has been proposed to explain these almost worldwide occurrences, ranging from eustatic sea‐level highstands to glacial phases connected with regressions. The succession of the Kachchh Basin shows almost stable conditions across this boundary with only a slight fall in relative sea‐level, reaching its minimum not before the late Early Oxfordian.     

Intrinsic and scattering attenuation in western India from aftershocks of the 26 January, 2001 Kachchh earthquake

176 vertical-component, short period observations from aftershocks of the M_w 7.7, 26 January, 2001 Kachchh earthquake are used to estimate seismic wave attenuation in western India using uniform and two layer models. The magnitudes (M_w) of the earthquakes are less than 4.5, with depths less than 46 km and hypocentral distances up to 110 km. The studied frequencies are between 1 and 30 Hz. Two seismic wave attenuation factors, intrinsic absorption (Q_i^− 1) and scattering attenuation (Q_s^− 1) are estimated using the Multiple Lapse Time Window method which compares time integrated seismic wave energies with synthetic coda wave envelopes for a multiple isotropic scattering model. We first assume spatial uniformity of Q_i^− 1, Q_s^− 1 and S wave velocity (β). A second approach extends the multiple scattering hypothesis to media consisting of several layers characterized by vertically varying scattering coefficient (g), intrinsic absorption strength (h), density of the media (ρ) and shear wave velocity structure. The predicted coda envelopes are computed using Monte Carlo simulation. Results show that, under the assumption of spatial uniformity, scattering attenuation is greater than intrinsic absorption only for the lowest frequency band (1 to 2 Hz), whereas intrinsic absorption is predominant in the attenuation process at higher frequencies (2 to 30 Hz). The values of Q obtained range from Q_t = 118, Q_i = 246 and Q_s = 227 at 1.5 Hz to Q_t ≈ 4000, Q_i ≈ 4600 and Q_s ≈ 33,300 at 28 Hz center frequencies, being Q_t^− 1 a measure of total attenuation. Results also show that Q_i^− 1, Q_s^− 1 and Q_t^− 1 decrease proportional to f^−ν. Two rates of decay are clearly observed for the low (1 to 6 Hz) and high (6 to 30 Hz) frequency ranges. Values of ν are estimated as 2.07 ± 0.05 and 0.44 ± 0.09 for total attenuation, 1.52 ± 0.21 and 0.48 ± 0.09 for intrinsic absorption and 3.63 ± 0.07 and 0.06 ± 0.08 for scattering attenuation for the low and high frequency ranges, respectively. Despite the lower resolution in deriving the attenuation parameters for a two layered crust, we find that scattering attenuation is comparable to or smaller than the intrinsic absorption in the crust whereas intrinsic absorption dominates in the mantle. Also, for a crustal layer of thickness 42 km, intrinsic absorption and scattering estimates in the crust are lower and greater than those of the mantle, respectively.     

柴达木盆地西部第四纪气候变化和流域风化

长期以来关于构造隆升、气候变化和大陆化学风化的相互关系存在诸多争议。在气候和构造相互作用典型区域建立高精度大陆化学风化序列是解决上述科学问题的有效途径之一。位于青藏高原东北缘长期封闭的柴达木盆地,其独特的位置和连续的沉积使其成为研究构造隆升、气候变化和大陆化学风化的理想场所。本文以柴达木盆地西部千米深钻SG-1钻孔高质量的连续细粒湖相岩芯为研究对象,使用盐类矿物的硫酸根和钾离子含量、碳酸盐锰含量和硅酸盐化学蚀变指数（CIA）和Nd同位素分析,重建该区第四纪以来湖泊流域气候变化过程和硅酸盐化学风化及可能的物源变化。结果表明柴达木盆地西部第四纪以来流域物源相对稳定,流域整体呈现出气候干旱化、流域硅酸盐风化强度减弱、湖水盐度增加和湖面降低的长期一致性演化过程;上述演化进程在2.2 Ma到2.0 Ma期间短暂加强,在约1.2 Ma和约0.6~0.5 Ma出现逐步加强趋势。过去60万年,柴达木盆地西部在冰期存在的相对高湖面时期与黄土高原粒度指标反映的冬季风减弱阶段可以很好对比。北大西洋海表温度反映的高纬过程是长时间尺度（>105年）驱动柴达木盆地西部气候变化和流域硅酸盐风化强度变化的主要因素;西伯利亚高压系统和西风系统的"跷跷板关系"可能是冰期-间冰期或者更短尺度影响柴达木盆地西部气候变化的主要因素。     

Chemical weathering in the Krishna Basin and Western Ghats of the Deccan Traps, India: Rates of basalt weathering and their controls

Rates of chemical and silicate weathering of the Deccan Trap basalts, India, have been determined through major ion measurements in the headwaters of the Krishna and the Bhima rivers, their tributaries, and the west flowing streams of the Western Ghats, all of which flow almost entirely through the Deccan basalts.Samples (n = 63) for this study were collected from 23 rivers during two consecutive monsoon seasons of 2001 and 2002. The Total dissolved solid (TDS) in the samples range from 27 to 640 mg l⁻¹. The rivers draining the Western Ghats that flow through patches of cation deficient lateritic soils have lower TDS (average: 74 mg l⁻¹), whereas the Bhima (except at origin) and its tributaries that seem to receive Na, Cl, and SO₄ from saline soils and anthropogenic inputs have values in excess of 170 mg l⁻¹. Many of the rivers sampled are supersaturated with respect to calcite. The chemical weathering rates (CWR) of “selected” basins, which exclude rivers supersaturated in calcite and which have high Cl and SO₄, are in range of ∼3 to ∼60 t km⁻² y⁻¹. This yields an area-weighted average CWR of ∼16 t km⁻² y⁻¹ for the Deccan Traps. This is a factor of ∼2 lower than that reported for the Narmada-Tapti-Wainganga (NTW) systems draining the more northern regions of the Deccan. The difference can be because of (i) natural variations in CWR among the different basins of the Deccan, (ii) “selection” of river basin for CWR calculation in this study, and (iii) possible contribution of major ions from sources, in addition to basalts, to rivers of the northern Deccan Traps.Silicate weathering rates (SWR) in the selected basins calculated using dissolved Mg as an index varies between ∼3 to ∼60 t km⁻² y⁻¹, nearly identical to their CWR. The Ca/Mg and Na/Mg in these rivers, after correcting for rain input, are quite similar to those in average basalts of the region, suggesting near congruent release of Ca, Mg, and Na from basalts to rivers. Comparison of calculated and measured silicate-Ca in these rivers indicates that at most ∼30% of Ca can be of nonsilicate origin, a likely source being carbonates in basalts and sediments.The chemical and silicate weathering rates of the west flowing rivers of the Deccan are ∼4 times higher than the east flowing rivers. This difference is due to the correspondingly higher rainfall and runoff in the western region and thus reemphasises the dominant role of runoff in regulating weathering rates. The silicon weathering rate (SWR) in the Krishna Basin is ∼15 t km⁻² y⁻¹, within a factor of ∼2 to those in the Yamuna, Bhagirathi, and Alaknanda basins of the Himalaya, suggesting that under favourable conditions (intense physical weathering, high runoff) granites and the other silicates in the Himalaya weather at rates similar to those of Deccan basalts. The CO₂ consumption rate for the Deccan is deduced to be ∼3.6 × 10⁵ moles km⁻² y⁻¹ based on the SWR. The rate, though, is two to three times lower than reported for the NTW rivers system; it still reinforces the earlier findings that, in general, basalts weather more rapidly than other silicates and that they significantly influence the atmospheric CO₂ budget on long-term scales.     

Assessment of predominant frequencies using ambient vibration in the Kachchh region of western India: implications for earthquake hazards

The Kachchh region is the second most seismically active region in India after the Himalaya. One of the disastrous Indian earthquakes of the millennium was the Bhuj earthquake of January 26, 2001, which caused about 14,000 casualties and huge property damage. The main reason for such devastation is due to lack of earthquake awareness and poor construction practices. Hence, an increase in the knowledge and awareness, based on improved seismic hazard assessment, is required to mitigate damage due to an earthquake. Natural predominant ground frequencies have been investigated in the Kachchh region of western India using ambient vibrations. The horizontal-to-vertical spectral ratio technique has been applied to estimate the predominant frequency at 126 sites. The ambient vibration measurements were conducted for about 1 h at each site in the continuous mode recording at 100 samples/s. We have validated the estimated predominant frequency with earthquake data recorded at six broadband stations in the region. It has been observed that geological time period has a significant effect on predominant frequency of the ground. The estimated predominant frequencies vary from 0.24 to 2.25 Hz for the Quaternary, 0.41–2.34 Hz for the Tertiary, 0.32–4.91 Hz for the Cretaceous, and 0.39–8.0 Hz for the Jurassic/Mesozoic. In the Deccan trap, it varies from 1.30 to 3.80 Hz. We found distinct variation of predominant frequencies of sites associated with hard rock and soft soil. The predominant frequencies were related to the thickness of the sediments, which are deduced by other geophysical and geological methods in the region. Our results suggest that frequencies of the region reveals the site characteristics that can be considered for studying the seismic risks to evolve a plan for disaster risk mitigation for the region.     

Petrography of Middle Jurassic to Early Cretaceous sandstones in the Kutch Basin,western India:Implications on provenance and basin evolution

This paper investigates the provenance of Middle Jurassic to Early Cretaceous sediments in the Kutch Basin, western India, on the basis of mineralogical investigations of sandstones composition(Quartz-Feldspar-Lithic(QFL)fragment), Zircon-Tourmaline-Rutile(ZTR) index, and mineral chemistry of heavy detrital minerals of the framework.The study also examines the compositional variation of the sandstone in relation to the evolution of the Kutch Basin, which originated as a rift basin during the Late Triassic and evolved into a passive margin basin by the end Cretaceous. This study analyzes sandstone samples of Jhumara, Jhuran and Bhuj Formations of Middle Jurassic,Upper Jurassic and Lower Cretaceous, respectively, in the Kutch Mainland. Sandstones record a compositional evolution from arkosic to subarkosic as the feldspar content decreases from 68% in the Jhumara Formation to 27%in the Bhuj Formation with intermediate values in the Jhuran Formation. The QFL modal composition indicates basement uplifted and transitional continental settings at source. Heavy mineral content of these sandstones reveals the occurrence of zircon, tourmaline, rutile, garnet, apatite, monazite and opaque minerals. Sub-rounded to well-rounded zircon grains indicate a polycyclic origin. ZTR indices for samples in Jhumara, Jhuran and Bhuj Formations are 25%, 30% and 50% respectively. Chemistry of opaque minerals reveals the occurrence of detrital varieties such as ilmenite, rutile, hematite/magnetite and pyrite, in a decreasing order of abundances. Chemistry of ilmenites in the Jhumara Formation reveals its derivation from dual felsic igneous and metabasic source, while those in Jhuran and Bhuj Formations indicate a metabasic derivation. Chemistry of garnet reveals predominantly Fe-rich(almandine) variety of metabasic origin. X-ray microscopic study provides the percentage of heavy minerals ranging from 3% to 5.26%. QFL detrital modes reflect the evolution of the basin from an active rift to a passive margin basin during the Mesozoic. Integration of results from QFL modal composition of the sandstones, heavy mineral analysis and mineral chemistry, suggests sediment supply from both northern and eastern highlands during the Middle Jurassic. The uplift along the Kutch Mainland Fault in the Early Cretaceous results in curtailment of sediment input from north.     

Petrography and geochemistry of Jurassic sandstones from the Jhuran Formation of Jara dome,Kachchh basin,India: Implications for provenance and tectonic setting

Sandstones of Jhuran Formation from Jara dome, western Kachchh, Gujarat, India were studied for major, trace and rare earth element (REE) geochemistry to deduce their paleo-weathering, tectonic setting, source rock characteristics and provenance. Petrographic analysis shows that sandstones are having quartz grains with minor amount of K-feldspar and lithic fragments in the modal ratio of Q ₈₉:F ₇:L ₄. On the basis of geochemical results, sandstones are classified into arkose, sub-litharenite, wacke and quartz arenite. The corrected CIA values indicate that the weathering at source region was moderate to intense. The distribution of major and REE elements in the samples normalized to upper continental crust (UCC) and chondrite values indicate similar pattern of UCC. The tectonic discrimination diagram based on the elemental concentrations and elemental ratios of Fe₂O₃ + MgOvs. TiO₂, SiO₂ vs. log(K₂O/Na₂O), Sc/Cr vs. La/Y, Th–Sc–Zr/10, La–Th–Sc plots Jhuran Formation samples in continental rift and collision settings. The plots of Ni against TiO₂, La/Sc vs. Th/Co and V–Ni–Th ?10 reveals that the sediments of Jhuran Formation were derived from felsic rock sources. Additionally, the diagram of (Gd/Yb) _N against Eu/Eu ^? suggest the post-Archean provenance as source possibly Nagar Parkar complex for the studied samples.     

Bedrock gorges in the central mainland Kachchh: Implications for landscape evolution

Kachchh possesses a fault-controlled first-order topography and several geomorphic features indicative of active tectonics. Though coseismic neotectonic activity is believed to be the major factor in the evolution of the landscape, detailed documentation and analysis of vital landscape features like drainage characteristics, bedrock gorges and terraces are lacking. The present study is a site-specific documentation of gorges developed in the central part of the mainland Kachchh. We analyzed and interpreted four gorges occurring on either side of Katrol Hill Fault (KHF). The Khari river gorge is endowed with six levels of bedrock terraces, some of which are studded with large potholes and flutings. Since no active development of potholes is observed along the rivers in the present day hyper-arid conditions, we infer an obvious linkage of gorges to the humid phases, which provided high energy runoff for the formation of gorges and distinct bedrock terraces and associated erosional features. Development of gorges within the miliolites and incision in the fluvial deposits to the south of the KHF indicates that the gorges were formed during Early Holocene. However, ubiquitous occurrence of gorges along the streams to the south of KHF, the uniformly N40‡ E trend of the gorges, their close association with transverse faults and the short length of the exceptionally well developed Khari river gorge in the low-relief rocky plain to the north of KHF suggests an important role of neotectonic movements     

Petrography and geochemical characteristics of the sediments of the small River Hemavati, Southern India: Implications for provenance and weathering processes

Small rivers (≤ 100 km length) are likely to drain fewer rock types. Therefore, their solutes and sediments are good indicators of weathering environments typical of their basins and help constraining the nature of their source rocks. To understand this, the texture, mineralogy, major and trace element compositions of the sediments deposited by the River Hemavati, a northern upland tributary of the Cauvery River in southern India, are analyzed and discussed.

The Hemavati sediments are overall of fine sand size (mean 2–3), and have high concentrations of FeO (≤ 7 wt.%), TiO₂ (≤ 1.2 wt.%), Cr (≤ 350 ppm) and Ni (≤ 125 ppm). Major and trace element distribution call for a binary source for the sediments, and particularly point to contrasting climatic conditions of their provenances. The source areas in the upstream and downstream parts are exposed to sub-humid high relief and sub-arid low relief conditions, respectively, with distinct weathering characteristics. The CIA values (85–48) decrease from near the source to downstream, suggesting that the downstream rain-shadow part of the catchment suffered only minor chemical weathering.

On the other hand, the REE distribution in the Hemavati sediments indicates contrasting lithologies in their provenance, and is not controlled by chemical weathering. On the basis of REE patterns, the sediments are divided into two compositional groups. The Type 1 sediments have a REE chemistry similar to the upper continental crust, and have been derived from the > 3.2 Ga composite peninsular gneisses occurring in the low-lying, semi-arid Mysore Plateau. The Type 2 sediments, however, have dominantly intermediate to mafic granulite contributions from the tectonically uplifted Western Ghats, weathered under sub-humid conditions. High concentrations of FeO, TiO₂, Cr and Ni in the sediments suggest mafic-dominated source lithologies in the upper catchment, a feature also confirmed by field observations and petrographic study.     

Seasonality in low latitudes during the Oxfordian (Late Jurassic) reconstructed via high-resolution stable isotope analysis of the oyster Actinostreon marshi (J. Sowerby, 1814) from the Kachchh Basin, western India

A high-resolution stable isotope (δ¹⁸O, δ¹³C) analysis of a specimen of the oyster Actinostreon marshi (J. Sowerby, 1814) from the Lower Oxfordian of the Kachchh Basin in western India was used to reconstruct average seasonal temperatures over a consecutive time interval of 10 years. The recorded temperatures during this period varied around a mean of 13 °C (maximum: 15.1 °C; minimum: 11.4 °C) with a generally low seasonality between 1 and 3 °C. Such weak seasonal changes can be expected from a subtropical palaeolatitude between 25° and 30°S. However, the low average temperatures are in contrast to studies on broadly contemporaneous fossils from Europe and the southern Malagasy Gulf which point to much warmer conditions in these areas. It is therefore proposed that the low temperatures in the Kachchh Basin are caused by upwelling currents which influenced the north-western coast of India during the Late Jurassic.     

Uranium isotopes in rivers,estuaries and adjacent coastal sediments of western India: their weathering,transport and oceanic budget

The two major river systems on the west coast of India, Narbada and Tapti, their estuaries and the coastal Arabian sea sediments have been extensively studied for their uranium concentrations and ${}^{238}\text{U}{}^{238}\text{U}$ activity ratios.The ²³⁸U concentrations in the aqueous phase of these river systems exhibit a strong positive correlation with the sum of the major cations, σ Na + K + Mg + Ca, and with the HCO₃^? ion contents. The abundance ratio of dissolved U to the sum of the major cations in these waters is similar to their ratio in typical crustal rocks. These findings lead us to conclude that ²³⁸U is brought into the aqueous phase along with major cations and bicarbonate. The strong positive correlation between ²³⁸U and total dissolved salts for selected rivers of the world yield an annual dissolved ²³⁸U flux of 0.88 × 10¹⁰g/yr to the oceans, a value very similar to its removal rate from the oceans, 1.05 × 10¹⁰g/yr, estimated based on its correlation with HCO₃^? contents of rivers.In the estuaries, both ²³⁸U and its great-grand daughter ²³⁴U behave conservatively beyond chlorosities 0.14 g/l. These data confirm our earlier findings in other Indian estuaries. The behavior of uranium isotopes in the chlorosity zone 0.02–0.14 g/l, was studied in the Narbada estuary in some detail. The results, though not conclusive, seem to indicate a minor removal of these isotopes in this region. Reexamination of the results for the Gironde and Zaire estuaries (Martin et al., 1978a and b) also appear to confirm the conservative behavior of U isotopes in unpolluted estuaries. It is borne out from all the available data that estuaries beyond 0.14 g/l chlorosities act neither as a sink nor as a source for uranium isotopes, the behavior in the low chlorosity zones warrants further detailed investigation.A review of the uranium isotope measurements in river waters yield a discharge weighted-average ²³⁸U concentration of 0.22 μg/l with a ${}^{234}\text{U}{}^{238}\text{U}$ activity ratio of 1.20 ± 0.06ismissing. The residence time of uranium isotopes in the oceans estimated from the ²³⁸U concentration and the ${}^{234}\text{U}{}^{238}\text{U}$ A. R. of the rivers yield conflicting results; the material balance of uranium isotopes in the marine environment still remains a paradox. If the disparity between the results is real, then an additional ²³⁴U flux of about 0.25 dpm/cm₂·10³ yr into the oceans (about 20% of its river supply) is necessitated.     

四川盆地西南缘龙马溪组泥岩地球化学特征及物源区和构造背景分析

本文对川西南荥经地区龙马溪组泥岩的岩石学、矿物学及元素地球化学开展了研究,探讨了龙马溪组沉积环境、物源区属性及构造背景。结果表明,研究区龙马溪组泥岩砂质、钙质含量较高,指示其沉积水体较浅。稀土元素特征及及A—CN—K图解说明龙马溪组泥岩组成较少受成岩及交代作用影响,样品较完整地保存了物源和风化作用信息。K2O、Rb、Al2O3 /TiO2含量较高及Eu负异常指示其母岩为偏酸性的长英质岩、花岗岩类,推测主要来自康滇古陆新元古代早期地台盖层。ICV值大于1,CIA平均值为66,Th/U与地壳UCC值相近,Rb/Sr值明显低于PAAS,指示其物源为近源初次旋回的快速沉积产物,受化学风化作用较小,沉积环境为干燥、寒冷环境。La/Yb、LREE/HREE及Sc/Cr等值均与被动大陆边缘值相近,结合Sc/Cr—La/Y等判别图解,说明研究区沉积构造背景主要为被动大陆边缘。     

Lithostratigraphic development and neotectonic significance of the Quaternary sediments along the Kachchh Mainland Fault (KMF) zone,western India

The Kachchh Mainland Fault (KMF) is a major E–W trending seismically active fault of the Kachchh palaeorift basin whose neotectonic evolution is not known. The present study deals with the eastern part of the KMF zone where the fault is morphologically expressed as steep north facing scarps and is divisible into five morphotectonic segments. The Quaternary sediments occurring in a narrow zone between the E–W trending KMF scarps and the flat Banni plain to the north are documented. The sediments show considerable heterogeneity vertically as well as laterally along the KMF zone. (The Quaternary sediments for a northward sloping and are exposed along the north flowing streams which also show rapid decrease in the depth of incision in the same direction.) The deposits, in general, comprise coarse as well as finer gravelly deposits, sands and aeolian and fluvial miliolites. The Quaternary sediments of the KMF zone show three major aggradation phases. The oldest phase includes the colluvio-fluvial sediments occurring below the miliolites. These deposits are strikingly coarse grained and show poor sorting and large angular clasts of Mesozoic rocks. The sedimentary characteristics indicate deposition, dominantly by debris flows and sediment gravity flows, as small coalescing alluvial fans in front of the scarps. These deposits suggest pre-miliolite neotectonic activity along the KMF. The second aggradation phase comprises aeolian miliolites and fluvially reworked miliolites that have been previously dated from middle to late Pleistocene. The youngest phase is the post-miliolite phase that includes all deposits younger than miliolite. These are represented by comparatively finer sandy gravels, gravelly sands and sand. The sediment characteristics suggest deposition in shallow braided stream channels under reduced level of neotectonic activity along the KMF during post-miliolite time evidenced by vertical dips of miliolites and tilting of gravels near the scarps. The tectonically controlled incision and dissection of the Quaternary deposits is the result of neotectonic activity that continues at present day. The overall nature, sedimentary characteristics and geomorphic setting of the sediments suggest that the KMF remained neotectonically active throughout the Quaternary period.     

Behaviour of lithium and its isotopes during weathering in the Mackenzie Basin, Canada

We report Li isotopic compositions, for river waters and suspended sediments, of about 40 rivers sampled within the Mackenzie River Basin in northwestern Canada. The aim of this study is to characterize the behaviour of Li and its isotopes during weathering at the scale of a large mixed lithology basin. The Mackenzie River waters display systematically heavier Li isotopic compositions relative to source rocks and suspended sediments. The range in δ⁷Li is larger in dissolved load (from +9.3‰ to +29.0‰) compared to suspended sediments (from −1.7‰ to +3.2‰), which are not significantly different from δ⁷Li values in bedrocks. Our study shows that dissolved Li is essentially derived from the weathering of silicates and that its isotopic composition in the dissolved load is inversely correlated with its relative mobility when compared to Na. The highest enrichment of ⁷Li in the dissolved load is reported when Li is not or poorly incorporated in secondary phases after its release into solution by mineral dissolution. This counterintuitive observation is interpreted by the mixing of water types derived from two different weathering regimes producing different Li isotopic compositions within the Mackenzie River Basin. The incipient weathering regime characterizing the Rocky Mountains and the Shield areas produces ⁷Li enrichment in the fluid phase that is most simply explained by the precipitation of oxyhydroxide phases fractionating Li isotopes. The second weathering regime is found in the lowland area and produces the lower δ⁷Li waters (but still enriched in ⁷Li compared to bedrocks) and the most Li-depleted waters (compared to Na). Fractionation factors suggest that the incorporation of Li in clay minerals is the mechanism that explains the isotopic composition of the lowland rivers. The correlation of boron and lithium concentrations found in the dissolved load of the Mackenzie Rivers suggests that precipitation of clay minerals is favoured by the relatively high residence time of water in groundwater. In the Shield and Rocky Mountains, Li isotopes suggest that clay minerals are not forming and that secondary minerals with stronger affinity for ⁷Li appear.Although the weathering mechanisms operating in the Mackenzie Basin need to be characterized more precisely, the Li isotope data reported here clearly show the control of Li isotopes by the weathering intensity. The spatial diversity of weathering regimes, resulting from a complex combination of factors such as topography, geology, climate and hydrology explains, in fine, the spatial distribution of Li isotopic ratios in the large drainage basin of the Mackenzie River. There is no simple relationship between Li isotopic composition and chemical denudation fluxes in the Mackenzie River Basin.